This application is based on and claims the benefit of priority from Japanese Patent Application Serial No. 2020-064762 (filed on Mar. 31, 2020), Japanese Patent Application Serial No. 2020-149825 (filed on Sep. 7, 2020) and Japanese Patent Application Serial No. 2021-034789 (filed on Mar. 4, 2021) the contents of which are hereby incorporated by reference in their entirety.
The present disclosure relates to a coil component.
A conventional coil component such as an inductor typically includes a magnetic base body made of a magnetic material, a coil conductor provided in the magnetic base body and wound around a coil axis, and an external electrode connected to an end portion of the coil conductor. A known material of the magnetic base body is a metal magnetic material formed of metal magnetic particles. Metal magnetic materials typically have a higher saturation magnetic flux density than ferrite materials and thus are suitable as materials for a magnetic base body of a coil component through which a large current flows. An example of such a coil component made of a metal magnetic material is disclosed in Japanese Patent Application Publication No. 2018-121023.
The magnetic base body made of a metal magnetic material has a higher saturation magnetic flux density but a lower insulation quality than a magnetic base body made of a ferrite material. In addition, heat treatment in the manufacturing process of the coil component may cause migration of the metal atoms included in the conductor, such that the metal atoms of the coil conductor disperse into the magnetic base body. Such migration of the metal atoms of the coil conductor may further reduce the insulation quality of the magnetic base body made of the metal magnetic material.
One object of the present invention is to provide a coil component less prone to migration of the metal atoms included in the coil conductor. Other objects of the present invention will be made apparent through the entire description in the specification.
A coil component according to one embodiment of the present invention comprises: a base body containing a plurality of metal magnetic particles; and a coil conductor provided in the base body so as to contact with the base body, wherein the base body has an insulating portion including a non-metal magnetic particle region defined by at least three of the plurality of metal magnetic particles in a sectional surface of the base body, and wherein in the insulating portion, an atomic percent of Si is highest among those of materials constituting the non-metal magnetic particle region other than oxygen. In one embodiment of the present invention, the coil conductor is wound around a coil axis.
In one embodiment of the present invention, at a geometric center of the non-metal magnetic particle region in a sectional surface thereof along the coil axis, an atomic percent of Si may be highest among those of the materials constituting the non-metal magnetic particle region other than oxygen. In one embodiment of the present invention, at a geometric center of the non-metal magnetic particle region in a sectional surface of the base body cut along a plane extending through the coil conductor, an atomic percent of Si may be highest among those of the materials constituting the non-metal magnetic particle region other than oxygen.
In one embodiment of the present invention, a surface of each of the plurality of metal magnetic particles may be coated with a coating layer containing Si, and a composition of a material of the coating layer may be different from a composition of the materials of the non-metal magnetic particle region at the geometric center.
In one embodiment of the present invention, the plurality of metal magnetic particles may be bonded to each other via the coating layer.
In one embodiment of the present invention, an atomic percent of Si in the non-metal magnetic particle region may be 50 at % to 95 at %.
In one embodiment of the present invention, the non-metal magnetic particle region may contain Fe, Cr, and/or Al.
In one embodiment of the present invention, the plurality of metal magnetic particles may be formed of an alloy containing Fe, Si, Cr, or Al.
In one embodiment of the present invention, the coil conductor may include a first conductor pattern and a second conductor pattern each extending along a planar direction perpendicular to the coil axis, and the first conductor pattern and the second conductor pattern may be separated from each other in a direction of the coil axis, and the insulating portion may be disposed between the first conductor pattern and the second conductor pattern.
In one embodiment of the present invention, the coil conductor may further comprise an external electrode provided on a surface of the base body and electrically connected to the coil conductor, and the insulating portion may be disposed between the coil conductor and the external electrode.
In one embodiment of the present invention, the coil conductor may be disposed in the insulating portion.
In one embodiment of the present invention, an entirety of the base body may be the insulating portion.
In one embodiment of the present invention, the insulating portion may be formed by heating a metal magnetic paste containing the plurality of metal magnetic particles and a silicon resin.
