Patent Application
20160194748
The present invention relates to a coated cutting tool comprising a body and a coating designed to be used in metal cutting applications generating high tool temperatures. The coating comprising at least one Zr,Cr,Al-based nitride layer. The invention also relates to a method for coating the cutting tool and to the use of the cutting tool.
Since the mid 1980's, efforts have been made to improve the properties, for example, wear resistance and hence the performance of tool coatings. At that time, the common practice was to coat cutting tools with TiN. However, due to its relatively poor oxidation resistance at elevated temperatures, the focus has shifted towards more complex ternary and quaternary compounds, e.g. Ti-Al-N, Ti-Al-Si-N and Ti-Cr-Al-N with improved high temperature performance. For example, Ti-Al-Si-N has been reported as super hard, H >40 GPa, explained in terms of a two phase structure consisting of crystalline phase of NaCl-type in combination with x-ray amorphous Si3N4 or SiNx.
JP 20060082209 discloses a coated cutting tool with a coating comprising an upper layer and an lower layer each formed of (Cr,Al,Zr)N. The upper layer has an average thickness of 0.5-1.5 μm and the lower has an average thickness of 2-6 μm. The upper layer has a laminated structure of a thin layer A and a thin layer B, each thin layer having a thickness of 5-20 nm. The lower layer has the formula (Cr1-x-yAlxZry)N, where 0.55≦x≦0.75 and 0.05≦y≦0.15.
The thin layer A has the formula (Cr1-x-yAlxZry)N, where 0.25≦x≦0.40 and 0.20≦y≦0.30.
The thin layer B has the formula (Cr1-x-yAlxZry)N, where 0.55≦x≦0.75 and 0.05≦y≦0.15.
JP 2006289537 discloses a coated cutting tool with a coating comprising an upper layer and an lower layer each formed of (Cr,Al,Zr)N. The upper layer has an average thickness of 0.5-1.5 μm and the lower has an average thickness of 2-6 μm. The upper layer has a laminated structure of a thin layer A and a thin layer B. Each A and B layer having an average thickness of 5-20 nm. The lower layer has the formula (Cr1-x-yAlxZry)N, where 0.55≦x≦0.75 and 0.05≦y≦0.15.
The thin layer A has the formula (Cr1-x-yAlxZry)N, where 0.01≦x≦0.06 and 0.35≦y≦0.55.
The thin layer B has the formula (Cr1-x-yAlxZry)N, where 0.25≦x≦0.40 and 0.20≦y≦0.30.
WO200605217 discloses a coated cutting tool with a wear resistant coating comprising the following composition Al 1-a-b-c-d CraXbSicBdZ, where X is at least one element from Nb, Mo, W or Ta; Z is one element or compound from N, C, CN, NO, CO, CNO; and 0.2<=a<=0.5; 0.01<=b<=0.2; 0<=c<=0.1; 0<=d<=0.1.
JP2007007765 discloses a coated cutting tool with a coating comprising an upper layer and an lower layer each formed of (Cr,Al,Zr)N. The upper layer has an average thickness of 0.5-1.5 μm and the lower has an average thickness of 2-6 μm. The upper layer has a laminated structure of a thin layer A and a thin layer B. Each A and B layer having an average thickness of 5-20 nm. The lower layer has the formula (Cr1-x-yAlxZry)N, where 0.50≦x≦0.65 and 0.01≦y≦0.10.
The thin layer A has the formula (Cr1-x-yAlxZry)N, where 0.15≦x≦0.30 and 0.35≦y≦0.50.
The thin layer B has the formula (Cr1-x-yAlxZry)N, where 0.50≦x≦0.65 and 0.01≦y≦0.10.
Today industry continuously seeks solutions for economic and high productivity/feed-through manufacturing. To meet these demands there is a need for new materials with advanced properties to improve tool life during operation. Within the metal cutting tool industry, a major part of this effort is focused to improve the wear behavior of the cutting tools by designing the properties of the coating material used in the application. Typically, a high productivity/feed-through cutting process results in a dramatic increase of the tool temperature and hence a coating material with a high temperature wear resistance is essential.
