Patent Application
20170051913
The term flue gas is commonly used in the art to refer to a mixture of gases flowing downstream from a combustion reaction, and typically includes products of the combustion reaction as well as other gas phase or gas entrained matter that might be present. The particular components of flue gas vary according a number of factors, such as, e.g., the composition of the fuel, composition of the air or other oxygen-containing fluid that supports the reaction, the temperature and duration of the combustion reaction, etc. For example, flue gas can include nitrogen (N2), water (H2O), carbon dioxide (CO2), residual oxygen (O2), carbon monoxide (CO), oxides of nitrogen (NOx), particulate matter (PM), un-combusted or partially combusted fuel, sulfur compounds, etc.
Many of the flue gas components that can be produced in a combustion reaction are considered to be pollutants, and are therefore regulated, with respect to their concentration in emissions from commercial combustion systems. Compliance with such regulations by many existing combustion systems can be difficult and/or expensive.
According to an embodiment, a combustion system includes a perforated flame holder disposed in a combustion volume defined by a combustion chamber wall, the perforated flame holder being configured to hold a combustion reaction supported by the fuel and combustion air; a fuel and oxidant source configured to output fuel and combustion air into the combustion volume and arranged to cause the fuel and air to mix in a mixing volume between the fuel and oxidant source and the perforated flame holder, and a flue gas recirculator (e.g., an external flue gas recirculator) configured to receive flue gas from a flue volume arranged to receive the flue gas from the combustion reaction held by the perforated flame holder and output the flue gas for mixing with the fuel and air in the mixing volume.
According to an embodiment, a combustion system is provided that includes a perforated flame holder positioned within a combustion volume, a nozzle configured to emit a fuel stream toward the perforated flame holder, an oxidant source configured to introduce an oxidizer fluid into the combustion volume, and a flue gas recirculation (FGR) channel having a first end in fluid communication with the combustion volume downstream of the perforated flame holder and a second end in fluid communication with the oxidant source. A controller is configured to hold a combustion parameter within a selected range of values by regulating a quantity of flue gas flowing in the FGR channel.
According to an embodiment, a combustion system is provided that comprises a perforated flame holder having an input face, an output face lying opposite the input face, and a plurality of perforations extending through the flame holder between the input and output faces. The flame holder is positioned within a combustion volume and is configured to hold a combustion reaction substantially within the plurality of perforations. A fuel nozzle is positioned and configured to emit a fuel stream toward the input face of the perforated flame holder, and an oxidant source is configured to introduce an oxidizer fluid into the combustion volume. A flue gas recirculation channel is provided that includes a first end in fluid communication with the combustion volume downstream of the perforated flame holder and a second end in fluid communication with the oxidant source.
According to an embodiment, a controller is configured to regulate a volume of flue gas flowing in the flue gas recirculation channel according to a parameter of the combustion reaction. A flue gas sensor can be configured to detect a value of the parameter of the combustion reaction and to transmit a signal to the controller that corresponds to the detected value. According to another embodiment, the controller is configured to regulate the volume of flue gas according to a plurality of parameters of the combustion reaction.
According to an embodiment, the controller is configured to monitor parameters associated with a working load of the system, and to control operation of the system to maintain those parameters within a selected range.
In the following detailed description, reference is made to the accompanying drawings, which form a part hereof. In the drawings, similar symbols typically identify similar components, unless context dictates otherwise. The illustrative embodiments described in the detailed description, drawings, and claims are not meant to be limiting. Other embodiments may be utilized, and other changes may be made, without departing from the spirit or scope of the subject matter presented here.
An external flue gas recirculator 112 can be configured to receive flue gas from a flue volume 114 arranged to receive the flue gas from the combustion reaction held by the perforated flame holder 102 and output the flue gas for mixing with the fuel and oxidant in the mixing volume 110.
In an embodiment, the perforated flame holder 102 is configured to hold, under at least a subset of operating conditions of the combustion system 100, the combustion reaction substantially between an input face 116 and an output face 118 of the perforated flame holder 102.
In an embodiment, the flue gas recirculator 112 is an external flue gas recirculation (EFGR) system. The external flue gas recirculator 112 can include a pipe or duct 122 arranged to convey flue gas received from an aperture 124 in a flue wall 126 adjacent to the flue volume 114 to an output point 128 into an air intake channel for mixture with incoming combustion air (as shown). In another embodiment, the flue gas recirculator 112 includes a pipe or duct 122 arranged to convey flue gas received from an aperture 124 in a flue wall 126 adjacent to the flue volume 114 to the fuel and oxidant source 108. In another embodiment, the external flue gas recirculator 112 can include a pipe or duct 122 arranged to convey flue gas received from an aperture 124 in a flue wall 126 adjacent to the flue volume 114 to the mixing volume 110.
A blower 130 can be configured to receive the flue gas conveyed by the pipe 122 and input air 132, and to output the flue gas and input air 132 into the fuel and oxidant source 108. The blower 130 can be arranged in various ways relative to the input air source and the external flue gas recirculator 112.
The external flue gas recirculator 112 can include the blower (either the same as or different than the blower 130 that propels combustion air) arranged to suck flue gas from the flue gas volume 114 and output the flue gas for mixing with the fuel and air prior to receipt of the mixed fuel, air, and flue gas at the input face 116 of the perforated flame holder 102. Optionally, a pair of blowers can separately pressurize input air 132 and flue gas to be introduced separately into the mixing volume 110.
The external flue gas recirculator 112 can include a recirculation valve or damper 134 configured to control the flow of flue gas through the external flue gas recirculator 112. The combustion system 100 can include a damper 136 configured to control a flow of flue gas out a stack 138 to the atmosphere 140. The external flue gas recirculator 112 can include ductwork maintained under a small partial vacuum by the blower 130, which can advantageously reduce fugitive emissions at damper fittings, etc.
