The present application claims a priority on the basis of Japanese patent application No. 2022-013251 filed on Jan. 31, 2022, which is incorporated herein by reference in its entirety.
The present disclosure relates to a coil device in which an exterior body covers a coil and a method for manufacturing the same.
A coil device in which an exterior body covers a columnar portion and a coil as shown in, for example, Patent Document 1 is known as a coil device used as an inductor or the like. The exterior body can cover the columnar portion by various molding techniques, such as dry molding, injection molding, transfer molding, and compression molding. When these molding techniques are used, a core having the coil disposed around the columnar portion is placed in a cavity, and the cavity is filled with an exterior material including magnetic particles and a resin. Filling the cavity with the exterior material so that the coil is covered with the exterior material and then compressing and hardening the material can manufacture the coil device in which the exterior body covers the coil.
A coil device according to one aspect of the present disclosure includes:
a coil;
a T-shaped core including a columnar portion around which the coil is disposed and a flange formed at a first end of the columnar portion in an axial direction thereof; and
an exterior body covering the coil and the columnar portion and made of an exterior material including magnetic particles and a resin; in which
the core is provided with a recess including at least one of a first recess or a second recess;
the first recess extends between the first end and a second end of the columnar portion in the axial direction; and
the second recess extends from an inner side towards an outer side of the flange.
A method of manufacturing a coil device according to one aspect of the present disclosure includes:
preparing a T-shaped core having a recess extending from a columnar portion of the core to a flange formed at a first end of the columnar portion in an axial direction thereof;
disposing a coil around the columnar portion;
disposing the core with the coil in a cavity so that the flange abuts a bottom of the cavity;
filling the cavity with an exterior material including magnetic particles and a resin so that part of the exterior material flows into the recess; and
compressing the exterior material.
Hereinafter, the present disclosure will be explained based on embodiments shown in the drawings.
A coil device 1 of a first embodiment shown in
The coil device 1 includes a coil 10, a core 20, and an exterior body 30. As shown in
Examples of the magnetic particles (magnetic material) forming the core 20 include ferrite particles and metal magnetic particles. Examples of the ferrite particles include Ni—Zn based ferrite and Mn—Zn based ferrite. The metal magnetic particles are not limited. Examples of the metal magnetic particles include an Fe—Ni alloy powder, an Fe—Si alloy powder, an Fe—Si—Cr alloy powder, an Fe—Co alloy powder, an Fe—Si—Al alloy powder, and amorphous iron. The resin forming the core 20 is not limited. Examples of the resin include an epoxy resin, a phenol resin, a polyester resin, a polyurethane resin, a polyimide resin, other synthetic resins, and other non-magnetic materials.
The core 20 includes a columnar portion 21 and a flange 22. The columnar portion 21 has a substantially cylindrical shape and is formed on an upper surface 220 of the flange 22. An axial direction of the columnar portion 21 corresponds to the Z-axis direction. Around the columnar portion 21, the coil 10 shown in
The flange 22 is formed at a first end 21a of the columnar portion 21 in its axial direction (the Z-axis direction). In the present embodiment, unlike a drum core, the flange 22 is formed only at the first end 21a of the columnar portion 21, and no flange is formed at a second end 21b of the columnar portion 21. The flange 22 has a disc shape having a predetermined thickness in the Z-axis direction. Although the flange 22 has a circular shape when viewed from below, the flange 22 may have a polygonal shape (e.g., a rectangular shape) as shown in
As shown in
As shown in
The wire 11 is not limited to a round wire and may be, for example, a rectangular wire, a square wire, or a litz wire. For example, the coil 10 may be an air core coil including a crosswise wound rectangular wire or an edgewise wound rectangular wire. Although the number of layers of the coil 10 in its radial direction is two as shown in
As shown in
Although part of the exterior body 30 is positioned at surroundings of the flange 22 (e.g., lateral sides of the flange 22), the exterior body 30 may be formed so that the exterior body 30 as a whole is substantially disposed above the upper surface 220 of the flange 22 as shown in
Although the magnetic particles (magnetic material) forming the exterior body 30 are the same as the above-mentioned magnetic particles (magnetic material) forming the core 20, these magnetic particles (magnetic materials) may be different types. The magnetic particles forming the exterior body 30 may have a size of 1 to 50 μm or 1 to 20 μm. Although the resin forming the exterior body 30 is the same as the above-mentioned resin forming the core 20, these resins may be different types.
