This application relates to coatings, including various techniques for treating gas turbine engine components with a thermal barrier coating.
Gas turbine engines are known, and can include a fan for propulsion air and to cool components. The fan also delivers air into a core engine where it is compressed. The compressed air is then delivered into a combustion section, where it is mixed with fuel and ignited. The combustion gas expands downstream over and drives turbine blades. Static vanes are positioned adjacent to the turbine blades to control the flow of the products of combustion. The blades and vanes are subject to extreme heat.
A method of treating a component for a gas turbine engine according to an example of the present disclosure includes injecting a suspension stream into a plasma gas stream, the suspension stream having coating particles moving in the gas stream toward a component, and placing the coating particles on the component at a coating location to form a top coat that has a columnar microstructure such that a porosity of the columnar microstructure is between 4.0-7.0 percent, exclusive of the intersegment gaps.
In a further embodiment of any of the foregoing embodiments, the coating particles comprise a ceramic material.
In a further embodiment of any of the foregoing embodiments, the step of moving includes accelerating the coating particles in the gas stream to a maximum velocity of greater than 500 meters per second.
In a further embodiment of any of the foregoing embodiments, the step of moving includes heating the coating particles to an average particle temperature of greater than 3250 degrees Celsius.
In a further embodiment of any of the foregoing embodiments, the maximum velocity of the coating particles in the gas stream is less than 700 meters per second.
In a further embodiment of any of the foregoing embodiments, the average particle temperature is less than 3500 degrees Celsius.
In a further embodiment of any of the foregoing embodiments, a porosity of the columnar microstructure is less than 25 percent, inclusive of intersegment gaps in the columnar microstructure.
In a further embodiment of any of the foregoing embodiments, the porosity of the columnar microstructure is less than 6.0 percent, exclusive of the intersegment gaps.
In a further embodiment of any of the foregoing embodiments, the ceramic material comprises gadolinium zirconate (Gd2Zr207).
In a further embodiment of any of the foregoing embodiments, the step of moving includes a standoff distance that is at least about 2.5 inches.
In a further embodiment of any of the foregoing embodiments, the porosity of the columnar microstructure is between 15-25 percent, inclusive of the intersegment gaps.
In a further embodiment of any of the foregoing embodiments, the average particle temperature is less than 3500 degrees Celsius.
In a further embodiment of any of the foregoing embodiments, the maximum velocity is less than 700 meters per second.
In a further embodiment of any of the foregoing embodiments, the component is one of a blade outer air seal, a rotatable blade, a static vane, a combustion panel, and a combustion liner for a gas turbine engine.
A further embodiment of any of the foregoing embodiments includes the step of placing a bond coat onto a substrate of the component.
In a further embodiment of any of the foregoing embodiments, the bond coat defines a plurality of ridges.
In a further embodiment of any of the foregoing embodiments, the component is one of a blade outer air seal, a rotatable blade, a static vane, a combustion panel, and a combustion liner for a gas turbine engine.
In a further embodiment of any of the foregoing embodiments, the porosity of the columnar microstructure is less than 6.5 percent, exclusive of the intersegment gaps.
In a further embodiment of any of the foregoing embodiments, the porosity of the columnar microstructure is between 15-25 percent, inclusive of the intersegment gaps.
In a further embodiment of any of the foregoing embodiments, the average particle temperature is between 3300 and 3500 degrees Celsius, the maximum velocity is less than 700 meters per second, and the step of moving includes a standoff distance that is at least about 2.5 inches.
The details of one or more embodiments are set forth in the accompanying drawings and the description below. Other features, objects, and advantages will be apparent from the description and drawings, and from the claims.
Like reference numbers and designations in the various drawings indicate like elements.
The exemplary engine 20 generally includes a low speed spool 30 and a high speed spool 32 mounted for rotation about an engine central longitudinal axis A relative to an engine static structure 36 via several bearing systems 38. It should be understood that various bearing systems 38 at various locations may alternatively or additionally be provided, and the location of bearing systems 38 may be varied as appropriate to the application.
The low speed spool 30 generally includes an inner shaft 40 that interconnects a fan 42, a first (or low) pressure compressor 44 and a first (or low) pressure turbine 46. The inner shaft 40 is connected to the fan 42 through a speed change mechanism, which in exemplary gas turbine engine 20 is illustrated as a geared architecture 48 to drive the fan 42 at a lower speed than the low speed spool 30. The high speed spool 32 includes an outer shaft 50 that interconnects a second (or high) pressure compressor 52 and a second (or high) pressure turbine 54. A combustor 56 is arranged in exemplary gas turbine 20 between the high pressure compressor 52 and the high pressure turbine 54. A mid-turbine frame 57 of the engine static structure 36 is arranged generally between the high pressure turbine 54 and the low pressure turbine 46. The mid-turbine frame 57 further supports bearing systems 38 in the turbine section 28. The inner shaft 40 and the outer shaft 50 are concentric and rotate via bearing systems 38 about the engine central longitudinal axis A which is collinear with their longitudinal axes.
