The present invention is a combustion system in which hot flue gases are split into at least two streams, mixed with recycled gas to control the gas temperature and introduced into a heat recovery steam generator. The split arrangement allows for lower recycling power requirements and a smaller heat exchange area.
Reducing the capital cost and/or increasing the efficiency of power generation is highly desirable especially given the ever growing market for electric power [1]. Besides economic concerns, efficiency in power generation is also important because the dominating majority of electric energy production is from non-renewable fossil fuels, and there are increasing concerns and regulations regarding the associated greenhouse gas emissions [2]. Flexibility to uncertain parameters, like fuel specifications, ambient conditions, and thermal load is another important characteristic required from the implemented technologies.
In thermal power generation there are several forms of unavoidable losses as well as several operations constraints and economic considerations. For example, heat exchanger areas are limited by capital cost considerations, resulting in less effective heat transfer and/or larger pressure drops of the streams due to the packed and constrained pathways; thus, the efficiency of the cycle decreases. Metallurgic properties pose temperature constraints on combustors, boilers, heat recovery steam generators (HRSG), turbines, etc., [3,4], thus resulting in energy waste and reduction of power output. For example, flue gas recycling (FGR) in coal boilers is required in order to quench the combustion gas to limit the radiative-dominant (high temperature) heat transfer requirement and enable a convective-dominant heat transfer; flue gas recycling (FGR) is applied because radiation is more expensive than convection for the same degree of thermal energy transfer, [5], PGR also increases the boiler efficiency and reduces emissions, and is applied in almost all relatively recent (younger than 30 years old) coal fired powerplants, [5, 6]. The FGR requires compression to compensate for losses in the boiler and the recycling pipes; moreover, throughout the heat exchange process, the temperature gradient between the hot and cold streams decreases as flue gas moves away from the inlet, which increases the heat exchange area required close to the cold end of the heat exchanger.
One of the promising concepts of carbon-capture and sequestration is pressurized oxy-coal combustion (OCC). Pressurizing the flue gas increases the effectiveness of the convection heat transfer, In [7, 8, 9, 10, 11, 12, 13, 14], a pressurized OCC concept is considered with an HRSG with relatively high FGR that relies on connective heat transfer. Note that in general the combustion process occurs in a section that may or may not be physically connected to the HRSG, referred to as a combustor. The capital cost of the HRSG is a relatively large portion of the capital cost of the powerplant, e.g., [15], and reducing its size results in significant savings.
The combustion system of the invention includes a combustor generating a combustion gas and a splitter for receiving the combustion gas and dividing the combustion gas into first and second gas streams. A temperature controller receives the first gas stream, mixes it with recycled gas and introduces it into a heat recovery steam generator at a desired temperature. A mixer receives the second gas stream mixing it with recycled gas and introducing it into the HRSG. Cool gas exits the HRSG with the cool gas forming the recycled gas. In a preferred embodiment, the combustor is an oxy-coal combustor. A preferred embodiment further includes recycling fans to pressurize the recycled gas for mixing with the first and second gas streams. The mass flow rate of the second gas stream, temperature at an inlet of the HRSG and flow rate of the recycled gas are controlled to optimize the system, to minimize heat exchanger area. Recycling power requirements are also smaller.
Herein, a novel split concept for the HRSG is introduced in order to enhance the rate of thermal energy transfer by increasing the average temperature between the involved streams, and reduce the compression requirements by reducing the recycling flow rates and/or pressure losses compared to the conventional operation. The concept is applicable to coal boilers and other heat exchange processes that require quenching of the hot fluid.
