Coextrusion fabrication method

Abstract
A method of forming a composite article by injecting at least two composite materials comprising metal carbides into a mold to form a green compact is disclosed. The composite materials may be metal powders comprising a binder metal, a hard particle. The composite material may further comprise a plastic binder. The two different composite materials are injected into the mold to form the green compact. Additionally, the composite materials may be injected through a die before entering the mold. In a specific embodiment, the die forms at least one internal channel within the green compact.
Description
TECHNICAL FIELD AND INDUSTRIAL APPLICABILITY

The present invention is generally directed to methods of forming articles, such as tool blanks and other injection molded articles, having a composite construction including regions of differing composition and/or microstucture. The present invention is additionally directed to rotary tools and tool blanks for rotary tools having a composite construction and at least one coolant channel. The method of the present invention finds general application in the production of articles and may be applied in, for example, the production of cemented carbide rotary tools used in material removal operations such as drilling, reaming, countersinking, counterboring, and end milling.


BACKGROUND

Cemented carbide rotary tools (i.e., tools driven to rotate) are commonly employed in machining operations such as, for example, drilling, reaming, countersinking, counterboring, end milling, and tapping. Such tools are typically of a solid monolithic construction. The manufacturing process for such tools may involve consolidating metallurgical powder (comprised of particulate ceramic and binder metal) to form a compact. The compact is then sintered to form a cylindrical tool blank having a solid monolithic construction. As used herein, monolithic construction means that the tools are composed of a material, such as, for example, a cemented carbide material, having substantially the same characteristics at any working volume within the tool. Subsequent to sintering, the tool blank is appropriately machined to form the cutting edge and other features of the particular geometry of the rotary tool. Rotary tools include, for example, drills, end mills, reamers, and taps.


Rotary tools composed of cemented carbides are adapted to many industrial applications, including the cutting and shaping of materials of construction such as metals, wood, and plastics. Cemented carbide tools are industrially important because of the combination of tensile strength, wear resistance, and toughness that is characteristic of these materials. Cemented carbides materials comprise at least two phases: at least one hard ceramic component and a softer matrix of metallic binder. The hard ceramic component may be, for example, carbides of elements within groups IVB through VIB of the periodic table. A common example is tungsten carbide. The binder may be a metal or metal alloy, typically cobalt, nickel, iron or alloys of these metals. The binder “cements” the ceramic component within a matrix interconnected in three dimensions. Cemented carbides may be fabricated by consolidating a metallurgical powder blend of at least one powdered ceramic component and at least one powdered binder.


The physical and chemical properties of cemented carbide materials depend in part on the individual components of the metallurgical powders used to produce the material. The properties of the cemented carbide materials are determined by, for example, the chemical composition of the ceramic component, the particle size of the ceramic component, the chemical composition of the binder, and the ratio of binder to ceramic component. By varying the components of the metallurgical powder, rotary tools such as drills and end mills can be produced with unique properties matched to specific applications.


Monolithic rotary tools may additionally comprise coolant channels extending through its body and shank to permit the flow of a coolant, such as oil or water, to the cutting surfaces of the rotary tool. The coolant may enter the channel at the shank end and exit at the drill point. The coolant cools the rotary tool and work piece and assists in ejecting chips and dirt from the hole. The use of coolant during machining operations allows for the use of higher cutting speeds of the rotary tool and faster feed rates, in addition to extending tool life. Rotary tools with coolant channels are especially suited for drilling deep holes in hard materials.


However, the monolithic construction of rotary tools inherently limits their performance and range of applications. As an example, FIGS. 1(a) and 1(b) depictside and end views of a twist drill 10 having a typical design used for creating and finishing holes in construction materials such as wood, metals, and plastics. The twist drill 10 includes a chisel edge 11, which makes the initial cut into the workpiece. The cutting tip 14 of the drill 10 follows the chisel edge 11 and removes most of the material as the hole is being drilled. The outer periphery 16 of the cutting tip 14 finishes the hole. During the cutting process, cutting speeds vary significantly from the center of the drill to the drill's outer periphery. This phenomenon is shown in FIG. 2(a) and 2(b), which in the graph of FIG. 2(a) compare cutting speeds at an inner (D1), outer (D3), and intermediate (D2) diameter (shown in FIG. 2(a)) on the cutting tip of a typical twist drill. In FIG. 2(b), the outer diameter (D3) is 1.00 inch and diameters D1 and D2 are 0.25 and 0.50 inch, respectively. FIG. 2(a) shows the cutting speeds at the three different diameters when the twist drill operates at 200 revolutions per minute. As illustrated in FIGS. 2(a) and (b), the cutting speeds measured at various points on the cutting edges of rotary tools will increase with the distance from the axis of rotation of the tools.


Because of these variations in cutting speed, drills and other rotary tools having a monolithic construction will not experience uniform wear and/or chipping and cracking of the tool's cutting edges at different points ranging from the center to the outside edge of the tool's cutting surface. Also, in drilling casehardened materials, the chisel edge is typically used to penetrate the case, while the remainder of the drill body removes material from the casehardened material's softer core, Therefore, the chisel edge of conventional drills of monolithic construction used in that application will wear at a much faster rate than the remainder of the cutting edge, resulting in a relatively short service life for such drills. In both instances, because of the monolithic construction of conventional cemented carbide drills, frequent regrinding of the cutting edge is necessary, thus placing a significant limitation on the service life of the bit. Frequent regrinding and tool changes also result in excessive downtime for the machine tool that is being used.


Therefore, composite articles, such as composite rotary tools have been used, such as those tools described in described in U.S. Pat. No. 6,511,265 which is hereby incorporated by reference in its entirety. If designed properly, composite rotary tools may have increased tool service life as compared to rotary tools having a more monolithic construction. However, there exists a need for drills and other rotary tools that have different characteristics at different regions of the tool and comprise coolant channels. As an example, a need exists for cemented carbide drills and other rotary tools that will experience substantially even wear regardless of the position on the tool face relative to the axis of rotation of the tool and allow cooling at the cutting surfaces. There is a need for a composite rotary tool having coolant channels so composite rotary tools may have the same benefits as monolithic rotary tools. There is also a need for a versatile method of producing composite rotary tools and composite rotary tools comprising coolant channels.


SUMMARY

The invention is directed to a method of forming an article, wherein the method comprises coextruding at least two composite materials comprising metal carbides to form a green compact. In an embodiment, at least one of the composite materials includes greater than zero to less than 5 weight percent cubic carbides. Embodiments of the method include a coextrusion process for forming cemented carbide articles. The two composite materials may be metal powders comprising a binder metal and hard particles. The composite material may further comprise a plastic binder. The two different composite materials may be coextruded to form the green compact. In a specific embodiment, the coextrusion process forms at least one internal channel within the green compact. The green compact formed in embodiments of the method comprises at least two cemented carbide grades. In certain embodiments, the cemented carbide grades are coaxially disposed and comprise two helical channels.


The reader will appreciate the foregoing details and advantages of the present invention, as well as others, upon consideration of the following detailed description of embodiments of the invention. The reader also may comprehend such additional details and advantages of the present invention upon using the invention.





BRIEF DESCRIPTION OF THE DRAWINGS

The features and advantages of the present invention may be better understood by reference to the accompanying drawings in which:



FIGS. 1(
a) and 1(b) are plan and on-end views, respectively, of a conventional twist drill with coolant channels;



FIG. 2(
a) is a graph indicating cutting speeds at the three diameters D1, D2, and D3 of a conventional twist drill indicated in FIG. 2(b);



FIGS. 3(
a) and (b) include a transverse section (FIG. 3(a) and a longitudinal section (FIG. 3(b)) of rods produced by embodiments of the method of the present invention comprising a core of centered carbide grade B and a shell of cemented carbide grade A;



FIGS. 4(
a)-(d) are representations of a cross-sectional views of an embodiments of a composite cemented carbide;



FIGS. 5 (a)-(d) are embodiments of blanks showing examples of the different configurations of coolant channels, such as a straight single coolant channel (FIG. 5(a)); two straight channels (FIG. 5(b)); two helical or spiral channels (FIG. 5(c)); and three helical or spiral channels (FIG. 5(d));



FIG. 6(
a) is a representation of the coextrusion pressing apparatus used in coextrusion of a tube of grade A and a rod of grade B through a die with internal spiral serrations to produce a blank with helical or spiral channels.



FIG. 6(
b) is a representation of a channel die;



FIG. 6(
c) is a photograph of a coextruded composite cemented carbide rod with internal channels exiting from a die with spiral serrations;



FIG. 7 is representation of a dry bag isostatic pressing apparatus used in an embodiment of a method of the present invention including consolidating cemented carbide grade B with an extruded rod with internal channels made from a cemented carbide grade A;



FIG. 8(
a) is a photograph of a longitudinal cross-section of a composite rod with internal coolant channels of the present invention, the nylon wires in the photograph have been inserted in the channels to more clearly show their location and the path of the coolant channels;



FIG. 8(
b) is a photograph of a longitudinal cross-section of a drill made from a composite cemented carbide having internal coolant channels;



FIG. 9 is a partial cut-away plan view of an embodiment of a step drill constructed according to the present invention; and



FIG. 10 is a representation of the injecting molding apparatus according to one embodiment of a method of the present invention.





DESCRIPTION OF EMBODIMENTS

The present invention provides rotary cutting tools, cutting tool blanks, rods, and other articles having a composite construction and a method of making such articles. The articles may further comprise internal channels, such as coolant channels, if desired. As used herein, a rotary tool is a tool having at least one cutting edge that is driven to rotate. As used herein, “composite” construction refers to an article having regions differing in chemical composition and/or microstructure. These differences result in the regions having properties differing with respect to at least one characteristic. The characteristic may be at least one of, for example, hardness, tensile strength, wear resistance, fracture toughness, modulus of elasticity, corrosion resistance, coefficient of thermal expansion, and coefficient of thermal conductivity. Composite rotary tools that may be constructed as provided in the present invention include drills and end mills, as well as other tools that may be used in, for example, drilling, reaming, countersinking, counterboring, end milling, and tapping of materials.


The present invention more specifically provides a composite rotary tool having at least one cutting edge, at least two regions of cemented carbide material that differ with respect to at least one characteristic, and at least one coolant channel. The differing characteristics may be provided by variation of at least one of the chemical composition and the microstructure among the two regions of cemented carbide material. The chemical composition of a region is a function of, for example, the chemical composition of the ceramic component and/or binder of the region and the carbide-to-binder ratio of the region. For example, one of the two cemented carbide material regions of the rotary tool may exhibit greater wear resistance, enhanced hardness, and/or a greater modulus of elasticity than the other of the two regions.


Aspects of present invention may be described in relation to the tool blank 400, shown in FIG. 4(a) in a cross-sectional view transverse to the axis. The tool blank 400 is a generally cylindrical sintered compact with two coaxially disposed cemented carbide regions 410, 420 and coolant channels 430. It will be apparent to one skilled in the art, however, that the following discussion of the present invention also may be adapted to the fabrication of composite rotary tools and tool blanks having more complex geometry and/or more than two regions. Thus, the following discussion is not intended to restrict the invention, but merely to illustrate embodiments of it.