The core airflow is compressed by the low pressure compressor 44 then the high pressure compressor 52, mixed and burned with fuel in the combustor 56, then expanded over the high pressure turbine 54 and low pressure turbine 46. The mid-turbine frame 57 includes airfoils 59 which are in the core airflow path C. The turbines 46, 54 rotationally drive the respective low speed spool 30 and high speed spool 32 in response to the expansion. It will be appreciated that each of the positions of the fan section 22, compressor section 24, combustor section 26, turbine section 28, and fan drive gear system 48 may be varied. For example, gear system 48 may be located aft of combustor section 26 or even aft of turbine section 28, and fan section 22 may be positioned forward or aft of the location of gear system 48.
The engine 20 in one example is a high-bypass geared aircraft engine. In a further example, the engine 20 bypass ratio is greater than about six (6), with an example embodiment being greater than about ten (10), the geared architecture 48 is an epicyclic gear train, such as a planetary gear system or other gear system, with a gear reduction ratio of greater than about 2.3 and the low pressure turbine 46 has a pressure ratio that is greater than about five. In one disclosed embodiment, the engine 20 bypass ratio is greater than about ten (10:1), the fan diameter is significantly larger than that of the low pressure compressor 44, and the low pressure turbine 46 has a pressure ratio that is greater than about five 5:1. Low pressure turbine 46 pressure ratio is pressure measured prior to inlet of low pressure turbine 46 as related to the pressure at the outlet of the low pressure turbine 46 prior to an exhaust nozzle. The geared architecture 48 may be an epicycle gear train, such as a planetary gear system or other gear system, with a gear reduction ratio of greater than about 2.3:1. It should be understood, however, that the above parameters are only exemplary of one embodiment of a geared architecture engine and that the present invention is applicable to other gas turbine engines including direct drive turbofans.
A significant amount of thrust is provided by the bypass flow B due to the high bypass ratio. The fan section 22 of the engine 20 is designed for a particular flight condition—typically cruise at about 0.8 Mach and about 35,000 feet (10,668 meters). The flight condition of 0.8 Mach and 35,000 ft (10,668 meters), with the engine at its best fuel consumption—also known as “bucket cruise Thrust Specific Fuel Consumption (‘TSFC’)”—is the industry standard parameter of lbm of fuel being burned divided by lbf of thrust the engine produces at that minimum point. “Low fan pressure ratio” is the pressure ratio across the fan blade alone, without a Fan Exit Guide Vane (“FEGV”) system. The low fan pressure ratio as disclosed herein according to one non-limiting embodiment is less than about 1.45. “Low corrected fan tip speed” is the actual fan tip speed in ft/sec divided by an industry standard temperature correction of [(Tram ° R)/(518.7° R)]0.5. The “Low corrected fan tip speed” as disclosed herein according to one non-limiting embodiment is less than about 1150 ft/second (350.5 meters/second).
The component 90 includes at least a substrate 90A. Example materials forming substrate 90A can include nickel-based superalloys or other high temperature materials. In some examples, the substrate 90A comprises a single crystal material or a directionally solidified material. The techniques for forming a single crystal or directionally solidified materials are known, but the use of such materials utilizing the techniques described herein are not known.
Referring to
In some examples, a bond coat 90E can be disposed or otherwise placed on the surface 90B at step 81. The bond coat 90E can form an oxidation layer for oxidation resistance and can improve adhesion of the thermal barrier coating to the substrate 90A. Example bond coats can include nickel chromium aluminum yttrium (NiCrAlY), or a NiCoCrAlY alloy, for example. Other example bond coats can include MCrAlX combinations, where M=Ni, Co, Fe or a combination thereof, and X=reactive elements such as Y, Hf or Zr. Other example bond coats can include diffusion aluminides with or without platinum group metals.
Step 77 includes situating a device such as a gas torch 78 relative to the component 90, as illustrated by
An injector 80 is situated adjacent to the gas torch 78, as seen in
The nozzle 80A of the injector 80 can be situated such that the suspension stream 84 defines an injection angle (α) that is substantially perpendicular or otherwise transverse to a major component of the gas stream 82 at injection location L1. The injection location L1 can be about 0.2 inches from the nozzle 78A, for example. In other examples, the injector 80 can be situated such that a suspension stream 84′ is substantially parallel or collinear with a major component of the gas stream 82. For the purposes of this disclosure, the terms “perpendicular” and “normal” mean 90 degrees relative to a major component of the gas stream 82 unless otherwise disclosed. Also, for the purposes of this disclosure, the term “substantially” means ±10 degrees unless otherwise disclosed. In some examples, the injector 80 can be situated such that an absolute value of the injection angle (α) between 80-85 degrees relative to a major component of the gas stream 82.
