The invention relates to a compact arrangement for multipole, surge-proof surge arresters, comprising internally wired, encapsulated spark gaps which are arranged essentially in parallel in a housing, the gaps having facing projecting contact surfaces connected to outer terminals and inner contact bars or bridges, and also comprising an electronic control or trigger circuit present on a wiring support, according to the preamble of claim 1, and an encapsulated surge arrester, in particular for use in such a compact arrangement, according to the preamble of claim 19.
Multipole surge arresters are known which are surge-proof up to 100 kA and which contain, although not in a 3+1 circuit, a plurality of encapsulated spark gaps.
In a so-called 3+1 circuit, the outer conductors L1, L2, L3 are connected to N, and the N-conductor is in turn connected to PE. Thus, in such embodiments of multipole surge arresters in one housing, a change of the internal wiring plane is required when all of the conductors (L1, L2, L3 and N) are to be connected from one side.
If such internal wiring is formed by an additional bridge, at least two more screw or weld connections are necessary for electrically bonding. Due to the fact that such a bridge is exposed to a very high mechanical load at the mentioned possible surges of up to a range of about 100 kA, the corresponding dimensional and mechanical configuration must be provided.
A further problem with multipole arresters alternating wiring planes is that as far as possible no additional space for the bridge itself should be taken up, so that the outer dimensions of the housing are not changed or so that standard housings also suited for other applications may be used.
Likewise for reasons of space minimization, the trigger circuit or a control circuit is to be integrated within the housing, with the electrical connection points having to be formed taking into account the work required for assembly and production.
In low-voltage systems, so-called N-PE-spark gaps are used for protection against surges between the N-conductor and the PE-conductor.
These spark gaps must have a very high surge arresting capacity of up to 100 kA 10/350 μs, in particular for protection from direct lightning strokes.
Encapsulated spark gaps having such a capacity are, for example, already known from DE 196 04 947 C1, DE 198 18 674 A1 or DE 298 10 937 U1. These spark gaps have a protection level of ≧2.5 kV.
In certain applications, however, spark gaps having lower protection levels are required. For realizing these requirements, the use of trigger circuits is appropriate. Powerful N-PE-spark gaps also comprising an additional efficient trigger electrode at constant high capacity, are not yet available.
The high current load, the associated high burning away of material, the high dynamic loads caused by electric current forces, pressure, energy and temperature, pose considerable constructional demands for encapsulated arresters.
Surge arresters having coaxial electrode arrangements, which are advantageous in manufacture due to their rotational symmetry, are for example disclosed in EP 0 840 413 A1 or EP 0 771 055 A1. Therein, a bilaterally insulated electrode is guided through a tube which at the same time constitutes the outer electrode and the housing cover. The inclusion of an additional trigger electrode is not possible or only in a complicated manner. Moreover, an additional electrode would be arranged directly in the arc area, and would hence influence the arcing behavior and be subjected to a strong burning. According to DE 35 28 556 A1 or EP 0 242 688 B1, coaxial electrode arrangements are formed by a rod electrode projecting unilaterally into a tube electrode. In the cited solutions, the insertion of a third electrode is not provided, and can also be hardly realized. Moreover, there is the risk with the ignition in particular of arcs of high current or long duration that these exit from the coaxial electrode area and cause severe damage to the gap encapsulation. Existent cavities outside of the preferred arc chamber may not be used for pressure compensation or as an expansion chamber, since heat discharge to the insulation material of the chamber wall is extremely inefficient.
From U.S. Pat. No. 3,849,704 but also from DE 198 17 063 A1, encapsulated spark gaps having a coaxial electrode arrangement are already known.
According to DE 198 17 063 A1, the interelectrode distance increases with an increasing distance from the point of spark-over. Here, the target is to achieve an arc migration with an arc extension for increasing the quenching capacity in the follow current. The arc extension, however, forcibly leads to higher energy turnovers and major temperature and pressure loads, which, in particular in N-PE-spark gaps are unnecessary and moreover undesired.
The cited surge arresters likewise do not have a third electrode for triggering. Nor does the above cited prior art show an expansion chamber, in which the heated gas can be efficiently cooled down after or even during load application. Such a measure, however, is in particular essential for N-PE-spark gaps in an encapsulated form, since the pressure load, the arc voltage and consequently the energy turnover and the temperature load may be limited to a minimum.
