The present invention is generally directed to methods of forming articles, such as tool blanks and other injection molded articles, having a composite construction including regions of differing composition and/or microstucture. The present invention is additionally directed to rotary tools and tool blanks for rotary tools having a composite construction and at least one coolant channel. The method of the present invention finds general application in the production of articles and may be applied in, for example, the production of cemented carbide rotary tools used in material removal operations such as drilling, reaming, countersinking, counterboring, and end milling.
Cemented carbide rotary tools (i.e., tools driven to rotate) are commonly employed in machining operations such as, for example, drilling, reaming, countersinking, counterboring, end milling, and tapping. Such tools are typically of a solid monolithic construction. The manufacturing process for such tools may involve consolidating metallurgical powder (comprised of particulate ceramic and binder metal) to form a compact. The compact is then sintered to form a cylindrical tool blank having a solid monolithic construction. As used herein, monolithic construction means that the tools are composed of a material, such as, for example, a cemented carbide material, having substantially the same characteristics at any working volume within the tool. Subsequent to sintering, the tool blank is appropriately machined to form the cutting edge and other features of the particular geometry of the rotary tool. Rotary tools include, for example, drills, end mills, reamers, and taps.
Rotary tools composed of cemented carbides are adapted to many industrial applications, including the cutting and shaping of materials of construction such as metals, wood, and plastics. Cemented carbide tools are industrially important because of the combination of tensile strength, wear resistance, and toughness that is characteristic of these materials. Cemented carbides materials comprise at least two phases: at least one hard ceramic component and a softer matrix of metallic binder. The hard ceramic component may be, for example, carbides of elements within groups IVB through VIB of the periodic table. A common example is tungsten carbide. The binder may be a metal or metal alloy, typically cobalt, nickel, iron or alloys of these metals. The binder “cements” the ceramic component within a matrix interconnected in three dimensions. Cemented carbides may be fabricated by consolidating a metallurgical powder blend of at least one powdered ceramic component and at least one powdered binder.
The physical and chemical properties of cemented carbide materials depend in part on the individual components of the metallurgical powders used to produce the material. The properties of the cemented carbide materials are determined by, for example, the chemical composition of the ceramic component, the particle size of the ceramic component, the chemical composition of the binder, and the ratio of binder to ceramic component. By varying the components of the metallurgical powder, rotary tools such as drills and end mills can be produced with unique properties matched to specific applications.
Monolithic rotary tools may additionally comprise coolant channels extending through its body and shank to permit the flow of a coolant, such as oil or water, to the cutting surfaces of the rotary tool. The coolant may enter the channel at the shank end and exit at the drill point. The coolant cools the rotary tool and work piece and assists in ejecting chips and dirt from the hole. The use of coolant during machining operations allows for the use of higher cutting speeds of the rotary tool and faster feed rates, in addition to extending tool life. Rotary tools with coolant channels are especially suited for drilling deep holes in hard materials.
However, the monolithic construction of rotary tools inherently limits their performance and range of applications. As an example,
Because of these variations in cutting speed, drills and other rotary tools having a monolithic construction will not experience uniform wear and/or chipping and cracking of the tool's cutting edges at different points ranging from the center to the outside edge of the tool's cutting surface. Also, in drilling casehardened materials, the chisel edge is typically used to penetrate the case, while the remainder of the drill body removes material from the casehardened material's softer core, Therefore, the chisel edge of conventional drills of monolithic construction used in that application will wear at a much faster rate than the remainder of the cutting edge, resulting in a relatively short service life for such drills. In both instances, because of the monolithic construction of conventional cemented carbide drills, frequent regrinding of the cutting edge is necessary, thus placing a significant limitation on the service life of the bit. Frequent regrinding and tool changes also result in excessive downtime for the machine tool that is being used.
Therefore, composite articles, such as composite rotary tools have been used, such as those tools described in described in U.S. Pat. No. 6,511,265 which is hereby incorporated by reference in its entirety. If designed properly, composite rotary tools may have increased tool service life as compared to rotary tools having a more monolithic construction. However, there exists a need for drills and other rotary tools that have different characteristics at different regions of the tool and comprise coolant channels. As an example, a need exists for cemented carbide drills and other rotary tools that will experience substantially even wear regardless of the position on the tool face relative to the axis of rotation of the tool and allow cooling at the cutting surfaces. There is a need for a composite rotary tool having coolant channels so composite rotary tools may have the same benefits as monolithic rotary tools. There is also a need for a versatile method of producing composite rotary tools and composite rotary tools comprising coolant channels.
The invention is directed to a method of forming an article, wherein the method comprises coextruding at least two composite materials comprising metal carbides to form a green compact. In an embodiment, at least one of the composite materials includes greater than zero to less than 5 weight percent cubic carbides. Embodiments of the method include a coextrusion process for forming cemented carbide articles. The two composite materials may be metal powders comprising a binder metal and hard particles. The composite material may further comprise a plastic binder. The two different composite materials may be coextruded to form the green compact. In a specific embodiment, the coextrusion process forms at least one internal channel within the green compact. The green compact formed in embodiments of the method comprises at least two cemented carbide grades. In certain embodiments, the cemented carbide grades are coaxially disposed and comprise two helical channels.
The reader will appreciate the foregoing details and advantages of the present invention, as well as others, upon consideration of the following detailed description of embodiments of the invention. The reader also may comprehend such additional details and advantages of the present invention upon using the invention.
The features and advantages of the present invention may be better understood by reference to the accompanying drawings in which:
a) and 1(b) are plan and on-end views, respectively, of a conventional twist drill with coolant channels;
a) is a graph indicating cutting speeds at the three diameters D1, D2, and D3 of a conventional twist drill indicated in
a) and (b) include a transverse section (
a)-(d) are representations of a cross-sectional views of an embodiments of a composite cemented carbide;
a) is a representation of the coextrusion pressing apparatus used in coextrusion of a tube of grade A and a rod of grade B through a die with internal spiral serrations to produce a blank with helical or spiral channels.
b) is a representation of a channel die;
c) is a photograph of a coextruded composite cemented carbide rod with internal channels exiting from a die with spiral serrations;
a) is a photograph of a longitudinal cross-section of a composite rod with internal coolant channels of the present invention, the nylon wires in the photograph have been inserted in the channels to more clearly show their location and the path of the coolant channels;
b) is a photograph of a longitudinal cross-section of a drill made from a composite cemented carbide having internal coolant channels;
The present invention provides rotary cutting tools, cutting tool blanks, rods, and other articles having a composite construction and a method of making such articles. The articles may further comprise internal channels, such as coolant channels, if desired. As used herein, a rotary tool is a tool having at least one cutting edge that is driven to rotate. As used herein, “composite” construction refers to an article having regions differing in chemical composition and/or microstructure. These differences result in the regions having properties differing with respect to at least one characteristic. The characteristic may be at least one of, for example, hardness, tensile strength, wear resistance, fracture toughness, modulus of elasticity, corrosion resistance, coefficient of thermal expansion, and coefficient of thermal conductivity. Composite rotary tools that may be constructed as provided in the present invention include drills and end mills, as well as other tools that may be used in, for example, drilling, reaming, countersinking, counterboring, end milling, and tapping of materials.
The present invention more specifically provides a composite rotary tool having at least one cutting edge, at least two regions of cemented carbide material that differ with respect to at least one characteristic, and at least one coolant channel. The differing characteristics may be provided by variation of at least one of the chemical composition and the microstructure among the two regions of cemented carbide material. The chemical composition of a region is a function of, for example, the chemical composition of the ceramic component and/or binder of the region and the carbide-to-binder ratio of the region. For example, one of the two cemented carbide material regions of the rotary tool may exhibit greater wear resistance, enhanced hardness, and/or a greater modulus of elasticity than the other of the two regions.
Aspects of present invention may be described in relation to the tool blank 400, shown in
In the embodiment of
The ceramic component preferably comprises about 60 to about 98 weight percent of the total weight of the cemented carbide material in each region. The carbide particles are embedded within a matrix of binder material that preferably constitutes about 2 to about 40 weight percent of the total material in each region. The binder preferably is one or more of Co, Ni, Fe, and alloys of these elements. The binder also may contain, for example, elements such as W, Cr, Ti, Ta, V, Mo, Nb, Zr, Hf, and C up to the solubility limits of these elements in the binder. Additionally, the binder may contain up to 5 weight percent of elements such as Cu, Mn, Ag, Al, and Ru One skilled in the art will recognize that any or all of the constituents of the cemented carbide material may be introduced in elemental form, as compounds, and/or as master alloys.
The core region 420 of the tool blank 400 is autogenously bonded to the outer region 410 at an interface 415. The interface 415 is shown in
One skilled in the art, after having considered the description of present invention, will understand that the improved rotary tool of this invention could be constructed with several layers of different cemented carbide materials to produce a progression of the magnitude of one or more characteristics from a central region of the tool to its periphery. Thus, for example, a twist drill may be provided with multiple, coaxially disposed regions of cemented carbide material and wherein each such region has successively greater hardness and/or wear resistance than the adjacent, more centrally disposed region. Coolant channels may be provided in any of the regions or intersecting two or more regions. The method of the present invention provides great design flexibility in the design of extruded articles. Alternately, rotary tools of the present invention could be made with other composite configurations wherein differences in a particular characteristic occur at different regions of the tool.
