The present disclosure relates generally to photovoltaic devices, such as solar cells, and methods of manufacturing such photovoltaic devices.
Photovoltaic devices, such as solar cells, solar modules, or solar panels, harness energy from the sun to generate a voltage, thereby converting light energy to electric energy. The photovoltaic devices may be used in a range of different applications, including, but not limited to, aerial or space vehicles, residential homes, or consumer products. Despite the use of different connections, materials, components, or assembly during manufacturing to meet specific application needs, different types of products having photovoltaic devices may visibly appear to be substantially the same. This may cause confusion when handling the products in a factory that can result in unnecessary manufacturing delays to determine appropriate subsequent processing, which tends to increase manufacturing costs.
Accordingly, there exists a need for further improvements to photovoltaic devices and the manufacturing thereof that may make it easier to identify different products by simple techniques such as visual inspections.
The following presents a simplified summary of one or more aspects in order to provide a basic understanding of such aspects. This summary is not an extensive overview of all contemplated aspects, and is intended to neither identify key or critical elements of all aspects nor delineate the scope of any or all aspects. Its sole purpose is to present some concepts of one or more aspects in a simplified form as a prelude to the more detailed description that is presented later.
In an aspect, a photovoltaic device that produces a unique color code in a color code scheme to identify a particular product configuration of the photovoltaic device is provided. The photovoltaic device may include one or more photovoltaic cells having a top surface on which light is to be incident. The photovoltaic device may include a rear contact layer formed on a rear surface of the one or more photovoltaic cells, the rear contact layer including one or both of a composition or a thickness configured to produce a unique color code in a color code scheme visible to a user in areas of the photovoltaic device outside of areas covered by the one or more photovoltaic cells and corresponding to a particular product configuration of the photovoltaic device. The photovoltaic device may include a back reflector formed on a rear surface of the rear contact layer.
In another aspect, a method of forming a photovoltaic device that produces a unique color code in a color code scheme to identify a particular product configuration of the photovoltaic device is provided. The method may include forming one or more photovoltaic cells. The method may include forming a rear contact layer on a rear surface of the one or more photovoltaic cells. The method may include forming a reflector on a rear surface of the contact layer, wherein the one or more photovoltaic cells have a top surface on which light is to be incident, and wherein the rear contact layer includes one or both of a composition or a thickness configured to produce the unique color code in the color code scheme visible to a user in areas of the photovoltaic device outside of areas covered by the one or more photovoltaic cells and corresponding to the particular product configuration of the photovoltaic device.
To the accomplishment of the foregoing and related ends, the one or more aspects comprise the features hereinafter fully described and particularly pointed out in the claims. The following description and the annexed drawings set forth in detail certain illustrative features of the one or more aspects. These features are indicative, however, of but a few of the various ways in which the principles of various aspects may be employed, and this description is intended to include all such aspects and their equivalents.
The disclosed aspects will hereinafter be described in conjunction with the appended drawings, provided to illustrate and not to limit the disclosed aspects, wherein like designations denote like elements, and in which:
The detailed description set forth below in connection with the appended drawings is intended as a description of various configurations and is not intended to represent the only configurations in which the concepts described herein may be practiced. The detailed description includes specific details for the purpose of providing a thorough understanding of various concepts. However, it will be apparent to those skilled in the art that these concepts may be practiced without these specific details. In some instances, well known structures and components are shown in block diagram form in order to avoid obscuring such concepts.
