TREA

Cold-workable laminate

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Information

  • Patent Application
  • 20060257648
  • Publication Number
    20060257648
  • Date Filed
    June 03, 2004
    20 years ago
  • Date Published
    November 16, 2006
    18 years ago
Information
Abstract
A cold-workable laminate for the production of containers for packaging of pharmaceutical and medical technical products and diagnostic agents has an aluminium film with a biaxially stretched plastic film on one side as an outer layer, and a sealing layer arranged on the second side. The aluminium film is connected with the biaxially stretched plastic film by extrusion laminating or the biaxially stretched plastic film is extrusion-coated with a polyolefin and lacquer-laminated to the aluminium film. The laminate has at least 15% higher cold-working capacity than laminates of the prior art and has improved delamination resistance.
Description

The invention concerns a cold-workable laminate for the production of containers for packaging of pharmaceutical and medical technical products and diagnostic agents, with an aluminium film, a biaxially stretched plastic film arranged on a first side of the aluminium film as an outer layer, and a sealing layer arranged on the second side of the aluminium film.


For the production of containers for packaging of pharmaceutical and medical technical products and diagnostic agents, such as e.g. base parts of blister and push-through packs, cold-workable laminates are known with the structure of biaxially stretched plastic film/aluminium film/sealing layer (lacquer, plastic film, or plastic coating). The external plastic film is connected to the aluminium film by way of an adhesive, where the aluminium film is mainly lacquered to compensate for the influence of the coatings on the aluminium film. It has also been proposed to create the connection between an external film of biaxially stretched polyamide and the aluminium film by hot calendering, where the adhesive or laminating medium has been previously applied and dried.


With the above laminates a maximum workability by cold forming of around 30% can be achieved. The resistance to damp and heat, i.e. the resistance of the external plastic film to delamination, is maximum 26 weeks under ICH conditions.


The invention is based on the object of creating a cold-workable laminate of the type cited initially which in comparison with the laminates according to the prior art allows at least 15% more cold working and has a delamination resistance under ICH conditions of at least 52 weeks.







The object according to the invention is achieved in principle by the following two routes:

    • 1. The aluminium film is connected with the biaxially stretched plastic film of the outer layer by extrusion laminating.
      • The biaxially stretched plastic film of the outer layer is preferably of the type PE (polyethylene), PP (polypropylene), PA (polyamide), polyester, PEN (polyethylene naphthalate), COC (cycloolefin-ethylene-copolymer) or PS (polystyrene). The film thickness lies in the range from 10 to 50 μm, preferably 15 to 30 μm.
      • Suitable laminating media are adhesion-modified polyolefins, in particular PE-MAH (polyethylene-maleic acid anhydride graft polymer), PP-MAH (polypropylene-maleic acid anhydride graft polymer), EVA (ethylene-vinyl acetate copolymer)-MAH or PE copolymers, in particular EAA (ethylene acrylic acid), EBA (ethylene-butylacrylate), EMA (ethylene-methacrylic acid), EEA (ethylene-ethylacrylate) or ionomers. The thickness of the extrusion lamination lies in the range of 2 to 30 μm, preferably 3 to 12 μm, as a mono-layer or co-extruded e.g. PP-MAH/PP/PP-MAH.
      • In a particularly preferred laminate structure the outer layer comprises a biaxially stretched (oriented) polyamide film (oPA film) which is extrusion-laminated with PE-LLD (linear low density)-MAH against the aluminium film.
      • The biaxially oriented plastic film and/or the aluminium film can be coated with a primer. Suitable primers are water- or solvent-based polyamide, PP-MAH, EAA or acrylate or similar primers.
    • 2. The biaxially stretched plastic film of the outer layer is extrusion-coated with a polyolefin and lacquer-laminated against the aluminium film. The side of the biaxially stretched plastic film coated with the polyolefin can be directed against the aluminium film or against the outside.
      • The biaxially stretched plastic film of the outer layer is preferably of the type PE, PP, polyamide, polyester, PEN, COC or polystyrene and is extrusion-coated with PE or PP. The extrusion coating has an application weight in the range of 5 to 40 g/M2, preferably 10 to 30 g/M2.