In the embodiment of FIG. 4(a), the cylindrical rotary tool blank 400 is comprised of two differing cemented carbide regions, a core region 420 and an outer region 410. The core region 420 and the outer region 410 are both of a cemented carbide material including ceramic particles in a continuous matrix of binder. Preferably, the cemented carbide materials in the core region 420 and in the outer region 410 include a ceramic component composed of carbides of one or more elements belonging to groups IVB through VIB of the periodic table including less than 5% cubic carbides or, in some applications, less than 3 wt. % cubic carbides. Embodiments of the present invention may comprise less than 5 wt. %, cubic carbides because cubic carbides may reduce strength transverse rupture strength of the article, increase the production costs, and reduce the fracture toughness. This is especially important for tools used to machine hard work pieces where the machining results in a shearing action and the strength of the drill should be the greatest.


The ceramic component preferably comprises about 60 to about 98 weight percent of the total weight of the cemented carbide material in each region. The carbide particles are embedded within a matrix of binder material that preferably constitutes about 2 to about 40 weight percent of the total material in each region. The binder preferably is one or more of Co, Ni, Fe, and alloys of these elements. The binder also may contain, for example, elements such as W, Cr, Ti, Ta, V, Mo, Nb, Zr, Hf, and C up to the solubility limits of these elements in the binder. Additionally, the binder may contain up to 5 weight percent of elements such as Cu, Mn, Ag, Al, and Ru One skilled in the art will recognize that any or all of the constituents of the cemented carbide material may be introduced in elemental form, as compounds, and/or as master alloys.


The core region 420 of the tool blank 400 is autogenously bonded to the outer region 410 at an interface 415. The interface 415 is shown in FIG. 4(a) to be cylindrical, but it will be understood that the shapes of the interfaces of cemented carbide material regions of the composite rotary tools of the present invention are not limited to cylindrical configurations. The autogenous bond between the regions at the interface 415 may be formed by, for example, a matrix of binder that extends in three dimensions from the core region 420 to the outer region 410, or vice versa. The ratio of binder to ceramic component in the two regions may be the same or different and may be varied between the regions to affect the regions' relative characteristics. By way of example only, the ratio of binder to ceramic component in the adjacent regions of the composite tool blank 30 may differ by 1 to 10 weight percent. The characteristics of the cemented carbide materials in the different regions of the composite rotary tools of the present invention may be tailored to particular applications.


One skilled in the art, after having considered the description of present invention, will understand that the improved rotary tool of this invention could be constructed with several layers of different cemented carbide materials to produce a progression of the magnitude of one or more characteristics from a central region of the tool to its periphery. Thus, for example, a twist drill may be provided with multiple, coaxially disposed regions of cemented carbide material and wherein each such region has successively greater hardness and/or wear resistance than the adjacent, more centrally disposed region. Coolant channels may be provided in any of the regions or intersecting two or more regions. The method of the present invention provides great design flexibility in the design of extruded articles. Alternately, rotary tools of the present invention could be made with other composite configurations wherein differences in a particular characteristic occur at different regions of the tool.


A major advantage of the composite cemented carbide rotary tools of the present invention is the flexibility available to the tool designer to tailor properties of regions of the tools to suit different applications. For example, the size, location, thickness, geometry, and/or physical properties of the individual cemented carbide material regions of a particular composite blank of the present invention may be selected to suit the specific application of the rotary tool fabricated from the blank. In addition, the coolant channels may be located in the desired locations and be helical, spiral, linear, or a combination of such shapes. Thus, for example, the stiffness of one or more cemented carbide regions of the rotary tool experiencing significant bending during use may be of a cemented carbide material having an enhanced modulus of elasticity; the hardness and/or wear resistance of one or more cemented carbide regions having cutting surfaces and that experience cutting speeds greater than other regions may be increased; and/or the corrosion resistance of regions of cemented carbide material subject to chemical contact during use may be enhanced.



FIGS. 4(
b) and 4(c) show additional embodiments of the present invention. These embodiments may additionally comprise channels, such as coolant channels. The embodiment of FIG. 4(b) comprises a tube with internal regions of different cemented carbide grades. In this example, the rod 440 comprises an outer region 441 of a first cemented carbide, a first inner region 442 of a second cemented carbide, and an additional inner regions 443 that could comprise the same or different cemented carbides. As shown in FIG. 4(c), the rod 440 could be produced, for example, by coextruding a set 450 comprising a tube 451 filled with rods 452 and 453. Rods 452 may be formed from a cemented carbide that has at least one characteristic that differs from the rods 453, for example.


By way of example only, an additional embodiment of a rotary tool of the present invention is shown in FIG. 9. FIG. 9 depicts a step drill 110 constructed according to the present invention. The drill 110 includes a cutting portion 112 including several helically oriented cutting edges 114. The drill 110 also includes a mounting portion 116 that is received by a chuck to mount the drill to a machine tool (not shown). The drill 110 is shown in partial cross-section to reveal three regions of cemented carbide materials that differ relative to one another with regard to at least one characteristic. A first region 118 is disposed at the cutting tip of the drill 110. The cemented carbide material from which region 118 is composed exhibits an enhanced wear resistance and hardness relative to a central region 120 forming the core of the drill 110. The core region is of a cemented carbide material that exhibits an enhanced modulus of elasticity relative to the remaining two regions. The enhanced modulus of elasticity reduces the tendency of the drill 110 to bend as it is forced into contact with a work piece. The drill also includes an outer region 122 that defines the several helically oriented cutting edges 114. The outer region surrounds and is coaxially disposed relative to the core region 120. The outer region 122 is composed of a cemented carbide material that exhibits enhanced hardness and wear resistance relative to both the core region 120 and the tip region 118. The cutting surfaces 114 that are defined by the outer region 122 experience faster cutting speeds than cutting regions proximate to the drill's central axis. Thus, the enhanced wear resistance and hardness of the outer region 122 may be selected so that uniformity of wear of the cutting surfaces is achieved.


Embodiments of the present invention also include additional methods of making composite cemented carbide articles. Embodiments include a method of forming a composite article by coextruding at least two composite materials comprising cemented carbides to form a green compact. The coextruding may be performed by direct or indirect extrusion process. The feed chamber of the extruder is filled with two grades of materials, such as two grades of carbide powder and binder powder mixed with a plastic binder. The plastic binder material may be present in concentrations from about 33 wt. % to 67 wt. % and decreases the viscosity of the powder metal mixture to allow extrusion.


The extrusion process for cemented carbides is well known in the art. In a typical extrusion process, metal powders are mixed with a plastic binder. Any typical plastic binder may be used such as plastic binders based upon benzyl alcohol, cellulose, polymers, or petroleum products. Typically, a high sheen mixing process is used to ensure intimate contact between the metal powders and the plastic binder.


The metal/binder mixer may then be pumped by screw feeder through the extruder to produce an extruded product. Embodiments of the method of the present invention include coextrusion of at least two cemented carbide grades. The term coextrusion, as used herein, means that two materials are extruded simultaneously to form a single article incorporating both materials. Any coextrusion process may be used in the method of the present invention such as, pumping two grades of cemented carbide to separate sections of funnel or die wherein the two grades exit the die in intimate contact with each other.


An embodiment of the coextrusion process is shown in FIG. 6(a). The feed chamber 600 is filled with a rod 610 of a first grade of cemented carbide powder and a tube 620 of a second grade of cemented carbide powder. The rod 610 and the tube 620 were individually formed by separate extrusion processes as known in art. In certain embodiments, the tube 620 may be extruded directly into the feed chamber 600. The rod 610, formed in a separate extrusion process may then be inserted into the tube 620 already in the feed chamber 600.


In this embodiment of the extrusion process, a plunger (not shown) pushes the rod 610 and the tube 620 through the feed chamber and into the funnel 630. The funnel 630 reduces in cross-sectional area from the feed chamber to the die 640. The funnel 630 causes compaction and consolidation of the cemented carbide powders resulting in intimate contact between the rod 610 and tube 620 and formation of a green compact (“extruded material”).


In certain embodiments, the extrusion process may also include a channel die 650 (see FIG. 6(b)) incorporated between the funnel 630 and the die 640. The channel die comprises two wires 660 or the channel die may comprise other means for making internal channels in the green compact. The wires 660 are connected to arms 670 which hold the wires 660 so they may contact the extruded material. The wires 660 result in the formation of channels in the extruded material. The wires 660 may be made from any material capable of forming channels in the extruded material, such as, but not limited to, nylon, polymer coated metal wire, polyethylene, high density polyethylene, polyester, polyvinyl chloride, polypropylene, an aramid, Kevlar, polyetheretherketone, natural materials, cotton, hemp, and jute. Preferably in certain applications, such as for formation of helically oriented channels, the wire is a flexible wire. However, for linearly oriented channels and in some helical applications, rigid wires may be used. The channels may be used as coolant channels in rotary tools. The wires 660 may be used to form helically oriented channels, linearly oriented channels, or a combination thereof. FIGS. 5(a)-(d) depict embodiments of blanks showing examples of the different configurations of coolant channels, such as a straight single coolant channel (FIG. 5(a)); two straight channels (FIG. 5(b)); two helical or spiral channels (FIG. 5(c)); and three helical or spiral channels (FIG. 5(d)). A cross-section of the wire or other channel making component may be any shape, such as round, elliptical, triangular, square, and hexagonal.


Helically oriented channels may be formed in the extruded material in embodiments where the extruded material rotates relative to the channel die 650. The extruded material may be rotated by incorporating spiral serrations in the die 640 (see FIG. 6(a)). In FIG. 6(c), extruded material 680 exits die 645 that includes helical serrations on the internal surface of the die 645. As the extruded material passes over the serrations, the extruded material is caused to rotate relative to the channel die (not shown). Alternatively, the die may rotate to cause the extruded material to rotate relative to the channel die. Other channel dies may be used, such dies comprising fixed helical coils wherein the extruded material is cause to rotate relative to the channel die in the same rotation as the helical coils, or any other channel forming means.


The channel die may be a separate component or may be integral to the funnel, die, or other component in the extrusion system. The channel die may be capable of making at least one channel in the extruded material. The number and size of the channels may be limited by the size of the extruded material, the size of the channels, and the application for the ultimate use of the extruded material. In embodiments comprising a channel die comprising wires, the number of wires will correspond to the number of channels formed in the extruded material. For a rotary tool application, it may be preferable to have an equal number of channels as there will be flutes for example.


