Color Adjustable Luminescent Powder and Preparation Method Thereof

TECHNICAL FIELD

The present invention belongs to the technical field of photo-electronics and illumination, and particularly relates to a. color-adjustable fluorescent powder and a method for preparing the same.

BACKGROUND

Along with the increasing development and application of high-quality display and illuminating devices in work and living, fluorescent powder having high efficiency and long service life has become an important component in illuminating and display devices. The performance of the fluorescent powder becomes a direct factor affecting the quality of the devices, especially field emission devices, wherein electrons are liable to accumulate on the surface of the fluorescent powder, which decreases the bombardment ability of the electron beam, and decreases the brightness of the devices. Therefore, the conductivity of the fluorescent powder has become a very important factor which restricts the performance of illuminating and display devices.

Currently used fluorescent materials are mainly zinc sulfide, and oxide and oxysulfide powders activated by rare earth ions. Sulfide fluorescent powders have relatively high luminescent brightness and certain conductivity, but are liable to decompose under the bombardment of large-beam electron beam, which decrease the luminescent efficiency of the fluorescent powder. Oxide fluorescent powders have good stability, but their luminescent efficiency under the bombardment of low voltage electron beam is not high enough, and the materials are nonconductive insulators, of which the performance needs improvement. Meanwhile, high-quality display and illuminating devices raise requirements on the color-adjustability of the fluorescent powder. Therefore, it has long been an important aspect of the research in the technical fields of materials, photo-electronics and illumination to achieve the color-adjustability of the luminescence of the fluorescent powder on the premise of achieving high luminescent brightness of the fluorescent powder.

SUMMARY

In view of the above, it is provided a fluorescent powder with high luminescent brightness and color-adjustability.

It is also provided a method for preparing a color-adjustable fluorescent powder.

A color-adjustable fluorescent powder has a chemical formula of (Y_aGd_bEu_c)₂O₃.Zn_(1-m)Al_mO wherein 0≦a≦0.99, 0≦b≦0.99, 0.01≦c≦0.08, and a+b c=1, a and b are not simultaneously 0, x is a molar ratio of Zn_(1-m)Al_mO to (Y_aGd_bEu_c)₂O₃wherein 0.01≦x≦0.20, and 0.001≦m≦0.05.

In addition, a method for preparing a color-adjustable fluorescent powder comprises the steps of:

preparing a solution of Zn²⁺and Al³⁺, and preparing a solution of Y³⁺, Eu³⁺and Gd³⁺ or of Eu³⁺ and Gd³⁺ or of Y³⁺ and Eu³⁺ according to molar ratio of corresponding elements in a chemical formula of (Y_aGd_bEu_c)₂O₃;
taking the above solutions according to corresponding molar ratio in a chemical formula of (Y_aGd_bEu_c)₂O₃·xZn_(1-m)Al_mO, wherein 0≦a≦0.99, 0≦b≦0.99, 0.01≦c≦0.08, and a+b+c=1, a and b are not simultaneously 0, x is a molar ratio of Zn_(1-m)Al_mO to (Y_aGd_bEu_c)₂O₃, 0.01≦x≦0.20, and 0.001≦m≦0.05; and adding an alcohol-water mixed solution contain a complexing agent, and a surfactant to give a precursor solution; and
aging the precursor solution, calcinating, cooling and milling to give the color-adjustable fluorescent powder.

By introducing conductive material ZnAlO into the fluorescent powder, electrons accumulated on the surface of the fluorescent powder can be effectively led out, which increases the luminescent brightness of the obtained fluorescent powder under the excitation of cathode rays, improves the conductivity over the currently used fluorescent powders, and achieves the color-adjustability, of the fluorescent powder by adjusting the ratio of the conductive materials which have luminescent properties and by changing the exciting voltage of the cathode rays.

BRIEF DESCRIPTION OF THE FIGURES

FIG. 1 shows a flow chart of the method for preparing a color-adjustable fluorescent powder of an embodiment of the present invention;

FIG. 2 shows the spectra of the fluorescent powder prepared in Example 6 of the present invention under the excitation of cathode rays of 7 kV (a) and of 5 kV (b);

FIG. 3 shows the color coordinates of the Y_1.90Eu_0.10O₃.0.05Zn_0.97Al_0.03O fluorescent powder prepared in Example 6 of the present invention under the excitation of cathode rays of 5 kV;

FIG. 4 shows the color coordinates of the Y_1.90Eu_0.10O₃.0.05Zn_0.97Al_0.03O fluorescent powder prepared in Example 6 of the present invention under the excitation of cathode rays of 7 kV;