The concept disclosed herein splits the hot combustion gas prior to its dilution by the secondary recycling stream. The flue gas entering the HRSG 12 decreases in temperature as it exchanges thermal energy with the working fluid 14 of the Rankine cycle; flue gas acid condensation in the HRSG is not allowed as discussed later. In essence, the mixing of the split stream in the HRSG 12 is intended to elevate the flue gas temperature. The primary flue gas is mixed with a recycling stream similar to the HRSG without splitting. The split flue gas is (potentially) mixed with another secondary recycling stream. The secondary recycling to the split allows larger ranges and larger feasible combinations of the mixing positions and the mixing temperatures. The specific amount of recycling to the split, if any, is determined by optimization. Minimal area does not require any recycling to the split, whereas minimal compensation power is required. The additional split pipe, the pipe of the recycling to the split (if used), and the recycling to the split recycling fan (if used) add some capital cost, however, it is insignificant compared to the savings in the HRSG. Note that even when two recycling streams are used, a single fan 16 can be installed by introducing some throttling at the outlet of the split recycling stream; obviously this results in higher compensation power requirements. For a given HRSG thermal load, the splitting process can increase the overall temperature difference between the streams of the exchanger, particularly avoiding small temperature differences which require the most heat transfer area. Moreover, the split allows for lower rates of recycled flue gas compared to regular HRSG: the required amount of recycling to the inlet of the HRSG is smaller because it needs to dilute a smaller amount of the combustion gas. Also, at the mixing position, the flue gas within the HRSG acts as a diluent to the split stream, thus a relatively small amount of the recycling to the split is required (if any).
The higher average temperature differences imply smaller exchanger area, and the lower recycling requirements imply lower pressure drops and lower compensation power requirements (CPR). The CPR consists of two components; the first is the power needed by the recycling fans 16 to re-pressurize the recycling streams to compensate for the pressure losses encountered in the HRSG 12 and the recycling pipes. The second component of the CPR is the power needed to maintain the main flue gas flow as it faces pressure losses while passing through the HRSG. For simplicity, only one split is illustrated and tested here. Multiple splits, that would be introduced sequentially at different intermediate locations, are possible and would further increase performance and decrease the heat transfer area, but would add structural complexity. Note that in general the split can be extracted from any point along the HRSG and not limited to the inlet combustion gas, and the recycling can also be withdrawn from any point along the HRSG and not limited to the outlet Cool-Gas; however, such processes are less practical to implement and more complicated to model and optimize.
To illustrate the possible advantages,
265 bar
250 bar
The first profile in
The second profile in
The third profile in
The fourth profile in
It can be proven geometrically that for a given split flowrate, the largest temperature differences between the hot and cold streams are attained when the inlet and the mixing temperatures are at the maximum allowed and when there is no recycling to the split. Also, by comparing the slopes of the temperature profiles, it can be proven that for any split flowrate operating with the mixing temperatures at the maximum possible value minimizes the flowrate of the recycling streams. It is tempting to say that for a given split flowrate the least area requirements and the least recycling requirements are obtained when the constraints of the maximum allowable temperatures are active; as the optimization shows, in fact the area is minimized when the maximum temperature constraints are active, however, this is not always true for the CPR.
It also can be proven that any split operation with a certain total amount of recycling, regardless of the number of splits, the splits flowrates, or the mixing positions, can at most reach the borders outlined by a profile with no split and the same total amount of recycling introduced all at once to the inlet; as an example Profile3 and Profile1 with an infinitesimal recycling to the inlet, respectively.
The purpose of the split disclosed herein is to reduce the capital cost by utilizing smaller surface area of the heat exchanger and reduce the CPR by reducing pressure drops and/or recycling flowrates. The two objectives are neither equivalent, nor mutually exclusive, and have to be accounted for simultaneously; smaller exchangers in general lead to larger pressure losses, and the flow properties affect the heat transfer coefficient, the HRSG pressure drop, and the recycling losses. The HRSG area may be calculated according to the logarithmic mean to temperature differences and heat exchanger elements.
The CPR consists of two components: the first component of the CPR is the power needed by the recycling fans to re-pressurize the recycling streams after experiencing pressure losses from the HRSG and the recycling pipes. The second component is the power needed to maintain the main gas flow and overcome the HRSG pressure losses. The extra compression needed to overcome the main flow losses can be introduced prior to combustion or after the HRSG. For example, in standard coal powerplants, the same fans or compressors that drive the inlet streams to the combustor force the flow through the main stream pressure losses. But in pressurized OCC combustors, since a compressor is already present after thermal recovery and needed for the carbon sequestration unit (CSU), the compensation power requirement is less costly to be accounted for by compressing a cooler stream with a lower flowrate post the thermal recovery.
