Patent Application
20230170476
This application claims priority to and the benefit of Korean Patent Application No. 10-2021-0166115, filed on Nov. 26, 2021, in the Korean Intellectual Property Office, the content of which is incorporated by reference herein in its entirety.
One or more embodiments of the present disclosure relate to a composite anode active material, an anode including the same, and a lithium battery including the same.
In order to meet the miniaturization and high performance of one or more suitable devices, lithium batteries need to have high energy density as well as miniaturization and weight reduction. Therefore, high-capacity lithium batteries are becoming more important.
In order to implement lithium batteries suitable for these utilizations, anode active materials having a high capacity are being actively studied.
Compared to carbonaceous anode active materials, silicon-based anode active materials in the art easily deteriorate due to the volume change caused by charging and discharging.
Therefore, there is a need or desire to develop lithium batteries that include a silicon-based anode active material and provide excellent or suitable cycle characteristics.
One or more aspects of embodiments of the present disclosure are directed toward a composite anode active material that prevents (or protects from) deterioration of lithium batteries.
One or more aspects of embodiments of the present disclosure are directed toward an anode including the composite anode active material.
One or more aspects of embodiments of the present disclosure are directed toward a lithium battery including the anode.
Additional aspects will be set forth in part in the description which follows and, in part, will be apparent from the description, or may be learned by practice of the presented embodiments of the disclosure.
According to one or more embodiments of the present disclosure, a composite anode active material may include:
a core; and
a shell on and conformed to a surface of the core, wherein:
the core may include a silicon-containing structure, a silicon-containing compound, or a combination thereof,
the shell may include at least one first metal oxide represented by Formula MaOb (0<a≤3, 0<b<4, and when a is 1, 2, or 3, b is not an integer), and a first carbonaceous material, and
the first metal oxide is placed in the first carbonaceous material, and M is at least one metal selected from among Group 2 to Group 13, Group 15, and Group 16 of the Periodic Table of Elements.
According to one or more embodiments of the present disclosure, an anode is provided to include the composite anode active material.
According to one or more embodiments of the present disclosure, an anode may include:
a dry composite anode active material;
a dry conductive material; and
a dry binder,
wherein the dry composite anode active material may include:
a core, and
a shell on and conformed to a surface of the core,
wherein the core may include a silicon-containing structure, a silicon-containing compound, or a combination thereof,
the shell may include at least one first metal oxide represented by Formula MaOb (0<a≤3, 0<b<4, and when a is 1, 2, or 3, b is not an integer) and a first carbonaceous material, and
the first metal oxide is placed in the first carbonaceous material, and M is at least one metal selected from among Group 2 to Group 13, Group 15, and Group 16 of the Periodic Table of Elements.
According to one or more embodiments of the present disclosure, a lithium battery is provided to include the anode.
The above and other aspects, features, and advantages of certain embodiments of the disclosure will be more apparent from the following description taken in conjunction with the accompanying drawings, in which:
Reference will now be made in more detail to embodiments, examples of which are illustrated in the accompanying drawings, wherein like reference numerals refer to like elements throughout, and duplicative descriptions thereof may not be provided. In this regard, the embodiments of the present disclosure may have different forms and should not be construed as being limited to the descriptions set forth herein. Accordingly, the embodiments are merely described, by referring to the drawings, to explain aspects of the present disclosure. As utilized herein, the terms “and/or” and “or” may include any and all combinations of one or more of the associated listed items. Expressions such as “at least one of,” when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.
Since the present disclosure to be described below may be variously modified and may have one or more embodiments, specific embodiments are illustrated in the drawings and described in more detail in the detailed description. However, this is not intended to limit the present disclosure to a specific embodiment, and it should be understood to include all modifications, equivalents, or substitutes included in the technical scope of the present disclosure.
The terms utilized below are only utilized to describe specific embodiments and are not intended to limit the present disclosure. Singular expressions may include plural expressions unless the context clearly indicates otherwise. Hereinafter, it will be further understood that the terms “comprise”, “include” or “have,” when utilized in the present disclosure, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. The “/” utilized below may be interpreted as “and” or as “or” depending on the situation.
In the drawings, thickness is enlarged or reduced in order to clearly express one or more layers and regions. Throughout the disclosure, like reference numerals designate like components. Throughout the disclosure, when a component such as a layer, a film, a region, or a plate is mentioned to be placed “on” another component, it will be understood that it may be directly on another component or that another component may be interposed therebetween. Throughout the disclosure, although the terms “first”, “second”, “third”, etc., may be utilized herein to describe one or more elements, components, regions, and/or layers, these elements, components, regions, and/or layers should not be limited by these terms. These terms are only utilized to distinguish one component from another component.
The term “particle diameter” utilized herein may refer to an average diameter when the particle is spherical (e.g., substantially spherical), or an average major axis length when the particle is non-spherical. The particle diameter of the particles may be measured utilizing a particle diameter analyzer (PSA). The “particle diameter” of the particles may be, for example, an average particle diameter. The average particle diameter is the median particle diameter (D50) unless explicitly stated otherwise. The median particle diameter (D50) may refer to a particle diameter corresponding to a cumulative value of 50% calculated from the side of the particle having the smallest particle diameter on the cumulative distribution curve of particle sizes where particles are accumulated in the order of particle diameter from the smallest particle to the largest particle. The cumulative value may be, for example, a cumulative volume. The median particle diameter (D50) may be measured by, for example, laser diffraction.