FIG. 5 shows the spectra of the Y_1.90Eu_0.10O₃fluorescent powder blended with various proportions of Zn_0.97Al_0.03O prepared in Examples 5 and 6 of the present invention under the excitation of cathode rays of 7 kV, wherein c is the spectrum of the Y_1.90Eu_0.10O₃.0.03Zn_0.97Al_0.03O fluorescent powder and d is the spectrum of the Y_1.90Eu_0.10O₃.0.05Zn_0.97Al_0.03O fluorescent powder;

FIG. 6 shows the color coordinates of the Y_1.90Eu_0.10O₃.0.03Zn_0.97Al_0.03O fluorescent powder prepared in Example 5 of the present invention under the excitation of cathode rays of 7 kV; and

FIG. 7 shows the color coordinates of the Y_1.90Eu_0.10O₃.0.05Zn_0.97Al_0.03O fluorescent powder prepared in Example 6 of the present invention under the excitation of cathode rays of 7 kV.

SPECIFIC EMBODIMENTS

In order to make the objectives, the technical solutions and the advantages of the present invention more obvious, the present invention will be further described in detail in combination with the Figures and the embodiments. It shall be understood that the specific embodiments described herein are only to illustrate rather than to limit the present invention.

A color-adjustable fluorescent powder has a chemical formula of (Y_aGd_bEu_c)₂O₃.xZn_(1-m)Al_mO, wherein 0≦a≦0.99, 0≦b≦0.99, 0.01≦c≦0.08, and a+b+c=1, a and b are not simultaneously 0, x is a molar ratio of Zn_(1-m)Al_mO to (Y_aGd_bEu_c)₂O₃, 0.01≦x≦0.20, and 0.001≦m≦0.05.

The difference of the ratio of Zn_(1-m)Al_mO in the fluorescent powder (Y_aGd_bEu_c)₂O₃.xZn_(1-m)Al_mO would result in a corresponding change in the ratio of the fluorescent emission peak of Zn_(1-m)Al_mO at 400˜600 not to the fluorescent emission peak of rare earth elements at 600˜625 nm, thereby achieving the color adjustability of the fluorescent powder due to the difference of the ratio. Meanwhile, the mechanisms of the fluorescent emissions of Zn_(1-m)Al_mO and rare earth elements are different. When the excitation voltages change, the intensity of the two emission peaks would also change. Therefore, the color adjustability of the fluorescent powder can be achieved by changing the excitation voltage.

It is Zn_(1-m)Al_mO which is conductive in the fluorescent powder. It is a compound semi-conductor, which can effectively lead out electrons accumulated on the surface of the fluorescent powder, leading to an increase of the luminescent brightness of the prepared fluorescent powder under the excitation of cathod rays.

Referring to FIG. 1, which shows a flow chart of the method for preparing a color-adjustable fluorescent powder of an embodiment of the present invention, the method comprised the steps of:

S01: preparing a solution of Zn²⁺and Al³⁺, and preparing a solution of Y³⁺, Eu³⁺ and Gd³⁺ or of Eu³⁺ and Gd³⁺or of Y³⁺ and Eu³⁺to molar ratio of corresponding elements in a chemical formula of (Y_aGd_bEu_c)₂O₃;
S02: taking the above solutions according to corresponding molar ratio in a chemical formula of (Y_aGd_bEu_c)₂O₃.xZn_(1-m)Al_mO , wherein 0≦a≦0.99, 0≦b≦0.99, 0.01≦c≦0.08, and a+b+c=1, a and b are not simultaneously 0, x is a molar ratio of Zn_(1-m)Al_mO to (Y_aGd_bEu_c)₂O₃, 0.01≦x≦0.20, and 0.001≦m≦0.05; and adding an alcohol-water mixed solution contain a complexing agent, and a surfactant to give a precursor solution; and
S03: aging the precursor solution, calcinating, cooling and milling to give the color-adjustable fluorescent powder.

