Cobalt catalysts

Abstract

A cobalt catalyst precursor includes a catalyst support impregnated with cobalt. All reducible cobalt is present in the support as supported cobalt oxide of formula-unit CoOaHb, where a≧1,7 and b≧0. A process for preparing a cobalt catalyst precursor, and a process for preparing a cobalt catalyst are also provided.

Description

[0001] THIS INVENTION relates to cobalt catalysts. It relates in particular to a cobalt catalyst precursor, to a process for preparing a cobalt catalyst precursor, and to a process for preparing a cobalt catalyst.

[0002] Processes for preparing cobalt catalysts are, in general, well defined in the literature. For example, U.S. Pat. No. 5,733,839 describes a process for preparing an impregnated Fischer-Tropsch catalyst comprising an alumina carrier and an active component selected from the group consisting of cobalt, iron and mixtures thereof. However, it is an object of the present invention to provide a supported cobalt catalyst having higher productivities than known cobalt catalysts.

[0003] Thus, according to a first aspect of the invention, there is provided a cobalt catalyst precursor which includes a catalyst support impregnated with cobalt, with all reducible cobalt being present in the support as supported cobalt oxide of formula-unit CoOaHb, where a≧1,7 and b≧0.

[0004] In other words, according to the first aspect of the invention, there is provided a cobalt catalyst precursor which includes a catalyst support that has been impregnated with cobalt and calcined in such a manner that all reducible cobalt present therein, ie cobalt that is associated with the elements hydrogen and oxygen in the absence of cobalt-support interaction, such as the formation of cobalt aluminates or cobalt silicates, that would decrease its reducibility, is present as the supported cobalt oxide of formula-unit CoOaHb, where a≧1,7 and b≧0.

[0005] Thus, for example, all the reducible cobalt could be present as Co2O3.H2O or CoO(OH), ie where a=2 and b=1. However, instead, the reducible cobalt may be present, for example, as a mixture of Ci3O4 and CoO(OH) or Co2O3.H2O with 45% of the reducible cobalt in the catalyst precursor being present as Co3O4 and 55% of the reducible cobalt being present as CoO(OH) or Co2O3.H2O. This would result in a catalyst precursor in which all the reducible cobalt is present as supported cobalt oxide of formula-unit CoOaHb where a=1,7 and b=0,55. Another example would be a mixture of Co2O3 and CoO(OH) or Co2O3.H2O with 60% of the reducible cobalt being present as Co2O3 and 40% of the reducible cobalt being present as CoO(OH) or Co2O3.H2O. This would result in a catalyst precursor in which all of the reducible cobalt is present as supported cobalt oxide of formula-unit CoOaHb where a=1,7 and b=0,4.

[0006] The catalyst precursor may contain between 5 gCo/100 g support and 70 gCo/100 g support, preferably between 20 gCo/100 g support and 50 gCo/100 g support, more preferably between 25 gCo/100 g support and 40 gCo/100 g support.

[0007] According to a second aspect of the invention, there is provided a process for preparing a cobalt catalyst precursor, which process includes

[0008] in a support impregnation stage, impregnating a particulate porous catalyst support with a cobalt salt, and partially drying the impregnated support; and

[0009] in a calcination stage, calcining the partially dried impregnated support to obtain the cobalt catalyst precursor, with the calcination being effected at calcination conditions selected so that all reducible cobalt is present in the support as a supported cobalt oxide of formula-unit CoOaHb, where a≧1,7 and b≧0.

[0010] The resultant cobalt catalyst precursor will, in practice, be reduced to obtain a cobalt catalyst, which will thus have enhanced productivities as compared to catalysts of which Co3O4 is the preferred product of calcination.

[0011] According to a third aspect of the invention, there is provided a process for preparing a cobalt catalyst, which process includes

[0012] in a support impregnation stage, impregnating a particulate porous catalyst support with a cobalt salt, and partially drying the impregnated support;

[0013] in a calcination stage, calcining the partially dried impregnated support to obtain a cobalt catalyst precursor, with the calcination being effected at calcination conditions selected so that all reducible cobalt is present in the support as a supported cobalt oxide of formula-unit CoOaHb, where a≧1,7 and b≧0; and

[0014] in a reduction stage, reducing the cobalt catalyst precursor, to obtain the cobalt catalyst.

[0015] The cobalt salt may, in particular, be cobalt nitrate, Co(NO3)2.6H2O.

[0016] Any commercially available porous oxide catalyst support, such as alumina (Al2O3), silica (SiO2), titania (TiO2), magnesia (MgO), and silica-alumina, may be used. The support preferably has an average pore diameter between 8 and 50 nanometers, more preferably between 10 and 15 nanometers. The support pore volume may be between 0,1 and 1,0 ml/g, preferably between 0,3 and 0,9 ml/g. The average particle size is preferably between 1 and 500 micrometers, more preferably between 10 and 250 micrometers, still more preferably between 45 and 200 micrometers.

[0017] The support may be a protected modified catalyst support, containing, for example, silicon as a modifying component, as described in WO 99/42214, which is hence incorporated herein by reference.

[0018] The impregnation of the catalyst support may, in principle, be effected by any known impregnation method or procedure such as incipient wetness impregnation or slurry phase impregnation. However, the impregnation stage may, in particular, comprise a process as described in WO 00/20116, and which is thus incorporated herein by reference. The support impregnation stage may thus involve a 2-step slurry phase impregnation process, -which is dependent on a desired cobalt loading requirement and the pore volume of the catalyst support.

[0019] During either of the two slurry phase impregnation steps, a water soluble precursor salt of palladium (Pd), platinum (Pt), ruthenium (Ru), or mixtures thereof, may be added, as a dopant capable of enhancing the reducibility of the cobalt. The mass proportion of the palladium, platinum or ruthenium metal, or the combined mixture of such metals when such a mixture is used, to the cobalt metal may be between 0,01:100 to 0,3:100.

[0020] The support impregnation and drying may typically be effected in a conical vacuum drier with a rotating screw or in a tumbling vacuum drier.