It is an object of the present invention to provide a coating material with improved high temperature performance in metal cutting applications.
It is further an object of the present invention to provide a method for coating a cutting tool with said coating.
According to a first aspect of the invention the object is achieved by a coated cutting tool comprising a body with a hard and wear resistant coating on the body, the coating comprises at least one metal based nitride layer, wherein said layer is (ZrxCr1-x-y-zAlyMez)Na with 0.55<x<0.85, 0.05<y<0.45, 0≦z<0.20, 0.95<a<1.10, and Me is one or more of the elements selected from the group consisting of Y, Ti, V, Nb, Ta, Mo, W, Mn or Si, and that the layer comprises a single cubic phase or a single hexagonal phase or a mixture thereof, preferably a cubic phase of a sodium chloride structure, and that the layer has a thickness between 0.5 μm and 15 μm. Thereby a hard and wear resistant coating with high temperature wear resistance is achieved. The enhanced temperature properties of the coating are, for example, observed as an improved crater wear resistance in metal machining by chip removal generating high temperature performance.
According to one embodiment of the invention 0.60<x<0.80, preferably 0.65<x<0.75. According to an alternative embodiment to the above described embodiment 0.55<x≦0.70. According to yet an alternative embodiment of the above described embodiment 0.70<x<0.85.
According to one embodiment of the invention 0.05 <y <0.35, preferably 0.05 <y <0.25. According to an alternative embodiment to the above described embodiment 0.05<y≦0.20. According to yet an alternative embodiment to the above described embodiment 0.20 <y <0.45.
According to one embodiment of the invention 0≦z<0.15, preferably 0≦z <0.10, most preferably z =0. According to an alternative embodiment to the above described embodiment 0.0523 z<0.20, preferably 0.10≦z<0.15.
According to one embodiment of the invention Me is one or more of the elements selected from the group consisting of Ta, Ti, Nb and Si. By the addition of small amounts of one or more of the elements Ta, Ti, Nb and Si, excellent high temperature resistance is achieved.
According to one embodiment of the invention the at least one metal based nitride layer has a thickness between 0.5 μm and 10 μm, preferably between 0.5 μm and 5 μm.
According to one embodiment of the invention the at least one metal based nitride layer has a nanohardness >20 GPa, preferably the nanohardness is between 25 GPa and 40 GPa, most preferably between 30 GPa and 40 GPa.
According to one embodiment of the invention the coating consists of an innermost single layer and/or multilayer comprising, e.g., TiN, TiC, Ti(C,N) or (Ti,Al)N, preferably a single layer of (Ti,Al)N, followed by said (Zr,Cr,Al,Me)N layer and an outer single layer and/or multilayer comprising, e.g., TiN, TiC, Ti(C,N) or (Ti,Al)N, preferably a single layer of TiN, to a total coating thickness between 1 μm and 20 μm, preferably between 1 μm and 15 μm, and most preferably between 1 μm and 7 μm.
According to one embodiment of the invention the coated cutting tool is a cutting tool insert for machining by chip removal, said insert comprises a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel. According to an alternative embodiment the coated cutting tool is a drill or an end mill.
According to a second aspect of the invention the object is achieved by a method for making a coated cutting tool with a hard and wear resistant coating by growing a metal based nitride layer by cathodic arc evaporation with an evaporation current between 50 A and 200 A using composite and/or alloyed cathodes, wherein said layer is (ZrxCr1-x-y-zAlyMez)Na with 0.55 <x <0.85, 0.05 <y <0.45, 0≦z<0.20 and 0.95 <a <1.10, where Me is one or more of the elements: Y, Ti, V, Nb, Ta, Mo, W, Mn or Si, in a reactive atmosphere containing N2 and optionally with a carrier gas such as, e.g. Ar, at a total gas pressure between 1.0 Pa and 7.0 Pa, preferably between 1.5 Pa and 4.0 Pa, with a negative substrate bias between 0 V and 300 V, preferably between 10 V and 150 V, at a temperature between 200° C. and 800° C., preferably between 300° C. and 600° C.