Typically, different photovoltaic devices are manufactured using the same manufacturing flow, meaning the same manufacturing process may be used with little to no retooling of machinery to manufacture the different photovoltaic devices. Different photovoltaic devices may refer to different product configurations in which, for example, different types of solar cells may be used, different processes may be used, different numbers of solar cells may be used, different arrangements of the solar cells may be used, or different binning of the solar cells may be used. However, during the manufacturing process and/or after the manufacturing process, the different photovoltaic devices may visually appear to be the same or very similar devices. In other words, it may be difficult for someone in the manufacturing line to determine a particular product configuration of a photovoltaic device by a simple visual inspection. Typically, the use of one or more identification methods or techniques for visual identification of the photovoltaic devices has included reconfiguration of front metal patterns. However, these methods or techniques may result in additional costs due to retooling the manufacturing process and/or may result in films being processed with an incorrect front metal pattern. Moreover, changes to an anti-reflective coating (ARC) or to the front metal on a top or front side of the photovoltaic device to produce some form of visual identification may instead result in a loss of performance of the photovoltaic device. As such, other methods or techniques are needed to help identify different types of photovoltaic device products.
Aspects of the present application use color-coded patterns (e.g., colors or color codes that are part of a color code scheme) for epitaxial lift-off (ELO) films in order to distinguish or identify between different photovoltaic devices that would otherwise be visually similar. In this regard, the photovoltaic device may be made from epitaxially grown photovoltaic structures (e.g., photovoltaic or solar cells) that are separated from a growth substrate by removing a sacrificial layer through an ELO process. The photovoltaic structures removed from the growth structure may be referred to as ELO films and may include photovoltaic cells and/or other layers. In some instances, these photovoltaic cells may have a common contact layer and reflector at the bottom (e.g., back or rear contact layer, back or rear metal reflector), and the photovoltaic cells may be isolated by an etching process that exposes the rear contact layer between the photovoltaic cells before an ARC coating is deposited over both the photovoltaic cells and the exposed portion of the rear contact layer. In an example, the finished photovoltaic device is such that there are areas around the photovoltaic cells (e.g., streets or edges in the outer perimeter of the cells) that contain some amount of the rear contact layer exposed by the etching process. By adjusting the composition and/or thickness of the rear contact layer during a metal organic chemical vapor deposition (MOCVD) epitaxial growth operation, an aesthetic effect, including color, iridescence, transparency, etc., produced by the exposed portion may be controlled such that a unique visual effect can be achieved and can be used to identify other aspects of the photovoltaic device. For example, by changing the aesthetic or visual effect, it is then possible during the manufacturing flow to enable a color-coding scheme associated with the effect to assist in flow identification without any changes in tooling other than the epitaxial growth recipe. Moreover, changing the composition and/or the thickness of the rear contact layer produces minimal effects on the overall performance of the photovoltaic device, so adjustments to this layer to produce a desired visual identifier in the form of a unique color code for a particular product configuration should not have much of an effect on the photovoltaic device.
Turning now to the figures, examples of photovoltaic devices and methods of manufacturing the photovoltaic devices are described herein. It is to be understood that layers and components in the figures may not be drawn to scale and are instead drawn for illustrative purposes.
Referring to
Returning to
In an aspect, one or more of the layers of the photovoltaic cells 102 may include compound semiconductor materials (e.g., non-silicon based materials) such as group III-V semiconductor materials, although other types of compound semiconductor materials may also be used (e.g., group II-IV semiconductor materials). The group III-V semiconductor material may include one or more group III semiconductor materials and one or more group V semiconductor materials (e.g., one group III semiconductor material and one group V semiconductor material, multiple group III semiconductor materials and one group V semiconductor material, one group III semiconductor material and multiple group V semiconductor materials, or multiple group III semiconductor materials and multiple group V semiconductor materials).
The layers having the group III-V semiconductor materials may be formed through epitaxial growth. In an example, the layers may contain a combination of two or more of gallium (Ga), arsenic (As), aluminum (Al), indium (In), or phosphorus (P) (e.g., GaAs, AlGaAs, InGaP, AlInGaP, InGaAs, AlInGaAs, InGaAsP, or AlInP). In some examples, the compound semiconductor materials of the photovoltaic cells 102 may include p-type (or p-doped), n-type (or n-doped) semiconductor materials, and/or undoped or lightly doped semiconductor materials. During manufacturing, one or more of the layers of the photovoltaic cells 102 may be formed through epitaxial growth, including the layers having the compound semiconductor materials.