On the other hand, an overvoltage protection system is known from DE 100 08 764 A1, featuring coaxial main electrodes that can be triggered. The connection of the electrodes is realized from the same side so as to effect within the discharge gap a directed movement of the arc towards a baffle.
This, however, results in an extension and division of the arc, whereby a quenching of follow currents is intended to be supported. As has already been explained, the extension of the arc is not purposeful for the N-PE-spark gap.
Moreover, the known spark gap has no suitable expansion chamber permitting the cooling down of hot gases. The high pressure developing thus causes an undesired increase of the arc voltage and causes unnecessary mechanical stress on the spark gap housing. A reduction of the pressure load can only be achieved by means of large outlet openings that are already efficient during the arc formation. However, there exists the risk of an undesired escape of electrically conducting gases.
DE-AS 12 82 153 discloses a spark gap having a so-called expansion chamber and a reflection chamber. The reflection chamber is intended to selectively press the arc into the expansion chamber by means of pressure arising during the arc ignition to protect the ignition point from-too high a burning, on the one hand, and for extending the arc, on the other hand, so that the quenching behavior of the spark gap is improved.
From the foregoing the object of the invention is firstly to provide an improved compact arrangement for multipole, surge-proof surge arresters comprising internally wired, encapsulated spark gaps which are arranged essentially in parallel in a housing and having a trigger circuit, which can also be used for a so-called 3+1 circuit and which can be produced in a particularly cost-efficient manner.
This part of the object of the invention is solved by a compact arrangement for multipole, surge-proof surge arresters according to the features of claim 1, with the dependent claims 2-18 providing at least purposeful configurations and further improvements.
Furthermore, it is an object of the invention to provide an improved encapsulated surge arrester with a spark gap arrangement, which can in particular be used as an N-PE-arrester in a compact arrangement. The surge arrester is intended to fulfill these essential requirements of high insulation capacity and a very high arresting capacity, and it should be possible for the surge arrester to be rendered triggerable by means of a third electrode.
This partial object of the invention is solved by an encapsulated surge arrester according to the features of claim 19, with the following dependent claims at least comprising purposeful configurations and further improvements.
According to a basic idea of the invention, a trough-shaped housing with inner dividing walls is provided, with the resulting housing chambers accommodating the individual spark gaps and the corresponding terminals.
An insulating plate with openings into which spring contact elements are introduced is provided on the upwardly opening housing trough.
Above said insulating plate is the wiring support for the electronic control or trigger circuit, whereby the spring contacts form an electrical connection between contact points on the underside of the wiring support on the one hand, and the outer covering of each of the spark gaps on the other hand.
Preferably the wiring support is a copper-clad circuit board, with the contact points on the underside of said circuit board formed as large-area solder lands.
Said circuit board comprises lateral, preferably offset connecting terminal lugs that can be electrically and mechanically connected to inner contact bars situated in the corresponding housing chambers. Thus, not only the desired electrical contact is achieved but also a mechanical locking of the insulation plate comprising the spring contact elements. Separate fastening means for the insulation plate itself may be omitted.
In the area of the openings, the underside of the insulation plate preferably features sleeve-like extensions cut at an angle to the longitudinal axis so that the spring contact elements, on the one hand, are secured from dropping out, and, on the other hand, a conductive portion thereof is exposed. In the non-cut lower area, the sleeve-like extension is closed to accommodate preferably cylindrical pressure springs, which on both sides of the corresponding openings are exposed or project, i.e. upwardly and downwardly beyond the cut portion.
If the encapsulated spark gaps have an essentially cylindrical shape, said cut portion of the sleeve-like extensions is formed like a circle segment and complementarily to the cylindrical spark gap housing.
Opposite each of the sleeve-like extensions, at least one other locking extension is formed on the insulating plate, which locking extension with its side facing the respective spark gap is adapted to the housing shape of same, so that the insulating plate aligns itself when being placed, thereby further simplifying assembly.
The upper side of the insulating plate features spacer cams formed thereon that rest against the underside of the circuit board. Undesired force effects acting upon the soldering points of the electronic components on the circuit board, as well as undesired tensions and forces acting upon the circuit board are thereby minimized. To this effect, said spacer cams are arranged distributed across the outer periphery of the upper side of the insulating plate.
The housing and the insulating plate are preferably injection-molded plastic parts, i.e. the insulating plate in particular is integrally formed with the sleeve-like extensions and the spacer cams.
