The present invention relates to a coin type battery and a manufacturing method thereof. The invention relates particularly to a coin type battery having an electrode plate group of a coiled structure constructed with a positive electrode plate, a negative electrode plate, and a separator interposed therebetween.
Batteries having such electrode plate structure as described above wherein one positive electrode pellet 32 and one negative electrode pellet 33 are arranged face-to-face with each other cannot have a large discharge capacity because of the small reaction area where the positive and negative electrode plates face each other. To achieve a larger discharge capacity, positive and negative electrode plates must face each other in a larger area, and accordingly, for relatively larger batteries other than coin type batteries, various structures that enlarge the reaction area have widely been adopted in an attempt to increase the battery energy density in high rate discharge performance. There is, for example, a layered structure in which a plurality of positive and negative electrode plates are layered upon one another with separators interposed therebetween. Another example is a coiled structure in which strips of positive and negative electrode plates are coiled together with a separator interposed therebetween. The discharge capacity of coin type battery could be increased if electrode plates of such a layered or coiled structure were accommodated in a coin-shaped, flat case. In fact, the applicants of the present invention have proposed a battery containing an electrode plate group of a coiled structure in a coin-shaped, flat case in Japanese Patent Laid-Open Applications Nos. 2000-241678 and 2000-241679.
This electrode plate group of the coiled structure is constructed as shown in
One problem is that, in the manufacture of the electrode plate group 1, the positive and negative electrode plates 7, 8 are not fixed in position relative to each other, and they can easily be displaced in the process step of coiling them into a flat shape. If the positive electrode layer faces 17a–17e upon the negative electrode layer faces 18a–18e are largely offset because of the displacement during the coiling process, there is a risk of internal short-circuiting caused by dendritic growth of lithium. Since the coin type battery contains a coiled electrode plate group 1 in a small, flat case, internal short-circuiting may also be caused if the electrode plates are not in register, as they may contact the sealing case 5 upon an impact of a falling accident or the like.
Accordingly, it is necessary to detect the presence of discrepancy in position between the positive electrode layer faces 17a–17e and negative electrode layer faces 18a–18e, which is, however, not possible after the positive and negative electrode plates 7, 8 have been coiled around with the separator therebetween, because the finished electrode plate group 1 is covered by the separator that is unified with the electrode plates. Thus there is a need to inspect, by some means, whether there is a discrepancy in position between the positive electrode layer faces 17a–17e and negative electrode layer faces 18a–18e, so that only the electrode plate groups 1 that are within a permissible range of positional displacement are used for assembling the batteries.
An object of the present invention is to provide a coin type battery having a feature that enables detection of positional displacement between positive and negative electrode plates of an assembled electrode plate group, and a manufacturing method of this coin type battery.
To achieve the above object, according to a first aspect of the present invention, there is provided a coin type battery comprising:
a strip of positive electrode plate formed of a plurality of positive electrode layer faces coupled together by a plurality of connecting pieces;
a strip of negative electrode plate formed of a plurality of negative electrode layer faces coupled together by a plurality of connecting pieces;
a separator interposed between the positive electrode plate and the negative electrode plate, the positive electrode plate and negative electrode plate being folded at the respective connecting pieces and coiled around into an electrode plate group of flat form such that the positive electrode layer faces and the negative electrode layer faces are alternately layered upon one another with the separator interposed therebetween;
a sealing case forming an inner space together with a gasket and a cap case for accommodating the electrode plate group, characterized in that
the positive electrode plate and the negative electrode plate are respectively formed with positional discrepancy detecting cut-outs for detecting positional displacement between the positive electrode layer faces and the negative electrode layer faces when both electrode plates are coiled around. Preferably, the positional discrepancy detecting cut-outs are holes, centers of which conform to each other when the positive electrode plate and negative electrode plate are coiled around in exact register. Alternatively, the positional discrepancy detecting cut-outs can be notches of same or similar form, peripheral edges of which conform to each other when the positive electrode plate and negative electrode plate are coiled around in exact register.
According to the above structure, after coiling around the positive and negative electrode plates formed with positional discrepancy detecting cut-outs into the electrode plate group of flat form, X-ray inspection is carried out to detect positional displacement in the positive and negative electrode plates based on the positional relationship between the positional discrepancy detecting cut-outs in the electrode plates. Non-conforming electrode plate groups in which positional displacement has occurred may cause short circuits if encased and assembled into coin type batteries. The inspection enables only the electrode plate groups that fall in a permissible range of positional displacement to be assembled into coin type batteries. Thus, coin type batteries constructed with coiled electrode plates are manufactured with a good yield.