In an aspect, the photovoltaic device 100 may include a rear contact layer 104 and a back reflector 106. In an example, the rear contact layer 104 may be positioned between the photovoltaic cells 102 and the back reflector 106. The rear contact layer 104 may also be referred to as a back or bottom contact layer 104. The rear contact layer 104 may be a p-type contact layer, for example. The rear contact layer 104 may be formed during manufacturing of the photovoltaic cells 102, as described herein, on the back sides of the photovoltaic cells 102. The rear contact layer 104 may be formed of group III-V semiconductor materials, as described herein.
The back reflector 106 (also referred to as a back metal reflector) may include one or more materials configured to reflect traversing light back into the photovoltaic cells 102 to improve overall efficiency. Examples of the materials may include gold (Au), silver (Ag), copper (Cu), aluminum (Al), or other reflective metals, derivatives thereof, and/or combinations thereof. In some examples, the back reflector 106 may be deposited on a back surface of the rear-contact layer 104 during manufacturing. However, in other examples, one or more additional layers (e.g., dielectric layer) may be positioned between the rear contact layer 104 and the back reflector 106.
The photovoltaic device 100 may also include one or more front contacts 110 (or contact fingers) configured to conduct voltage and current, produced through a photovoltaic process, to external circuitry (not shown) corresponding to semiconductor layers (e.g., n-type or p-type semiconductor layers) of the photovoltaic cells 102. The one or more front contacts 110 may be located on a front or top side of the photovoltaic cells 102. In an aspect, the one or more front contacts 110 may include a metallic stack (e.g., metal contact stack) containing multiple layers of varying compositions of materials.
In an aspect, the photovoltaic device 100 may include an anti-reflective coating (ARC) layer 112 including one or more materials that are configured to allow light to pass through a front surface of the ARC layer 112 and prevent light reflection from the ARC layer 112. The ARC layer 112 may be disposed on different surfaces of the photovoltaic device 100, including surfaces of the photovoltaic cells 102, a front surface 120 of the rear contact layer 104, and surfaces of the one or more front contacts 110. In some examples, the ARC layer 112 may contain magnesium fluoride (MgF2), zinc sulfide (ZnS), titanium oxide (TiO), titanium dioxide (TiO2), niobium oxide (NbO, NbO2, or Nb2O5), silicon nitride (Si3N4), silicon oxynitride (SiOxNy), silicon oxide (SiO), silicon dioxide (SiO2), derivatives thereof, or combination thereof. In some examples, the ARC layer 112 may be made of one or more layers of material.
As shown in
Referring to
In an aspect, the photovoltaic device 200 may be formed during a manufacturing process and include a plurality of photovoltaic cells 202 that correspond to the first application described above in connection with the photovoltaic cells 102 or to a second application (e.g., one of space vehicle, residential home, or consumer product) different from the first application for the photovoltaic cells 102. In either case, the photovoltaic device 200 and the photovoltaic cells 202 may be configured for a particular product that is different from the product associated with the photovoltaic device 100 and the photovoltaic cells 102. A gap or area 250 may be formed between each of the photovoltaic cells 202 in order to isolate one from another. In an example, the photovoltaic cells 202 may be formed using the above-described materials of the photovoltaic cells 102.
In an aspect, the photovoltaic device 200 may include a rear contact layer 204 and a back reflector 206. In an example, the rear contact layer 204 and the back reflector 206 may be positioned and formed of materials as described herein for the rear contact layer 104 and the back reflector 106, respectively.
The photovoltaic device 200 may also include the one or more front contacts 110 deposited on the photovoltaic cells 202 and the ARC layer 112 deposited on different surfaces of the photovoltaic device 200, including surfaces of the photovoltaic cells 202, a front surface 220 of the rear contact layer 204, and surfaces of the one or more front contacts 110.