[0021] In the calcination stage, the calcination may include passing hot air over and around the partially dried impregnated support, thereby drying the impregnated support further by removal of residual moisture present therein; and calcining the resultant dried impregnated support by decomposition of the cobalt salt into decomposition products comprising oxide(s) and any water of hydration, with the decomposition products being released in vapour form, to enhance formation of a supported catalyst precursor containing the supported cobalt oxide of formula-unit CoOaHb, where a≧1,7 and b≧0.

[0022] In particular, since the cobalt salt is cobalt nitrate, the oxide (s) can be nitrogen dioxide, an equilibrium between NO2 and N2O4, as well as nitric oxide (NO).

[0023] The process may include diluting the decomposition products that are obtained during the calcination. In other words, formation of the supported cobalt oxide, with the formula-unit CoOaHb, where a≧1,7 and b≧0, is enhanced by ensuring dilution of the decomposition products during calcination.

[0024] The presence of the supported cobalt oxide phase with the formula-unit CoOaHb, where a≧, 7 and b≧0, may be determined by using Temperature Programmed Reduction (TPR) as fingerprint technique.

[0025] The minimum temperature at which the calcination is performed is the temperature at which decomposition of the cobalt precursor, ie the cobalt salt, starts, while the maximum calcination temperature is the temperature at which the preferred supported cobalt oxide phase with the formula-unit CoOaHb, where a≧1,7 and b≧0, is converted to the undesired Co3O4 spinel phase.

[0026] The calcination may be performed in any known calcination equipment such as a fluidized bed calciner, a rotary kiln, torbed calciner or a furnace.

[0027] In particular, the calcination may be performed in a fluidized bed calciner. Preferably, the calcination is performed in air, at temperatures between 95° C. and 400° C. The minimum calcination temperature is thus determined by the temperature at which nitrate decomposition starts, ie about 120° C., while the maximum calcination temperature is the temperature at which the preferred cobalt oxide with the formula-unit CoOaHb, is converted into the undesired Co3O4 spinel phase. The maximum calcination temperature is typically between 200 and 300° C. After calcination, the nitrogen concentration in the catalyst precursor is preferably less than 1,0 m %.

[0028] In a preferred embodiment of the invention, the removal of the nitrogen oxide(s) and water during the calcination in air is enhanced, to stabilize the supported cobalt oxide phase of formula-unit CoOaHb, where a≧1,7 and b≧0.

[0029] During the calcination in the fluidized bed, the heating rate of the impregnated and dried support and the space velocity of the air may be controlled such that the residual moisture in the support is first driven off, whereafter decomposition of the cobalt nitrate is effected.

[0030] Preferably a minimum air space velocity is used in order to attain a maximum relative intrinsic cobalt catalyst activity in respect of the resultant catalyst; however, a maximum heating rate is associated with the minimum space velocity. In particular, the Applicant has found that for a particular support impregnated with cobalt nitrate, there is a minimum air space velocity, 1,0 mn3/(kg Co(NO3)2.6H2O)/h, which must be used in order to attain the maximum relative intrinsic catalyst activity. If a space velocity lower than 1,0 mn3/kg Co(NO3)2.6H2O)/h, is used, the maximum initial activity of the resultant catalyst will thus not be attainable. However, the Applicant has also found that there is then a maximum heating rate of 1° C./min, preferably 0,5° C./min, and typically between 0,1 and 0,5° C./min, associated with the minimum space velocity, 1,0 m3/(kg Co(NO3)2.6H2O)/h. In other words, if the support heating rate exceeds 1° C./min while maintaining a minimum space velocity of 1,0 mn3/(kg Co(NO3)2.6H2O)/h, then this will have a detrimental influence on the initial activity.

[0031] However, if a space velocity greater than 1,0 mn3/(kg Co(NO3)2.6H2O)/h is used, say a space velocity of 1000 mn3/(kg Co(NO3)2.6H2O)/h), then there will be a higher maximum or threshold heating rate at which the support can be heated, associated therewith, viz 100° C./min. Thus, flash calcination can be applied provided sufficiently high space velocities are employed.

[0032] The process may include, in the calcination stage, initially heating the impregnated support until it reaches a calcination temperature, Tc. Thus, the heating up of the support to the calcination temperature, Tc, may be effected while maintaining a space velocity of at least 1,0 mn3/(kg Co(NO3)2.6H2O)/h and an appropriate bed heating rate associated with the space velocity, as described hereinbefore. The process may also include, thereafter, maintaining the support at the calcination temperature, Tc, for a period of time, tc.

[0033] The heating rate may be controlled by controlling feed gas (air) pre-heaters through which the air required for fluidization and calcination passes and/or by controlling the calciner wall temperature. While the heating rate up to Tc can be linear, it is believed that enhanced activity may be obtainable if the heating rate is non-linear in order to tailor the release profiles of the nitrogen oxide(s) and water.

[0034] The period of time, tc, for which isothermal calcination is applied at the calcination temperature, Tc, may be between 0,1 and 20 hours, provided that the nitrogen content of the calcined catalyst is less then 1,0 m %.

[0035] The partially dried impregnated support from the support impregnation stage is preferably not stored and not heated or cooled prior to the subsequent fluidized bed calcination stage so that it passes into the fluidized bed calcination stage at substantially the same temperature at which it leaves the support impregnation stage. Thus, the partially dried impregnated support typically leaves the support impregnation stage at a temperature between 60° C. and 95° C., typically at around 75° C., and enters the fluidized bed calcination stage at about the same temperature, and without storage thereof between the stages. The fluidized bed calcination stage is thus preferably provided by a fluidized bed calciner connected directly to the vacuum drier.

[0036] The fluidized medium employed in the calciner is thus the air which is required for the calcination, and the linear air velocity through the calciner must naturally be sufficiently high to ensure proper fluidization.

[0037] The invention extends also to a catalyst when obtained by the process according to the third aspect of the invention, or when obtained by reducing the catalyst precursor of the first aspect of the invention or the catalyst precursor obtained by the process according to the second aspect of the invention.

