This application relates to a compact dual fuel combustion system for the purpose of heat generation, methods of using a dual fuel combustion system, and methods of fluid heating incorporating a compact dual fuel combustion system.
Combustion systems are used to provide a heated thermal transfer fluid for a variety of commercial, industrial, and domestic applications such as hydronic, steam, and thermal fluid boilers, for example. Many applications benefits from the incorporation of combustion systems capable of utilizing more than one type of fuel source; for example, combustion systems that can utilize natural gas or hydrocarbon fuel oil as selectable alternatives using the same device. However, different combustion fuels may have distinctly different material properties and thermodynamic characteristics, which present significant challenges in the design of multi-fuel combustion systems. Because of the desire for improved energy efficiency, compactness, reliability, and cost reduction, there remains a need for improved multi-fuel combustion systems, as well as improved methods of manufacture thereof.
Incomplete combustion, suboptimal combustion product flow fields, and large temperature gradients can result in a decrease in overall burner system performance. This is particularly true of combustion systems incorporated into fluid heating systems for the production of hot water, steam, and thermal fluid for hot liquid or steam for ambient temperature regulation, hot water consumption, or commercial and industrial applications. Moreover, residential, commercial, industrial and government uses of combustion systems for a variety of applications benefit from improvements that decrease the size, volume and footprint of these apparatuses, particularly those that utilize premix fuel and air (oxygen) combinations. Thus there remains a need for an improved compact multi-fuel combustion system having improved thermal efficiency.
Disclosed herein is a dual-fuel combustion system utilizing an inward firing premix burner for natural gas combustion and a short-flame length fuel oil burner system utilizing preheated oil.
Also disclosed is an inward firing premix burner combustion system with a composite semi-cone combustion substrate that also defines the combustion cavity for a preheated oil burner.
Also disclosed is an inward firing premix burner combustion system with a composite semi-cone combustion substrate that also defines the combustion cavity for a preheated oil burner also comprising a guide or baffle for directing the air or fuel-air mixture.
Also disclosed is a method for isenthalpic expansion of fuel oil that can be exploited in fluid heating system combustion systems.
Also disclosed is a method for the control of thermodynamic state of liquid fuel to achieve the correct thermodynamic condition necessary to realize the benefits of isenthalpic expansion at the burner dispersion nozzle.
Also disclosed are combustion systems comprising elements of both inward-firing gas burner geometries and isenthalpic oil burner components integrated to provide dual fuel combustion systems that alleviates many of the disadvantages of gas burners and oil jet burners.
Also disclosed are methods of utilizing isenthalpic expansion of a preheated, pressurized fuel oil can produce short flame envelopes compatible with highly compact combustion systems.
Also disclosed is that isenthalpic expansion of a preheated, pressurized fuel oil are amenable to standard burner temperature control methods common to fluid heating systems.
Also disclosed are combustion volume geometries comprising dual-fuel premix gas and isenthalpic expansion of preheated, pressurized fuel oil elements that can be optimized to concurrently achieve high performance of both the premix and oil operating modes.
Also disclosed are combustion systems comprising tangential or oblique inlet ports for air or premix gas-air mixtures further comprising dual-fuel premix gas and isenthalpic expansion of preheated, pressurized fuel oil elements that can obviate the requirement for baffles to guide and direct the incoming flow stream.
Also disclosed are dual fuel combustion systems comprising dual-fuel premix gas and isenthalpic expansion of a preheated, pressurized fuel oil elements that result in reduction of produced nitrogen oxide (NOx) byproducts.
Also disclosed are dual fuel combustion systems comprising dual-fuel premix gas and isenthalpic expansion of a preheated, pressurized fuel oil elements that admit the use of different shapes for the combustion volume and still achieve compact, thermally efficient design objectives.
The above described and other features are exemplified by the following figures and detailed description.
Referring to the figures, which are exemplary embodiments, and wherein the like elements are numbered alike.
In U.S. Provisional Application No. 62/634,476 and International Application (PCT) PCT/US19/19460, the inventors disclosed improvements to premix burner combustion systems comprising inward-firing geometries, including the use of composite semi-cone burner combustion substrates and flow guides or baffles. The applicants also discovered that outward firing combustion systems can suffer incomplete combustion due to the small and constrained combustion volume available, large temperature gradients that can result in material and performance failures, and undesirable flow characteristics of the hot combustion gases and products can be produced in the apparatus.
In the U.S. Provisional Application No. 62/634,520 the inventors further discovered that premix fuel-air burner combustion systems with composite semi-cone substrates that further comprises a metal fiber mesh layer on the inner surface of the substrate improves the performance and reliability of embodiments, particularly when operated in the surface combustion regime, as described herein.
As further discussed herein, the Applicants have further surprisingly discovered that compact dual-fuel type combustion systems may be achieved based on integrating inward-firing gas burner elements and isenthalpic expansion-enabled (alternatively, “flashed”) preheated and pre-pressurized oil burner components.
Disclosed is an improved compact dual fuel combustion system for applications that require heat generation that provides improved efficiency, apparatus lifecycle and performance while still supporting dual fuel operation.
While not wanting to be bound by theory, the following nomenclature is useful in the detailed description that follows:
Consistent with convention, a cone is a geometric surface that can be used to describe certain features of embodiments.
For a semi-cone, the generator angle (alpha or a, as discussed further herein, e.g., regarding an angle of a combustion surface or substrate as described herein) is the angle 114 formed between a specific generator ray 116 and the axis 114 at the vertex 102. For a right circular semi-cone, right circular truncated cone or right circular frustum, all the generator angles are equal and a unique generator angle can be determined.
A semi-cone with a generator angle of ninety degrees (90°) is a flat plate, surface, disk or annulus and the limit of a family of semi-cone that share a common distal end dimensions and shape.
A burner is a combustion system designed to provide thermal energy through a combustion process to apparatuses used for a variety of applications. The burner may include, depending upon the fuel, combustion geometry and target application, a burner head that supports the combustion process, one or a plurality of nozzles or orifices, air blower with damper, burner control system, shut-off devices, fuel regulator, fuel filters, fuel pressure switches, air pressure switches, flame detector, ignition devices, air damper and fuel valves and fittings. Typical burner systems range in capacity from 30 kW to 1,500 kW (approximately 40 HP to 2,100 HP) and can be adapted to a wide range of uses including incinerators, boilers, drying systems, industrial ovens and furnaces.