In step S01, the solution of Zn²⁺and Al³⁺be prepared from corresponding soluble salts thereof, such as acetate, nitrate, chloride and sulfate. Specifically, the reactants are weighed in appropriate amounts and dissolved in de-ionized water in a container to give a solution in which the total concentration of Zn²⁺ and Al³⁺may be 0.1˜2.00 mol/L, and the molar ratio of Zn²⁺to Al³⁺may be 99.9:0.1˜95:5. The solution of Y³⁺, Eu³⁺and Gd³⁺(solution I) or of Eu³⁺and Gd³⁺(solution II) or of Y³⁺and Eu³⁺(solution III) may be prepared from corresponding soluble salts thereof, such as nitrate and chloride, or may be prepared from oxides or oxalates of the rare earth elements. When soluble salts are used, the preparation method is similar to that of solution of Zn²⁺and Al³⁺. When the oxides or oxalates of the rare earth elements is used, the specific procedure comprises: dissolving appropriate amounts of the oxides or oxalates of the rare earth elements in analytical pure hydrochloric acid. (36˜37%, 11.7 mol/L) or analytical pure nitric acid (65˜68%, 14.4˜15.2 mol/L) in a container at 15° C.˜100° C. under heating and stirring, and adding de-ionized water to achieve a required concentration.

Step S02 specifically comprises: weighing an appropriate amount of the prepared solution I or solution II or solution III; adding the prepared solution of Zn²⁺and Al³⁺while keeping the molar ratio of Zn²⁺ and Al³⁺to the solution I or solution II or solution III at (0.01˜0.20):1; adding an alcohol-water mixed solution contain a complexing agent, to prepare 40 mL of an alcohol-water solution of the solution I or solution II or solution III containing Zn²⁺and Al³⁺at a concentration of 0.1˜1.00 mol/L, wherein the volume ratio of water to alcohol is 1:(1˜7), and the molar ratio of citric acid to the metal ions in the raw material is kept at (1˜5):1; adding a surfactant into the solution to give a concentration of the surfactant of 0.05˜0.20 g/mL. The prepared alcohol-water solution of the solution I or solution II or solution III impregnated with Zn²⁺and Al³⁺is stirred for 2˜6 h in a 40˜70° C. water bath, and then placed in an oven at 60˜100° C. and aged for 40˜60 h to give a gel of the solution I or solution II or solution III impregnated with Zn²⁺ and Al³⁺. The complexing agent is preferably analytical pure citric acid. The surfactant is preferably at least one of analytical pure polyethylene glycol 6000, polyethylene glycol 8000, polyethylene glycol 10000, and polyethylene glycol 20000.

Step S03 specifically comprises: placing the prepared solution I or solution II or solution III impregnated with Zn²⁺and Al³⁺in an oven at 100˜200° C. and aging for 48˜96 h, drying, placing the dried product in a corundum crucible, calcinating for 0.5˜6 h at 800˜1300° C. in an air atmosphere, cooling, and milling.

The method for preparing the color-adjustable fluorescent powder employs a sol-gel method, wherein the product can be obtained by merely controlling the temperature and adding the reactants in an appropriated proportion. Therefore, the method for preparing the color-adjustable fluorescent powder has a simple process, low requirement on the equipments, and low preparation cycle.

Various compositions of the color-adjustable fluorescent powder and the methods for the preparation thereof and the performances thereof are illustrated by various examples.

EXAMPLE 1

21.9281 g of Zn(CH₃COO)₂.2H₂O and 0.0375 g of Al(NO₃)₃.9H₂O are weighed and dissolved in 100 mL of de-ionized water to prepared a 1 mol/L aqueous solution of Zn²⁺and Al³⁺, wherein the molar ratio of Zn²⁺to Al³⁺is 99.9:0.1.

37.9180 g of Y(NO₃)₃.6H₂O and 0.4441 g of Eu(NO₃)₃.6H₂O are weighed and dissolved in de-ionized water to prepare a 1 mol/L aqueous solution of Y³⁺and Eu³⁺, wherein the molar ratio of Eu³⁺to Y³⁺is 1:99.

To 4 mL of the 1 mol/L aqueous solution of Y³⁺ and Eu³⁺ are added 1 mL of de-ionized water and 35 mL of absolute ethanol, followed by adding 0.4 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 3.3817 g of citric acid and 2 g of polyethylene glycol 10000. The resulted mixture is stirred for 4 h in a 60° C. water bath to give a precursor solution of Y³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 90° C. and aged for 40 h to give a homogeneous gel of Y³⁺ and Eu³¹impregnated with Zn²⁺ and Al³⁺.

The prepared gel is placed in an oven at 100° C. and is dried for 48 h, and then kept in a muffle furnace at 800° C. for 2 followed by cooling and milling to give a fluorescent powder having a chemical formula of Y_1.98Eu_0.02O₃.0.1Zn_0.999Al_0.001O.

EXAMPLE 2

43.0220 g of Zn(CH₃COO)₂.2H₂O and 1.1502 of ZnSO₄.7H₂O are weighed and dissolved in 100 mL of de-ionized water to prepared a 2 mol/L aqueous solution of Zn²⁺and Al³⁺, wherein the molar ratio of Zn²⁺ to Al³⁺ is 98:2.