A major advantage of the composite cemented carbide rotary tools of the present invention is the flexibility available to the tool designer to tailor properties of regions of the tools to suit different applications. For example, the size, location, thickness, geometry, and/or physical properties of the individual cemented carbide material regions of a particular composite blank of the present invention may be selected to suit the specific application of the rotary tool fabricated from the blank. In addition, the coolant channels may be located in the desired locations and be helical, spiral, linear, or a combination of such shapes. Thus, for example, the stiffness of one or more cemented carbide regions of the rotary tool experiencing significant bending during use may be of a cemented carbide material having an enhanced modulus of elasticity; the hardness and/or wear resistance of one or more cemented carbide regions having cutting surfaces and that experience cutting speeds greater than other regions may be increased; and/or the corrosion resistance of regions of cemented carbide material subject to chemical contact during use may be enhanced.
b) and 4(c) show additional embodiments of the present invention. These embodiments may additionally comprise channels, such as coolant channels. The embodiment of
By way of example only, an additional embodiment of a rotary tool of the present invention is shown in
Embodiments of the present invention also include additional methods of making composite cemented carbide articles. Embodiments include a method of forming a composite article by coextruding at least two composite materials comprising cemented carbides to form a green compact. The coextruding may be performed by direct or indirect extrusion process. The feed chamber of the extruder is filled with two grades of materials, such as two grades of carbide powder and binder powder mixed with a plastic binder. The plastic binder material may be present in concentrations from about 33 wt. % to 67 wt. % and decreases the viscosity of the powder metal mixture to allow extrusion.
The extrusion process for cemented carbides is well known in the art. In a typical extrusion process, metal powders are mixed with a plastic binder. Any typical plastic binder may be used such as plastic binders based upon benzyl alcohol, cellulose, polymers, or petroleum products. Typically, a high sheen mixing process is used to ensure intimate contact between the metal powders and the plastic binder.
The metal/binder mixer may then be pumped by screw feeder through the extruder to produce an extruded product. Embodiments of the method of the present invention include coextrusion of at least two cemented carbide grades. The term coextrusion, as used herein, means that two materials are extruded simultaneously to form a single article incorporating both materials. Any coextrusion process may be used in the method of the present invention such as, pumping two grades of cemented carbide to separate sections of funnel or die wherein the two grades exit the die in intimate contact with each other.
An embodiment of the coextrusion process is shown in
In this embodiment of the extrusion process, a plunger (not shown) pushes the rod 610 and the tube 620 through the feed chamber and into the funnel 630. The funnel 630 reduces in cross-sectional area from the feed chamber to the die 640. The funnel 630 causes compaction and consolidation of the cemented carbide powders resulting in intimate contact between the rod 610 and tube 620 and formation of a green compact (“extruded material”).
In certain embodiments, the extrusion process may also include a channel die 650 (see
Helically oriented channels may be formed in the extruded material in embodiments where the extruded material rotates relative to the channel die 650. The extruded material may be rotated by incorporating spiral serrations in the die 640 (see
The channel die may be a separate component or may be integral to the funnel, die, or other component in the extrusion system. The channel die may be capable of making at least one channel in the extruded material. The number and size of the channels may be limited by the size of the extruded material, the size of the channels, and the application for the ultimate use of the extruded material. In embodiments comprising a channel die comprising wires, the number of wires will correspond to the number of channels formed in the extruded material. For a rotary tool application, it may be preferable to have an equal number of channels as there will be flutes for example.
Embodiments of the present invention may further include loading the feed chamber with at least two cemented carbide grades. At least one cemented carbide grade loaded in the feed chamber may be an extruded form of either a rod, tube, bar, strips, rectangles, gear profiles, star shapes, or any other shape that may be formed in an extrusion process. In rotary tool or roller applications, it may be preferable that at least one of the two cemented carbide grades be in the form of a rod shape and at least one cemented carbide in a shape of a tube. In other applications, the feed chamber may be filled with multiple tubes and/or multiple rods of different cemented carbide grades. If multiple rods are used, the extruded material may be formed with specific grades of cemented carbides in specific regions or randomly distributed throughout the cross-section of the extruded material.
a) is a photograph of a longitudinal cross-section of a composite rod with internal coolant channels of the present invention, wherein the nylon wires in the photograph have been inserted in the channels to more clearly show their location and the path of the coolant channels.
A further embodiment of the present invention may comprise extruding a cemented carbide grade to form an extruded green compact and pressing the extruded green compact with a second cemented carbide grade to form a pressed green compact. The extruded green compact may optionally comprise internal channels formed as described above, for example.
The present invention is generally directed to methods of forming articles, such as tool blanks, having a composite construction including regions of differing composition and/or microstructure. An embodiment of the method includes injection molding of articles having a composite construction including regions of differing composition and/or microstructure. The method of the present invention finds general application in the production of rotary tools and may be applied in, for example, the production of cemented carbide rotary tools used in material removal operations such as drilling, reaming, countersinking, counter boring, and end milling.
Referring to
In one embodiment, the method comprises mixing powdered metals with a plastic binder to form the composite material prior to injecting the composite material into the mold. The plastic binder material may be present in concentrations from about 25 vol. % to 75 vol. % and decreases the viscosity of the powder metal mixture to facilitate injection.
The primary difference between extrusion and injection molding is that while extrusion may be considered a continuous process for one batch (with material continuously entering at one end of the die and leaving the other end), injection molding comprises stopping the process when the mold is filled. Generally, an injection molding method is a technique for making more complex articles. Cemented carbides mixed with a plastic binder are injected at high pressure into a mold. The mold is the inverse of the desired shape. Molds are typically made from metal, usually either steel or aluminum, but may be carbon, or other heat resistant material, if the green compact is to be heat treated, for example by sintering or presintering, in the mold and optionally may be further machined to form or refine the features of the desired part.
The design of molded parts and their molds is carefully considered to ensure that the injection molded part may be released from the mold, that the molds can be completely filled and the composite material densified, and to compensate for material shrinkage due to plastic binder removal and normal sintering shrinkage.
Molds typically comprise at least two parts to permit the part to be extracted. Complex parts are formed using more complex molds, which may require moveable sections, called slides, which are inserted into the mold to form particular features that cannot be formed using only two parts, but are then withdrawn to allow the part to be released. Some molds allow previously molded parts to be re-inserted to allow a new plastic layer to form around the first part. The molds of the present invention may be simple or complex and may incorporate many features, such as steps such as rods having sections of different radii, flutes, shanks, keys, holes, edges, etc.
In embodiments of the method, the blended metal powders are intimately mixed with a plastic binder and forced under pressure into a mold cavity. The powdered metal may be placed into a feed hopper, a large open bottomed container, which feeds the metal into a screw. A hydraulic or electric motor rotates the screw feeding the pellets through the screw. As the screw rotates, the pellets are moved forward in the screw undergoing increasing pressure and friction which causes heating and compaction of the powdered metal.
Although the present invention has been described in connection with certain embodiments, those of ordinary skill in the art will, upon considering the foregoing description, recognize that many modifications and variations of the invention may be employed. All such variations and modifications of the present invention are intended to be covered by the foregoing description and the following claims.
This application is a continuation application claiming priority under 35 U.S.C. §120 to U.S. application Ser. No. 11/585,408, filed on Oct. 24, 2006, now U.S. Pat. No. 8,318,063, which in turn claims priority under 35 U.S.C. §120 as a continuation-in-part of co-pending U.S. application Ser. No. 11/167,811, filed on Jun. 27, 2005.