The term “particle diameter D10” utilized herein may refer to a particle diameter corresponding to a cumulative value of 10% calculated from the side of the particle having the smallest particle diameter on the cumulative distribution curve of particle sizes.
The term “particle diameter D90” utilized herein may refer to a particle diameter corresponding to a cumulative value of 90% calculated from the side of the particle having the smallest particle diameter on the cumulative distribution curve of particle sizes.
The term “silicon suboxide” utilized herein may have, for example, a single composition represented by SiOx (0<x<2). Alternatively, “silicon suboxide” may include, for example, at least one selected from among Si and SiO2 to have an average composition of SiOx (0<x<2). Alternatively, “silicon suboxide” may also include, for example, a silicon-suboxide-like material. The silicon suboxide-like material is a material that has properties similar to those of silicon suboxide, and may include, for example, at least one selected from among Si and SiO2 to have an average composition of SiOx (0<x<2).
As utilized herein, the singular forms “a,” “an,” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. Further, the use of “may” when describing embodiments of the present disclosure refers to “one or more embodiments of the present disclosure”.
As utilized herein, the terms “substantially,” “about,” and similar terms are used as terms of approximation and not as terms of degree, and are intended to account for the inherent deviations in measured or calculated values that would be recognized by those of ordinary skill in the art.
Any numerical range recited herein is intended to include all sub-ranges of the same numerical precision subsumed within the recited range. For example, a range of “1.0 to 10.0” is intended to include all subranges between (and including) the recited minimum value of 1.0 and the recited maximum value of 10.0, that is, having a minimum value equal to or greater than 1.0 and a maximum value equal to or less than 10.0, such as, for example, 2.4 to 7.6. Any maximum numerical limitation recited herein is intended to include all lower numerical limitations subsumed therein and any minimum numerical limitation recited in this specification is intended to include all higher numerical limitations subsumed therein. Accordingly, Applicant reserves the right to amend this specification, including the claims, to expressly recite any sub-range subsumed within the ranges expressly recited herein.
Hereinafter, a composite anode active material according to one or more embodiments of the present disclosure, an anode including the composite anode active material, and a lithium battery including the anode will be described in more detail.
The composite anode active material may include: a core; and a shell on (e.g., located on) and conformed to a surface of the core, wherein the core may include a silicon-containing structure, a silicon-containing compound, or a combination thereof, the shell may include at least one first metal oxide represented by Formula MaOb (0<a≤3, 0<b<4, and when a is 1, 2, or 3, b is not an integer) and a first carbonaceous material, and the first metal oxide may be placed in the first carbonaceous material (e.g., in a matrix of the first carbonaceous material), and M is at least one metal selected from among Group 2 to Group 13, Group 15, and Group 16 of the Periodic Table of Elements. Referring to
Hereinafter, a theoretical basis for providing an excellent or suitable effect of the composite anode active material according to one or more embodiments will be described, but this is to aid understanding of the present disclosure and is not intended to limit the present disclosure in any way.
The composite anode active material may include a matrix of the first carbonaceous material, and by utilizing a composite including a plurality of first metal oxides located inside the matrix, a uniform (e.g., substantially uniform) shell may be on (e.g., located on) the core while preventing or reducing agglomeration of the first carbonaceous material. Accordingly, a contact between a core and an electrolyte is effectively blocked, thereby effectively preventing or reducing the side reactions due to the contact between the core and the electrolyte. In one or more embodiments, the first carbonaceous material may be, for example, a crystalline carbonaceous material. In one or more embodiments, the first carbonaceous material may be, for example, a carbonaceous nanostructure. In one or more embodiments, the first carbonaceous material may be, for example, a carbonaceous two-dimensional nanostructure. In one or more embodiments, the first carbonaceous material may be, for example, carbonaceous flakes. In one or more embodiments, the first carbonaceous material may be, for example, graphene. Since the shell including graphene and/or a matrix thereof has flexibility, the volume change in the core during charging and discharging may be easily tolerated. Therefore, the occurrence of cracks on the surface and/or inside of the composite anode active material during charging and discharging may be suppressed or reduced, and the formation of a solid electrolyte film (SEI) on the surface and/or inside of the composite anode active material may be suppressed or reduced. As a result, deterioration of the lithium battery containing the composite anode active material is suppressed or reduced. In contrast, in the case of silicon-based anode active materials of the related art, in general, cracks occur on the surface and/or inside of the silicon-containing anode active material due to volume change during charging and discharging. A new surface is generated inside and/or outside the silicon-based anode active material by the cracks. On the new surface, a solid electrolyte film (SEI) is formed by a side reaction between the silicon-based anode active material and the electrolyte. The continuous formation of the solid electrolyte film (SEI), as the charging and discharging proceeds, increases the internal resistance of the silicon-based anode active material, and consequently degrades the performance of the lithium battery. In addition, carbonaceous materials of the related art are easily agglomerated during the coating process, so that it is difficult to uniformly coat the core.
The core of the composite anode active material may contain a silicon-containing anode active material, such as a silicon-containing structure, a silicon-containing compound, or a combination thereof. In one or more embodiments, the silicon-containing structure may be, for example, a silicon composite structure. In one or more embodiments, the silicon composite structure may be, for example, a silicon-carbon composite. In one or more embodiments, the silicon-carbon composite may be, for example, a silicon-carbon nanocomposite. The silicon-carbon nanocomposite may refer to a composite in which at least one selected from among silicon and carbon has a nanoscale size of less than 1 μm. For example, in one or more embodiments, the silicon-carbon nanocomposite may be a composite in which silicon nanoparticles and carbon nanoparticles are complexed. The silicon-containing compound may include, for example, silicon, silicon alloy, silicon oxide, silicon nitride, silicon nitroxide, silicon carbide, or one or more combinations thereof. In one or more embodiments, the silicon-containing compound may be, for example, SiOx (0<x<2).
