Patent Application
20200017643
The present invention relates to a color masterbatch composition, and more particularly to a color masterbatch composition for textiles or engineering plastics and an article produced therefrom.
Dark textiles are commonly used in clothing, curtains and sofas, and dark engineering plastics are widely used in electrical appliances and automotive components; they have a good shading and dirt avoidance. Generally, the pre-spinning coloring of dark textiles or engineering plastics is obtained by adding carbon black which is easily obtained as a pigment to the raw materials, but the problems of easily absorbing infrared light and causing its products to be rapidly increased in temperature are thus generated.
Taiwan patent TW 1509038 discloses an infrared low temperature-rise pigment composition, capable of reducing the temperature rise caused by the absorption of infrared light by selecting specific pigments to combine. However, it is noted that the plastic films formed by most of the pigment compositions disclosed in the above patents and thermoplastic polyesters cannot maintain the original colors of the pigment compositions after the necessary processing of the textiles or engineering plastics (e.g. heating at 285-300° C.); they must be further dyed after the products are formed, and the dark textiles (post-spinning coloring) or engineering plastics can then be produced such that the processing complexity and wastewater pollution are increased.
The first object of the disclosure is to provide a color masterbatch composition, capable of overcoming the above shortcomings.
The color masterbatch composition of the disclosure includes thermoplastic polyester, a yellow colorant component, a red colorant component, and a blue colorant component. The yellow colorant component is selected from Pigment Yellow 147, Pigment Yellow 181, Pigment Yellow 183, Dye Brown 53, or a combination thereof The red colorant component is selected from Pigment Red 122, Pigment Red 144, Pigment Red 202, Pigment Red 214, or a combination thereof The blue colorant component is selected from Pigment Blue 60, Dye Blue 67, or a combination thereof, the above colorants is expressed in color index common names
The second object of the disclosure is to provide a colloidal particle, obtained by developing the color masterbatch composition in a base material mainly composed of thermoplastic polyester.
The third object of the disclosure is to provide a fiber, obtained by drawing the above colloidal particle.
The fourth object of the disclosure is to provide a prepreg, obtained by molding the above colloidal particle.
The above and other purposes, features and advantages of the present invention will become apparent with reference to the following detailed description and preferred embodiments.
Unless otherwise defined, all technical and scientific terms used herein have a common understanding among those skilled in the art. Those skilled in the art will recognize many methods and materials similar or equivalent to those described herein, which can be used to implement the present invention. Of course, the present invention is by no means limited by the described methods and materials.
The present disclosure provides a color masterbatch composition, including thermoplastic polyester, a yellow colorant component, a red colorant component, and a blue colorant component. The yellow colorant component is selected from Pigment Yellow 147, Pigment Yellow 181, Pigment Yellow 183, Dye Brown 53, or a combination thereof The red colorant component is selected from Pigment Red 122, Pigment Red 144, Pigment Red 202, Pigment Red 214, or a combination thereof The blue colorant component is selected from Pigment Blue 60, Dye Blue 67, or a combination thereof The present invention further provides a colloidal particle that is obtained by developing the above masterbatch composition in a base material mainly composed of a thermoplastic polyester. The above colorants are expressed according to color index common names
In some embodiments, the color masterbatch composition may further include titanium dioxide. With the total weight of the color masterbatch component being 100 wt %, the content range of the titanium dioxide can be greater than 0 wt % to 5 wt %.
Examples of thermoplastic polyesters suitable for use in the present disclosure include, but are not limited to, polyethylene terephthalate (PET), polybutylene terephthalate (PBT), functionalized derivatives of PET, functionalized derivatives of PBT, copolymers thereof, or blenders thereof
According to the disclosure, the total weight of the color masterbatch composition is 100 wt %, the content of the red colorant component may range from 8 wt % to 15 wt %. The total weight of the color masterbatch composition is 100 wt %, and the content of the yellow colorant component ranges from 7 wt % to 15 wt %. The total weight of the color masterbatch is 100 wt %, and the content of the blue colorant component ranges from 5 wt % to 15 wt %.
In some embodiments, the total weight of the color masterbatch composition is 100 wt %, and the yellow colorant component is dye brown 53 with content ranging from 7 wt % to 10 wt %.
In some embodiments, the blue colorant component is dye blue 67 with content ranging from 5 wt % to 10 wt %.
According to the present disclosure, the color masterbatch composition may also include existing additives such as ultraviolet absorbers, antioxidants, flame retardants, or combinations thereof
In addition, the present disclosure provides a colloidal particle that is obtained by developing the above masterbatch composition in a base material mainly composed of thermoplastic polyester. The present disclosure also discloses a method for preparing a colloidal particle, including developing the above color masterbatch composition in a base material mainly composed of thermoplastic polyester. In some embodiments, the content of the color masterbatch ranges from 1 wt % to 10 wt %, with the total weight of the colloidal particles being 100 wt %.
According to the disclosure, the thermoplastic polyester in the base material may be the same as or different from the thermoplastic polyester in the above color masterbatch composition.
Furthermore, it is found that processed articles (such as fibers or plastics) made from the above colloidal particles have the effect of slowing down and reducing heat absorption and maintain its original color during the necessary processing to allow them to be conducive to be applied in textiles or engineering plastics, especially dark textiles or engineering plastics.
Therefore, the disclosure also discloses a method for preparing a fiber, including the fiber drawing of the above colloidal particle. The above fiber drawing can be carried out according to the operating conditions conventionally used in the art, for example, 285-300° C.