Both routes lead to laminates which meet the requirements with regard to degree of cold-working and delamination resistance.


The thickness of the aluminium films used for laminates according to the invention lies in the range from 20 to 100 μm, preferably 30 to 70 μm. The aluminium film can be soft or have a defined hardness.


The laminates according to the invention can be processed into packaging containers on existing packaging plants.


The inner or sealing layer can be an unstretched plastic film which is lacquer- or extrusion-laminated with the aluminium film. Preferred are plastics based on PVC (polyvinyl chloride), PVDC (polyvinylidene chloride) PE, PP, polyolefin copolymers, in particular EAA, EEA, and ionomers, polyamide, polystyrene, COC, PET, PEN or PCTFE (polychlorotetrafluoroethylene, ACLAR®). The thickness of the plastic film or combination of two or more films lies in the range from 10 to 120 μm, preferably 19 to 100 μm. The extrusion lamination can e.g. be performed with a PE terpolymer. Lacquer lamination can be performed with a watery solvent-based or solvent-free lamination media.


The sealing layer can also be a polyolefin and aluminium foil extrusion-coated with the sealing layer. Preferred sealing layers produced by extrusion coating comprise polyolefin plastics, in particular PE, PP, EAA, EAA-PE-LD or an ionomer, e.g. a sodium or zinc acrylate co- or terionomer, such as SURLYN® with an application weight in the range of 5 to 80 g/M2, preferably 15 to 40 g/M2, or coated with PVDC with an application weight in the range of 5 to 120 g/M2, preferably 20 to 60 g/M2.


Extrusion laminated sealing layers or sealing layers produced by extrusion coating are environmentally friendly as they do not require solvents and consequently do not pollute the atmosphere with VOC's.


Further preferred sealing layers are hot sealing layers based on acrylate, polybutylate, morprime, styrene acrylate with polyolefin groups, PVC/AC plus acrylate, PP/butadiene or polyester/butadiene/styrene with an application weight in the range from 2 to 20 g/m2, preferably 5 to 15 g/m2.


The aluminium film can also be coated with a primer and the sealing layer applied to the primer. Suitable primers are e.g. EAA or polyamide primers.


The plastic used for the sealing layer depends on the structure of the cover films provided for sealing the packaging containers made from the laminates.


Further advantages, features and details of the invention arise from the description below of preferred embodiment examples.


The table below gives a selection of cold-workable laminates constructed according to the invention with biaxially stretched, oriented polyamide (oPA) as an outer layer. The “outside” of packaging containers is the side of the laminate forming the outside, the “inside” is the side facing the plastic of a cover film as a seal, in each case with the application weight for lacquer coating or film thickness for film coating.