Number | Name | Date | Kind |
---|---|---|---|
1509438 | Miller | Sep 1924 | A |
1530293 | Breitenstein | Mar 1925 | A |
1808138 | Hogg et al. | Jun 1931 | A |
1811802 | Newman | Jun 1931 | A |
1912298 | Newman | May 1933 | A |
2054028 | Benninghoff | Sep 1936 | A |
2093507 | Bartek | Sep 1937 | A |
2093742 | Staples | Sep 1937 | A |
2093986 | Staples | Sep 1937 | A |
2240840 | Fischer | May 1941 | A |
2246237 | Benninghoff | Jun 1941 | A |
2283280 | Nell | May 1942 | A |
2299207 | Bevillard | Oct 1942 | A |
2351827 | McAllister | Jun 1944 | A |
2422994 | Taylor | Jun 1947 | A |
2819958 | Abkowitz et al. | Jan 1958 | A |
2819959 | Abkowitz et al. | Jan 1958 | A |
2906654 | Abkowitz | Sep 1959 | A |
2954570 | Couch | Oct 1960 | A |
3041641 | Hradek et al. | Jul 1962 | A |
3093850 | Kelso | Jun 1963 | A |
3368881 | Abkowitz et al. | Feb 1968 | A |
3471921 | Feenstra | Oct 1969 | A |
3482295 | Trent | Dec 1969 | A |
3490901 | Hachisuka et al. | Jan 1970 | A |
3581835 | Stebley | Jun 1971 | A |
3629887 | Urbanic | Dec 1971 | A |
3660050 | Iler et al. | May 1972 | A |
3757879 | Wilder et al. | Sep 1973 | A |
3762882 | Grutza | Oct 1973 | A |
3776655 | Urbanic | Dec 1973 | A |
3782848 | Pfeifer | Jan 1974 | A |
3806270 | Tanner et al. | Apr 1974 | A |
3812548 | Theuerkaue | May 1974 | A |
3855444 | Palena | Dec 1974 | A |
3889516 | Yankee et al. | Jun 1975 | A |
RE28645 | Aoki et al. | Dec 1975 | E |
3936295 | Cromwell et al. | Feb 1976 | A |
3942954 | Frehn | Mar 1976 | A |
3980549 | Grutza | Sep 1976 | A |
3987859 | Lichte | Oct 1976 | A |
4009027 | Naidich et al. | Feb 1977 | A |
4017480 | Baum | Apr 1977 | A |
4047828 | Makely | Sep 1977 | A |
4094709 | Rozmus | Jun 1978 | A |
4097180 | Kwieraga | Jun 1978 | A |
4097275 | Horvath | Jun 1978 | A |
4105049 | Anderson | Aug 1978 | A |
4106382 | Salje et al. | Aug 1978 | A |
4126652 | Oohara et al. | Nov 1978 | A |
4128136 | Generoux | Dec 1978 | A |
4170499 | Thomas et al. | Oct 1979 | A |
4181505 | De Vries et al. | Jan 1980 | A |
4198233 | Frehn | Apr 1980 | A |
4221270 | Vezirian | Sep 1980 | A |
4229638 | Lichte | Oct 1980 | A |
4233720 | Rozmus | Nov 1980 | A |
4255165 | Dennis et al. | Mar 1981 | A |
4270952 | Kobayashi | Jun 1981 | A |
4276788 | van Nederveen | Jul 1981 | A |
4277106 | Sahley | Jul 1981 | A |
4277108 | Wallace | Jul 1981 | A |
4306139 | Shinozaki et al. | Dec 1981 | A |
4311490 | Bovenkerk et al. | Jan 1982 | A |
4325994 | Kitashima et al. | Apr 1982 | A |
4327156 | Dillon et al. | Apr 1982 | A |
4331741 | Wilson | May 1982 | A |
4340327 | Martins | Jul 1982 | A |
4341557 | Lizenby | Jul 1982 | A |
4351401 | Fielder | Sep 1982 | A |
4376793 | Jackson | Mar 1983 | A |
4389952 | Dreier et al. | Jun 1983 | A |
4396321 | Holmes | Aug 1983 | A |
4398952 | Drake | Aug 1983 | A |
4423646 | Bernhardt | Jan 1984 | A |
4478297 | Radtke | Oct 1984 | A |
4497358 | Gnadig et al. | Feb 1985 | A |
4499048 | Hanejko | Feb 1985 | A |
4499795 | Radtke | Feb 1985 | A |
4520882 | van Nederveen | Jun 1985 | A |
4526748 | Rozmus | Jul 1985 | A |
4547104 | Holmes | Oct 1985 | A |
4547337 | Rozmus | Oct 1985 | A |
4550532 | Fletcher, Jr. et al. | Nov 1985 | A |
4552232 | Frear | Nov 1985 | A |
4553615 | Grainger | Nov 1985 | A |
4554130 | Ecer | Nov 1985 | A |
4562990 | Rose | Jan 1986 | A |
4574011 | Bonjour et al. | Mar 1986 | A |
4579713 | Lueth | Apr 1986 | A |
4587174 | Yoshimura et al. | May 1986 | A |
4592685 | Beere | Jun 1986 | A |
4596694 | Rozmus | Jun 1986 | A |
4597456 | Ecer | Jul 1986 | A |
4597730 | Rozmus | Jul 1986 | A |
4604106 | Hall | Aug 1986 | A |
4604781 | Rankin, III | Aug 1986 | A |
4605343 | Hibbs, Jr. et al. | Aug 1986 | A |
4609577 | Long | Sep 1986 | A |
4630693 | Goodfellow | Dec 1986 | A |
4642003 | Yoshimura | Feb 1987 | A |
4646857 | Thompson | Mar 1987 | A |
4649086 | Johnson | Mar 1987 | A |
4656002 | Lizenby et al. | Apr 1987 | A |
4662461 | Garrett | May 1987 | A |
4667756 | King et al. | May 1987 | A |
4686080 | Hara et al. | Aug 1987 | A |
4686156 | Baldoni, II et al. | Aug 1987 | A |
4694919 | Barr | Sep 1987 | A |
4708542 | Emanuelli | Nov 1987 | A |
4722405 | Langford | Feb 1988 | A |
4729789 | Ide et al. | Mar 1988 | A |
4735656 | Schaefer et al. | Apr 1988 | A |
4743515 | Fischer et al. | May 1988 | A |
4744943 | Timm | May 1988 | A |
4749053 | Hollingshead | Jun 1988 | A |
4752159 | Howlett | Jun 1988 | A |
4752164 | Leonard, Jr. | Jun 1988 | A |
4761844 | Turchan | Aug 1988 | A |
4779440 | Cleve et al. | Oct 1988 | A |
4780274 | Barr | Oct 1988 | A |
4804049 | Barr | Feb 1989 | A |
4809903 | Eylon et al. | Mar 1989 | A |
4813823 | Bieneck | Mar 1989 | A |
4831674 | Bergstrom et al. | May 1989 | A |
4838366 | Jones | Jun 1989 | A |
4861350 | Phaal et al. | Aug 1989 | A |
4871377 | Frushour | Oct 1989 | A |
4881431 | Bieneck | Nov 1989 | A |
4884477 | Smith et al. | Dec 1989 | A |
4889017 | Fuller et al. | Dec 1989 | A |
4899838 | Sullivan et al. | Feb 1990 | A |
4919013 | Smith et al. | Apr 1990 | A |
4923512 | Timm et al. | May 1990 | A |
4934040 | Turchan | Jun 1990 | A |
4943191 | Schmitt | Jul 1990 | A |
4956012 | Jacobs et al. | Sep 1990 | A |
4968348 | Abkowitz et al. | Nov 1990 | A |
4971485 | Nomura et al. | Nov 1990 | A |
4991670 | Fuller et al. | Feb 1991 | A |
5000273 | Horton et al. | Mar 1991 | A |
5010945 | Burke | Apr 1991 | A |
5030598 | Hsieh | Jul 1991 | A |
5032352 | Meeks et al. | Jul 1991 | A |
5041261 | Buljan et al. | Aug 1991 | A |
5049450 | Dorfman et al. | Sep 1991 | A |
RE33753 | Vacchiano et al. | Nov 1991 | E |
5067860 | Kobayashi et al. | Nov 1991 | A |
5075315 | Rasmussen | Dec 1991 | A |
5075316 | Hubele | Dec 1991 | A |
5080538 | Schmitt | Jan 1992 | A |
5090491 | Tibbitts et al. | Feb 1992 | A |
5092412 | Walk | Mar 1992 | A |
5094571 | Ekerot | Mar 1992 | A |
5096465 | Chen et al. | Mar 1992 | A |
5098232 | Benson | Mar 1992 | A |
5110687 | Abe et al. | May 1992 | A |
5112162 | Hartford et al. | May 1992 | A |
5112168 | Glimpel | May 1992 | A |
5116659 | Glatzle et al. | May 1992 | A |
5126206 | Garg et al. | Jun 1992 | A |
5127776 | Glimpel | Jul 1992 | A |
5135801 | Nyström et al. | Aug 1992 | A |
5161898 | Drake | Nov 1992 | A |
5174700 | Sgarbi et al. | Dec 1992 | A |
5179772 | Braun et al. | Jan 1993 | A |
5186739 | Isobe et al. | Feb 1993 | A |
5203513 | Keller et al. | Apr 1993 | A |
5203932 | Kato et al. | Apr 1993 | A |
5217081 | Waldenström et al. | Jun 1993 | A |
5232522 | Doktycz et al. | Aug 1993 | A |
5250355 | Newman et al. | Oct 1993 | A |
5266415 | Newkirk et al. | Nov 1993 | A |
5273380 | Musacchia | Dec 1993 | A |
5281260 | Kumar et al. | Jan 1994 | A |
5286685 | Schoennahl et al. | Feb 1994 | A |
5305840 | Liang et al. | Apr 1994 | A |
5311958 | Isbell et al. | May 1994 | A |
5326196 | Noll | Jul 1994 | A |
5333520 | Fischer et al. | Aug 1994 | A |
5335738 | Waldenström et al. | Aug 1994 | A |
5338135 | Noguchi et al. | Aug 1994 | A |
5346316 | Okada et al. | Sep 1994 | A |
5348806 | Kojo et al. | Sep 1994 | A |
5354155 | Adams | Oct 1994 | A |
5359772 | Carlsson et al. | Nov 1994 | A |
5373907 | Weaver | Dec 1994 | A |
5376329 | Morgan et al. | Dec 1994 | A |
5413438 | Turchan | May 1995 | A |
5423899 | Krall et al. | Jun 1995 | A |