According to a third aspect of the invention the object is achieved by use of a cutting tool insert for machining by chip removal, specifically generating high temperatures, at cutting speeds of 50-400 m/min, preferably 75-300 m/min, with an average feed, per tooth in the case of milling, of 0.08-0.5 mm, preferably 0.1-0.4 mm, depending on cutting speed and insert geometry.
According to one embodiment of the present invention, there is provided a body 1 onto which a hard and wear resistant coating is deposited comprising at least one metal based nitride layer 3 as shown in
The elemental composition of said layer, x, y and z including 0 and C, is estimated from measurements by, e.g., EDS or WDS techniques and is, within the measurement accuracy, essentially constant all through the layer thickness with a variation less than 10%, including the influence of normal process variations such as, e.g., rotation of the inserts during growth.
Said layer has a columnar microstructure with an average column width of <1 μm, preferably <0.6 μm, as determined by cross sectional transmission electron microscopy of a middle region of the layer, i.e. a region within 30% to 70% of the layer thickness in the growth direction, and said average columnar width is the average of at least 10 adjacent columns.
Said layer has a compressive stress level of −6.0 GPa <σ<−0.5 GPa, preferably of −3.0 GPa <σ<−1.0 GPa. The residual stress is evaluated by XRD using the sin2ψ-method with a Poisson's ratio of ν=0.23 and a Young's modulus of E =379 GPa.
Said layer has a nanohardness >20 GPa, as measured by nanoindentation measurements. Nanohardness data were estimated by the nanoindentation technique of the layers after mechanical polishing of the surface using a UMIS 2000 nanoindentation system with a Berkovich diamond tip with a maximum tip load of 25 mN.
According to one embodiment of the invention, z =0, and said layer is (ZrxCr1-x-yAly)Na with 0.55<x<0.85, preferably 0.60<x<0.80, most preferably 0.65 <x <0.75, 0.05 <y <0.45, preferably 0.05<y<0.35, most preferably 0.05<y<0.25, 0≦z<0.20 and 0.95 <a <1.10.
It is evident that said (Zr,Cr,Al,Me)N layer can be part of a complex coating design and used as an inner, middle and/or an outer layer of said complex coating.
According to one embodiment of the invention, said body is a cutting insert for machining by chip removal comprising a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel. It is, however, obvious that said body can be other metal cutting tools, e.g., drills and end mills.
The deposition method for said layer is based on PVD techniques, e.g., cathodic arc evaporation or magnetron sputtering using one or more pure, composite and/or alloyed (Zr,Cr,Al, Me) cathodes/targets.
In the case of cathodic arc evaporation, the metal based nitride layer is grown with an evaporation current between 50 A and 200 A depending on the cathode size, and said layer is (ZrxCr1 -x-y-zAlyMez)Na with 0.55 <x <0.85, 0.05 <y <0.45, 0≦z<0.20 and 0.95 <a <1.10. A higher evaporation current is needed for larger cathodes in order to achieve comparable deposition conditions. The layers are grown using one or more composite and/or alloyed cathodes. The desired layer composition is obtained by selecting appropriate composition of the (Zr,Cr,Al,Me) cathode and gas atmosphere, where Me, when present in the layer, is one or more of the elements selected from the group consisting of Y, Ti, V, Nb, Ta, Mo, W, Mn and Si in a reactive atmosphere containing N2 and optionally with a carrier gas such as, e.g., Ar at a total gas pressure between 1.0 Pa and 7.0 Pa, preferably between 1.5 Pa and 4.0 Pa. The negative substrate bias is between 0 V and 300 V, preferably between 10 V and 150 V, most preferably between 15 V and 60 V. The deposition temperature is between 200° C. and 800° C., preferably between 300° C. and 600° C.