The disclosure also provides a plastic material which is obtained by molding the above colloidal particle. The disclosure also provides a method for preparing a plastic material, including molding the above colloidal particle. According to the disclosure, the examples of the plastic material include, but are not limited to, a prepreg and thin plastic film
As used herein, the term “molding” means a method of forming a raw material using a mold or a matrix. Examples of molding methods suitable for the present disclosure include, but are not limited to, injection molding, extrusion molding, compression molding, and rotational molding and similar methods. The molding can be carried out according to the operating conditions conventionally used in the art, for example, 285° C. to 300° C.
The disclosure will be described with reference to the following embodiments, but it should be understood that the embodiments are merely illustrative and not to be construed as limiting.
The colorants were mixed into the pulverized thermoplastic polyester granules according to the content ratio of Table 1 below, and further subjected to extrusion kneading at 240-280° C. in a twin-screw extruder to obtain the color masterbatch compositions of the implementation examples A1 to A32.
The colorant was added to the pulverized thermoplastic polyester granules according to the content ratio of Table 2 below (95 wt % total), and 5 wt % of titanium dioxide was added, followed by extrusion at 240-280° C. in a twin-screw extruder. The mixture was kneaded to obtain the color masterbatch compositions of implementation examples B1 to B32.
The steps of implementation examples C1 to C32 and D1 to D32 are similar to those of implementation examples A1 to A32 and B1 to B32, respectively. The difference is that PBT replaces PET to prepare the masterbatch compositions of implementation examples C1-C32 and D1-D32, respectively.
Carbon black (30 wt %) was added to the pulverized thermoplastic polyester granules (70 wt %), and further subjected to extrusion kneading at 240-280° C. in a twin-screw extruder to obtain the color masterbatch composition of comparative example CB. In addition, the colorants were added to the pulverized thermoplastic polyester granules according to the content ratios in Table 3 below, and then subjected to extrusion kneading at 240 to 280° C. in a twin-screw extruder to obtain the color masterbatch compositions of comparative examples Z1 to Z4.
The color masterbatch compositions of the above implementation examples A1 to A32, B1 to B32, C1 to C32 and D1 to D32 were pelletized and then added to PET for color development (the color masterbatch composition accounted for 6 wt % of the total weight) to obtain the PET colloidal particles PETA1 to A32, PETB1 to B32, PET C1 to C32 and PETD1 to D32 of application example 1.
The PET colloidal particles PETA1 to A32, PETB1 to B32, PETC1 to C32 and PETD1 to D32 of above application example 1 were drawn at 285 to 300° C. to obtain fibers FA1 to A32, FB1 to B32, FC1 to C32 and FD1 to D32 (the fiber fineness is 3 DPF) of application example 2, where fibers FA1 to A32 and FB1 to B32 are black, and FC1 to C32 and FD1 to D32 are dark grey, which can be suitable for dark textiles.
The PET colloidal particles PETA1 to A32, PETB1 to B32, PETC1 to C32 and PETD1 to D32 of the above application example 1 were shot at 285-300° C. to obtain the prepregs SA1 to A32, SB1 to B32, SC1 to C32 and SD1 to D32 of application example 3, where the prepregs SA1 to A32 and SB1 to B32 are black, and the prepregs SC1 to C32 and SD1 to D32 are dark gray, which can be applied to dark engineering plastics.
The color masterbatch composition of the above comparative example CB and Z1 to Z4 was pelletized and then added to PET for color development (the color masterbatch composition accounted for 5.5 wt % of the total weight) to obtain the carbon black PET colloidal particles PETCB and black PET colloidal particles PETZ1-Z4 of comparative application example 1.
The carbon black PET colloidal PETCB of comparative application example 1 and the black PET colloidal particles PETZ1 to Z4 of comparative application example 2 were drawn at 285 to 300° C. to obtain fibers FCB and FZ1 to Z4 of comparative application example 3, respectively, where the fibers FZ1 to Z4 are all faded and close to brown, and cannot be directly applied to dark textiles.
The PET colloidal particles are irradiated at 23° C. with an infrared lamp (Philips PA 38 I Red 150W 125-130V, wavelength range 600 to 1400 nm) at a distance 17 cm between them for 55 minutes, and an infrared thermometer is used to measure the temperature of the PETCB of the above comparative application example 1 and the PET colloidal particles of application example 1 every 5 minutes, respectively, and the results are shown in Table 4 below.
The infrared heating test results of Table 4 show that the temperature of PETA1-A32 prepared by using the color masterbatch composition of the disclosure is below 67° C. after 10 minutes of infrared absorption and below 74° C. after 55 minutes of infrared absorption, while the temperature of the carbon black PET colloidal particle PETCB prepared by carbon black has already been higher than 100° C. after 10 minutes of infrared absorption, which indicates that the heating rate is faster and the temperature rise is larger.
In addition, the heating test results of PETB1 to B32, PETC1 to C32 and PETD1 to D32 were similar to those of PETA1 to A32, respectively. The above experimental results show that the color masterbatch composition of the disclosure can slow down and reduce the heating effect caused by infrared absorption.
In summary, the color masterbatch composition of the present disclosure can slow down and reduce the temperature rise effect caused by absorbing infrared rays without additionally adding other heat dissipating materials or modifying, and Its original color can still be maintained during the processing of preparing fibers or plastics such that it is suitable for the preparation of dark textiles or engineering plastics, so it is indeed possible to achieve the objects of the present invention.
The above is only the embodiments of the present invention, and the scope of the present invention is not limited thereto, that is, the simple equivalent changes and modifications made in the claims and the description of the present invention still fall in the scope of the present invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 106105677 | Feb 2017 | TW | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/IB2018/050864 | 2/13/2018 | WO | 00 |