[0038] The process is particularly suited to preparing a cobalt slurry phase Fischer-Tropsch catalyst, ie a catalyst suitable for catalyzing the conversion of a synthesis gas comprising carbon monoxide and hydrogen to hydrocarbon products, at elevated temperature and pressure.

[0039] The invention will now be described by way of example with reference to the following non-limiting examples and the accompanying diagrammatic drawings.

[0040] In the drawings

[0041] FIG. 1 shows, schematically, apparatus used for the preparation of the catalysts of Example 1, on a pilot plant scale;

[0042] FIG. 2 shows the Temperature Programmed Reduction pattern of catalyst P. The TPR experiment was performed using a heating rate of 10° C./min and a hydrogen/argon gas mixture having 10% hydrogen;

[0043] FIG. 3 shows the Temperature Programmed Reduction pattern of catalyst H; The TPR experiment was performed using a heating rate of 10° C./min and a hydrogen/argon gas mixture having 10% hydrogen;

[0044] FIG. 4 shows the relative intrinsic specific Fischer-Tropsch activities of catalysts of Examples 1, 2 and 8, as a function of the space velocity during fluidized bed calcination thereof;

[0045] FIG. 5 shows the relative intrinsic specific Fischer-Tropsch activities of catalysts of Examples 1, 2 and 8, as a function of the heating rate during fluidized bed calcination thereof;

[0046] FIG. 6 shows the undesired, preferred, and most preferred catalyst Fischer-Tropsch productivity regions as functions of the air space velocity and the heating rate during fluidized bed calcination;

[0047] FIGS. 7 and 8 show thermogravimetric analyses (TGA) of catalyst B of Example 1, after support impregnation/vacuum drying and before calcination with air, with

[0048] FIG. 7 showing the weight loss of catalyst B as a function of time, using a heating rate of 0,40° C./min and a hold time at 250° C. of 6 hours; and

[0049] FIG. 8 showing the weight loss of catalyst B as a function of time, using a heating rate of 5° C./min from 30° C. to 75° C., a heating rate of 0,4° C./min from 75° C. to 130° C., a 4 hour hold time at 130° C., a heating rate of 0,17° C./min from 130° C. to 160° C., a heating rate of 0,7° C./min from 160° C. to 250° C., and a hold time at 250° C. of 4 hours;

[0050] FIG. 9 shows the Temperature Programmed Reduction pattern of Catalyst Q. The TPR experiment was performed using a heating rate of 10° C./min and a hydrogen/argon gas mixture with 10% hydrogen; and

[0051] FIG. 10 shows the Temperature Programmed Reduction pattern of Catalyst R. The TPR experiment was performed using a heating rate of 10° C./min and a hydrogen/argon gas mixture with 10% hydrogen.

EXAMPLE 1

[0052] A series of cobalt alumina-based Fischer-Tropsch catalysts, identified as A, B, C, D, E, G, H and I were prepared in a pilot plant scale apparatus as shown in FIG. 1. The catalysts were thus prepared using a fluidized bed calciner. Catalysts D, E, G, H and I are in accordance with the invention. Catalysts A, B and C have been included for comparison.

[0053] In FIG. 1, reference numeral 10 generally indicates pilot plant scale apparatus for preparing the Fischer-Tropsch catalysts.

[0054] The apparatus 10 includes a 100 dm3 conical vacuum drier 12 having a discharge passageway fitted with a valve 16. The passageway 14 is connected directly to a disengagement section 18 of a fluidized bed calciner, which is generally indicated by reference numeral 20.

[0055] The calciner 20 includes a vent 22 leading from the section 18 to a scrubber (not shown). The section 18 is mounted, by means of flanges 24, 26, to a tubular component 28 providing a cylindrical calciner wall having an internal diameter of 350 mm and a height of 655 mm. A heating element 30 is located around the component 28, with a component 32 of a temperature indicator/controller being located between the element 30 and the component 28.

[0056] At its lower end, the component 28 is provided with a flange 34 which is mounted to the flange 36 of a funnel-shaped component 38. A filter 40 is sandwiched between the flanges 34, 36 and spans the passageway of the component 28. The component 38 has an air inlet 42 through which preheated air enters the calciner.

[0057] A temperature sensor/indicator 44 is located in the passageway of the component 28 to measure the temperature inside the fluidized bed (not shown) of dried particulate impregnated support material that forms on the filter 40. The temperature sensor/indicator 44 is located about 35 mm above the filter 40. A similar temperature sensor/indicator 46 is located below the filter 40.

[0058] In the apparatus 10, the vacuum drier 12, used for the impregnation and vacuum drying of the support, is thus directly connected to the fluidized bed calciner 20.

[0059] The catalysts were prepared by means of a slurry phase impregnation and vacuum drying procedure. The procedure was identical for all catalysts in this Example.

[0060] In each case, in a first impregnation and calcination step, a solution of 17,4 kg of Co(NO3)2. 6H2O, 9,6 g of (NH3)4Pt(N3)2, and 11 kg of distilled water was mixed with 20,0 kg of a gamma alumina support (Puralox SCCa 5/150, pore volume of 0,48 ml/g, from Condea Chemie GmbH of Uberseering 40, 22297 Hamburg, Germany) by adding the support to the solution. The resultant slurry was added to the conical vacuum drier 12 and continuously mixed. The temperature of this slurry was increased to 60° C. after which a vacuum of 20 kpa(a) was applied. During the first 3 hours of the drying step, the temperature was increased slowly and reached 95° C. after 3 hours. After 3 hours the vacuum was decreased to 3-15 kpa(a). The impregnated catalyst support was dried for 9 hours, after which this impregnated catalyst support was immediately and directly loaded into the fluidized bed calciner 20. The temperature of the dried impregnated catalyst support was about 75° C. at the time of loading into the calciner. The loading took about 1 to 2 minutes, and the temperature inside the calciner remained at its set point of about 75° C. To obtain a catalyst with a cobalt loading of 30 gCo/100 gAl2O3, a second impregnation and drying step was performed. A solution of 9,4 kg of Co(NO3)2.6H2O, 15,7 g of (NH3)4Pt(NO3)2, and 15,1 kg of distilled water was mixed with 20,0 kg of impregnated and calcined material from the first impregnation and calcination step, by adding this solid intermediate material to the solution. The resultant slurry was added to the conical vacuum drier and continuously mixed. The temperature of this slurry was increased to 60° C. after which a vacuum of 20 kPa(a) was applied. During the first 3 hours of the drying step, the temperature was increased slowly and reached 95° C. after 3 hours. After 3 hours the vacuum was decreased to 3-15 kPa(a). The resultant impregnated catalyst support was dried for 9 hours, after which this impregnated catalyst support was immediately and directly loaded into the fluidized bed calciner. The temperature of the dried impregnated catalyst support was about 75° C. at the time of loading into the calciner. The loading took about 1 to 2 minutes, and the temperature inside the calciner remained at its set point of about 75° C.