76.5254 g of Y(NO₃)₃.6H₂O and 0.8920 g of Eu(NO₃)₃.6H₂O are weighed and dissolved in de-ionized water to prepare a 2 mol/L aqueous solution of Y³⁺and Eu³⁺, wherein the molar ratio of Eu³⁺to Y³⁺ is 1:99.

To 20 mL of the 2.00 mol/L aqueous solution of Y³⁺and Eu³⁺added 20 mL of absolute ethanol, 0.2 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 7.7625 g of citric acid and 8 g of polyethylene, glycol 10000. The resulted mixture is stirred for 6 h in a 50° C. water bath to give a precursor solution of Y³⁺ and Eu³⁺ impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 60° C. and aged for 60 h to give a gel of Y³⁺ and Eu³⁺ impregnated with Zn²⁺ and Al³⁺.

The prepared gel is placed in an oven at 200° C. and is dried for 50 h, and then kept in a muffle furnace at 1000° C. for 3 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Y_1.98Eu_0.02O₃.0.01Zn_0.98Al_0.02O.

EXAMPLE 3

10.5769 g of ZnCl₂and 0.9003 g of Al(NO₃)₃.9H₂O are weighed and dissolved in 100 mL of de-ionized water to prepared a 0.8 mol/L aqueous solution of Zn²⁺and Al³⁺, wherein the molar ratio of Zn²⁺ to Al³⁺is 97:3.

18.7675 g of Y(NO₃)₃.6H₂O and 0.4461 g of Eu(NO₃)₃.6H₂O are weighed and dissolved in de-ionized water to prepare a 0.5 mol/L aqueous solution of Y³⁺ and Eu³⁺, wherein the molar ratio of Eu³⁺to Y³⁺is 1:49.

To 8 mL of the 0.50 mol/L aqueous solution of Y³⁺and Eu³⁺are added 32 mL of absolute ethanol, 0.5 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 4.2271 g of citric acid and 4 g of polyethylene glycol 8000. The resulted mixture is stirred for 6 h in a 40° C. water bath to give a precursor solution of Y³⁺and Eu³⁺impregnated with Zn²⁺ and Al³⁺. The precursor solution is then placed in an oven at 90° C. and aged for 60 h to give a gel of Y³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺.

The prepared gel is placed in an oven at 150° C. and is dried for 96 h, and then kept in a muffle furnace at 1300° C. for 0.5 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Y_1.96Eu_0.04O₃.0.1Zn_0.97Al_0.03O.

EXAMPLE 4

22.3147 g of ZnSO₄.7H₂O and 0.5794 g of AlCl₃.6H₂O are weighed and dissolved in 100 mL of de-ionized water to prepared a 0.8 mol/L aqueous solution of Zn²⁺ and Al³⁺, wherein the molar ratio of Zn²⁺ to Al³⁺is 97:3.

To 20 mL of the 1.00 mol/L aqueous solution of Y³⁺and Eu³⁺are added 20 mL of absolute ethanol, 1.25 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 4.0349 g of citric acid and 5 g of polyethylene glycol 20000. The resulted mixture is stirred for 4 h in a 60° C. water bath to give a precursor solution of Y³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 80° C. and aged for 56 h to give a gel of Y³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺.

The prepared gel is placed in an oven at 100° C. and is dried for 96 h, and then kept in a muffle furnace at 800° C. for 6 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Y_1.98Eu_0.02O₃.0.05Zn_0.97Al_0.03O.

EXAMPLE 5

22.3147 g of ZnSO₄.7H₂O and 0.5794 g of AlCl₃.6H₂O are weighed and dissolved in 100 mL of de-ionized water to prepared a 0.8 mol/L aqueous solution of Zn²⁺and Al³⁺, wherein the molar ratio of Zn²⁺to Al³⁺is 97:3.

28.6899 g of yttrium oxalate and 1.7201 g of europium oxalate are weighed and dissolved in 20 mL of nitric acid under stirring at 15° C., to which is added de-ionized water to make up to 100 mL to prepare a 1 mol/L aqueous solution of Y³⁺and Eu³⁺, wherein the molar ratio of Eu³⁺to Y³⁺is 1:19.

