Cobalt-boron compounds

Many commercial rubber articles, for example pneumatic tyres, conveyor belts or high-pressure hoses, are provided with reinforcing inserts of steel which has a high carbon content and is often used in the form of steel cords.
A strong and lasting bond between metal and rubber is necessary in order to ensure a good efficiency and life of the articles.
In the absence of additional adhesive, this can only be achieved if the filaments of the steel cord are plated with a thin layer of .alpha.-brass or with another alloy having the main constituents copper and zinc or with pure zinc.
The cord thus treated is directly vulcanised into the rubber mixture which usually contains in particular adhesion-promoting additives.
The most common additives for improving the binding power, hereinafter termed "adhesives" may be classified into two groups according to their chemical structure.
The first group includes all adhesives which are only efficient as multicomponent systems.
It is common to them all that they contain highly active silicas.
The other components are resorcinol or resorcinol-formaldehyde condensation products and formaldehyde-releasing compounds, such as hexamethylene tetramine, etherified or esterified methylolmalamines having different degrees of etherification or esterification, and condensation products thereof.
Although these systems produce good adhesion values, they sometimes give rise to vapours and an unpleasant odour during vulcanisation. Furthermore, the processibility in the mixing machines, for example on a roller mixer, is severely impaired because resorcinol tends towards sublimation, particularly at a temperature in the vicinity of its melting point.
Organometallic compounds belong to the second group, and the compounds of cobalt predominate. Above all, cobalt soaps, of the type which are also conventional as siccatives in the lacquer industry, have been used for a comparatively long time.
Thus, FR-PS, No. 1,323,934 claims various cobalt salts, for example cobalt stearate, cobalt linolate or cobalt naphthenate. Boron-organic cobalt compounds, corresponding to U.S. Pat. No. 3,296,242, are also suitable. In addition to cobalt, the following are also included as metals: copper, nickel, lead or zinc. (See DE-OS No. 2,303,674; DE-OS No. 2,447,853 or U.S. Pat. No. 4,154,911).
Other compound classes include nickel and cobalt complexes of succinylosuccinic acid esters (EP-OS No. 0,003,820) or transition metal salts of some 1,2-diols (EP-OS No. 0,009,000).
Single organic salts do not generally improve the adhesion of a rubber mass to metallic carrier materials. On the contrary, they often act as rubber poisons and reduce the stability of the rubber-metal bond.
There are clear differences in effect between the adhesives of the first group and those of the second group.
Organometallic compounds, added to the rubber mixture, usually result in an improved metal-rubber adhesion after vulcanisation, and may also retard, in a lasting manner, the corrosion of the metallic carrier.
However, they have a substantial disadvantage in that the adhesiveness is greatly reduced, in particular in the case of high temperature vulcanisation (180.degree.-240.degree. C.). The reversion also becomes noticeable in a very disadvantageous manner.