[0061] The air space velocity in the calciner and the heating rate of the impregnated and dried material, from 75° C. to 250° C., were varied in an attempt to obtain a catalyst with maximum relative initial intrinsic activity. The hold time at 250° C. was kept constant at 6 hours during all catalyst preparations. The fluidized bed temperature (component 44 in FIG. 1) was monitored during the whole of each calcination cycle.

[0062] The conditions that were investigated during the direct fluidized bed calcination of the impregnated and dried material are set out in Table 1.

TABLE 1
Conditions used during fluidized bed calcination
of dried impregnated supports.
	Catalyst batch	Heating rate	Air flow	Space velocity
Catalyst *	size (kg)	(° C./min)	(kg/h)	**
A	20	0,1	6,0	0,26
B	30	0,3	17,3	0,51
C	30	0,6	17,3	0,51
D	20	0,4	23,0	1,02
E	20	0,4	23,0	1,02
G	20	0,5	23,0	1,02
H	20	0,1	23,0	1,02
I	30	100	—	1000
* All catalysts had the composition 30Co/0, 075Pt/100Al2O3 (given on a mass basis)
** The space velocity is expressed as m3n air/(kg Co(NO3)2.6H2O)/h

[0063] The nitrogen content of each of these Pilot Plant prepared catalysts was less or equal to 0,5 wt %, as given in Table 2.

TABLE 2
Nitrogen content of catalysts A, B, C, D, and I,
after calcination.
Catalyst Nitrogen content (m %)
A        0,50
B        0,45
C        0,45
D        0,48
I        0,50

EXAMPLE 2

[0064] A series of cobalt alumina-based Fischer-Tropsch catalysts, identified as K, L, M, and O, were prepared on a laboratory scale, applying the same procedures used during the pilot plant scale catalyst preparations described in Example 1, but starting with 50 g of support instead of 20 kg. The amounts of the other chemicals used were also scaled down using the ratio 0,05/20. These catalysts were also prepared using fluidized bed calcination. The preparation of these catalysts was effected in laboratory equipment similar to the apparatus 10. Catalysts L and M are in accordance with the invention. Catalysts K and O have been included for comparison.

[0065] The conditions during fluidized bed calcination of the laboratory prepared catalyst supports are set out in Table 3.

TABLE 3
Conditions used during fluidized bed calcination
of dried impregnated supports.
			Heating	Space
		Mass	Rate	velocity
	Catalyst *	(g)	(° C./min)	**
	K	50	1,3	0,41
	L	50	0,3	0,76
	M	50	1,0	0,76
	O	50	8,0	0,76
	* All catalysts had the composition 30Co/0, 075Pt/100Al2O3, on a mass basis.
	** The space velocity is expressed as m3n air/(kg Co(NO3)2.6H2O)/h.

EXAMPLE 3

[0066] A cobalt catalyst P, which is not in accordance with the invention was prepared by means of slurry impregnation. In a first impregnation and calcination step, a solution of 43, 68 g of Co(NO3)2.6H2O, 0,024 g of (NH3)4Pt(NO3)2, and 50 ml of distilled water was mixed with 50 g of a gamma alumina support (Puralox SCCa 5/150, pore volume of 0,48 ml/g, from Condea Chemie GmbH of Uberseering 40, 22297 Hamburg, Germany) by adding the support to the solution. The resultant slurry was added to a rotarvap and continuously mixed. The temperature of this slurry was increased to 60° C. after which a vacuum of 25 kpa(a) was applied. During the first 3 hours of the drying step, the temperature was increased slowly and reached 95° C. after 3 hours. After 3 hours the vacuum was decreased to 5 kPa (a). The impregnated catalyst support was dried for 9 hours, after which the catalyst support was immediately calcined. The calcination was performed in a static furnace calciner at 250° C., without flushing air over the sample. To obtain a catalyst with a cobalt loading of 30 gCo/100 gAl2O3, a second impregnation and calcination step was performed. A solution of 23,51 kg of Co(NO3)2.6H2O, 0,039 g of (NH3)4Pt(NO3)2, and 50 ml of distilled water was mixed with 50 g of impregnated and calcined material from the first impregnation and calcination step, by adding this solid intermediate material to the solution. The slurry was added to a rotarvap and continuously mixed. The temperature of this slurry was increased to 60° C. after which a vacuum of 25 kPa(a) was applied. During the first 3 hours of the drying step, the temperature was increased slowly and reached 95° C. after 3 hours. After 3 hours the vacuum was decreased to 5 kPa (a). The impregnated catalyst support was dried for 9 hours, after which the catalyst support was immediately calcined. The calcination was performed in a static furnace calciner at 250° C., without flushing air over the sample.

EXAMPLE 4

[0067] Catalysts A, H, and P were tested for Fischer-Tropsch synthesis performance. The experimental data, as well as the Fischer-Tropsch conditions, are presented in Table 4.