According to a second aspect of the invention, there is also provided a coin type battery comprising:
a strip of positive electrode plate formed of a plurality of positive electrode layer faces coupled together by a plurality of connecting pieces;
a strip of negative electrode plate formed of a plurality of negative electrode layer faces coupled together by a plurality of connecting pieces;
a separator interposed between the positive electrode plate and the negative electrode plate, the positive electrode plate and negative electrode plate being folded at the respective connecting pieces and coiled around into an electrode plate group of flat form such that the positive electrode layer faces and the negative electrode layer faces are alternately layered upon one another with the separator interposed therebetween;
a sealing case forming an inner space together with a gasket and a cap case for accommodating the electrode plate group, characterized in that
the electrode plate group is provided, at least in one positive electrode layer face and one negative electrode layer face that face each other at a coiling finish end, or at least in the positive electrode layer faces and the negative electrode layer faces that face each other at a coiling start end and at a coiling finish end, with positional discrepancy detecting cut-outs for detecting positional displacement between the positive electrode layer face and the negative electrode layer face when both electrode plates are coiled around. The positional discrepancy detecting cut-outs can be either holes or notches as mentioned above.
According to the above structure, after coiling around the positive and negative electrode plates formed with positional discrepancy detecting cut-outs in their respective layer faces into the electrode plate group, X-ray inspection is carried out to detect positional displacement in the positive and negative electrode plates based on the positional relationship between the positional discrepancy detecting cut-outs in the opposing positive and negative electrode layer faces. Thus, short circuits that may occur after encasing and assembling the electrode plate group into the coin type battery is prevented, and coin type batteries constructed with coiled electrode plates are manufactured with a good yield.
In the battery above, the positive electrode plate and the negative electrode plate are coiled around such that a first positive electrode layer face is placed upon a negative electrode layer face that is second from the coiling start end; a first negative electrode layer face is folded back at a first connecting piece upon the first positive electrode layer face; the first negative electrode layer face is further folded back at a second connecting piece upon a second positive electrode layer face. The positional discrepancy detecting cut-outs are formed in the first negative electrode layer face and the first and second positive electrode layer faces that face the first negative electrode layer face. The layer faces of positive and negative electrode plates are thus layered alternately, and a positional discrepancy at the coiling start end is reliably detected.
The negative electrode layer faces are formed larger than the positive electrode layer faces, and the positional discrepancy detecting cut-outs are formed as holes or notches. The holes or notches formed in either one of the positive electrode layer faces and the negative electrode layer faces are larger than the holes or notches formed in the other, and their positional relationship is determined based on a permissible range of positional displacement between the positive electrode plate and the negative electrode plate. The positional relationship, i.e., whether the smaller detecting hole is located inside the larger detecting hole, can be detected from transmitted X-ray images obtained by irradiating X-rays to the electrode plate group in the layering direction. X-ray inspection thus enables determination of whether the positional displacement is within the permissible range or not.
The positional discrepancy detecting cut-outs respectively formed in the first and the second positive electrode layer faces are formed in different sizes. Thereby, a positional discrepancy between the first and second layer faces of the positive electrode at its coiling start end is detected.
The detecting holes formed in the positive electrode layer faces are larger than the holes in the negative electrode layer faces. That way, it is prevented that the negative electrode layer face is offset from the positive electrode layer face. When constructing the battery as a lithium rechargeable battery, this will prevent dendritic growth of lithium.
The positional discrepancy detecting cut-outs formed in the positive electrode layer face and the negative electrode layer face that face each other at the coiling start end and the positional discrepancy detecting cut-outs formed in the positive electrode layer face and the negative electrode layer face that face each other at the coiling finish end are located at different positions on the positive electrode layer faces and the negative electrode layer faces. Thereby, positional displacement at the coiling start end and the coiling finish end is detected at the same time in the X-ray inspection.