In one or more embodiments, the silicon composite structure may include, for example, porous silicon secondary particles and a first carbon flake on (e.g., located on) the porous silicon secondary particles, wherein the porous silicon secondary particles are (e.g., are each) aggregates of a plurality of silicon composite primary particles, and the silicon composite primary particles may include: silicon, silicon suboxide (SiOx, 0<x<2) on (e.g., located on) the silicon, and a second carbon flake on (e.g., located on) the silicon suboxide.
In one or more embodiments, the silicon composite structure may include a porous silicon secondary particle containing an agglomerate of a plurality of silicon composite primary particles and a first carbon flake on (e.g., located on) the porous silicon secondary particle. In some embodiments, the first carbon flake on (e.g., located on) the porous silicon secondary particles may be located to cover at least one surface of the porous silicon secondary particles. In some embodiments, the first carbon flake may be deposited directly on the porous silicon secondary particles. In some embodiments, the first carbon flake may be grown directly on the silicon suboxide of the porous silicon secondary particles. In some embodiments, the first carbon flake may be grown directly on the surface of the porous silicon secondary particles to be located directly on the surface of the porous silicon secondary particles. In some embodiments, the first carbon flake may completely cover the surface of the porous silicon secondary particles or may cover a portion thereof. The coverage of the first carbon flake may be, for example, 5% to 100%, 10% to 99%, 20% to 95%, or 40% to 90%, based on the total surface area of the porous silicon secondary particles. The carbon of the first carbon flake exists on the surface of the porous silicon secondary particles and effectively buffers the volume change of the porous silicon secondary particles. The size of the porous silicon secondary particles may be, for example, about 1 μm to about 20 μm, about 2 μm to about 18 μm, or about 3 μm to about 10 μm. The size of the first carbon flake may be, for example, about 1 nm to about 200 nm, about 5 nm to about 150 nm, or about 10 nm to about 100 nm. The term “size” utilized herein refers to the diameter or the major axis length.
In one or more embodiments, a silicon composite primary particle may include silicon, silicon suboxide (SiOx, 0<x<2) on (e.g., located on) at least one surface of the silicon, and a second carbon flake on (e.g., located on) one side of the silicon suboxide. The silicon may be, for example, plate-shaped, needle-shaped, spherical (e.g., substantially spherical), or a combination thereof. The shape of silicon is not particularly limited, and may be, for example, the shape of sphere, nanowire, needle, rod, particle, nanotube, nanorod, wafer, and nanoribbon, or a combination thereof. The average size (e.g., average diameter) of silicon may be, for example, about 10 nm to about 1 μm, about 10 nm to about 500 nm, about 20 nm to about 150 nm, or 100 nm. Regarding the average size (diameter) of silicon, when the silicon is spherical particles (e.g., substantially spherical particles), the average size is an average particle diameter. When the silicon is non-spherical particles, for example, plate-shaped particles or needle-shaped particles, the average size (diameter) is a major axis length, width, or thickness. Silicon suboxide (SiOx) on silicon in silicon composite primary particles (0<x<2) may cover at least a surface of silicon. In some embodiments, silicon suboxide may be located directly on silicon. The silicon suboxide may completely cover the surface of silicon or may cover a portion thereof. The coverage of the silicon suboxide may be, for example, from about 1 to about 100%, from about 5% to about 99%, from about 10% to about 95%, or from about 20% to about 90%, based on the total surface area of silicon. A second carbon flake on (e.g., located on) the silicon suboxide may be located to cover at least one surface of the silicon suboxide. The second carbon flake may be located directly on the silicon suboxide. The second carbon flake may be grown directly from the surface of the silicon suboxide and located directly on the surface of the silicon suboxide. In some embodiments, the second carbon flake may completely cover the surface of silicon suboxide or may cover a portion thereof. The coverage of the second carbon flake may be, for example, about 10% to about 100%, about 10% to about 99%, about 20% to about 95%, or about 40% to about 90%, based on the total surface area of the silicon suboxide. The carbon of the second carbon flake exists on the surface of silicon and/or silicon suboxide and may effectively buffer the volume change of silicon composite primary particles. The size of the second carbon flake may be, for example, about 1 nm to about 200 nm, about 5 nm to about 150 nm, or about 10 nm to about 100 nm. The term “size” utilized herein refers to the diameter or the major axis length.
In one or more embodiments, the silicon composite structure may include porous silicon secondary particles and a first carbon flake on (e.g., located on) the porous silicon secondary particles. The first carbon flake may completely cover the porous silicon secondary particles or may cover a portion thereof. In some embodiments, for example, the first carbon flake may completely surround the porous silicon secondary particles or may surround a portion thereof. In some embodiments, the silicon composite structure may include a second carbon flake on (e.g., located on) the silicon composite primary particles included in the porous silicon secondary particles. During volume expansion/contraction of the silicon composite structure, silicon included in the porous silicon secondary particles may maintain contact with the first carbon flake and/or the second carbon flake. Since the porous silicon secondary particles may include pores, the pores may act as an internal buffer space during volume expansion/contraction of the silicon composite structure. Therefore, unlike silicon-based anode active materials of the related art, the silicon composite structure may suppress or reduce the increase in internal resistance while effectively accommodating the volume change of the silicon composite structure during charging and discharging.