A package burner is a burner combustion system designed to be incorporated as a standalone modular subsystem unit into apparatuses used for a variety of applications. The package burner may include, depending upon the fuel, combustion geometry and target application, an integrated subsystem comprising a burner head that supports the combustion process, one or a plurality of nozzles or orifices, air blower with damper, burner control system, shut-off devices, fuel regulator, fuel filters, fuel pressure switches, air pressure switches, flame detector, ignition devices, air damper and fuel valves and fittings. Typical package burner systems range in capacity from 30 kW to 1,500 kW (approximately 40 HP to 2,100 HP) and can be adapted to a wide range of uses including incinerators, boilers, drying systems, industrial ovens & furnaces.
In the discussion that follows, we distinguish three types of physical combustion mechanisms. First, “volume combustion” occurs where a fuel-air mixture is ignited in a spatial volume. A physical structure may contain the combustion process, such as in a cavity burner, but the details of the structure do not directly participate in the thermodynamic combustion process. Second, for “surface combustion”, the combustion process (or a majority thereof) occurs directly upon—or very near, or largely in contact with—a burner combustion surface. In some cases, some form of physical insulating or separation layer may be needed at the burner surface to ensure the burner surface does not get too hot or to provide otherwise needed separation from the surface. The physical, geometrical and material characteristics of the surface contribute to determining the thermodynamic physics. Third, in “suspended flame combustion” (SF combustion), the combustion process (or a majority thereof) occurs near—but not directly on—the surface of a combustion substrate, which provides physical support for the generation of the flame front. In some conditions, a small portion of the flame may contact the burner surface (as described more hereinafter). In SF combustion, the flame front (or a majority thereof) is suspended near a positional equilibrium at a distance from the substrate determined partly by a balance of opposing forces due to fuel-air mass flow and flame migration toward its fuel source. If the fuel-air mass flow is reduced below a threshold, the flame front can approach the substrate and enter a regime of surface combustion. If the fuel-air mass flow is increased above a threshold, the flame front can enter a regime of volume combustion. A boiler is a fluid heating system incorporating a heat exchanger that may be used to exchange heat between any suitable fluids, e.g., a first fluid and the second fluid, wherein the first and second fluids may each independently be a gas or a liquid. In the disclosed system, the first fluid, which is directed through the heat exchanger core, is a thermal transfer fluid, and may be a combustion gas, e.g., a gas produced by fuel fired combustor, and may comprise water, carbon monoxide, nitrogen, oxygen, carbon dioxide, combustion byproducts or combination thereof. The thermal transfer fluid may be a product of combustion from a hydrocarbon fuel such as natural gas, propane, or diesel, for example.
Also, the second fluid, which is directed through the pressure vessel and contacts an entire outer surface of the heat exchanger core, is a production fluid and may comprise water, steam, oil, a thermal fluid (e.g., a thermal oil), or combination thereof. The thermal fluid may comprise water, a C2 to C30 glycol such as ethylene glycol, a unsubstituted or substituted C1 to C30 hydrocarbon such as mineral oil or a halogenated C1 to C30 hydrocarbon wherein the halogenated hydrocarbon may optionally be further substituted, a molten salt such as a molten salt comprising potassium nitrate, sodium nitrate, lithium nitrate, or a combination thereof, a silicone, or a combination thereof. Representative halogenated hydrocarbons include 1,1,1,2-tetrafluoroethane, pentafluoroethane, difluoroethane, 1,3,3,3-tetrafluoropropene, and 2,3,3,3-tetrafluoropropene, e.g., chlorofluorocarbons (CFCs) such as a halogenated fluorocarbon (HFC), a halogenated chlorofluorocarbon (HCFC), a perfluorocarbon (PFC), or a combination thereof. The hydrocarbon may be a substituted or unsubstituted aliphatic hydrocarbon, a substituted or unsubstituted alicyclic hydrocarbon, or a combination thereof. Commercially available examples include Therminol® VP-1, (Solutia Inc.), Diphyl® DT (Bayer A. G.), Dowtherm® A (Dow Chemical) and Therm® S300 (Nippon Steel). The thermal fluid can be formulated from an alkaline organic compound, an inorganic compound, or a combination thereof. Also, the thermal fluid may be used in a diluted form, for example with a concentration ranging from 3 weight percent to 60 weight percent, wherein the concentration is determined based on a weight percent of the non-water contents of the thermal transfer fluid in a total content of the thermal transfer fluid.
An embodiment in which the thermal transfer fluid comprises predominately gaseous products from combustion of natural gas or propane, and further comprises liquid water, steam, or a combination thereof and the production fluid comprises liquid water, steam, a thermal fluid, or a combination thereof is specifically mentioned.
A gaseous fuel burner is a type of (non-premix) burner combustion system wherein fuel is ejected from one or a plurality of orifices or nozzles, and the partially oxygenated fuel is ignited to produce a flame. An oil fuel burner is a type of burner combustion system wherein oil fuel is ejected from one or a plurality of orifices or nozzles, and the partially oxygenated fuel is ignited to produce a flame. A dual fuel burner is a type of burner combustion system wherein either gaseous fuel or oil fuel may be used as the fuel source, only one type in operation at a time.
A jet burner is a type of burner combustion system wherein fuel is ejected from one or a plurality of orifices or nozzles, and the lean or partially oxygenated fuel is ignited to produce a flame.
Disclosed in
The long flame length characteristic of a jet burner flame can be mitigated by using a porous substrate to support the flame, breaking the single long flame structure into many small flames concentrated in a compact region in certain specialized embodiments such as an outward-firing premix (air and fuel are mixed upstream of the combustion region and delivered to the burner apparatus) burner.
The flame 200 produced by the ignited fuel jet stream is a rotating structure 236 and can extend in length Lf a significant distance in the furnace 230 cavity. An example of a jet burner combustion system is the Fulton 40-60 Horsepower LONOX® Burner where the flame may be two-to-four feet (0.6 to 1.2 meters) in length and occupy over half the length of the furnace 230.