5429459 | Palm | Jul 1995 | A |
5433280 | Smith | Jul 1995 | A |
5438108 | Umemura et al. | Aug 1995 | A |
5438858 | Friedrichs | Aug 1995 | A |
5443337 | Katayama | Aug 1995 | A |
5447549 | Yoshimura | Sep 1995 | A |
5452771 | Blackman et al. | Sep 1995 | A |
5467669 | Stroud | Nov 1995 | A |
5474407 | Rodel et al. | Dec 1995 | A |
5479997 | Scott et al. | Jan 1996 | A |
5480272 | Jorgensen et al. | Jan 1996 | A |
5482670 | Hong | Jan 1996 | A |
5484468 | Östlund et al. | Jan 1996 | A |
5487626 | Von Holst et al. | Jan 1996 | A |
5492186 | Overstreet et al. | Feb 1996 | A |
5496137 | Ochayon et al. | Mar 1996 | A |
5498142 | Mills | Mar 1996 | A |
5505748 | Tank et al. | Apr 1996 | A |
5506055 | Dorfman et al. | Apr 1996 | A |
5518077 | Blackman et al. | May 1996 | A |
5525134 | Mehrotra et al. | Jun 1996 | A |
5541006 | Conley | Jul 1996 | A |
5543235 | Mirchandani et al. | Aug 1996 | A |
5544550 | Smith | Aug 1996 | A |
5560238 | Allebach et al. | Oct 1996 | A |
5560440 | Tibbitts | Oct 1996 | A |
5570978 | Rees et al. | Nov 1996 | A |
5580666 | Dubensky et al. | Dec 1996 | A |
5586612 | Isbell et al. | Dec 1996 | A |
5590729 | Cooley et al. | Jan 1997 | A |
5593474 | Keshavan et al. | Jan 1997 | A |
5601857 | Friedrichs | Feb 1997 | A |
5603075 | Stoll et al. | Feb 1997 | A |
5609286 | Anthon | Mar 1997 | A |
5609447 | Britzke et al. | Mar 1997 | A |
5611251 | Katayama | Mar 1997 | A |
5612264 | Nilsson et al. | Mar 1997 | A |
5628837 | Britzke et al. | May 1997 | A |
RE35538 | Akesson et al. | Jun 1997 | E |
5641251 | Leins et al. | Jun 1997 | A |
5641921 | Dennis et al. | Jun 1997 | A |
5662183 | Fang | Sep 1997 | A |
5666864 | Tibbitts | Sep 1997 | A |
5672382 | Lux | Sep 1997 | A |
5677042 | Massa et al. | Oct 1997 | A |
5679445 | Massa et al. | Oct 1997 | A |
5686119 | McNaughton, Jr. | Nov 1997 | A |
5697042 | Massa et al. | Dec 1997 | A |
5697046 | Conley | Dec 1997 | A |
5697462 | Grimes et al. | Dec 1997 | A |
5704736 | Giannetti | Jan 1998 | A |
5712030 | Goto et al. | Jan 1998 | A |
5718948 | Ederyd et al. | Feb 1998 | A |
5732783 | Truax et al. | Mar 1998 | A |
5733078 | Matsushita et al. | Mar 1998 | A |
5733649 | Kelley et al. | Mar 1998 | A |
5733664 | Kelley et al. | Mar 1998 | A |
5750247 | Bryant et al. | May 1998 | A |
5753160 | Takeuchi et al. | May 1998 | A |
5755033 | Gunter et al. | May 1998 | A |
5755298 | Langford, Jr. et al. | May 1998 | A |
5762843 | Massa et al. | Jun 1998 | A |
5765095 | Flak et al. | Jun 1998 | A |
5776593 | Massa et al. | Jul 1998 | A |
5778301 | Hong | Jul 1998 | A |
5789686 | Massa et al. | Aug 1998 | A |
5791833 | Niebauer | Aug 1998 | A |
5792403 | Massa et al. | Aug 1998 | A |
5803152 | Dolman et al. | Sep 1998 | A |
5806934 | Massa et al. | Sep 1998 | A |
5830256 | Northrop et al. | Nov 1998 | A |
5851094 | Strand et al. | Dec 1998 | A |
5856626 | Fischer et al. | Jan 1999 | A |
5865571 | Tankala et al. | Feb 1999 | A |
5873684 | Flolo | Feb 1999 | A |
5880382 | Fang et al. | Mar 1999 | A |
5890852 | Gress | Apr 1999 | A |
5893204 | Symonds | Apr 1999 | A |
5897830 | Abkowitz et al. | Apr 1999 | A |
5899257 | Alleweireldt et al. | May 1999 | A |
5947660 | Karlsson et al. | Sep 1999 | A |
5957006 | Smith | Sep 1999 | A |
5963775 | Fang | Oct 1999 | A |
5964555 | Strand | Oct 1999 | A |
5967249 | Butcher | Oct 1999 | A |
5971670 | Pantzar et al. | Oct 1999 | A |
5976707 | Grab et al. | Nov 1999 | A |
5988953 | Berglund et al. | Nov 1999 | A |
6007909 | Rolander et al. | Dec 1999 | A |
6012882 | Turchan | Jan 2000 | A |
6022175 | Heinrich et al. | Feb 2000 | A |
6029544 | Katayama | Feb 2000 | A |
6051171 | Takeuchi et al. | Apr 2000 | A |
6063333 | Dennis | May 2000 | A |
6068070 | Scott | May 2000 | A |
6073518 | Chow et al. | Jun 2000 | A |
6076999 | Hedberg et al. | Jun 2000 | A |
6086003 | Gunter et al. | Jul 2000 | A |
6086980 | Foster et al. | Jul 2000 | A |
6089123 | Chow et al. | Jul 2000 | A |
6109377 | Massa et al. | Aug 2000 | A |
6109677 | Anthony | Aug 2000 | A |
6117493 | North | Sep 2000 | A |
6135218 | Deane et al. | Oct 2000 | A |
6148936 | Evans et al. | Nov 2000 | A |
6200514 | Meister | Mar 2001 | B1 |
6209420 | Butcher et al. | Apr 2001 | B1 |
6214134 | Eylon et al. | Apr 2001 | B1 |
6214287 | Waldenström | Apr 2001 | B1 |
6220117 | Butcher | Apr 2001 | B1 |
6227188 | Tankala et al. | May 2001 | B1 |
6228134 | Erickson | May 2001 | B1 |
6228139 | Oskarsson | May 2001 | B1 |
6234261 | Evans et al. | May 2001 | B1 |
6241036 | Lovato et al. | Jun 2001 | B1 |
6248277 | Friedrichs | Jun 2001 | B1 |
6254658 | Taniuchi et al. | Jul 2001 | B1 |
6287360 | Kembaiyan et al. | Sep 2001 | B1 |
6290438 | Papajewski | Sep 2001 | B1 |
6293986 | Rodiger et al. | Sep 2001 | B1 |
6299658 | Moriguchi et al. | Oct 2001 | B1 |
6302224 | Sherwood, Jr. | Oct 2001 | B1 |
6326582 | North | Dec 2001 | B1 |
6345941 | Fang et al. | Feb 2002 | B1 |
6353771 | Southland | Mar 2002 | B1 |
6372346 | Toth | Apr 2002 | B1 |
6374932 | Brady | Apr 2002 | B1 |
6375706 | Kembaiyan et al. | Apr 2002 | B2 |
6386954 | Sawabe et al. | May 2002 | B2 |
6394711 | Brosius | May 2002 | B1 |
6395108 | Eberle et al. | May 2002 | B2 |
6402439 | Puide et al. | Jun 2002 | B1 |
6425716 | Cook | Jul 2002 | B1 |
6450739 | Puide et al. | Sep 2002 | B1 |
6453899 | Tselesin | Sep 2002 | B1 |
6454025 | Runquist et al. | Sep 2002 | B1 |
6454028 | Evans | Sep 2002 | B1 |
6454030 | Findley et al. | Sep 2002 | B1 |
6458471 | Lovato et al. | Oct 2002 | B2 |
6461401 | Kembaiyan et al. | Oct 2002 | B1 |
6474425 | Truax et al. | Nov 2002 | B1 |
6475647 | Mendez Acevedo et al. | Nov 2002 | B1 |
6499917 | Parker et al. | Dec 2002 | B1 |
6499920 | Sawabe | Dec 2002 | B2 |
6500226 | Dennis | Dec 2002 | B1 |
6502623 | Schmitt | Jan 2003 | B1 |
6511265 | Keller et al. | Jan 2003 | B1 |
6541124 | Suggs | Apr 2003 | B1 |
6544308 | Griffin et al. | Apr 2003 | B2 |
6546991 | Dworog et al. | Apr 2003 | B2 |
6551035 | Bruhn et al. | Apr 2003 | B1 |
6562462 | Griffin et al. | May 2003 | B2 |
6576182 | Ravagni et al. | Jun 2003 | B1 |
6582126 | North | Jun 2003 | B2 |
6585064 | Griffin et al. | Jul 2003 | B2 |
6585864 | Fisher et al. | Jul 2003 | B1 |
6589640 | Griffin et al. | Jul 2003 | B2 |
6599467 | Yamaguchi et al. | Jul 2003 | B1 |
6607693 | Saito et al. | Aug 2003 | B1 |
6607835 | Fang et al. | Aug 2003 | B2 |
6637528 | Nishiyama et al. | Oct 2003 | B2 |
6648068 | Dewey et al. | Nov 2003 | B2 |
6649682 | Breton et al. | Nov 2003 | B1 |
6651757 | Belnap et al. | Nov 2003 | B2 |
6655481 | Findley et al. | Dec 2003 | B2 |
6655882 | Heinrich et al. | Dec 2003 | B2 |
6676863 | Christiaens et al. | Jan 2004 | B2 |
6682780 | Tzatzov et al. | Jan 2004 | B2 |
6685880 | Engström et al. | Feb 2004 | B2 |
6688988 | McClure | Feb 2004 | B2 |
6695551 | Silver | Feb 2004 | B2 |
6706327 | Blomstedt et al. | Mar 2004 | B2 |
6716388 | Bruhn et al. | Apr 2004 | B2 |
6719074 | Tsuda et al. | Apr 2004 | B2 |
6725953 | Truax et al. | Apr 2004 | B2 |
6737178 | Ota et al. | May 2004 | B2 |
6742608 | Murdoch | Jun 2004 | B2 |
6742611 | Illerhaus et al. | Jun 2004 | B1 |
6756009 | Sim et al. | Jun 2004 | B2 |
6764555 | Hiramatsu et al. | Jul 2004 | B2 |
6766870 | Overstreet | Jul 2004 | B2 |
6767505 | Witherspoon et al. | Jul 2004 | B2 |