[0068] Prior to the laboratory micro slurry reactor Fischer-Tropsch synthesis runs at realistic Fischer-Tropsch conditions, the calcined catalyst precursors were reduced in the laboratory using a standard laboratory reduction procedure (heating rate of 1° C./min from 25 up to 425° C., 16 hours at 425° C., GHSV of 200 mln hydrogen/(g cat.hour), 1 bar pure hydrogen), unloaded and coated with Fischer-Tropsch wax.

[0069] Having applied a known cobalt based Fischer-Tropsch kinetic equation, such as:

r FT =(kFTPH2PCO)/ (1+KPCO)2

[0070] the Arrhenius derived pre-exponential factor AFT (ie AFT=kFT/(e−Ea/RT)) was estimated for each of the reported runs. The relative intrinsic specific Fischer-Tropsch activity is defined as ((pre-exponential factor of catalyst x)/(pre-exponential factor of catalyst A))*100, in which catalyst x is the catalyst of the specific examples, ie catalysts H and P.

[0071] Temperature programmed reduction (TPR) experiments were performed on catalysts H and P (FIGS. 2 and 3), using a heating rate of 10° C./min and a hydrogen/argon gas mixture having 10 vol % hydrogen.

[0072] The Fischer-Tropsch synthesis performance results show that catalyst H is much more active (ie relative intrinsic FT factor of 138) than catalyst P (ie relative intrinsic FT factor of 62). The TPR patterns also show a clear difference between these two catalysts. The differences are typified by the following parameters:

[0073] 1. The ratio of the peak heights of peak 2 and peak 4;

[0074] 2. The width of peak 2 at half height;

[0075] 3. The presence/absence of peak 3.

[0076] The TPR pattern of catalyst H is typical for a supported cobalt catalyst containing reducible cobalt oxide with a formula-unit of CoOaHb, where a≧1,7 and b≧0, whilst the TPR pattern of catalyst P displays the presence of the undesired Co3O4 spinel phase.

[0077] It can thus be concluded that a catalyst which is properly calcined will have a TPR pattern typical for the desired cobalt oxide phase with the formula-unit CoOaHb, where a≧1, 7 and b≧0, as well as a desired high relative intrinsic Fischer-Tropsch activity.

TABLE 4
Fischer-Tropsch synthesis performance of
catalysts A, H, and P.
	Catalyst
	A	H	P
Run analysis	140F	174F	153F
Synthesis conditions
Calcined catalyst mass (g)	20,1	20,9	19,2
Reactor temperature (° C.)	218,0	220,4	220,4
Reactor pressure (bar)	20,1	19,9	20,0
Time on stream (h)	15,3	15,0	15,0
Feed gas composition:
H2 (vol %)	51,4	52,9	52,6
CO (vol %)	27,8	27,4	26,7
CO2 (vol %)	0,68	0,60	0,59
Syngas (H2 + CO) space velocity (m3n/kg cat/h)	3,24	3,73	3,59
Reactor partial pressures
H2 (bar)	6,74	5,50	8,14
CO (bar)	3,69	2,80	3,91
H2 O (bar)	3,06	4,40	2,23
CO2 (bar)	0,29	0,27	0,15
Synthesis performance
% syngas conversion	47,6	62,3	34,2
Relative intrinsic specific Fischer-Tropsch activity	100	138	62
% C-atom CH4 selectivity	9,6	5,2	12,0
% CO of total amount of CO converted to CO2	3,6	2,3	0,6

EXAMPLE 5

[0078] Catalysts A, B, C, D, E, G, H, K, L, M, and O, all prepared by using fluidized bed calcination, were tested for Fischer-Tropsch synthesis performance. The experimental data, as well as the Fischer-Tropsch conditions, are presented in Tables 5 and 6.

[0079] The catalysts were reduced and tested as described in Example 4. The relative intrinsic Fischer-Tropsch activity factors were also calculated as described in Example 4.

[0080] The relative intrinsic specific Fischer-Tropsch activities of all the catalysts were plotted as a function of the space velocity during fluidized bed calcination (FIG. 4) The activities of catalysts A, B, C, D, E, G, H, K, L and M increased linearly to a relative intrinsic specific Fischer-Tropsch activity of about 140 at a space velocity of 1,02 mn3/(kg Co(NO3)2.6H2O)/h, after which it is expected to level off at a relative intrinsic specific Fischer-Tropsch activity of about 140.

[0081] It is believed that the positive influence of the space velocity on the presence of the preferred, ex calcination cobalt oxide phase and on the catalyst performance is due to the fact that, at higher space velocities, the maximum NOx and water concentrations around the catalyst particles during calcination is lower.

[0082] The relative intrinsic specific Fischer-Tropsch activities of catalysts A, B, C, D, E, G, H, I, K, L, M and O were also plotted as function of the heating rate during fluidized bed calcination (FIG. 5). At a fixed air space velocity, it can be concluded that the intrinsic catalyst Fischer-Tropsch activity is not influenced by variations in the heating rate within the range 0,1° C. to 0,5° C./min. It appears that at high heating rates the initial intrinsic activity may decline (eg catalyst O), as also indicated by the dotted extrapolations. It is believed that this is caused by increased NOx and water concentrations around the catalyst due to the rapid decomposition of cobalt nitrates at high heating rates. Included in this FIG. 5 is the initial (ie 15 hours on stream under realistic synthesis conditions) intrinsic FT activity of catalyst I. Catalyst I shows that if the space velocity is extremely high, ie 1000 m3n/(kg Co(NO3)2.6H2O)/h, flash calcination, ie a heating rate of 100° C./min, can be tolerated.

[0083] In FIG. 6, it can be seen that the right combination of heating rates and air space velocities has to be selected to obtain a catalyst with the desired intrinsic Fischer-Tropsch activity.