A wiring plane change-over bridge provided for a 3+1 circuit essentially features a Z-shape with two short connection legs facing in opposite directions, and one longer connection leg, with the fastening and electrical contact being achieved by a fitting essentially based only on a form fit.
Existing contact surfaces projecting from the spark gaps are used to achieve the fastening and bonding of the wiring plane change-over bridge through these quasi bolts. The longer connection leg of the wiring plane change-over bridge may be provided with an insulation covering.
In the short legs, fitting bores or recesses are formed corresponding to the outer dimensions of each of the projecting contact surfaces of the spark gap.
Moreover, the material thickness of at least the short legs is essentially equal to or by a minor amount less than the height of the contact surface projection of each spark gap. The wiring plane change-over bridge is then arranged in the outer housing of the surge arrester so that the long leg extends in the spacing of the space between two of the spark gaps or between two chambers.
For internal connection and for accommodating outer terminals, the contact bars necessary for this effect are formed in one embodiment of the invention as metallic angular elements, with a first angle leg being non-positively connected with the corresponding projecting contact surface of the spark gap, and a form-fit support being provided in the housing by this leg. A second angle leg accommodates the mentioned outer terminals or serves for fastening same.
The first angle leg of the contact bars is connected with the corresponding contact surface of the spark gap by screw connections, with the therein provided internally threaded bore being used for this purpose.
The screw connection as mentioned before serves at the same time for securing the corresponding short legs of the wiring plane change-over bridge.
Consequently, no further screw connection or a similar contact measure for the change of the wiring plane, e.g. across the contact bars, is necessary.
In a three-phase arrangement of the multipole surge arrester with a neutral conductor, one of the contact bars connects three of the four spark gaps on one of the longitudinal housing sides. The contact bar provided on the opposite longitudinal housing side either is formed as a single bar per spark gap or as a contact bar that features insulating portions. This contact bar featuring in each case single contact bars or the insulating portions receives the terminals of the phase or neutral conductors.
For the PE-connection, a further contact bar is provided with at least one outer terminal that is connected with the fourth spark gap.
The wiring plane change-over bridge extends between the third phase spark gap and the neutral conductor spark gap and is there correspondingly electrically connected.
The wiring plane change-over bridge is preferably made of a conductive flat material, in particular copper.
As mentioned before, the chambers formed in the housing accommodate the spark gaps, with the longitudinal housing sides comprising grooves or slots serving to guide and fasten the contact bars.
One of the chamber walls may be formed to guidingly receive at least a partial portion of the wiring plane change-over bridge.
In the area of the short legs of the wiring plane change-over bridge, tongue-like elevations or projections are arranged or provided, which when assembled, form a counter-bearing facing the corresponding first angle leg of the contact bar so that extension forces of the wiring plane change-over bridge arising with a surge current, can be safely absorbed.
With the current flow resulting in a 3+1 circuit with a change of the wiring plane, the change-over bridge is arranged so that current-contingent electrical forces will compensatingly cancel each other out, a fact which constitutes another essential advantage of the invention.
Due to the fact that the contact of the wiring plane change-over bridge directly ensues at the spark gap stacks via bores in the bridge, no further additional mechanical connections are necessary. The preferred fitting and the additional securing of the fit clamping by means of the contact bars creates an optimal electrical and mechanical construction without increasing space and the outer dimensions of the housing of the multipole arrester being changed as a consequence.
The preferred stack arrangement of spark gaps in a first plane, an insulating plate arranged above, and the circuit board including an electronic circuit arranged above same advantageously reduces space as desired. The insulating plate thereby not only fulfills the function of electric insulation but also serves as the support element of preferably cylindrical pressure springs, which serve the purpose of electrically contacting or connecting the control or trigger circuit to the spark gaps present in the first plane. An outer cover then completes the overall arrangement and provides safety from contact and protection of the assembly.
In the surge arrester improved according to the invention, a coaxial construction of at least partially overlapping main electrodes is provided that have oppositely directed connections. The main electrodes include an arc chamber in conjunction with at least one insulation part.
According to the invention, at least one of the main electrodes has an inner expansion chamber, and a preferably radially or axially rotationally symmetrically extending trigger electrode is provided in the area of the insulation part.
Preferably, the first main electrode is formed as a rod electrode with a cavity, with the latter being in flow-side communication with the arc chamber through openings.
In the connection area of the second, hollow-cylindrically formed main electrode, a further expansion chamber is present.
The expansion chambers may feature a minimized pressure compensation opening, which is preferably formed in the area of the connections.