To 20 mL of the 1.00 mol/L aqueous solution of Y³⁺and Eu³⁺are added 20 mL of absolute ethanol, 0.75 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 7.9162 g of citric acid and 4 g of polyethylene glycol 10000. The resulted mixture is stirred for 4 h in a 70° C. water bath to give a precursor solution of Y³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 60° C. and aged for 60 h to give a gel of Y³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺.

The prepared gel is placed in an oven at 100° C. and is dried for 56 h, and then kept in a muffle furnace at 1000° C. for 2 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Y_1.90Eu_0.10O₃.0.03Zn_0.97Al_0.03O.

EXAMPLE 6

22.3147 g of ZnSO₄.7H₂O and 0.5794 g of AlCl₃.6H₂O are weighed and dissolved in 100 mL of de-ionized water to prepared a 0.8 mol/L aqueous solution of Zn²⁺and Al³⁺, wherein the molar ratio of Zn²⁺to Al³⁺is 97:3.

To 20 mL of the 1.00 mol/L aqueous solution of Y³⁺ and Eu³⁺are added 20 mL of absolute ethanol, 1.25 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 7.9162 g of citric acid and 4 g of polyethylene glycol 10000. The resulted mixture is stirred for 4 h in a 70° C. water bath to give a precursor solution of Y³⁺and Eu³⁺impregnated with Zn²⁺ and Al³⁺. The precursor solution is then placed in an oven at 60° C. and aged for 60 h to give a gel of Y³⁺ and Eu³⁺ impregnated with Zn²⁺ and Al³⁺.

EXAMPLE 7

10.7260 g of Y₂O₃and 0.8798 g of Eu₂O₃are weighed and dissolved in 27 mL of hydrochloric acid under stirring at 60° C., to which is added de-ionized water to make up to 100 mL to prepare a 1 mol/L aqueous solution of Y³⁺and Eu³⁺, wherein the molar ratio of Eu³⁺ to Y³⁺ is 1:19.

To 8 mL of the 1.00 mol/L aqueous solution of Y³⁺and Eu³⁺are added 32 mL of absolute ethanol, 1.6 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 7.3781 g of citric acid and 7 g of polyethylene glycol 6000. The resulted mixture is stirred for 4 h in a 60° C. water bath to give a precursor solution of Y³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 70° C. and aged for 60 h to give a gel of Y³⁺ and Eu³⁺ impregnated with Zn²⁺ and Al³⁺.

The prepared gel is placed in an oven at 120° C. and is dried for 48 h, and then kept in a muffle furnace at 1000° C. for 2 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Y_1.90Eu_0.10O₃.0.2Zn_0.999Al_0.001O.

EXAMPLE 8

2.8857 g of Zn(NO₃)₂.6H₂O and 0.0724 g of AlCl₃.6H₂O are weighed and dissolved in 100 mL of de-ionized water to prepared a 0.1 mol/L aqueous solution of Zn²⁺and Al³⁺, wherein the molar ratio of Zn²⁺to Al³⁺is 97:3.

42.4281 g of Gd(NO₃)₃.6H₂O and 2.6760 g of Eu(NO₃)₃.6H₂O are weighed and dissolved in de-ionized water to prepare 1 L of a 0.1 mol/L aqueous solution of Gd³⁺and Eu³⁺, wherein the molar ratio of Eu³⁺to Gd³⁺ is 3:47.

To 20 mL of the 0.1 mol/L aqueous solution of Gd³⁺ and Eu³⁺ are added 20 mL of absolute ethanol. 1.6 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 2.0751 g of citric acid and 5 g of polyethylene glycol 10000. The resulted mixture is stirred for 2 h in a 70° C. water bath to give a precursor solution of Gd³⁺ and Eu³⁺ impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 90° C. and aged for 40 h to give a gel of Gd³⁺ and Eu³⁺impregnated with Zn²⁺and Al³⁺.

The prepared gel is placed in an oven at 130° C. and is dried for 59 h, and then kept in a muffle furnace at 1100° C. for 2 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Gd_1.88Eu_0.12O₃.0.08Zn_0.97Al_0.03O.

EXAMPLE 9

14.1308 g of Zn(NO₃)₂.6H₂O and 0.9378 g of Al(NO₃)₃.9H₂O are weighed and dissolved in 100 mL of de-ionized water to prepared a 0.5 mol/L aqueous solution of Zn²⁺and Al³⁺, wherein the molar ratio of Zn²⁺ to Al³⁺is 95:5.

22.1166 g of Gd (NO₃)₃.6H₂O and 0.4461 g of Eu(NO₃)₃.6H₂O are weighed and dissolved in de-ionized water to prepare a 0.5 mol/L aqueous solution of Gd³⁺and Eu³⁺, wherein the molar ratio of Eu³⁺ to Gd³⁺is 1:49.