As shown in
Referring back to
As noted above, the color, also referred to as the color code, that is visible to a user from the gap 150 (or area) and used to identify the type of product configuration of the photovoltaic device 100 may be determined based on the thickness and/or the composition of the rear contact layer 104, which is exposed to the user in the gap 150. For example, a greater thickness may produce one color or color code in the color code scheme, while a smaller thickness may produce a different color or color code in the color code scheme, each of which is configured according to a corresponding product configuration of the photovoltaic device 100. Similarly, one composition (e.g., semiconductor material, molar composition, and/or doping) may produce one color or color code in the color code scheme, while a different composition may produce a different color or color code in the color code scheme, each of which is configured according to a corresponding product configuration of the photovoltaic device 100. Generally changing the thickness and/or the composition of the rear contact layer 104 need not have a significant impact on the functionality of the rear contact layer 104.
Prior to manufacturing of the photovoltaic device 100 a thickness of the rear contact layer 104 may be selected based on a particular product or product configuration of the photovoltaic device 100. For example, different thickness may be used such that different visible colors (e.g., different color codes from a gamut in a color code scheme) are produced for different products or product configurations, where the different products or product configurations may be used for the same application or for different applications.
During manufacturing, the rear contact layer 104 may be epitaxially grown to a particular thickness that corresponds to the desired color code. The thickness of the rear contact layer 104 may affect reflectivity and/or absorption of visible wavelengths resulting in a change in visible coloring characteristics. For example, a thickness of the rear contact layer 104 may be selected in which a first color code may correspond to a thickness 130 of the rear contact layer 104. As shown by
However, in other examples, such as in the example in
The different color codes in the color scheme may include, for example, reds, pinks, purples, and blues, where smaller thicknesses of the rear contact layer may correspond to blue and purple colors (e.g., colors with smaller visible wavelengths) and larger thicknesses of the rear contact layer may correspond to red and pink colors (e.g., colors with larger visible wavelengths). For example, a first color code (e.g., color code 1) produced by a visual inspection of the rear contact layer 104 having the thickness 130 may be a red color code that identifies the photovoltaic device 100 as being associated with one product, while a second color code (e.g., color code 2) produced by a visual inspection of the rear contact layer 204 having the thickness 230 may be a purple color that identifies the photovoltaic device 200 as being associated with another product. In this example, two different products may be visually identified by using two different thicknesses for the rear contact layer.
In another example, a first color code produced by a visual inspection of the rear contact layer 104 made with a first composition may identify the photovoltaic device 100 as being associated with one product, while a second color code produced by a visual inspection of the rear contact layer 104 made with a second composition may identify the photovoltaic device 100 as being associated with another product. In this example, two different products may be visually identified by using two different compositions to make the rear contact layer.
In yet another example, a first color code produced by a visual inspection of the rear contact layer 104 having the thickness 130 and made with a first composition may identify the photovoltaic device 100 as being associated with one product, while a second color code produced by a visual inspection of the rear contact layer 204 having the thickness 230 and made with a second composition may identify the photovoltaic device 200 as being associated with another product. In this example, two different products may be visually identified by using two different combinations of thickness and composition to make the rear contact layer.
Referring to
At 304, the method 300 may also include forming a rear contact layer on a back surface of the one or more semiconductor layers. For example, the rear contact layer 104 may be formed on the back surface of the one or more semiconductor layers that form the photovoltaic cells 102. In an example, the rear contact layer 104 may be formed by epitaxial growth on the one or more semiconductor layers. Further, a composition and/or a thickness of the rear contact layer 104 may be determined based on an application of the photovoltaic device 100. The determination of the composition and/or thickness of the rear contact layer 104 may control aesthetic characteristics of the unique color code of the photovoltaic device 100 which corresponds to the application/product of the photovoltaic device 100, as disclosed herein.
At 306, the method 300 may also include depositing a back reflector on a back surface of the rear contact layer. For example, the back reflector 106 may be deposited on the back surface of the rear contact layer 104.