In one or more embodiments, the porosity of the silicon composite structure may be, for example, 60% or less, 30% to 60%. In some embodiments, the silicon composite structure may be non-porous. In some embodiments, the non-porous structure may have, for example, a porosity of 10% or less or 5% or less. In some embodiments, the non-porous structure may have, for example, a porosity of 0.01% to 5%, or 0%. Porosity may be measured by a mercury adsorption method (porosimetry) or a nitrogen adsorption method.
In one or more embodiments, the silicon composite structure may have, for example, a non-spherical shape. The circularity of the silicon composite structure may be, for example, 0.9 or less. The circularity of the silicon composite structure may be, for example, 0.7 to 0.9, 0.8 to 0.9, or 0.85 to 0.9. Circularity is determined by, for example, 4ΠA/P2 (A is an area, P is a perimeter).
In one or more embodiments, the silicon composite structure may include a first carbon flake and a second carbon flake. The first carbon flake and the second carbon flake may be, for example, same carbon flakes. The first carbon flake and the second carbon flake may be any carbonaceous material that has a flake shape. The first carbon flake and the second carbon flake may be each independently graphene, graphite, carbon fiber, graphitic carbon, graphene oxide, or a mixture thereof. In some embodiments, the silicon composite structure may include, for example, first graphene and second graphene as the first carbon flake and the second carbon flake, respectively. The first graphene and the second graphene may each have a structure such as a nanosheet, a film (or film), or a flake. Nanosheet may refer to a form formed in an irregular state with a thickness of about 1000 nm or less, for example, 1 nm to 1000 nm on silicon suboxide or porous silicon secondary particles. The film may refer to a form continuously and uniformly formed on silicon suboxide or porous silicon secondary particles.
In one or more embodiments, the silicon-containing structure may further include a carbonaceous coating layer on (e.g., located on) the silicon composite structure. The carbonaceous coating layer may improve the physical stability of the silicon composite structure and more effectively prevent or reduce side reactions between the silicon and the electrolyte during charging and discharging. In some embodiments, the carbonaceous coating layer may include, for example, first amorphous carbon. The carbonaceous coating layer may include first amorphous carbon having a high density. The first amorphous carbon may include, for example, pitch carbon, soft carbon, hard carbon, mesophase pitch carbide, calcined coke, carbon fiber, or a mixture thereof. In some embodiments, the carbonaceous coating layer may further include crystalline carbon. By further including crystalline carbon, the carbonaceous coating layer may more effectively act as a buffer for the volume change of the silicon composite structure. The crystalline carbon may be, for example, natural graphite, artificial graphite, graphene, fullerene, carbon nanotubes, or a mixture thereof. The thickness of the carbonaceous coating layer may be, for example, about 1 nm to about 5000 nm, about 10 nm to about 2000 nm, or about 5 nm to about 2500 nm.
In one or more embodiments, the silicon-containing structure may further include, for example, a second amorphous carbon located within the silicon composite structure. For example, in some embodiments, the silicon composite structure may include porous silicon secondary particles, and the second amorphous carbon may be located in the pores of the porous silicon secondary particles. The second amorphous carbon may be located between the plurality of silicon composite primary particles constituting the porous silicon secondary particles. The silicon composite primary particle may include, for example, silicon, silicon suboxide (SiOx, 0<x<2) on (e.g., located on) silicon, and a second carbon flake on (e.g., located on) the silicon suboxide; and second amorphous carbon on (e.g., located on) the second carbon flake. The silicon composite structure may have a dense structure having a non-porous structure due to the filling of the pores with dense second amorphous carbon therein. Since the silicon composite structure has such a non-porous structure, a side reaction with an electrolyte during charging and discharging may be further reduced, and the volume change of silicon may be more effectively reduced. The second amorphous carbon may include, for example, pitch carbon, soft carbon, hard carbon, mesophase pitch carbide, calcined coke, carbon fiber, or a mixture thereof.
A mixing ratio of the total weight of a first carbon, which is the sum of the carbon of the first carbon flake and the carbon of the second carbon flake to the weight of a second carbon, which is the carbon of the carbonaceous coating layer, in the silicon composite structure may be, for example, 30:1 to 1:3, 20:1 to 1:1, or 10:1 to 1:0.9. When the first carbon and the second carbon have these ranges of mixing ratio, a lithium battery having improved cyclic characteristics may be provided. The mixing ratio of the first carbon and the second carbon may be confirmed through thermogravimetric analysis. The first carbon is associated with a peak appearing in a region of 700° C. to 750° C., and the second carbon is associated with a peak appearing in a region of 600° C. to 650° C. Thermogravimetric analysis may be performed in conditions including, for example, the temperature increase rate of about 10° C./min, an air atmosphere of 25° C. to 1,000° C. The first carbon may be, for example, crystalline carbon, and the second carbon may be, for example, amorphous carbon. A mixing ratio of the total weight of the carbon of the first carbon flake and the carbon of the second carbon flake to the total weight of the first amorphous carbon and the second amorphous carbon may be, for example, 1:99 to 99:1, 1:20 to 80:1, or 1:1 to 1:10.