The exterior body 30 and the core 20 may have different relative permeability. For example, the exterior body 30 may be composed of a material having smaller relative permeability than the core 20. The relative permeability of the exterior body 30 is not limited and is, for example, 1 to 20,000. The same applies to the core 20.
The core 20 (the columnar portion 21 and/or the flange 22) and the exterior body 30 may have different thermal expansion coefficients. For example, the thermal expansion coefficient of the core 20 (the columnar portion 21 and/or the flange 22) may be smaller than that of the exterior body 30.
For example, the thermal expansion coefficient of the columnar portion 21 is 10 ppm/K, and the thermal expansion coefficient of the exterior body 30 is 15 ppm/K. The difference between the thermal expansion coefficients of the columnar portion 21 and the exterior body 30 may be 2 ppm or more or may be 5 ppm or more. This structure allows for prevention of cracks of the exterior body 30 covering the columnar portion 21 due to the thermal expansion coefficient of the columnar portion 21.
Examples of methods of making the thermal expansion coefficient of the columnar portion 21 smaller than that of the exterior body 30 include heating of the columnar portion 21. When the columnar portion 21 includes the magnetic particles and the resin, heating the columnar portion 21 can reduce the content ratio of the resin to reduce the thermal expansion coefficient of the columnar portion 21.
In some embodiments, the core 20 may be made of a material (magnetic particles) different from the exterior body 30 to make the thermal expansion coefficient of the columnar portion 21 smaller than that of the exterior body 30. Alternatively, when the core 20 and the exterior body 30 both include the magnetic particles and the resin, a mixing ratio of the resin in the core 20 may be smaller than a mixing ratio of the resin in the exterior body 30 to make the thermal expansion coefficient of the columnar portion 21 smaller than that of the exterior body 30.
As shown in
As shown in
The first electrode 51 and the second electrode 52 are each composed of, for example, a multilayer electrode film including a base electrode film and a plating film formed thereon. Examples of the base electrode film include a conductive paste film containing metal (e.g., Sn, Ag, Ni, and Cu) and their alloy. Examples of the plating film include metal (e.g., Sn, Au, Ni, Pt, Ag, and Pd) and their alloy. The first electrode 51 and the second electrode 52 each have a thickness of, for example, 3 to 100 μm.
As shown in
In some embodiments, the shapes of the first electrode 51 and the second electrode 52 are not limited to the shape (sheet shape) shown in the drawings and may be changed as appropriate. For example, part of the first electrode 51 may be formed on the side (front) of the exterior body 30, and the first lead-out portion 11a and the first electrode 51 may be connected at the front of the exterior body 30. Similarly, part of the second electrode 52 may be formed on the side (front) of the exterior body 30, and the second lead-out portion 11b and the second electrode 52 may be connected at the front of the exterior body 30.
As shown in
As explained above, the exterior body 30 is formed by, for example, pouring the exterior material into the cavity of the mold where the core 20 is placed and compressing and hardening the material. Because it is difficult for the exterior material (particularly the magnetic particles) to enter the spaces G1 and G2 from an outer side of the coil 10 when the coil 10 is disposed around the columnar portion 21, an air gap may be formed in the spaces G1 and G2 unless a measure is taken.
Because the air gap has lower permeability than the exterior material does, formation of the air gap is a factor in relative reduction of magnetic properties of the coil device 1. Thus, in terms of improving the magnetic properties, it is desirable that formation of the air gap in the spaces G1 and G2 should be prevented. The air gap also reduces adhesion between the coil 10 and the columnar portion 21 to become a factor in misalignment of the coil 10 with respect to the columnar portion 21 or reduction of yield of the coil device 1 due to the misalignment. Thus, also in terms of improving the yield of the coil device 1, it is desirable that formation of the air gap in the spaces G1 and G2 should be prevented. Therefore, in the present embodiment, the two recesses 40 are formed on the surface of the core 20 as shown in
Each of the two recesses 40 extends in a substantially L shape and is formed from the columnar portion 21 to the flange 22. One recess 40 and the other recess 40 may have 180-degree rotational symmetry with respect to the axis of the columnar portion 21 or the winding axis of the coil 10 (
The first recess 41 is formed on the outer peripheral surface 210 of the columnar portion 21 and extends from the second end 21b to the first end 21a of the columnar portion 21 along the axial direction of columnar portion 21 and the winding axis direction of the coil 10 (
As shown in
As shown in
At the second end 21b of the columnar portion 21, upper ends of the respective recesses 40 (first recesses 41) in the Z-axis direction are open ends. At a side surface 222 of the flange 22, outer ends of the respective recesses 40 (second recesses 42) in the radial direction are open ends. Because the flange 22 is not formed at the second end 21b of the columnar portion 21 of the coil device 1 of the present embodiment, neither end of the recesses 40 is blocked. The recesses 40 thus function as a passage where the exterior material forming the exterior body 30 flows when the exterior body 30 is molded as explained above. Thus, the exterior material can be guided into the recesses 40 from the upper ends of the first recesses 41 in the Z-axis direction.