AluminiumExampleOutsideFilmInside1.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-with PE-LLD-MAH, 10 μmlaminated2.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, extrusion-with PE-LLD-MAH, 10 μmlaminated3.oPA, 25 μm, extrusion-laminated45 μmco-extrusion-coated with EAA/with PE-LLD-MAH, 10 μmPE-LD4.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-with PE-LLD-MAH, 10 μm, againstlaminatedprimer5.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-with PP-MAH, 10 μmlaminated6.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, extrusion-with PP-MAH, 10 μmlaminated7.oPA, 25 μm, extrusion-laminated45 μmco-extrusion-coated with EAA/with PP-MAH, 10 μmPE-LD8.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-with EVA-MAH, 10 μm, againstlaminatedprimer9.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-with EVA-MAH, 10 μmlaminated10.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, extrusion-with EVA-MAH, 10 μmlaminated11.oPA, 25 μm, extrusion-laminated45 μmco-extrusion-coated with EAA/with EVA-MAH, 10 μmPE-LD12.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-with EVA-MAH, 10 μm, againstlaminatedprimer13.oPA, 25 μm/primer, extrusion-45 μmPVC, PP or PE film, lacquer-laminated with EAA, 10 μmlaminated14.oPA, 25 μm/primer, extrusion-45 μmPVC, PP or PE film, extrusion-laminated with EAA, 10 μmlaminated15.oPA, 25 μm/primer, extrusion-45 μmco-extrusion-coated with EAA/laminated with EAA, 10 μmPE-LD16.oPA, 25 μm/primer, extrusion-45 μmPVC, PP or PE film, lacquer-laminated with EAA, 10 μm, againstlaminatedprimer17.oPA, 25 μm/primer, extrusion-45 μmPVC, PP or PE film extrusion-laminated with EAA, 10 μm, againstlaminatedprimer18.oPA, 25 μm/primer, extrusion-45 μmco-extrusion-coated with EAA/laminated with EAA, 10 μm, againstPE-LDprimer19.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-with ionomer, 10 μmlaminated20.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, extrusion-with ionomer, 10 μmlaminated21.oPA, 25 μm, extrusion-laminated45 μmco-extrusion-coated with EAA/with ionomer, 10 μmPE-LD22.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-with ionomer, 10 μm, against primerlaminated23.oPA, 25 μm/primer, extrusion-45 μmPVC, PP or PE film, lacquer-laminated with ionomer, 10 μmlaminated24.oPA, 25 μm/primer, extrusion-45 μmPVC, PP or PE film, extrusion-laminated with ionomer, 10 μmlaminated25.oPA, 25 μm/primer, extrusion-45 μmco-extrusion-coated with EAA/laminated with ionomer, 10 μmPE-LD26.oPA, 25 μm/primer, extrusion-45 μmPVC, PP or PE film, lacquer-laminated with ionomer, 10 μm,laminatedagainst primer27.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-with EMA, 10 μmlaminated28.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, extrusion-with EMA, 10 μmlaminated29.oPA, 25 μm, extrusion-laminated45 μmco-extrusion-coated with EAA/with EMA, 10 μmPE-LD30.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-EMA, 10 μm, against primerlaminated31.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, lacquer-with EEA, 10 μmlaminated32.oPA, 25 μm, extrusion-laminated45 μmPVC, PP or PE film, extrusion-with EEA, 10 μmlaminated33.oPA, 25 μm, extrusion-laminated45 μmco-extrusion-coated with EAA/with EEA, 10 μmPE-LD34.oPA, 25 μm, extrusion-laminated45 μmPVC, PPE or PE film, lacquer-with EEA, 10 μm, against primerlaminated35.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PE layer lies againstmedium against primer, PE layeraluminium filmlies against aluminium film36.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PEmedium against primer, PE layerlayer lies against aluminium filmlies against aluminium film37.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PE layer lies againstmedium, PE layer lies againstaluminium filmaluminium film38.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PEmedium, PE layer lies againstlayer lies against aluminium filmaluminium film39.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PE layer lies againstmedium against primer, PE layeraluminium filmlies against aluminium film40.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PEmedium against primer, PE layerlayer lies against aluminium filmlies against aluminium film41.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PE layer lies againstmedium, PE layer lies againstaluminium filmaluminium film42.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PEmedium, PE layer lies againstlayer lies against aluminium filmaluminium film43.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium against primer, oPA filmaluminium filmlies against aluminium film44.