Embodiments of the present invention may further include loading the feed chamber with at least two cemented carbide grades. At least one cemented carbide grade loaded in the feed chamber may be an extruded form of either a rod, tube, bar, strips, rectangles, gear profiles, star shapes, or any other shape that may be formed in an extrusion process. In rotary tool or roller applications, it may be preferable that at least one of the two cemented carbide grades be in the form of a rod shape and at least one cemented carbide in a shape of a tube. In other applications, the feed chamber may be filled with multiple tubes and/or multiple rods of different cemented carbide grades. If multiple rods are used, the extruded material may be formed with specific grades of cemented carbides in specific regions or randomly distributed throughout the cross-section of the extruded material.



FIG. 7 is representation of a dry bag isostatic pressing apparatus used in an embodiment of a method of the present invention including consolidating cemented carbide grade B with an extruded rod with internal channels made from a cemented carbide grade A. The figure depicts powder compaction of an outer cemented carbide grade onto the extruded rod including integral coolant holes.



FIG. 8(
a) is a photograph of a longitudinal cross-section of a composite rod with internal coolant channels of the present invention, wherein the nylon wires in the photograph have been inserted in the channels to more clearly show their location and the path of the coolant channels. FIG. 8(b) is a photograph of a longitudinal cross-section of a drill according to the invention made from a composite cemented carbide having internal coolant channels.


A further embodiment of the present invention may comprise extruding a cemented carbide grade to form an extruded green compact and pressing the extruded green compact with a second cemented carbide grade to form a pressed green compact. The extruded green compact may optionally comprise internal channels formed as described above, for example.


The present invention is generally directed to methods of forming articles, such as tool blanks, having a composite construction including regions of differing composition and/or microstructure. An embodiment of the method includes injection molding of articles having a composite construction including regions of differing composition and/or microstructure. The method of the present invention finds general application in the production of rotary tools and may be applied in, for example, the production of cemented carbide rotary tools used in material removal operations such as drilling, reaming, countersinking, counter boring, and end milling.


Referring to FIG. 10, the present invention is directed to methods of forming an article comprising injecting at least two composite materials 1010, 1020 comprising metal carbides into a mold 1030 to form a green compact. The composite materials may be as described above. The injecting at least two composite materials may be performed through a die 1040 and, in certain embodiments, the die may comprise means for making internal channels in the green compact. As described above, the die may comprise at least one wire to form an internal channel within the green compact, wherein the wire may be rigid or flexible. The die for making internal channels may be used in combination with a die or mold that has helical serrations causing the composite material to twist as it enters the mold. In certain embodiments, the mold may be partially filled with at least one composite material or other component prior to the injecting the composite material into the mold.


In one embodiment, the method comprises mixing powdered metals with a plastic binder to form the composite material prior to injecting the composite material into the mold. The plastic binder material may be present in concentrations from about 25 vol. % to 75 vol. % and decreases the viscosity of the powder metal mixture to facilitate injection.


The primary difference between extrusion and injection molding is that while extrusion may be considered a continuous process for one batch (with material continuously entering at one end of the die and leaving the other end), injection molding comprises stopping the process when the mold is filled. Generally, an injection molding method is a technique for making more complex articles. Cemented carbides mixed with a plastic binder are injected at high pressure into a mold. The mold is the inverse of the desired shape. Molds are typically made from metal, usually either steel or aluminum, but may be carbon, or other heat resistant material, if the green compact is to be heat treated, for example by sintering or presintering, in the mold and optionally may be further machined to form or refine the features of the desired part.


The design of molded parts and their molds is carefully considered to ensure that the injection molded part may be released from the mold, that the molds can be completely filled and the composite material densified, and to compensate for material shrinkage due to plastic binder removal and normal sintering shrinkage.


Molds typically comprise at least two parts to permit the part to be extracted. Complex parts are formed using more complex molds, which may require moveable sections, called slides, which are inserted into the mold to form particular features that cannot be formed using only two parts, but are then withdrawn to allow the part to be released. Some molds allow previously molded parts to be re-inserted to allow a new plastic layer to form around the first part. The molds of the present invention may be simple or complex and may incorporate many features, such as steps such as rods having sections of different radii, flutes, shanks, keys, holes, edges, etc.


In embodiments of the method, the blended metal powders are intimately mixed with a plastic binder and forced under pressure into a mold cavity. The powdered metal may be placed into a feed hopper, a large open bottomed container, which feeds the metal into a screw. A hydraulic or electric motor rotates the screw feeding the pellets through the screw. As the screw rotates, the pellets are moved forward in the screw undergoing increasing pressure and friction which causes heating and compaction of the powdered metal.


Although the present invention has been described in connection with certain embodiments, those of ordinary skill in the art will, upon considering the foregoing description, recognize that many modifications and variations of the invention may be employed. All such variations and modifications of the present invention are intended to be covered by the foregoing description and the following claims.

Claims
  • 1. A method of forming an article, the method comprising: coextruding at least two composite material powders comprising metal carbides to form an extruded green compact having at least two regions, wherein at least one of the composite material powders includes greater than zero to less than 5 weight percent cubic carbides, andforming at least one internal channel within the extruded green compact intersecting at least two regions of the extruded green compact.
  • 2. The method of claim 1, wherein the at least one of the composite material powders includes greater than zero to less than 3 weight percent cubic carbides.
  • 3. The method of claim 1, wherein the at least two composite material powders comprise a first composite material powder and a second composite material powder, wherein the composition of the first composite material powder differs from the composition of the second composite material powder.
  • 4. The method of claim 1, wherein the at least two composite material powders individually comprise a metal carbide and a binder.
  • 5. The method of claim 1 comprising coextruding at least two composite material powders through at least one of a funnel and a die.
  • 6. The method of claim 5, wherein coextruding at least two composite material powders comprises pumping a first composite material powder through a first portion of the funnel, and pumping a second composite material powder through a second portion of the funnel, wherein the two composite material powders exit the funnel in intimate contact with each other.
  • 7. The method of claim 5, wherein the at least one of a funnel and a die comprises at least one element to form the at least one internal channel within the extruded green compact.
  • 8. The method of claim 5, wherein the at least one of a funnel and a die comprises at least one wire to form the at least one internal channel within the extruded green compact.
  • 9. The method of claim 1, wherein the at least two regions of the extruded green compact differ in at least one characteristic.
  • 10. The method of claim 1, wherein the at least one internal channel in the extruded green compact intersects an outer region of the extruded green compact and a core region of the extruded green compact.
  • 11. The method of claim 5, wherein the at least one of a funnel and a die comprises at least two wires, wherein each wire forms an internal channel within the extruded green compact.
  • 12. The method of claim 5, wherein the at least one of a funnel and a die comprises internal spiral serrations.
  • 13. The method of claim 5 wherein the at least one of a funnel and a die comprises a rotating die.
  • 14. The method of claim 5, wherein the at least one of a funnel and a die comprises a channel die.
  • 15. The method of claim 1 comprising loading a feed chamber of a coextruder with the at least two composite material powders.
  • 16. The method of claim 1, wherein the extruded green compact comprises a first composite material powder and a second composite material powder, and the composite material powders are coaxially disposed.
  • 17. The method of claim 1, wherein the extruded green compact comprises at least an outer region and a coaxially disposed core region, wherein the outer region comprises the first composite material powder, the core region comprises the second composite material powder, and the first composite material powder differs from the second composite material powder in at least one characteristic.
  • 18. The method of claim 1, wherein the extruded green compact comprises at least one helical channel.
  • 19. The method of claim 1, wherein the extruded green compact comprises two channels.
  • 20. The method of claim 1, wherein the method comprises coextruding three composite material powders comprising metal carbides to form the extruded green compact, wherein at least one of the composite material powders includes greater than zero to less than 5 weight percent cubic carbides.
  • 21. The method of claim 20, wherein the extruded green compact comprises an outer region comprising the first composite material powder, a first inner region comprising the second composite material powder, and a second inner region comprising the third composite material powder.
  • 22. The method of claim 20, wherein the extruded green compact comprises a tip comprising the first composite material powder, an inner region comprising the second composite material powder, and an outer region comprising the third composite material powder.
  • 23. The method of claim 20 wherein the first composite material powder, the second composite material powder, and the third composite material powder are cemented carbide powders, each cemented carbide powder individually comprising a metal carbide and a binder.
  • 24. The method of claim 1, wherein the first composite material powder and the second composite material powder are cemented carbide powders, each cemented carbide powder individually comprising a metal carbide and a binder.
  • 25. The method of claim 1, wherein the article is selected from a rotary cutting tool blank, a rotary cutting tool, and a rod.
  • 26. The method of claim 1, wherein the article is a rotary cutting tool selected from a drill, an end mill, a reaming tool, a countersinking tool, a counterboring tool, and a tapping tool.
  • 27. The method of claim 1, wherein the article is an elongate generally cylindrical article.
  • 28. A method of forming an article, the method comprising: providing two composite material powders comprising metal carbides, wherein at least one composite material powder includes greater than zero to less than 5 weight percent cubic carbides, andcoextruding the at least two composite material powders to form an extruded green compact,wherein the composite material powders are in individually extruded forms prior to coextruding.
  • 29. The method of claim 28, wherein the extruded forms prior to coextruding is one of a rod, a tube, a bar, and a strip.
  • 30. The method of claim 28, wherein the extruded forms prior to coextruding have a shape that is one of a rectangle, a gear profile, and a star shape.
  • 31. The method of claim 28 comprising loading a feed chamber of a coextruder with the at least two composite material powders.
  • 32. The method of claim 31, wherein loading the feed chamber comprises loading a first composite material powder in the form of an extruded rod into the feed chamber.
  • 33. The method of claim 32, wherein the extruded rod is formed by individually extruding the first composite material powder directly into the feed chamber.
  • 34. The method of claim 32, wherein loading the feed chamber comprises loading a second composite material powder in the form of an extruded tube into the feed chamber.
  • 35. The method of claim 34, wherein the extruded tube is individually extruded directly into the feed chamber.
  • 36. The method of claim 28, wherein a first extruded form is an extruded rod and a second extruded form is an extruded tube.
  • 37. The method of claim 36, wherein the extruded rod is disposed in the extruded tube prior to coextruding the extruded forms.
  • 38. The method of claim 28, wherein the composition of a first composite material powder differs from the composition of a second composite material powder.
  • 39. The method of claim 28, wherein the first and second composite material powders include a binder.
  • 40. The method of claim 28, wherein the first composite material powder and the second composite material powder are cemented carbide powders, each cemented carbide powder individually comprising a metal carbide and a binder.
  • 41. The method of claim 28, wherein the at least two composite material powders are coextruded through at least one of a funnel and a die.
  • 42. The method of claim 41, wherein the at least one of a funnel and a die comprises internal spiral serrations.
  • 43. The method of claim 28, wherein the extruded green compact includes an internal channel.
  • 44. The method of claim 28, wherein the at least one composite material powder includes greater than zero to less than 3 weight percent cubic carbides.
  • 45. The method of claim 28, wherein the article is selected from a rotary cutting tool blank, a rotary cutting tool, and a rod.
  • 46. The method of claim 28, wherein the article is a rotary cutting tool selected from a drill, an end mill, a reaming tool, a countersinking tool, a counterboring tool, and a tapping tool.
  • 47. The method of claim 28, wherein the article is an elongate generally cylindrical article.
CROSS REFERENCE TO RELATED APPLICATIONS

This application is a continuation application claiming priority under 35 U.S.C. §120 to U.S. application Ser. No. 11/585,408, filed on Oct. 24, 2006, now U.S. Pat. No. 8,318,063, which in turn claims priority under 35 U.S.C. §120 as a continuation-in-part of co-pending U.S. application Ser. No. 11/167,811, filed on Jun. 27, 2005.