One embodiment of the present invention relates to a circuit board comprising any one of the above electronic components. One embodiment of the present invention relates to an electronic device comprising the above circuit board.
The present invention provides a coil component less prone to migration of the metal atoms included in the coil conductor.
Various embodiments of the present invention will be hereinafter described with reference to the accompanying drawings. The constituents common to multiple drawings are denoted by the same reference signs throughout the drawings. For convenience of explanation, the drawings are not necessarily drawn to scale.
The coil component 1 in the embodiment shown includes a laminated body (base body) 10 containing a plurality of metal magnetic particles, a coil conductor 25 disposed in the laminated body 10 and wound around a coil axis A, an external electrode 21 electrically connected to one end of the coil conductor 25, and an external electrode 22 electrically connected to the other end of the coil conductor 25. The laminated body 10 is a laminate of magnetic layers each made of a magnetic material. The coil conductor 25 includes conductor patterns C11 to C16. The conductor patterns C11 to C16 extend along the planar direction perpendicular to the coil axis A and are separated from each other in the direction of the coil axis A. Each of the conductor patterns C11 to C16 is electrically connected to adjacent conductor patterns through the vias V1 to V5. In this way, the coil conductor 25 is constituted by the conductor patterns C11 to C16 and the vias V1 to V5. The conductor pattern C11 is electrically connected to the external electrode 21, and the conductor pattern C16 is electrically connected to the external electrode 22.
As shown, in one embodiment of the present invention, the laminated body 10 is formed in a rectangular parallelepiped shape, for example. The laminated body 10 has a first principal surface 10e, a second principal surface 10f, a first end surface 10a, a second end surface 10c, a first side surface 10b, and a second side surface 10d. The outer surface of the laminated body 10 is defined by these six surfaces. The first principal surface 10e and the second principal surface 10f are opposed to each other, the first end surface 10a and the second end surface 10c are opposed to each other, and the first side surface 10b and the second side surface 10d are opposed to each other. In a case where the laminated body 10 is formed in a rectangular parallelepiped shape, the first principal surface 10e and the second principal surface 10f are parallel to each other, the first end surface 10a and the second end surface 10c are parallel to each other, and the first side surface 10b and the second side surface 10d are parallel to each other.
In the embodiment of
In this specification, a “length” direction, a “width” direction, and a “thickness” direction of the coil component 1 are referred to as an “L axis” direction, a “W axis” direction, and a “T axis” direction in
In one embodiment of the present invention, the coil component 1 has a length (the dimension in the direction of the L axis) of 0.2 to 6.0 mm, a width (the dimension in the direction of the W axis) of 0.1 to 4.5 mm, and a thickness (the dimension in the direction of the T axis) of 0.1 to 4.0 mm. These dimensions are mere examples, and the coil component 1 to which the present invention is applicable can have any dimensions that conform to the purport of the present invention. In one embodiment, the coil component 1 has a low profile. For example, the coil component 1 has a width larger than the thickness thereof.
The top cover layer 18 includes four magnetic layers 18a to 18d. The top cover layer 18 includes the magnetic layer 18a, the magnetic layer 18b, the magnetic layer 18c, and the magnetic layer 18d that are stacked in this order from the bottom to the top in
The bottom cover layer 19 includes four magnetic layers 19a to 19d. The bottom cover layer 19 includes the magnetic layer 19a, the magnetic layer 19b, the magnetic layer 19c, and the magnetic layer 19d that are stacked in this order from the top to the bottom in
The magnetic layers 11 to 16 constituting the body portion 20, the magnetic layers 18a to 18d constituting the top cover layer 18, and the magnetic layers 19a to 19d constituting the bottom cover layer 19 include metal magnetic particles and an insulating resin material. Metal magnetic particles applicable to the present invention are made of a material in which magnetism is developed in an unoxidized metal portion, and such metal magnetic particles are, for example, particles including unoxidized metal particles or alloy particles. Magnetic particles applicable to the present invention include, for example, Fe and at least one of Al and Mn as an alloy component. Materials of the magnetic particles applicable to the present invention may be particles of, for example, a Fe—Si—Cr—Al, Fe—Si—Cr—Mn, Fe—Si—Al, Fe—Si—Mn, or Fe—Ni alloy, a Fe—Si—Cr—B—C or Fe—Si—B—Cr amorphous alloy, Fe, or a mixture thereof. The resin material contained in the magnetic layers will be described later.