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, oPAmedium against primer, oPA filmfilm lies against aluminium filmlies against aluminium film45.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium, oPA film lies againstaluminium filmaluminium film46.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, oPAmedium, oPA film lies againstfilm lies against aluminium filmaluminium film47.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium against primer, oPA filmaluminium filmlies against aluminium film48.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, oPAmedium against primer, oPA filmfilm lies against aluminium filmlies against aluminium film49.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium against primer, oPA filmaluminium filmlies against aluminium film50.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPE, 20 g/m2, lacquer-laminated withwith PE, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, oPAmedium, oPA film lies againstfilm lies against aluminium filmaluminium film51.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PP layer lies againstmedium against primer, PP layeraluminium filmlies against aluminium film52.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PPmedium against primer, PP layerlayer lies against aluminium filmlies against aluminium film53.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PP layer lies againstmedium, PP layer lies againstaluminium filmaluminium film54.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PPmedium, PP layer lies againstlayer lies against aluminium filmaluminium film55.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PP layer lies againstmedium against primer, PP layeraluminium filmlies against aluminium film56.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PPmedium against primer, PP layerlayer lies against aluminium filmlies against aluminium film57.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PP layer lies againstmedium, PP layer lies againstaluminium filmaluminium film58.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PPmedium, PP layer lies againstlayer lies against aluminium filmaluminium film59.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium against primer, oPA filmaluminium filmlies against aluminium film60.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, oPAmedium against primer, oPA filmfilm lies against aluminium filmlies against aluminium film61.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium, oPA film lies againstaluminium filmaluminium film62.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, oPAmedium, oPA film lies againstfilm lies against aluminium filmaluminium film63.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium against primer, oPA filmaluminium filmlies against aluminium film64.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, oPAmedium against primer, oPA filmfilm lies against aluminium filmlies against aluminium film65.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium, oPA film lies againstaluminium filmaluminium film66.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, oPAmedium, oPA film lies againstfilm lies against aluminium filmaluminium film67.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PP layer lies againstmedium against primer, PP layeraluminium filmlies against aluminium film68.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PP layer lies againstmedium against primer, PP layeraluminium filmlies against aluminium film69.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PP layer lies againstmedium, PP layer lies againstaluminium filmaluminium film70.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PPmedium, PP layer lies againstlayer lies against aluminium filmaluminium film71.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PP layer lies againstmedium against primer, PP layeraluminium filmlies against aluminium film72.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PPmedium against primer, PP layerlayer lies against aluminium filmlies against aluminium film73.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, PP layer lies againstmedium, PP layer lies againstaluminium filmaluminium film74.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, PPmedium, PP layer lies againstlayer lies against aluminium filmaluminium film75.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium against primer, oPA filmaluminium filmlies against aluminium film76.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, oPAmedium against primer, oPA filmfilm lies against aluminium filmlies against aluminium film77.