US Referenced Citations (522)
Number Name Date Kind
1509438 Miller Sep 1924 A
1530293 Breitenstein Mar 1925 A
1808138 Hogg et al. Jun 1931 A
1811802 Newman Jun 1931 A
1912298 Newman May 1933 A
2054028 Benninghoff Sep 1936 A
2093507 Bartek Sep 1937 A
2093742 Staples Sep 1937 A
2093986 Staples Sep 1937 A
2240840 Fischer May 1941 A
2246237 Benninghoff Jun 1941 A
2283280 Nell May 1942 A
2299207 Bevillard Oct 1942 A
2351827 McAllister Jun 1944 A
2422994 Taylor Jun 1947 A
2819958 Abkowitz et al. Jan 1958 A
2819959 Abkowitz et al. Jan 1958 A
2906654 Abkowitz Sep 1959 A
2954570 Couch Oct 1960 A
3041641 Hradek et al. Jul 1962 A
3093850 Kelso Jun 1963 A
3368881 Abkowitz et al. Feb 1968 A
3471921 Feenstra Oct 1969 A
3482295 Trent Dec 1969 A
3490901 Hachisuka et al. Jan 1970 A
3581835 Stebley Jun 1971 A
3629887 Urbanic Dec 1971 A
3660050 Iler et al. May 1972 A
3757879 Wilder et al. Sep 1973 A
3762882 Grutza Oct 1973 A
3776655 Urbanic Dec 1973 A
3782848 Pfeifer Jan 1974 A
3806270 Tanner et al. Apr 1974 A
3812548 Theuerkaue May 1974 A
3855444 Palena Dec 1974 A
3889516 Yankee et al. Jun 1975 A
RE28645 Aoki et al. Dec 1975 E
3936295 Cromwell et al. Feb 1976 A
3942954 Frehn Mar 1976 A
3980549 Grutza Sep 1976 A
3987859 Lichte Oct 1976 A
4009027 Naidich et al. Feb 1977 A
4017480 Baum Apr 1977 A
4047828 Makely Sep 1977 A
4094709 Rozmus Jun 1978 A
4097180 Kwieraga Jun 1978 A
4097275 Horvath Jun 1978 A
4105049 Anderson Aug 1978 A
4106382 Salje et al. Aug 1978 A
4126652 Oohara et al. Nov 1978 A
4128136 Generoux Dec 1978 A
4170499 Thomas et al. Oct 1979 A
4181505 De Vries et al. Jan 1980 A
4198233 Frehn Apr 1980 A
4221270 Vezirian Sep 1980 A
4229638 Lichte Oct 1980 A
4233720 Rozmus Nov 1980 A
4255165 Dennis et al. Mar 1981 A
4270952 Kobayashi Jun 1981 A
4276788 van Nederveen Jul 1981 A
4277106 Sahley Jul 1981 A
4277108 Wallace Jul 1981 A
4306139 Shinozaki et al. Dec 1981 A
4311490 Bovenkerk et al. Jan 1982 A
4325994 Kitashima et al. Apr 1982 A
4327156 Dillon et al. Apr 1982 A
4331741 Wilson May 1982 A
4340327 Martins Jul 1982 A
4341557 Lizenby Jul 1982 A
4351401 Fielder Sep 1982 A
4376793 Jackson Mar 1983 A
4389952 Dreier et al. Jun 1983 A
4396321 Holmes Aug 1983 A
4398952 Drake Aug 1983 A
4423646 Bernhardt Jan 1984 A
4478297 Radtke Oct 1984 A
4497358 Gnadig et al. Feb 1985 A
4499048 Hanejko Feb 1985 A
4499795 Radtke Feb 1985 A
4520882 van Nederveen Jun 1985 A
4526748 Rozmus Jul 1985 A
4547104 Holmes Oct 1985 A
4547337 Rozmus Oct 1985 A
4550532 Fletcher, Jr. et al. Nov 1985 A
4552232 Frear Nov 1985 A
4553615 Grainger Nov 1985 A
4554130 Ecer Nov 1985 A
4562990 Rose Jan 1986 A
4574011 Bonjour et al. Mar 1986 A
4579713 Lueth Apr 1986 A
4587174 Yoshimura et al. May 1986 A
4592685 Beere Jun 1986 A
4596694 Rozmus Jun 1986 A
4597456 Ecer Jul 1986 A
4597730 Rozmus Jul 1986 A
4604106 Hall Aug 1986 A
4604781 Rankin, III Aug 1986 A
4605343 Hibbs, Jr. et al. Aug 1986 A
4609577 Long Sep 1986 A
4630693 Goodfellow Dec 1986 A
4642003 Yoshimura Feb 1987 A
4646857 Thompson Mar 1987 A
4649086 Johnson Mar 1987 A
4656002 Lizenby et al. Apr 1987 A
4662461 Garrett May 1987 A
4667756 King et al. May 1987 A
4686080 Hara et al. Aug 1987 A
4686156 Baldoni, II et al. Aug 1987 A
4694919 Barr Sep 1987 A
4708542 Emanuelli Nov 1987 A
4722405 Langford Feb 1988 A
4729789 Ide et al. Mar 1988 A
4735656 Schaefer et al. Apr 1988 A
4743515 Fischer et al. May 1988 A
4744943 Timm May 1988 A
4749053 Hollingshead Jun 1988 A
4752159 Howlett Jun 1988 A
4752164 Leonard, Jr. Jun 1988 A
4761844 Turchan Aug 1988 A
4779440 Cleve et al. Oct 1988 A
4780274 Barr Oct 1988 A
4804049 Barr Feb 1989 A
4809903 Eylon et al. Mar 1989 A
4813823 Bieneck Mar 1989 A
4831674 Bergstrom et al. May 1989 A
4838366 Jones Jun 1989 A
4861350 Phaal et al. Aug 1989 A
4871377 Frushour Oct 1989 A
4881431 Bieneck Nov 1989 A
4884477 Smith et al. Dec 1989 A
4889017 Fuller et al. Dec 1989 A
4899838 Sullivan et al. Feb 1990 A
4919013 Smith et al. Apr 1990 A
4923512 Timm et al. May 1990 A
4934040 Turchan Jun 1990 A
4943191 Schmitt Jul 1990 A
4956012 Jacobs et al. Sep 1990 A
4968348 Abkowitz et al. Nov 1990 A
4971485 Nomura et al. Nov 1990 A
4991670 Fuller et al. Feb 1991 A
5000273 Horton et al. Mar 1991 A
5010945 Burke Apr 1991 A
5030598 Hsieh Jul 1991 A
5032352 Meeks et al. Jul 1991 A
5041261 Buljan et al. Aug 1991 A
5049450 Dorfman et al. Sep 1991 A
RE33753 Vacchiano et al. Nov 1991 E
5067860 Kobayashi et al. Nov 1991 A
5075315 Rasmussen Dec 1991 A
5075316 Hubele Dec 1991 A
5080538 Schmitt Jan 1992 A
5090491 Tibbitts et al. Feb 1992 A
5092412 Walk Mar 1992 A
5094571 Ekerot Mar 1992 A
5096465 Chen et al. Mar 1992 A
5098232 Benson Mar 1992 A
5110687 Abe et al. May 1992 A
5112162 Hartford et al. May 1992 A
5112168 Glimpel May 1992 A
5116659 Glatzle et al. May 1992 A
5126206 Garg et al. Jun 1992 A
5127776 Glimpel Jul 1992 A
5135801 Nyström et al. Aug 1992 A
5161898 Drake Nov 1992 A
5174700 Sgarbi et al. Dec 1992 A
5179772 Braun et al. Jan 1993 A
5186739 Isobe et al. Feb 1993 A
5203513 Keller et al. Apr 1993 A
5203932 Kato et al. Apr 1993 A
5217081 Waldenström et al. Jun 1993 A
5232522 Doktycz et al. Aug 1993 A
5250355 Newman et al. Oct 1993 A
5266415 Newkirk et al. Nov 1993 A
5273380 Musacchia Dec 1993 A
5281260 Kumar et al. Jan 1994 A
5286685 Schoennahl et al. Feb 1994 A
5305840 Liang et al. Apr 1994 A
5311958 Isbell et al. May 1994 A
5326196 Noll Jul 1994 A
5333520 Fischer et al. Aug 1994 A
5335738 Waldenström et al. Aug 1994 A
5338135 Noguchi et al. Aug 1994 A
5346316 Okada et al. Sep 1994 A
5348806 Kojo et al. Sep 1994 A
5354155 Adams Oct 1994 A
5359772 Carlsson et al. Nov 1994 A
5373907 Weaver Dec 1994 A
5376329 Morgan et al. Dec 1994 A
5413438 Turchan May 1995 A
5423899 Krall et al. Jun 1995 A
5429459 Palm Jul 1995 A
5433280 Smith Jul 1995 A
5438108 Umemura et al. Aug 1995 A
5438858 Friedrichs Aug 1995 A
5443337 Katayama Aug 1995 A
5447549 Yoshimura Sep 1995 A
5452771 Blackman et al. Sep 1995 A
5467669 Stroud Nov 1995 A
5474407 Rodel et al. Dec 1995 A
5479997 Scott et al. Jan 1996 A
5480272 Jorgensen et al. Jan 1996 A
5482670 Hong Jan 1996 A
5484468 Östlund et al. Jan 1996 A
5487626 Von Holst et al. Jan 1996 A
5492186 Overstreet et al. Feb 1996 A
5496137 Ochayon et al. Mar 1996 A
5498142 Mills Mar 1996 A
5505748 Tank et al. Apr 1996 A
5506055 Dorfman et al. Apr 1996 A
5518077 Blackman et al. May 1996 A
5525134 Mehrotra et al. Jun 1996 A
5541006 Conley Jul 1996 A
5543235 Mirchandani et al. Aug 1996 A
5544550 Smith Aug 1996 A
5560238 Allebach et al. Oct 1996 A
5560440 Tibbitts Oct 1996 A
5570978 Rees et al. Nov 1996 A
5580666 Dubensky et al. Dec 1996 A
5586612 Isbell et al. Dec 1996 A
5590729 Cooley et al. Jan 1997 A
5593474 Keshavan et al. Jan 1997 A
5601857 Friedrichs Feb 1997 A
5603075 Stoll et al. Feb 1997 A
5609286 Anthon Mar 1997 A
5609447 Britzke et al. Mar 1997 A
5611251 Katayama Mar 1997 A
5612264 Nilsson et al. Mar 1997 A
5628837 Britzke et al. May 1997 A
RE35538 Akesson et al. Jun 1997 E
5641251 Leins et al. Jun 1997 A
5641921 Dennis et al. Jun 1997 A
5662183 Fang Sep 1997 A
5666864 Tibbitts Sep 1997 A
5672382 Lux Sep 1997 A
5677042 Massa et al. Oct 1997 A
5679445 Massa et al. Oct 1997 A
5686119 McNaughton, Jr. Nov 1997 A
5697042 Massa et al. Dec 1997 A
5697046 Conley Dec 1997 A
5697462 Grimes et al. Dec 1997 A
5704736 Giannetti Jan 1998 A
5712030 Goto et al. Jan 1998 A
5718948 Ederyd et al. Feb 1998 A
5732783 Truax et al. Mar 1998 A
5733078 Matsushita et al. Mar 1998 A
5733649 Kelley et al. Mar 1998 A
5733664 Kelley et al. Mar 1998 A
5750247 Bryant et al. May 1998 A
5753160 Takeuchi et al. May 1998 A