In one or more embodiments, the core is a silicon-containing anode active material, and may include a silicon-containing compound SiOx (0<x<2). In some embodiments, the average particle diameter of SiOx(0<x<2) may be, for example, 1 μm or more, 3 μm or more, or 5 μm or more. In some embodiments, the average particle diameter of SiOx(0<x<2) may be, for example, about 1 μm to about 30 μm, about 3 μm to about 20 μm, or about 5 μm to about 15 μm.
In one or more embodiments, the shell may include a first metal oxide and a first carbonaceous material.
Since the first carbonaceous material, for example, graphene, has high electronic conductivity, the interfacial resistance between the composite anode active material and the electrolyte may be reduced. Accordingly, an increase in the internal resistance of the lithium battery is suppressed or reduced despite the introduction of the shell including the first carbonaceous material. In some embodiments, because the first carbonaceous material included in the shell of the composite anode active material is derived from the graphene matrix, the density thereof is relatively low and porosity is high, compared to carbon-based materials of the related art derived from a graphite-based material. The d 002 interplanar distance of the first carbonaceous material included in the shell of the composite anode active material may be, for example, 3.38 Å or more, 3.40 Å or more, 3.45 Å or more, 3.50 Å or more, 3.60 Å or more, 3.80 Å or more, or 4.00 Å or more. In some embodiments, the d 002 interplanar distance of the first carbonaceous material included in the shell of the composite anode active material may be, for example, about 3.38 Å to about 4.0 Å, about 3.38 Å to about 3.8 Å, about 3.38 Å to about 3.6 Å, about 3.38 Å to about 3.5 Å, or about 3.38 Å to about 3.45 Å. In contrast, the d 002 interplanar distance of the carbonaceous material of the related art derived from the graphite-based material may be, for example, 3.38 Å or less, or 3.35 Å to 3.38 Å. Because the first metal oxide has voltage resistance, the deterioration of the core during charging and discharging at a high voltage may be prevented or reduced. In some embodiments, the shell may include, for example, one kind of first metal oxide or two or more kinds of different first metal oxides. As a result, the cyclic characteristics of the lithium battery including the composite anode active material is improved, and the volume change thereof may be suppressed or reduced.
In one or more embodiments, the amount of the shell may be about 0.1 wt % to about 5 wt %, about 0.1 wt % to about 4 wt %, about 0.1 wt % to about 3 wt %, or about 0.1 wt % to about 2 wt % of the total weight of the composite anode active material. In one or more embodiments, the amount of the first metal oxide may be, for example, about 0.06 wt % to about 3 wt %, about 0.06 wt % to about 2.4 wt %, about 0.06 wt % to about 1.8 wt %, or 0.06 wt % to 1.2 wt % of the total weight of the composite anode active material. Because the composite anode active material includes these amount ranges of the shell and the first metal oxide, the cyclic characteristics of the lithium battery are further improved.
In one or more embodiments, the shell may include a first metal, and the amount of the first metal may be, for example, about 0.1 at % to about 10 at %, about 0.5 at % to about 7 at %, or about 1 at % to about 5 at %, based on the total number of atoms of the shell. When the shell includes these amount ranges of the first metal, cyclic characteristics of the lithium battery including the composite anode active material may be further improved. The amount of a first metal element (e.g., the first metal) included in the shell may be obtained from, for example, a peak obtained by measuring an XPS spectrum on the surface of the composite anode active material. The first metal may be a metal included in the first metal oxide.
In one or more embodiments, the shell may include oxygen (O), and the amount of oxygen (O) may be, for example, about 6 at % to about 20 at %, about 7 at % to about 15 at %, about 8 at % to about 15 at %, or about 10 at % to about 15 at %, based on the total number of atoms in the shell. When the shell includes these amount ranges of the oxygen, cyclic characteristics of the lithium battery including the composite anode active material may be further improved. The amount of an oxygen (O) included in the shell may be obtained from, for example, a peak obtained by measuring an XPS spectrum on the surface of the composite anode active material.
In one or more embodiments, the shell may include aluminum (Al) as the first metal, and the amount of aluminum (Al) may be, for example, about 0.1 at % to about 10 at %, about 0.5 at % to about 10 at %, about 1 at % to about 9 at %, about 1 at % to about 7 at %, or about 1 at % to about 5 at %, based on the total number of atoms of the shell. When the shell includes these amount ranges of aluminum, cyclic characteristics of the lithium battery including the composite anode active material may be further improved. The amount of aluminum (Al) included in the shell may be obtained from, for example, a peak obtained by measuring an XPS spectrum on the surface of the composite anode active material.
In one or more embodiments, the shell may include carbon (C), and the amount of carbon (C) may be, for example, about 70 at % to about 95 at %, about 70 at % to about 90 at %, about 75 at % to about 90 at %, about 80 at % to about 90 at %, about 80 at % to about 87 at %, or about 80 at % to about 85 at %, based on the total number of atoms of the shell. When the shell includes these amount ranges of carbon, cyclic characteristics of the lithium battery including the composite anode active material may be further improved. The amount of carbon included in the shell may be obtained from, for example, a peak obtained by measuring an XPS spectrum on the surface of the composite anode active material.