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium, oPA film lies againstaluminium filmaluminium film78.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium, oPA film lies againstaluminium filmaluminium film79.oPA, 25 μm, extrusion-coated with60 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium against primer, oPA filmaluminium filmlies against aluminium film80.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer2, oPAmedium against primer, oPA filmfilm lies against aluminium filmlies against aluminium film81.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated, oPA film lies againstmedium, oPA film lies againstaluminium filmaluminium film82.oPA, 25 μm, extrusion-coated with45 μmoPA, 25 μm, extrusion-coatedPP, 20 g/m2, lacquer-laminated withwith PP, 20 g/m2, lacquer-solvent-containing laminatinglaminated against primer, oPAmedium, oPA film lies againstfilm lies against aluminium filmaluminium film83.oPA, 25 μm, extrusion-coated with45 μmPVC film, 60 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film84.oPA, 25 μm, extrusion-coated with45 μmPVC film, 30 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film85.oPA, 25 μm, extrusion-coated with45 μmPP film, 60 μm, lacquer-laminatedPE, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film86.oPA, 25 μm, extrusion-coated with60 μmPP film, 60 μm, lacquer-laminatedPE, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film87.oPA, 25 μm, extrusion-coated with45 μmPE film, 60 μm, lacquer-laminatedPE, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film88.oPA, 25 μm, extrusion-coated with60 μmPE film, 60 μm, lacquer-laminatedPE, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film89.oPA, 25 μm, extrusion-coated with45 μmPVC film, 100 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film90.oPA, 25 μm, extrusion-coated with45 μmCOC film, 20 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film91.oPA, 25 μm, extrusion-coated with60 μmCOC film, 20 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film92.oPA, 25 μm, extrusion-coated with45 μmACLAR ® film, 23 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film93.oPA, 25 μm, extrusion-coated with45 μmACLAR ® film, 15 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film94.oPA, 25 μm, extrusion-coated with45 μmExtrusion-coated with SURLYN ®,PE, 20 g/m2, lacquer-laminated with20 g/m2solvent-containing laminatingmedium against primer, PE layerlies against aluminium film95.oPA, 25 μm, extrusion-coated with45 μmExtrusion-coated with PE, 20 g/m2PE, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, PE layerlies against aluminium film96.oPA, 25 μm, extrusion-coated with45 μmPVC film, 60 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film97.oPA, 25 μm, extrusion-coated with45 μmPVC film, 30 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film98.oPA, 25 μm, extrusion-coated with45 μmPP film, 60 μm, lacquer-laminatedPE, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film99.oPA, 25 μm, extrusion-coated with60 μmPP film, 60 μm, lacquer-laminatedPE, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film100.oPA, 25 μm, extrusion-coated with45 μmPE film, 60 μm, lacquer-laminatedPE, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film101.oPA, 25 μm, extrusion-coated with60 μmPE film, 60 μm, lacquer-laminatedPE, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film102.oPA, 25 μm, extrusion-coated with45 μmPVC film, 100 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film103.oPA, 25 μm, extrusion-coated with45 μmCOC film, 20 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film104.oPA, 25 μm, extrusion-coated with60 μmCOC film, 20 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film105.oPA, 25 μm, extrusion-coated with45 μmACLAR ® film, 23 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film106.oPA, 25 μm, extrusion-coated with45 μmACLAR ® film, 15 μm, lacquer-PE, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film107.oPA, 25 μm, extrusion-coated with45 μmExtrusion-coated with SURLYN ®,PE, 20 g/m2, lacquer-laminated with20 g/m2solvent-containing laminatingmedium against primer, oPA layerlies against aluminium film108.oPA, 25 μm, extrusion-coated with45 μmExtrusion-coated with PE, 20 g/m2PE, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film109.oPA, 25 μm, extrusion-coated with45 μmPVC film, 60 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film110.oPA, 25 μm, extrusion-coated with45 μmPVC film, 30 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film111.oPA, 25 μm, extrusion-coated with45 μmPP film, 60 μm, lacquer-laminatedPP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film112.oPA, 