Moreover, the jet burner embodiment of
Second, to achieve the higher pressure required at the burner head, both the air stream 210 and the lean 212 and rich 216 fuel flows must be maintained at relatively high pressures. That is, a significant fraction of the fan power used to drive these flows must be expended to overcome the pressure drops from the air 226, lean fuel 214 and rich fuel 218 conduits to the burner head 222 and maintain a relative high flow velocity.
Third, the mixing of the lean fuel 214 and rich fuel 218 flow streams with the air flow 204 is primarily generated by the flow of the fuels through small orifices in the burner head 222. Low turndown ratios consequently imply a reduction in fuel-air mixing, which can increase the production of incomplete combustion byproducts and undesirable emissions (e.g., NOx). Hence, the requirement for higher air and fuel flow velocities imposes limitations on low power operation, durability, lifecycle, maintenance requirements and emission characteristics.
Disclosed in
Simultaneously, air is directed from an outside 260 through an air inlet 252 and into a blast tube 265. The air stream, under pressure, passes around and through a spinner 268 designed to create a vertical flow structure 280 that promotes downstream mixing of the air stream and the atomized oil spray. The air stream is directed 270 out of the blast tube into the combustion region 278. The atomized liquid oil spray 290 and the incoming airstream from the blast tube 265 mix in a relatively cool preheating zone 285 within the flame envelope 275. Once the liquid fuel vaporizes on the surface of the oil droplets sufficiently in the presence of oxygen from the blast tube, the mixture ignites in the combustion zone 273 to release heat energy.
A key disadvantage of the oil jet burner embodiment of
The inventors have unexpectedly discovered that for premix gaseous fuel combustion systems, an inward-firing burner geometry alleviates many of the disadvantages inherent in established designs. (“Inward” firing denotes the general case where flow of air and/or gaseous fuel and/or a mixture thereof occurs, or is directed, from a region bounded by or near an inner wall of the burner or furnace inward, or generally towards, the burner centerline where combustion occurs. In structures related to families of semicone geometries, like flat semicones with semicone angle α=90 degrees, any ambiguity is resolved by considering the application of the definition of “inward” direction applied to the corresponding family of semicones.)
α=arctan[(Dd,Dp)/H] Eq. 1
Dimensions of the combustion substrate depend upon the burner power, capacity, performance and size requirements of a specific application. Proximal diameters (Dp) between 1 inch and 59 inches is specifically mentioned. Distal diameters (Dd) between 2 inches and 60 inches is specifically mentioned. Substrate height (H) between 1 inch and 60 inches is specifically mentioned.
The semi-cone sections of the burner combustion substrate angle may have any suitable generator angle between 1 degree, 2 degrees, 3 degrees, 4 degrees, 5 degrees, 10 degrees to 11 degrees, 12 degrees, 13 degrees, 14 degrees, 15 degrees, 16 degrees, 17 degrees, 18 degrees, 19 degrees, 20 degrees, 21 degrees, 22 degrees, 23 degrees, 24 degrees, 25 degrees, 26 degrees, 27 degrees, 28 degrees, 29 degrees, 30 degrees, 31 degrees, 32 degrees, 33 degrees, 34 degrees, 35 degrees, 36 degrees, 37 degrees, 38 degrees, 39 degrees, 40 degrees, 50 degrees, 60 degrees, 70 degrees, 80 degrees, 85 degrees, and 90 degrees wherein the foregoing upper and lower bounds can be independently combined. For the right circular semi-cone, right circular truncated cone, and the right circular frustum, the burner combustion substrate angles between 18 degrees and 35 degrees is specifically mentioned. For the right circular semi-cone, right circular truncated cone, and the right circular frustum, the burner combustion substrate angle of 25 degrees is also specifically mentioned.
In some embodiments, a burner combustion substrate angle α may be 90 degrees which corresponds to a flat structure, surface, plate, disk or annulus, which may be viewed as a degenerate semi-cone that is the limit of a family of semi-cones with circumference diameter, Dd. For the right circular semi-cone, right circular truncated cone, and the right circular frustum, the burner combustion substrate angle α=90 degrees is specifically mentioned.
The burner combustion substrate is porous to the flow of premix fuel-air mixtures predominately in a vapor state. Substrate pores 306 are distributed over the area of the burner combustion substrate to support a flame front near the interior surface. (The pore 312 size in a local area 310 are exaggerated in the diagram for clarity and are not meant to be to scale.) The combustion process may be monitored by a sensor 308 which can detect if the flame is extinguished.
In the embodiment shown a premix(ed) fuel-air mixture 314 enters the inlet 304 of the burner and flows around and through the burner combustion substrate inward toward the axis 309. The fuel-air mixture ratio is arranged so that the premix fuel is ignited near the interior surface to form a flame structure suspended over the interior surface of the burner combustion substrate, within a burner combustion cavity 335. The flame structure may comprise individual flamelets—relatively small, distinct and stable laminar regions of combustion—which may merge at higher combustion production conditions to form a flame front suspended on or over the substrate as described below.
In a boiler application comprising a shell and tube heat exchanger, the combustion products (e.g., hot gases, particulate byproducts) flow 318 towards the tubesheet 302 where they pass through the openings 300 of the heat exchanger tubes 308. Heat generated by the combustion process is transferred across the walls of the heat exchanger tubes 308 to production fluid occupying the space between the outer surfaces of the furnace 330 and heat exchanger tubes 308 and the inner surface of the pressure vessel 322, sealed at one end by the boiler top head 328.
Without being bound by theory, the burner combustion substrate provides a physical structure to support the flame front generated when the premix fuel-air mixture is ignited, and the porosity of the substrate determines certain features of the resulting combustion process as illustrated in
The tendency for the reaction zone to consume the premix fuel-air mixture creates a force toward the pore that tends to move the combustion interface 404 near its apex over the pore with a velocity vgnormal 408. Thus, these two opposing forces balance at a condition where the flame equilibrium ratio number:
in a time-average sense, where the right inequality means “less than approximately”, denoting the fact that the upper bound has been empirically determined by practical examples and should not be construed to limit or constrain the interpretation of the claims. Other embodiments may possess practical upper bounds that are higher or lower when designed by those skilled in the art. That is, an important design characteristic is to select burner substrate construction, porosity and operation conditions that ensures the flame reaction zone remains approximately stationary relative to the pore opening suspended at a distance from the pore.