For example, at the time of molding the exterior body 30, by placing the core 20 in the cavity in the same direction as the core 20 shown in the drawings (i.e., so that a lower surface 221 of the flange 22 abuts the bottom of the cavity) and filling the cavity with the exterior material having fluidity, part of the exterior material flows into the first recesses 41 through the upper ends of the first recesses 41 in the Z-axis direction. The exterior material that has flowed into the first recesses 41 flows into the second recesses 42 and then out of the second recesses 42 through the outer ends of the second recesses 42 in the radial direction.
In a process in which the exterior material flows inside the first recesses 41 and the second recesses 42, part of the exterior material that has flowed into the first recesses 41 overflows the first recesses 41 (particularly, outwards in the radial direction of the columnar portion) and enters the space G1 (particularly, the space G1 in the vicinity of the first recesses 41) shown in
As a result, as shown in
In the present embodiment, the spaces G1 and G2 can be filled with the exterior material not only from the outer side of the coil 10 but also from an inner side of the coil 10 (between the inner peripheral surface 10b of the coil 10 and the outer peripheral surface 210 of the columnar portion 21, or between the bottom surface 10a of the coil 10 and the upper surface 220 of the flange 22). When the coil 10 is an air core coil, a clearance may be inevitably formed between the outer peripheral surface 210 of the columnar portion 21 and the inner peripheral surface 10b of the coil 10 in manufacturing, which may reduce adhesion between the outer peripheral surface 210 of the columnar portion 21 and the inner peripheral surface 10b of the coil 10. In the present embodiment, the exterior material can also flow into such a clearance through the first recesses 41 from the inner side of the coil 10.
Once the cavity is filled with a certain amount or more of the exterior material, the exterior material that has flowed into the recesses 40 does not readily flow any more. Thus, the recesses 40 are filled with the exterior material, and the exterior material hardens inside the recesses 40. Consequently, at the first recesses 41, the outer peripheral surface 210 of the columnar portion 21 and the inner peripheral surface 10b of the coil 10 are joined by the exterior material inside the first recesses 41. Similarly, at the second recesses 42, the upper surface 220 of the flange 22 and the bottom surface 10a of the coil 10 are joined by the exterior material inside the second recesses 42.
As shown in
A ratio W/L may be 1/32 to ¼ or 1/8 to 1/4, where W is the width of the recesses 40 in the direction orthogonal to the extending direction and L is the length (diameter) of the columnar portion 21 in its radial direction. In this case, a sufficient amount of the exterior material can flow into the recesses 40, and a sufficient amount of the exterior material can flow into the spaces G1 and G2 through the recesses 40.
The spaces G1 and G2 shown in
The recesses 40 have a depth D, shown in
The coil device 1 is manufactured, for example, using the following method. First, the core 20 shown in
Next, the core 20 is placed in the cavity of the mold, and the cavity is filled with the exterior material. At this time, the core 20 is disposed in the cavity of the mold so that the lower surface 221 (
Next, as shown in
In some embodiments, a plurality of sections (rooms) may be formed in the cavity used in the above-mentioned method of manufacturing the coil device 1, and a plurality of cores 20 may be placed in the respective sections. In this case, the sections may be filled with the exterior material separately, and the exterior material in each section may be compressed and hardened separately, so that the exterior material does not connect the cores 20 when the cavity is filled with the exterior material. This can give a plurality of molded bodies, i.e. the cores 20 each covered with the exterior body 30.
Alternatively, the cavity may be entirely filled with the exterior material, and the exterior material may be compressed and hardened, so that the exterior material connects the cores 20. This can give one molded body, i.e. the cores 20 collectively covered with the exterior body 30. In this case, cutting the molded body with a dicer to singulate it into elements can give molded bodies, i.e. the cores 20 each covered with the exterior body 30.