A start-up apparatus 142 is configured to pre-heat the perforated flame holder 102 during start-up from a temperature below a nominal operating temperature of the perforated flame holder 102. A controller 144 can be operatively coupled to the start-up apparatus 142 and the recirculation valve or damper 134. The controller 144 can be configured to substantially prevent external recirculation of flue gas while the start-up apparatus 142 is pre-heating the perforated flame holder 102. Additionally or alternatively, the controller 144 can be operatively coupled to the start-up apparatus 142 and the blower 130.
The controller 144 can be configured to control (or output a prompt onto a computer display screen to cause an operator to control) the blower 130 and/or damper 134 to substantially prevent external recirculation of flue gas while the start-up apparatus 142 is pre-heating the perforated flame holder 102. In one embodiment, the blower 130 includes actuated vanes (not shown) that control the relative impelling efficiency of combustion air and flue gas. The controller 144 can be operatively coupled to the vanes to control the relative volume of combustion air and flue gas in the mixture delivered to the perforated flame holder 102.
In an embodiment, the combustion system 100 can include a controller 144, a flue gas sensor 146 operatively coupled to the controller 144, and at least one apparatus (such as a flue gas blower 130 and/or a damper 134) configured to control a flow of flue gas into the combustion volume 104. The controller can be configured to control the at least one apparatus 130, 134 to cause flue gas to flow into the combustion volume 104 only when the flue gas sensor 146 outputs a signal indicating that the perforated flame holder 102 is at a nominal operating temperature or above (or from which such an inference can be made). For example, the sensor 146 can include a stack temperature sensor that detects a sequence of temperatures. As the perforated flame holder 102 is heated sufficiently, it sinks less and less heat from a start-up flame supported by the start-up apparatus 142, and the temperature in the stack 138 approaches a start-up steady-state value. In experiments, the inventors transitioned systems 100 into the perforated flame holder 102—supported combustion when stack temperatures range from 850 to 1000 degrees F. In another embodiment, the sensor 146 can include a carbon monoxide sensor. A carbon monoxide sensor is illustrative of a class of sensors from which proper start-up conditions for the perforated flame holder 102 can be inferred, if not directly sensed. The inventors have found that, during a transitory period corresponding to system start-up, when the perforated flame holder 102 is relatively cool (below a start up flame holder temperature), combustion may be relatively incomplete, causing carbon monoxide (CO) concentration in the stack 138 to be relatively high. As the perforated flame holder 102 is raised to higher and higher temperature by the start-up apparatus 142, heat from the perforated flame holder body is output to maintain the reactants (including CO) at a high enough temperature for sufficient time for CO to oxidize more fully to (carbon dioxide) CO2.
Upon the perforated flame holder 102 reaching a temperature sufficient for start up, fuel and combustion air are allowed to flow to the perforated flame holder 102 for combustion.
During full scale experiments, after combustion had transitioned to the perforated flame holder 102, the inventors found that providing a small amount of external flue gas recirculation (EFGR) (about 5% of total flow) reduced an output of oxides of nitrogen (NOx) from about 5 ppm to about 2 ppm, but at a cost of adding detectable CO to the flue 114. Larger amounts of EFGR reduced NOx further, but at a cost of significantly increased CO. Accordingly, the inventors recommend maintaining EFGR at a relatively low flow rate such as 5% of total flow.
Despite the increased CO, the system 100 provided a favorable result. While CO is toxic, it eventually (e.g., in the stack or an exhaust plume) tends to react to form CO2. Thus small to moderate increases in CO may be viewed as an acceptable trade off for reducing NOx further. Unlike CO, which further reacts to form the non-toxic and relatively abundant species CO2, NOx (first in the form NO, and later in the form NO2) tends to react further to produce ozone, a pollutant when in the lower atmosphere.
The combustion system 100 can include a radiantly-heated heat load 148 configured to receive infrared radiation from the perforated flame holder 102 and a convectively-heated heat load 150 configured to receive heat from hot combustion products output by the combustion reaction held by the perforated flame holder 102. This was the arrangement used in full scale experiments wherein the combustion system 100 was a OTSG. The inventors found that adding the perforated flame holder 102 to the OTSG resulted in a decrease in NOx output from double-digit to low single-digit parts per million.
These remarkable results were measured at 3% (dry) oxygen (O2) concentration with undetectable CO at stack temperatures typical of industrial furnace applications (1400-1600° F.). Moreover, these results did not require any extraordinary measures such as selective catalytic reduction (SCR), selective non-catalytic reduction (SNCR), water/steam injection, or other heroic extremes that may be required for conventional burners to even approach such clean combustion.
According to embodiments, the burner system 200 includes a fuel and oxidant source 108 disposed to output fuel and oxidant into a combustion volume 104 to form a fuel and oxidant mixture 206. As used herein, the terms combustion volume, combustion chamber, furnace volume, and the like shall be considered synonymous unless further definition is provided. The perforated flame holder 102 is disposed in the combustion volume 104 and positioned to receive the fuel and oxidant mixture 206.
The fuel can include hydrogen, a hydrocarbon gas, a vaporized hydrocarbon liquid, an atomized hydrocarbon liquid, or a powdered or pulverized solid. The fuel can be a single species or can include a mixture of gas(es), vapor(s), atomized liquid(s), and/or pulverized solid(s). For example in a process heater application, the fuel can include fuel gas or byproducts from the process that include CO, hydrogen (H2), and methane (CH4). In another application the fuel can include natural gas (mostly CH4) or propane (C3H8). In another application, the fuel can include #2 fuel oil or #6 fuel oil. Dual fuel applications and flexible fuel applications are similarly contemplated by the inventors. The oxidant can include oxygen carried by air and/or can include another oxidant, either pure or carried by a carrier gas. The terms oxidant and oxidizer shall be considered synonymous herein.