For certain combinations of pore geometry, premix flow rate and operating conditions, the preheating zone 403, combustion interface 604 and reaction zone 405 remain attached 409 to edges of the pore 312A, forming a stable, persistent structure called a flamelet anchored to the interior surface of the burner substrate 401. Because the flamelet's preheating zone 403 contains uncombusted fuel-air mixture, it is relatively cool compares to the reaction zone 405. That is, the preheating zone 403 serves to insulate the substrate from the high temperature of the reaction zone 405. This is a desirable condition since it allows for high burner heat production capacity while simultaneously maintaining cooler temperatures at the burner substrate surface that promotes longevity of the substrate and reduces the likelihood of material failure. The separation of the reaction zone 405 from the substrate 401 inner surface that promotes this insulative effect can be expressed—in a local sense—as the flamelet separation distance, dSFL, 410 from the inner surface of the substrate 401 over the pore 312A and the apex of the combustion interface 404. In practice, flamelet separation distances for premixtures of natural gas and air are between zero (0) inches (surface combustion) and approximately 1.75 inches (suspended flame combustion, SF), although the distance will vary (stochastically and as an average distance observed over relatively long time periods) in practice. In some embodiments, the flamelets may overlap depending on the distance between pores, flow rate, and other conditions.
Under certain operating conditions, which may be referred to herein as the “suspended flame front” state, particularly when the premix fuel-air mixture flow velocity is high, the flamelets may detach from the inner surface of the burner substrate, as illustrated in the embodiment shown in
The conditions or states described herein with
These principles have been verified using an experimental test apparatus. Based on experimental data, Table 1 shows typical geometry and operating conditions that will exhibit suspended flame (SF) combustion in a burner using a semi-cone substrate geometry.
Porosity of the burner combustion substrate can be achieved by a number of constructive means, so long as they equivalently achieve and maintain the semi-conical shape and porosity characteristics required by a specific set of design parameters. Perforations in a solid substrate, including perforations in a metal sheet, are specifically mentioned.
The pore 2-dimensional and 3-dimensional structure, together with the distribution of pores in the burner combustion substrate, are designed in concert to achieve an operational flame structure required to meet the specifications a particular application.
The shapes and distributions of pores can be mixed to produce desirable heat production, pressure drop across the cross-section of the substrate and combustion stability properties as illustrated by the embodiment shown in
There are several important advantages to the arrangements in the disclosed embodiments. Depending upon the specific parametric choices for design parameters (including pore size and density, the fuel-air flow velocity and combustion substrate geometry)—while the burner can be operated in a range of combustion modes from surface combustion to volume combustion, the geometry is suitable for stable suspended flame (SF) combustion applications. This is desirable since the resulting separation distance between the flamelet or flame front and the combustion substrate in SFF combustion: (a) relaxes the material demands on the substrate in the presence of high temperatures during operation, eliminating the need for insulation of the substrate; and, (b) reduces the risk of substrate material failure or contamination of the pores by combustion byproducts.
Semi-cone combustion substrate geometry also promotes uniformity of the combustion process over the entire interior surface of the substrate.
Moreover, the burner combustion substrate defines a combustion volume delineated by the interior surface of the substrate that is optimized for improved and complete combustion of the premix fuel-air mixture, homogeneous distribution of the flame front on the interior surface of the porous substrate (equivalently, diffuser), and uniformity of the resulting flow field of combustion products.
The desirable flow field and temperature distribution properties persist for a range of semi-cone burner substrate geometries.
Even when the fuel-air mass flow rate is increased into the volume combustion regime, the semi-cone geometry alters the cavity flame structure so that the power density is increased, and a smaller flame is required to achieve a prescribed level of heat generation. Because the fuel-air mass flow is equally distributed over the surface of the porous combustion substrate, when driven into a volume combustion regime the entire length of the flame is equally impinged by the premix fuel. Hence, the structure of the body of the flame—normally divided into cool and hot regions—is altered to produce a hotter, more efficient combustion process. As a result, the same heat generation capacity is achieved by a smaller flame size with higher power density, and more complete combustion can occur in a smaller burner cavity.
Moreover, semi-cone combustion substrate geometry promotes homogeneity and uniformity of the flow field exiting the burner casing. This is particularly important in apparatus comprising heat-generating burners for fluid heating applications utilizing, for example, shell-and-tube heat exchangers.
Towards this end, in certain embodiments a composite semi-cone combustion substrate is used when optimization of the combustion flow field over the height, H, requires a change in the local generator angle (alternatively, range of generator angles in the case of a general semi-cone). Otherwise, when optimization of the combustion flow field can be achieved using a single semi-cone, a semi-cone, truncated cone or frustum shape may be used.
Uniform combustion over the surface of the substrate and uniformity of the flow field exiting the burner contributes to an increase in thermodynamic efficiency of the combustion system. A result of the uniform flow field and temperature distribution of combustion products generated by the premix burner comprising a composite semi-cone combustion substrate is an increase in overall system thermodynamic efficiency. This is a particularly important result for applications like fluid heating where energy efficiency and reduction of environmentally hazardous byproducts are key.
The various components of the premix fuel burner combustion system can each independently comprise any suitable material. Use of a metal is specifically mentioned. Representative metals include iron, aluminum, magnesium, titanium, nickel, cobalt, zinc, silver, copper, and an alloy comprising at least one of the foregoing. Representative metals include carbon steel, mild steel, cast iron, wrought iron, a stainless steel such as a 300 series stainless steel or a 400 series stainless steel, e.g., 304, 316, or 439 stainless steel, Monel, Inconel, bronze, and brass. Specifically mentioned is an embodiment in which the premix fuel burner combustion system components each comprise steel, specifically stainless steel. The premix burner combustion system may comprise a burner head, a combustion substrate, a baffle, a furnace wall that can each independently comprise any suitable material. Use of a steel, such as mild steel or stainless steel this mentioned. While not wanting to be bound by theory, it is understood that use of stainless steel in the dynamic components can help to keep the components below their respective fatigue limits, potentially eliminating fatigue failure as a failure mechanism, and promote efficient heat exchange.
