Patent Application
20110059410
THIS INVENTION relates to a combustion apparatus for combusting fuel media and in particular but not limited thereto a thermodynamic system having a combustion apparatus for combusting one or more relatively low grade fuel media, and a thermodynamic apparatus adapted to receive heat energy from the combustion apparatus.
Known thermodynamic apparatus general have a turbine with a built in combustion chamber. The combustion chamber is configured to burn a relative high grade fuel such as high yielding coal. Consequently there is abundance of relatively low grade resources such as low grade coal, biomass, municipal waste and the like, which are unused and considered waste materials. These waste materials are normally left in the open and generally looked upon as environmental scars.
Coal mine vVentilation air methane (CH4) contributes approximately 64% of coalmine CH4 emissions, and is difficult to use as an energy source, as the air volume is large and the methane resource is dilute and variable in concentration and flow rate. The low concentration of methane in mine ventilation air is a major problem, and mitigation requires either treatment in its dilute state, or concentrating up to levels that can be used in conventional methane fueled engines. Effective technology for increasing the concentration of methane is not available but it is being developed, and most work has focussed on the oxidation of very low concentration methane. These processes are complex and not cost effective.
Methane is a homogonous gas that requires large amounts of heat energy to oxidise at low concentrations <1% in air. This is normally accomplished by exposing low concentration to very high temperatures >1000° C. for 0.3 of a second. The combustion mechanism of methane may be overall represented by the following equation:
CH4+2O2═CO2+2H2O DH(298)=−802.7 kJ/mol
This is a gross simplification, since the actual reaction mechanism involves many free radical chain reactions. The combustion of methane may produce CO or CO2 depending on the air/methane ratio by the reactions.
CH4+2O2═CO2+2H2O
CH4+3/2O2═CO+2H2O
Other reactions may also be present, such as:
CH4+H2O═CO+3H2
2H2+O2=2H2O
CO+H2O═CO2+H2
Studies of the kinetic mechanisms of methane catalytic combustion are quite involved when multi-step surface reactions are considered. As described in the reference entitled Numerical Studies of Methane Catalytic Combustion inside a Monolith Honeycomb Reactor Using Multi-Step Surface Reactions, Combustion Science and Technology 2000; 150:27-58, the authors used 23 different reactions in their numerical study of methane catalytic combustion in a monolith honeycomb reactor. The situation becomes even more complicated when considering heterogeneous reactions.
In general, catalytic combustion is a multi-step process involving diffusion to the catalyst surface, adsorption onto the catalyst, reaction, and desorption of the product species from the catalyst surface and diffusion back into the bulk. Most kinetic investigations have been performed in conditions where methane is present in excess of the stoichiometric ratio. The result of this is that the reaction has generally been found to be independent of the oxygen concentration. The reaction order with respect to methane is generally found to be between 0.5 and 1. The activation energies are quite variable, being dependent on the catalyst and operating temperature. Platinum and palladium are generally accepted as the most active catalysts for low temperature total oxidation. Other catalysts have been tested but are less active.
Accordingly, there is a need to address one or more of the areas of existing and developing technologies for coal mine ventilation air methane (CH4) mitigation and utilisation, particularly the field of CH4 oxidation, with respect to technical feasibility, engineering applicability, and potential to recover the heat released from CH4 oxidation.
An object of the present invention is to provide a combustion apparatus which will at least reduce one or more of the above prior art disadvantages.
A further object of the present invention is to provide an indirect fired thermodynamic system which may be adapted to use relatively low grade fuel resources.
In one aspect therefore the present invention resides in a combustion apparatus for combusting one or more combustible media. The apparatus comprises a combustion unit having a fuel inlet adapted to receive said one or more combustible media for combustion therein, and a gas outlet adapted for combustion gas formed during combustion to flow out of said combustion unit to provide heat energy to a down stream apparatus. The combustion unit is arranged to provide a volatile release reaction, a char combustion reaction and a gas phase reaction.
It is preferred that the fuel inlet is configured to receive gaseous and solid combustible media, and the apparatus includes a preheating arrangement adapted to preheat the gaseous medium or any of said gaseous media.
It is also preferred that the heating arrangement is arranged to receive the combustion gas before or subsequent to reaching said down stream apparatus.
The apparatus may have a mixing unit arranged upstream of said combustion unit. The mixing unit is adapted to mix the gaseous fuel media and solid waste fuel media from said combustion unit, and the mixed media are then conveyed to the combustion unit.
Preferably, said one or more fuel media include a low grade fuel in the form of low grade coal, biomass or municipal waste.
More preferably, said combustion unit is a kiln. Desirably, said combustion unit is a rotary kiln.
Said down stream apparatus may be a thermodynamic apparatus comprising a compressor, an expander and heat exchange means connecting the compressor and the expander in an open or closed cycle, and a compressible working medium arranged to flow in the open or closed cycle. In preference, said combustion gas is arranged to heat said working medium at the heat exchange means.
The expander may release exhaust gas and the exhaust gas is conveyed to the combustion unit or the mixing unit for heating media therein.
Desirably, said solid fuel medial is a low grade coal and the kiln is adapted to convert said coal into flue gas and ash which can be formed as a by-product such as closed or open cell spherical nodules for lightweight building materials. Limestone may be added to convert any sulphur dioxide to calcium sulphate. This should at least reduce the amount of low grade coal which poses environmental problems.
In one form, said gaseous fuel media is methane gas. This is specially advantageous as very low concentration methane from an underground mine can be put into good use while at the same time removing it from the mine.
In one form the heat exchange means includes a first heat exchanger arranged for receiving said combustion gas from said combustion unit.