The coil component 1 can include any number of magnetic layers as necessary in addition to the magnetic layers 11 to 16, the magnetic layers 18a to 18d, and the magnetic layers 19a to 19d. Some of the magnetic layers 11 to 16, the magnetic layers 18a to 18d, and the magnetic layers 19a to 19d can be omitted as appropriate.
The magnetic layers 11 to 16 have corresponding conductor patterns C11 to C16 embedded therein, respectively. Before the magnetic layers 11 to 16 are stacked together, the top-side surfaces of the conductor patterns C11 to C16 are exposed at the top-side surfaces of the magnetic layers 11 to 16, respectively. The conductor patterns C11 to C16 extend around the coil axis A. In the embodiment shown, the coil axis A extends in the T axis direction, which is the same as the lamination direction of the magnetic layers 11 to 16.
The magnetic layers 11 to 15 are provided with vias V1 to V5, respectively, at predetermined locations therein. The vias V1 to V5 are formed by forming a through-hole at the predetermined location in the magnetic layers 11 to 15 so as to extend through the magnetic layers 11 to 15 in the T axis direction and then filling the through-holes with a metal material.
The conductor patterns C11 to C16 and the vias V1 to V5 are formed to contain a metal having an excellent electrical conductivity, such as Ag, Pd, Cu, or Al, or any alloy of these metals.
In one embodiment, the external electrode 21 is provided on the first end surface 10a of the laminated body 10, and the external electrode 22 is provided on the second end surface 10c of the laminated body 10. As shown, the external electrode 21 and the external electrode 22 may extend onto the top surface 10e, the bottom surface 10f, the first side surface 10b, and the second side surface 10d of the laminated body 10. In this case, the external electrode 21 covers the entirety of the first end surface 10a and a part of each of the top surface 10e, the bottom surface 10f, the first side surface 10b, and the second side surface 10d of the laminated body 10, and the external electrode 22 covers the entirety of the second end surface 10c and a part of each of the top surface 10e, the bottom surface 10f, the first side surface 10b, and the second side surface 10d of the laminated body 10. The shapes of the external electrode 21 and the external electrode 22 are not particularly limited and can be adjusted as appropriate. For example, the external electrode 21 may be L-shaped and cover a part of each of the first end surface 10a and the bottom surface 10f, or it may be plate-shaped and cover a part of the bottom surface 10f. Likewise, the external electrode 22 may be L-shaped and cover a part of each of the second end surface 10c and the bottom surface 10f, or it may be plate-shaped and cover a part of the bottom surface 10f.
Next, with reference to
In one or more embodiments of the present invention, the laminated body 10 includes the insulating portion 30 that forms at least a part of the laminated body 10. The laminated body 10 may be entirely formed of the insulating portion 30. In the embodiment shown in
The magnetic layers of the laminated body 10 are formed of a metal magnetic paste containing the metal magnetic particles and the insulating resin material. The metal magnetic paste used for the magnetic layers 11 to 16, 18a, 19a constituting the insulating portion 30 contains a silicon resin as the resin material. The proportion of the silicon resin in the metal magnetic paste may be, for example, 5 vol % to 50 vol %. For the metal magnetic paste used for the magnetic layers not constituting the insulating portion 30 (the magnetic layers 18b to 18d, 19b to 19d in this embodiment), examples of the resin material contained in this metal magnetic paste include a polyvinyl butyral (PVB) resin, an ethyl cellulose resin, a polyvinyl alcohol resin, and an acrylic resin. The resin material used for the magnetic layers 18b to 18d, 19b to 19d not constituting the insulating portion 30 may be a highly insulating thermosetting resin. Examples of this thermosetting resin include an epoxy resin, a polyimide resin, a polystyrene (PS) resin, a high-density polyethylene (HDPE) resin, a polyoxymethylene (POM) resin, a polycarbonate (PC) resin, a polyvinylidene fluoride (PVDF) resin, a phenolic resin, a polytetrafluoroethylene (PTFE) resin, or a polybenzoxazole (PB 0) resin.