A flat substrate (annular substrate with Dd and Dp prescribed) is the geometrical limit of a sequence of semi-cone combustion substrate configurations within the inventive species sharing a common furnace diameter. A family of semi-cone substrates sharing a common furnace diameter (e.g., Dd in
The design of the perforation pattern, dimensions and distributions are separate inventive concepts from the semi-cone substrate structure, and the resulting flow and temperature properties can be exploited in various distinct configurations. The desirable flow, temperature and combustion properties such a pore pattern can be expected to have similarities in two different semi-cone geometries, but will also have distinct properties that may be exploited by one skilled in the art of burner design.
The inventors have unexpectedly discovered that embodiments of fuel oil combustion systems based on isenthalpic expansion-enabled (flash) combustion can alleviate many of the disadvantages of known oil fuel-based systems described above and, moreover, can exploit advantages of the cavity geometries described above for the premix gaseous fuel combustion systems when used in a dual fuel configuration.
For example,
The operating temperature and pressure for isenthalpic expansion enabled burner combustion depends upon the oil components and properties in the fuel. However, in practical applications using common fuel oils, a preheating temperature between 350 degrees Fahrenheit and 900 degrees Fahrenheit is specifically mentioned. Also, pre-pressurization of the fuel oil between 200 PSI and 500 PSI is specifically mentioned. Combustion burner operation enabled by isenthalpic expansion using fuel oil at approximately 700 degrees Fahrenheit and a pressure of 300 PSI is also specifically mentioned. Other values for temperature and pressure may be used if desired, provided it results in the desired isenthalpic expansion discussed herein.
An isenthalpic transition occurs when—for a fixed enthalpy—a pressure change causes a change of state of the mixture. In
The inventors have surprisingly discovered that these thermodynamics state changes can be utilized to mitigate or eliminate the disadvantages inherent in an oil jet burner apparatus. The principle is illustrated in
A first feature of the present disclosure is that the inventors have surprisingly discovered that isenthalpic expansion of fuel oil can be exploited in fluid heating system combustion systems.
When burning oil, liquid fuel contained in a storage location is conveyed by an oil pump 560 to a preheater; for example, a preburner 542 comprising a blower 540 and heat exchanger 544 (oil heater). In an alternative embodiment, the preheater may comprise an electric element. The oil pump 560 and heat exchanger 544 (alternatively, electric element or an equivalent) increase the oil pressure and enthalpy (total heat) by heating the oil (e.g., by a secondary combustion process, or electric heating element). The hot, pressurized oil is conveyed through a conduit 545 into the fluid system burner combustion cavity 562 within the furnace 548 where it is dispersed by an oil nozzle 554. As the hot oil enters the enlarged combustion volume 562 through the nozzle 554, it experiences an isenthalpic pressure drop, and the oil mixture changes state to a composition of liquid and gas. The oil dispersed by the nozzle 554 is mixed with oxygen (air) forced into the burner by a blower 552 through an inlet conduit 550. An igniter 564 is used to combust the oil vapor and the resulting ambient heat released causes combustion of the remaining liquid fraction.
Thus, although not wanting to be bound by theory, the inventors have discovered that the benefits of isenthalphic expansion can be realized by apparatuses comprising a means 542 for preheating and pressurizing the liquid fuel, a means 554 for dispersing the heated fuel under pressure into a combustion volume 562, and a means for delivering oxygen (typically, ambient air) into the combustion volume 551. The apparatus may further comprise a means 564 for igniting the resulting mixed fuel vapor-gas and air when operated from a cold condition.
The inventors have also surprisingly discovered that a second feature pertaining to embodiments of the present disclosure is that fuel must be controlled throughout the process to achieve the correct thermodynamic condition. Maintaining the correct fuel thermodynamic state requires, at distinct stages, matching the system temperature and pressure requirements to the material and chemical properties of the fuel using the geometry of the apparatus, and the combustion stoichiometry and dynamics.
For example, in the system depicted in
Moreover, the high pressure of the liquid fuel through the nozzle promotes the generation of a spray of fine droplets from the dispersion nozzle. Because the liquid fuel is preheated, once the fuel is dispersed into the larger combustion volume 562 by the nozzle, the droplets are already carrying the heat required for vaporization. Hence, the fuel is combustible immediately after the pressure drop in the presence of oxygen (air) delivered into the combustion volume by the blower 551, since the products of isenthalphic expansion are injected into a region that already includes a high volume of gas. This process can be referred to as instantaneous atomization-vaporization.
A third feature of the present disclosure is that the inventors have surprisingly discovered that embodiments comprising elements of both inward-firing gas burner geometries and isenthalpic oil burner components may be integrated to provide dual fuel combustion systems that also alleviates many of the disadvantages described above for gas burners and oil jet burners. Referring again to
A fourth feature of the present disclosure is that the inventors have surprisingly discovered that embodiments utilizing isenthalpic expansion of a preheated, pressurized fuel oil can produce short flame envelopes compatible with highly compact combustion systems.
The inventors have unexpectedly discovered that isenthalpic expansion of heated oil can be used to substantially shorten the flame length of an oil combustion system, by nearly eliminating the first and second flame regions illustrated in
Dimensions of the combustion substrate depend upon the burner power, capacity, performance and size requirements of a specific application. Proximal diameters (Dp) between 1 inch and 59 inches is specifically mentioned. Distal diameters (Dd) between 2 inches and 60 inches is specifically mentioned. Substrate height (H) between 1 inch and 60 inches is specifically mentioned.
