Patent Application
20130344379
The present application is a continuation of International Application No. PCT/KR2012/004768 filed on Jun. 15, 2012, which claims priority to Korean Patent Application No. 10-2011-0059255 filed in the Republic of Korea on Jun. 17, 2011, Korean Patent Application No. 10-2011-0093615 filed in the Republic of Korea on Sep. 16, 2011, and Korean Patent Application No. 10-2012-0064368 filed in the Republic of Korea on Jun. 15, 2012, the disclosures of which are incorporated herein by reference.
The present invention relates to a secondary battery technology, and more particularly, to a component for a secondary battery which improves the safety of a secondary battery and a method of manufacturing the component, and a secondary battery manufactured by using the component.
With the increase in the use of portable electronic products such as video cameras, mobile phones, portable PCs, or the like, a secondary battery is commonly used as a main power source, and thus the importance of the secondary battery is growing.
Unlike a primary battery incapable of recharging, extensive research is undertaken regarding a secondary battery capable of charging and discharging so that they may be used in digital cameras, cellular phones, laptop computers, power tools, electric bicycles, electric vehicles, hybrid vehicles, large-capacity power storage apparatuses, or the like that are fast developing in the high-tech industry.
Particularly, since a lithium secondary battery has a higher energy density per unit weight and is capable of charging quickly compared to other secondary batteries such as lead accumulators, NiCd batteries, NiMH batteries, Li-Zinc batteries, or the like, the use of a lithium secondary battery is increasing.
A lithium secondary battery has an operating voltage of 3.6 V or more and used as a power source of portable electric apparatuses, or a plurality of lithium secondary batteries is connected in series or in parallel to be used in high-power electric vehicles, hybrid vehicles, power tools, electric bicycles, power storage apparatuses, UPS, etc.
Also, since a lithium secondary battery has an operating voltage three times higher than those of NiCd batteries or NiMH batteries and has excellent energy density characteristics per unit weight, the use of a lithium secondary battery is widely expanding.
Depending on the type of an electrolyte, a lithium secondary battery is categorized into a lithium ion battery using a liquid electrolyte and a lithium ion polymer battery using a polymer solid electrolyte. The lithium ion polymer battery is also divided into two types of batteries depending on the type of the polymer solid electrolyte: an all-solid lithium ion polymer battery containing no electrolyte solution and a lithium ion polymer battery containing an electrolyte solution and using a gel type polymer electrolyte.
Generally, a lithium ion battery using a liquid electrolyte is received in a cylindrical or prismatic metal can-shaped container and hermetically sealed for use. However, since a can-typed secondary battery using a metal can-shaped container is fixed in the shape thereof, electronic products having the can type secondary battery as a power source is limited in design, and has difficulty reducing its volume. Accordingly, a pouch type lithium secondary battery manufactured by receiving an electrode assembly and an electrolyte in a pouch packing made of a film, followed by sealing has been developed and in use.
However, a potential for explosion hazard may exist when a lithium secondary battery overheats, so ensuring the safety of a secondary battery is essential. The overheating of a lithium secondary battery is caused by various factors. One of the factors is the presence of an over-current in a lithium secondary battery. That is, if an over-current flows through a lithium secondary battery, heat is generated by Joule heating, and thus an internal temperature of the battery is quickly increased. Such an increase in temperature causes decomposition reaction of an electrolyte which brings about thermal running, causing the battery to inevitably explode. The over-current occurs when a sharp metal object penetrates a lithium secondary battery, or if an insulator between a cathode plate and an anode plate is destroyed by contraction of a separator being interposed between the cathode and anode plates, or if a rush current is applied to the battery due to an abnormal charge circuit or a load connected to the external.
In order to protect a lithium secondary battery from abnormalities such as an over-current, the battery is generally coupled to a protection circuit before use, and the protection circuit includes a fuse element which irreversibly disconnects a line where a charge or discharge current flows.
As shown in
The fuse element 10 is installed in a main line connected to the outermost terminal of a cell assembly 20. The main line is a wire in which a charge current or discharge current flows.
The fuse element 10 has three terminals, among these, two terminals are in contact with the main line in which a charge or discharge current flows, while the remaining one terminal is in contact with the switch 40. Also, the fuse element 10 includes a fuse 11 serially connected with the main line and melted at a predetermined temperature and a resistor 12 which applies heat to the fuse 11.