6772849 | Oldham et al. | Aug 2004 | B2 |
6782958 | Liang et al. | Aug 2004 | B2 |
6799648 | Brandenberg et al. | Oct 2004 | B2 |
6808821 | Fujita et al. | Oct 2004 | B2 |
6844085 | Takayama et al. | Jan 2005 | B2 |
6848521 | Lockstedt et al. | Feb 2005 | B2 |
6849231 | Kojima et al. | Feb 2005 | B2 |
6892793 | Liu et al. | May 2005 | B2 |
6899495 | Hansson et al. | May 2005 | B2 |
6918942 | Hatta et al. | Jul 2005 | B2 |
6932172 | Dvorachek | Aug 2005 | B2 |
6933049 | Wan et al. | Aug 2005 | B2 |
6948890 | Svensson et al. | Sep 2005 | B2 |
6949148 | Sugiyama et al. | Sep 2005 | B2 |
6955233 | Crowe et al. | Oct 2005 | B2 |
6958099 | Nakamura et al. | Oct 2005 | B2 |
7014719 | Suzuki et al. | Mar 2006 | B2 |
7014720 | Iseda | Mar 2006 | B2 |
7017677 | Keshavan et al. | Mar 2006 | B2 |
7036611 | Radford et al. | May 2006 | B2 |
7044243 | Kembaiyan et al. | May 2006 | B2 |
7048081 | Smith et al. | May 2006 | B2 |
7070666 | Druschitz et al. | Jul 2006 | B2 |
7080998 | Hall et al. | Jul 2006 | B2 |
7090731 | Kashima et al. | Aug 2006 | B2 |
7101128 | Hansson | Sep 2006 | B2 |
7101446 | Takeda et al. | Sep 2006 | B2 |
7112143 | Muller | Sep 2006 | B2 |
7125207 | Craig et al. | Oct 2006 | B2 |
7128773 | Liang et al. | Oct 2006 | B2 |
7147413 | Henderer et al. | Dec 2006 | B2 |
7152701 | Butland et al. | Dec 2006 | B2 |
7172142 | Taylor et al. | Feb 2007 | B2 |
7175404 | Kondo et al. | Feb 2007 | B2 |
7192660 | Ruppi | Mar 2007 | B2 |
7207401 | Dewey et al. | Apr 2007 | B2 |
7207750 | Annanolli et al. | Apr 2007 | B2 |
7216727 | Wardley | May 2007 | B2 |
7231984 | Jaensch | Jun 2007 | B2 |
7234541 | Scott et al. | Jun 2007 | B2 |
7234550 | Azar et al. | Jun 2007 | B2 |
7235211 | Griffo et al. | Jun 2007 | B2 |
7238414 | Benitsch et al. | Jul 2007 | B2 |
7244519 | Festeau et al. | Jul 2007 | B2 |
7250069 | Kembaiyan et al. | Jul 2007 | B2 |
7261782 | Hwang et al. | Aug 2007 | B2 |
7262240 | Breton et al. | Aug 2007 | B1 |
7267187 | Kembaiyan | Sep 2007 | B2 |
7267543 | Freidhoff et al. | Sep 2007 | B2 |
7270679 | Istephanous et al. | Sep 2007 | B2 |
7296497 | Kugelberg et al. | Nov 2007 | B2 |
7350599 | Lockwood et al. | Apr 2008 | B2 |
7381283 | Lee et al. | Jun 2008 | B2 |
7384413 | Gross et al. | Jun 2008 | B2 |
7384443 | Mirchandani et al. | Jun 2008 | B2 |
7395882 | Oldham et al. | Jul 2008 | B2 |
7410610 | Woodfield et al. | Aug 2008 | B2 |
7487849 | Radtke | Feb 2009 | B2 |
7494507 | Dixon | Feb 2009 | B2 |
7497280 | Brackin et al. | Mar 2009 | B2 |
7497396 | Splinter et al. | Mar 2009 | B2 |
7513320 | Mirchandani et al. | Apr 2009 | B2 |
7524351 | Hua et al. | Apr 2009 | B2 |
7556668 | Eason et al. | Jul 2009 | B2 |
7575620 | Terry et al. | Aug 2009 | B2 |
7625157 | Prichard et al. | Dec 2009 | B2 |
7632323 | Ganguly et al. | Dec 2009 | B2 |
7661491 | Kembaiyan et al. | Feb 2010 | B2 |
7687156 | Fang | Mar 2010 | B2 |
7703555 | Overstreet | Apr 2010 | B2 |
7810588 | McClain et al. | Oct 2010 | B2 |
7832456 | Calnan et al. | Nov 2010 | B2 |
7832457 | Calnan et al. | Nov 2010 | B2 |
7846551 | Fang et al. | Dec 2010 | B2 |
7887747 | Iwasaki et al. | Feb 2011 | B2 |
7954569 | Mirchandani et al. | Jun 2011 | B2 |
8007714 | Mirchandani et al. | Aug 2011 | B2 |
8007922 | Mirchandani et al. | Aug 2011 | B2 |
8025112 | Mirchandani et al. | Sep 2011 | B2 |
8087324 | Mirchandani et al. | Jan 2012 | B2 |
8109177 | Kembaiyan et al. | Feb 2012 | B2 |
8137816 | Fang et al. | Mar 2012 | B2 |
8141665 | Ganz | Mar 2012 | B2 |
8221517 | Mirchandani et al. | Jul 2012 | B2 |
8225886 | Mirchandani et al. | Jul 2012 | B2 |
8272816 | Mirchandani | Sep 2012 | B2 |
20020004105 | Kunze et al. | Jan 2002 | A1 |
20030010409 | Kunze et al. | Jan 2003 | A1 |
20030041922 | Hirose et al. | Mar 2003 | A1 |
20030219605 | Molian et al. | Nov 2003 | A1 |
20040013558 | Kondoh et al. | Jan 2004 | A1 |
20040105730 | Nakajima | Jun 2004 | A1 |
20040228695 | Clauson | Nov 2004 | A1 |
20040234820 | Majagi | Nov 2004 | A1 |
20040244540 | Oldham et al. | Dec 2004 | A1 |
20040245022 | Izaguirre et al. | Dec 2004 | A1 |
20040245024 | Kembaiyan | Dec 2004 | A1 |
20050008524 | Testani | Jan 2005 | A1 |
20050019114 | Sung | Jan 2005 | A1 |
20050084407 | Myrick | Apr 2005 | A1 |
20050103404 | Hsieh et al. | May 2005 | A1 |
20050117984 | Eason et al. | Jun 2005 | A1 |
20050194073 | Hamano et al. | Sep 2005 | A1 |
20050211475 | Mirchandani et al. | Sep 2005 | A1 |
20050268746 | Abkowitz et al. | Dec 2005 | A1 |
20060016521 | Hanusiak et al. | Jan 2006 | A1 |
20060024140 | Wolff et al. | Feb 2006 | A1 |
20060032677 | Azar et al. | Feb 2006 | A1 |
20060043648 | Takeuchi et al. | Mar 2006 | A1 |
20060060392 | Eyre | Mar 2006 | A1 |
20060162415 | Friedrichs | Jul 2006 | A1 |
20060185773 | Chiovelli | Aug 2006 | A1 |
20060286410 | Ahlgren et al. | Dec 2006 | A1 |
20060288820 | Mirchandani et al. | Dec 2006 | A1 |
20070082229 | Mirchandani et al. | Apr 2007 | A1 |
20070102198 | Oxford et al. | May 2007 | A1 |
20070102199 | Smith et al. | May 2007 | A1 |
20070102200 | Choe et al. | May 2007 | A1 |
20070102202 | Choe et al. | May 2007 | A1 |
20070108650 | Mirchandani et al. | May 2007 | A1 |
20070126334 | Nakamura et al. | Jun 2007 | A1 |
20070163679 | Fujisawa et al. | Jul 2007 | A1 |
20070193782 | Fang et al. | Aug 2007 | A1 |
20070251732 | Mirchandani et al. | Nov 2007 | A1 |
20080011519 | Smith et al. | Jan 2008 | A1 |
20080101977 | Eason et al. | May 2008 | A1 |
20080196318 | Bost et al. | Aug 2008 | A1 |
20080302576 | Michandani et al. | Dec 2008 | A1 |
20090032501 | Swingley et al. | Feb 2009 | A1 |
20090041612 | Fang et al. | Feb 2009 | A1 |
20090136308 | Newitt | May 2009 | A1 |
20090180915 | Mirchandani et al. | Jul 2009 | A1 |
20090301788 | Stevens et al. | Dec 2009 | A1 |
20100044114 | Mirchandani et al. | Feb 2010 | A1 |
20100044115 | Mirchandani et al. | Feb 2010 | A1 |
20100278603 | Fang et al. | Nov 2010 | A1 |
20100323213 | Aitchison et al. | Dec 2010 | A1 |
20110011965 | Mirchandani et al. | Jan 2011 | A1 |
20110107811 | Mirchandani et al. | May 2011 | A1 |
20110265623 | Mirchandani et al. | Nov 2011 | A1 |
20110284179 | Stevens et al. | Nov 2011 | A1 |
20110287238 | Stevens et al. | Nov 2011 | A1 |
20110287924 | Stevens | Nov 2011 | A1 |
20120237386 | Mirchandani et al. | Sep 2012 | A1 |
20120240476 | Mirchandani et al. | Sep 2012 | A1 |
20120241222 | Mirchandani et al. | Sep 2012 | A1 |
20120282051 | Mirchandani | Nov 2012 | A1 |
20120285293 | Mirchandani et al. | Nov 2012 | A1 |
20130048701 | Mirchandani et al. | Feb 2013 | A1 |
20130075165 | Coleman et al. | Mar 2013 | A1 |
Number | Date | Country |
---|---|---|
695583 | Feb 1998 | AU |
1018474 | Oct 1977 | CA |
1158073 | Dec 1983 | CA |
1250156 | Feb 1989 | CA |
2022065 | Feb 1991 | CA |
2120332 | Jun 1993 | CA |
2107004 | May 1996 | CA |
2228398 | Feb 1997 | CA |
2198985 | Sep 1998 | CA |
2108274 | Jul 2000 | CA |
2212197 | Oct 2000 | CA |
2201969 | Feb 2003 | CA |
2213169 | Mar 2005 | CA |
2498073 | Aug 2006 | CA |
2556132 | Feb 2007 | CA |
2570937 | Jun 2007 | CA |
2357407 | Jan 2008 | CA |
19634314 | Jan 1998 | DE |
10300283 | Jun 2004 | DE |
102006030661 | Jan 2008 | DE |
102007006943 | Aug 2008 | DE |
0157625 | Oct 1985 | EP |
0264674 | Apr 1988 | EP |
