The present invention pertains to a combined cycle power plant for the generation of electric power having a gas turbine, a steam turbine, and a heat recovery steam generator, and furthermore a plant for the capture and compression of carbon dioxide. The invention pertains in particular to an integration of a liquefied natural gas processing system with the power plant.
Combined cycle power plants for the generation of electricity are known to include a gas turbine, a steam turbine, and a heat recovery steam generator utilizing the hot flue gases emitted by the gas turbine to generate steam to drive the steam turbine. In order to reduce emissions that contribute to the greenhouse effect, various measures have been proposed to minimize the amount of carbon dioxide emitted into the atmosphere. Such measures include the arrangement of systems in the power plant that capture and process CO2 contained in the flue gases exhausted by a heat recovery steam generator HRSG or a coal-fired boiler. Such CO2 capture processes operate for example on the basis of chilled ammonia or amine processes. In order to work effectively, both of these processes require that the flue gases are cooled to temperatures below 10° C. Furthermore, for the captured CO2 to be transported and stored economically, it is purified, separated from water, chilled, compressed, and liquefied. For this, among others, sufficiently cold heat exchange media need to be provided at economical conditions. A CO2 capture plant of this type requires a given amount of energy, which reduces the overall efficiency of the power plant. In order to design a combined cycle power plant with CO2 capture more energy efficiently, it has been proposed to use the cold energy from the LNG regasification for some power plant processes.
JP2000024454 discloses the use of vaporization heat of LNG to cool waste gases and solidify carbon dioxide contained in the waste gases. JP60636999 discloses the use of cold heat generated upon the evaporation of LNG to recover carbon dioxide from exhaust gas as liquefied carbon dioxide. WO 2008/009930 discloses the use of such cold energy in an air separation unit to produce nitrogen and oxygen.
U.S. Pat. No. 6,367,258 discloses the vaporization of liquefied natural gas for a combined cycle power plant, where the cold energy of the vaporization is utilized for the chilling of gas turbine intake air, steam turbine condenser cooling water, or a first heat transfer fluid intended to cool components in the gas turbine.
Velautham et al., <<Zero emission combined Power cycle using LNG cold>>, JSME International Journal, Series B, Vol. 44, No. 4, 2001, discloses the use of liquefied natural gas cold for cooling air in heat exchange with air in view of separating oxygen from the air for further use in a combined cycle power plant. The use of liquefied natural gas cold reduces the energy consumption of the oxygen-air-separation process. The use of liquefied natural gas cold energy in heat exchange with CO2 for its liquefication is also disclosed.
The WO2007/148984 discloses a LNG regasification plant in which natural gas is burned in pure oxygen. The plant also comprises a boiler and a steam turbine to generate electricity from the hot combustion gases. From the resulting flue gas CO2 is separated by condensation of water vapor. Further, CO2 is cooled against LNG for liquefaction.
The U.S. Pat. No. 5,467,722 discloses a combined cycle power plant with a subsequent CO2 capture system and a LNG regasification plant. The CO2 capture system comprises heat exchangers, which cool the flue gas for cryogenic CO2 capture using liquid LNG as a heat sink.
It is an object of the present invention to provide a combined cycle power plant operating with a CO2 capture plant having increased power plant efficiency over known power plants of this type.
A combined cycle power plant comprises a gas turbine, a steam turbine, and a heat recovery steam generator (HRSG), both turbines driving a generator. The power plant comprises furthermore a CO2 capture system operating on the basis of a chilled ammonia or an amine process and arranged to process exhaust gases from the HRSG. According to the invention the combined cycle power plant comprises a liquefied natural gas regasification system, which comprises heat exchangers operatively connected with one or more heat exchangers within the CO2 capture system.
The regasification of the liquefied natural gas LNG provides the cold energy necessary to operate cooling processes in the CO2 capture system. The heat gained by the heat exchange medium in that cooling process is in turn used to support the regasification process of the LNG. The LNG regasification system and the cooling systems of the CO2 capture system are integrated in a closed circuit system. This integration reduces the amount of energy needed to operate the CO2 capture system and LNG system, which otherwise would to be provided by other means, for example by steam extraction and electricity from the power plant. It therefore mitigates the efficiency reduction due to the CO2 capture process and LNG regasification processes.