However, the adhesives of the first group have a better resistance of the rubber-metal bond to reheating procedures. Such bonds with the adhesives of the second group are also more sensitive to heat and moisture influences.
Thus, adhesive combinations are also frequently added to the adhesive mixtures, in which case either individual components of an adhesive system, or the adhesive system as a whole may be used (DE-OS No. 1,720,144; DE-OS No. 2,841,401).
A disadvantage of all adhesive systems which correspond to the prior art is the sensitivity of the rubber-metal bond, which is promoted or caused by such systems, to the influence of moisture or of moisture together with heat.
Therefore, there is interest in an adhesive system which has the greatest possible resistance to such influences.
Thus, an object of the present invention is to provide an adhesive system for rubber-metal adhesion which does not have the above-mentioned disadvantages or does not have such disadvantages to the previous extent.
New cobalt compounds have now been found which are outstandingly suitable for such adhesive systems.
Therefore, the present invention provides compounds corresponding to the formula: ##STR3## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are the same or different, and represent hydrogen, hydroxy, C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.1 -C.sub.16 alkylthio, C.sub.6 -C.sub.14 aryl, C.sub.6 -C.sub.14 aryl-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.18 alkoxy, C.sub.6 -C.sub.14 aryloxy, C.sub.6 -C.sub.14 -aryl-C.sub.1 -C.sub.4 alkyloxy, halogen or a hydrocarbon radical having from 2 to 18 carbon atoms and having one or more double bonds, and
R.sub.6 represents a linear or branched, saturated or mono- or poly-unsaturated hydrocarbon radical having from 1 to 22 carbon atoms, or a radical of the formula ##STR4## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 have the above mentioned meaning.
Preferred compounds contain one radical of the formula ##STR5## per boron atom.
The compounds corresponding to formula I are obtained by reacting, while heating
(a) a cobalt salt of a C.sub.1 -C.sub.4 carboxylic acid,
(b) an optionally substituted phenol,
(c) a boric acid trialkylester and
(d) optionally a linear or branched, saturated or mono- or poly-unsaturated C.sub.8 -C.sub.22 alcohol.
Preferably the compounds are reacted in such amounts that per mol of cobalt salt one mol boric acid trialkyl ester, one to two mols phenol and zero to one mol C.sub.8 -C.sub.22 -alcohol are added, wherein the sum of components (b) and (d) is at most 2 mols.
The boric acid trialkylester can be added in substance or can be produced in situ from boron trioxide and a C.sub.1 -C.sub.7 -alcohol, which can be added in excess. Excess C.sub.1 -C.sub.7 -alcohol and alcohol which is released from boric acid trialkyl ester is distilled off.
The present invention also relates to a process for increasing the adhesivenss between rubber and metals, characterised in that a compound corresponding to formula I is added to the rubber.
The following are mentioned as preferred carboxylic acid components of the cobalt salt: acetic acid, formic acid, propionic acid or butyric acid, in particular acetic acid.
The radicals R.sub.1, R.sub.2, R.sub.4 and R.sub.5 preferably represent hydrogen, and R.sub.3 preferably represents C.sub.6 -C.sub.12 alkyl or C.sub.6 -C.sub.14 aryl-C.sub.1 -C.sub.4 alkyl.