As shown in
The proportion of Si in each non-metal magnetic particle region R2 is based on the geometric center C of the non-metal magnetic particle region R2 as viewed in the sectional surface thereof along the coil axis A. At the geometric center C of the non-metal magnetic particle region R2 as viewed in the sectional surface thereof along the coil axis A, the atomic percent of Si is the highest among those of the materials other than oxygen. The proportion of Si is measured by, for example, EDS (energy dispersive X-ray spectroscopy) analysis.
The surface of each metal magnetic particle 31 may be coated with a coating layer 32. The coating layer 32 may be, for example, an oxide film formed of oxidized surface of the metal magnetic particle 31, a coating film containing Si, or a coating film containing an element other than Si. The oxide film and the coating film may be insulating films. The metal magnetic particles 31 are bonded to each other via the coating layers 32. When the coating layer 32 is formed on the surface of the metal magnetic particle 31, the coating layer 32 is a part of the metal magnetic particle 31 and is included in the metal magnetic particle region R1. The composition of the material of the coating layer 32 may be different from the composition of the materials of the non-metal magnetic particle region R2 at the geometric center C.
Next, a description is given of an example of a method of manufacturing the coil component 1. The first step is to form a top laminate, an intermediate laminate, and a bottom laminate. The top laminate will constitute the top cover layer 18, and the bottom laminate will constitute the bottom cover layer 19. The top laminate is formed by stacking together a plurality of magnetic sheets that are to be the magnetic layers 18a to 18d. Likewise, the bottom laminate is formed by stacking together a plurality of magnetic sheets that are to be the magnetic layers 19a to 19d. These magnetic sheets are formed by, for example, applying a metal magnetic paste to a surface of a plastic base film, drying the metal magnetic paste, and cutting the dried metal magnetic paste to a predetermined size. The metal magnetic paste is formed of, for example, a resin material containing metal magnetic particles mixed with a solvent. The magnetic sheets to be the magnetic layers constituting the insulating portion 30 (the magnetic layers 11 to 16, 18a, 19a in the embodiment shown) are formed using a silicon resin as the resin material. The resin material used in the magnetic sheets to be the magnetic layers not constituting the insulating portion 30 (the magnetic layers 18b to 18d, 19b to 19d in the embodiment shown) may be, for example, a polyvinyl butyral (PVB) resin, an epoxy resin, or any other resin materials having an excellent insulation quality.
The intermediate laminate is formed by stacking together a plurality of sheets each including a conductor pattern, a magnetic layer, and an insulator. In producing each sheet, a green sheet is first formed on a base film. The green sheet has a through-hole extending through the green sheet in the lamination direction and configured to receive a via formed therein. Next, the conductor pattern is formed on the green sheet by screen printing or any other method. At this time, the metal material that forms the conductor pattern is filled into the through-hole to form the via. The magnetic layer is then printed where the conductor pattern is not formed. After the sheets including the conductor patterns C11 to C16 are formed, the base film is removed, and the sheets are stacked together in the order from the sheet including the conductor pattern C16 to the sheet including the conductor pattern C11. Since there is no conductor pattern below the conductor pattern C16, the sheet including the conductor pattern C16 may not have a through-hole for forming the via.