The semi-cone sections of the burner combustion substrate angle, α, may have any suitable generator angle between 1 degree, 2 degrees, 3 degrees, 4 degrees, 5 degrees, 10 degrees to 11 degrees, 12 degrees, 13 degrees, 14 degrees, 15 degrees, 16 degrees, 17 degrees, 18 degrees, 19 degrees, 20 degrees, 21 degrees, 22 degrees, 23 degrees, 24 degrees, 25 degrees, 26 degrees, 27 degrees, 28 degrees, 29 degrees, 30 degrees, 31 degrees, 32 degrees, 33 degrees, 34 degrees, 35 degrees, 36 degrees, 37 degrees, 38 degrees, 39 degrees, 40 degrees, 50 degrees, 60 degrees, 70 degrees, 80 degrees, 85 degrees and 90 degrees wherein the foregoing upper and lower bounds can be independently combined. For the right circular semi-cone, right circular truncated cone, and the right circular frustum, the burner combustion substrate angles between 18 degrees and 35 degrees is specifically mentioned. For the right circular semi-cone, right circular truncated cone, and the right circular frustum, the burner combustion substrate angle of 25 degrees is also specifically mentioned. Notice that a burner combustion substrate angle of 90 degrees corresponds to a flat structure, a degenerate semi-cone that is the limit of a family of semi-cones with circumference diameter, Dd. For the right circular semi-cone, right circular truncated cone, and the right circular frustum, the burner combustion substrate angle of 90 degrees is specifically mentioned.
When operated to burn a premix gas and air composition, the burner combustion substrate is porous to the flow of premix fuel-air mixtures predominately in a vapor state. Substrate pores 626 are distributed over the area of the burner combustion substrate to support a flame front 628 near the interior surface. (The pore 626 size in a local area 624 are exaggerated in the diagram for clarity and are not meant to be to scale.) The combustion process may be monitored by a sensor 604 which can detect if the flame is extinguished.
In the embodiment shown a premix(ed) fuel-air mixture 648 enters the inlet 632 of the burner and flows around and through the burner combustion substrate inward toward the axis 610. The fuel-air mixture ratio is composed so that the premix fuel is ignited near the interior surface to form a flame 628 suspended over the interior surface of the burner combustion substrate.
When operated to burn a fuel oil using isenthalpic expansion, the burner combustion substrate defines (part of the) cavity for the combustion of the oil mixture as well as the pathway for air required in the combustion process. Preheated fuel oil is conveyed under pressure through an oil conduit 638 and into a dispersion nozzle 640. The nozzle 640 disperses the oil under pressure at a heightened enthalpy state into the combustion cavity delineated by the porous substrate 630 and the inner wall of the furnace 618. Virtually immediately (for all practical purposes) after the oil composition is dispersed into the combustion volume by the nozzle 640, a significant mass fraction vaporizes and is mixed with air entering through the inlet conduit 632, through the space between the furnace wall 618 and the porous substrate 630, through the porous substrate 630 and into the combustion cavity. The oil vapor and air mixture is ignited either by the elevated temperature or a (e.g., spark) igniter 636 to achieve a sustained combustion process.
In a boiler application comprising a shell and tube heat exchanger, the combustion products (e.g., hot gases, particulate byproducts)—created either from the combustion of the premix gas-air mixture or by the isenthalpic oil expansion process—flows towards the tubesheet 616 where they pass through the openings 608 of the heat exchanger tubes 614. Heat generated by the combustion process is transferred across the walls of the heat exchanger tubes 614 to production fluid occupying the space between the outer surfaces of the furnace 620 and heat exchanger tubes 614 and the inner surface of the pressure vessel 618, sealed at one end by the boiler top head 606.
In the embodiment shown of an integrated dual-fuel combustion system in
A fifth feature of the present disclosure is that the inventors have surprisingly discovered that embodiments utilizing isenthalpic expansion of a preheated, pressurized fuel oil are amenable to standard burner temperature control methods common to fluid heating systems. That is, despite the fact that the incorporation of instantaneous atomization-vaporization by isenthalpic expansion has significantly altered the combustion dynamics and shortened the flame structure, methods for controlling and modulating the burner output characteristics, including control of the fuel spray at the nozzle, can be used. The dispersion nozzle is responsible for creating an atomized spray of from the liquid stream of high-pressure, enhanced-enthalpy fuel in a geometrical pattern that promotes mixing and complete combustion. For example, without being limited to specific nozzle configurations, properties, characteristics or properties, Fulton Oil Nozzle Dual Fuel Burner (FT-0400-C-FT-1400-C) provides one example of an oil dispersion nozzle applicable to the present disclosure.
A more sophisticated method of controlling the burner output and performance is illustrated in
The fuel nozzle head pressure and flow rate is modulated by a control valve 697 disposed on the outlet conduit 693. An actuator 691 receives a control signal 693, C, which acts to vary the fuel flow pressure in the outlet conduit 693. Increasing the return flow pressure in the return conduit 693 acts to increase the nozzle fuel pressure and the causes more fuel to be atomized and ejected by the dispersion nozzle 698 into the combustion volume, thereby raising the burner temperature.
A sixth feature of the present disclosure is that the inventors have surprisingly discovered that the combustion volume geometry of embodiments comprising dual-fuel premix gas and isenthalpic expansion of a preheated, pressurized fuel oil elements can be optimized to concurrently achieve high performance of both the premix and oil operating modes.
When operated as an oil burner, the semicone combustion substrate defines a combustion volume (equivalently, combustion cavity) for the combustion of liquid fuel based on isenthalpic expansion combustion and instantaneous atomization-vaporization. Preheated liquid fuel under pressure is delivered to the burner through an oil conduit 638 to the dispersion nozzle 640. The dispersion nozzle is disposed on the burner top head 602 at an offset distance, h. Liquid fuel is dispersed by the nozzle 640 in a spray pattern; a spray pattern in the shape of a cone with a dispersion angle 702, Θ, is specifically mentioned. When dispersed by the nozzle at a particular dispersion angle 702, Θ, the atomized fuel spray expands in a conical shape concentrated between an inner 706 and outer 704 dimension. Once the atomized liquid spray enters the combustion volume in this geometry, it vaporizes very rapidly. Air enters the burner system through the inlet port 632, flows 648B in the space between the outside surface of the combustion substrate 630 and the inner wall 618 of the furnace, passes inward through the pores 626 in the combustion substrate 630, and enters the combustion volume to be mixed with the fuel spray and ignited, either by the autoignition, gas pilot or by a (e.g., spark) igniter 636.