The suspension comprises a liquid for carrying coating particles to form a thermal barrier coating. The suspension liquid may comprise ethanol, for example. The liquid provides momentum to entrain the relatively fine coating particles into the high velocity gas stream 82. In the illustrated example, the coating particles comprise a ceramic material, and can have a mean size between about 10 nanometers (nm) to about 10 microns, or more narrowly between about 50 nm and 2.0 microns, when introduced in the suspension stream 84. Example ceramic coating materials comprise zirconia based and hafnia based ceramics that are partially or fully stabilized primarily by rare earth oxides, such as yttria, scandia, or any lanthanide series oxides. Some specific examples include yttria-stabilized zirconia (YSZ) or gadolinium zirconate (Gd2Zr207). Additional example ceramic coating materials can include aluminum oxide (Al2O3), tantala (Ta2O5) or niobia (Nb2O5). For the purposes of this disclosure, the term “about” means ±5% unless otherwise disclosed.
At step 83, the gas stream 82 is directed toward a localized region of the component 90. At step 85, the suspension stream 84 including coating particles is injected into the gas stream 82 at injection location L1. In some examples, a velocity of the suspension stream 84 at the injection location L1 is between about 10-40 meters/second, or more narrowly about 15-35 meters/second, at the injection location L1 prior to being influenced by the gas stream 82. At step 86, the coating particles in the suspension stream 84 are accelerated in the gas stream 82 in direction D1 toward the component 90. The relative momentum difference between the two streams 82, 84 causes a break-up of the suspension stream 84 into droplets. Exposure to the relatively high temperatures of the gas stream 82 cause substantially all of the liquid portion of the suspension stream 84 to evaporate, and cause at least some or most of the coating particles to melt.
At step 87, the coating particles are deposited or otherwise placed onto the component 90 at coating location L2. The coating location L2 is a localized area or region of the component 90 situated at an intersection of the gas stream 82. Although coating location L2 can be a single point defined along an axis of the nozzle 78A of the gas torch 78, the coating location L2 can include a localized region due to dispersion of some of the coating particles carried by the gas stream 82. For example, some coating particles or droplets can move tangentially in directions D2 and/or D3 (
Coating particles that comprise the top coat 90F form a columnar microstructure 90G at the coating location L2, as illustrated by
Utilizing the techniques described herein, the coating particles collect on the peaks 90C and form voids in adjacent valleys 90D, thereby reducing peak shadowing or coating buildup in the valleys 90D. The coating particles comprising the columns 90H can be more densely packed, which can improve durability of the columnar microstructure 90G. For example, each of the gaps G defines a corresponding surface gap width W 1. The gap widths W1 can be the same or can vary along a vertical height of the columnar microstructure 90G depending on interaction with neighboring columns 90H.
The exemplary densities described herein can be associated with an intercolumnar or intracolumnar porosity of the columnar microstructure 90G. For the purposes of this disclosure, porosity is measured with respect to a percentage void area by image analysis on micrographs at 250 times magnification. Voids in the imagery of less than 2 square microns are associated with columns 90H, and voids greater than or equal to 2 square microns are associated with intersegment gaps G in the columnar microstructure 90G. In some examples, an intercolumnar porosity of the columnar microstructure 90G is less than about 25 percent, or more narrowly about 10-20 percent, or more narrowly between about 12-17 percent, inclusive of intersegment gaps G in the columnar microstructure 90G.
Intracolumnar porosity of the columnar microstructure 90G can be reduced to increase the durability of the TBC. For example, intracolumnar porosity can be concentrated in interpass boundaries defined by layers of the coating particles from each pass. These boundaries with higher porosity can act as weak planes within the TBC and parallel to the interface that can reduce durability of the TBC. Reducing this interpass boundary accumulation of porosity or total intracolumnar porosity can increase durability of the TBC with respect to mechanically and thermally induced strain. In some examples, an intracolumnar porosity of the columnar microstructure 90G is less than about 8 or 10 percent, such as below 7 percent, or more narrowly below 6.5 percent, exclusive of the intersegment gaps G but inclusive of the columns 90H. The density and porosity values disclosed herein can improve durability of the component 90 and can reduce ingestion of debris in the columnar microstructure 90G, for example.
Various techniques can be utilized to increase density and/or reduce porosity of the columnar microstructure 90G, including driving higher energy into the coating particles between injection of the suspension stream 84 and contact with the target surface at the coating location L2. Techniques for increasing the energy can include increasing a kinetic and/or thermal energy of the coating particles or associated droplets.
