Claims
- 1. Colored polyester composition comprising a linear thermoplastic or unsaturated cross-linkable polyester containing a coloring amount of a dye component comprising the copolymerized residue of one or more dyes of the formula ##STR12## wherein either or both of rings A and B may contain in any position thereon one or two groups of the formula ##STR13## R and R.sup.3 each is hydrogen, lower alkyl or hydroxy substituted lower alkyl; R.sup.1, R.sup.2, R.sup.4 and R.sup.5 each represents hydrogen or 1-3 substituents selected from lower alkyl, lower alkyl substituted with lower alkoxy, phenyl, Cl, Br, or lower alkanoylamino, lower alkoxy, lower alkoxy substituted with lower alkoxy, phenyl, Cl, Br, or lower alkanoylamino, chlorine, bromine, amino, lower alkylamino, lower alkylamino substituted with lower alkoxy, cyclohexyl, phenyl, Cl, Br, or lower alkanoylamino, arylamino, arylthio, aroylamino, lower alkylsulfonyl, lower alkylthio, lower alkanoylamino, and cyclohexylamino, wherein each aforesaid aryl moiety is 6-10 carbons; X is --S-- or --NH--; n is 1 or 2; m is 0, 1, or 2; and wherein from about 5 to about 200 parts of copper phthalocyanine is admixed therewith, said parts being per million parts of polyester.
- 2. The composition of claim 1 wherein the dye component is 1,5-bis(2-carboxyphenylthio)anthraquinone or 1,5-bis(o-carboxyanilino)anthraquinone or mixtures thereof, each being present in a concentration of from about 1.0 part per million to about 3.0 percent by weight of the polyester.
- 3. The composition of claim 2 wherein the polyester is prepared from dimethyl terephthalate and a diol component comprising ethylene glycol and, based on total moles of diol, from 0 to about 30 mole % of 1,4-cyclohexanedimethanol, and up to about 5 mole % of diethylene glycol, each dye is present in reacted form in a concentration of from about 2.0 to about 1500 parts per million parts of polyester.
- 4. The composition of claim 1 wherein the polyester is unsaturated and is prepared from one or more diols, fumaric or maleic acid and up to about 60 mole percent of total acid component of one or a mixture of o-phthalic, isophthalic, and terephthalic acids, and wherein each dye is present in reacted form in a concentration of from about 2.0 to about 1500 parts per million parts of polyester.
- 5. The composition of claim 4 wherein the diol component comprises one or more of propylene glycol, neopentyl glycol, 2,2,4-trimethyl-1,3-pentanediol, ethylene glycol, and diethylene glycol.
- 6. The composition of claim 5 wherein the diol is propylene glycol and the acid component comprises in a mole ratio of from about 1/2 to about 2/1 o-phthalic anhydride and maleic anhydride.
- 7. The composition of claim 1, wherein the dye component comprises one or both of the dyes of the formulae ##STR14## wherein X and R are as defined therein.
Parent Case Info
This is a continuation-in-part of application Ser. No. 265,524, now abandoned, filed May 20, 1981, which is a continuation-in-part of application Ser. No. 147,978, filed May 8, 1980, now abandoned.
US Referenced Citations (5)
Foreign Referenced Citations (3)
Number |
Date |
Country |
1450575 |
Aug 1966 |
FRX |
838716 |
Jun 1960 |
GBX |
852646 |
Oct 1960 |
GBX |
Non-Patent Literature Citations (2)
Entry |
Kunststoffhandbuch, vol. VIII, Polyester, 1973, Carl Hanser Verlag, Munchen, pp. 250-261. |
Encyclopedia of Polymer Science and Technology, vol. 11, 1969, Interscience Publishers, N.Y., pp. 139-153. |
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
265524 |
May 1981 |
|
Parent |
147978 |
May 1980 |
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