The microcontroller 30 monitors whether an over-current occurs or not by periodically detecting the voltage of both ends of the sense resistor 20, and when the occurrence of an over-current is determined, the microcontroller 30 turns on the switch 40. Then, the current which flows in the main line is bypassed to the fuse element 10 and applied to the resistor 12. Thereby, Joule heat generated from the resistor 12 is conducted to the fuse 11 to increase a temperature of the fuse 11, and when the temperature of the fuse 11 reaches the melting temperature, the fuse 11 melts, and thus the main line is irreversibly disconnected. When the main line is disconnected, an over-current no ° longer flows, thereby overcoming the problems associated with the over-current.
However, there are many problems in the conventional technology described above. That is, if there is a problem with the microcontroller 30, the switch 40 may not turn on even when an over-current occurs. In this case, since a current does not flow into the resistor 12 of the fuse element 10, there is a problem in that the fuse element 10 will not operate. In addition, a space for disposing the fuse element 10 is separately required in the protection circuit, and a program algorithm for controlling the operation of the fuse element 10 has to be loaded in the microcontroller 30. As a result, the space efficiency of the protection circuit deteriorates and the load of the microcontroller 30 increases.
The present invention is designed to solve the problems of the prior art, and therefore it is an object of the present invention to provide a new type component for a secondary battery to implement a function which manually interrupts an over-current in a secondary battery, separately from the active over-current interrupting function of a protection circuit, and a method of manufacturing the component.
It is another object of the present invention to provide a component for a secondary battery, which may manually interrupt an over-current with a minimum structural change while maintaining an overall shape identical to that of a conventional component, and a method of manufacturing the component.
It is still another object of the present invention to provide a secondary battery and a multi-battery system manufactured by using the component for a secondary battery.
However, the present invention is not limited to the technical problems described above, and those skilled in the art may understand other technical problems from the following description.
While searching for a way to improve the safety of a lithium secondary battery, the inventors of the present invention found out that when an electrode lead made of metal and having a plate shape was broken into a first metal plate and a second metal plate and these plates were connected by using a plane shaped lead-free soldering material having a melting point of 150° C. to 300° C., safety problems associated with an over-current may be overcome. The inventors of the present invention also confirmed that the electrode lead having the structure described above may be applied to all types of secondary batteries as well as be widely used as a component capable of replacing various kinds of secondary battery components positioned at a current flow path, before completing the present invention.
In order to achieve the above-mentioned objects, in accordance with one aspect of the present invention, there is provided a component for a secondary battery comprising a first metal plate and a second metal plate connected by using a lead-free soldering bridge having a melting point of 150° C. to 300° C. and containing tin (Sn) and copper (Cu) as a main ingredient thereof.
According to an embodiment of the present invention, the first and second metal plates are positioned on substantially the same plane surface, and the lead-free soldering bridge forms a bridge between the first and second metal plates on any one surface or both surfaces of the first and second metal plates.
A portion in which the first and second metal plates are connected to each other with the lead-free soldering bridge is called a melting and separating portion in terms of its function.
Preferably, a minute crack (a gap) is presented between the first and second metal plates. The smaller the width of the gap, the more favorable, so that it is preferably, 1 mm or less, more preferably, 0.5 mm or less, most preferably, 0.3 mm or less, and still most preferably, 0.1 mm or less.
Preferably, at the center of the melting and separating portion, the gap has any one pattern selected from a straight pattern, a zigzag pattern, a saw-toothed pattern, a wave pattern, and a combination thereof.
Preferably, the lead-free soldering bridge forms a bridge between the first and second metal plates through a first coupling portion and a second coupling portion which couple with the first metal plate and the second metal plate, respectively. The first and second coupling portions may be positioned in the same line or different lines depending on the shape of the gap. Preferably, the first and second coupling portions are formed by means of line welding using laser. Alternatively, the first and second coupling portions are formed by means of ultrasound welding, resistance welding, arc welding, or the like.
Preferably, the line welding is performed on the upper surfaces of the first and second metal plates, corresponding to the points where the first and second coupling portions are formed. Therefore, a line welding pattern is made on the surfaces of the first and second metal plates neighboring the gap.