The compounds may be present as an isomeric mixture.
In particular, the radicals R.sub.1 to R.sub.5 may represent the following: hydrogen, methyl, ethyl, propyl, iso-propyl, n-butyl, sec. butyl, iso-butyl, tert.-butyl, n-pentyl, iso-pentyl, sec.-pentyl, neopentyl, n-hexyl, iso-hexyl, sec.-hexyl, cyclohexyl, n, heptyl, iso-heptyl, tert.-heptyl, octyl, 2-ethylhexyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, methyl-cyclohexyl, cyclohexylmethyl, naphthyl, anthracenyl, naphthylmethyl, cycloheptyl, cyclooctyl, phenyl, benzyl, cyclononyl, cyclodecyl, cycloundecyl, cyclododecyl, 9-octadecenyl or methylphenyl.
The same radicals as those mentioned under alkyl, but merely extended with oxygen or sulphur, may be mentioned as alkoxy and alkylthio.
However, pure or isomeric compounds of butylphenol, propylphenol, octylphenol, nonylphenol benzylphenol, dodecylphenol and tolylcresol are generally used. Nonylphenol, dodecylphenol, tolylcresol and benzylphenol are preferred.
The following compounds are mentioned as C.sub.8 -C.sub.22 alcohols: n-octanol, 2-ethylhexanol, n-nonanol, trimethylhexanol (commercial isomer mixture), decanol, undecanol, dodecanol, tridecanol, tetradecanol, pentadecanol, hexadecanol, heptadecanol, octadecanol, octadecenyl alcohol, nonadecanol or C.sub.20 -C.sub.22 alcohols, olein alcohol and mixtures of saturated or mono- or poly-unsaturated C.sub.10 -C.sub.22 alcohols, in particular natural and commercial mixtures.
Esters having in each case C.sub.1 -C.sub.8, preferably C.sub.3 -C.sub.5, and in particular C.sub.4 alkyl, for example isobutyl, groups are mentioned as boric acid trialkylesters.
The adhesive system produces good adhesion values, clearly improves the ageing values of the rubber articles (for example steam ageing) and reduces the reversion.
The adhesive system is added to the rubber within the quantity range which is conventional for these systems. The quantities are generally from 0.1 to 20% by weight, preferably from 0.2 to 10% by weight, and in particular from 0.3 to 5% by weight, based on the rubber.
The production of the compounds corresponding to formula I is a three-to-five-component reaction. The following combinations of starting materials are preferred, cobalt acetate-tetrahydrate being used in every case as the cobalt salt.
______________________________________No. Boron compound Phenol Alcohol______________________________________1 Tributylester Nonylphenol --2 Tri-2-ethylhexylester Nonylphenol --3 Tri-(trimethylhexyl)es- Nonylphenol -- ter4 Tributylester isom.-p-tolyl -- phenol5 Tri-(trimethylhexyl) isom.-p-tolyl- -- ester phenol6 Tri-2-ethylhexylester isom.-p-tolyl- -- phenol7 Tri-isobutylester isom.-p-tolyl- -- phenol8 Tri-isobutylester Nonylphenol Tetradecanol9 Trioxide/Isobutanol Nonylphenol Tetradecanol10 Tri-isobutylester Nonylphenol Stearyl al- cohol11 Tri-isobutylester Nonylphenol C.sub.14 -C.sub.22 fatty alcohol mixture12 Tri-isobutylester Nonylphenol 9-octadece- nyl alcohol*13 Tri-isobutylester Nonylphenol C.sub.12 -C.sub.18 fatty alcohol mixture14 Tri-isobutylester isom.-p-tolyl- Dodecanol phenol15 Tri-isobutylester Nonylphenol Dodecanol16 Tri-isobutylester Dodecylphenol Dodecanol______________________________________ *90% of 9octadecenyl alcohol and various C.sub.8 -C.sub.22 alcohols. 2,3,8,9,10,11,12,13,15 and 16 are particularly preferred products.