To 10 mL of the 0.5 mol/L aqueous solution of Gd³⁺and Eu³⁺ are added 8 mL of de-ionized water and 22 mL of absolute ethanol, 0.6 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 3.0550 g of citric acid and 4 g polyethylene glycol 10000. The resulted mixture is stirred for 6 h a 50° C. water bath to give a precursor solution of Gd³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 100° C. and aged for 40 h to give a gel of Gd³⁺and Eu³⁺ impregnated with Zn²⁺and Al³⁺.

The prepared gel is placed in an oven at 130° C. and is dried for 59 h, and then kept in a muffle furnace at 1200° C. for 2 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Gd_1.96Eu_0.04O₃.0.06Zn_0.95Al_0.05O.

EXAMPLE 10

62.5670 g of gadolinium oxalate and 1.7201 g of europium oxalate are weighed and dissolved in 20 mL of nitric acid under stirring at 60° C., to which is added de-ionized water to make up to 100 mL to prepare a 1 mol/L aqueous solution of Gd³⁺ and Eu³⁺, wherein the molar ratio of Eu³⁺to Gd³⁺ is 1:19.

To 8 mL of the 1 mol/L aqueous solution of Gd³⁺and Eu³⁺are added 32 mL of absolute ethanol, 0.4 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 3.2280 g of citric acid and 4 g of polyethylene glycol 10000. The resulted mixture is stirred for 6 h in a 70° C. water bath to give a precursor solution of Gd³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 90° C. and aged for 60 h to give a gel of Gd³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺.

EXAMPLE 11

34.4375 g of Y₂O₃and 0.8798 g of Eu₂O₃are weighed and dissolved in 20 mL of nitric acid under stifling at 40° C., to which is added de-ionized water to make up to 100 mL to prepare a 1 mol/L aqueous solution of Gd³⁺and Eu³⁺, wherein the molar ratio of Eu³⁺ to Gd³⁺ is 1:19.

To 20 mL of the 1.00 mol/L aqueous solution of Gd³⁺and Eu³⁺ are added 20 mL of absolute ethanol, 0.2 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 11.7590 g of citric acid and 4 g of polyethylene glycol 10000. The resulted mixture is stirred for 4 h in a 60° C. water bath to give a precursor solution of Gd³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 80° C. and aged for 56 h to give a gel of Gd³⁺and Eu³⁺ impregnated with Zn²⁺and Al³⁺.

The prepared gel is placed in an oven at 100° C. and is dried for 50 h, and then kept in a muffle furnace at 800° C. for 2 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Gd_1.9Eu_0.1O₃.0.01Zn_0.999Al_0.001O.

EXAMPLE 12

34.1964 g of GdCl₃and 2.8154 g of EuCl₃are weighed and dissolved in de-ionized water under stirring at 15° C. to prepare 1 L of a 0.1 mol/L aqueous solution of Gd³⁺and Eu³⁺, wherein the molar ratio of Eu³⁺to Gd³⁺ is 2:23.

To 20 mL of the 0.1 mol/L aqueous solution of Gd³⁺and Eu³⁺are added 20 mL of absolute ethanol, 2 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 0.8454 g of citric acid and 4 g of polyethylene glycol 10000. The resulted mixture is stirred for 4 h in a 60° C. water bath to give a precursor solution of Gd³⁺and Eu³⁺ impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 60° C. and aged for 60 h to give a gel of Gd³⁺and Eu³⁺impregnated with Zn²⁺ and Al³⁺.

The prepared gel is placed in an oven at 100° C. and is dried for 48 h, and then kept in a muffle furnace at 1200° C. for 2 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Gd_1.84Eu_0.16O₃.0.1Zn_0.97Al_0.03O.

EXAMPLE 13

14.1308 g of Zn(NO₃)₂.6H₂O and 0.9378 g of Al(NO₃)₃.9H₂O are weighed and dissolved in 100 mL of de-ionized water to prepared a 0.5 mol/L aqueous solution of Zn²⁺ and Al³⁺, wherein the molar ratio of Zn²+ to Al³⁺ is 95:5.

3.4471 g of Y(NO₃)₃.6H₂O, 18.0544 g of Gd(NO₃)₃.6H₂O and 0.4461 g of Eu(NO₃)₃.6H₂O are weighed and dissolved in de-ionized water to prepared a 0.5 mol/L aqueous solution of Y³⁺, Gd³⁺and Eu³⁺, wherein the molar ratio of Y³⁺, Gd³⁺, Eu³⁺ is 18:80:2.