0453428 | Oct 1991 | EP |
0605585 | Aug 1995 | EP |
0641620 | Feb 1998 | EP |
0995876 | Apr 2000 | EP |
1065021 | Jan 2001 | EP |
1066901 | Jan 2001 | EP |
1106706 | Jun 2001 | EP |
0759480 | Jan 2002 | EP |
1077268 | May 2003 | EP |
1244531 | Oct 2004 | EP |
1686193 | Aug 2006 | EP |
1788104 | May 2007 | EP |
2627541 | Aug 1989 | FR |
622041 | Apr 1949 | GB |
945227 | Dec 1963 | GB |
1082568 | Sep 1967 | GB |
1309634 | Mar 1973 | GB |
1420906 | Jan 1976 | GB |
1491044 | Nov 1977 | GB |
2064619 | Jun 1981 | GB |
2158744 | Nov 1985 | GB |
2218931 | Nov 1989 | GB |
2315452 | Feb 1998 | GB |
2324752 | Nov 1998 | GB |
2352727 | Feb 2001 | GB |
2384745 | Aug 2003 | GB |
2385350 | Aug 2003 | GB |
2393449 | Mar 2004 | GB |
2397832 | Aug 2004 | GB |
2409467 | Jun 2005 | GB |
2435476 | Aug 2007 | GB |
51-114307 | Oct 1976 | JP |
51-124876 | Oct 1976 | JP |
56-52604 | May 1981 | JP |
59-54510 | Mar 1984 | JP |
59-56501 | Apr 1984 | JP |
59-67333 | Apr 1984 | JP |
59-169707 | Sep 1984 | JP |
59-175912 | Oct 1984 | JP |
60-48207 | Mar 1985 | JP |
60-172403 | Sep 1985 | JP |
60-224790 | Nov 1985 | JP |
61-226231 | Oct 1986 | JP |
61-243103 | Oct 1986 | JP |
61057123 | Dec 1986 | JP |
62-34710 | Feb 1987 | JP |
62-063005 | Mar 1987 | JP |
62-218010 | Sep 1987 | JP |
62-278250 | Dec 1987 | JP |
1-171725 | Jul 1989 | JP |
2-95506 | Apr 1990 | JP |
2-269515 | Nov 1990 | JP |
3-43112 | Feb 1991 | JP |
3-73210 | Mar 1991 | JP |
04-217414 | Aug 1992 | JP |
5-50314 | Mar 1993 | JP |
5-92329 | Apr 1993 | JP |
H05-64288 | Aug 1993 | JP |
H03-119090 | Jun 1995 | JP |
7-276105 | Oct 1995 | JP |
8-120308 | May 1996 | JP |
H8-209284 | Aug 1996 | JP |
8-294805 | Nov 1996 | JP |
9-11005 | Jan 1997 | JP |
9-192930 | Jul 1997 | JP |
9-253779 | Sep 1997 | JP |
10-138033 | May 1998 | JP |
10-156607 | Jun 1998 | JP |
10219385 | Aug 1998 | JP |
H10-511740 | Nov 1998 | JP |
11-10409 | Jan 1999 | JP |
11-300516 | Nov 1999 | JP |
2000-237910 | Sep 2000 | JP |
2000-296403 | Oct 2000 | JP |
2000-355725 | Dec 2000 | JP |
2001-179517 | Jul 2001 | JP |
2002-097885 | Apr 2002 | JP |
2002-166326 | Jun 2002 | JP |
2002-317596 | Oct 2002 | JP |
2003-306739 | Oct 2003 | JP |
2004-160591 | Jun 2004 | JP |
2004-181604 | Jul 2004 | JP |
2004-190034 | Jul 2004 | JP |
2004-315904 | Nov 2004 | JP |
2005-111581 | Apr 2005 | JP |
2005-519448 | Jun 2005 | JP |
2006-328477 | Jun 2005 | JP |
2006-524173 | Oct 2006 | JP |
20050055268 | Jun 2005 | KR |
2135328 | Aug 1999 | RU |
2173241 | Feb 2000 | RU |
2167262 | May 2001 | RU |
967786 | Oct 1982 | SU |
975369 | Nov 1982 | SU |
990423 | Jan 1983 | SU |
1269922 | Nov 1986 | SU |
1292917 | Feb 1987 | SU |
1350322 | Nov 1987 | SU |
6742 | Dec 1994 | UA |
63469 | Jan 2006 | UA |
23749 | Jun 2007 | UA |
WO 9205009 | Apr 1992 | WO |
WO 9222390 | Dec 1992 | WO |
WO 9719201 | May 1997 | WO |
WO 9734726 | Sep 1997 | WO |
WO 9828455 | Jul 1998 | WO |
WO 9913121 | Mar 1999 | WO |
WO 9700734 | Jul 1999 | WO |
WO 9936590 | Jul 1999 | WO |
WO 0043628 | Jul 2000 | WO |
WO 0052217 | Sep 2000 | WO |
WO 0143899 | Jun 2001 | WO |
WO 03010350 | Feb 2003 | WO |
WO 03011508 | Feb 2003 | WO |
WO 03049889 | Jun 2003 | WO |
WO 2004053197 | Jun 2004 | WO |
WO 2005045082 | May 2005 | WO |
WO 2005054530 | Jun 2005 | WO |
WO 2005061746 | Jul 2005 | WO |
WO 2005106183 | Nov 2005 | WO |
WO 2006071192 | Jul 2006 | WO |
WO 2006104004 | Oct 2006 | WO |
WO 2007001870 | Jan 2007 | WO |
WO 2007022336 | Feb 2007 | WO |
WO 2007030707 | Mar 2007 | WO |
WO 2007044791 | Apr 2007 | WO |
WO 2007127680 | Nov 2007 | WO |
WO 2008098636 | Aug 2008 | WO |
WO 2008115703 | Sep 2008 | WO |
WO 2011000348 | Jan 2011 | WO |
WO 2011008439 | Jan 2011 | WO |
Entry |
---|
US 4,966,627, 10/1990, Keshavan et al. (withdrawn). |
Coyle, T.W. and A. Bahrami, “Structure and Adhesion of Ni and Ni-WC Plasma Spray Coatings,” Thermal Spray, Surface Engineering via Applied Research, Proceedings of the 1st International Thermal Spray Conference, May 8-11, 2000, Montreal, Quebec, Canada, 2000, pp. 251-254. |
Deng, X. et al., “Mechanical Properties of a Hybrid Cemented Carbide Composite,” International Journal of Refractory Metals and Hard Materials, Elsevier Science Ltd., vol. 19, 2001, pp. 547-552. |
Gurland, Joseph, “Application of Quantitative Microscopy to Cemented Carbides,” Practical Applications of Quantitative Matellography, ASTM Special Technical Publication 839, ASTM 1984, pp. 65-84. |
Hayden, Matthew and Lyndon Scott Stephens, “Experimental Results for a Heat-Sink Mechanical Seal,” Tribology Transactions, 48, 2005, pp. 352-361. |
Metals Handbook, vol. 16 Machining, “Cemented Carbides” (ASM International 1989), pp. 71-89. |
Metals Handbook, vol. 16 Machining, “Tapping” (ASM International 1989), pp. 255-267. |
Peterman, Walter, “Heat-Sink Compound Protects the Unprotected,” Welding Design and Fabrication, Sep. 2003, pp. 20-22. |
Shi et al., “Composite Ductility—The Role of Reinforcement and Matrix”, TMS Meeting, Las Vegas, NV, Feb. 12-16, 1995, 10 pages. |
Sriram, et al., “Effect of Cerium Addition on Microstructures of Carbon-Alloyed Iron Aluminides,” Bull. Mater. Sci., vol. 28, No. 6, Oct. 2005, pp. 547-554. |
Tracey et al., “Development of Tungsten Carbide-Cobalt-Ruthenium Cutting Tools for Machining Steels” Proceedings Annual Microprogramming Workshop, vol. 14, 1981, pp. 281-292. |
Underwood, Quantitative Stereology, pp. 23-108 (1970). |
Vander Vort, “Introduction to Quantitative Metallography”, Tech Notes, vol. 1, Issue 5, published by Buehler, Ltd. 1997, 6 pages. |
J. Gurland, Quantitative Microscopy, R.T. DeHoff and F.N. Rhines, eds., McGraw-Hill Book Company, New York, 1968, pp. 279-290. |
You Tube, “The Story Behind Kennametal's Beyond Blast”, dated Sep. 14, 2010, http://www.youtube.com/watch?v=8—A-bYVwmU8 (3 pages) accessed on Oct. 14, 2010. |
Kennametal press release on Jun. 10, 2010, http://news.thomasnet.com/companystory/Kennametal-Launches-Beyond-BLAST-TM-at-IMTS-2010-Booth-W-1522-833445 (2 pages) accessed on Oct. 14, 2010. |
Pages from Kennametal site, https://www.kennametal.com/en-US/promotions/Beyond—Blast.jhtml (7 pages) accessed on Oct. 14, 2010. |
ASM Materials Engineering Dictionary, J.R. Davis, Ed., ASM International, Fifth printing, Jan. 2006, p. 98. |
Childs et al., “Metal Machining”, 2000, Elsevier, p. 111. |
Brookes, Kenneth J. A., “World Directory and Handbook of Hardmetals and Hard Materials”, International Carbide Data, U.K. 1996, Sixth Edition, p. 42. |
Firth Sterling grade chart, Allegheny Technologies, attached to Declaration of Prakash Mirchandani, Ph.D. as filed in U.S. Appl. No. 11/737,993 on Sep. 9, 2009. |
Metals Handbook Desk Edition, definition of ‘wear’, 2nd Ed., J.R. Davis, Editor, ASM International 1998, p. 62. |
McGraw-Hill Dictionary of Scientific and Technical Terms, 5th Edition, Sybil P. Parker, Editor in Chief, 1994, pp. 799, 800, 1933, and 2047. |
ProKon Version 8.6, The Calculation Companion, Properties for W, Ti, Mo, Co, Ni and FE, Copyright 1997-1998, 6 pages. |
Tibtech Innovations, “Properties table of stainless steel, metals and other conductive materials”, printed from http://www.tibtech.com/conductivity.php on Aug. 19, 2011, 1 page. |
“Material: Tungsten Carbide (WC), bulk”, MEMSnet, printed from http://www.memsnet.org/material/tungstencarbidewcbulk/ on Aug. 19, 2001, 1 page. |