As aforementioned, a single split is considered herein. The independent decision variables are chosen to facilitate optimization, since they allow satisfying some constraints by properly setting their ranges. Also, these variables are considered the simplest to monitor and to set their desired values during operation. The optimization variables are: i-the split flowrate, {dot over (m)}Split 1,, ii-the temperature at the inlet of the HRSG TMix,0, iii-the flowrate of the recycling stream to the split, {dot over (m)}Rec, 1, and finally iv-the temperature of the flue gas in the HRSG after introducing the split, TMix,1. The variables are illustrated in
Based on this choice of independent variables, important variables are now dependent. For example, the flowrate of the recycling stream to the inlet, {dot over (m)}Rec,0, is dependent once the split flowrate and the inlet temperatures are specified; i.e., the stream entering the HRSG is fully specified. Further, the position of introducing mixture of the split and its recycling in the heat exchanger,
is dependent once the split flowrate, the flowrate of the recycling to the split, and the mixing temperature are specified.
The operation of the heat exchanger is subject to physical limitations. Introducing the split provides better performance while still satisfying these constraints. The temperatures of the streams inside the heat exchanger are a major concern. Defined by the metallurgic properties, the maximum temperature allowed in the HRSG is limited to THRSG max=800° C. In essence the constraint has to be satisfied at every point within the heat exchanger, but because the temperature monotonically decreases along the HRSG (apart form the mixing point), the constraint needs only to be imposed at the inlet and at the mixing position. For the addressed values of the input stream, the temperature of the cold stream entering the HRSG is safely above the acid condensation temperature of the flue gas, [11], therefore, there is no need to include the constraint on the minimum allowed temperature for avoiding condensation of acids in the flue gas or on the feedwater tubes in the flue gas. In contrast, it is beneficial to include constrains on the MITA to avoid temperature crossovers and ensure a realistic operation. The physical limit of MITA is zero, but a value of 0.5° C is used to speed the optimization process. In other words, the intuition that small MITAs are clearly undesirable since they result in huge area requirement, is communicated to the optimizer.
A coal powerplant utilizes different types of coals during its lifetime. The advantages of the split concept are not limited to the type of coal used; for any coal utilized for power generation, the HRSG-split can be designed accordingly in order to reduce the area and/or the CPR. Since during the operation of the powerplant the utilized coal is expected to change, it is extremely important that the optimal design of the HRSG-split for one coal is flexible to changing the coal; i.e., the design is also optimal for the other coal.
Assessing the flexibility of the HRSG-split in general requires characterizing the variables as design or operation valuables, [13, 14]. Design variables are fixed upon design while operation variables can change with the different operations of the HRSG. The four independent variables for the optimization of the standalone HRSG-split TMIX0, {dot over (m)}Split1, TMix1, & {dot over (m)}Rec1, are all operation variables, However, dependent variables of the standalone model, in particular the split mixing position, Mix-Pos, and the resulting HRSG area
are design variables and have to be common between the different operations. Luckily, based on the following approach, there is no need to reformulate the problem to include design variables as decision variables, which pose a lot of difficulties in solving for the objective function which would require complicated numerical methods, and result in large domains of infeasible operations.
The ideal flexibility is demonstrated herein by a much simpler approach; the same optimization above is performed on a standalone HRSG-split but with the new specifications of the input streams which are relevant to a coal different from the original. The input streams specifications used above are a result of the pressurized OCC process designed for ideal flexibility to uncertainties when operating with a typical bituminous coal with composition similar to Venezuelan and Indonesian coals (referred to as CoalA), while the new streams' specifications result from operating with a lower quality South African coal almost identical to Douglas Premium or Kleincopje coal (referred to as CoalB), as presented in [13], The multi-objective optimization of the HRSG-split operating with the streams conditions of CoalB results in a Pareto front curve very similar to that seen for the HRSG-split multi-objective optimization (presented above) operating with the conditions of CoalA. More specifically, equal areas of the two Pareto fronts have identical mixing positions, therefore, a given Pareto optimal design of the HRSG-split for one coal is also a Pareto optimal design for the second, therefore, the HRSG is thermodynamically ideally flexible. Moreover, equal areas between the original and new Pareto curves are a result of equal weight vectors for the multi-objective optimization, therefore, the HRSG-split is also economically ideally flexible; determining the most profitable design does not require to consider the coal distribution because any optimal design for one operation is optimal for the other, and has the same tendencies/preferences towards each of the two objectives. A similar behavior to that of the coal variation is encountered for the other uncertainties. As a conclusion, the HRSG-split is ideally flexible to uncertainties, and at least capable of maintaining the flexibility of the process it is incorporated in.