According to an embodiment, the perforated flame holder body 208 can be bounded by an input face 116 disposed to receive the fuel and oxidant mixture 206, an output face 118 facing away from the fuel and oxidant source 108, and a peripheral surface 216 defining a lateral extent of the perforated flame holder 102. The plurality of perforations 210 which are defined by the perforated flame holder body 208 extend from the input face 116 to the output face 118. The plurality of perforations 210 can receive the fuel and oxidant mixture 206 at the input face 116. The fuel and oxidant mixture 206 can then combust in or near the plurality of perforations 210 and combustion products can exit the plurality of perforations 210 at or near the output face 118.
According to an embodiment, the perforated flame holder 102 is configured to hold a majority of the combustion reaction 302 within the perforations 210. For example, on a steady-state basis, more than half the molecules of fuel output into the combustion volume 104 by the fuel and oxidant source 108 may be converted to combustion products between the input face 116 and the output face 118 of the perforated flame holder 102. According to an alternative interpretation, more than half of the heat output by the combustion reaction 302 may be output between the input face 116 and the output face 118 of the perforated flame holder 102. Under nominal operating conditions, the perforations 210 can be configured to collectively hold at least 80% of the combustion reaction 302 between the input face 116 and the output face 118 of the perforated flame holder 102. In some experiments, the inventors produced a combustion reaction that was apparently wholly contained in the perforations 210 between the input face 116 and the output face 118 of the perforated flame holder 102. According to an alternative interpretation, the perforated fame holder 102 can support combustion between the input face 116 and output face 118 when combustion is “time-averaged”. For example, during transients, such as before the perforated flame holder 102 is fully heated, or if too high a (cooling) load is placed on the system, the combustion may travel somewhat downstream from the output face 118 of the perforated flame holder 102.
While a “flame” is described in a manner intended for ease of description, it should be understood that in some instances, no visible flame is present. Combustion occurs primarily within the perforations 210, but the “glow” of combustion heat is dominated by a visible glow of the perforated flame holder 102 itself. In other instances, the inventors have noted transient “huffing” wherein a visible flame momentarily ignites in a region lying between the input face 116 of the perforated flame holder 102 and the fuel source 218, within the dilution region DD. Such transient huffing is generally short in duration such that, on a time-averaged basis, a majority of combustion occurs within the perforations 210 of the perforated flame holder 102, between the input face 116 and the output face 118. In still other instances, the inventors have noted apparent combustion occurring above the output face 118 of the perforated flame holder 102, but still a majority of combustion occurred within the perforated flame holder 102 as evidenced by the continued visible glow (a visible wavelength tail of blackbody radiation) from the perforated flame holder 102.
The perforated flame holder 102 can be configured to receive heat from the combustion reaction 302 and output a portion of the received heat as thermal radiation 304 to heat-receiving structures (e.g., furnace walls and/or radiant section working fluid tubes) in or adjacent to the combustion volume 104. As used herein, terms such as thermal radiation, infrared radiation, radiant heat, heat radiation, etc. are to be construed as being substantially synonymous, unless further definition is provided. Specifically, such terms refer to blackbody radiation of electromagnetic energy, primarily in infrared wavelengths.
Referring especially to
The perforated flame holder body 208 can be characterized by a heat capacity. The perforated flame holder body 208 may hold heat from the combustion reaction 302 in an amount corresponding to the heat capacity times temperature rise, and transfer the heat from the heat receiving regions 306 to heat output regions 310 of the perforation walls 308. Generally, the heat output regions 310 are nearer to the input face 116 than are the heat receiving regions 306. According to one interpretation, the perforated flame holder body 208 can transfer heat from the heat receiving regions 306 to the heat output regions 310 via thermal radiation, depicted graphically as 304. According to another interpretation, the perforated flame holder body 208 can transfer heat from the heat receiving regions 306 to the heat output regions 310 via heat conduction along heat conduction paths 312. The inventors contemplate that both radiation and conduction heat transfer mechanisms may be operative in transferring heat from the heat receiving regions 306 to the heat output regions 310. In this way, the perforated flame holder 102 may act as a heat source to maintain the combustion reaction 302, even under conditions where a combustion reaction would not be stable when supported from a conventional flame holder.
The inventors believe that the perforated flame holder 102 causes the combustion reaction 302 to occur within thermal boundary layers 314 formed adjacent to walls 308 of the perforations 210. As the relatively cool fuel and oxidant mixture 206 approaches the input face 116, the flow is split into portions that respectively travel through individual perforations 210. The hot perforated flame holder body 208 transfers heat to the fluid, notably within thermal boundary layers 314 that progressively thicken as more and more heat is transferred to the incoming fuel and oxidant mixture 206. After reaching a combustion temperature (e.g. the auto-ignition temperature of the fuel), the reactants continue to flow while a chemical ignition delay time elapses, over which time the combustion reaction 302 occurs. Accordingly, the combustion reaction 302 is shown as occurring within the thermal boundary layers 314. As flow progresses, the thermal boundary layers 314 merge at a merger point 316. Ideally, the merger point 316 lies between the input face 116 and output face 118 that defines the ends of the perforations 210. At some point, the combustion reaction 302 causes the flowing gas (and plasma) to output more heat to the body 208 than it receives from the body 208. The heat is received at the heat receiving region 306, is held by the body 208, and is transported to the heat output region 310 nearer to the input face 116, where the heat recycles into the cool reactants (and any included diluent) to raise them to the combustion temperature.
In an embodiment, the plurality of perforations 210 are each characterized by a length L defined as a reaction fluid propagation path length between the input face 116 and the output face 118 of the perforated flame holder 102. The reaction fluid includes the fuel and oxidant mixture 206 (optionally including nitrogen, flue gas, and/or other “non-reactive” species), reaction intermediates (including transition states in a plasma that characterizes the combustion reaction), and reaction products.