To 10 mL of the 0.5 mat aqueous solution of Y³⁺, Gd³⁺and Eu³⁺ are added 5 mL of de-ionized water, 25 mL of absolute ethanol, 1.5 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 2.2096 g of citric acid and 4 g of polyethylene glycol 10000. The resulted mixture is stirred for 4 h in a 60° C. water bath to give a precursor solution of Y³⁺, Gd³⁺ and Eu³⁺ impregnated with Zn²⁺ and Al³⁺. The precursor solution is then placed in an oven at 70° C. and aged for 60 h to give a gel of Y³⁺, Gd³⁺and Eu³⁺ impregnated with Zn²⁺and Al³⁺.

The prepared gel is placed in an oven at 150° C. and is dried for 75 h, and then kept in a muffle furnace at 1200° C. for 2 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Y_0.36Gd_1.6Eu_0.04O₃.0.15Zn_0.95Al_0.05O.

EXAMPLE 14

43.0220 g of Zn(CH₃COO)₂.2H₂O and 1.1502 g Al₂(SO₄)₃are weighed and dissolved in 100 mL of de-ionized water to prepared a 2 mol/L aqueous solution of Zn²⁺and Al³⁺, wherein the molar ratio of Zn²⁺to Al³⁺is 98:2.

3.4471 g of Y(NO₃)₃.6H₂O, 40.6224 g of Gd(NO₃)₃.6H₂O and 0.4441 g of Eu(NO₃)₃.6H₂O are weighed and dissolved in de-ionized water to prepared a 1 mol/L aqueous solution of Y³⁺, Gd³⁺ and Eu³⁺, wherein the molar ratio of Y³+, Gd³⁺, Eu³⁺ is 9:90:1.

To 8 mL of the 1.00 mol/L aqueous solution of Y³⁺, Gd³⁺and Eu³⁺are added 32 mL of absolute ethanol, 0.2 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 3.2280 g of citric acid and 4 g of polyethylene glycol 10000. The resulted mixture is stirred for 4 h in a 60° C. water bath to give a precursor solution of Y³⁺, Gd³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 70° C. and aged for 60 h to give a gel of Y³⁺, Gd³⁺and Eu³⁺ impregnated with Zn²⁺and Al³⁺.

EXAMPLE 15

21.9281 g of Zn(CH₃COO)₂.2H₂O and 0.0375 g of Al(NO₃)₃.9H₂O are weighed and dissolved in 100 mL of de-ionized water to prepared a 1 mol/L aqueous solution of Zn²⁺and Al³⁺the molar ratio of Zn²⁺to Al³⁺is 99.9:0.1.

30.2000 g of yttrium oxalate, 29.6370 g of gadolinium oxalate and 1.7201 g of europium oxalate are weighed and dissolved in 27 mL of hydrochloric acid under stirring at 60° C., followed by adding de-ionized water to make up to 100 mL to prepare a 1 mol/L aqueous solution of Y³⁺, Gd³⁺ and Eu³⁺, wherein the molar ratio of Y³⁺, Gd³⁺, Eu³⁺is 50:45:5.

To 4 mL of the 1.00 mol/L aqueous solution of Y³⁺, Gd³⁺and Eu³⁺added 6 mL of de-ionized water, 30 mL of absolute ethanol, 0.48 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 2.5824 g of citric acid and 4 g of polyethylene glycol 10000. The resulted mixture is stirred for 4 h in a 60° C. water bath to give a precursor solution of Y³⁺, Gd³⁺ and Eu³⁺ impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 70° C. and aged for 60 h to give a gel of Y³⁺, Gd³⁺and Eu³⁺ impregnated with Zn²⁺and Al³⁺.

EXAMPLE 16

43.0220 g of Zn(CH₃COO)₂.2H₂O and 1.1502 g of Al₂(SO₄)₃are weighed and dissolved in 100 mL of de-ionized water to prepared a 2 mol/L aqueous solution of Zn²⁺and Al³⁺, wherein the molar ratio of Zn²⁺to Al³⁺is 98:2.

19.1939 g of Y₂O₃, 3.6250 g of Gd₂O₃and 0.8798 g of Eu₂O₃are weighed and dissolved in 27 m L of hydrochloric acid under stirring at 60° C., followed by added de-ionized water to make up to 100 mL to prepare a 1 mol/L aqueous solution of Y³⁺, Gd³⁺and Eu³⁺, wherein the molar ratio of Y³⁺, Gd³⁺, Eu³⁺ is 85:10:5.