The envelope of the burner flame 708 that results from igniting the mix vaporized fuel and air has a length 708, Lsf, and is contained partially or entirely within the cavity defined by the combustion substrate. For this embodiment as described, a number of critical parameters define the characteristics of the combustion volume, including the combustion substrate proximal edge diameter, Dp, combustion substrate distal edge diameter, Dd, the substrate cone angle, α, the surface area of the combustion substrate, A, the nozzle dispersion angle, Θ, and the nozzle offset distance, h. Several important considerations affect choices for these parameters, depending upon the size, capacity and performance requirements of the burner system, including (but not limited to):
Substrate distal edge diameter, Dd: Typically, equal to the inside diameter of the inner wall of the furnace 618;
Substrate cone angle, α: Small substrate cone angles contribute to smaller deviations of the resulting flow stream of hot combustion gases and byproducts from the burner axis, since this flow stream is driven (in part) by the air stream through the porous combustion substrate. However, larger substrate cone angles promote mixing of fuel vapor and air within the combustion volume.
Substrate proximal edge diameter, Dp: Determined by the distal edge diameter, Dd, the substrate cone angle, α, and the substrate cone height, H.
Dispersion nozzle angle, Θ: Small dispersion angles prevent impingement of the atomized oil spray on the combustion substrate 630, but results in poorer air-fuel mixing and, hence, less complete combustion. Conversely large dispersion angle promotes mixing and stable combustion but can risk impingement of oil on the inner surface of the combustion substrate 630 leading to fouling or the substrate pores.
Dispersion nozzle offset, h: An important parameter used in conjunction with the dispersion angle, Θ, to prescribe the oil spray geometry. Larger nozzle offset better utilize air flow behind the nozzle but exposes the nozzle to higher flame temperatures. Smaller offset displacements risk oil impingement on the combustion substrate.
The tradeoffs described above between the nozzle dispersion angle, Θ, and the substrate cone angle, α, is illustrated in
Similarly, useful values for the substrate cone angle, α, are limited to the range of acceptable values discussed herein for a desired burner design, as shown by vertical dashed lines in
A seventh feature of the present disclosure is that the inventors have surprisingly discovered that the use of tangential or oblique inlet ports for air or premix gas-air mixtures in embodiments comprising dual-fuel premix gas and isenthalpic expansion of a preheated, pressurized fuel oil elements can obviate the requirement for baffles to guide and direct the incoming flow stream.
In the embodiment shown in
An eighth feature of the present disclosure is that the inventors have surprisingly discovered that embodiments comprising dual-fuel premix gas and isenthalpic expansion of a preheated, pressurized fuel oil elements, production of nitrogen oxide (NOx) byproducts can be reduced. The primary cause of NOx emissions are derived from nitrogen in the fuels used or from nitrogen in the combustion air (thermal NOx). For natural gas-fired and No. 2 oil-fired boilers, thermal NOx represents the majority of NOx produced from commercial and industrial boilers. Thermal NOx emissions increase with increasing residence times of combustion products at high temperatures and are affected by oxygen availability in the boiler combustion zone. Embodiments of the present disclosure reduce the dwell times due to the compactness of the burner and smooth, laminar flow through the combustion system, and the efficient control of oxygen present in the combustion volume.
An ninth feature of the present disclosure is that the inventors have surprisingly discovered that embodiments comprising dual-fuel premix gas and isenthalpic expansion of a preheated, pressurized fuel oil elements admit the use of different shapes for the combustion volume and still can achieve compact, thermally efficient design objectives. In what follows is described embodiments comprising combustion volumes wherein the substrate that delineates all or part of the combustion volume is defined by specific choices of composite semicone (including cylindrical components) or cylindrical elements.
Air or premix gas-air composition 648, depending upon the operating mode, enters the inlet port 632 and is directed 1120 through the space between the inner furnace wall 618, the burner top head 602, and the outer surfaces of the first 1100 and second 1110 substrate semicones.
Air or premix gas-air composition 648, depending upon the operating mode, enters the inlet port 632 and is directed 1320 through the space between the inner furnace wall 618, the burner top head 602, and the outer surfaces of the first 1300 and second 1310 substrate cylindrical surfaces.
Air or premix gas-air composition 648, depending upon the operating mode, enters the inlet port 632 and is directed 1520 through the space between the inner furnace wall 618, the burner top head 602, and the outer surface of the substrate cylindrical surface 1500.
A tenth feature of the present disclosure is that the geometry of the premix fuel-air combustion substrate that partially forms the boundaries of the combustion cavity, and the geometry of the fuel oil dispersion configuration can be optimized to achieve desirable performance objectives for the system operated in either mode.
When operated as a liquid oil fuel burner, oil contained in a storage location is conveyed by an oil pump 560 to a preheater; for example, a preburner 542 comprising a blower 540 and heat exchanger 544 (oil heater). In an alternative embodiment, the preheater may comprise an electric element. The oil pump 560 and heat exchanger 544 (alternatively, electric element or an equivalent) increase the oil pressure and enthalpy (total heat) by heating the oil (e.g., by a secondary combustion process, or electric heating element). The hot, pressurized oil is conveyed through a conduit 545 to the fluid system through a conduit where it is dispersed by an oil nozzle 640. As the hot oil enters the enlarged combustion volume 640 through the nozzle 640, it experiences an isenthalpic pressure drop, and the oil mixture changes state to a composition of liquid and gas. The oil dispersed by the nozzle 640 is mixed with oxygen (air) forced into the burner by a blower through the inlet 632 and passing from the region 1706 behind the combustion substrate 630, through the substrate pores, shown here as a pattern of slots 426 and holes 428. An igniter 636, which may or may not be the same as for ignition for premix gas operation as it is shown here, is used to combust the oil vapor and the resulting ambient heat released causes combustion of the remaining liquid fraction.
Note that in
Vertical flow is illustrated in
The oil nozzle(s)—whether in a configuration utilizing a single nozzle or a distribution pattern of a plurality of nozzles—may have a dispersion angle parallel to the burner axis (as shown above), or at an angle relative to the burner longitudinal axis.