As explained above, the coil device 1 of the present embodiment includes the substantially T-shaped core 20 having the flange 22 at the first end 21a of the columnar portion 21 in its axial direction as shown in
When transfer molding is used to cover the columnar portion 21 and the coil 10 with the exterior body 30, provided that the core 20 is substantially T-shaped (provided that the flange 22 is formed only at one side of the columnar portion 21 in its axial direction), the exterior material inside the cavity can have improved fluidity and smoothly flow in the surrounding area of the coil 10.
In the present embodiment, the volume of the exterior body 30 can be increased by the amount of the exterior material that has flowed into the spaces G1 and G2 shown in
In particular, when an air core coil is disposed around the columnar portion 21 in the process of manufacturing the coil device 1, the space G1 is readily formed between the outer peripheral surface 210 of the columnar portion 21 and the inner peripheral surface 10b of the coil 10. Even under such conditions in which the space G1 is readily formed, in the coil device 1 of the present disclosure, filling the recesses 40 (the first recesses 41) with part of the exterior material allows the space G1 to be filled and various defects caused by formation of the air gap in the space G1 to be prevented.
Moreover, because the inner wall 400 of each recess 40 is curved as shown in
The second recesses 42 are interconnected with the respective first recesses 41 at the first end 21a of the columnar portion 21. Thus, part of the exterior material that has flowed into the first recesses 41 flows into the second recesses 42, and part of the exterior material that has flowed into the second recesses 42 flows into the space G2 between the upper surface 220 of the flange 22 and the bottom surface 10a of the coil 10. This enables a sufficient amount of the exterior material to flow into the second recesses 42, allowing the space G2 between the upper surface 220 of the flange 22 and the bottom surface 10a of the coil 10 to be effectively filled with the exterior material to effectively prevent formation of the air gap in the space G2.
In using the method of manufacturing the coil device 1 of the present disclosure, part of the exterior material flows into the recesses 40 when the exterior material is poured into the cavity. Thus, the space G1 between the outer peripheral surface 210 of the columnar portion 21 and the inner peripheral surface 10b of the coil 10 and the space G2 between the upper surface 220 of the flange 22 and the bottom surface 10a of the coil 10 can be filled with the exterior material to prevent formation of the air gap in the spaces G1 and G2 and improve adhesion between the coil 10 and the columnar portion 21. This can improve the magnetic properties and yield of the coil device 1. Also, because the core 20 is substantially T-shaped, not only is it easy to form the exterior body 30 covering the coil 10, but also part of the exterior material can easily flow into the recesses 40 without being obstructed by the flange 22 when the cavity is filled with the exterior material.
A coil device 1A of a second embodiment shown in
As shown in
The present embodiment can also achieve the same effects as in the first embodiment. Additionally, in the present embodiment, the shape of the inner wall 400A allows for a larger volume of the recesses 40A than the recesses 40 of the first embodiment. Thus, the amount of the exterior material that flows in the recesses 40A can be increased to let the exterior material efficiently flow into the spaces G1 and G2 (
A coil device 1B of a third embodiment shown in
As shown in
The present embodiment can also achieve the same effects as in the second embodiment. Additionally, in the present embodiment, because the inner wall 400B includes the angled portions, the surface area of the inner wall 400B can be larger than that of the recesses 40A of the second embodiment. Thus, bonding strength between the exterior material with which the recesses 40B are filled and the inner wall 400B can be increased, which can prevent peeling defects of the exterior body 30 (
Moreover, because the inner wall 400B includes the angled portions having the shape shown in
A coil device 1C of a fourth embodiment shown in
As shown in
The present embodiment can also achieve the same effects as in the second embodiment. Additionally, in the present embodiment, because the inner wall 400C of each recess 40C includes the angled portions having the shape shown in
In some embodiments, in terms of ensuring moldability, it may be that only the inner wall 400C of the first recess 41C has the angled portions shown in
A coil device 1D of a fifth embodiment shown in
As shown in
The present embodiment can also achieve the same effects as in the fourth embodiment. Additionally, in the present embodiment, because the inner wall 400D is curved, fluidity of the exterior material that flows inside the recesses 40D is readily ensured, and the exterior material (particularly the magnetic particles) can be efficiently transferred through the recesses 40D into the spaces G1 and G2 (
In some embodiments, in terms of ensuring moldability, it may be that only the inner wall 400D of the first recess 41D has the curved shape shown in
A coil device 1E of a sixth embodiment shown in
As shown in
Each third recess 43 extends along the circumferential direction of the columnar portion 21. This extending direction is substantially the same as the winding direction of the coil 10 (
At any location between the first end 21a and the second end 21b of the columnar portion 21, the third recesses 43 are connected to the first recesses 41A. Although the third recesses 43 are connected to the first recesses 41A at a central part of the columnar portion 21 in the Z-axis direction in the present embodiment, the third recesses 43 may be connected to the first recesses 41A at a location above or below the central part.