According to another embodiment of the present invention, the first and second metal plates are positioned on substantially the same plane surface, and the lead-free soldering bridge is directly interposed between facing surfaces where the first and second metal plates face each other, which forms a bridge therebetween.
For example, the facing surfaces of the first and second metal plates have tapered slopes toward the lead-free soldering bridge. For another example, the facing surfaces of the first and second metal plates have convex shapes toward the lead-free soldering bridge, and in this configuration, the center areas of the facing surfaces have flat surfaces facing each other in parallel and the periphery areas provided at the upper and lower ends of the center areas have tapered slopes toward opposing direction. For another example, the facing surfaces of the first and second metal plates have a recess structure.
Preferably, regardless of a shape of the facing surfaces, the lead-free soldering bridge and the facing surfaces of the first and second metal plates are coupled by means of laser welding. Alternatively, the lead-free soldering bridge and the facing surfaces of the first and second metal plates are coupled by means of ultrasound welding, resistance welding, arc welding, or the like.
According to another embodiment of the present invention, the first and second metal plates are positioned on substantially the same plane surface, and the lead-free soldering bridge forms a bridge between the first and second metal plates at the area formed by the encounter of first and second bending portions formed at the edges of the first and second metal plates facing each other. Preferably, the first and second bending portions have a bending structure which may be encountered in a plane symmetry or point symmetry.
According to another embodiment of the present invention, the lead-free soldering bridge forms a bridge between the first and second metal plates at the area formed by the edges of the first and second metal plates vertically disposing and overlapping.
According to another embodiment of the present invention, the lead-free soldering bridge forms a bridge between the first and second metal plates at the area formed by the encounter of grooves formed at the facing portions where the first and second metal plates face each other.
In the present invention, the content of tin used as a main ingredient of the lead-free soldering bridge may be 80 to 98 wt % and the content of copper used as an alloy ingredient, may be 2 to 20 wt %.
According to another embodiment of the present invention, the lead-free soldering bridge further comprises at least one additional metal selected from nickel, zinc and silver. The total content of the additional metal is adjusted preferably in the range of 0.01 to 10 wt %.
The component for a secondary battery described above further comprises an insulating tape for covering the melting and separating portion so as to cover the lead-free soldering bridge. Preferably, the insulating tape is comprised of any one group selected from polyolefin film, polypropylene film, acid modified polypropylene, and a combination thereof.
In order to achieve the object described above, in accordance with another aspect of the present invention, there is provided a secondary battery according to the present invention manufactured by using the aforementioned component for a secondary battery as an electrode lead thereof. Accordingly, for a secondary battery according to the present invention, a cathode lead, an anode lead, or both have the structure of the aforementioned component for a secondary battery.
The purpose of the present invention is also achieved by applying a structure of the component for a secondary battery to a connector connecting the adjacent terminals to each other in a multi-battery system having a plurality of secondary batteries connected to each other in series or in parallel.
In order to solve the problems described above, in accordance with still another aspect of the present invention, there is provided a method of manufacturing a component for a secondary battery according to the present invention comprising steps for facing a first metal plate and a second metal plate separated from each other by approaching and positioning on substantially the same plane surface to form a gap between the plates; providing a lead-free soldering bridge having a melting point of 150° C. to 300° C. and containing tin (Sn) and copper (Cu) at the facing portions of the first and second metal plates; and coupling one side of the lead-free soldering bridge with the first metal plate and the other side of the lead-free soldering bridge with the second metal plate.
The method of manufacturing a component for a secondary battery may further comprise a step of covering the lead-free soldering bridge, the gap, or both with an insulating tape.
The component for a secondary battery according to an aspect of the present invention has a structure in which a first metal plate and a second metal plate are minutely spaced from each other through a gap therebetween and connected by means of a lead-free soldering bridge melted at 150° C. to 300° C. Therefore, when an over-current flows through the component for a secondary battery, the temperature of the lead-free soldering bridge rapidly reaches to the melting point described above and the bridge melts to interrupt the flow of an over-current. Also, since the gap formed between the first and second metal plates has a small width, the resistance increase of the component generated by the lead-free soldering bridge is limited to an ignorable level, and substantial changes associated with the overall size and shape are not resulted.
