Patent Grant
8215879
This application claims priority to Swedish Application No. 0702781-6 filed Dec. 14, 2007, the entire disclosure of which is incorporated herein by reference.
This invention relates to coated cemented carbide inserts (cutting tools) particularly useful for wet or dry machining of steels and stainless steels.
When machining low and medium alloyed steels and stainless steels with cemented carbide tools, the cutting edge is worn according to different wear mechanisms, such as chemical wear, abrasive wear, and adhesive wear and by edge chipping caused by cracks formed along the cutting edge. The domination of any of the wear mechanisms is determined by the application, and is dependent on properties of the machined material, applied cutting parameters, and the properties of the tool material. In general, it is very difficult to improve all tool properties simultaneously, and commercial cemented carbide grades have usually been optimized with respect to one or few of the above mentioned wear types, and have consequently been optimized for specific application areas.
WO 2007/069973 discloses a coated cutting tool insert particularly useful for dry and wet machining, preferably milling, in low and medium alloyed steels, stainless steels, with or without raw surface zones. The insert is characterized by a WC—TaC—NbC—Co cemented carbide with a W alloyed Co-binder phase and a coating including an innermost layer of TiCxNyOz with columnar grains and a top layer at least on the rake face of a smooth α-Al2O3.
U.S. Pat. No. 5,879,823 discloses a coated cutting tool with a (Ti,Al)N-layer applied by PVD and an alumina layer applied by PVD on top of the (Ti,Al)N-layer.
U.S. Pat. No. 5,310,607 discloses a hard coating including mainly (Al,Cr)2O3 crystals and a chrome content higher than 5 at % wherein the (Al,Cr)2O3 is a single crystal. The coating is deposited at a temperature lower or equal to 500° C. The hard coating is deposited by a CVD or PVD process.
What is needed is a coated cutting tool with enhanced performance for machining of steels and stainless steels. The invention is directed to these, as well as other, important needs.
Accordingly, the invention is directed to cutting tool inserts, comprising a cemented carbide substrate with a wear resisting coating comprising a first, innermost, layer of (Ti,Al)N and a second layer of (Al,Cr)2O3, particularly useful for wet or dry machining of steels and stainless steels.
In one embodiment, the invention is directed to cutting tool inserts, particularly useful for wet or dry machining of steels and stainless steels, comprising:
a cemented carbide substrate; and
a coating;
wherein said coating comprises:
a first (innermost) layer of Ti1-xAlxN with about 0.25≦x≦ about 0.7 with columnar grains and a total thickness of about 0.5-5 μm; and
In other embodiments, the invention is directed to methods for machining of steel or stainless steel, comprising the step of:
using a cutting tool insert described herein at cutting speeds of about 75-600 m/min with an average feed, per tooth in the case of milling, of about 0.08-0.5 mm.
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention. In the drawings:
1. Cemented carbide substrate,
2. Innermost (Ti,Al)N layer and
3. (Al,Cr)2O3 layer.
The coating deposited on a cemented carbide substrate comprises:
a first (innermost) layer of Ti1-xAlxN with about 0.25≦x≦ about 0.7, preferably x>about 0.4, more preferably x>about 0.6, with columnar grains and a total thickness of about 0.5-5 preferably, about 1-4 μm.
a layer of (Al1-yCry)2O3 with about 0.1≦y≦about 0.6, preferably with about 0.3≦y≦about 0.55, most preferably y=about 0.5, with a thickness of about 1-5 μm, preferably about 1.5-4.5 μm, more preferably about 2-4 with columnar grains.
In a further alternative embodiment, there is a thin, less than about 1 μm thick, TiN layer on top of the (Al,Cr)2O3 layer.
In a first embodiment, the cemented carbide substrate has a composition of about 9.3-10.9 wt-% Co, preferably about 9.75-10.7 wt-% Co, more preferably about 9.9-10.5 wt-% Co; about 0.5-2.5 wt-%, about preferably 1.0-2.0 wt-%, more preferably about 1.2-1.8 wt-% total amount of the metals Ti, Nb, and Ta; and balance WC. Ti, Ta, and/or Nb may also be partially or totally replaced by other elements from groups IVb, Vb, or VIb of the periodic table. The content of Ti is preferably on a level corresponding to a technical impurity. Preferably, the ratio between the weight concentrations of Ta and Nb is within about 7.0-12.0, preferably about 7.6-11.4, more preferably about 8.2-10.5. The cemented carbide has a coercivity (Hc) of about 10-15, preferably about 11-14, more preferably about 11.5-13.5 kA/m.
In a second embodiment the a cemented carbide substrate has a composition of about 4.7-5.9 wt-% Co, preferably about 4.9-5.6 wt-% Co, more preferably about 5.0-5.5 wt-% Co; about 5.0-10.0 wt-%, preferably about 6.0-9.0 wt-%, more preferably about 7.0-8.0 wt-% total amount of the metals Ti, Nb and Ta; and balance WC. Ti, Ta, and/or Nb may also be partially or totally replaced by other elements from groups IVb, Vb, or VIb of the periodic table. Preferably, the weight ratio between Ta and Nb is about 1.0-5.0, more preferably about 1.5-4.5. The cemented carbide has a coercivity (Hc) of about 11-17, preferably about 12-16, more preferably about 13-15 kA/m.
A cutting insert according to the invention are made by powder metallurgical technique, wet milling of powders forming hard constituents and binder phase, compacting the milled mixture to bodies of desired shape and size and sintering, comprising a cemented carbide substrate, with compositions according to the above, and a coating comprising a layer of (Ti,Al)N and a layer of (Al,Cr)2O3.
