Claims
- 1. A method for the entrained flow combustion of a carbon- and sulfur-containing fuel for substantially reducing emission of gaseous sulfur compounds formed during the combustion of the fuel with a substoichiometric amount of oxygen, comprising:
- introducing said fuel, an inorganic alkaline absorbent and an oxygen-containing gas into a first combustion sulfur capture zone of an entrained-flow combustor to form a fluent mixture therein of fuel and absorbent entrained in said gas,
- the oxygen being present in said zone in an amount to provide from about 25% to 40% of the total stoichiometric amount required for complete combustion of the fuel,
- the inorganic alkaline absorbent being present in an amount to provide a molar ratio of alkaline absorbent to sulfur compounds of from about 1.0:1 to 3.0:1, said ratio including any alkaline absorbents contained in the fuel;
- reacting said fuel and absorbent entrained in said oxygen-containing gas by maintaining them in said zone at a temperature of from about 1000.degree. to 1800.degree. K. for a time sufficient
- (a) to gasify at least about 75% of the carbon content of the fuel and substantially all of the sulfur in the fuel,
- (b) to combust the gasified fuel and oxygen to produce a fuel-rich stoichiometry in the gas phase, and
- (c) to react in excess of about 70% of the fuel sulfur with the inorganic alkaline absorbent to form a solid alkaline sulfide compound; and
- discharging the resultant combustion mixture having a substantially reduced gaseous sulfur compound content.
- 2. The method of claim 1 wherein said alkaline absorbent is selected from the group consisting of the oxides, hydroxides, and carbonates of magnesium, calcium, and sodium, and said temperature is maintained within the range of from about 1200.degree. to 1600.degree. K.
- 3. The method of claim 2 wherein said alkaline absorbent is lime.
- 4. The method of claim 2 wherein said oxygen is introduced in an amount to provide from about 32% to 37% of said total stoichiometric amount.
- 5. The method of claim 1 wherein said temperature is maintained by preheating said oxygen-containing gas.
- 6. The method of claim 1 wherein said temperature is from about 1200.degree. to 1600.degree. K. and said time is from about 50 to 600 milliseconds.
- 7. The method of claim 1 wherein said fuel is a solid carbonaceous fuel selected from the group consisting of asphalt, coal, coal tars, lignite, and petroleum by-products which are solid at ambient temperatures.
- 8. The method of claim 7 wherein said time is from about 200 to 600 milliseconds.
- 9. The method of claim 1 wherein said fuel is selected from the group consisting of crude petroleum, petroleum residua, and petroleum by-products and said fuel is introduced as a liquid.
- 10. The method of claim 9 wherein said time is from about 50 to 200 milliseconds.
- 11. The method of claim 1 wherein said alkaline absorbent is present in an amount to provide a molar ratio of alkaline absorbent to sulfur compounds of about 2:1.
Parent Case Info
This application is a continuation-in-part of application Ser. No. 239,943 filed Mar. 3, 1981 now abandoned.
US Referenced Citations (14)
Continuation in Parts (1)
|
Number |
Date |
Country |
Parent |
239943 |
Mar 1981 |
|