According to another aspect of the present invention, when the component for a secondary battery is used as an electrode lead of a secondary battery, separately from a protection circuit, a secondary battery may irreversibly interrupt an over-current, thereby improving the safety of the secondary battery. In addition, when the component for a secondary battery is used as an electrode lead, no substantial change is made in the size and shape of the electrode lead, so that it is possible to graft an over-current interrupting function onto a secondary battery without a structural modification in design of a secondary battery.
According to another aspect of the present invention, it is advantageous in that the component for a secondary battery may be applied to various kinds of secondary batteries adopting an electrode lead having a plate shape therein.
According to another aspect of the present invention, if the component for a secondary battery is used as a connector used in a multi-battery system having a plurality of secondary battery therein, the connector may have the over-current interrupting function therein.
Other objects and aspects of the present invention will become apparent from the following descriptions of the embodiments with reference to the accompanying drawings in which:
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. Prior to the description, it should be understood that the terms used in the specification and the appended claims should not be construed as limited to general and dictionary meanings, but interpreted based on the meanings and concepts corresponding to technical aspects of the present invention on the basis of the principle that the inventor is allowed to define terms appropriately for the best explanation. Therefore, the description proposed herein is just a preferable example for the purpose of illustrations only, not intended to limit the scope of the disclosure, so it should be understood that other equivalents and modifications could be made thereto without departing from the spirit and scope of the disclosure.
Referring to
The gap 24 is a minute crack between the first metal plate 22 and the second metal plate 23. The gap 24 functions as a resistance component which allows most currents flowing through the component 20 to flow from the first metal plate 22 to the second metal plate 23 by means of the lead-free soldering bridge 21. Also, the width of the gap 24 directly associates with the variation of a current flow path through a lead-free soldering bridge 21, and the increase of the width of the gap 24 results in increasing the resistance of the component 20. Accordingly, the smaller the width of the gap 24, the more favorable, so that it is preferably 1 mm or less, more preferably 0.5 mm or less, most preferably 0.3 mm or less, still most preferably 0.1 mm or less.
The first metal plate 22 and the second metal plate 23 are substantially positioned on the surface of a XY plane and consist of a metal or alloy having an electrical resistance of 0.1 mΩ or less. For example, the first metal plate 22 and the second metal plate 23 may be made of a copper substrate, an aluminum substrate or a copper substrate coated with nickel. The first metal plate 22 and the second metal plate 23 are made of the same material, or different materials.
The lead-free soldering bridge 21 has a melting point of 150° C. to 300° C. lower than those of the first metal plate 22 and the second metal plate 23, contains tin (Sn) as a main ingredient and copper (Cu) as an alloy ingredient, and consists of eco-friendly materials, instead of lead (Pb) which is noxious on the environment and the human body.
The melting range of the lead-free soldering bridge 21 is set in consideration of an over-current level intended to interrupt. If a melting point is less than 150° C., the lead-free soldering bridge may melt despite a normal flow. For example, if the component 20 for a secondary battery is used in a secondary battery of electric vehicles, and a melting point is less than 150° C., the lead-free soldering bridge 21 may melt by a rapid charge or discharge current. Also, if a melting point is higher than 300° C., it is difficult to efficiently interrupt an over-current, thereby presenting no advantageous effects of using the component 20 for a secondary battery.
Among the compositions of the lead-free soldering bridge 21, tin affects the melting point and tensile strength characteristics of the bridge 21. In order for the lead-free soldering bridge 21 to have a melting point in the range of 150° C. to 300° C. and also have fine tensile strength characteristics, the content of tin is adjusted to 80 wt % or more, preferably in the range of 85 to 98 wt %. Copper functions to improve the electric conductivity of the component 20 for a secondary battery, so the content of copper is adjusted in the range of 2 to 20 wt %, preferably in the range of 4 to 15 wt %. The wt % which is used herein is a unit based on the total weight of the materials comprised in the lead-free soldering bridge 21 and has the same meaning below.
As mentioned above, by adjusting the contents of tin and copper in a range such as above, not only is the fine tensile strength of the lead-free soldering bridge 21 achieved but also the increase of resistance by the lead-free soldering bridge 21 may be restrained within a low level of a number of %.
In order to have even further improved properties, the lead-free soldering bridge 21 may include a metal having excellent electrical conductivity, such as nickel (Ni), silver (Ag), zinc (Zn) as an additional alloy ingredient, besides tin and copper. The content of the additional alloy ingredient is preferably 0.01 to 10 wt % based on the total material weight.