Williams, Wendell S., “The Thermal Conductivity of Metallic Ceramics”, JOM, Jun. 1998, pp. 62-66. |
Brookes, Kenneth J. A., “World Directory and Handbook of Hardmetals and Hard Materials”, International Carbide Data, U.K. 1996, Sixth Edition, pp. D182-D184. |
Thermal Conductivity of Metals, The Engineering ToolBox, printed from http://www.engineeringtoolbox.com/thermal-conductivity-metals-d—858.html on Oct. 27, 2011, 3 pages. |
The Thermal Conductivity of Some Common Materials and Gases, The Engineering ToolBox, printed from http://www.engineeringtoolbox.com/thermal-conductivity-d—429.html on Dec. 15, 2011, 4 pages. |
ASTM G65-04, Standard Test Method for Measuring Abrasion Using the Dry Sand, Nov. 1, 2004, printed from http://infostore.saiglobal.com. |
Tool and Manufacturing Engineers Handbook, Fourth Edition, vol. 1, Machining, Society of Manufacturing Engineers, Chapter 12, vol. 1, 1983, pp. 12-110-12-114. |
Beard, T. “The INS and OUTS of Thread Milling; Emphasis: Hole Making, Interview”, Modern Machine Shop, Gardner Publications, Inc. 1991, vol. 64, No. 1, 5 pages. |
Koelsch, J., “Thread Milling Takes on Tapping”, Manufacturing Engineering, 1995, vol. 115, No. 4, 6 pages. |
Johnson, M. “Tapping”, Traditional Machining Processes, 1997, pp. 255-265. |
“Thread Milling”, Traditional Machining Processes, 1997, pp. 268-269. |
Scientific Cutting Tools, “The Cutting Edge”, 1998, printed on Feb. 1, 2000, 15 pages. |
Helical Carbide Thread Mills, Schmarje Tool Company, 1998, 2 pages. |
Pyrotek, Zyp Zircwash, www.pyrotek.info, Feb. 2003, 1 page. |
Sims et al., “Casting Engineering”, Superalloys II, Aug. 1987, pp. 420-426. |
Sikkenga, “Cobalt and Cobalt Alloy Castings”, Casting, vol. 15, ASM Handbook, ASM International, 2008, pp. 1114-1118. |
Starck, H.C., Surface Technology, Powders for PTA-Welding, Lasercladding and other Wear Protective Welding Applications, Jan. 2011, 4 pages. |
Ancormet®, Data Sheet, 0001-AM101-D-1, Hoeganaes, www.hoeganaes.com, 7 pages. (date unavailable). |
Office Action mailed Oct. 4, 2012 in U.S. Appl. No. 13/491,638. |
U.S. Appl. No. 13/558,769, filed Jul. 26, 2012 (62 pages). |
U.S. Appl. No. 13/591,282, filed Aug. 22, 2012 (54 pages). |
Office Action mailed Mar. 12, 2009 in U.S. Appl. No. 11/585,408. |
Office Action mailed Sep. 22, 2009 in U.S. Appl. No. 11/585,408. |
Office Action mailed Sep. 7, 2010 in U.S. Appl. No. 11/585,408. |
Office Action mailed Feb. 16, 2011 in U.S. Appl. No. 11/585,408. |
Advisory Action mailed May 3, 2011 in U.S. Appl. No. 11/585,408. |
Office Action mailed Aug. 17, 2011 in U.S. Appl. No. 11/585,408. |
Notice of Allowance mailed May 9, 2012 in U.S. Appl. No. 11/585,408. |
Notice of Allowance mailed Jul. 20, 2012 in U.S. Appl. No. 11/585,408. |
Corrected Notice of Allowability mailed Oct. 18, 2012 in U.S. Appl. No. 11/585,408. |
Restriction Requirement mailed Jul. 24, 2008 in U.S. Appl. No. 11/167,811. |
Office Action mailed Oct. 21, 2008 in U.S. Appl. No. 11/167,811. |
Final Office Action mailed Jun. 12, 2009 in U.S. Appl. No. 11/167,811. |
Office Action mailed Aug. 28, 2009 in U.S. Appl. No. 11/167,811. |
Office Action mailed Mar. 2, 2010 in U.S. Appl. No. 11/167,811. |
Office Action mailed Aug. 19, 2010 in U.S. Appl. No. 11/167,811. |
Advisory Action Before the Filing of an Appeal Brief mailed May 12, 2010 in U.S. Appl. No. 11/167,811. |
Office Action mailed Feb. 3, 2011 in U.S. Appl. No. 11/167,811. |
Advisory Action mailed May 11, 2011 in U.S. Appl. No. 11/167,811. |
Office Action mailed Jul. 22, 2011 in U.S. Appl. No. 11/167,811. |
Office Action mailed Mar. 28, 2012 in U.S. Appl. No. 11/167,811. |
Office Action mailed Mar. 19, 2009 in U.S. Appl. No. 11/737,993. |
Office Action mailed Jun. 3, 2009 in U.S. Appl. No. 11/737,993. |
Office Action mailed Dec. 9, 2009 in U.S. Appl. No. 11/737,993. |
Office Action mailed Feb. 24, 2010 in U.S. Appl. No. 11/737,993. |
Office Action mailed Jun. 29, 2010 in U.S. Appl. No. 11/737,993. |
Advisory Action Before the Filing of an Appeal Brief mailed Sep. 9, 2010 in U.S. Appl. No. 11/737,993. |
Pre-Brief Appeal Conference Decision mailed Nov. 22, 2010 in U.S. Appl. No. 11/737,993. |
Office Action mailed Apr. 20, 2011 in U.S. Appl. No. 11/737,993. |
Office Action mailed Aug. 3, 2011 in U.S. Appl. No. 11/737,993. |
Office Action mailed Oct. 11, 2011 in U.S. Appl. No. 11/737,993. |
Office Action mailed Jan. 6, 2012 in U.S. Appl. No. 11/737,993. |
Advisory Action Before the Filing of an Appeal Brief mailed Mar. 22, 2012 in U.S. Appl. No. 11/737,993. |
Notice of Allowance mailed Jul. 25, 2012 in U.S. Appl. No. 11/737,993. |
Restriction Requirement mailed Sep. 17, 2010 in U.S. Appl. No. 12/397,597. |
Office Action mailed Nov. 15, 2010 in U.S. Appl. No. 12/397,597. |
Office Action mailed Jun. 7, 2011 in U.S. Appl. No. 12/397,597. |
Advisory Action Before the Filing of an Appeal Brief mailed Aug. 31, 2011 in U.S. Appl. No. 12/397,597. |
Office Action mailed Nov. 17, 2011 in U.S. Appl. No. 12/397,597. |
Advisory Action mailed Jan. 26, 2012 in U.S. Appl. No. 12/397,597. |
Office Action mailed Apr. 13, 2012 in U.S. Appl. No. 12/397,597. |
Office Action mailed Dec. 29, 2005 in U.S. Appl. No. 10/903,198. |
Office Action mailed Sep. 29, 2006 in U.S. Appl. No. 10/903,198. |
Office Action mailed Mar. 27, 2007 in U.S. Appl. No. 10/903,198. |
Office Action mailed Sep. 26, 2007 in U.S. Appl. No. 10/903,198. |
Office Action mailed Jan. 16, 2008 in U.S. Appl. No. 10/903,198. |
Office Action mailed Oct. 31, 2008 in U.S. Appl. No. 10/903,198. |
Office Action mailed Apr. 17, 2009 in U.S. Appl. No. 10/903,198. |
Advisory Action before mailing of Appeal Brief mailed Jun. 29, 2009 in U.S. Appl. No. 10/903,198. |
Examiner's Answer mailed Aug. 17, 2010 in U.S. Appl. No. 10/903,198. |
Office Action mailed Apr. 22, 2010 in U.S. Appl. No. 12/196,951. |
Office Action mailed Oct. 29, 2010 in U.S. Appl. No. 12/196,951. |
Office Action mailed Apr. 12, 2011 in U.S. Appl. No. 12/196,951. |
Office Action mailed Oct. 19, 2011 in U.S. Appl. No. 12/196,951. |
Office Action mailed Mar. 19, 2012 in U.S. Appl. No. 12/196,951. |
Notice of Allowance mailed Jul. 31, 2012 in U.S. Appl. No. 12/196,951. |
Office Action mailed Oct. 13, 2011 in U.S. Appl. No. 12/179,999. |
Notice of Allowance mailed Apr. 30, 2012 in U.S. Appl. No. 12/179,999. |
Office Action mailed Aug. 29, 2011 in U.S. Appl. No. 12/476,738. |
Office Action mailed Dec. 21, 2011 in U.S. Appl. No. 12/476,738. |
Notice of Allowance mailed Apr. 17, 2012 in U.S. Appl. No. 12/476,738. |
Corrected Notice of Allowability mailed Jun. 21, 2012 in U.S. Appl. No. 12/476,738. |
Office Action mailed Nov. 14, 2011 in U.S. Appl. No. 12/502,277. |
Office Action mailed Jan. 20, 2012 in U.S. Appl. No. 12/502,277. |
Notice of Allowance mailed Jul. 10, 2012 in U.S. Appl. No. 12/502,277. |
Supplemental Notice of Allowability mailed Jul. 20, 2012 in U.S. Appl. No. 12/502,277. |
Office Action mailed Mar. 15, 2012 in U.S. Appl. No. 12/464,607. |
Notice of Allowance mailed Apr. 9, 2012 in U.S. Appl. No. 12/464,607. |
Notice of Allowance mailed Jul. 16, 2012 in U.S. Appl. No. 12/464,607. |
Office Action mailed Oct. 31, 2011 in U.S. Appl. No. 13/207,478. |