Although the third recess 43 of one recess 40E connects the first recess 41A of one recess 40E and the first recess 41A of the other recess 40E, the third recess 43 may be connected to only the first recess 41A of the one recess 40E. Although the third recess 43 of the other recess 40E connects the first recess 41A of the one recess 40E and the first recess 41A of the other recess 40E, the third recess 43 may be connected to only the first recess 41A of the other recess 40E. That is, each recess 40E may include one first recess 41A, one second recess 42A, and one third recess 43.
Although the number of the third recesses 43 formed on the outer peripheral surface 210 of the columnar portion 21 is two, three or more third recess 43 may be formed. The third recesses and the first recesses 41A may be formed on the outer peripheral surface 210 so as to intersect in a lattice pattern.
The present embodiment can also achieve the same effects as in the second embodiment. Additionally, in the present embodiment, part of the exterior material that has flowed into the first recesses 41A flows into the third recesses 43, and part of the exterior material that has flowed into the third recesses 43 outflows outside the third recesses 43 into the space G1 (
A coil device 1F of a seventh embodiment shown in
As shown in
One first recess 41F (the one interconnected with the second recess 42A in the positive direction of the Y-axis) spirals down counterclockwise about halfway around the outer peripheral surface of the columnar portion 21 from its end in the negative direction of the Y-axis to its end in the positive direction of the Y-axis. The location of the upper end of this first recess 41F corresponds to the location of the second recess 42A in the negative direction of the Y-axis, and the upper end is located directly above this second recess 42A.
The other first recess 41F (the one interconnected with the second recess 42A in the negative direction of the Y-axis) spirals down counterclockwise about halfway around the outer peripheral surface of the columnar portion 21 from its end in the positive direction of the Y-axis to its end in the negative direction of the Y-axis. The location of the upper end of this first recess 41F corresponds to the location of the second recess 42A in the positive direction of the Y-axis, and the upper end is located directly above this second recess 42A.
The present embodiment can also achieve the same effects as in the second embodiment. Additionally, in the present embodiment, each first recess 41F includes a component extending in the axial direction of the columnar portion 21 from the second end 21b to the first end 21a of the columnar portion 21 and a component extending in the circumferential direction of the columnar portion 21. Consequently, the space G1 (
A coil device 1G of an eighth embodiment shown in
As shown in
In some embodiments, the first recess 41G may widen in the direction orthogonal to the extending direction of the first recess 41G towards the first end 21a of the columnar portion. Also, the second recess 42A may be formed so as to be narrower (or wider) towards the outer side of the flange 22 in its radial direction.
The present embodiment can also achieve the same effects as in the second embodiment. Additionally, in the present embodiment, because the width W2 of the first recess 41G widens towards the second end 21b of the columnar portion 21 (corresponding to the opening side of the cavity), part of the exterior material readily enters the first recess 41G when the exterior material is poured into the cavity. This allows a sufficient amount of the exterior material to flow into the first recess 41G and the second recess 42A. Thus, the spaces G1 and G2 (
In terms of ensuring easiness of the exterior material entering the first recess 41G, a ratio (W1/W2) of the width W1 of the first recess 41G to the width W2 thereof may satisfy 1/8≤W1/W2<1 or 1/8≤W1/W2<1/2.
Moreover, because the first recess 41G having the above-mentioned shape functions as a draft angle when the core 20G is removed from the mold, molding of the core 20G is easy.
A coil device 1H of a ninth embodiment shown in
As shown in
The present embodiment can also achieve the same effects as in the second embodiment. Additionally, in the present embodiment, the exterior material that has flowed into each first recess 41A flows into the second recesses 42A. Part of the exterior material that has flowed into one second recess 42A flows into the space G2 (
The present disclosure is not limited to the above-mentioned embodiments and may variously be modified within the scope of the present disclosure.