In the case of magnetron sputtering, (Zr,Cr,Al,Me)N layers may be grown with a power density applied to the sputter target between 0.5 W/cm2 and 15 W/cm2, preferably between 1 W/cm2 and 5 W/cm2, from co-sputtering of pure elemental targets by altering the power to the respective targets (alter the deposition rate for each target) or from a composite and/or alloyed target, where Me, when present, is one or more of the elements selected from the group consisting of Y, Ti, V, Nb, Ta, Mo, W, Mn and Si in a reactive atmosphere containing N2 and optionally with a carrier gas such as, e.g., Ar at a total pressure between 0.1 Pa and 5.0 Pa, preferably between 0.1 Pa and 2.5 Pa. The desired layer composition is obtained by selecting appropriate composition of the (Zr,Cr,Al,Me) target, target power density and gas atmosphere. The negative substrate bias is between 0 V and 300 V, preferably between 10 V and 150 V, most preferably between 10 V and 80 V. The deposition temperature is between 200° C. and 800° C., preferably between 300° C. and 600° C.
The invention also relates to the use of coated cutting tool insert according to the above for machining at cutting speeds of 50-400 m/min, preferably 75-300 m/min, with an average feed, per tooth in the case of milling, of 0.08-0.5 mm, preferably 0.1-0.4 mm, depending on cutting speed and insert geometry.
Cemented carbide inserts with composition 94 wt % WC-6 wt % Co were used as a body for the layer depositions by cathodic arc evaporation.
Before deposition, the inserts were cleaned in ultrasonic baths of an alkali solution and alcohol. The system was evacuated to a pressure of less than 2.0×10−3 Pa, after which the inserts were sputter cleaned with Ar ions. (ZrxCr1-x-y-zAlyMez)Na layers, 0.43 <x <0.85, 0.05 <y <0.45, z =0 and 1.00 21 a <1.09, coatings 1 - 18 in Table 1, were grown using (Zr,Cr,Al) cathodes, with compositions according to coatings 1-18 in Table 2. The layers were deposited at 450° C. in a pure N2 atmosphere, a process pressure of 3 Pa, a bias of −30 V and an evaporation current of 60 A to a total thickness of about 3 μm.
Example 1 was repeated using (Zr,Cr,Al,Me) cathodes for the deposition of the (ZrxCr1-x-y-zAlyMez)Na layers, coatings 19-24 in Table 1 using cathodes as specified for coatings 19-24 in Table 2.
The composition x, y, z and a, of the (ZrxCr1-x-y-zAlyMez)Na layers was estimated by energy dispersive spectroscopy (EDS) analysis using a LEO Ultra 55 scanning electron microscope operated at 10 kV and equipped with a Thermo Noran EDS detector. The data were evaluated using the Noran System Six (NSS ver 2) software.
The phase structure of as-deposited (ZrxCr1-x-y-zAlyMez)Na layers where characterized by X-ray diffraction (XRD) using Cu K alpha radiation and a θ-2θ configuration in a Bruker AXS D8 Advance diffractometer.
The residual stresses, a, of the (Zr1-x-zSixMez)Ny layers were evaluated by XRD measurements using the sin2ψ method (see e.g. I.C. Noyan, J.B. Cohen, Residual Stress Measurement by Diffraction and Interpretation, Springer-Verlag, New York, 1987). The measurements were performed using CuKα-radiation on the (311)-reflection. The residual stress values were within −5.0 GPa <σ<−1.0 GPa for the different layers as evaluated using a Poisson's ratio of ν=0.23 and Young's modulus of E =379 GPa.
Hardness data were estimated by the nanoindentation technique of the layers after mechanical polishing of the surface using a UMIS 2000 nanoindentation system with a Berkovich diamond tip with a maximum tip load of 25 mN.
For a cutting test using the coatings from Table 1 (example 1) in a turning operation with the following data:
Geometry: CNMG120408-MF1
Application: Facing
Work piece material: 100Cr6
Cutting speed: 200 m/min
Feed: 0.25 mm/rev.
Depth of cut: 2 mm
Performance criterion: Crater wear resistance
the following relative cutting results, as shown in Table 3, are expected. Coatings 12-15 of the invention are expected with improved crater wear performance with a stop criteria of 1 mm2 crater area, and compared to the reference materials according to prior art.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10 2012 215 624.0 | Sep 2012 | DE | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2013/068237 | 9/5/2013 | WO | 00 |