The lead-free soldering bridge 21 forms a bridge between the first metal plate 22 and the second metal plate 23 on one surface (i.e., lower surface) of the first metal plate 22 and the second metal plate 23.
Here, if the temperature of the lead-free soldering bridge 21 increases to 150° C. to 300° C., the bridge 21 melts into liquid, and the first metal plate 22 and the second metal plate 23 are broken and divided into two separate plates based on a gap 24.
Accordingly, hereinafter, the portion in which the first metal plate 22 and the second metal plate 23 are connected with each other by means of the lead-free soldering bridge 21 is named as a melting and separating portion A.
The melting and separating portion A includes a first coupling portion 25 and a second coupling portion 26. The first coupling portion 25 indicates an area where the lead-free soldering bridge 21 and the first metal plate 22 are coupled with each other, and the second coupling portion 26 indicates an area where the lead-free soldering bridge 21 and the second metal plate 23 are coupled with each other.
The first coupling portion 25 and the second coupling portion 26 are formed by line welding driven toward Y-axis. The first coupling portion 25 is formed at an interface between the first metal plate 22 and the lead-free soldering bridge 21, and the second coupling portion 26 is formed at an interface between the second metal plate 23 and the lead-free soldering bridge 21.
The line welding is performed preferably at the upper portion (see point B) of the first metal plate 22 and the second metal plate 23. Accordingly, line welding patterns are formed on the surfaces of the first metal plate 22 and the second metal plate 23 neighboring a gap 24. The line welding is preferably laser welding, but various welding technologies such as ultrasound welding, resistance welding, arc welding or the like may be applied thereto.
Meanwhile, in order to increase a welding strength, the number of line welding performed may also increase. In this case, coupling portions are additionally formed at the melting and separating portion A, which will be obvious in the art. Also, the first coupling portion 25 and the second coupling portion 26 have continuous or discontinuous line-patterns, but the present invention is not limited thereto.
The gap 24 may have a saw-toothed pattern as shown in
In addition, as shown in
Meanwhile, the gap 24 may have various patterns beside the patterns shown in
Referring to
Referring to
Referring to
Regarding the modified structure of
That is, first, one piece of a metal plate is prepared and a line-shaped groove, at which a lead-free soldering bridge 21 is formed, is formed on the upper surface of the metal plate.
The line-shaped groove may be formed by using any one technology selected from a physical or chemical etching technology, a mechanical cutting technology using a saw blade or the like, a local scratching technology using a high hardness knife such as a diamond, an etching technology using an electron beam, and a skiving technology.
After the line-shaped groove is formed, soldering materials for forming a lead-free soldering bridge 21 are disposed at the place where the groove is formed. For the soldering materials, a soldering wire which has a cross-sectional structure identical or similar to that of the lead-free soldering bridge 21 may be used. Alternatively, as a soldering material, a soldering paste in which minute soldering powders are dispersed may be used.
The contents of tin, copper and additional metal contained in the soldering materials are determined in consideration of a melting temperature range allowed to a lead-free soldering bridge 21 which will be formed in the groove, an over-current level intended to interrupt by using a component for a secondary battery, and electrical or mechanical properties intended to assign to a component for a secondary battery.
When the soldering materials are disposed, a rolling process proceeds at least at the place where the soldering materials are disposed by applying pressures with a jig, a roller or the like. Thermal energy capable of causing a local melting is applied to the place where the soldering materials are in contact with the inner surface of the groove. Then, an alloy is formed from each of metal constituents comprised in the metal plate and the soldering materials along the contact interface. Like this, when an alloy is formed from different metal constituents, the surface resistance formed in the interface between the soldering materials and the metal plate may be minimized.
The thermal energy may be applied by using various methods such as a thermal conductivity method, an ultrasound vibration method, an electric energy beam radiation method, an electromagnetic inducing method, or the like. However, the present invention is not limited to a specific method for applying thermal energy, and may use various known methods in the art, which can generate thermal energy at the portion to which pressures are applied while a rolling process proceeds.
After completing the rolling process, a lead-free soldering bridge 21 is formed in the groove, a gap is formed at the lower portion of the lead-free soldering bridge 21 to separate the first metal plate 22 and the second metal plate 23 from the metal plate. The gap may be formed by using any one technology for forming the groove as described above.