In the description of the above-mentioned embodiments, examples of applying the present disclosure to an inductor are illustrated. However, the present disclosure may be applied to other coil devices, such as transformers.
In the first embodiment, either the first recesses 41 or the second recesses 42 shown in
Although the core 20 includes the two recesses 40 in the first embodiment, the number of the recesses 40 may be one or may be three or more. The same applies to the second to ninth embodiments.
Although one recess 40 and the other recess 40 have the same shape in the first embodiment, the two recesses 40 may have different shapes. For example, the first recess 41 and the second recess 42 of one recess 40 may have a width W larger than that of the first recess 41 and the second recess 42 of the other recess 40. The same applies to the second to ninth embodiments.
Although the outer end of each second recess 42 in the radial direction is an open end in the first embodiment, the outer end may be a closed end. That is, the outer end of the second recess 42 in the radial direction may be closed with a wall. The same applies to the second to ninth embodiments.
In the sixth embodiment (
Although the third recesses 43 extend along the circumferential direction of the columnar portion 21 in the sixth embodiment, the third recesses 43 may extend in a direction inclined to the circumferential direction of the columnar portion 21. For example, the third recesses 43 may have a spiral shape like the first recesses 41F of the seventh embodiment.
Techniques illustrated in the seventh embodiment (
Hereinafter, the present disclosure will be explained based on further detailed examples. However, the present disclosure is not limited to the examples.
A coil device 1 (sample) shown in
Ten such samples were prepared, and the inductance of each sample was measured to calculate the average inductance of these samples. Table 1 shows the results.
A defect rate of the samples was evaluated. The defect rate of the samples was evaluated based on whether the exterior body 30 peeled from the columnar portion 21 or whether the exterior body 30 peeled from the flange 22. Peeling was evaluated as “peeling confirmed” when, in observation of a cross section of a sample with an optical microscope, presence of a gap was able to be confirmed at an interface between the columnar portion 21 and the exterior body 30 or an interface between the flange 22 and the exterior body 30. Table 1 shows the results. Table 1 shows the percentage of the ten samples evaluated as “peeling confirmed”.
Samples similar to those of Example 1 were manufactured for evaluation as in Example 1 except that a core (corresponding to a core 20G) having a smaller width W of the first recess 41 towards the lower end of the columnar portion 21 as shown in
Samples similar to those of Example 1 were manufactured for evaluation as in Example 1 except that a core having a larger width W of the first recess 41 towards the lower end of the columnar portion 21 (i.e., a core having an upside down tapered shape of a first recess 41G shown in
Samples similar to those of Example 1 were manufactured for evaluation as in Example 1 except that a core having only the first recesses 41 and not having the second recesses 42 was used as the core 20. Table 1 shows the results.
Samples similar to those of Example 1 were manufactured for evaluation as in Example 1 except that a core having only the second recesses 42 and not having the first recesses 41 was used as the core 20. Table 1 shows the results.
Samples similar to those of Example 1 were manufactured for evaluation as in Example 1 except that a core having neither the first recesses 41 nor the second recesses 42 was used as the core 20. Table 1 shows the results.
As shown in Table 1, the samples had better inductance in Examples 1 to 5 than in Comparative Example. These results revealed that forming the first recesses 41 and/or the second recesses 42 on a surface of the core 20 could improve magnetic properties of the coil device 1. In particular, it was revealed that the samples had extremely good inductance in Examples 1 and 2 and that the shapes of the first recesses 41 of Examples 1 and 2 significantly contributed to improvement of the magnetic properties of the coil device 1.
As shown in Table 1, in Examples 1 to 3, no peeling was confirmed at the interface between the columnar portion 21 and the exterior body 30 or the interface between the flange 22 and the exterior body 30. In Example 4 in which the recesses were formed on the columnar portion 21, no peeling was confirmed at the interface between the columnar portion 21 and the exterior body 30 whereas slight peeling was confirmed at the interface between the flange 22 and the exterior body 30. In Example 5 in which the recesses were formed on the flange 22, no peeling was confirmed at the interface between the flange 22 and the exterior body 30 whereas slight peeling was confirmed at the interface between the columnar portion 21 and the exterior body 30. In contrast, in Comparative Example, it was confirmed that peeling occurred at a relatively high percentage at both the interface between the columnar portion 21 and the exterior body 30 and the interface between the flange 22 and the exterior body 30.
Number | Date | Country | Kind |
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2022-013251 | Jan 2022 | JP | national |