According to a third aspect of the invention, there is further provided a method of manufacturing a coin type battery, comprising:
folding a strip of positive electrode plate formed of a plurality of positive electrode layer faces coupled together by a plurality of connecting pieces, and a strip of negative electrode plate formed of a plurality of negative electrode layer faces coupled together by a plurality of connecting pieces at the respective connecting pieces and coiling it around into an electrode plate group of flat form such that the positive electrode layer faces and the negative electrode layer faces are alternately layered upon one another with a separator interposed therebetween;
accommodating the electrode plate group into a sealing case;
injecting liquid electrolyte thereinto;
placing a cap case onto the sealing case via a gasket; and
crimping the cap case to seal the inside of the sealing case, characterized in that
the positive electrode plate and the negative electrode plate are respectively formed with positional discrepancy detecting cut-outs for detecting positional displacement between the positive electrode layer faces and the negative electrode layer faces when both electrode plates are coiled around;
after coiling around the positive electrode plate and the negative electrode plate into the electrode plate group, X-rays are irradiated thereto in a direction in which the electrode plates are layered so as to obtain transmitted X-ray images of the electrode plate group;
a positional discrepancy is detected, by processing the images, between the positional discrepancy detecting cut-outs in the positive electrode layer faces and the positional discrepancy detecting cut-outs in the negative electrode layer faces; and
when the detected positional discrepancy is within a predetermined permissible range, the electrode plate group is accommodated in the sealing case.
According to the above method of manufacturing coin type batteries, electrode plate groups formed with positional discrepancy detecting cut-outs are subjected to X-ray inspection for selecting the groups in which no positional displacement has occurred between the positive and negative electrode plates, and these groups are encased and assembled into coin type batteries. Short circuits that may be caused by positional displacement after completing the batteries is thus prevented, and coin type batteries constructed with electrode plates of a coiled structure are manufactured with a good yield.
Preferred embodiments of the present invention will be described below with reference to the accompanying drawings for a better understanding of the present invention. It should be noted that the embodiments described below are merely examples of carrying out the invention and should not pose any limitation on the technical scope of the invention.
The coin type battery according to this embodiment is manufactured through the following process steps: An electrode plate group 10 is encased in a sealing case 5 of circular half shell form as shown in
The electrode plate group 10 is constructed in a flat coiled shape with wound positive and negative electrode plates 11, 12 and a separator interposed therebetween: The negative electrode plate 12 consists of six negative electrode layer faces 23a–23f coupled together by connecting pieces 25a–25e and the negative electrode lead 27 formed at the coiling finish end, as shown in
As shown in
When coiling around the positive and negative electrodes 11, 12 into a flat electrode plate group 10 as described above, if the electrode plates 11, 12 are not in register, there may be a discrepancy in face-to-face positions of the positive electrode layer faces 22a–22e and negative electrode layer faces 23a–23f. If part of the positive electrode layer faces 22a–22e upon the negative electrode layer faces 23a–23f is offset because of the positional discrepancy, there are risks of internal short-circuiting caused by dendritic growth of lithium, or of internal short-circuiting across the electrode plates and sealing case 5 upon an impact of a falling accident or the like. Consequently, it is necessary to detect whether there is a positional discrepancy in the finished electrode plate group 10. For this purpose, the positive and negative electrode plates 11, 12 are respectively provided with positional discrepancy detecting holes or cut-outs 41a, 41b, 42 and 43, 44 in the positive electrode layer faces 22a, 22b and negative electrode layer face 23a that face each other at the coiling start end, and in the positive electrode layer face 22e and negative electrode layer face 23f that face each other at the coiling finish end.
Since the negative electrode layer face 23a faces the positive electrode layer faces 22a, 22b at the coiling start end as described above, when the electrode plates are coiled together in exact register, the positional discrepancy detecting hole 43 in the negative electrode layer face 23a is concentric with the holes 41a, 41b respectively formed in the positive electrode layer faces 22a, 22b as shown in
Since the diameter of the layer faces 23a–23f of the negative electrode plate 12 in the direction of its width is larger than that of the layer faces 22a–22e of the positive electrode plate 11, a positional discrepancy of the positive electrode plate 11 in the width direction of the negative electrode plate 12 should be allowable in physical terms by the difference in the widthwise diameter. The widthwise diameter of the negative electrode layer faces 23a–23f in this embodiment is 24.0 mm, while that of the positive electrode layer faces 22a–22e is 22.0 mm, and therefore a positional discrepancy of positive electrode layer faces 22a–22e on the negative electrode layer faces 23a–23f should be allowable by 1.0 mm on both sides in the widthwise direction. However, it is preferable to ensure that positive electrode layer faces 22a–22e are placed exactly upon the negative electrode layer faces 23a–23f in order to suppress the dendritic growth of lithium. If the edges of the positive electrode layer faces 22a–22e conform to the edges of the negative electrode layer faces 23a–23f, it is likely that a short circuit is formed upon an impact of a falling accident or the like. For this reason, in this embodiment, the permissible range of positional discrepancy is determined by the diameters of the detecting holes 41a, 41b, 42 in the positive electrode and those 43, 44 in the negative electrode.