At 308, the method 300 may also include performing an epitaxial lift-off (ELO) operation to separate the substrate from the one or more semiconductor layers. For example, a sacrificial layer may be formed between the one or more semiconductor layers and the substrate, and the ELO operation may include an etching process performed to remove the sacrificial layer, thereby separating the one or more semiconductor layers from the substrate. In some examples, the rear contact layer and/or the back reflector may be formed after the separation of the photovoltaic cells 102 from the substrate.
At 310, the method 300 may also include performing isolation etching. For example, an etching process may be performed to form the gaps 150 between the photovoltaic cells 102 and the edges of the photovoltaic device 100. Further, the isolation etching may expose the surface of the rear contact layer 104 such that the surface 120 is visibly exposed such that the unique color code produced by the rear contact layer 104 may be visible to a user.
At 312, the method 300 may also include depositing front contacts on the photovoltaic cells. For example, the front contacts 110 may be deposited on the photovoltaic cells 102.
At 314, the method 300 may include depositing an ARC layer on the photovoltaic device. For example, the ARC layer 112 may be deposited on the surface (e.g., color code surface 120) of the rear contact layer 104, and one or more surfaces of the photovoltaic cells 102 and the front contacts 110.
At 316, the method 300 may include verifying a color code of the photovoltaic device corresponds to an application/product of the photovoltaic device. For example, a verification camera may be used to verify that the unique color code produced by the photovoltaic device 100 corresponds to the correct application/product of the photovoltaic device 100.
Referring to
The pre-processing inspection system 405 may be used to verify or ensure the color code of a particular photovoltaic cell as described above in 315 of the method 300.
It is understood that the specific order or hierarchy of blocks in the processes/flowcharts disclosed is an illustration of exemplary approaches. Based upon different implementations, it is understood that the specific order or hierarchy of blocks in the processes/flowcharts may be rearranged. Further, some blocks may be combined or omitted. The accompanying method claims present elements of the various blocks in a sample order, and are not meant to be limited to the specific order or hierarchy presented.
The previous description is provided to enable any person skilled in the art to practice the various aspects described herein. Various modifications to these aspects will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other aspects. Thus, the claims are not intended to be limited to the aspects shown herein, but is to be accorded the full scope consistent with the language claims, wherein reference to an element in the singular is not intended to mean “one and only one” unless specifically so stated, but rather “one or more.” The word “exemplary” is used herein to mean “serving as an example, instance, or illustration.” Any aspect described herein as “exemplary” is not necessarily to be construed as preferred or advantageous over other aspects. Unless specifically stated otherwise, the term “some” refers to one or more.
Combinations such as “at least one of A, B, or C,” “one or more of A, B, or C,” “at least one of A, B, and C,” “one or more of A, B, and C,” and “A, B, C, or any combination thereof” include any combination of A, B, and/or C, and may include multiples of A, multiples of B, or multiples of C. Specifically, combinations such as “at least one of A, B, or C,” “one or more of A, B, or C,” “at least one of A, B, and C,” “one or more of A, B, and C,” and “A, B, C, or any combination thereof” may be A only, B only, C only, A and B, A and C, B and C, or A and B and C, where any such combinations may contain one or more member or members of A, B, or C. All structural and functional equivalents to the elements of the various aspects described throughout this disclosure that are known or later come to be known to those of ordinary skill in the art are expressly incorporated herein by reference and are intended to be encompassed by the claims. Moreover, nothing disclosed herein is intended to be dedicated to the public regardless of whether such disclosure is explicitly recited in the claims. The words “module,” “mechanism,” “element,” “device,” and the like may not be a substitute for the word “means.” As such, no claim element is to be construed as a means plus function unless the element is expressly recited using the phrase “means for.”
This application claims the benefit of U.S. Provisional Application No. 63/083,250, entitled “Color-Coded Patterns for Epitaxial Lift-Off (ELO) Films Background” and filed on Sep. 25, 2020, which is expressly incorporated by reference herein in its entirety.
Number | Date | Country | |
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63083250 | Sep 2020 | US |