The process is explained using the following Example.
249 g of cobalt acetate-tetrahydrate are mixed with 220 g of nonylphenol (commercial isomer mixture) and heated with stirring under normal pressure up to 200.degree. C. in an apparatus provided with a column. The water of crystallisation is split off during this operation. The mixture is then cooled to 140.degree. to 160.degree. C. and stirred under vacuum for several hours to remove residues of moisture.
A mixture of 230 g of boric acid triisobutyl ester and 214 g of tetradecanol is then added (may be added at 140.degree. C.) and the mixture is further heated slowly. After a short initial foaming, a volatile reaction product distills off at from 90.degree. to 115.degree. C. The internal temperature is slowly increased as the distillation of the volatile product of isobutanol and isobutyl acetate subsides. At an internal temperature of from 220.degree. to 240.degree. C., the distillation of the volatile mixture is completed after some time. The mixture is then stirred for 2 to 3 hours, cooled to 200.degree. C. and evacuated. 560 g of a dark blue, low viscosity oil is obtained having the following elemental analytical composition:
______________________________________ C found 64.7% H 9.9 B 2.1 Co 11.0______________________________________
The dehydration of the cobalt salt which is described above may also be carried out by azeotropic distillation using toluene or xylene.
In a variant, boric acid trioxide and excess isobutanol are used instead of boric acid trialkylester.
An additional increase in the adhesiveness may be achieved by adding to the rubber, in addition to the compound corresponding to formula I, a formaldehyde-releasing compound in quantities of from 0.01 to 10% by weight, preferably from 1 to 3% by weight, based on the rubber.
Moreover, the following may also be added to the rubber in quantities of from 0.01 to 10% by weight, preferably from 0.5 to 5% by weight, based on the rubber: resorcinol or derivatives thereof, such as dimethoxybenzene, diacetoxybenzene, dibenzoyloxybenzene, dipropoxybenzene, dipropionyloxybenzene, di(trimethylsilyloxy)benzene, and sulphoesters, phosphoric acid esters, phosphorous acid esters and urethanes and carbonates of resorcinol.
The resorcinol compound may be added to the rubber separately or combined with the formaldehyde-releasing compound. It is also possible to add resorcinol precondensed with formaldehyde in quantities of from 0.01 to 10% by weight, preferably from 3 to 5% by weight, based on rubber, the precondensate containing from 1 to 3 mols of formaldehyde per mole of resorcinol.
Furthermore, silica may be added in the conventional quantities.
The expression "formaldehyde-releasing compounds" is understood as designating those substances which, upon heating, for example at a temperature ranging from 40.degree. to 200.degree. C., in particular under vulcanisation conditions, are capable of splitting off formaldehyde, optionally in the presence of water. When methylol esters are used, condensation reactions may also occur with the release of alcohols or acids. These products will be termed hereinafter in brief "formaldehyde-releasers".
They are known and described in BL-PS No. 621 923, 624 519, U.S. Pat. No. 2,512,128 "Helvetica chimica acta", 24, P. 315 E, CH-PS No. 197 486 and Houben-Weyl, "Methoden der organischen Chemie volume 8, P. 242.
Particularly high adhesions are obtained using the following: hexamethylol melamine, hexamethylol melamine-pentamethylether, mixtures of hexamethylol melamine-tetramethylether and -trimethylether, pentamethylol melamine-trimethylether, tetramethylolhydrazodicarbonamide, tetramethylol-acetylene-diurea, N,N'-dimethylol-urea, N-methylol-dicyanodiamide, methylene-amino-acetonitrile, N-allyl-dioxazine, N-phenyl-dioxazine, 1-aza-3,7-di-oxabicyclo[3,3]-octane, and hexamethylene tetramine.
The rubber masses provided with the above-mentioned adhesive combination result in outstanding adhesion properties with respect to iron, copper, brass, zinc, bronze, aluminium and other reinforcing metals. Typical types of rubber which may be used for such adhesive mixtures include rubbers of the diene type, such as natural rubber, polyisoprene, polybutadiene, styrene-butadiene copolymers, acrylonitrile-butadiene rubber, chloroprene rubber, EPDM and mixtures of these types mentioned above.
The rubber mixtures may contain conventional constituents, including reinforcing carbon blacks, inactive and active fillers, for example silicas and zinc oxide, processing auxiliaries, sulphur and vulcanisation accelerators.