In one embodiment of the invention, the rod electrode, with its end distal from the connection, is centered and held within the surrounding second main electrode by a further insulation part.
The second insulation part has return channels up to the expansion chamber of the second main electrode.
Both expansion chambers can be in flow-side communication by at least one insulating channel.
By a variation of the radial distance between the coaxially arranged, partially overlapping electrodes, a corresponding response voltage may be selectively predetermined.
At least one of the electrodes has a shoulder or a stepped configuration directed towards the arc chamber for a stepped response behavior and a secure quenching capacity even in the case of triggering failing.
According to the invention, there exists the further possibility of forming the arc chamber to be divisible by a circumferential ridge mounted on the rod electrode.
On their surfaces facing the arc chamber, the main electrodes may have groove-shaped contours, ridges and/or cams for minimization of burning away.
The second main electrode surrounding the first main electrode may constitute an essential part of the encapsulation.
The first and/or second insulation part may feature at least one circumferential ridge for supporting sparking in air.
In one pressure-proof embodiment of the surge arrester, a quenching gas filling is preferably provided.
By the arrangement proposed according to the invention of two electrodes realized one in another in coaxial position and made of a burning-resistant material, having oppositely directed connections, with the main electrodes disposing of internal expansion chambers, a configuration develops permitting the inclusion of a rotationally symmetrical third, so-called trigger electrode. The overall arrangement has a high insulation capacity at a correspondingly high surge arresting capacity, and is therefore particularly destined for use as an N-PE-spark gap.
The invention will be described in the following by means of example embodiments and with reference to the Figures.
According to
On the upwardly opening housing trough, an insulating plate 25 is placed that has several sleeve-like extensions 26 on its underside. These sleeve-like extensions serve to receive a cylindrical pressure spring 27 (cf. also
In the spark gaps 1 through 4 in a form with a cylindrical metallic outer housing, said sleeve-like extensions 26 are cut or recessed in the shape of a circle segment, whereby a part of the cylindrical pressure spring 27 is exposed. The lower end portion 28 of the sleeve-like extensions 26 is closed, whereby the respective cylindrical pressure springs 27 are prevented from dropping out.
Hence, it can be seen from
Opposite each of the sleeve-like extensions 26, at least one further locking extension 29 is formed on the underside of the insulating plate 25 respectively. Further extensions 30 in the edge area of the underside of the insulating plate secure same against undesired displacement.
On the upper side of the insulating plate 25, spacer cams 31 are present formed on the outer edge area which in conjunction with the offset terminal lugs 32 present on the circuit board 33 prevent undesired tension forces from acting upon the soldering points for the electronic components on the circuit board 33 or upon the circuit board itself.
With reference to
The diameter of the contact points 34 is equal to or larger than the diameter of the cylindrical pressure springs or of the upper end of said contact spring 27. The typical flat cone shape of a solder point, in conjunction with the elasticity of the corresponding cylindrical pressure spring results in a centering and secure connection even when unavoidable tolerances with respect to the position and the embodiment of the terminal lugs 32 and their fastening by means of screws 13 are present.
The size ratios between the contact points 34, on one side, and remaining soldering lands 35 for fastening the electronic components on the circuit board 33 may be derived from
In multipole surge arresters in a 3+1 circuit, the necessity arises with a correspondingly desired clamp connection for an internal change of wiring planes, for which purpose a corresponding bridge between one of the phases and the neutral conductor is required.
The practical realization of a multiple, surge-resistant surge arrester in a 3+1 circuit may be seen in
On the opposite side of the housing 6, single contact bars 8 through 11 are provided. These single contact bars each receive a pair of outer terminals 12 (cf. also
The contact bar 7 or the single contact bars 8 through 11 are electrically connected with a projecting contact surface 14 of the corresponding spark gaps 1 through 4 by a screw that is received by an internally threaded bore of the projecting contact surface 14.
The necessary wiring plane change-over bridge 15, which essentially has a Z-shape, is located between the surge arresters 3 and 4 with its longer connection leg.
In the example embodiment as per
As can be particularly clearly seen from the upper part of
Therewith, each short leg 18 can be brought into positive connection with the projecting contact surface 14, with the final fixation then being effected by means of a corresponding contact bar such as is apparent from the lower part of
The material thickness at least of the short legs 18 is essentially equal to or less than the height of the contact surface projection 14 of each of the spark gaps 1 through 4.