The plurality of perforations 210 can be each characterized by a transverse dimension D between opposing perforation walls 308. The inventors have found that stable combustion can be maintained in the perforated flame holder 102 if the length L of each perforation 210 is at least four times the transverse dimension D of the perforation. In other embodiments, the length L can be greater than six times the transverse dimension D. For example, experiments have been run where L is at least eight, at least twelve, at least sixteen, and at least twenty-four times the transverse dimension D. Preferably, the length L is sufficiently long for thermal boundary layers 314 formed adjacent to the perforation walls 308 in a reaction fluid flowing through the perforations 210 to converge at merger points 316 within the perforations 210 between the input face 116 and the output face 118 of the perforated flame holder 102. In experiments, the inventors have found L/D ratios between 12 and 48 to work well (i.e., produce low NOx, produce low CO, and maintain stable combustion).
The perforated flame holder body 208 can be configured to convey heat between adjacent perforations 210. The heat conveyed between adjacent perforations 210 can be selected to cause heat output from the combustion reaction portion 302 in a first perforation 210 to supply heat to stabilize a combustion reaction portion 302 in an adjacent perforation 210.
Referring especially to
The perforated flame holder 102 can be held by the perforated flame holder support structure 120 configured to hold the perforated flame holder 102 a distance DD away from the fuel nozzle 218. The fuel nozzle 218 can be configured to emit a fuel jet selected to entrain the oxidant to form the fuel and oxidant mixture 206 as the fuel jet and oxidant travel along a path to the perforated flame holder 102 through a dilution distance DD between the fuel nozzle 218 and the perforated flame holder 102. Additionally or alternatively (particularly when a blower is used to deliver oxidant combustion air), the oxidant or combustion air source can be configured to entrain the fuel, and the fuel and oxidant travel through the dilution distance DD. In some systems, an internal flue gas recirculation (FGR) path 224 can be inferred. This type of natural internal FGR 224 can be caused, for example, by vortices that can drive upstream propagation of flue gas through any area of the combustion volume 104 peripheral to the perforated flame holder 102 and inside the combustion chamber wall 106 (e.g., see
The fuel nozzle 218 can be configured to emit the fuel through one or more fuel orifices 226 having a dimension that is referred to as “nozzle diameter”. The perforated flame holder support structure 120 can support the perforated flame holder 102 to receive the fuel and oxidant mixture 206 at a distance DD away from the fuel nozzle 218 greater than 20 times the nozzle diameter. In another embodiment, the perforated flame holder 102 is disposed to receive the fuel and oxidant mixture 206 at a distance DD away from the fuel nozzle 218 between 100 times and 1100 times the nozzle diameter. Preferably, the perforated flame holder support structure 120 is configured to hold the perforated flame holder 102 about 200 times the nozzle diameter or more away from the fuel nozzle 218. When the fuel and oxidant mixture 206 travels about 200 times the nozzle diameter or more, the mixture is sufficiently homogenized to cause the combustion reaction to output minimal NOx.
The fuel and oxidant source 108 can alternatively include a premix fuel and oxidant source, according to an embodiment. A premix fuel and oxidant source can include a premix chamber (not shown), a fuel nozzle configured to output fuel into the premix chamber, and an air channel configured to output combustion air into the premix chamber. A flame arrestor can be disposed between the premix fuel and oxidant source and the perforated flame holder 102 and be configured to prevent flame flashback into the premix fuel and oxidant source.
The combustion air source, whether configured for entrainment in the combustion volume 104 or for premixing can include a blower configured to force air through the fuel and air source 108.
The support structure 120 can be configured to support the perforated flame holder 102 from a floor or wall (not shown) of the combustion volume 104, for example. In another embodiment, the support structure 120 supports the perforated flame holder 102 from the fuel and oxidant source 108. Alternatively, the support structure 120 can suspend the perforated flame holder 102 from an overhead structure (such as a flue, in the case of an up-fired system). The support structure 120 can support the perforated flame holder 102 in various orientations and directions.
The perforated flame holder 102 can include a single perforated flame holder body 208. In another embodiment, the perforated flame holder 102 can include a plurality of adjacent perforated flame holder sections that collectively provide a tiled perforated flame holder 102.
The perforated flame holder support structure 120 can be configured to support the plurality of perforated flame holder sections. The perforated flame holder support structure 120 can include a metal superalloy, a cementatious, and/or ceramic refractory material. In an embodiment, the plurality of adjacent perforated flame holder sections can be joined with a fiber reinforced refractory cement.
The perforated flame holder 102 can have a width dimension W between opposite sides of the peripheral surface 216 at least twice a thickness dimension T between the input face 116 and the output face 118. In another embodiment, the perforated flame holder 102 can have a width dimension W between opposite sides of the peripheral surface 216 at least three times, at least six times, or at least nine times a thickness dimension T between the input face 116 and the output face 118 of the perforated flame holder 102.
In an embodiment, the perforated flame holder 102 can have a width dimension W less than a width of the combustion volume 104. This can allow the FGR path 224 from above to below the perforated flame holder 102 to lie between the peripheral surface 216 of the perforated flame holder 102 and the combustion volume wall (not shown).
Referring again to both
In one range of embodiments, each of the plurality of perforations has a lateral dimension D between 0.05 inch and 1.0 inch. Preferably, each of the plurality of perforations 210 has a lateral dimension D between 0.1 inch and 0.5 inch. For example the plurality of perforations 210 can each have a lateral dimension D of about 0.2 to 0.4 inch.
The void fraction of a perforated flame holder 102 is defined as the total volume of all perforations 210 in a section of the perforated flame holder 102 divided by a total volume of the perforated flame holder including body 208 and perforations 210. The perforated flame holder 102 should have a void fraction between 0.10 and 0.90. In an embodiment, the perforated flame holder 102 can have a void fraction between 0.30 and 0.80. In another embodiment, the perforated flame holder 102 can have a void fraction of about 0.70. Using a void fraction of about 0.70 was found to be especially effective for producing very low NOx.
The perforated flame holder 102 can be formed from a fiber reinforced cast refractory material and/or a refractory material such as an aluminum silicate material. For example, the perforated flame holder 102 can be formed from mullite or cordierite. Additionally or alternatively, the perforated flame holder body 208 can include a metal superalloy such as Inconel or Hastelloy. The perforated flame holder body 208 can define a honeycomb.