In an embodiment of the invention, the LNG regasification system comprises one or more heat exchangers, configured for the operation at a specific temperature range of the natural gas in a cascaded arrangement, form a LNG inlet temperature up to ambient temperature, for heat exchange between the LNG on the cold stream side and a heat exchange medium on the hot stream side of the heat exchanger. The heat exchange medium on the hot stream side has cryogenic or chilling temperatures at the output of the heat exchanger depending on the cold requirements of the process. The chilling temperatures can be for example in the range from above a cryogenic temperature (cryogenic temperatures are temperatures below −150° C.) up to 10° C. or even up to ambient temperature, or in an embodiment in a range from 5° C. to 2° C. for chilled ammonia process applications.
In a further embodiment, the CO2 capture system is arranged for the chilled ammonia process. In order to support this process, the power plant comprises lines to direct the heat exchange medium from this regasification heat exchanger generating a medium having cryogenic or chilling temperatures to one or more refrigeration systems within the CO2 capture system, where the refrigeration systems are
In a further embodiment of the invention, the CO2 absorption system is a system for the removal of the CO2 from flue gases by means of an amine process and the system for the LNG regasification is operatively connected to cooling systems within this CO2 absorption system. This amine process system requires a heat exchange medium for cooling the absorption lean solution to temperatures of about 45° C. As is the case in the embodiments above, the use of cooling power from the LNG system mitigates the efficiency reduction due to the CO2 capture process. In a particular embodiment of the invention, lines lead from the heat exchanger of the LNG system to a cooler for amine process lean solution and back to the heat exchanger.
The heat exchangers are arranged in a cascaded way (the natural gas output temperature of a heat exchanges is the input temperature of the subsequent heat exchanger, and the natural gas is heated up form an LNG inlet cryogenic temperature up to −10° C. or more, preferably up to 0° C. or up to ambient temperature), and each of the heat exchangers of the LNG regasification system is configured and arranged for heat exchange within a specific temperature range based on load and temperature requirements of the cold utilities (such as an air separation unit, a CO2 liquefaction process, a chilled ammonia CO2 capture process, cooling requirements in combined cycle power plants, etc) optimized via process integration. More specifically in one exemplary embodiment the natural gas temperature range in the first heat exchanger is defined by the cryogenic inlet temperature of the LNG as well as the requirements of the cold utility and heat exchange medium on the hot stream side of this first heat exchanger. The boiling temperature of the LNG at the regasification pressure can be used as the natural gas outlet design temperature for this first heat exchanger. In order to reduce equipment size the natural gas outlet temperature of the first range can be higher, typically 10° C. to 50° C. higher that the LNG boiling temperature This first heat exchanger will provide cryogenic cold or very low temperature chilling power to the cold utility which requires extremely low temperature cold such as an air separation unit, etc. The natural gas inlet temperature of the second temperature range is the outlet temperature of the first range and the output temperature of the second range is the inlet temperature of the third range. This heat exchanger can be designed to provide very low temperature chilling power, at a temperature higher than the first heat exchanger.
The natural gas inlet temperature of the third temperature range is the outlet temperature of the second range. This heat exchanger can be designed to provide chilling power, which has a higher temperature than the second heat exchanger.
In such a cascaded arrangement, the energy losses of the LNG chilling power is minimized when providing cold to different cold utilizes.
Specifically the following temperature ranges are used in an exemplary embodiment: First natural gas temperature range: −165° C. to −120° C., second temperature range: −120° C. to −80° C., and third temperature range: −80° C. to 0° C.
Each one of these heat exchangers can comprise one or more heat exchange apparatuses, which can be arranged either in series or in parallel to one another. Such arrangements allow flexibility in flow and temperature control of the heat exchange medium and allow flexibility in control in different operation modes of the power plant.
In a further embodiment of the invention, the LNG regasification system comprises cold storage units for the storage of LNG, which are arranged for providing cold heat exchange media to the above-mentioned cooling systems within the power plant. In case of non-operation of LNG regasification or regasification, the cold energy contained in these cold storage units can be used for the CO2 liquefication process, thereby enabling reduction of power consumption of the CO2 absorption system.
In a further embodiment of the invention, the LNG regasification system, in particular a heat exchanger arranged for operation with a heat exchange medium having chilling temperatures at its output, is additionally operatively connected with a system for cooling the inlet air to the gas turbine of the combined cycle power plant. The chilling temperatures of the medium can be in a range of 10° C. or less, or in a range from 5° C. to 2° C.
In a further exemplary embodiment of the invention, the LNG regasification system is additionally operatively connected with one or more of the following systems associated with the process of the capture of CO2 from the flue gas from the combined cycle power plant:
The recirculation of flue gas increases the CO2 concentration in the flue gas and thereby increases the CO2 capture process efficiency.
In a further exemplary embodiment of the invention, the LNG regasification system is additionally operatively connected with a cooling water system for the steam turbine condenser. This further increases the overall efficiency by effectively using the cold energy available for cooling and in turn using the low-level heat available from the condensation for the LNG regasification process.