TABLE 5
Fischer-Tropsch synthesis performance of
catalysts B, C, D, E, G, and I.
	Catalyst
	B	C	D	E	G	I
Run analysis	131F	124F	147F	163F	169F	265$
Synthesis conditions
Calcined catalyst mass (g)	20,1	20,9	21,3	20,5	19,9	20,7
Reactor temperature (° C.)	220,8	219,8	220,2	219,3	216,9	220,1
Reactor pressure (bar)	20,0	20,3	20,2	20,0	20,0	20,3
Time on stream (h)	15,0	15,0	15,0	15,5	15,0	15,3
Feed gas composition:
H2 (vol %)	50,0	51,8	47,4	53,2	52,7	55,5
CO (vol %)	28,6	27,2	30,4	27,2	27,3	27,5
CO2 (vol %)	0,76	0,66	0,64	0,61	0,56	0,50
Syngas (H2 + CO) space	3,15	3,16	2,97	3,76	3,77	2,4
velocity
(m3n/kg cat/h)
Reactor partial pressures
H2 (bar)	5,65	5,75	4,56	5,70	6,20	3,90
CO (bar)	3,26	3,23	3,31	3,10	3,30	2,30
H2O (bar)	3,94	4,03	4,68	4,20	3,90	6,10
CO2 (bar)	0,29	0,27	0,26	0,24	0,19	0,40
Synthesis performance
% syngas conversion	56,2	58,4	62,3	60,1	55,5	76,8
Relative intrinsic specific	110	114	148	143	143	138
Fischer-Tropsch activity
% C-atom CH4 selectivity	7,0	2,8	1,4	4,0	3,9	3,4
% CO of total amount of CO	2,3	2,2	1,8	1,5	1,2	3,9
converted to CO2

[0084]

TABLE 6
Fischer-Tropsch synthesis performance of catalysts
K, L, M, and O.
	Catalyst
	K	L	M	O
Run analysis	55(SR3)1	55(SR3)1	155F	57(SR3)1
Synthesis conditions
Calcined catalyst	12,7	12,1	20,0	11,7
mass (g)
Reactor temperature	219,0	220,5	220,4	219,8
(° C.)
Reactor pressure (bar)	20,0	20,5	20,0	20,5
Time on stream (h)	15,3	15,0	15,8	15,0
Feed gas composition:
H2 (vol %)	58,8	59,6	53,3	57,7
CO (vol %)	30,3	29,5	26,3	31,1
CO2 (vol %)	0,6	0,8	0,6	0,6
Syngas (H2 + CO) space	1,94	2,08	3,52	2,14
velocity (m3n/kg
cat/h)
Reactor partial pressures
H2 (bar)	3,49	2,74	5,33	3,46
CO (bar)	1,81	1,45	2,64	1,84
H2O (bar)	4,62	5,20	4,49	4,95
CO2 (bar)	0,26	0,42	0,27	0,26
Synthesis performance
% syngas conversion	73,1	80,5	64,1	73,5
Relative intrinsic specific	105	133	129	114
Fischer-Tropsch activity
% C-atom CH4	4,1	5,1	6,4	5,6
selectivity
% CO of total amount of	2,8	4,1	2,3	2,3
CO converted to CO2

EXAMPLE 6

[0085] The bulk of the cobalt nitrate decomposition, ie the bulk of the NOx release, occurs between 130° C. and 160° C., as can be seen from FIG. 7. For suppression of the NOx peak maximum, ie to enhance initial activity, tailoring of this NOx release profile, ie adoption of a non-linear heating rate, was investigated with the following as target: maximum removal of residual moisture and crystal waters prior to ca 130° C., to be followed by a smoothing out of the NOx release between 130° C. and 160° C. This was simulated by means of a TGA experiment, in which a hold time at 130° C., a slow heating rate between 130° C. and 160° C., and a fast heating rate between 160° C. and 250° C. was used, as shown in FIG. 8. The NOx release was found to be spread out over a much longer period of time, and the maximum NOx concentration around the catalyst was thus lower.

EXAMPLE 7

[0086] Catalyst Q was prepared in similar fashion to Catalyst I of Example 1. The TPR pattern of Catalyst Q can be seen in FIG. 9.

[0087] Part of this catalyst sample Q was calcined additionaly at 450° C., ie at a temperature higher than specified in the invention, to obtain Catalyst R. This was done to ensure the presence of Co3O4 in this particular catalyst sample R. The TPR of Catalyst R can be seen in FIG. 10.

[0088] It can be concluded from the relative hydrogen consumption per reduction step, as calculated from the areas under peaks 1, 2 and 4 in FIGS. 9 and 10, that Catalyst R, which has thus not been prepared according to the invention, mainly contained Co3O4. Catalyst Q, however, which has been prepared according to the invention, is predominantly CoO(OH). This also emerges from Table 7.

TABLE 7
Relative hydrogen consumption for different steps
in the reduction of Catalysts Q and R.
	Catalyst Q	Catalyst R
	Peak	Mole	Peak	Mole
Reaction	no	H2 *	no	H2 *
3CoO(OH) + O,5H2 → Co3O4 + 2H2O	1	0,4
Co3O4 + H2 → 3CoO + H2O	2	1,1	2	1,1
3CoO + 3H2 → 3Co + 3H2O	4	3,0	4	3,0
* The amount of hydrogen was calculated from the areas under the respective reduction peaks.

EXAMPLE 8

[0089] A series of alumina supported cobalt based Fischer-Tropsch catalysts were prepared on a laboratory scale, applying the same procedures as used in Example 2. The calcination conditions that were used are shown in Table 8.

[0090] Catalysts V, W and Z are in accordance with the invention. Catalysts X and Y have been included for comparison.

TABLE 8
Conditions used during fluidised bed calcination
of dried impregnated supports.
			Heating rate	Space velocity
	Catalyst	Mass (g)	(° C./min)	**
	V	50	1,0	1,8
	W	50	1,0	4,5
	X	50	4,0	1,0
	Y	50	8,0	1,8
	Z	50	8,0	4,5
	* All catalysts had the composition 30Co/0075Pt/100Al2O3,
	#on a mass basis.
	** The space velocity is expressed as m3n air/
	#(kg Co (NO3)2.6H2 O)/h

[0091] The catalysts were reduced and tested for Fischer-Tropsch synthesis performance as described in Example 4. The relative intrinsic Fischer-Tropsch activity factors were also calculated as described in Example 4. The data are presented in Table 9 as well as in FIGS. 4 to 6.