The inventors have found that the perforated flame holder 102 can be formed from VERSAGRID® ceramic honeycomb, available from Applied Ceramics, Inc. of Doraville, S.C.
The perforations 210 can be parallel to one another and normal to the input and output faces 116, 118. In another embodiment, the perforations 210 can be parallel to one another and formed at an angle relative to the input and output faces 116, 118. In another embodiment, the perforations 210 can be non-parallel to one another. In another embodiment, the perforations 210 can be non-parallel to one another and non-intersecting. In another embodiment, the perforations 210 can be intersecting. The body 208 can be one piece or can be formed from a plurality of sections.
In another embodiment, which is not necessarily preferred, the perforated flame holder 102 may be formed from reticulated fibers formed from an extruded ceramic material. The term “reticulated fibers” refers to a netlike structure.
In another embodiment, the perforated flame holder 102 can include a plurality of tubes or pipes bundled together. The plurality of perforations 210 can include hollow cylinders and can optionally also include interstitial spaces between the bundled tubes. In an embodiment, the plurality of tubes can include ceramic tubes. Refractory cement can be included between the tubes and configured to adhere the tubes together. In another embodiment, the plurality of tubes can include metal (e.g., superalloy) tubes. The plurality of tubes can be held together by a metal tension member circumferential to the plurality of tubes and arranged to hold the plurality of tubes together. The metal tension member can include stainless steel, a superalloy metal wire, and/or a superalloy metal band.
The perforated flame holder body 208 can alternatively include stacked perforated sheets of material, each sheet having openings that connect with openings of subjacent and superjacent sheets. The perforated sheets can include perforated metal sheets, ceramic sheets and/or expanded sheets. In another embodiment, the perforated flame holder body 208 can include discontinuous packing bodies such that the perforations 210 are formed in the interstitial spaces between the discontinuous packing bodies. In one example, the discontinuous packing bodies include structured packing shapes. In another example, the discontinuous packing bodies include random packing shapes. For example, the discontinuous packing bodies can include ceramic Raschig ring, ceramic Berl saddles, ceramic Intalox saddles, and/or metal rings or other shapes (e.g. Super Raschig Rings) that may be held together by a metal cage.
The inventors contemplate various explanations for why burner systems including the perforated flame holder 102 provide such clean combustion.
In one aspect, the perforated flame holder 102 acts as a heat source to maintain a combustion reaction even under conditions where a combustion reaction would not be stable when supported by a conventional flame holder. This capability can be leveraged to support combustion using a leaner fuel-to-oxidant mixture than is typically feasible. Thus, according to an embodiment, at the point where the fuel stream 206 contacts the input face 116 of the perforated flame holder 102, an average fuel-to-oxidant ratio of the fuel stream 206 is below a (conventional) lower combustion limit of the fuel component of the fuel stream—lower combustion limit defines the lowest concentration of fuel at which a fuel/air mixture will burn when exposed to a momentary ignition source under normal atmospheric pressure and an ambient temperature of 25° C. (77° F.).
According to one interpretation, the fuel and oxidant mixtures supported by the perforated flame holder may be more fuel-lean than mixtures that would provide stable combustion in a conventional burner. Combustion near a lower combustion limit of fuel generally burns at a lower adiabatic flame temperature than mixtures near the center of the lean-to-rich combustion limit range. Lower flame temperatures generally evolve a lower concentration of NOx than higher flame temperatures. In conventional flames, too-lean combustion is generally associated with high CO concentration at the stack. In contrast, the perforated flame holder 102 and systems including the perforated flame holder 102 described herein were found to provide substantially complete combustion of CO (single digit parts per million down to undetectable, depending on experimental conditions), while supporting low NOx. In some embodiments, the inventors achieved stable combustion at what was understood to be very lean mixtures (that nevertheless produced only about 3% or lower measured O2 concentration at the stack). Moreover, the inventors believe perforation walls 308 may act as a heat sink for the combustion fluid. This effect may alternatively or additionally reduce combustion temperature.
According to another interpretation, production of NOx can be reduced if the combustion reaction 302 occurs over a very short duration of time. Rapid combustion causes the reactants (including oxygen and entrained nitrogen) to be exposed to NOx-formation temperature for a time too short for NOx-formation kinetics to cause significant production of NOx. The time required for the reactants to pass through the perforated flame holder 102 is very short compared to a conventional flame. The low NOx production associated with perforated flame holder combustion may thus be related to the short duration of time required for the reactants (and entrained nitrogen) to pass through the perforated flame holder 102.
Since CO oxidation is a relatively slow reaction, the time for passage through the perforated flame holder (perhaps plus time passing toward the flue from the perforated flame holder 102) is apparently sufficient and at sufficiently elevated temperature, in view of the very low measured (experimental and full scale) CO concentrations, for oxidation of CO to carbon dioxide (CO2).
According to a simplified description, the method 400 begins with step 402, wherein the perforated flame holder is preheated to a start-up temperature, TS. After the perforated flame holder is raised to the start-up temperature, the method proceeds to step 404, wherein fuel and oxidant are provided to the perforated flame holder and combustion is held by the perforated flame holder.
According to a more detailed description, step 402 begins with step 406, wherein start-up energy is provided at the perforated flame holder. Simultaneously or following providing start-up energy, a decision step 408 determines whether the temperature T of the perforated flame holder is at or above the start-up temperature, TS. As long as the temperature of the perforated flame holder is below its start-up temperature, the method loops between steps 406 and 408 within the preheat step 402. In step 408, if the temperature T of at least a predetermined portion of the perforated flame holder is greater than or equal to the start-up temperature, the method 400 proceeds to overall step 404, wherein fuel and oxidant is supplied to and combustion is held by the perforated flame holder.
Step 404 may be broken down into several discrete steps, at least some of which may occur simultaneously.