In one or more embodiments, the first metal oxide may include the first metal, and the first metal may be, for example, at least one selected from among aluminum (Al), niobium (Nb), magnesium (Mg), scandium (Sc), titanium (Ti), zirconium (Zr), vanadium (V), tungsten (W), manganese (Mn), iron (Fe), cobalt (Co), palladium (Pd), copper (Cu), silver (Ag), zinc (Zn), antimony (Sb), and selenium (Se). The first metal oxide may be, for example, at least one selected from Al2Oz (0<z<3), NbOx (0<x<2.5), MgOx (0<x<1), Sc2Oz (0<z<3), TiOy (0<y<2), ZrOy (0<y<2), V2Oz (0<z<3), WOy (0<y<2), MnOy (0<y<2), Fe2Oz (0<z<3), Co3Ow (0<w<4), PdOx (0<x<1), CuOx (0<x<1), AgOx (0<x<1), ZnOx (0<x<1), Sb2Oz (0<z<3), and SeOy (0<y<2). Because such a first metal oxide is placed in the matrix of a carbonaceous material, uniformity of the shell placed on the core is improved, and voltage resistance of the composite anode active material may be further improved. For example, in some embodiments, the shell may include Al2Ox (0<x<3) as the first metal oxide.
In one or more embodiments, the shell may further include at least one kind of second metal oxide represented by MaOc (0<a≤3, 0<c≤4, when a is 1, 2, or 3, c is an integer). M may be at least one metal selected from among Group 2 to Group 13, Group 15, and Group 16 of the Periodic Table of Elements. For example, in some embodiments, the second metal oxide may include the same metal as the first metal oxide, and the ratio c/a of c to a in the second metal oxide is greater than the ratio b/a of b to a in the first metal oxide. For example, c/a>b/a. The second metal oxide may be selected from among Al2O3, NbO, NbO2, Nb2O5, MgO, Sc2O3, TiO2, ZrO2, V2O3, WO2, MnO2, Fe2O3, Co3O4, PdO, CuO, AgO, ZnO, Sb2O3, and SeO2. The first metal oxide may be, for example, a reduction product of the second metal oxide. The first metal oxide is obtained by reducing a part or all of the second metal oxide. Accordingly, the first metal oxide has a lower oxygen amount and a lower metal oxidation number than the second metal oxide. For example, in some embodiments, the shell may include Al2Ox (0<x<3) as the first metal oxide and Al2O3 as the second metal oxide.
In one or more embodiments, the shell may include at least one selected from among the first metal oxide and the second metal oxide. The particle diameter of one or more selected from among the first metal oxide and the second metal oxide may be, for example, about 1 nm to about 100 nm, about 1 nm to about 50 nm, about 1 nm to about 30 nm, about 5 nm to about 30 nm, or about 10 nm to about 30 nm Within these nanometer ranges of a particle diameter, the first metal oxide and/or the second metal oxide may be more uniformly distributed in the matrix of the first carbonaceous material of the shell. When the particle diameter of at least one selected from among the first metal oxide and the second metal oxide is excessively increased, the internal resistance of the composite anode active material may be increased due to the increase in the thickness of the shell. When the particle diameter of at least one selected from among the first metal oxide and the second metal oxide is excessively reduced, uniform dispersion may be difficult.
In one or more embodiments, the shell may include the first metal oxide and/or the second metal oxide, and may include a first carbonaceous material. The first carbonaceous material may be located in a direction protruding from the surface of the first metal oxide and/or the second metal oxide. Because the first carbonaceous material grows directly from the surface of the first metal oxide and/or the second metal oxide, the first carbonaceous material may be located in a direction protruding from the surface of the first metal oxide and/or the second metal oxide. The first carbonaceous material located in a direction protruding from the surface of the first metal oxide and/or the second metal oxide may be, for example, two-dimensional carbonaceous nanostructures, carbonaceous flakes, or graphene.
In one or more embodiments, the shell may include, for example, a first carbonaceous material, and the core may include, for example, a silicon-containing structure and/or a silicon-containing compound as a silicon-containing anode active material. For example, in some embodiments, the first carbonaceous material may be formed as a composite through a mechanochemical reaction with the silicon-containing structure and/or the silicon-containing compound. The first carbonaceous material may be chemically bonded to, for example, a silicon-containing structure and/or a silicon-containing compound through chemical bonding. The core and the shell may be formed as a composite by chemically bonding the first carbonaceous material located in the shell and the silicon-containing structure and/or the silicon-containing compound located in the core through chemical bonding. Accordingly, the composite anode active material is distinguished from a simple physical mixture of the first carbonaceous material and the silicon-containing structure and/or the silicon-containing compound. In some embodiments, the first metal oxide and the carbonaceous material included in the shell may also be chemically bound to each other through a chemical bond. Here, the chemical bond may be, for example, a covalent bond or an ionic bond.
In one or more embodiments, the thickness of the shell may be, for example, from about 1 nm to about 5 μm, from about 1 nm to about 1 μm, from about 1 nm to about 500 nm, from about 1 nm to about 200 nm, from about 1 nm to about 100 nm, from about 1 nm to about 50 nm, from about 1 nm to about 30 nm, or from about 1 nm to about 20 nm. When the shell has these ranges of thickness, the electronic conductivity of the anode including the composite anode active material may be further improved.
In one or more embodiments, the shell on (e.g., located on) and conformed to the surface of the core may include, for example, at least one selected from among: a composite including a first metal oxide and a first carbonaceous material, for example, graphene; and a result of milling the composite. The first metal oxide may be located in a matrix of the first carbonaceous material, for example, a graphene matrix. The shell may be manufactured from, for example, a composite including a first metal oxide and a first carbonaceous material, for example, graphene. In some embodiments, the composite may further include a second metal oxide as well as the first metal oxide. In some embodiments, the composite may include, for example, two or more kinds of first metal oxides. In some embodiments, the composite may include, for example, two or more kinds of first metal oxides and two or more kinds of second metal oxides.