5755033 Gunter et al. May 1998 A
5755298 Langford, Jr. et al. May 1998 A
5762843 Massa et al. Jun 1998 A
5765095 Flak et al. Jun 1998 A
5776593 Massa et al. Jul 1998 A
5778301 Hong Jul 1998 A
5789686 Massa et al. Aug 1998 A
5791833 Niebauer Aug 1998 A
5792403 Massa et al. Aug 1998 A
5803152 Dolman et al. Sep 1998 A
5806934 Massa et al. Sep 1998 A
5830256 Northrop et al. Nov 1998 A
5851094 Strand et al. Dec 1998 A
5856626 Fischer et al. Jan 1999 A
5865571 Tankala et al. Feb 1999 A
5873684 Flolo Feb 1999 A
5880382 Fang et al. Mar 1999 A
5890852 Gress Apr 1999 A
5893204 Symonds Apr 1999 A
5897830 Abkowitz et al. Apr 1999 A
5899257 Alleweireldt et al. May 1999 A
5947660 Karlsson et al. Sep 1999 A
5957006 Smith Sep 1999 A
5963775 Fang Oct 1999 A
5964555 Strand Oct 1999 A
5967249 Butcher Oct 1999 A
5971670 Pantzar et al. Oct 1999 A
5976707 Grab et al. Nov 1999 A
5988953 Berglund et al. Nov 1999 A
6007909 Rolander et al. Dec 1999 A
6012882 Turchan Jan 2000 A
6022175 Heinrich et al. Feb 2000 A
6029544 Katayama Feb 2000 A
6051171 Takeuchi et al. Apr 2000 A
6063333 Dennis May 2000 A
6068070 Scott May 2000 A
6073518 Chow et al. Jun 2000 A
6076999 Hedberg et al. Jun 2000 A
6086003 Gunter et al. Jul 2000 A
6086980 Foster et al. Jul 2000 A
6089123 Chow et al. Jul 2000 A
6109377 Massa et al. Aug 2000 A
6109677 Anthony Aug 2000 A
6117493 North Sep 2000 A
6135218 Deane et al. Oct 2000 A
6148936 Evans et al. Nov 2000 A
6200514 Meister Mar 2001 B1
6209420 Butcher et al. Apr 2001 B1
6214134 Eylon et al. Apr 2001 B1
6214287 Waldenström Apr 2001 B1
6220117 Butcher Apr 2001 B1
6227188 Tankala et al. May 2001 B1
6228134 Erickson May 2001 B1
6228139 Oskarsson May 2001 B1
6234261 Evans et al. May 2001 B1
6241036 Lovato et al. Jun 2001 B1
6248277 Friedrichs Jun 2001 B1
6254658 Taniuchi et al. Jul 2001 B1
6287360 Kembaiyan et al. Sep 2001 B1
6290438 Papajewski Sep 2001 B1
6293986 Rodiger et al. Sep 2001 B1
6299658 Moriguchi et al. Oct 2001 B1
6302224 Sherwood, Jr. Oct 2001 B1
6326582 North Dec 2001 B1
6345941 Fang et al. Feb 2002 B1
6353771 Southland Mar 2002 B1
6372346 Toth Apr 2002 B1
6374932 Brady Apr 2002 B1
6375706 Kembaiyan et al. Apr 2002 B2
6386954 Sawabe et al. May 2002 B2
6394711 Brosius May 2002 B1
6395108 Eberle et al. May 2002 B2
6402439 Puide et al. Jun 2002 B1
6425716 Cook Jul 2002 B1
6450739 Puide et al. Sep 2002 B1
6453899 Tselesin Sep 2002 B1
6454025 Runquist et al. Sep 2002 B1
6454028 Evans Sep 2002 B1
6454030 Findley et al. Sep 2002 B1
6458471 Lovato et al. Oct 2002 B2
6461401 Kembaiyan et al. Oct 2002 B1
6474425 Truax et al. Nov 2002 B1
6475647 Mendez Acevedo et al. Nov 2002 B1
6499917 Parker et al. Dec 2002 B1
6499920 Sawabe Dec 2002 B2
6500226 Dennis Dec 2002 B1
6502623 Schmitt Jan 2003 B1
6511265 Keller et al. Jan 2003 B1
6541124 Suggs Apr 2003 B1
6544308 Griffin et al. Apr 2003 B2
6546991 Dworog et al. Apr 2003 B2
6551035 Bruhn et al. Apr 2003 B1
6562462 Griffin et al. May 2003 B2
6576182 Ravagni et al. Jun 2003 B1
6582126 North Jun 2003 B2
6585064 Griffin et al. Jul 2003 B2
6585864 Fisher et al. Jul 2003 B1
6589640 Griffin et al. Jul 2003 B2
6599467 Yamaguchi et al. Jul 2003 B1
6607693 Saito et al. Aug 2003 B1
6607835 Fang et al. Aug 2003 B2
6637528 Nishiyama et al. Oct 2003 B2
6648068 Dewey et al. Nov 2003 B2
6649682 Breton et al. Nov 2003 B1
6651757 Belnap et al. Nov 2003 B2
6655481 Findley et al. Dec 2003 B2
6655882 Heinrich et al. Dec 2003 B2
6676863 Christiaens et al. Jan 2004 B2
6682780 Tzatzov et al. Jan 2004 B2
6685880 Engström et al. Feb 2004 B2
6688988 McClure Feb 2004 B2
6695551 Silver Feb 2004 B2
6706327 Blomstedt et al. Mar 2004 B2
6716388 Bruhn et al. Apr 2004 B2
6719074 Tsuda et al. Apr 2004 B2
6725953 Truax et al. Apr 2004 B2
6737178 Ota et al. May 2004 B2
6742608 Murdoch Jun 2004 B2
6742611 Illerhaus et al. Jun 2004 B1
6756009 Sim et al. Jun 2004 B2
6764555 Hiramatsu et al. Jul 2004 B2
6766870 Overstreet Jul 2004 B2
6767505 Witherspoon et al. Jul 2004 B2
6772849 Oldham et al. Aug 2004 B2
6782958 Liang et al. Aug 2004 B2
6799648 Brandenberg et al. Oct 2004 B2
6808821 Fujita et al. Oct 2004 B2
6844085 Takayama et al. Jan 2005 B2
6848521 Lockstedt et al. Feb 2005 B2
6849231 Kojima et al. Feb 2005 B2
6892793 Liu et al. May 2005 B2
6899495 Hansson et al. May 2005 B2
6918942 Hatta et al. Jul 2005 B2
6932172 Dvorachek Aug 2005 B2
6933049 Wan et al. Aug 2005 B2
6948890 Svensson et al. Sep 2005 B2
6949148 Sugiyama et al. Sep 2005 B2
6955233 Crowe et al. Oct 2005 B2
6958099 Nakamura et al. Oct 2005 B2
7014719 Suzuki et al. Mar 2006 B2
7014720 Iseda Mar 2006 B2
7017677 Keshavan et al. Mar 2006 B2
7036611 Radford et al. May 2006 B2
7044243 Kembaiyan et al. May 2006 B2
7048081 Smith et al. May 2006 B2
7070666 Druschitz et al. Jul 2006 B2
7080998 Hall et al. Jul 2006 B2
7090731 Kashima et al. Aug 2006 B2
7101128 Hansson Sep 2006 B2
7101446 Takeda et al. Sep 2006 B2
7112143 Muller Sep 2006 B2
7125207 Craig et al. Oct 2006 B2
7128773 Liang et al. Oct 2006 B2
7147413 Henderer et al. Dec 2006 B2
7152701 Butland et al. Dec 2006 B2
7172142 Taylor et al. Feb 2007 B2
7175404 Kondo et al. Feb 2007 B2
7192660 Ruppi Mar 2007 B2
7207401 Dewey et al. Apr 2007 B2
7207750 Annanolli et al. Apr 2007 B2
7216727 Wardley May 2007 B2
7231984 Jaensch Jun 2007 B2
7234541 Scott et al. Jun 2007 B2
7234550 Azar et al. Jun 2007 B2
7235211 Griffo et al. Jun 2007 B2
7238414 Benitsch et al. Jul 2007 B2
7244519 Festeau et al. Jul 2007 B2
7250069 Kembaiyan et al. Jul 2007 B2
7261782 Hwang et al. Aug 2007 B2
7262240 Breton et al. Aug 2007 B1
7267187 Kembaiyan Sep 2007 B2
7267543 Freidhoff et al. Sep 2007 B2
7270679 Istephanous et al. Sep 2007 B2
7296497 Kugelberg et al. Nov 2007 B2
7350599 Lockwood et al. Apr 2008 B2
7381283 Lee et al. Jun 2008 B2
7384413 Gross et al. Jun 2008 B2
7384443 Mirchandani et al. Jun 2008 B2
7395882 Oldham et al. Jul 2008 B2
7410610 Woodfield et al. Aug 2008 B2
7487849 Radtke Feb 2009 B2
7494507 Dixon Feb 2009 B2
7497280 Brackin et al. Mar 2009 B2
7497396 Splinter et al. Mar 2009 B2
7513320 Mirchandani et al. Apr 2009 B2
7524351 Hua et al. Apr 2009 B2
7556668 Eason et al. Jul 2009 B2
7575620 Terry et al. Aug 2009 B2
7625157 Prichard et al. Dec 2009 B2
7632323 Ganguly et al. Dec 2009 B2
7661491 Kembaiyan et al. Feb 2010 B2
7687156 Fang Mar 2010 B2
7703555 Overstreet Apr 2010 B2
7810588 McClain et al. Oct 2010 B2
7832456 Calnan et al. Nov 2010 B2
7832457 Calnan et al. Nov 2010 B2
7846551 Fang et al. Dec 2010 B2
7887747 Iwasaki et al. Feb 2011 B2
7954569 Mirchandani et al. Jun 2011 B2
8007714 Mirchandani et al. Aug 2011 B2
8007922 Mirchandani et al. Aug 2011 B2
8025112 Mirchandani et al. Sep 2011 B2
8087324 Mirchandani et al. Jan 2012 B2
8109177 Kembaiyan et al. Feb 2012 B2
8137816 Fang et al. Mar 2012 B2
8141665 Ganz Mar 2012 B2
8221517 Mirchandani et al. Jul 2012 B2
8225886 Mirchandani et al. Jul 2012 B2
8272816 Mirchandani Sep 2012 B2
20020004105 Kunze et al. Jan 2002 A1
20030010409 Kunze et al. Jan 2003 A1
20030041922 Hirose et al. Mar 2003 A1
20030219605 Molian et al. Nov 2003 A1
20040013558 Kondoh et al. Jan 2004 A1
20040105730 Nakajima Jun 2004 A1
20040228695 Clauson Nov 2004 A1
20040234820 Majagi Nov 2004 A1
20040244540 Oldham et al. Dec 2004 A1
20040245022 Izaguirre et al. Dec 2004 A1
20040245024 Kembaiyan Dec 2004 A1
20050008524 Testani Jan 2005 A1
20050019114 Sung Jan 2005 A1
20050084407 Myrick Apr 2005 A1
20050103404 Hsieh et al. May 2005 A1
20050117984 Eason et al. Jun 2005 A1
20050194073 Hamano et al. Sep 2005 A1
20050211475 Mirchandani et al. Sep 2005 A1
20050268746 Abkowitz et al. Dec 2005 A1