The combustion apparatus according to the present invention thus not only mitigates mine methane and utilises waste coal, but also to recover waste energy for power generation. The waste coal could be combusted with mine methane from both drainage gas and ventilation air inside a rotating kiln, in particular, drainage gas flame could play a role in stabilising combustion process inside the kiln. The rotary kiln has an “open structure” which earmarks it for mass burn applications involving bulky and “gooey” fuels and wastes.
In order that the present invention be more readily understood and be put into practical effect, reference will now be made to the accompanying drawings wherein:—
Referring initially to
The apparatus 14 has a compressor 16 for compressing a working medium which in this case is air. The compressed air from the compressor 16 is preheated in a recuperator 20 with exhaust air from a turbine 18. The preheated compressed air is then conveyed to a high temperature heat exchanger 22 from which it returns to the turbine 18 where it expands to provide energy (power output) to perform work at the turbine 18. The turbine in this case turns a generator (not shown) to generate electricity.
The combustion apparatus 12 has a combustion unit in the form of a rotary kiln 24 having an inlet 26 with a port for feed gas and another port 27 for feed coal.
Combustion gas in the combustion unit 24 travels from the outlet 28 to provide heat energy to the high temperature heat exchanger 22 for heating the compressed gas. The combustion gas then travels further to a low temperature heat exchanger for preheating ventilation air or drain air from a coal mine or any location in which methane is generated, before being put to flue. The preheated ventilation air is mixed with solid wastes from the kiln 24 at a mixing unit 32 and the mixed materials are then subject to further heating at a recuperator 34 prior to feeding into the combustion unit 24.
The combustion unit 24 represents the reactions occurring between feed coal and pre-heated feed gas, including volatile release, char combustion and gas phase reaction. Char burnout is estimated using an empirical correlation dependent on the temperature of reaction, as given in the equation below. This is for an arbitrary kiln and should be modified to correlate with experimental results for a specific kiln, operating conditions and feed coal. The product gas from the kiln is taken to be at equilibrium at the kiln exit. An estimate of heat loss from the kiln is determined from experimental data. Two products exit the kiln, one is a hot combustion gas and the other solid wastes comprising of char and ash. These are used to pre-heat the feed gas by mixing and re-separating the solids and gas;
X
C=−32+0.1168<T−2596E−5×T2
The net power output of the system 10 is calculated by subtracting the power requirements for the compressor and fan from the power generated by the turbine. The efficiency is determined by dividing the net power output by the sum of the calorific values of the feed coal and ventilation air. In the system shown the calculated efficiency is 26.1%, with the coal being 50% ash content (heating value 10.1 MJ/kg) and the ventilation air containing 0.37% methane
Referring to
X
C=−32+0.1168<T−2596E−5×T2
The indirectly fired turbine system constitutes the right half of the process diagram. This is comprised of two heat exchangers that transfer heat from the kiln product gas to compressed air, a topping combustor to heat the air to the required temperature and a turbine-compressor set (shown as a separate turbine and compressor units). The diagram also includes a number of fictional heat exchangers that are used to represent heat losses from pipework and unit items of equipment. The topping combustor burns methane in the compressed air to maintain the turbine inlet temperature at the target temperature. The net power output of the system is calculated by subtracting the power requirements for the compressor and fan from the power generated by the turbine.
By inputting measured values of feed flows, temperatures and gas compositions measured, it can tune the model to identify the heat losses for the major components, the performance of the rotating plant and the unknown flow rates using the model. Besides allowing verification of the system performance and identifying flaws in the experimental apparatus, the model can then be used as a tool for predicting the performance of the experimental plant under different operating conditions and developing designs for improved configurations.
The combustion unit 24 of the apparatus 12 is in the form of a rotary kiln adapted to receive low grade coal which has been ground to a size about 6-8 mm. The rotary kiln 24 is also designed so that the low grade coal has a relatively long residence time therein and a relatively large surface area of high temperatures, for ensuring combustion of very low concentration mine methane.
The apparatus 24 shown in
The ash from the burnt coal can be processed so that it is converted into a useful by-product such as closed or open cell spherical nodules ideal for manufacture of lightweight building materials and gravel substitutes. In this manner, little or no fly ash or slag is produced from combustion of low grade coal with extremely high ash contents.
Limestone can be added to convert any sulphur compound to calcium sulphate.
Greenhouse benefits can be maximised by sizing the plant to use all the mine ventilation air and rejects. This utilises carbonaceous waste that may eventually become carbon dioxide emissions by spontaneous combustion if stockpiled on the surface. Having separate flow paths provides the system with the flexibility to vary the proportion of ventilation air to gas turbine flow rate. This is managed by setting the temperature at which the gas is exhausted from the high temperature heat exchanger.
Changing the kiln/turbine flow ratio alters the proportion of energy derived from ventilation air compared to the waste coal and this is illustrated by
If full utilisation of rejects is not the primary consideration, then by increasing the kiln/turbine flow ratio, the size, output and, hence, capital cost of the gas turbine can be reduced. As the HTHx and gas turbine are related by size, and are the main capital cost items for the system, the overall capital cost of the system is reduced for a given ventilation flowrate. However,
Alternatively, if maximum utilisation of waste coal is a priority, the flow rate of coal can also be maximised by changing the kiln/turbine ratio.
Whilst the above have been given by way of illustrative examples of the present invention many variations and modifications thereto will be apparent to those skilled in the art without departing from the broad ambit and scope of the invention as herein set forth in the following claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2006907028 | Dec 2006 | AU | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/AU2007/001938 | 12/13/2007 | WO | 00 | 11/30/2010 |