Office Action mailed Mar. 2, 2012 in U.S. Appl. No. 13/207,478. |
Notice of Allowance mailed Apr. 13, 2012 in U.S. Appl. No. 13/207,478. |
Supplemental Notice of Allowability mailed Jun. 29, 2012 in U.S. Appl. No. 13/207,478. |
Office Action mailed Dec. 5, 2011 in U.S. Appl. No. 13/182,474. |
Office Action mailed Apr. 27, 2012 in U.S. Appl. No. 13/182,474. |
Notice of Allowance mailed Jul. 18, 2012 in U.S. Appl. No. 13/182,474. |
NOtice of Reopening of Prosecution Due to Consideration of an Information Disclosure Statement Filed After Mailing of a Notice of Allowance mailed Oct. 10, 2012 in U.S. Appl. No. 13/182,474. |
Office Action mailed Jun. 1, 2001 in U.S. Appl. No. 09/460,540. |
Office Action mailed Dec. 1, 2001 in U.S. Appl. No. 09/460,540. |
Office Action mailed Mar. 15, 2002 in U.S. Appl. No. 09/460,540. |
Office Action mailed Jun. 18, 2002 in U.S. Appl. No. 09/460,540. |
Notice of Allowance mailed Oct. 21, 2002 in U.S. Appl. No. 09/460,540. |
Office Action mailed Jan. 16, 2007 in U.S. Appl. No. 11/013,842. |
Office Action mailed Jul. 16, 2008 in U.S. Appl. No. 11/013,842. |
Office Action mailed Jul. 30, 2007 in U.S. Appl. No. 11/013,842. |
Notice of Allowance mailed Nov. 26, 2008 in U.S. Appl. No. 11/013,842. |
Office Action mailed Oct. 13, 2006 in U.S. Appl. No. 10/922,750. |
Notice of Allowance mailed May 21, 2007 for U.S. Appl. No. 10/922,750. |
Supplemental Notice of Allowability mailed Jul. 3, 2007 for U.S. Appl. No. 10/922,750. |
Office Action mailed May 14, 2009 in U.S. Appl. No. 11/687,343. |
Office Action mailed Jan. 21, 2010 in U.S. Appl. No. 11/687,343. |
Notice of Allowance mailed May 18, 2010 in U.S. Appl. No. 11/687,343. |
Restriction Requirement mailed Aug. 4, 2010 in U.S. Appl. No. 12/196,815. |
Office Action mailed Oct. 27, 2010 in U.S. Appl. No. 12/196,815. |
Office Action mailed Nov. 17, 2010 in U.S. Appl. No. 12/196,815. |
Notice of Allowance mailed Jan. 27, 2011 in U.S. Appl. No. 12/196,815. |
Notice of Allowance mailed May 16, 2011 in U.S. Appl. No. 12/196,815. |
Office Action mailed Aug. 31, 2007 in U.S. Appl. No. 11/206,368. |
Office Action mailed Feb. 28, 2008 in U.S. Appl. No. 11/206,368. |
Pre-Appeal Conference Decision mailed Jun. 19, 2008 in U.S. Appl. No. 11/206,368. |
Notice of Allowance mailed Nov. 13, 2008 in U.S. Appl. No. 11/206,368. |
Office Action mailed Apr. 30, 2009 in U.S. Appl. No. 11/206,368. |
Notice of Allowance mailed Nov. 30, 2009 in U.S. Appl. No. 11/206,368. |
Office Action mailed Sep. 2, 2011 in U.S. Appl. No. 12/850,003. |
Notice of Allowance mailed Nov. 15, 2011 in U.S. Appl. No. 12/850,003. |
Office Action mailed May 3, 2010 in U.S. Appl. No. 11/924,273. |
Office Action mailed Oct. 14, 2010 in U.S. Appl. No. 11/924,273. |
Office Action mailed Feb. 2, 2011 in U.S. Appl. No. 11/924,273. |
Interview Summary mailed Feb. 16, 2011 in U.S. Appl. No. 11/924,273. |
Interview Summary mailed May 9, 2011 in U.S. Appl. No. 11/924,273. |
Notice of Allowance mailed Jun. 24, 2011 in U.S. Appl. No. 11/924,273. |
U.S. Appl. No. 13/652,508, filed Oct. 16, 2012 (46 pages). |
U.S. Appl. No. 13/652,503, filed Oct. 16, 2012 (26 pages). |
U.S. Appl. No. 13/632,178, filed Oct. 1, 2012 (51 pages). |
U.S. Appl. No. 13/646,857, filed Oct. 8, 2012 (36 pages). |
U.S. Appl. No. 13/646,854, filed Oct. 8, 2012 (38 pages). |
U.S. Appl. No. 13/647,419, filed Oct. 9, 2012 (35 pages). |
Nassau, K. Ph.D. and Julia Nassau, “The History and Present Status of Synthetic Diamond, Part I and II”, reprinted from The Lapidary Journal, Inc., vol. 32, No. 1, Apr. 1978; vol. 32, No. 2, May 1978, 15 pages. |
Specialty Metals, “Tungchip Dispenser, An improved feeder design, to allow for accurate delivery of Tungsten Carbide granules into the molten weld pool, generated by a MIG (GMAW) welding system”, (undated) 2 pages. |
Dynalloy Industries, G.M.A.C.E, 2003, printed Jul. 8, 2009, 1 page. |
Alloys International (Australasia) Pty. Ltd., “The Tungsten Carbide Vibratory Feeder System”, (undated) 6 pages. |
Dynalloy Industries, Hardhead Technology, Tungsten Carbide Pellets, 2003, printed Jul. 8, 2009, 1 page. |
Lincoln Electric, MIG Carbide Vibratory Feeder Assembly, (undated) 1 page. |
Wearshield Hardfacing Electrodes, Tungsten Carbide Products, (undated) 1 page. |
Postalloy, The best in hardfacing, Postle Industries, Inc., (undated) 13 pages. |
Postalloy, Postle Industries, Inc., Postalloy PS-98, Tungsten Matrix Alloy, (undated) 1 page. |
Postalloy, Data Sheet, Postle Industries, Inc., Postalloy 299-SPL, (undated) 1 page. |
Postalloy, Data Sheet, Postle Industries, Inc., Postalloy CP 63070, (undated) 1 page. |
Postalloy, Data Sheet, Postle Industries, Inc., Postalloy 14 TC, (undated) 1 page. |
Postalloy, Data Sheet, Postle Industries, Inc., Postalloy PS-98, A Tungsten Carbide Matrix Wire for Carbide Embedding, (undated) 1 page. |
Industrial Renewal Services, Steel BOC (Basic Oxygen Furnace) & BOP (Basic Oxygen Process) Hoods, printed Nov. 8, 2007, 2 pages. |
UWO Products, printed Nov. 8, 2007 from http://www.universalweld.com/products.htm, 2 pages. |
Shi et al., “Study on shaping technology of nanocrystalline WC-Co composite powder”, Rare Metal and Materials and Engineering, vol. 33, Suppl. 1, Jun. 2004, pp. 93-96. (English abstract). |
Haynes et al., “Physical Constants of Inorganic Compounds”, CRC Handbook of Chemistry and Physics, 93rd Edition, Internet Version 2013, downloaded May 15, 2013, 2 pages. |
“Percentage by Weight to Percentage by Volume Conversion Calculator”, Roseller Sunga, n.d., May 15, 2013, http://www.handymath.com/cgi-bin/dnstywtvol.cgi?sumit=Entry, 1 page. |
Office Action mailed Feb. 27, 2013 in U.S. Appl. No. 13/550,690. |
Office Action mailed Jan. 23, 2013 in U.S. Appl. No. 13/652,508. |
Office Action mailed Jul. 25, 2013 in U.S. Appl. No. 13/652,508. |
Office Action mailed Feb. 5, 2013 in U.S. Appl. No. 13/652,503. |
Office Action mailed Jul. 5, 2013 in U.S. Appl. No. 13/652,503. |
Restriction Requirement mailed Jan. 3, 2013 in U.S. Appl. No. 13/632,178. |
Office Action mailed Mar. 6, 2013 in U.S. Appl. No. 13/632,178. |
Office Action mailed May 22, 2013 in U.S. Appl. No. 13/487,323. |
Office Action mailed Jun. 28, 2012 in U.S. Appl. No. 13/222,324. |
Office Action mailed Jul. 11, 2012 in U.S. Appl. No. 13/222,324. |
Office Action mailed Nov. 6, 2012 in U.S. Appl. No. 13/222,324. |
Notice of Allowance mailed Jul. 1, 2013 in U.S. Appl. No. 11/167,811. |
Office Action mailed Nov. 16, 2012 in U.S. Appl. No. 12/397,597. |
Office Action mailed Jun. 20, 2013 in U.S. Appl. No. 12/397,597. |
Decision on Appeal mailed Jun. 3, 2013 in U.S. Appl. No. 10/903,198. |
Office Action mailed May 16, 2013 in U.S. Appl. No. 13/182,474. |
Notice of Allowance mailed Feb. 4, 2008 in U.S. Appl. No. 11/013,842. |
Notice of Allowance mailed Mar. 6, 2013 in U.S. Appl. No. 13/491,638. |
Number | Date | Country | |
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20130043615 A1 | Feb 2013 | US |
Number | Date | Country | |
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Parent | 11585408 | Oct 2006 | US |
Child | 13632177 | US |
Number | Date | Country | |
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Parent | 11167811 | Jun 2005 | US |
Child | 11585408 | US |