After forming the gap, the residues of the soldering materials attached to the first metal plate 22 and the second metal plate 23 are removed, to complete the manufacturing of the component for a secondary battery.
Meanwhile, in the modified structure of
Referring to
Meanwhile, in order to enlarge the size of coupling areas between the lead-free soldering bridge 21 and the first and second metal plates 22, 23 and improve the tensile strength characteristic thereof, the facing surfaces S1, S2 are likely to be modified in various shapes.
For example, as shown in
Referring to
Referring to
A method of manufacturing the component for a secondary battery according to the present invention is obvious to understand based on the aforementioned embodiment. First, the first and second metal plates are prepared to perfectly fit on the structure of the components shown in the drawings. The first metal plate and the second metal plate are neighbored on the same plane and faced each other to form a gap therebetween. There are various structures of the portion where the first metal plate and the second metal plate face each other as shown in the drawings. Then, a lead-free soldering bridge having a melting point of 150° C. to 300° C. and containing tin (Sn) and copper (Cu) is provided at the facing portions of the first metal plate and the second metal plate. Then, one side of the lead-free soldering bridge is welded to the first metal plate and the other side thereof is welded to the second metal plate. Although it is not essential, an additional step for attaching an insulating tape to block the lead-free soldering bridge or a gap from the air may proceed.
The component for a secondary battery according to the present invention may be used in various ways for manufacturing a secondary battery.
Referring to
The cathode lead 41 and the anode lead 42 have a structure substantially identical to the component for a secondary battery according to the present invention. That is, the cathode lead 41 and the anode lead 42 have a structure in which two metal plates are connected to each other by using a melting and separating portion A in a bridge form. Unlike
The electrode assembly 43 has a structure in which at least one or more unit cells are aggregated and the unit cells have separation membranes between a cathode and an anode. At least one side of the cathode and the anode is coated with active materials required for operating a secondary battery, and an insulating membrane which breaks electrical connections between unit cells may be interposed in the adjacent unit cells. For example, the cathode and anode may be coated with a lithium-based cathode active material and a carbon-based anode active material, respectively. The separating membrane and the insulating membrane may comprise a polyolefin-based porous polymer film. Such a secondary battery structure described above is widely known in the art and the present invention is not limited to the specific structure and the material composition of an electrode assembly 43.
The electrode assembly 43 includes a plurality of cathode taps 44 and anode taps 45 elongated from each of a cathode and an anode. The plurality of cathode taps 44 and anode taps 45 are collected as a whole by a first welding and then coupled with each of the cathode lead 41 and anode lead 42 after a second welding.
The electrode assembly 43 is tightly sealed in a packing 46 to externally expose the ends of the cathode lead 41 and anode lead 42. The packing 46 comprises aluminum pouch films in which a thermal adhesive layer is formed at its inside toward the electrode assembly 43. Accordingly, the electrode assembly 43 is sealed in a packing 46 by applying heat along the edges of the packing 46. Depending on the type of a secondary battery, the packing 46 may include a liquid electrolyte, a solid electrolyte, a gel-typed electrolyte, or the like.
Since the secondary battery 40 according to the present invention includes a melting and separating portion A in electrode leads, when an over-current flows through the electrode leads and the temperature of the lead-free soldering bridge included in a melting and separating portion A increases until 150° C. to 300° C., the breakage of the electrode leads is resulted from the center of the melting and separating portion A to irreversibly interrupt the over-current flow. Therefore, independently of a protection circuit, a secondary battery may be protected from an over-current.
The component 20 for a secondary battery according to the present invention may be used as a connector component for connecting a plurality of secondary batteries in series or in parallel, instead of using an electrode lead of a secondary battery.
As shown in
The multi-battery system means a battery module in which a plurality of secondary batteries is connected to each other in series or in parallel; a battery pack in which a plurality of battery modules is connected to each other in series or in parallel; a pack assembly in which a plurality of battery packs are connected to each other in series or in parallel; or the like.
As mentioned above, when the component 20 for a secondary battery is interposed in the adjacent terminals 50, 60 and an over-current flows between the terminals 50, 60 to increase the temperature of the lead-free soldering bridge included in the component 20 for a secondary battery until 150° C. to 300° C., the electric connection between the terminals 50, 60 is broken mainly from the separating melting portion A to irreversibly interrupt the over-current flow. Therefore, independently of a protection circuit, a multi-battery system may be protected from an over-current.