Next, the intermediate laminate formed in the above-described manner is sandwiched between the top laminate on the top side and the bottom laminate on the bottom side, and the top laminate and the bottom laminate are bonded to the intermediate laminate by thermal compression to obtain a body laminate. Next, the body laminate is diced into pieces of a desired size using a cutter such as a dicing machine or a laser processing machine to obtain chip laminates corresponding to the laminated body 10. Next, the chip laminate is degreased and then heated at a predetermined temperature. This heat treatment causes the silicon resin contained in the metal magnetic paste to be thermally decomposed into a Si oxide that is filled into the non-metal magnetic particle regions R2 in the insulating portion 30. When the metal magnetic particles contain at least one of Al and Mn as an alloy component, the heat treatment produces at least one of Al oxide and Mn oxide that fills the non-metal magnetic particle regions R2 in the insulating portion 30. In this way, the non-metal magnetic particle regions R2 may contain the Si oxide and at least one of Al oxide and Mn oxide mixed together. Since the metal magnetic particles contain at least one of Al and Mn, the voids of the non-metal magnetic particle regions R2 can be reduced as compared to the case where the metal magnetic particles do not contain Al or Mn. Further, since at least one of Al oxide and Mn oxide is present in the non-metal magnetic particle regions R2, adjacent metal magnetic particles can be bound firmly to each other to increase the mechanical strength of the base body 10. Following the heat treatment, a conductive paste is applied to the both end portions of the chip laminate to form the external electrode 21 and the external electrode 22. The coil component 1 is thus obtained.
Next, another embodiment of the invention will be described with reference to
Next, another embodiment of the invention will be described with reference to
Next, another embodiment of the invention will be described with reference to
Next, another embodiment of the invention will be described with reference to
Next, another embodiment of the invention will be described with reference to
The coil conductor 125 is positioned so as to be enclosed in the insulating portion 30 of the laminated body 10. The coil conductor 125 is provided in the laminated body 10 so as to contact with the insulating portion 30. The coil conductor 125 is exposed at one end thereof to the outside of the magnetic base body 10 through the first end surface 10c and is connected to the external electrode 21 at the one end. The coil conductor 125 is also exposed at the other end thereof to the outside of the magnetic base body 10 through the second end surface 10d and is connected to the external electrode 22 at the other end. In this manner, the coil conductor 125 is connected at one end thereof to the external electrode 21 and connected at the other end thereof to the external electrode 22.
The coil conductor 125 extends linearly from the external electrode 21 to the external electrode 22 in plan view (as viewed from the T axis). Stated differently, the coil conductor 125 has no separate parts facing each other in the laminated body 10 in a plan view. Herein, when the coil conductor 125 has no separate parts facing each other in the laminated body 10 in a plan view, this can mean the coil conductor 125 extends linearly from the external electrode 21 to the external electrode 22. In the embodiment shown, the coil conductor 125 has a rectangular parallelepiped shape. The coil conductor 125 may be formed by only a single conductor pattern or by a plurality of conductor patterns electrically insulated from each other in the laminated body 10. When the coil conductor 125 is formed by a plurality of conductor patterns, these conductor patterns have the same shape, and adjacent ones of the conductor patterns are separated from each other by a part of the insulating portion 30 of the laminated body 10.
In the embodiment shown in
The shape of the coil conductor 125 is not limited to the illustrated. As shown in
In one or more embodiments of the present invention, the laminated body 10 of the coil component has the insulating portion 30 that includes the non-metal magnetic particle regions R2 each defined by at least three metal magnetic particles 31, and the atomic percent of Si is the highest among those of the materials constituting the non-metal magnetic particle regions R2 other than oxygen. In conventional coil components, the resin contained in the metal magnetic paste is thermally decomposed into carbon dioxide and others by the heat treatment in the manufacturing process, and therefore, voids are formed in the regions each defined by a plurality of metal magnetic particles (corresponding to the non-metal magnetic particle regions R2). Presence of such voids encourages the metal magnetic particles to contact with oxygen and thus encourages oxidation of Fe, Si, Cr and the like contained in the metal magnetic particles. As a result, ionizable substances contained in the metal material of the coil conductor are encouraged to receive electrons, which may cause migration of the metal atoms in the coil conductor. By contrast, in the coil component 1 according to one embodiment of the present invention, the Si oxide is present in the non-metal magnetic particle regions R2, as described above. This is because a silicon resin is used as the resin contained in the metal magnetic paste and, when the silicon resin is thermally decomposed by the heat treatment, the Si component contained in the silicon resin remains after the thermal decomposition and oxidizes to form the Si oxide. Since the Si oxide is present in the non-metal magnetic particle regions R2, less voids are formed by the heat treatment, and thus the oxidation of Fe, Si, Cr and the like contained in the metal magnetic particles is inhibited. Therefore, the metal atoms of the coil conductor 25 can be inhibited from migrating by the heat treatment.