The diameter of the detecting holes 41a, 41b, 42 in the positive electrode is set larger than the detecting holes 43, 44 in the negative electrode, and if the detecting holes 43, 44 are located inside the detecting holes 41a, 41b, 42 with a certain clearance, it is judged that the positional discrepancy is within the permissible range. In this embodiment, the diameter of the detecting holes 41a, 42 in the positive electrode is 3.2 mm, and that of the hole 41b is 4.2 mm. The diameter of the detecting hole 43 in the negative electrode is 1.5 mm. When the detecting hole 41a in the positive electrode is not inside its detecting hole 41b, it is assumed that there has been a positional discrepancy when folding the positive electrode plate 11 at its connecting piece 24a shown in
Detection of positional discrepancy using these detecting holes 41a, 41b, 42 and 43, 44 in the positive and negative electrodes is achieved by irradiating X-rays to the complete electrode plate group 10 and by processing the transmitted X-ray images of the electrode plate group 10.
Determination of non-conforming electrode plate groups 10 using the transmitted X-ray images can be made based on whether a positional discrepancy is detected between the centers of the detecting hole 41a in the positive electrode and of the hole 43 in the negative electrode, and between the centers of the detecting hole 42 in the positive electrode and of the hole 44 in the negative electrode. Alternatively, it can be made based on whether the detecting hole 41a in the positive electrode is located inside its detecting hole 41b and by detecting the minimum distance between the peripheral edges of the detecting hole 41a in the positive electrode and the hole 43 in the negative electrode, and between the peripheral edges of the detecting hole 42 in the positive electrode and the hole 44 in the negative electrode.
The diameter of the detecting holes 41a, 42 in the positive electrode is 3.2 mm in this embodiment as mentioned above, while the diameter of the detecting holes 43, 44 in the negative electrode is 1.5 mm. In the case where the inspection is based on detected minimum distances between the peripheral edges of the detecting hole 41a in the positive electrode and the hole 43 in the negative electrode, and between the peripheral edges of the detecting hole 42 in the positive electrode and the hole 44 in the negative electrode, if it is detected from a processed image of transmitted X-rays that these minimum distances are 0.2 mm or more, it is determined that the positional discrepancy is within the permissible range, and the electrode plate group 10 is identified as a conforming product that can be assembled into a coin type battery. If the detected minimum distances are 0.2 mm or less, then the electrode plate group 10 is disposed as a non-conforming product in which large positional displacement has occurred.
In the embodiment described above, the holes for detecting positional displacement formed at the coiling start/finish ends are offset from each other in a direction orthogonal to the coiling direction, but they may be offset from each other along the coiling direction.
In the embodiment described above, the holes 41a, 41b, 42, 43, 44 or cut-outs for detecting positional displacement are of circular form, but they can be in other forms such as squares. Alternatively, they can be formed as notches 71a, 71b, 72, 73, 74 as shown in
The positive and negative electrode plates 11, 12 shown in
As described above, according to the present invention, it is possible to detect positional displacement in a coiled electrode plate group that is applied to flat shaped batteries such as coin type batteries. It prevents short circuits caused by positional displacement of electrode plates, and is advantageously adopted for the manufacture of coin type batteries with a good yield.
Number | Date | Country | Kind |
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2001-243425 | Aug 2001 | JP | national |
2002-230344 | Aug 2002 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP02/08206 | 8/9/2002 | WO | 00 | 4/10/2003 |
Publishing Document | Publishing Date | Country | Kind |
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WO03/015208 | 2/20/2003 | WO | A |
Number | Name | Date | Kind |
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20010041289 | Hikmet et al. | Nov 2001 | A1 |
20020064710 | Kawakami et al. | May 2002 | A1 |
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53-149630 | Dec 1978 | JP |
59-4169 | Jan 1984 | JP |
2001-068143 | Mar 2001 | JP |
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Number | Date | Country | |
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20040028997 A1 | Feb 2004 | US |