The multi-battery system may be used as a large-capacity secondary battery system used for power tools; vehicles powered by electricity including electric vehicles (EV), hybrid vehicles (HEV), and plug-in hybrid electric vehicles (PHEV); electric trucks; or power storage apparatuses.
Hereinafter, the present invention is explained in more detail using the Embodiments. However, the following Embodiments may be modified in various ways, and the present invention should not be interpreted as being limited thereto.
A pouch type lithium secondary battery having a capacity of 45 Ah was manufactured and the structure of the component for a secondary battery of
The procedure of Example 1 was repeated, except that an alloy substrate containing 99.4 wt % of tin, 0.5 wt % of copper and 0.1 wt % of nickel was used for forming a lead-free soldering bridge, to fabricate a pouch type lithium secondary battery having a capacity of 45 Ah.
The procedure of Example 1 was repeated, except that an anode lead having no lead-free soldering bridge and made of copper plates having a thickness of 0.2 mm was used, to fabricate a pouch type lithium secondary battery having a capacity of 45 Ah.
The lithium secondary battery of Example 1 was charged and discharged at 25° C. under an atmospheric pressure, in which the levels of a charge current and a discharge current were set at 72 A and 95 A, respectively. When the lithium secondary battery was charged, the resistance of the secondary battery was measured whenever State of Charge (SOC) increased by 10%, and thus, an average resistance value of 1.515 mOhm was obtained.
Similarly, the resistance of the lithium secondary battery of Example 2 was measured, and thus, an average resistance value of 1.529 mOhm was obtained.
In addition, the resistance of the lithium secondary battery of Comparative Example was measured, and thus, an average resistance value of 1.494 mOhm was obtained.
According to the results of such a test, the lithium secondary battery of Example 1 exhibited resistance characteristic increased by 1.4% as compared with Comparative Example and the lithium secondary battery of Example 2 exhibited resistance characteristic increased by 2.3% as compared with Comparative Example. Therefore, it is understood that even though the structure of the component for a secondary battery according to the present invention is applied to an anode lead, a resistance level thereof is not significantly changed compared to that of a conventional lithium secondary battery.
In addition, in Example 2, considering that the extremely low content of copper was 0.5 wt %, it is obvious that if the content of cooper comprised in a lead-free soldering bridge is adjusted in the range of 2 to 20 wt %, the resistance characteristic will just increase at least in a level of less than 2.3%.
In order to test the safety of a lithium secondary battery using the component for a secondary battery according to the present invention as an electrode lead, a short-circuit test was performed under an over-current circumstance.
The lithium secondary batteries of Examples 1 and 2 were fully charged to be SOC 100%, and the cathode lead and the anode lead thereof were connected to each other to form a short-circuit condition. After forming the short-circuit condition, a short-circuit current level was measured at a predetermined time interval, and a temperature change over time of the anode lead plate and the center portion of the secondary battery packing were observed over time. The monitoring results with respect to short-circuit current and temperature are shown in
As shown in
In addition, as shown in
A short-circuit test was identically performed with respect to the battery module of the Comparative Example. Based on the test results, it was confirmed that the temperature of the lithium secondary battery rapidly increased to 100° C. or higher within two minutes, and the sealing portion of the lithium secondary battery was opened to emit gas. After gas emission, the temperature of the lithium secondary battery was maintained to approximately 60° C.
Based on the results of such test for the lithium secondary batteries of Examples 1 and 2, it can be understood that as soon as a short-circuit current occurred, an over-current was interrupted by the breakage of the electrode leads, and a temperature locally increased from 150° C. to 300° C. only at the breakage portion of the electrode leads in which the lead-free soldering bridge melted, so that the generation of an over-current does not substantially affect the secondary batteries.
Therefore, it is confirmed that if a structure of the component for a secondary battery according to the present invention is applied to electrode leads of a lithium secondary battery, the safety of the lithium secondary battery can be improved under an over-current circumstance.
In order to evaluate the safety of a secondary battery under the overcharge condition in which a structure of the component for a secondary battery according to the present invention is applied to electrode leads of a lithium secondary battery, the following experiment was carried out.
Lithium secondary batteries fabricated in Examples 1 and 2 and Comparative Example were used, and each secondary battery was overcharged under the condition of 10V/1A and the monitoring results are shown in the following Table 1.