In one or more embodiments of the present invention, the migration of the metal atoms of the coil conductor 25 may occur when the metal atoms move in the non-metal magnetic particle regions R2 by application of a voltage to the coil component 25. In the coil component 1 according one embodiment of the present invention, it is inhibited that the voids are formed in the non-metal magnetic particle regions R2 of the insulating portion 30, and therefore, even after the coil component 1 is mounted on a circuit board, the metal atoms of the coil conductor 25 are inhibited from migrating by application of the voltage.
In one or more embodiments of the present invention, the coil conductor 25 is provided in the insulating portion 30. With this arrangement, the migration of the metal materials of the coil conductor 25 can be inhibited between any two of the conductor patterns C11 to C16 of the coil conductor 25 and between the coil conductor 25 and the external electrodes 21, 22. Accordingly, it is more secure that short circuits are inhibited from occurring in the coil component 1.
In one or more embodiments of the present invention, the insulating portion 30 is formed by heating a metal magnetic paste containing the metal magnetic particles 31 and the silicon resin. Since the silicon resin can be more easily fed into gaps between the metal magnetic particles 31 as compared to Si oxide particles, the filling factor of the Si oxide in the non-metal magnetic particle regions R2 can be increased. Therefore, the metal atoms of the coil conductor 25 can be more effectively inhibited from migrating by the heat treatment.
In one or more embodiments of the present invention, the coil conductor 25 includes the conductor patterns C11 to C16 extending along the planar direction perpendicular to the coil axis A and separated from each other in the direction of the coil axis A, and the insulating portion 30 may be provided between adjacent ones of the conductor patterns C11 to C16. With this arrangement, the migration of the metal materials of the coil conductor 25 can be inhibited between adjacent ones of the conductor patterns C11 to C16.
In one or more embodiments of the present invention, the coil component further includes the external electrodes 21, 22 provided on the surface of the laminated body 10 and electrically connected to the coil conductor 25, and the insulating portion 30 may be provided between the coil conductor 25 and the external electrode 21, 22. With this arrangement, the migration of the metal materials of the coil conductor 25 can be inhibited between the coil conductor 25 and the external electrodes 21, 22.
In one or more embodiments of the present invention, the metal magnetic particles 31 may contain Al. With this arrangement, the metal magnetic particles 31 tends to have a thick coating layer 32, and therefore, the gaps of the non-metal magnetic particle regions R2 defined by the metal magnetic particles 31 are smaller. Accordingly, narrower paths are left for movement of the metal elements constituting the coil conductor 25 that are ionized, and thus the migration of the metal elements can be inhibited.
In one or more embodiments of the present invention, the metal magnetic particles 31 may contain Cr. Since Cr inhibits oxidation of Fe contained in the metal magnetic particles 31, the metal elements of the coil conductor 25 can be inhibited from ionizing due to oxidation of Fe. Therefore, the metal materials of the coil conductor 25 can be inhibited from migrating.
The dimensions, materials, and arrangements of the constituent elements described for the above various embodiments are not limited to those explicitly described for the embodiments, and these constituent elements can be modified to have any dimensions, materials, and arrangements within the scope of the present invention. Furthermore, constituent elements not explicitly described herein can also be added to the above-described embodiments, and it is also possible to omit some of the constituent elements described for the embodiments.
For example, as to the various examples of the positions of the insulating portion 30 represented by the above embodiments, it is only required that the insulating portion 30 is provided in at least a part of the laminated body 10, and the position of the insulating portion 30 is not limited to those in the above embodiments.
Number | Date | Country | Kind |
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2020-064762 | Mar 2020 | JP | national |
2020-149825 | Sep 2020 | JP | national |
2021-034789 | Mar 2021 | JP | national |