In one or more embodiments, the amount of at least one selected from among the composite and the milling result thereof may be 5 wt % or less, 3 wt % or less, 2 wt % or less, 1 wt % or less, or 0.5 wt % or less of the total weight of the composite anode active material. In some embodiments, the amount of at least one selected from among the composite and the milling result thereof included in the composite anode active material may be, for example, about 0.1 wt % to about 5 wt %, about 0.1 wt % to about 4 wt %, about 0.1 wt % to about 3 wt %, or about 0.1 wt % to about 2 wt %. When the composite anode active material includes these amount ranges of at least one selected from among the composite and the milling result thereof, cyclic characteristics of a lithium battery including the composite anode active material may be further improved.
In one or more embodiments, the composite may include at least one selected from among the first metal oxide and the second metal oxide. The particle diameter of one or more particle diameters selected from among the first metal oxide and the second metal oxide may be, for example, about 1 nm to about 100 nm, about 1 nm to about 50 nm, about 1 nm to about 30 nm, about 5 nm to about 30 nm, or about 10 nm to about 30 nm. Within these nanometer ranges of a particle diameter, the first metal oxide and/or the second metal oxide may be more uniformly distributed in the matrix of the first carbonaceous material of the composite. Therefore, such a composite may be uniformly applied on the core to form a shell. Further, the first metal oxide and/or the second metal oxide may be more evenly on (e.g., located on) the core because the first metal oxide and/or the second metal oxide has a particle diameter within this nanometer range. Therefore, the first metal oxide and/or the second metal oxide may be uniformly on (e.g., located on) the core, thereby more effectively exhibiting voltage resistance characteristics. The average particle diameter of the first metal oxide and the second metal oxide is measured by a measurement apparatus utilizing a laser diffraction method or a dynamic light scattering method. In some embodiments, the particle diameter thereof is measured utilizing a scattering particle size distribution meter (for example, LA-920 of Horiba Corporation), and is a value of the median diameter (D50) when the metal oxide particles are accumulated to 50% from smaller particles in volume conversion. The uniformity deviation of at least one selected from among the first metal oxide and second metal oxide may be 3% or less, 2% or less, or 1% or less. The uniformity may be obtained, for example, by XPS. Accordingly, at least one selected from among the first metal oxide and second metal oxide may have a uniformity deviation of 3% or less, 2% or less, or 1% or less, and may be uniformly distributed in the composite.
In one or more embodiments, the composite may include a first carbonaceous material. The first carbonaceous material may have, for example, a branched structure, and at least one metal oxide selected from among the first metal oxide and the second metal oxide may be distributed in the branched structure of the first carbonaceous material. In some embodiments, the branched structure of the first carbonaceous material may include, for example, a plurality of particles of the first carbonaceous material in contact with each other. Because the first carbonaceous material has a branched structure, one or more conduction paths may be provided. In some embodiments, The first carbonaceous material may be, for example, graphene. Graphene may have, for example, a branched structure, and at least one metal oxide selected from among the first metal oxide and the second metal oxide may be distributed in the branched structure of graphene. The branched structure of the graphene may include a plurality of graphene particles contacting each other. Because the graphene has a branched structure, one or more conduction paths may be provided.
In one or more embodiments, the first carbonaceous material may have, for example, a spherical structure (e.g., substantially spherical structure), and at least one metal oxide selected from among the first metal oxide and the second metal oxide may be distributed in the spherical structure thereof. The size (diameter) of the spherical structure of the first carbonaceous material may be from about 50 nm to about 300 nm. There may be a plurality of first carbonaceous materials having a spherical structure. Since the first carbonaceous material has a spherical structure, the composite may have a rigid structure. In some embodiments, the first carbonaceous material may be, for example, graphene. Graphene may have, for example, a spherical structure, and at least one metal oxide selected from among the first metal oxide and the second metal oxide may be distributed in the spherical structure thereof. The spherical structure of the graphene may have a size of about 50 nm to 300 nm. A plurality of graphene having a spherical structure may be provided. Because the graphene has a spherical structure, the composite may have a robust structure.
In one or more embodiments, the first carbonaceous material may have a spiral structure in which a plurality of spherical structures (e.g., substantially spherical structures) are connected to each other, and at least one metal oxide selected from among the first metal oxide and the second metal oxide may be distributed within the spherical structure of the spiral structure. The size of the spiral structure of the first carbonaceous material may be from about 500 nm to about 100 μm. Because the first carbonaceous material has a spiral structure, the composite may have a rigid structure. In some embodiments, the first carbonaceous material may be, for example, graphene. The graphene may have a spiral structure in which a plurality of spherical structures (e.g., substantially spherical structures) are connected to each other, and at least one metal oxide selected from among the first metal oxide and the second metal oxide may be distributed within the spherical structure of the spiral structure. The spiral structure of the graphene may have a size of about 500 nm to 100 μm. Because the graphene has a spiral structure, the composite may have a robust structure.