20060016521 Hanusiak et al. Jan 2006 A1
20060024140 Wolff et al. Feb 2006 A1
20060032677 Azar et al. Feb 2006 A1
20060043648 Takeuchi et al. Mar 2006 A1
20060060392 Eyre Mar 2006 A1
20060162415 Friedrichs Jul 2006 A1
20060185773 Chiovelli Aug 2006 A1
20060286410 Ahlgren et al. Dec 2006 A1
20060288820 Mirchandani et al. Dec 2006 A1
20070082229 Mirchandani et al. Apr 2007 A1
20070102198 Oxford et al. May 2007 A1
20070102199 Smith et al. May 2007 A1
20070102200 Choe et al. May 2007 A1
20070102202 Choe et al. May 2007 A1
20070108650 Mirchandani et al. May 2007 A1
20070126334 Nakamura et al. Jun 2007 A1
20070163679 Fujisawa et al. Jul 2007 A1
20070193782 Fang et al. Aug 2007 A1
20070251732 Mirchandani et al. Nov 2007 A1
20080011519 Smith et al. Jan 2008 A1
20080101977 Eason et al. May 2008 A1
20080196318 Bost et al. Aug 2008 A1
20080302576 Michandani et al. Dec 2008 A1
20090032501 Swingley et al. Feb 2009 A1
20090041612 Fang et al. Feb 2009 A1
20090136308 Newitt May 2009 A1
20090180915 Mirchandani et al. Jul 2009 A1
20090301788 Stevens et al. Dec 2009 A1
20100044114 Mirchandani et al. Feb 2010 A1
20100044115 Mirchandani et al. Feb 2010 A1
20100278603 Fang et al. Nov 2010 A1
20100323213 Aitchison et al. Dec 2010 A1
20110011965 Mirchandani et al. Jan 2011 A1
20110107811 Mirchandani et al. May 2011 A1
20110265623 Mirchandani et al. Nov 2011 A1
20110284179 Stevens et al. Nov 2011 A1
20110287238 Stevens et al. Nov 2011 A1
20110287924 Stevens Nov 2011 A1
20120237386 Mirchandani et al. Sep 2012 A1
20120240476 Mirchandani et al. Sep 2012 A1
20120241222 Mirchandani et al. Sep 2012 A1
20120282051 Mirchandani Nov 2012 A1
20120285293 Mirchandani et al. Nov 2012 A1
20130048701 Mirchandani et al. Feb 2013 A1
20130075165 Coleman et al. Mar 2013 A1
Foreign Referenced Citations (154)
Number Date Country
695583 Feb 1998 AU
1018474 Oct 1977 CA
1158073 Dec 1983 CA
1250156 Feb 1989 CA
2022065 Feb 1991 CA
2120332 Jun 1993 CA
2107004 May 1996 CA
2228398 Feb 1997 CA
2198985 Sep 1998 CA
2108274 Jul 2000 CA
2212197 Oct 2000 CA
2201969 Feb 2003 CA
2213169 Mar 2005 CA
2498073 Aug 2006 CA
2556132 Feb 2007 CA
2570937 Jun 2007 CA
2357407 Jan 2008 CA
19634314 Jan 1998 DE
10300283 Jun 2004 DE
102006030661 Jan 2008 DE
102007006943 Aug 2008 DE
0157625 Oct 1985 EP
0264674 Apr 1988 EP
0453428 Oct 1991 EP
0605585 Aug 1995 EP
0641620 Feb 1998 EP
0995876 Apr 2000 EP
1065021 Jan 2001 EP
1066901 Jan 2001 EP
1106706 Jun 2001 EP
0759480 Jan 2002 EP
1077268 May 2003 EP
1244531 Oct 2004 EP
1686193 Aug 2006 EP
1788104 May 2007 EP
2627541 Aug 1989 FR
622041 Apr 1949 GB
945227 Dec 1963 GB
1082568 Sep 1967 GB
1309634 Mar 1973 GB
1420906 Jan 1976 GB
1491044 Nov 1977 GB
2064619 Jun 1981 GB
2158744 Nov 1985 GB
2218931 Nov 1989 GB
2315452 Feb 1998 GB
2324752 Nov 1998 GB
2352727 Feb 2001 GB
2384745 Aug 2003 GB
2385350 Aug 2003 GB
2393449 Mar 2004 GB
2397832 Aug 2004 GB
2409467 Jun 2005 GB
2435476 Aug 2007 GB
51-114307 Oct 1976 JP
51-124876 Oct 1976 JP
56-52604 May 1981 JP
59-54510 Mar 1984 JP
59-56501 Apr 1984 JP
59-67333 Apr 1984 JP
59-169707 Sep 1984 JP
59-175912 Oct 1984 JP
60-48207 Mar 1985 JP
60-172403 Sep 1985 JP
60-224790 Nov 1985 JP
61-226231 Oct 1986 JP
61-243103 Oct 1986 JP
61057123 Dec 1986 JP
62-34710 Feb 1987 JP
62-063005 Mar 1987 JP
62-218010 Sep 1987 JP
62-278250 Dec 1987 JP
1-171725 Jul 1989 JP
2-95506 Apr 1990 JP
2-269515 Nov 1990 JP
3-43112 Feb 1991 JP
3-73210 Mar 1991 JP
04-217414 Aug 1992 JP
5-50314 Mar 1993 JP
5-92329 Apr 1993 JP
H05-64288 Aug 1993 JP
H03-119090 Jun 1995 JP
7-276105 Oct 1995 JP
8-120308 May 1996 JP
H8-209284 Aug 1996 JP
8-294805 Nov 1996 JP
9-11005 Jan 1997 JP
9-192930 Jul 1997 JP
9-253779 Sep 1997 JP
10-138033 May 1998 JP
10-156607 Jun 1998 JP
10219385 Aug 1998 JP
H10-511740 Nov 1998 JP
11-10409 Jan 1999 JP
11-300516 Nov 1999 JP
2000-237910 Sep 2000 JP
2000-296403 Oct 2000 JP
2000-355725 Dec 2000 JP
2001-179517 Jul 2001 JP
2002-097885 Apr 2002 JP
2002-166326 Jun 2002 JP
2002-317596 Oct 2002 JP
2003-306739 Oct 2003 JP
2004-160591 Jun 2004 JP
2004-181604 Jul 2004 JP
2004-190034 Jul 2004 JP
2004-315904 Nov 2004 JP
2005-111581 Apr 2005 JP
2005-519448 Jun 2005 JP
2006-328477 Jun 2005 JP
2006-524173 Oct 2006 JP
20050055268 Jun 2005 KR
2135328 Aug 1999 RU
2173241 Feb 2000 RU
2167262 May 2001 RU
967786 Oct 1982 SU
975369 Nov 1982 SU
990423 Jan 1983 SU
1269922 Nov 1986 SU
1292917 Feb 1987 SU
1350322 Nov 1987 SU
6742 Dec 1994 UA
63469 Jan 2006 UA
23749 Jun 2007 UA
WO 9205009 Apr 1992 WO
WO 9222390 Dec 1992 WO
WO 9719201 May 1997 WO
WO 9734726 Sep 1997 WO
WO 9828455 Jul 1998 WO
WO 9913121 Mar 1999 WO
WO 9700734 Jul 1999 WO
WO 9936590 Jul 1999 WO
WO 0043628 Jul 2000 WO
WO 0052217 Sep 2000 WO
WO 0143899 Jun 2001 WO
WO 03010350 Feb 2003 WO
WO 03011508 Feb 2003 WO
WO 03049889 Jun 2003 WO
WO 2004053197 Jun 2004 WO
WO 2005045082 May 2005 WO
WO 2005054530 Jun 2005 WO
WO 2005061746 Jul 2005 WO
WO 2005106183 Nov 2005 WO
WO 2006071192 Jul 2006 WO
WO 2006104004 Oct 2006 WO
WO 2007001870 Jan 2007 WO
WO 2007022336 Feb 2007 WO
WO 2007030707 Mar 2007 WO
WO 2007044791 Apr 2007 WO
WO 2007127680 Nov 2007 WO
WO 2008098636 Aug 2008 WO
WO 2008115703 Sep 2008 WO
WO 2011000348 Jan 2011 WO
WO 2011008439 Jan 2011 WO
Non-Patent Literature Citations (198)
Entry
US 4,966,627, 10/1990, Keshavan et al. (withdrawn).
Coyle, T.W. and A. Bahrami, “Structure and Adhesion of Ni and Ni-WC Plasma Spray Coatings,” Thermal Spray, Surface Engineering via Applied Research, Proceedings of the 1st International Thermal Spray Conference, May 8-11, 2000, Montreal, Quebec, Canada, 2000, pp. 251-254.
Deng, X. et al., “Mechanical Properties of a Hybrid Cemented Carbide Composite,” International Journal of Refractory Metals and Hard Materials, Elsevier Science Ltd., vol. 19, 2001, pp. 547-552.
Gurland, Joseph, “Application of Quantitative Microscopy to Cemented Carbides,” Practical Applications of Quantitative Matellography, ASTM Special Technical Publication 839, ASTM 1984, pp. 65-84.
Hayden, Matthew and Lyndon Scott Stephens, “Experimental Results for a Heat-Sink Mechanical Seal,” Tribology Transactions, 48, 2005, pp. 352-361.
Metals Handbook, vol. 16 Machining, “Cemented Carbides” (ASM International 1989), pp. 71-89.
Metals Handbook, vol. 16 Machining, “Tapping” (ASM International 1989), pp. 255-267.
Peterman, Walter, “Heat-Sink Compound Protects the Unprotected,” Welding Design and Fabrication, Sep. 2003, pp. 20-22.
Shi et al., “Composite Ductility—The Role of Reinforcement and Matrix”, TMS Meeting, Las Vegas, NV, Feb. 12-16, 1995, 10 pages.
Sriram, et al., “Effect of Cerium Addition on Microstructures of Carbon-Alloyed Iron Aluminides,” Bull. Mater. Sci., vol. 28, No. 6, Oct. 2005, pp. 547-554.
Tracey et al., “Development of Tungsten Carbide-Cobalt-Ruthenium Cutting Tools for Machining Steels” Proceedings Annual Microprogramming Workshop, vol. 14, 1981, pp. 281-292.
Underwood, Quantitative Stereology, pp. 23-108 (1970).
Vander Vort, “Introduction to Quantitative Metallography”, Tech Notes, vol. 1, Issue 5, published by Buehler, Ltd. 1997, 6 pages.
J. Gurland, Quantitative Microscopy, R.T. DeHoff and F.N. Rhines, eds., McGraw-Hill Book Company, New York, 1968, pp. 279-290.
You Tube, “The Story Behind Kennametal's Beyond Blast”, dated Sep. 14, 2010, http://www.youtube.com/watch?v=8—A-bYVwmU8 (3 pages) accessed on Oct. 14, 2010.
Kennametal press release on Jun. 10, 2010, http://news.thomasnet.com/companystory/Kennametal-Launches-Beyond-BLAST-TM-at-IMTS-2010-Booth-W-1522-833445 (2 pages) accessed on Oct. 14, 2010.
Pages from Kennametal site, https://www.kennametal.com/en-US/promotions/Beyond—Blast.jhtml (7 pages) accessed on Oct. 14, 2010.