Further disclosed is a dual fuel burner comprising: a burner casing with an inlet conduit for a premix fuel-air mixture to be disposed in the burner casing; a porous burner combustion substrate disposed in the burner casing wherein: For premix gas-air operation, a premix fuel-air mixture enters the inlet conduit on an outside (exterior) of the burner combustion substrate; a premix fuel-air mixture is disposed under pressure through the burner inlet to an outside of the porous burner combustion substrate; passes through pores in the burner combustion substrate to an interior of the substrate; the fuel-air mixture is ignited in the interior of the burner combustion substrate; combustion gases and products flow from the interior of the burner combustion substrate through an outlet in the burner casing. For liquid fuel operation, a pressurized and preheated liquid fuel is disposed to one or a plurality of dispersion nozzle(s), mixed with air passing through the substrate and ignited or autoignited.
Further disclosed is the dual fuel burner of Embodiment A, wherein the porous burner combustion substrate has the shape of a cylinder.
Further disclosed is the dual fuel burner of Embodiment A, wherein the porous burner combustion substrate has the shape of a composite semi-cone.
Further disclosed is the dual fuel burner of Embodiment A, wherein the porous burner combustion substrate has the shape of a semi-cone.
Further disclosed is the dual fuel burner of Embodiment A, wherein the porous burner combustion substrate has the shape of a truncated cone.
Further disclosed is the dual fuel burner of Embodiment A, wherein the porous burner combustion substrate has the shape of a circular truncated cone.
Further disclosed is the dual fuel burner of Embodiment A, wherein the porous burner combustion substrate has the shape of a right circular truncated cone.
Further disclosed is the dual fuel burner of Embodiment A, wherein the porous burner combustion substrate has the shape of a frustum.
Further disclosed is the dual fuel burner of Embodiment A, wherein the porous burner combustion substrate has the shape of a circular frustum.
Further disclosed is the dual fuel burner of Embodiment A, wherein the porous burner combustion substrate has the shape of a right circular frustum.
Further disclosed is the dual fuel burner of Embodiment A, wherein the porous burner combustion substrate has the shape of a semicone with zero height; equivalently, semicone angel equal to 90 degrees; equivalently, a plate, surface, disk, annulus.
Further disclosed is the dual fuel burner of any of Embodiments A to L, further comprising a plurality of burner casing inlets disposed on the burner casing.
Further disclosed is the dual fuel burner of any of Embodiments A to L, further comprising a plurality of oil dispersion nozzles.
Further disclosed is the dual fuel burner of any of Embodiments A to M, further comprising one or a plurality of oil dispersion nozzles with dispersion oriented at a vertical angle between zero and 180 degrees relative to the combustion burner centerline.
Further disclosed is the dual fuel burner of any of Embodiments A to N, further comprising one or a plurality of oil dispersion nozzles with dispersion oriented rotated at a horizontal angle between zero and 360 degrees relative to the combustion burner centerline.
Further disclosed is a hydronic fluid heating system (equivalently, a “hydronic boiler”) comprising a dual fuel combustion system of any of Embodiments A to O or elsewhere disclosed in this specification.
Further disclosed is a steam fluid heating system (equivalently, a “steam boiler”) comprising a dual fuel combustion system of any of Embodiments A to K or elsewhere disclosed in this specification.
Further disclosed is a thermal fluid heating system (equivalently, a “thermal fluid boiler”) comprising a dual fuel combustion system of any of Embodiments A to K or elsewhere disclosed in this specification.
Further disclosed is a packaged burner comprising a dual fuel combustion system of any of Embodiments A to K or elsewhere disclosed in this specification.
The disclosed system can alternately comprise, consist of, or consist essentially of, any appropriate components herein disclosed. The disclosed system can additionally be substantially free of any components or materials used in the prior art that are not necessary to the achievement of the function and/or objectives of the present disclosure.
The terms “a” and “an” do not denote a limitation of quantity, but rather denote the presence of at least one of the referenced item. The term “or” means “and/or” unless clearly indicated otherwise by context. Reference throughout the specification to “an embodiment”, “another embodiment”, “some embodiments”, and so forth, means that a particular element (e.g., feature, structure, step, or characteristic) described in connection with the embodiment is included in at least one embodiment described herein, and may or may not be present in other embodiments. In addition, it is to be understood that the described elements may be combined in any suitable manner in the various embodiments. “Optional” or “optionally” means that the subsequently described event or circumstance may or may not occur, and that the description includes instances where the event occurs and instances where it does not. The terms “first,” “second,” and the like, “primary,” “secondary,” and the like, as used herein do not denote any order, quantity, or importance, but rather are used to distinguish one element from another. The terms “front”, “back”, “bottom”, and/or “top” are used herein, unless otherwise noted, merely for convenience of description, and are not limited to any one position or spatial orientation.
The endpoints of all ranges directed to the same component or property are inclusive of the endpoints, are independently combinable, and include all intermediate points. For example, ranges of “up to 25 N/m, or more specifically 5 to 20 N/m” are inclusive of the endpoints and all intermediate values of the ranges of “5 to 25 N/m,” such as 10 to 23 N/m.
Unless defined otherwise, technical and scientific terms used herein have the same meaning as is commonly understood by one of skill in the art to which this invention belongs.
All cited patents, patent applications, and other references are incorporated herein by reference in their entirety. However, if a term in the present application contradicts or conflicts with a term in the incorporated reference, the term from the present application takes precedence over the conflicting term from the incorporated reference.
This application claims priority to U.S. provisional patent application Ser. No. 62/657,062, filed on Apr. 13, 2018; and is a Continuation-in-part of U.S. patent application Ser. No. 16/285,119, filed Feb. 25, 2019, which claims priority to U.S. provisional patent application Ser. No. 62/634,476, filed on Feb. 23, 2018, and which claims priority to U.S. provisional patent application Ser. No. 62/634,520, filed on Feb. 23, 2018; and is a Continuation-in-part of International Application PCT/US2019/019441, filed Feb. 25, 2019, which claims priority to U.S. provisional patent application Ser. No. 62/634,520, filed on Feb. 23, 2018, the entire contents of each above are incorporated herein by reference in their entirety to the extent permitted by applicable law.
Number | Date | Country | |
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62657062 | Apr 2018 | US | |
62634476 | Feb 2018 | US | |
62634520 | Feb 2018 | US | |
62634520 | Feb 2018 | US |
Number | Date | Country | |
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Parent | 16285119 | Feb 2019 | US |
Child | 16439873 | US | |
Parent | PCT/US2019/019441 | Feb 2019 | US |
Child | 16285119 | US |