From all of the above-mentioned cooling systems, the return heat exchange medium is directed back to the heat exchanger within the LNG regasification system.
The LNG regasification system can thereby be operated with the heat provided by the cooler and chiller systems of the combined cycle power plant. In return, the cooler and chiller systems can be operated with the cold energy provided by the LNG.
The use of the cold energy available from the LNG regasification system in any of the above cooling systems increases the overall power plant efficiency as these cooling systems no longer have to be operated with energy taken from other sources of the power plant. The heat taken back from the above-mentioned cooling systems on the other hand provide a heat source for the LNG regasification. Therefore, no or less steam extraction from the combined cycle power plant will be needed to operate the LNG regasification. The power plant's performance (efficiency and power output) can be improved.
In a further exemplary embodiment of the invention the system for LNG regasification comprises a heat exchanger configured and arranged for the liquefication of CO2 extracted by the CO2 capture system. The power plant with such LNG system requires no, or fewer, compressors for the liquefaction of the CO2. In addition, that heat exchanger of the LNG regasification system is provided with heat from the CO2 liquefaction process.
In a further embodiment, the power plant comprises lines to direct the heat exchange medium from the first heat exchanger of the liquefied natural gas regasification system to an air separation unit. The heat exchange medium has cryogenic temperatures (temperatures below −150° C.) at the output of that heat exchanger and is used for the operation of the air separation process thereby reducing the energy required to operate that unit. A further line for the return heat exchange medium from the air separation unit leads back to that first heat exchanger and provides its heat to the liquefied natural gas regasification process.
In an alternative embodiment the chilling power from the first heat exchanger of the liquefied natural gas regasification system is exchanged to the inlet air of the air separation unit and the chilling power from a second heat exchanger of the liquefied natural gas regasification system is used to cool the outlet air of the first compressor of the air separation unit.
The gas turbine of power plant 10 is operated with natural gas supplied by the liquefied natural gas LNG regasification plant 20. The power plant 10 is operatively connected with a LNG processing system 20 having one more stages, which vaporizes cryogenic liquefied natural gas LNG for use in the gas turbine combustion chamber CC. According to the invention, the LNG regasification processes in system 20 is integrated with one or more cooling and chilling systems within the power plant 10 in order to optimize the overall power plant efficiency. For this, the LNG system 20 comprises several stages 21-23, which are arranged in series, where each stage is dedicated to the regasification of the LNG within a range about a specific temperature level. In particular, the cooling or chilling systems within the CO2 capture system are integrated in closed heat exchange circuits with the LNG regasification system 20.
A first embodiment comprises a power plant with a CO2 capture system 5a, which is a system operating on the basis of a chilled ammonia process, as shown in
Gas that is free of CO2 exits from the column A via line G5 and is directed to a water wash WW, from which a gas line G6 for cleaned flue gas extends to the direct contact cooler DCC2. Finally, the cleaned flue gas is directed from the direct contact cooler DCC via line G7 to a stack S and the atmosphere.
The water wash W W is operatively connected to a stripper St and a water cooler 32 via water lines W. A line for a pure CO2 flow leads from the stripper St to a regenerator RG. The CO2 captured from the flue gas is finally released at the top of the regenerator RG, from where it is directed to further processing, for example compression, drying, or chilling.
The CO2 absorption column A is connected with a system for the regeneration of the chilled ammonia, its absorption solution. The CO2-rich absorption solution RS is reheated by means of a regenerator RG in order to release the CO2 and produce a CO2-lean solution LS to be reused in the absorption column A. The absorption solution regeneration system comprises additionally a cooler 33 for the rich solution RS.
Each of the above-mentioned coolers 31, 32, 33 within the chilled ammonia CO2 capture system 5A require chilling water as cooling medium having temperatures of less than 10° C., which can be provided by the heat exchanger 23 of the LNG system 20. Each of these coolers is connected in a closed circuit with heat exchanger 23 by means of lines 25 and 26.
According to a further embodiment of the invention, the CO2 capture system can also be a system 5B based on an amine process, as shown
The CO2 extracted from the flue gas exits from the regenerator column ARC and is directed to further processing such as compression, drying, or chilling.