ASM Materials Engineering Dictionary, J.R. Davis, Ed., ASM International, Fifth printing, Jan. 2006, p. 98.
Childs et al., “Metal Machining”, 2000, Elsevier, p. 111.
Brookes, Kenneth J. A., “World Directory and Handbook of Hardmetals and Hard Materials”, International Carbide Data, U.K. 1996, Sixth Edition, p. 42.
Firth Sterling grade chart, Allegheny Technologies, attached to Declaration of Prakash Mirchandani, Ph.D. as filed in U.S. Appl. No. 11/737,993 on Sep. 9, 2009.
Metals Handbook Desk Edition, definition of ‘wear’, 2nd Ed., J.R. Davis, Editor, ASM International 1998, p. 62.
McGraw-Hill Dictionary of Scientific and Technical Terms, 5th Edition, Sybil P. Parker, Editor in Chief, 1994, pp. 799, 800, 1933, and 2047.
ProKon Version 8.6, The Calculation Companion, Properties for W, Ti, Mo, Co, Ni and FE, Copyright 1997-1998, 6 pages.
Tibtech Innovations, “Properties table of stainless steel, metals and other conductive materials”, printed from http://www.tibtech.com/conductivity.php on Aug. 19, 2011, 1 page.
“Material: Tungsten Carbide (WC), bulk”, MEMSnet, printed from http://www.memsnet.org/material/tungstencarbidewcbulk/ on Aug. 19, 2001, 1 page.
Williams, Wendell S., “The Thermal Conductivity of Metallic Ceramics”, JOM, Jun. 1998, pp. 62-66.
Brookes, Kenneth J. A., “World Directory and Handbook of Hardmetals and Hard Materials”, International Carbide Data, U.K. 1996, Sixth Edition, pp. D182-D184.
Thermal Conductivity of Metals, The Engineering ToolBox, printed from http://www.engineeringtoolbox.com/thermal-conductivity-metals-d—858.html on Oct. 27, 2011, 3 pages.
The Thermal Conductivity of Some Common Materials and Gases, The Engineering ToolBox, printed from http://www.engineeringtoolbox.com/thermal-conductivity-d—429.html on Dec. 15, 2011, 4 pages.
ASTM G65-04, Standard Test Method for Measuring Abrasion Using the Dry Sand, Nov. 1, 2004, printed from http://infostore.saiglobal.com.
Tool and Manufacturing Engineers Handbook, Fourth Edition, vol. 1, Machining, Society of Manufacturing Engineers, Chapter 12, vol. 1, 1983, pp. 12-110-12-114.
Beard, T. “The INS and OUTS of Thread Milling; Emphasis: Hole Making, Interview”, Modern Machine Shop, Gardner Publications, Inc. 1991, vol. 64, No. 1, 5 pages.
Koelsch, J., “Thread Milling Takes on Tapping”, Manufacturing Engineering, 1995, vol. 115, No. 4, 6 pages.
Johnson, M. “Tapping”, Traditional Machining Processes, 1997, pp. 255-265.
“Thread Milling”, Traditional Machining Processes, 1997, pp. 268-269.
Scientific Cutting Tools, “The Cutting Edge”, 1998, printed on Feb. 1, 2000, 15 pages.
Helical Carbide Thread Mills, Schmarje Tool Company, 1998, 2 pages.
Pyrotek, Zyp Zircwash, www.pyrotek.info, Feb. 2003, 1 page.
Sims et al., “Casting Engineering”, Superalloys II, Aug. 1987, pp. 420-426.
Sikkenga, “Cobalt and Cobalt Alloy Castings”, Casting, vol. 15, ASM Handbook, ASM International, 2008, pp. 1114-1118.
Starck, H.C., Surface Technology, Powders for PTA-Welding, Lasercladding and other Wear Protective Welding Applications, Jan. 2011, 4 pages.
Ancormet®, Data Sheet, 0001-AM101-D-1, Hoeganaes, www.hoeganaes.com, 7 pages. (date unavailable).
Office Action mailed Oct. 4, 2012 in U.S. Appl. No. 13/491,638.
U.S. Appl. No. 13/558,769, filed Jul. 26, 2012 (62 pages).
U.S. Appl. No. 13/591,282, filed Aug. 22, 2012 (54 pages).
Office Action mailed Mar. 12, 2009 in U.S. Appl. No. 11/585,408.
Office Action mailed Sep. 22, 2009 in U.S. Appl. No. 11/585,408.
Office Action mailed Sep. 7, 2010 in U.S. Appl. No. 11/585,408.
Office Action mailed Feb. 16, 2011 in U.S. Appl. No. 11/585,408.
Advisory Action mailed May 3, 2011 in U.S. Appl. No. 11/585,408.
Office Action mailed Aug. 17, 2011 in U.S. Appl. No. 11/585,408.
Notice of Allowance mailed May 9, 2012 in U.S. Appl. No. 11/585,408.
Notice of Allowance mailed Jul. 20, 2012 in U.S. Appl. No. 11/585,408.
Corrected Notice of Allowability mailed Oct. 18, 2012 in U.S. Appl. No. 11/585,408.
Restriction Requirement mailed Jul. 24, 2008 in U.S. Appl. No. 11/167,811.
Office Action mailed Oct. 21, 2008 in U.S. Appl. No. 11/167,811.
Final Office Action mailed Jun. 12, 2009 in U.S. Appl. No. 11/167,811.
Office Action mailed Aug. 28, 2009 in U.S. Appl. No. 11/167,811.
Office Action mailed Mar. 2, 2010 in U.S. Appl. No. 11/167,811.
Office Action mailed Aug. 19, 2010 in U.S. Appl. No. 11/167,811.
Advisory Action Before the Filing of an Appeal Brief mailed May 12, 2010 in U.S. Appl. No. 11/167,811.
Office Action mailed Feb. 3, 2011 in U.S. Appl. No. 11/167,811.
Advisory Action mailed May 11, 2011 in U.S. Appl. No. 11/167,811.
Office Action mailed Jul. 22, 2011 in U.S. Appl. No. 11/167,811.
Office Action mailed Mar. 28, 2012 in U.S. Appl. No. 11/167,811.
Office Action mailed Mar. 19, 2009 in U.S. Appl. No. 11/737,993.
Office Action mailed Jun. 3, 2009 in U.S. Appl. No. 11/737,993.
Office Action mailed Dec. 9, 2009 in U.S. Appl. No. 11/737,993.
Office Action mailed Feb. 24, 2010 in U.S. Appl. No. 11/737,993.
Office Action mailed Jun. 29, 2010 in U.S. Appl. No. 11/737,993.
Advisory Action Before the Filing of an Appeal Brief mailed Sep. 9, 2010 in U.S. Appl. No. 11/737,993.
Pre-Brief Appeal Conference Decision mailed Nov. 22, 2010 in U.S. Appl. No. 11/737,993.
Office Action mailed Apr. 20, 2011 in U.S. Appl. No. 11/737,993.
Office Action mailed Aug. 3, 2011 in U.S. Appl. No. 11/737,993.
Office Action mailed Oct. 11, 2011 in U.S. Appl. No. 11/737,993.
Office Action mailed Jan. 6, 2012 in U.S. Appl. No. 11/737,993.
Advisory Action Before the Filing of an Appeal Brief mailed Mar. 22, 2012 in U.S. Appl. No. 11/737,993.
Notice of Allowance mailed Jul. 25, 2012 in U.S. Appl. No. 11/737,993.
Restriction Requirement mailed Sep. 17, 2010 in U.S. Appl. No. 12/397,597.
Office Action mailed Nov. 15, 2010 in U.S. Appl. No. 12/397,597.
Office Action mailed Jun. 7, 2011 in U.S. Appl. No. 12/397,597.
Advisory Action Before the Filing of an Appeal Brief mailed Aug. 31, 2011 in U.S. Appl. No. 12/397,597.
Office Action mailed Nov. 17, 2011 in U.S. Appl. No. 12/397,597.
Advisory Action mailed Jan. 26, 2012 in U.S. Appl. No. 12/397,597.
Office Action mailed Apr. 13, 2012 in U.S. Appl. No. 12/397,597.
Office Action mailed Dec. 29, 2005 in U.S. Appl. No. 10/903,198.
Office Action mailed Sep. 29, 2006 in U.S. Appl. No. 10/903,198.
Office Action mailed Mar. 27, 2007 in U.S. Appl. No. 10/903,198.
Office Action mailed Sep. 26, 2007 in U.S. Appl. No. 10/903,198.
Office Action mailed Jan. 16, 2008 in U.S. Appl. No. 10/903,198.
Office Action mailed Oct. 31, 2008 in U.S. Appl. No. 10/903,198.
Office Action mailed Apr. 17, 2009 in U.S. Appl. No. 10/903,198.
Advisory Action before mailing of Appeal Brief mailed Jun. 29, 2009 in U.S. Appl. No. 10/903,198.
Examiner's Answer mailed Aug. 17, 2010 in U.S. Appl. No. 10/903,198.
Office Action mailed Apr. 22, 2010 in U.S. Appl. No. 12/196,951.
Office Action mailed Oct. 29, 2010 in U.S. Appl. No. 12/196,951.
Office Action mailed Apr. 12, 2011 in U.S. Appl. No. 12/196,951.
Office Action mailed Oct. 19, 2011 in U.S. Appl. No. 12/196,951.
Office Action mailed Mar. 19, 2012 in U.S. Appl. No. 12/196,951.
Notice of Allowance mailed Jul. 31, 2012 in U.S. Appl. No. 12/196,951.
Office Action mailed Oct. 13, 2011 in U.S. Appl. No. 12/179,999.
Notice of Allowance mailed Apr. 30, 2012 in U.S. Appl. No. 12/179,999.
Office Action mailed Aug. 29, 2011 in U.S. Appl. No. 12/476,738.
Office Action mailed Dec. 21, 2011 in U.S. Appl. No. 12/476,738.
Notice of Allowance mailed Apr. 17, 2012 in U.S. Appl. No. 12/476,738.