TABLE 9
Fischer-Tropsch synthesis conditions and
performance of catalysts V, W, X, Y, and Z, as
tested in a laboratory CSTR micro slurry reactor.
	V	W	X	Y	Z
run analysis	103SR3	279F	347F	101SR3	95SR3
Synthesis conditions
Calcined catalyst mass (g)	12,7	19,8	19,4	20	12,3
Reactor temperature (° C.)	220	222	220	220	220
Reactor pressure (bar)	20,5	20,3	20,0	20,5	20,5
Time on stream (h)	15,0	15,0	15,0	15,0	15,0
Feed gas composition:
H2 (vol %)	55	53,7	52,4	55	56
CO (vol %)	33	27,6	27,8	33	32
CO2 (vol %)	0,6	0,6	0,58	0,8	0,8
Syngas (H2 + CO) space	3,7	4,2	3,7	3,3	4,0
velocity (m3n/kg cat/h)
Reactor partial pressures
H2 (bar)	5,87	5,39	6,36	6,03	6,15
CO (bar)	3,55	2,75	3,42	3,61	3,37
H2O (bar)	4,22	4,91	3,69	3,91	3,97
CO2 (bar)	0,16	0,28	0,20	0,21	0,23
Synthesis performance
% syngas conversion	54,7	65,0	53,0	52,3	53,2
Relative intrinsic specific	133	147	113	111	129
Fischer-Tropsch activity
% C-atom CH4 selectivity	—	3,6	5,0	5,0	6,1
% CO of total amount of	0,4	2,1	1,2	0,9	1,2
CO converted to CO2

EXAMPLE 9

[0092] Two catalysts (AA and AB) were prepared by means of incipient wetness impregnation. 50 grams of alumina, with a pore volume of 0,48 ml/g, was impregnated with 24 ml of an aqueous cobalt nitrate solution, also containing ammonium platinum nitrate. After impregnation, the resultant intermediate was dried and calcined, in a fluidised bed calcination unit, up to 250° C. The exact calcination conditions are given in Table 10. After calcination, the intermediate was impregnated for a second time, by means of incipient wetness impregnation, and calcined in the same manner as during the first impregnation and calcination step. The second impregnation and calcination was performed to obtain a catalyst with the composition: 30Co/0,075Pt/100Al2O3.

[0093] Catalyst AA is in accordance with the invention. Catalyst AB has been included for comparison.

TABLE 10
Conditions used during fluidised bed calcination
of dried impregnated supports.
		Heating rate	Air flow	Space velocity
Catalyst	Mass (g)	(° C./min)	(1/min)	**
AA	50	1,0	1,7	1,8
BB	50	1,0	0,3	0,3
* All catalyst had the composition 30Co/0, 075Pt/100Al2O3 , on a mass basis.
** The space velocity is expressed as m3n air/(kg Co(NO3)2.6H2O)/h

[0094] The catalysts were reduced and tested for Fischer-Tropsch synthesis performance as described in Example 4. The relative intrinsic Fischer-Tropsch activity factors were also calculated as described in Example 4. The data are presented in Table 11.

TABLE 11
Fischer-Tropsch synthesis conditions and
performance of catalysts AA and AB, as tested in
a laboratory CSTR micro slurry reactor.
		AA	BB
	run analysis	292F	107SR3
	Synthesis conditions
	Calcined catalyst mass (g)	20,1	13,1
	Reactor temperature (° C.)	220	220
	Reactor pressure (bar)	20,0	20,5
	tome on stream (h)	15,0	15,0
	Feed gas composition:
	H2 (vol %)	54,0	51
	CO (vol %)	27,4	27
	C)2 (vol %)	0,8	1,5
	Syngas (H2 + CO) space velocity	4,2	3,4
	(m3n/kg cat/h)
	Reactor partial pressures
	H2 (bar)	6,12	6,96
	CO (bar)	3,17	3,73
	H2O (bar)	4,21	3,27
	CO2 (bar)	0,28	0,20
	synthesis performance
	% syngas conversion	58,3	44,3
	Relative intrinsic specific Fischer-	140	86
	Tropsch activity
	% C-atom CH4 selectivity	3,9	5,0
	% CO of total amount of CO	1,5	0,5
	converted to CO2

[0095] The results show that for cobalt catalysts prepared by incipient wetness impregnation procedures, calcination conditions according to the invention also have to be applied to obtain a catalyst with improved Fischer-Tropsch synthesis performance.

EXAMPLE 10

[0096] Thermogravimetric analysis (TGA) in air of catalyst Q, after the second impregnation and calcination thereof, showed a weight loss of 3,5-4,0 m % between 250° C. and 550° C. Assuming that during the TGA the cobalt compound Co3O4 is formed, it can be calculated which cobalt compound was present after standard catalyst calcination at 250° C. The compounds CoO, CoOOH or Co2O3.H2O, Co(NO3)2, and/or Co2O3 are possible candidates. The expected weight change during the conversion of these compounds into Co3O4 is presented in Table 12. It can be concluded from these data that the cobalt compound present after calcination at 250° C., using the conditions according to the invention, is predominantly CoOOH or Co2O3.H2O.

TABLE 12
Mass change of cobalt compounds during
decomposition to Co3O4.
		Mass change during	Mass change if compound
		decomposition to	is present on catalyst with
	Compound	CO3O4 (%)	20 m % cobalt (%)
	CoO	+6,6	+1,8
	CoOOH or	−13	−4,0
	Co2O3.H2O
	Co(NO3)2	−56	−35
	Co2O3	−3,2	−0,9

Claims

1. A cobalt catalyst precursor which includes a catalyst support impregnated with cobalt, with all reducible cobalt being present in the support as supported cobalt oxide of formula-unit CoOaHb, where a≧1,7 and b≧0.