25 μm, extrusion-coated with60 μmPP film, 60 μm, lacquer-laminatedPP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film113.oPA, 25 μm, extrusion-coated with45 μmPE film, 60 μm, lacquer-laminatedPP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film114.oPA, 25 μm, extrusion-coated with60 μmPE film, 60 μm, lacquer-laminatedPP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film115.oPA, 25 μm, extrusion-coated with45 μmPVC film, 100 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film116.oPA, 25 μm, extrusion-coated with45 μmCOC film, 20 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film117.oPA, 25 μm, extrusion-coated with60 μmCOC film, 20 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film118.oPA, 25 μm, extrusion-coated with45 μmACLAR ® film, 23 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film119.oPA, 25 μm, extrusion-coated with45 μmACLAR ® film, 15 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film120.oPA, 25 μm, extrusion-coated with45 μmExtrusion-coated with SURLYN ®,PP, 20 g/m2, lacquer-laminated with20 g/m2solvent-containing laminatingmedium against primer, PP layerlies against aluminium film121.oPA, 25 μm, extrusion-coated with45 μmExtrusion-coated with PE, 20 g/m2PP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, PP layerlies against aluminium film122.oPA, 25 μm, extrusion-coated with45 μmPVC film, 60 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film123.oPA, 25 μm, extrusion-coated with45 μmPVC film, 30 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film124.oPA, 25 μm, extrusion-coated with45 μmPP film, 60 μm, lacquer-laminatedPP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film125.oPA, 25 μm, extrusion-coated with60 μmPP film, 60 μm, lacquer-laminatedPP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film126.oPA, 25 μm, extrusion-coated with45 μmPE film, 60 μm, lacquer-laminatedPP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film127.oPA, 25 μm, extrusion-coated with60 μmPE film, 60 μm, lacquer-laminatedPP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film128.oPA, 25 μm, extrusion-coated with45 μmPVC film, 100 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film129.oPA, 25 μm, extrusion-coated with45 μmCOC film, 20 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film130.oPA, 25 μm, extrusion-coated with60 μmCOC film, 20 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film131.oPA, 25 μm, extrusion-coated with45 μmACLAR ® film, 23 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film132.oPA, 25 μm, extrusion-coated with45 μmACLAR ® film, 15 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film133.oPA, 25 μm, extrusion-coated with45 μmExtrusion-coated with SURLYN ®,PP, 20 g/m2, lacquer-laminated with20 g/m2solvent-containing laminatingmedium against primer, oPA layerlies against aluminium film134.oPA, 25 μm, extrusion-coated with45 μmExtrusion-coated with PE, 20 g/m2PP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film135.oPA, 25 μm, extrusion-coated with50 μmPE film, 40 μm, lacquer-laminatedPP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film136.oPA, 25 μm, extrusion-coated with45 μmPVDC film, 19 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film137.oPA, 25 μm, extrusion-coated with60 μmPVDC film, 19 μm, lacquer-PP, 20 g/m2, lacquer-laminated withlaminatedsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film138.oPA, 25 μm, extrusion-coated with45 μmLacquered with PVC/AC plusPP, 20 g/m2, lacquer-laminated withacrylate, 10 g/m2solvent-containing laminatingmedium against primer, oPA layerlies against aluminium film139.oPA, 25 μm, extrusion-coated with60 μmLacquered with PVC/AC plusPP, 20 g/m2, lacquer-laminated withacrylate, 10 g/m2solvent-containing laminatingmedium against primer, oPA layerlies against aluminium film140.oPA, 25 μm, extrusion-coated with45 μmLacquered with PP/butadiene, 7 g/m2PP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film141.oPA, 25 μm, extrusion-coated with60 μmLacquered with PP/butadiene, 7 g/m2PP, 20 g/m2, lacquer-laminated withsolvent-containing laminatingmedium against primer, oPA layerlies against aluminium film142.oPA, 25 μm, extrusion-coated with45 μmLacquered with polyester/PP, 20 g/m2, lacquer-laminated withbutadiene/styrene, 7 g/m2solvent-containing laminatingmedium against primer, oPA layerlies against aluminium film143.oPA, 25 μm, extrusion-coated with60 μmLacquered with polyester/PP, 20 g/m2, lacquer-laminated withbutadiene/styrene, 7 g/m2solvent-containing laminatingmedium against primer, oPA layerlies against aluminium film