Preferably the wiring plane change-over bridge 15 consists of a flat copper material, which can be provided with an insulation covering 19 (cf.
The contact bar 7 but also the single contact bars 8 through 11 are formed as metallic angular elements, with a first angle leg 20 being in non-positive connection with the corresponding projecting contact surface 14 of the corresponding spark gap. Through this leg 20, a positive connection or a corresponding support can be achieved in the housing 6 which has corresponding grooves or similar recesses for this purpose.
A second angle leg 21 carries the terminals 12. The first angle leg 20 is connected with the corresponding contact surface 14 of the corresponding spark gap by a screw connection (cf.
Tongue-like elevations or projections 22 arranged or incorporated in the area of the short legs 18 of the wiring plane change-over bridge 15 when assembled face the corresponding first angle leg so that a counter-bearing develops which can absorb electrodynamic forces in case of a surge.
This counter-bearing in particular counteracts an extension of the bow when current flows.
With an essentially, at least in portions, U-shape of the contact bars 8 through 11 or 23 for the PE-connection, a third tongue angle leg 24 (cf. upper image part as per
Preferably, said first main electrode is formed as a rod electrode having a cavity 47 inside. This cavity 47 constitutes an inner expansion chamber.
Said cavity 47 is in connection with the arc chamber 48 by at least one opening 49.
The first main electrode 41 partially projects into the tubular area of the second main electrode 42 in a coaxial arrangement. Specifically, this overlapping area constitutes the desired coaxial structure.
By means of the pot-shaped form of the second main electrode 42, this can directly form a part of the encapsulation of the entire spark gap so that technological and also material savings are achieved.
To improve guidance and adjustment, it is possible to arrange an insulation part 44 between the first main electrode 41 and the second main electrode 42. This insulation part 44 then simultaneously axially delimits the arc chamber 48.
Preferably, the insulation part 44 has appropriate openings or through-flow channels 410 so that an additional cavity 47 within the second main electrode 42 is in communication with the arc chamber 48.
In order to achieve a complete encapsulation of the electrode arrangement and to further delimit the arc chamber, a (first) insulation part 43 is arranged between the first main electrode 41 and the open end of the main electrode 42.
A solution where the encapsulation is effected outside of the main electrode arrangement and where the arc chamber is not directly delimited by insulation parts is likewise within the scope of the invention.
The insulation part 43 features an additional third electrode for triggering the main gap between the first and second main electrode. This electrode or several electrodes 46 may be arranged in a rod shape, a pin shape but also in a ring shape.
In a preferred embodiment, a disk electrode is used which is aligned coaxially to the first and second main electrodes.
Preferably, said described spark gap is pressed or screwed with additional insulation in a pressure-proof metal housing.
The influence of force thereby takes place along the axis of symmetry. For decoupling to the highest degree the possible sparkover paths of the spark gap along the insulation parts 43 and 44 from the influence of force during the assembly process, these parts extend radially from the axis of symmetry. Thus, it is guaranteed that the influence on the response voltage of the spark gap, due to the assembly process as well as during thermal load of the pressurized insulation parts, remains slight.
The function of the arrangement will be explained in the following.
Upon triggering the spark gap, the trigger electrode 46 strikes one or several ignition sparks 411 to one or both of the main electrodes 41 and/or 42.
Thereupon, the arc 100 strikes between the main electrodes 41 and 42. In that case where the spark gap is formed without a trigger electrode 6, the arc 100 forms by a sliding discharge along the insulation gaps 43 or 44, or by sparking in air between the main electrodes 41 and 42.
After ignition, the arc 100 is present in the arc chamber 48 and may rotate about the first main electrode 41 within this chamber according to the coaxial arrangement. At the time of the arc ignition, overpressure develops within the arc chamber 48 by the gases present heating. This overpressure would lead to an increased mechanical load of the parts, and would in addition increase the arc voltage resulting in an unnecessarily high energy turnover within the spark gap and hence also in high thermal loads.
Also, the high heating of all parts in the arc chamber would complicate the quenching of the arc. For avoiding these negative phenomena, at least one additional cavity 47 is made available for the expanding gas within the spark gap as an expansion chamber, which is not directly exposed to the arc. After ignition of the arc, the heated gas may flow off through the mentioned openings or channels 40 and 410, respectively, into the expansion chamber 47. Due to the large volume, the high heat capacity and the large surface of the metal electrodes present in that chamber 47, the heated gas is immediately cooled down and depressurized.