Proceeding from step 408, a fuel and oxidant mixture is provided to the perforated flame holder, as shown in step 410. The fuel and oxidant may be provided by a fuel and oxidant source that includes a separate fuel nozzle and combustion air source, for example. In this approach, the fuel and combustion air are output in one or more directions selected to cause the fuel and combustion air mixture to be received by an input face of the perforated flame holder. The fuel may entrain the combustion air (or alternatively, the combustion air may dilute the fuel) to provide a fuel and oxidant mixture at the input face of the perforated flame holder at a fuel dilution selected for a stable combustion reaction that can be held within the perforations of the perforated flame holder.
Proceeding to step 412, the combustion reaction is held by the perforated flame holder.
In step 414, heat may be output from the perforated flame holder. The heat output from the perforated flame holder may be used to power an industrial process, heat a working fluid, generate electricity, or provide motive power, for example.
In optional step 416, the presence of combustion may be sensed. Various sensing approaches have been used and are contemplated by the inventors. Generally, combustion held by the perforated flame holder is very stable and no unusual sensing requirement is placed on the system. Combustion sensing may be performed using an infrared sensor, a video sensor, an ultraviolet sensor, a charged species sensor, thermocouple, thermopile, and/or other known combustion sensing apparatuses. In an additional or alternative variant of step 416, a pilot flame or other ignition source may be provided to cause ignition of the fuel and oxidant mixture in the event combustion is lost at the perforated flame holder.
Proceeding to decision step 418, if combustion is sensed not to be stable, the method 400 may exit to step 424, wherein an error procedure is executed. For example, the error procedure may include turning off fuel flow, re-executing the preheating step 402, outputting an alarm signal, igniting a stand-by combustion system, or other steps. If, in step 418, combustion in the perforated flame holder is determined to be stable, the method 400 proceeds to decision step 420, wherein it is determined if combustion parameters should be changed. According to an embodiment, one candidate for combustion parameter change is an amount of EFGR.
If no combustion parameters are to be changed, the method loops (within step 404) back to step 410, and the combustion process continues. If a change in combustion parameters is indicated, the method 400 proceeds to step 422, wherein the combustion parameter change is executed. For example, upon reaching stable combustion, an operator or an electronic controller can opt to begin to provide EFGR. In step 422, the combustion parameter change can thus include opening a damper (e.g., see
Combustion parameters may be scheduled to be changed, for example, if a change in heat demand is encountered. For example, if less heat is required (e.g., due to decreased electricity demand, decreased motive power requirement, or lower industrial process throughput), the fuel and oxidant flow rate may be decreased in step 422. Conversely, if heat demand is increased, then fuel and oxidant flow may be increased. Additionally or alternatively, if the combustion system is in a start-up mode, then fuel and oxidant flow may be gradually increased to the perforated flame holder over one or more iterations of the loop within step 404.
Referring again to
Various heating apparatuses have been used and are contemplated by the inventors. In some embodiments, the heater 228 can include a flame holder configured to support a flame disposed to heat the perforated flame holder 102. The fuel and oxidant source 108 can include a fuel nozzle 218 configured to emit a fuel stream and an air source 220 configured to output combustion air adjacent to the fuel stream. The fuel nozzle 218 and air source 220 can be configured to output the fuel stream to be progressively diluted by the combustion air. The perforated flame holder 102 can be disposed to receive a diluted fuel and air mixture 206 that supports a combustion reaction that is stabilized by the perforated flame holder 102 when the perforated flame holder 102 is at an operating temperature. A start-up flame holder, in contrast, can be configured to support a start-up flame at a location corresponding to a relatively rich fuel and air mixture that is stable without stabilization provided by the heated perforated flame holder 102.
The burner system 200 can further include a controller 230 operatively coupled to the heater 228 and to a data interface 232. For example, the controller 230 can be configured to control a start-up flame holder actuator configured to cause the start-up flame holder to hold the start-up flame when the perforated flame holder 102 needs to be pre-heated and to not hold the start-up flame when the perforated flame holder 102 is at an operating temperature (e.g., when T≧TS).
Various approaches for actuating a start-up flames are contemplated. In one embodiment, the start-up flame holder includes a mechanically-actuated bluff body configured to be actuated to intercept the fuel and oxidant mixture 206 to cause heat-recycling vortices and thereby hold a start-up flame; or to be actuated to not intercept the fuel and oxidant mixture 206 to cause the fuel and oxidant mixture 206 to proceed to the perforated flame holder 102. In another embodiment, a fuel control valve, blower, and/or damper may be used to select a fuel and oxidant mixture flow rate that is sufficiently low for a start-up flame to be jet-stabilized; and upon reaching an perforated flame holder 102 operating temperature, the flow rate may be increased to “blow out” the start-up flame. In another embodiment, the heater may include an electrical power supply operatively coupled to the controller 230 and configured to apply an electrical charge or voltage to the fuel and oxidant mixture 206. An electrically conductive start-up flame holder may be selectively coupled to a voltage ground or other voltage selected to attract the electrical charge in the fuel and oxidant mixture 206. The attraction of the electrical charge was found by the inventors to cause a start-up flame to be held by the electrically conductive start-up flame holder.
In another embodiment, the heater 228 may include an electrical resistance heater configured to output heat to the perforated flame holder and/or to the fuel and oxidant mixture 206. The electrical resistance heater can be configured to heat up the perforated flame holder 102 to an operating temperature. The heater 228 can further include a power supply and a switch operable, under control of the controller 230, to selectively couple the power supply to the electrical resistance heater.
An electrical resistance heater 228 can be formed in various ways. For example, the electrical resistance heater 228 can be formed from KANTHAL wire (available from Sandvik Materials Technology division of Sandvik AB of Hallstahammar, Sweden) threaded through at least a portion of the perforations 210 defined formed by the perforated flame holder body 208. Alternatively, the heater 228 can include an inductive heater, a high energy (e.g. microwave or laser) beam heater, a frictional heater, or other types of heating technologies.