The examples above constitute a selection of preferred laminates. The invention is not limited to the examples given.

Claims
  • 1. Cold-workable laminate for the production of containers for packaging of pharmaceutical and medical technical products and diagnostic agents, with an aluminum film, a biaxially stretched plastic film arranged on a first side of the aluminum film as an outer layer, and a sealing layer arranged on the second side of the aluminum film, characterized in that the aluminum film is connected with the biaxially stretched plastic film by extrusion laminating.
  • 2. Cold-workable laminate for the production of containers for packaging of pharmaceutical and medical technical products and diagnostic agents, with an aluminum film, a biaxially stretched plastic film arranged on a first side of the aluminum film as an outer layer and a sealing layer arranged on the second side of the aluminum film, characterized in that the biaxially stretched plastic film is extrusion-coated with a polyolefin and lacquer-laminated against the aluminum film.
  • 3. Cold-workable laminate according to claim 1 characterized in that the sealing layer is an unstretched plastic film and is lacquer- or extrusion-laminated with the aluminum film.
  • 4. Cold-workable laminate according to claim 1 characterized in that the sealing layer is a polyolefin and the aluminum film is extrusion-coated with the sealing layer.
  • 5. Cold-workable laminate according to claim 1 characterized in that the sealing layer is a hot sealing lacquer.
  • 6. Cold-workable laminate according to claim 1, characterized in that the biaxially stretched plastic film of the outer layer is of the type PE, PP, polyamide, polyester, PEN, COC or polystyrene and is extrusion-laminated against the aluminum film with adhesion-modified polyolefins in particular PE-MAH, PP-MAH, EVA-MAH or polyethylene co-polymers, in particular EAA, EMA, EEA or ionomers.
  • 7. Cold-workable laminate according to claim 6, characterized in that the thickness of the biaxially stretched plastic film is 10 to 50 μm, preferably 15 to 30 μm.
  • 8. Cold-workable laminate according to claim 6, characterized in that the aluminum film is coated with a primer.
  • 9. Cold-workable laminate according to claim 2, characterized in that the biaxially stretched plastic film of the outer layer is of the type PE, PP, polyamide, polyester, PEN, COC or polystyrene and is extrusion-coated with PE or PP.
  • 10. Cold-workable laminate according to claim 9, characterized in that the application weight of the extrusion coating is 5 to 40 g/m2, preferably 15 to 30 g/m2.
  • 11. Cold-workable laminate according to claim 3, characterized in that the sealing layer is an unstretched plastic film based on PVC, PVDC, PE, PP, polyolefin copolymers, in particular EAA, EEA, and ionomers, polyamide, polystyrene, COC, PET, PEN or PCTFE.
  • 12. Cold-workable laminate according to claim 11, characterized in that the thickness of the sealing layer is 10 to 120 μm, preferably 19 to 100 μm.
  • 13. Cold-workable laminate according to claim 4, characterized in that the sealing layer is PE, PP, EAA or an ionomer.
  • 14. Cold-workable laminate according to claim 5, characterized in that the sealing layer is a hot sealing lacquer based on acrylate, polybutylate, morprime, styrene acrylate with polyolefin groups, PVC/AC plus acrylate, PP/butadiene or polyester/butadiene/styrene.
  • 15. Cold-workable laminate according to claim 14, characterized in that the application weight of the hot sealing lacquer is 2 to 20 g/m2, preferably 5 to 15 g/m2.
  • 16. Cold-workable laminate according to claim 11 characterized in that the aluminum film is coated with a primer and the sealing layer is applied to the primer.
  • 17. Cold-workable laminate according to claim 2, characterized in that the sealing layer is an unstretched plastic film and is lacquer- or extrusion-laminated with the aluminum film.
  • 18. Cold-workable laminate according to claim 2, characterized in that the sealing layer is a polyolefin and the aluminum film is extrusion-coated with the sealing layer.
  • 19. Cold-workable laminate according to claim 2, characterized in that the sealing layer is a hot sealing lacquer.
  • 20. Cold-workable laminate according to claim 12, characterized in that the aluminum film is coated with a primer and the sealing layer is applied to the primer.
  • 21. Cold-workable laminate according to claim 13, characterized in that the aluminum film is coated with a primer and the sealing layer is applied to the primer.
  • 22. Cold-workable laminate according to claim 14, characterized in that the aluminum film is coated with a primer and the sealing layer is applied to the primer.
  • 23. Cold-workable laminate according to claim 15, characterized in that aluminum film is coated with a primer and the sealing layer is applied to the primer.
Priority Claims (1)
Number Date Country Kind
03405435.3 Jun 2003 EP regional
PCT Information
Filing Document Filing Date Country Kind 371c Date
PCT/EP04/05978 6/3/2004 WO 12/8/2005