Corrected Notice of Allowability mailed Jun. 21, 2012 in U.S. Appl. No. 12/476,738.
Office Action mailed Nov. 14, 2011 in U.S. Appl. No. 12/502,277.
Office Action mailed Jan. 20, 2012 in U.S. Appl. No. 12/502,277.
Notice of Allowance mailed Jul. 10, 2012 in U.S. Appl. No. 12/502,277.
Supplemental Notice of Allowability mailed Jul. 20, 2012 in U.S. Appl. No. 12/502,277.
Office Action mailed Mar. 15, 2012 in U.S. Appl. No. 12/464,607.
Notice of Allowance mailed Apr. 9, 2012 in U.S. Appl. No. 12/464,607.
Notice of Allowance mailed Jul. 16, 2012 in U.S. Appl. No. 12/464,607.
Office Action mailed Oct. 31, 2011 in U.S. Appl. No. 13/207,478.
Office Action mailed Mar. 2, 2012 in U.S. Appl. No. 13/207,478.
Notice of Allowance mailed Apr. 13, 2012 in U.S. Appl. No. 13/207,478.
Supplemental Notice of Allowability mailed Jun. 29, 2012 in U.S. Appl. No. 13/207,478.
Office Action mailed Dec. 5, 2011 in U.S. Appl. No. 13/182,474.
Office Action mailed Apr. 27, 2012 in U.S. Appl. No. 13/182,474.
Notice of Allowance mailed Jul. 18, 2012 in U.S. Appl. No. 13/182,474.
NOtice of Reopening of Prosecution Due to Consideration of an Information Disclosure Statement Filed After Mailing of a Notice of Allowance mailed Oct. 10, 2012 in U.S. Appl. No. 13/182,474.
Office Action mailed Jun. 1, 2001 in U.S. Appl. No. 09/460,540.
Office Action mailed Dec. 1, 2001 in U.S. Appl. No. 09/460,540.
Office Action mailed Mar. 15, 2002 in U.S. Appl. No. 09/460,540.
Office Action mailed Jun. 18, 2002 in U.S. Appl. No. 09/460,540.
Notice of Allowance mailed Oct. 21, 2002 in U.S. Appl. No. 09/460,540.
Office Action mailed Jan. 16, 2007 in U.S. Appl. No. 11/013,842.
Office Action mailed Jul. 16, 2008 in U.S. Appl. No. 11/013,842.
Office Action mailed Jul. 30, 2007 in U.S. Appl. No. 11/013,842.
Notice of Allowance mailed Nov. 26, 2008 in U.S. Appl. No. 11/013,842.
Office Action mailed Oct. 13, 2006 in U.S. Appl. No. 10/922,750.
Notice of Allowance mailed May 21, 2007 for U.S. Appl. No. 10/922,750.
Supplemental Notice of Allowability mailed Jul. 3, 2007 for U.S. Appl. No. 10/922,750.
Office Action mailed May 14, 2009 in U.S. Appl. No. 11/687,343.
Office Action mailed Jan. 21, 2010 in U.S. Appl. No. 11/687,343.
Notice of Allowance mailed May 18, 2010 in U.S. Appl. No. 11/687,343.
Restriction Requirement mailed Aug. 4, 2010 in U.S. Appl. No. 12/196,815.
Office Action mailed Oct. 27, 2010 in U.S. Appl. No. 12/196,815.
Office Action mailed Nov. 17, 2010 in U.S. Appl. No. 12/196,815.
Notice of Allowance mailed Jan. 27, 2011 in U.S. Appl. No. 12/196,815.
Notice of Allowance mailed May 16, 2011 in U.S. Appl. No. 12/196,815.
Office Action mailed Aug. 31, 2007 in U.S. Appl. No. 11/206,368.
Office Action mailed Feb. 28, 2008 in U.S. Appl. No. 11/206,368.
Pre-Appeal Conference Decision mailed Jun. 19, 2008 in U.S. Appl. No. 11/206,368.
Notice of Allowance mailed Nov. 13, 2008 in U.S. Appl. No. 11/206,368.
Office Action mailed Apr. 30, 2009 in U.S. Appl. No. 11/206,368.
Notice of Allowance mailed Nov. 30, 2009 in U.S. Appl. No. 11/206,368.
Office Action mailed Sep. 2, 2011 in U.S. Appl. No. 12/850,003.
Notice of Allowance mailed Nov. 15, 2011 in U.S. Appl. No. 12/850,003.
Office Action mailed May 3, 2010 in U.S. Appl. No. 11/924,273.
Office Action mailed Oct. 14, 2010 in U.S. Appl. No. 11/924,273.
Office Action mailed Feb. 2, 2011 in U.S. Appl. No. 11/924,273.
Interview Summary mailed Feb. 16, 2011 in U.S. Appl. No. 11/924,273.
Interview Summary mailed May 9, 2011 in U.S. Appl. No. 11/924,273.
Notice of Allowance mailed Jun. 24, 2011 in U.S. Appl. No. 11/924,273.
U.S. Appl. No. 13/652,508, filed Oct. 16, 2012 (46 pages).
U.S. Appl. No. 13/652,503, filed Oct. 16, 2012 (26 pages).
U.S. Appl. No. 13/632,178, filed Oct. 1, 2012 (51 pages).
U.S. Appl. No. 13/646,857, filed Oct. 8, 2012 (36 pages).
U.S. Appl. No. 13/646,854, filed Oct. 8, 2012 (38 pages).
U.S. Appl. No. 13/647,419, filed Oct. 9, 2012 (35 pages).
Nassau, K. Ph.D. and Julia Nassau, “The History and Present Status of Synthetic Diamond, Part I and II”, reprinted from The Lapidary Journal, Inc., vol. 32, No. 1, Apr. 1978; vol. 32, No. 2, May 1978, 15 pages.
Specialty Metals, “Tungchip Dispenser, An improved feeder design, to allow for accurate delivery of Tungsten Carbide granules into the molten weld pool, generated by a MIG (GMAW) welding system”, (undated) 2 pages.
Dynalloy Industries, G.M.A.C.E, 2003, printed Jul. 8, 2009, 1 page.
Alloys International (Australasia) Pty. Ltd., “The Tungsten Carbide Vibratory Feeder System”, (undated) 6 pages.
Dynalloy Industries, Hardhead Technology, Tungsten Carbide Pellets, 2003, printed Jul. 8, 2009, 1 page.
Lincoln Electric, MIG Carbide Vibratory Feeder Assembly, (undated) 1 page.
Wearshield Hardfacing Electrodes, Tungsten Carbide Products, (undated) 1 page.
Postalloy, The best in hardfacing, Postle Industries, Inc., (undated) 13 pages.
Postalloy, Postle Industries, Inc., Postalloy PS-98, Tungsten Matrix Alloy, (undated) 1 page.
Postalloy, Data Sheet, Postle Industries, Inc., Postalloy 299-SPL, (undated) 1 page.
Postalloy, Data Sheet, Postle Industries, Inc., Postalloy CP 63070, (undated) 1 page.
Postalloy, Data Sheet, Postle Industries, Inc., Postalloy 14 TC, (undated) 1 page.
Postalloy, Data Sheet, Postle Industries, Inc., Postalloy PS-98, A Tungsten Carbide Matrix Wire for Carbide Embedding, (undated) 1 page.
Industrial Renewal Services, Steel BOC (Basic Oxygen Furnace) & BOP (Basic Oxygen Process) Hoods, printed Nov. 8, 2007, 2 pages.
UWO Products, printed Nov. 8, 2007 from http://www.universalweld.com/products.htm, 2 pages.
Shi et al., “Study on shaping technology of nanocrystalline WC-Co composite powder”, Rare Metal and Materials and Engineering, vol. 33, Suppl. 1, Jun. 2004, pp. 93-96. (English abstract).
Haynes et al., “Physical Constants of Inorganic Compounds”, CRC Handbook of Chemistry and Physics, 93rd Edition, Internet Version 2013, downloaded May 15, 2013, 2 pages.
“Percentage by Weight to Percentage by Volume Conversion Calculator”, Roseller Sunga, n.d., May 15, 2013, http://www.handymath.com/cgi-bin/dnstywtvol.cgi?sumit=Entry, 1 page.
Office Action mailed Feb. 27, 2013 in U.S. Appl. No. 13/550,690.
Office Action mailed Jan. 23, 2013 in U.S. Appl. No. 13/652,508.
Office Action mailed Jul. 25, 2013 in U.S. Appl. No. 13/652,508.
Office Action mailed Feb. 5, 2013 in U.S. Appl. No. 13/652,503.
Office Action mailed Jul. 5, 2013 in U.S. Appl. No. 13/652,503.
Restriction Requirement mailed Jan. 3, 2013 in U.S. Appl. No. 13/632,178.
Office Action mailed Mar. 6, 2013 in U.S. Appl. No. 13/632,178.
Office Action mailed May 22, 2013 in U.S. Appl. No. 13/487,323.
Office Action mailed Jun. 28, 2012 in U.S. Appl. No. 13/222,324.
Office Action mailed Jul. 11, 2012 in U.S. Appl. No. 13/222,324.
Office Action mailed Nov. 6, 2012 in U.S. Appl. No. 13/222,324.
Notice of Allowance mailed Jul. 1, 2013 in U.S. Appl. No. 11/167,811.
Office Action mailed Nov. 16, 2012 in U.S. Appl. No. 12/397,597.
Office Action mailed Jun. 20, 2013 in U.S. Appl. No. 12/397,597.
Decision on Appeal mailed Jun. 3, 2013 in U.S. Appl. No. 10/903,198.
Office Action mailed May 16, 2013 in U.S. Appl. No. 13/182,474.
Notice of Allowance mailed Feb. 4, 2008 in U.S. Appl. No. 11/013,842.
Notice of Allowance mailed Mar. 6, 2013 in U.S. Appl. No. 13/491,638.
Related Publications (1)
Number Date Country
20130043615 A1 Feb 2013 US
Continuations (1)
Number Date Country
Parent 11585408 Oct 2006 US
Child 13632177 US
Continuation in Parts (1)
Number Date Country
Parent 11167811 Jun 2005 US
Child 11585408 US