Depending on the type of CO2 capture system installed, the flue gas from the HRSG should be cooled to specific temperature ranges prior to its processing within that system. In the case of chilled ammonia process, the flue gas has a preferred temperature from of less than 10° C. prior to entering the absorber. In the case of an amine process, the flue gas should have a temperature of ca. 50° C. in order to assure optimal operation. For such flue gas cooling, the power plant comprises a flue gas cooler 3A, or if necessary, additionally a flue gas chiller 3B arranged in the flue gas line for cooling or chilling the flue gas prior to its processing in the CO2 capture processing. The cold energy therefore may be entirely drawn from the LNG system. The cooler/chiller system 3A, 3B in turn supports the LNG system with heat gained from the flue gas and directed to the LNG system via line 26.
The power plant comprises several further cooling systems connected or associated with the CO2 capture system, which can be integrated with the LNG system, in addition to the cooling systems of the CO2 capture system itself.
The CO2 capture system 5A, 5B is connected to a CO2 drying and cooling system 6 for processing the captured CO2, which has been separated from the flue gas in the CO2 capture system. An optional compressor for CO2 compression may be arranged following the cooling system 6.
In order to enhance the efficiency of the CO2 capture process by means of increasing the CO2 concentration in the flue gas, the power plant 10 can furthermore comprise a flue gas recirculation system, which can include a line branching off the exhaust line from the HRSG, which directs untreated flue gas back to the gas turbine inlet via a flue gas cooler 4a followed by an optional flue gas chiller 4b. Cooled or chilled flue gas exiting from the flue gas cooler or flue gas chiller respectively is directed and admixed to the inlet air flow A intended for the gas turbine compressor.
For a further power plant capacity increase, the power plant can comprise an inlet air chilling system 2, which cools the inlet air for example in case of high ambient air temperatures using a chilled medium from heat exchanger 23 via line 25. The heated medium is returned to heat exchanger 23 via line 26.
The power plant is operatively connected with the liquefied natural gas processing system 20, which vaporizes cryogenic liquefied natural gas LNG for use in the gas turbine combustion chamber CC and/or for export via a gas pipeline. The regasification processes and the various cooling and chilling systems within the power plant 10 are integrated in a manner to optimize the overall power plant efficiency. The LNG system 20 comprises for example several stages 21-23, which are arranged in series, where each stage vaporizes the LNG to a different temperature level. A first stage 21 is configured and arranged to vaporize the LNG and is operatively connected in a closed circuit to an air separation unit ASU within power plant 10 via lines 27 and 28. Line 27 directs cryogenic cold via a flow medium to operate the ASU, where a line 28 directs the heat generated in the ASU back to vaporizer stage 21 to vaporize the LNG.
The air separation unit ASU is arranged in a line for ambient air, which branches off the inlet airflow line A for the gas turbine compressor. Pure oxygen extracted from ambient air is directed either back to the ambient air line to the compressor, and/or the combustion chamber CC of the gas turbine, and/or the heat recovery steam generator HRSG to support supplementary firing.
A second heat exchanger 22 of the LNG system 20, as shown in
The integration of the second heat exchanger 22 of the LNG vaporizer into the CO2 processing of the power plant allows a liquefaction of the CO2 without the need of additional CO2 compressors and intercoolers to compress the CO2 to higher pressures. This arrangement allows a significant savings in investment and operating cost as well as plant efficiency.
The third heat exchanger 23 of the LNG regasification system 20 is operatively connected by means of lines 25 and 26 with cooler systems of the CO2 capture system 5A or 5B. In order to additionally optimize the overall power plant efficiency, further cooling systems within the power plant 10 can be integrated in similar manner. These systems include for example the cooling system for the steam turbine condenser 1.
Each one of the heat exchangers 21-23 may in themselves comprise one or more vaporizer units, where in the case of several units, the units can be arranged in series or in parallel. Such arrangements allow for flexible control of the LNG and heat exchange flows and the respective temperatures.
Additionally, the last heat exchanger 23 may be combined with a cold storage unit 24, which is also connected by lines to lines 25 and 26. Also heat exchanger 22 may be connected with a cold storage unit 35, which is connected with lines to compressor 37 and the transport facility T. Similarly, the heat exchanger 21 may be combined with a cold storage unit 36, which is connected via lines to lines 27 and 28. This configuration allows the operation of the cooling and chilling systems within the power plant during a shut-down of the LNG regasification process or insufficient cold available from the process.
Number | Date | Country | Kind |
---|---|---|---|
11152823.8 | Feb 2011 | EP | regional |
This application claims priority to PCT/EP2012/051267 filed Jan. 26, 2012, which in turn claims priority to European Application 11152823.8 filed on Feb. 1, 2011, both of which are hereby incorporated in their entirety.
Number | Date | Country | |
---|---|---|---|
Parent | PCT/EP2012/051267 | Jan 2012 | US |
Child | 13953143 | US |