Particularly suitable as accelerators are sulpheneamides which are derived from 2-mercaptobenzothiazole, for example N-cyclohexyl-thiobenzothiazole, N-morpholino-thiobenzothiazole, N,N-dicyclohexyl-thiobenzothiazole or N,N-diisopropylaminothiobenzothiazole. Of course, other accelerators may also be used on their own or combined together. Examples include thiurams, mercaptobenzothiazole or dithiocarbamates.
The vulcanisation temperature is selected in a manner complying with practice, for example from 120.degree. to 220.degree. C., preferably from 140.degree. to 180.degree. C.
The advantages of the present invention in the production of highly resistant bonds with steel cables or steel cords having a brass-plated surface, as they may be used, for example, in the production of rubber tyres, high-pressure hoses or conveyor belts, are illustrated by the following Examples.
These examples are based on the following mixture composition:
______________________________________Natural rubber (RSS 1) 100 parts by weightCarbon black N 326 43 "Carbon black N 539 20 "Colophonium 3 "Phenyl-.beta.-naphthylamine 1.5 "Zinc oxide 10 "Sulphur 7 "N,N--dicyclohexyl-thiobenzothia 0.7 "zole______________________________________
The basic mixture which is free of sulphur and accelerator is pre-mixed at 70.degree. C. in a laboratory internal mixer and is then mixed with sulphur, accelerator and optionally adhesive in a laboratory mixing apparatus at a roller temperature of 60.degree. C.
To test the adhesion according to the T test method (see Bayer-Mitteilungen fur die Gummi-Industrie, No. 29 of 1961, P 69), test bodies are produced having dimensions of 20.times.15.times.6 mm.
Steel cords having a brass-plated surface and dimensions of 7.times.3.times.0.15 mm are used.
The test bodies are vulcanised at 150.degree. C. corresponding to the t.sub.90 value. For the ageing procedure, the test bodies are exposed for several days to hot air at 100.degree. C., exposed to superheated steam at 120.degree. C. for a few hours or are stored for several months at 40.degree. C. and at 95% relative humidity.
If necessary, the rubber mixture is vulcanised at 180.degree. C. for 45 minutes beyond the vulcanisation optimum.
The adhesion values are determined at 80.degree. C. test temperature using a tension-testing device with a clamp draw-off speed of 100 mm/min. The values are stated in N/20 mm as the maximum force necessary for tearing the cord out of the rubber sample. For one measurement, at least four test bodies having the same structure are used, and the median (x) according to DIN 53, 598, and the difference between the highest and the lowest individual value, the span (R), as a measurement of the variation, are evaluated from these individual values.
Moreover, the covering of the reinforcement with rubber (C) is assessed visually after the separating test has been carried out.
The observation result is recorded in Roman numerals or in letters which satisfy the following assignment:
I: Reinforcement without any rubber covering
II: Reinforcement slightly covered with rubber
III: Reinforcement mainly covered with rubber
IV: Structural break in the rubber
GR: Complete transposition of the brass layer, bright steel on the surface.
Table 1 shows the adhesion-improving influence of some of the compounds according to the present invention.
TABLE 1__________________________________________________________________________ Test mixture containing adhesive Adhesion acc. to the present invention Relevant test mixture without improvement CO content.sup.+ .about.X (N/20 mm) R (N/20 mm) C .about.X (N/20 mm) R (N/20 mm) C X (N/20__________________________________________________________________________ mm)CompoundNo.1 0.3 460 50 IV 400 115 III 601 0.1 390 75 IV 335 50 III 552 0.3 485 50 IV 400 115 III 852 0.1 380 40 III 335 50 III 554 0.3 400 40 IV 340 60 III 608 0.1 405 40 IV 350 50 III 5515 0.3 390 70 IV 360 70 III 30Comparison 0.1 430 80 IV 385 80 III 45__________________________________________________________________________ .sup.+ in % by weight of cobalt metal, based on polymer
The corresponding values with cabalt-naphthenate as an adhesion-improving substance are reproduced under "Comparison".
The numerical values show that when a compound according to the present invention is used on brass-plated steel cords, improvements in adhesion are achieved which attain the prior art level and, in some cases, surpass this level.