Other forms of start-up apparatuses are contemplated. For example, the heater 228 can include an electrical discharge igniter or hot surface igniter configured to output a pulsed ignition to the air and fuel. Additionally or alternatively, a start-up apparatus can include a pilot flame apparatus disposed to ignite a fuel and oxidant mixture 206 that would otherwise enter the perforated flame holder 102. An electrical discharge igniter, hot surface igniter, and/or pilot flame apparatus can be operatively coupled to the controller 230, which can cause the electrical discharge igniter or pilot flame apparatus to maintain combustion of the fuel and oxidant mixture 206 in or upstream from the perforated flame holder 102 before the perforated flame holder 102 is heated sufficiently to maintain combustion.
The burner system 200 can further include a sensor 234 operatively coupled to the control circuit 230. The sensor 234 can include a heat sensor configured to detect infrared radiation or a temperature of the perforated flame holder 102. The control circuit 230 can be configured to control the heating apparatus 228 responsive to input from the sensor 234. Optionally, a fuel control valve 236 can be operatively coupled to the controller 230 and configured to control a flow of fuel to the fuel and oxidant source 108. Additionally or alternatively, an oxidant blower or damper 238 can be operatively coupled to the controller 230 and configured to control flow of the oxidant (or combustion air).
The sensor 234 can further include a combustion sensor operatively coupled to the control circuit 230, the combustion sensor being configured to detect a temperature, video image, and/or spectral characteristic of a combustion reaction held by the perforated flame holder 102. The fuel control valve 236 can be configured to control a flow of fuel from a fuel source 218 to the fuel and oxidant source 108. The controller 230 can be configured to control the fuel control valve 236 responsive to input from the combustion sensor 234. The controller 230 can be configured to control the fuel control valve 236 and/or oxidant blower or damper 238 to control a preheat flame type of heater 228 to heat the perforated flame holder 102 to an operating temperature. The controller 230 can similarly control the fuel control valve 236 and/or the oxidant blower or damper 238 to change the fuel and oxidant mixture 206 flow responsive to a heat demand change received as data via the data interface 232.
The combustion system 500 includes a combustion volume 104 defined, primarily, by sidewalls 502 of a housing 504. The housing further includes an oxidant source 220 and a flue stack 138. A flame holder support structure 120 is configured to support the perforated flame holder 102 within the housing 504. A fuel nozzle 218 is positioned and configured to emit a fuel stream 206 toward the flame holder 102, and is coupled to a fuel source 218 via a fuel line 508. An air line 510 is coupled to the oxidant source 220 and is configured to provide an oxidant, such as air, to support the combustion of fuel within the combustion volume 104. An air blower 238 in the air line 510 can be employed to increase the pressure and volume of air introduced into the combustion volume 104. Air entering the combustion volume 104 via the oxidant source 220 is entrained by the fuel stream 206 and supports the combustion of the fuel in the perforated flame holder 102, as discussed in more detail below. Reference to the fuel stream is to be construed as referring also to any oxidants and/or diluents that are entrained therein. The term fuel and oxidant mixture may also be used to refer to the mixture of fuel and oxidants in the fuel stream 206.
An FGR line 512 is operatively coupled to the flue stack 138 at a first end and to the oxidant source 220 at a second end, and is configured to carry a quantity of flue gas from the flue stack 138 back to the oxidant source 220 to be reintroduced into the combustion volume 104. In the embodiment shown, the first end of the FGR line 512 is coupled to the flue stack 138 via an FGR duct 514 and an FGR blower 516. At its second end, the FGR line 512 is coupled to the air line 510 upstream of the air blower 238. The FGR blower 516 draws flue gas from the flue stack 138 and pressurizes the FGR line 512. Flue gas entering the air line 510 is mixed with incoming air as they pass through the air blower 238 before being introduced to the combustion volume 104.
Hereafter, the use of terms such as air, input air, etc., is to be construed broadly as referring to a fluid that includes oxygen, and that is to be introduced into a combustion volume to support a combustion reaction. Specifically, such a fluid can be ambient air, a mixture of ambient air with other fluids, i.e., flue gas or inert gas, etc.
A load 518, represented in
A load output sensor 524 is positioned at an output of the load 518, and is configured to detect or monitor any of a number of parameters associated with the load, and to provide a corresponding signal on a respective sensor line 522. The fuel control valve 236 is positioned to control a flow in the fuel line 508 from a fuel source to the fuel nozzle 218, an air volume control valve 526 is positioned to control a flow air in the air line 510 from an air intake to the oxidant source 220, and an FGR control valve 528 is positioned to control a flow of flue gas in the FGR line 512 from the flue stack 138 to the oxidant source 220. Each of the control valves 236, 526, 528 are configured to be controlled by a signal on a respective control line 530.
A controller 532 is coupled to receive signals from the sensors 146, 524 via the respective sensor lines 522, and to provide corresponding control signals to the control valves 236, 526, 528 via the respective control lines 530. The controller 532 is configured to control operation of the combustion system 500, in part, in response to signals from sensors such as the flue gas sensor 146 and the load sensor 524.
The elements shown in
In operation, according to an embodiment, the controller 532 is configured to compare a signal from the load sensor 524 with a reference value or range of values to determine whether the output of the load 518 is within acceptable limits. For example, in an embodiment in which the load 518 is a component of a water boiler, the load sensor 524 may be configured to monitor one or more of temperature, flow rate, and/or “quality,” i.e., the ratio of steam to water at the load output. Assuming that the load sensor 524 is configured to monitor steam quality, if the quality drops below an acceptable value, i.e., the quantity of steam relative to water drops, the controller 532 can be configured to control the fuel control valve 236 to open further, increasing the volume of fuel emitted from the nozzle 218. This results in an increase of heat produced by the combustion reaction held by the perforated flame holder 102, delivering increased thermal energy to the load 518, which converts a greater percentage of the water into steam, thereby increasing the steam quality. Concurrently, the controller 532 can be configured to control the air volume control valve 526 to open further in order to increase the supply of air introduced into the oxidant source 220, in order to provide sufficient for the combustion reaction.