Relatively higher gas velocities can result in a relatively higher droplet to gas momentum ratio. This can cause the droplets to impact the surface of the substrate 90A at relatively larger (e.g., perpendicular) angles and/or velocities which can increase a packing density of the columns 90H that result from the droplets interacting with the peaks 90C, as compared to impacting surfaces of the substrate 90A at relatively shallow (e.g., tangential) angles or lower velocity. Relatively shallow angles can result in peak shadowing of the valleys 90D. Since the droplets have a relatively larger mass than the gas particles, the droplets that are accelerated prior to impact at the coating location L2 are more difficult to deflect from their impact trajectory by the low mass gas and have higher kinetic energy for compaction on impact. It may be desirable to keep the maximum particle velocity within a particular range, or below a threshold value, to allow for some tangential flow of the droplets relative substrate and shadowing of droplets in the valleys 90D to provide a desired density and porosity of the columnar microstructure 90G.
The kinetic energy and velocity of the coating particles can be increased by adjusting the power level, gas flow rates and/or an opening of nozzle 78A of the gas torch 78. Relatively higher mass gases or mixtures, such as relatively higher amounts of Argon (Ar) or Nitrogen (N2) and lesser amounts of Hydrogen (H2), can be utilized to increase coating particle speeds and kinetic energy at a time of impact with the substrate. In some examples, the gas torch 78 is operable to deliver about 450-600 SCFH of a mixture of Argon (Ar)/Nitrogen (N2)/Hydrogen (H2). In one example, the gas torch 78 is operable to deliver about 565 SCFH of a mixture of Ar/N2/H2 (about 300/160/105 SCFH, respectively), with a diameter of the nozzle 78A being about 0.45 centimeters. Example power levels include between about 80-120 kW, such as between about 100-120 kW for yttria-stabilized zirconia or between about 90-110 kW for other zirconates.
Other techniques for increasing gas volume and a velocity of the coating particles can also include changing a diameter of the nozzle 78A of the gas torch 78, with relatively smaller diameters having relatively high particle velocities and/or temperatures. In some examples, a diameter of the nozzle 78A is between about 0.2-0.6 centimeters, or more narrowly between about 0.25-0.45 centimeters.
In some examples, the coating particles are accelerated in the gas stream 82 to a maximum velocity of greater than about 470 or 500 meters per second, or more narrowly less than or equal to about 650 or 700 meters per second. In other examples, the maximum velocity is less than about 600 meters per second, such as between about 550-560 meters per second. The maximum velocities may correspond to coating particles comprising a ceramic material such as gadolinium zirconate (Gd2Zr207), for example. In some examples, the standoff distance is at least about about 2.5 inches, or more narrowly between about 3.0-4.0 inches.
Increasing a temperature of the coating particles can also increase a thermal energy of the droplets. Increased thermal energy of the coating particles can cause the associated droplets to more completely interact with the target surface prior to solidification of the droplets, thereby achieving a relatively denser TBC. Increasing the velocity of the coating particles can also increase the maximum temperature of coating particles. Techniques for increasing the temperature of the coating particles can include increasing the power of the gases forming the gas stream 82, and also by reducing the standoff distance between the nozzle 78A of the gas torch 78 and the substrate, for example.
In some examples, after injection of the suspension stream 84 into the gas stream 82, the coating particles are heated in the gas stream 82 to an average particle temperature that is greater than or equal to about 3000 or about 3250 degrees Celsius, or more narrowly less than 3500 degrees Celsius. In some examples, the average particle temperature is greater than about 3300 or about 3400 degrees Celsius. In other examples, the average particle temperature is less than about 3400 degrees Celsius, such as between 3100 and 3200 degrees Celsius.
It should be understood that the maximum velocities disclosed herein are measured without a substrate situated in place relative to the gas torch 78, and do not reflect any backpressure from exertion of gases on the substrate.
Utilizing the techniques disclosed herein, increased particle temperatures, increased particle velocities and/or standoff distances can be selected to more densely pack the columns 90H of the columnar microstructure 90G. This can improve column toughness, improve coating strain tolerance, and reduce porosity of the columnar microstructure 90G, thereby improving durability of the TBC and the component 90.
One or more embodiments have been described. Nevertheless, it will be understood that various modifications may be made. For example, when reengineering from a baseline engine configuration, details of the baseline may influence details of any particular implementation. Accordingly, other embodiments are within the scope of the following claims.
The present disclosure is a continuation of U.S. patent application Ser. No. 15/698,774, filed Sep. 8, 2017.
Number | Date | Country | |
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Parent | 15698774 | Sep 2017 | US |
Child | 17172505 | US |