Pressure increase, arc voltage and energy turnover within the arc chamber thus are limited to a minimum.
In the area of the connections 45 or in a location within the expansion chambers 47, the shown arrangement may in addition have minimal pressure compensation openings that after dying-out of the pressure load provide for a pressure compensation with the environment. This is then particularly advantageous when decomposition of the materials used and consequently a possible additional gas formation arises due to the arc influence within the spark gap. Due to the position and size of the pressure compensation openings, a fast pressure compensation in the range of milliseconds or a slow pressure reduction in the range of minutes may take place.
The arrangement according to
By correspondingly designing the electrode arrangement as a whole, triggerable arresters with a high demand on triggering energy may thus be created, whereby a response of the main spark gap of the arrester only ensues at high-energy overvoltages.
The aforementioned renders the network less sensitive to disturbances and guarantees a better utilization of the capacity of downstream protection means.
On the other hand, however, an arrester may be created by a design of the electrode arrangements shown in
Should the trigger electrode 46 fail, the spark gap features rather high response values due to the centric arrangement of the trigger electrode 46 and the twofold insulation gap implied due to this fact.
In order to achieve here a certain emergency running property of the spark gap, the insulation part 44 according to
This construction results at the same time in the possibility of a stepped response behavior of the spark gap at different rates of voltage rise. This allows for a decoupling of the spark gap just at these different rates of voltage rise. At minor rates of rise, the spark gap is controlled by the trigger circuit and the corresponding trigger gap. Contrary thereto, an overhead ignition of the spark gap may be achieved at high rates of voltage rise, which overhead ignition is characterized in that the trigger unit of the spark gap itself remains uninvolved. The spark gap then ignites quasi automatically in the area of the stepped configuration 412, without the trigger unit being loaded.
Due to the attachment not shown of a high, circumferential ridge made of an insulation material on the first main electrode 41 in the arc chamber, this may be subdivided, and, more precisely, into an area with a trigger electrode and an area without a trigger electrode. This arrangement results in the advantage that in normal function mode only the arc chamber with the trigger electrode is loaded, and the other arc chamber remains unloaded, whereby in case of emergency, i.e. when the triggering fails, the desired emergency running properties may be guaranteed, since these arc chambers have not been impaired by burning, temperature or pollution up to just this given case of emergency. Such a function mode may also be achieved with two completely independent and separated arc chambers.
This arrangement ensures both the protection of the trigger electrode from excessive burning and a reduction of the response voltage without triggering. Furthermore, the required trigger energy may be reduced to a minimum with this arrangement. The ignition spark forming between the trigger electrode 46 and the second main electrode 42 during the response of the trigger circuit, in particular in case of an insulation part 414 minimally projecting into the arc chamber 48 and a minor distance of the main electrodes 41 and 42, may contact the first main electrode 41 already during its formation. Thereby, the insulation gap between the main electrodes 41 and 42 is abruptly bridged and the trigger energy is reduced to a minimum.
In the arrangement as per
For supporting the desired arc rotation and for avoiding too strong a deposit of melt material, one or several circumferential contours, e.g. as grooves or ridges mounted on top may be formed or incorporated into the main electrodes 41 and 42 within the arc chamber 48. Single cams may also be placed on top or other elevations for controlling the response voltage during sparking in air or for controlling burning behavior.
For supporting sparking in air, the insulation parts 43 and 44 may also be provided with at least one circumferential ridge (not shown) projecting into the arc chamber.
Number | Date | Country | Kind |
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100 58 977 | Nov 2000 | DE | national |
101 11 954 | Mar 2001 | DE | national |
101 18 210 | Apr 2001 | DE | national |
101 25 941 | May 2001 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP01/13775 | 11/27/2001 | WO | 00 | 5/27/2003 |
Publishing Document | Publishing Date | Country | Kind |
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WO02/45224 | 6/6/2002 | WO | A |
Number | Name | Date | Kind |
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4475066 | Lee | Oct 1984 | A |
4631453 | DeSouza et al. | Dec 1986 | A |
5936824 | Carpenter, Jr. | Aug 1999 | A |
Number | Date | Country |
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679 715 | Mar 1992 | CH |
690 480 | Sep 2000 | CH |
2 203 286 | Oct 1988 | GB |
98 26480 | Jun 1998 | WO |
Number | Date | Country | |
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20040160723 A1 | Aug 2004 | US |