The operation sequence described above is appropriate in a situation in which a total load output is substantially fixed, i.e., a specific quantity of steam is desired. In a case in which a fuel quantity is either a fixed value or varies in response to factors that are external to the combustion system 500, then the controller 532 can be configured to control a flow of water to the load 518. In such a case, if the load sensor 524 detects a drop in output quality, the controller 532 can be configured to control a valve (not shown) to reduce a volume of water admitted to the load 518. With less water flowing through the load 518, a larger proportion of the water is converted to steam, thereby increasing output quality.
It is generally understood in the art that recirculation of flue gas can result in a reduction of NOx in a combustion reaction. Adding flue gas to the input air increases the volume relative to the quantity of O2 in the resulting mix. The general understanding is that the increased volume acts as a heat sink, reducing the temperature of the combustion reaction, which results in a reduced production of NOx. According to an embodiment, the controller 532 is configured to regulate a flow of flue gas in the FGR line 512 according to the values of combustion parameters detected by the flue gas sensor. For example, if a signal from the flue gas sensor 146 indicates an increase in production of NOx, the controller 532 can be configured to control the FGR control valve 528 to increase a flow of flue gas in the FGR line 512. On the other hand, if the controller 532 determines that the level of is well below threshold levels, the controller can be configured to control the FGR control valve 528 to reduce the flow of flue gas, thereby reducing the efficiency losses associated with FGR.
Production of NOx is highly correlated with flame temperature and residence time. In fact, in many industrial combustion systems, NOx production is not directly measured, but is inferred from other data, including flame temperature and residence time. In the configuration shown in
However, if other parameters of the system change, the accuracy of the temperature determination can be affected. For example, the heat load on the combustion system 500 varies according to the volume of fluid flowing through the working load 518. An increase in fluid volume increases the heat load, and more thermal energy is extracted by the working load 518. Assuming a constant flame temperature, an increased heat load will result in a lower temperature detected by the flue gas sensor 146.
Thus, according to another embodiment, the controller 532 is configured to integrate data from the load output sensor 524, in addition to data from the flue gas sensor 146 in controlling the flow of flue gas. The load sensor 524 is configured to detect steam quality and flow rate, and a correlation of these two values is used to determine the current heat load. This in turn is correlated with the temperature value detected by the flue gas sensor 146 to correct for changes in the measured temperature.
In the embodiment shown in
According to a further embodiment, the FGR blower 516 and the FGR control valve 528 are both omitted. Instead, the controller 532 is configured to control throughput of the air blower 238, a manner similar that was described previously with reference to the FGR blower 516. The total volume of the air mixture introduced into the combustion volume 104 is controlled primarily by the air blower 238, while the ratio of air to flue gas is controlled by operation of the air volume control valve 526. For example, in order to increase the volume of recirculated flue gas, the controller 532 is configured to control the air volume control valve 526 to reduce the volume of air admitted. This results in a greater drop in air pressure upstream of the air blower 238, as the air volume control valve 526 chokes the input air. The pressure drop, in turn, draws an increased volume of flue gas from the FGR line 512, thus changing the ratio of air to flue gas.
According to an embodiment, the controller 532 is configured to control operation of the combustion system 500 to preheat the perforated flame holder 102 prior to normal operation. For example, during a start-up procedure, the controller can be configured to control the fuel control valve 236 to admit a flow of fuel reduced relative to a normal operating level, so that the volume and velocity of the resulting fuel stream 206 exiting the nozzle 218 are also reduced. This enables a preheat flame to be supported in the fuel stream 206 between the nozzle 218 and the flame holder 102. An ignition source, such as a spark generator, etc., is employed to ignite the preheat flame, which produces heat that is transmitted to the flame holder 102. When at least a portion of the flame holder 102 reaches a selected minimum operating temperature, the controller 532 controls the fuel control valve 236 to admit an increased flow of fuel appropriate for normal operation. The start-up flame, which becomes unstable in the increasing volume and velocity of the fuel stream 206, is extinguished or blown upward toward the flame holder 102. The minimum operating temperature is selected to be sufficiently high to cause auto-combustion when the fuel stream 206 comes into contact. Thus, a combustion reaction is ignited within the perforated flame holder 102. Principles of the operation of the flame holder 102 are discussed in more detail above, with reference to
In the embodiment of
The combustion system operates substantially as described with reference to the embodiment of
According to an embodiment, an air intake 612 has a relatively reduced intake aperture 614, which ensures that the blower 238 is able to draw down the air pressure at its upstream side, enabling a strong draught of recirculated flue gas into the air line 510.
In describing the embodiments illustrated in the drawings, directional references, such as right, left, top, bottom, etc., are used to refer to elements or movements as they are shown in the figures. Such terms are used to simplify the description and are not to be construed as limiting the claims in any way. Furthermore, while the drawings show respective embodiments with a perforated flame holder in a horizontal orientation and a fuel nozzle positioned below, embodiments are contemplated in which the combustion system is differently oriented, such as, for example, with the flame holder oriented vertically, and the nozzle is positioned to one side.
The abstract of the present disclosure is provided as a brief outline of some of the principles of the invention according to one embodiment, and is not intended as a complete or definitive description of any embodiment thereof, nor should it be relied upon to define terms used in the specification or claims. The abstract does not limit the scope of the claims.
While various aspects and embodiments have been disclosed herein, other aspects and embodiments are contemplated. The various aspects and embodiments disclosed herein are for purposes of illustration and are not intended to be limiting, with the true scope and spirit being indicated by the following claims.
The present application claims priority benefit from U.S. Provisional Patent Application No. 62/206,633, entitled “COMBUSTION SYSTEM WITH A PERFORATED FLAME HOLDER AND AN EXTERNAL FLUE GAS RECIRCULATION APPARATUS,” filed Aug. 18, 2015 (docket number 2651-268-02); which, to the extent not inconsistent with the disclosure herein, is incorporated by reference.
| Number | Date | Country | |
|---|---|---|---|
| 62206633 | Aug 2015 | US |