As is known, during the vulcanisation of sulphur-containing rubber mixtures together with reinforcements having a brass-plated surface, an adhesion-promoting layer is formed by the reaction of the copper with sulphur (see S. Buchan, Rubber to Metal Bonding, Palmerton Publishing Company New York, (1959)), which layer is particularly sensitive to influences of moisture and heat (see W. J. van OOij Rub. Chem. Techn. 51, 52 (1978)).
Table 2 demonstrates that the use of the compounds according to the present invention retards in a lasting manner the destruction of the adhesive layer which is caused by moisture and heat.
It has been found with respect to this stabilizing effect that the compounds of the present invention provide a significant advantage over the prior art.
TABLE 2__________________________________________________________________________ Test mixture vulcanised Test mixture vulcanised acc. to the t.sub.90 value and Co acc. to the t.sub.90 value aged in super heated steam (2d/120.degree. C.) Content.sup.+ X (N/20 mm) R (N/20 mm) C X (N/20 mm) R (N/20 mm) C X rel.__________________________________________________________________________ (%).sup.++CompoundNo.-- -- 340 60 III 100 10 GR 712 0.3 380 40 III 320 30 II 164 0.3 400 40 IV 310 70 II 22.58 0.3 400 55 IV 330 40 II 17.511 0.3 370 60 IV 285 80 II 2316 0.3 380 40 IV 290 50 III 2412 0.3 370 70 IV 260 70 III 29Comparison 0.3 380 90 IV 160 20 II 57Cobalt-naphthenate__________________________________________________________________________ .sup.+ in % by weight of cobalt metal, based on polymer ##STR6##
Moreover, the adhesives of the previously mentioned type are distinguished by an altogether well-balanced property spectrum.
Table 3 shows, using three Compoud Examples, that the bond remains effectively adhesive even when subjected to the most varied stresses, such as thermal reheating and the influence of moisture at true-to-practice temperatures.
The quantity of adhesive which is used in the rubber mixture corresponded to 0.3% by weight of cobalt metal, based on the polymer.
TABLE 3______________________________________ Example 8 Example 3 Example 2______________________________________Vulcanisation correspondingto the t.sub.90 value of themixtureX (N/20 mm) 380 380 380R (N/20 mm) 80 30 45C III III IIIAdditional ageing in aGeer furnace;duration: 6 daysX (N/20 mm) 360R (N/20 mm) 55C IIIAdditional ageing insuperheated steam at120.degree. C.Duration: 4 daysX (N/20 mm) 275 320 320R (N/20 mm) 60 20 60C IV III IVAdditional ageing inhumid atmosphere(95% RH) at 40.degree. C.Duration: 1 monthX (N/20 mm) 330 300 310R (N/20 mm) 60 70 80C III II IIIVulcanisation at 180.degree. C.for 45 min longer thancorresponds to thet.sub.90 valueX (N/20 mm) 280 280 280R (N/20 mm) 25 75 30C III III III______________________________________
The use of the adhesives according to the present invention is also advantageous in combination with adhesives of the "multicomponent system" type.
The resistance of the adhesion to thermal and humid stresses is also greatly improved. The test formulation stated below is used for the data given in the following. The other test conditions remain unchanged.
______________________________________Natural rubber (RSSI) 100 parts by weightCarbon black N-330 50 "Highly active precipitated 10 "silicaPhenol-formaldehyde resin 4 "Isopropyl-phenyl- 2.5 "p-phenylenediamineZinc oxide 6 "Resorcinol 2 "Hexamethylolmelamine- 2 "pentamethylether (HMMM)Sulphur 4.5 "N,N--dicyclohexyl-thiobenzo- 2 "thiazoleN--cyclohexyl-thiophthalimide 0.3 "Adhesive as stated______________________________________
TABLE 4______________________________________ Additional ageing Vulcanisation corre- in superheated sponding to the t.sub.90 steam at 120.degree. C. value of the mixture Duration: 2 days Example Example Example Example 8 3 8 3______________________________________Resorcinol + HMMM.about.X (N/20 mm) 345 170R (N/20 mm) 40 30C IV GRResorcinol + HMMM+ adhesiveof present invention.about.X (N/20 mm) 365 370 295 225R (N/20 mm) 70 68 35 40C IV IV II I______________________________________

Number	Name	Date
3438799	Eck et al.	Apr 1969
4360473	Marzocchi et al.	Nov 1982
4416824	Reimer et al.	Nov 1983

Cobalt-boron compounds

Information

Patent Number

Date Filed

Date Issued

Inventors

Original Assignees

Examiners

Agents

CPC

US Classifications

Field of Search

US

International Classifications

Abstract

Description

Claims

Priority Claims (1)

US Referenced Citations (3)

Non-Patent Literature Citations (1)