According to the results of the test, when the secondary battery of Comparative Example was overcharged, the temperature of the battery dramatically increased, thereby resulting in the ignition and explosion of the battery. However, the electrode leads comprised in the lithium secondary batteries of Examples of the present invention were broken by the rapidly increased temperature, thereby ensuring their safety. Accordingly, it can be understood that when the structure of the component for a secondary battery according to the present invention is applied to an electrode lead comprised in a lithium secondary battery, the safety of a secondary battery can be improved under an over-charge circumstance as well as the over-current circumstance.
In order to evaluate the tensile strength characteristics of the component for a secondary battery according to an embodiment of the present invention, the following test was performed.
First, weld strength between the soldering material used as a lead-free soldering bridge comprised in the component for a secondary battery according to the present invention and a metal plate was measured.
Sample 1
A copper substrate with a width of 1 cm, a length of 4 cm, and a thickness of 0.5 mm, and a soldering alloy substrate comprising an alloy with a width of 1 cm, a length of 4 cm, and a thickness of 0.5 mm and having 96 weight % of tin and 4 weight % of copper were overlapped in 3 mm, and then line welding was performed with laser along the center of the overlapped portion, to fabricate Sample 1.
Sample 2
A copper substrate with a width of 1 cm, a length of 4 cm, and a thickness of 0.5 mm, and an aluminum substrate with a width of 1 cm, a length of 4 cm, and a thickness of 0.2 mm were overlapped in 3 mm, and then, line welding was performed with laser along the center of the overlapped portion, like Sample 1, to fabricate Sample 2.
After Samples 1 and 2 were prepared, the tensile strength of each sample was measured by means of Universal Testing Machine (UTM). As a result, the tensile strength of Sample 1 was 233.2 N, and the tensile strength of Sample 2 was 150.9 N, and it was recognized that Sample 1 has approximately 54.5% higher tensile strength than that of Sample 2. Accordingly, it was confirmed that the lead-free soldering material used in the component for a secondary battery according to the present invention has excellent weld characteristic with a metal plate. Meanwhile, the tensile strength level of Sample 2 is larger than the level required for various kinds of connecters used in an electrode lead of a secondary battery or a multi-battery system. Accordingly, it can be understood that a lead-free soldering bridge according to the present invention can substitute various kinds of connectors used in an electrode lead of a secondary battery or a multi-battery system.
Next, for the soldering connector including tin and copper, the change of tensile strength characteristics was evaluated depending on the change of copper content. To achieve this, six samples in which cooper content was adjusted to 4 w %, 6 w %, 8 w %, 10 w %, 15 w % and 20 wt %, respectively, were prepared and named Samples 3 to 8.
The Samples 3 to 8 were prepared to have the same thickness, width, and length, that is, a thickness of 0.5 mm, a width of 1 cm and a length of 5 cm, and the tensile strength of each sample was measured by means of UTM. The measuring results were shown in
As shown in
Meanwhile, it was confirmed that if the content of copper increases by 10 to 20 wt %, a tensile strength decreases a little compared to the case in which the content of copper is in the range of 4 to 8 wt %. However, since the decrease of a tensile strength is subtle, even a lead-free soldering material having a copper content of 10 to 20 wt % has enough tensile strength capable of applying to the component for a secondary battery according to the present invention, as being obvious in the art.
Based on the test result described above, it can be understood that the lead-free soldering material used to implement the structure of the component for a secondary battery according to the present invention has enough tensile strength capable of using as various kinds of connectors used for an electrode lead of a secondary battery or a multi-battery system.
Accordingly, without modifying geometrical specifications of a conventional electrode lead or connectors, a component for a secondary battery according to the present invention may be used as a substitute for the electrode lead or connectors.
The present invention has been described in detail. However, it should be understood that the detailed description and specific examples, while indicating preferred embodiments of the disclosure, are given by way of illustration only, since various changes and modifications within the spirit and scope of the disclosure will become apparent to those skilled in the art from this detailed description.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2011-0059255 | Jun 2011 | KR | national |
| 10-2011-0093615 | Sep 2011 | KR | national |
| 10-2012-0064368 | Jun 2012 | KR | national |
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/KR2012/004768 | Jun 2012 | US |
| Child | 14012357 | US |