2. A cobalt catalyst precursor according to claim 1, wherein all the reducible cobalt is present as Co2O3H2O or CoO (OH).

3. A cobalt catalyst precursor according to claim 1, wherein all. the reducible cobalt is present as a mixture of Co3O4 and CoO (OH) or Co2O3.H2O.

4. A cobalt catalyst precursor according to claim 1, which contains between 5 gCo/100 g support and 70 gCo/100 g support.

5. A process for preparing a cobalt catalyst precursor, which process includes in a support impregnation stage, impregnating a particulate porous catalyst support with a cobalt salt, and partially drying the impregnated support, with the resultant partially dried impregnated support containing residual moisture; and in a calcination stage, calcining the partially dried impregnated support to obtain the cobalt catalyst precursor, with the calcination being effected in air at a temperature between 95° C. and 400° C., and by using an air space velocity and a support heating rate such that all reducible cobalt is present in the support of the precursor as a supported cobalt oxide of formula unit CoOaHb, where a≧1,7 and b>0.

6. A process for preparing a cobalt catalyst, which process includes preparing a cobalt catalyst precursor by means of the process as claimed in claim 5; and in a reduction stage, reducing the cobalt catalyst precursor, to obtain the cobalt catalyst.

7. A process according to claim 5 wherein, in the calcination stage, the calcination includes passing hot air over and around the partially dried impregnated support, thereby drying the impregnated support further by removal, of the residual moisture present therein; and calcining the resultant dried impregnated support by decomposition of the cobalt salt into decomposition products comprising oxide(s) and any water of hydration, with the decomposition products being released in vapour form.

8. A process according to claim 7, which includes diluting or removing the decomposition products that are obtained during the calcination.

9. A process according to claim 7, wherein the cobalt salt is cobalt nitrate so that the oxides that are formed as decomposition products are nitrogen oxides; wherein the calcination is performed in a fluidized bed calciner; and wherein, after calcination, the nitrogen concentration in the catalyst precursor is less than 1,0 m %.

10. A process according to claim 9, wherein, during the calcination in the fluidized bed, the heating rate of the impregnated support and the space velocity of the air are controlled such that the residual moisture in the support is first driven off, whereafter decomposition of the cobalt nitrate is effected.

11. A process according to claim 10, wherein the air space velocity is at least 1,0 mn3/(kg Co (NO3)2.6H2O)/h; and wherein the heating rate complies with the following criteria.; when the air space velocity=1,0 mn3/(kg Co(NO3)2.6H2O)/h, the heating rate ≦1° C./min; however, when the air space velocity >1,0 mn3/(kg Co(NO3)2.6H2O)/h used, heating rates up to x° C./min, where x≧1, are allowed.

12 A process according to claim 10, which includes, in the calcination stage, initially heating the impregnated support until it reaches a calcination temperature, Tc, and thereafter; maintaining it at the calcination temperature, Tc, for a period of time, tc.

13. A process according to claim 12, wherein the heating rate up to the calcination temperature, Tc, is nonlinear.

14 A process according to claim 12, wherein the period of time, tc, for which isothermal calcination is applied at the calcination temperature; Tc, is between 0,1 and 20 hours.

15. A process according to claim 9, wherein the partially dried impregnated support from the support impregnation stage is not stored and not heated or cooled prior to the subsequent fluidized bed calcination stage so that it passes into the fluidized bed calcination stage at substantially the same temperature at which it leaven the support impregnation stage.

16. A process for preparing a cobalt catalyst precursor, which process includes in a support impregnation, stage, impregnating a particulate porous catalyst support with a cobalt salt, and partially drying the impregnated support, with the resultant partially dried impregnated support containing residual moisture; and in a calcination stage, calcining the partially dried impregnated support by passing air over and around the partially dried impregnated support and by heating the impregnated support to a temperature between 95° C. and 400° C. to obtain the cobalt catalyst precursor, with the heating rate of the impregnated support and the space velocity of the air being controlled such that the residual moisture in the support is first driven off, whereafter decomposition of the cobalt salt into decomposition products comprising oxide(s) and any water of. hydration, is effected, and with all reducible cobalt then being present in the support of the precursor as a supported cobalt oxide of formula unit CoOaHb, where a≧1,7 and b>0.

17. A process for preparing a cobalt catalyst, which process includes preparing a cobalt catalyst precursor by means of the process as claimed in claim 16; and in a reduction stage, reducing the cobalt catalyst precursor, to obtain the cobalt catalyst.

18. A process according to claim 16, wherein the decomposition products are released in vapour form, with the process including diluting or removing the decomposition products.

19. A process according to claim 16, wherein the cobalt salt is cobalt nitrate so that the oxides that are formed as decomposition products are nitrogen oxides; wherein the calcination is performed in a fluidized bed calciner; and wherein, after calcination, the nitrogen concentration in the catalyst precursor is less than 1,0 m %.

20. A process according to claim 19, wherein the air space velocity is at least 1,0 mn3/(kg Co(NO3)2.6H2O)/h; and wherein the heating rate complies with the following criteria: when the air space velocity=1,0 mn3/(kg Co(NO3)2.6H2O)/h, the heating rate ≦1° C./min; however, when the air space velocity >1,0 mn3/(kg Co (NO3)26H2O)/h used, heating rates up to x° C./min, where x≧1, are allowed.

21. A process according to claim 19, which includes, in the calcination stage, initially heating the impregnated support until it reaches a calcination temperature, Tc, and thereafter, maintaining it at the calcination temperature, Tc, for a period of time, tc.

22. A process according to claim 21, wherein the heating rate up to the calcination temperature; Tc, is non-linear.

23. A process according to claim 21, wherein the period of time, tc, for which isothermal calcination is applied at the calcination temperature, Tc, is between 0,1 and 20 hours.

24. A process according to claim 19, wherein the partially dried impregnated support from the support impregnation stage is not stored and not heated or cooled prior to the subsequent fluidized bed calcination stage so that it passes into the fluidized bed calcination stage at substantially the same temperature at which it leaves the support impregnation stage.