The application of the HRSG-split is not limited to the OCC process. The split concept can be applied to any heat exchanger process that requires a recycling stream to control the temperature of the main stream; for example, in conventional boilers, both the PGR rates and the heat exchange area, particularly radiative, can be reduced. The concept can be readily applied to new powerplants; moreover, the retrofit of existing plants in conceivable.
Although not shown here, the benefits of the HRSG-split in subcritical power cycles can have larger magnitudes than those obtained here for a supercritical. Recall that the smaller the temperature differences between the streams, the larger the area required for the same amount of heat transfer, and therefore, the exchanger area is directly related to the value of the MITA. In the case study above, the feedwater conditions are those from an optimized supercritical Rankine cycle, where the pinch in the HRSG is located at the cold end; the feedwater temperature entering the HRSG is relatively large, by utilizing the FWHs regeneration, allowing higher rates of feedwater through the HRSG while respecting the MITA specifications, and thus larger flowrates through the expansion line to increase the power output and efficiency. Since the pinch is at the cold end, introducing the HRSG-split cannot avoid the pinch because the flue gas temperature at the exit of the HRSG varies only slightly due to the variations in the CPR. Also, the feedwater temperature profile in the HRSG is smooth due to the absence of phase transition. On the other hand, with subcritical feedwater, the transition from the subcooled liquid state to the two-phase state is marked by a sharp kink, and usually the pinch point occurs at that location rather than at the cold end. Since in an HRSG-split the temperature of the flue gas after mixing is larger than that of the basecase operation, except very close to the exit of the HRSG where the temperature might be slightly lower depending on the CPR, then the temperature difference at the location of the pinch is larger than that of the basecase. Now since in subcritical operations the pinch is alleviated, the reduction in area and pressure losses are significantly larger compared to the supercritical scenario. Note that the increase in the temperature approach due to the split in the suberitical process allows, upon process optimization, for even larger feedwater flowrate through the HRSG which increases the power output and the efficiency; i.e., compared to the supercritical scenario, in a suberitical process the savings on area and CPR are larger, and there is a possibility of increased power output and further in the efficiency.
The split concept disclosed herein is applicable to heat exchangers that require recycling of the hot stream for temperature control, e.g., coal boilers and HRSGs. The concept proposes splitting the hot stream, which has a temperature higher than that allowed in the heat exchanger, before its dilution and its introduction into the heat exchanger. At the inlet of the flue gas, a lower amount of dilution is required to control the temperature of the now smaller fluid flowrate. The split fraction is then introduced into the heat exchanger at an intermediate point downstream, increasing the temperature of the hot stream and enhancing the temperature gradient of the heat exchange process. The concept is able to reduce the cost by reducing the area requirements and/or increase the efficiency by decreasing the power required to compensate for the pressure losses of the flue gas. The concept is illustrated in a standalone model of an HRSG in the context of a pressurized oxy-coal combustion process. Multi-objective optimization is performed by constructing the Pareto front of minimal area and minimal power requirements. Both the heat exchange area and the compensation power requirements are shown to be reduced compared to the conventional operation; in the illustrated case, the area can be reduced down to 0.63 the original size, and the compensation power requirements can be reduced down to 0.82 the original requirements. The design and operation is not limited to new heat exchangers and retrofitting in considered easily possible because no changes in the internal structure of the heat exchanger is required.
Moreover, facing uncertainty in input parameters and operating conditions, the split concept is shown to be ideally flexible and preserves the flexibility of the process it belongs to.
Herein, the heat exchanger process is enhanced by a modification to the design of heat exchanger while holding the input streams and the total transferred thermal energy constant. However, the input streams to the exchanger are variables of the process it belongs to. Therefore, the overall performance of the process and the performance of the HRSG and the capital cost savings can be enhanced by simultaneous optimization of the HRSG-Split and the powerplant design.
Further details of the invention are included in “A Split Concept for HRSG (Heat Recovery Steam Generation) with Simultaneous Area Reduction and Performance Improvement,” Zehian and Mitsos, Vol. 71, pp. 421-431, Energy (2014).
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This application claims priority to provisional application Ser. No. 61/880266 filed on Sep. 20, 2013, the contents of which are incorporated herein by reference.
This invention was made with government support under Grant No. DE-FE0009478 awarded by the Department of Energy. The government has certain rights in the invention.
Number | Date | Country | |
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61880266 | Sep 2013 | US |