To 10 mL of the 1.00 mol/L aqueous solution of Y³⁺, Gd³⁺ and are added 10 mL of de-ionized water, 20 mL of absolute ethanol, 0.2 mL of the prepared aqueous solution of Zn²⁺and Al³⁺, 3.9965 g of citric acid and 4 g of polyethylene glycol 10000. The resulted mixture is stirred for 4 h in a 60° C. water bath to give a precursor solution of Y³⁺, Gd³⁺and Eu³⁺ impregnated with Zn²⁺and Al³⁺. The precursor solution is then placed in an oven at 70° C. and aged for 60 h to give a gel of Y³⁺, Gd³⁺and Eu³⁺impregnated with Zn²⁺and Al³⁺.

The prepared gel is placed in an oven at 120° C. and is dried for 48 h, and then kept in a muffle furnace at 1300° C. for 2 h, followed by cooling and milling to give a fluorescent powder having a chemical formula of Y_1.7Gd_0.2Eu_0.1O₃.0.1Zn_0.98Al_0.02O.

The sample prepared in Example 6 is taken as an example. Refer to FIG. 2, which shows the spectra of the Y_1.90Eu_0.10O₃.0.05Zn_0.97Al_0.03O fluorescent powder prepared in the above Example 6 under the excitation of cathode rays, wherein a is the spectrum of the sample prepared in Example 6 under the excitation of cathode rays of 7 kV, and b is the spectrum of the sample prepared in Example 6 under the excitation of cathode rays of 5 kV. The spectra are obtained on Shimadzu RF-5301PC Spectrometer. FIG. 3 shows the color coordinates of the Y_1.90Eu_0.10O₃.0.05Zn_0.97Al_0.03O fluorescent powder prepared in Example 6 of the present invention under the excitation of cathode rays of 5 kV, and FIG. 4 shows the color coordinates of the Y_1.90Eu_0.10O₃.0.05Zn_0.97Al_0.03O fluorescent powder prepared in Example 6 of the present invention under the excitation of cathode rays of 7 kV. It can be seen from FIGS. 3 and 4 that the prepared fluorescent powder can achieve color adjustability under the excitation of cathode rays of different voltages. The color coordinates in FIG. 3 are; X=0.3406, Y=0.4074; ad the color coordinates in FIG. 4 are: X=0.3357, Y=0.4136.

FIG. 5 shows the spectra of the Y_1.90Eu_0.10O₃fluorescent powder blended with various proportions of Zn_0.97Al_0.03O prepared in Examples 5 ad 6 of the present invention under the excitation of cathode rays of 7 kV, wherein c is the emission spectrum of the Y_1.90Eu_0.10O₃.0.05Zn_0.97Al_0.03O fluorescent powder and d is the emission spectrum of the Y_1.90Eu_0.10O₃.0.05Zn_0.97Al_0.03O fluorescent powder. The spectra are obtained on Shimadzu RF-5301PC Spectrometer, it can be seen from the figure that the luminescent brightness of the prepared fluorescent powder under the excitation of cathode rays is increased because ZnAlO can effected lead out the electrons accumulated on the surface of the fluorescent powder. FIG. 6 shows the color coordinates of the Y_1.90Eu_0.10O₃.0.03Zn_0.97Al_0.03O fluorescent powder prepared in Example 5 of the present invention under the excitation of cathode rays of 7 kV; and FIG. 7 shows the color coordinates of the Y_1.90Eu_0.10O₃.0.05Zn_0.97Al_0.03O fluorescent powder prepared in Example 6 of the present invention under the excitation of cathode rays of 7 kV. It can be seen from FIGS. 6 and 7 that the prepared fluorescent powder comprising different proportions of Zn_(1-m)Al_mO can achieve color adjustability. The color coordinates in FIG. 6 are: X=0.5189, Y=0.3781; and the color coordinates in FIG. 7 are: X=0.3357, Y=0.4136.

It can be seen from the results in the Examples and Comparative Examples that in the method for preparing the color-adjustable fluorescent powder, a sol-gel method is employed, and a color-adjustable fluorescent powder having superior luminescent performance is prepared by controlling the ratio of the raw materials. The preparation method has a simple process and low cost and has a broad production and application prospect.

Described above are only preferred embodiments of the present invention, which are not intended to limit the present invention. All modifications, equivalent substitutions and improvements within the spirit and principle of the present invention shall be within the scope of the present invention.

Color Adjustable Luminescent Powder and Preparation Method Thereof

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