The layer of (Ti,Al)N is arc-deposited using known technique. The (Al,Cr)2O3 layer is deposited according to Example 1 in US 2007/0000772.
In an alternative embodiment, a thin, less than about 1 μm, TiN top layer is deposited on the (Al,Cr)2O3 layer using known techniques.
In a further preferred embodiment, the cutting tool insert as described above is treated after coating with a wet blasting or brushing operation, such that the surface quality of the coated tool is improved.
The invention also relates to the use of cutting tool inserts according to the above for wet or dry milling of steels and stainless steels at cutting speeds of about 75-600 m/min, preferably about 150-500 m/min, with an average feed, per tooth in the case of milling, of about 0.08-0.5 mm, preferably about 0.1-0.4 mm depending on cutting speed and insert geometry.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Although any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention, the preferred methods and materials are now described. All publications mentioned hereunder are incorporated herein by reference. Unless mentioned otherwise, the techniques employed or contemplated herein are standard methodologies well known to one of ordinary skill in the art. The materials, methods, and examples are illustrative only and not limiting.
The present invention is further defined in the following Examples, in which all parts and percentages are by weight and degrees are Celsius, unless otherwise stated. It should be understood that these examples, while indicating preferred embodiments of the invention, are given by way of illustration only. From the above discussion and these examples, one skilled in the art can ascertain the essential characteristics of this invention, and without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions.
Grade A: A cemented carbide substrate with the composition 10.3 wt % Co, 1.35 wt % Ta, 0.15 wt % Nb and balance WC, was produced by conventional milling of the powders, pressing of green compacts and subsequent sintering at 1430° C. The He value of the cemented carbide was 12.5 kA/m, indicating a mean intercept length of about 0.7 μm. The substrate was coated with a 3.0 μm thick layer of (Ti0.5Al0.5)N, according to known arc evaporation technique, columnar grains, a 2.9 μm thick layer of columnar (Al0.5Cr0.5)2O3 deposited according to Example 1 in US2007/0000772.
Grade B: Example 1 was repeated using a carbide substrate with the composition 5.3 wt % Co, 2.0 wt % Ti, 3.4 wt % Ta, 2.0 wt % Nb, and balance WC. The He value of the cemented carbide was 13.8 kA/m.
Grade C: A layer of 6.0 μm Ti0.33Al0.67N was deposited on the substrates according to Examples 1 and 2 using known arc evaporation techniques.
Grades A and C were tested in machining in steel.
The test was stopped at the same maximum flank wear. The wear resistance was much improved with the grade according to the invention.
Grades A and C were tested in machining in stainless steel.
The test was stopped at the same maximum flank wear. The wear resistance was much improved with the grade according to the invention.
Grades B and C were tested in machining in stainless steel.
The test was stopped at the same maximum flank wear. The wear resistance was much improved with the grade according to the invention.
Grades B and C were tested in machining in steel.
The test was stopped at the same maximum flank wear. The wear resistance was much improved with the grade according to the invention.
When ranges are used herein for physical properties, such as molecular weight, or chemical properties, such as chemical formulae, all combinations and subcombinations of ranges specific embodiments therein are intended to be included.
The disclosures of each patent, patent application, and publication cited or described in this document are hereby incorporated herein by reference, in their entirety.
Those skilled in the art will appreciate that numerous changes and modifications can be made to the preferred embodiments of the invention and that such changes and modifications can be made without departing from the spirit of the invention. It is, therefore, intended that the appended claims cover all such equivalent variations as fall within the true spirit and scope of the invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 0702781 | Dec 2007 | SE | national |
| Number | Name | Date | Kind |
|---|---|---|---|
| 5310607 | Schulz | May 1994 | A |
| 5656383 | Tanaka | Aug 1997 | A |
| 5750247 | Bryant | May 1998 | A |
| 5879823 | Prizzi | Mar 1999 | A |
| 6062776 | Sandman | May 2000 | A |
| 6200671 | Lindskog | Mar 2001 | B1 |
| 6333100 | Palmqvist | Dec 2001 | B1 |
| 6395379 | Braendle | May 2002 | B1 |
| 6632514 | Sulin | Oct 2003 | B1 |
| 6767627 | Morikawa | Jul 2004 | B2 |
| 7097901 | Larsson | Aug 2006 | B2 |
| 7132153 | Zackrisson | Nov 2006 | B2 |
| 7431542 | Hessman | Oct 2008 | B2 |
| 7674520 | Schier | Mar 2010 | B2 |
| 7767319 | Åkesson | Aug 2010 | B2 |
| 20040022662 | Lipkin | Feb 2004 | A1 |
| 20040033393 | Nordgren | Feb 2004 | A1 |
| 20040121147 | Morikawa | Jun 2004 | A1 |
| 20060219325 | Kohara | Oct 2006 | A1 |
| 20070000772 | Ramm | Jan 2007 | A1 |
| Number | Date | Country |
|---|---|---|
| 2002-053946 | Feb 2002 | JP |
| 2002053945 | Feb 2002 | JP |
| 9803691 | Jan 1998 | WO |
| 2007069973 | Jun 2007 | WO |
| Number | Date | Country | |
|---|---|---|---|
| 20110299950 A1 | Dec 2011 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 12332874 | Dec 2008 | US |
| Child | 13209652 | US |