In one or more embodiments, the first carbonaceous material may have a cluster structure in which a plurality of spherical structures (e.g., substantially spherical structures) are aggregated, and at least one metal oxide selected from among the first metal oxide and the second metal oxide may be distributed within the spherical structure of the cluster structure. The size of the cluster structure of the first carbonaceous material may be from about 0.5 mm to about 10 mm. Because the first carbonaceous material has a cluster structure, the composite may have a rigid structure. In some embodiments, the first carbonaceous material may be, for example, graphene. Graphene may have a cluster structure in which a plurality of spherical structures (e.g., substantially spherical structures) are aggregated, and at least one metal oxide selected from among the first metal oxide and the second metal oxide may be distributed within the spherical structure of the cluster structure. The cluster structure of the graphene may have a size of about 0.5 mm to 10 mm. Because the graphene has a cluster structure, the composite may have a robust structure.
In one or more embodiments, the composite may be a crumpled faceted-ball structure, and at least one selected from among the first metal oxide and the second metal oxide may be distributed inside the crumpled faceted-ball structure or on the surface of the crumpled faceted-ball structure. Because the composite is such a faceted-ball structure, the composite may be easily applied on the surface irregularities of the core.
In one or more embodiments, the composite may be, for example, a planar structure, and at least one selected from among the first metal oxide and the second metal oxide may be distributed inside the planar structure or on the surface of the planar structure. Because the composite is such a two-dimensional planar structure, the composite may be easily applied on the irregular surface of the core.
In one or more embodiments, the first carbonaceous material may extend by a distance of 10 nm or less from the first metal oxide, and may include at least 1 to 20 first carbonaceous material layers. For example, in some embodiments, because the plurality of first carbonaceous material layers are stacked, the first carbonaceous material having a total thickness of 12 nm or less may be on (e.g., located on) the first metal oxide. For example, in some embodiments, the total thickness of the carbonaceous material may be from about 0.6 nm to about 12 nm. In some embodiments, the first carbonaceous material may be, for example, graphene. The graphene may extend by a distance of 10 nm or less from the first metal oxide, and may include at least 1 to 20 graphene layers. For example, in some embodiments, because a plurality of graphene layers are stacked, graphene having a total thickness of 12 nm or less may be on (e.g., disposed on) the first metal oxide. For example, in some embodiments, the total thickness of graphene may be about 0.6 nm to about 12 nm.
In one or more embodiments, the shell may further include a second carbonaceous material that is fibrous carbon. The second carbonaceous material may include fibrous carbon.
When the shell further includes a second carbonaceous material that is fibrous carbon, a conduction path of the composite anode active material may be further lengthened. The second carbonaceous material may form a three-dimensional conductive network among the plurality of composite anode active materials to reduce internal resistance of the anode including the composite anode active material. Because the fibrous carbon is on (e.g., fixed on) the composite anode active material, a substantially uniform and stable three-dimensional conductive network may be formed among the plurality of composite anode active materials. Accordingly, the high rate characteristics of a lithium battery including the composite anode active material including the second carbonaceous material may be improved.
Referring to
In one or more embodiments, the aspect ratio of the second carbonaceous material may be 10 or more or 20 or more. In some embodiments, the aspect ratio of the second carbonaceous material may be, for example, about 10 to about 100,000, about 10 to about 80,000, about 10 to about 50,000, about 10 to about 10,000, about 10 to about 5000, about 10 to about 1000, about 10 to about 500, about 10 to about 100, or about 10 to about 50. The aspect ratio of the second carbonaceous material may be, for example, the ratio of the length of the major axis passing through the center of the second carbonaceous material to the length of the minor axis passing through the center of the second carbonaceous material and perpendicular to the major axis, for example, the diameter of the second carbonaceous material.
In one or more embodiments, the diameter of the second carbonaceous material may be, for example, 50 nm or less, 30 nm or less, 20 nm or less, or 10 nm or less. In some embodiments, the diameter of the second carbonaceous material may be, for example, from about 1 nm to about 50 nm, from about 1 nm to about 30 nm, or about 1 nm to about 10 nm. When the diameter of the second carbonaceous material is excessively large, the absolute number of strands per volume may be decreased; thus the effect of reducing internal resistance may be insignificant. When the diameter of the second carbonaceous material is too small, uniform dispersion may be difficult.
In one or more embodiments, the length of the second carbonaceous material may be, for example, 1000 μm or less, 100 μm or less, 50 μm or less, 10 μm or less, 5 μm or less, 2 μm or less, 1 μm or less, 500 nm or less, or 300 nm or less. In some embodiments, the length of the second carbonaceous material may be, for example, about 100 nm to about 1000 μm, about 100 nm to about 500 μm, about 100 nm to about 100 μm, about 100 nm to about 50 μm, about 100 nm to about 10 μm, about 100 nm to about 5 μm, about 100 nm to about 2 μm, about 100 nm to about 1 μm, about 100 nm to about 500 nm, or 100 nm to about 300 nm. In some embodiments, the length of the second carbonaceous material may be, for example, about 500 nm to about 1000 μm, about 500 nm to about 500 μm, about 500 nm to about 100 μm, about 500 nm to about 50 μm, about 500 nm to about 10 μm, about 500 nm to about 5 μm, or about 500 nm to about 2 μm. As the length of the second carbonaceous material is increased the internal resistance of the electrode may decrease. When the length of the second carbonaceous material is too short, it may be difficult to provide an effective conductive path.
In one or more embodiments, the second carbonaceous material may include, for example, carbon nanofibers, carbon nanotubes, or a combination thereof.
The carbon nanotube may include, for example, a carbon nanotube primary structure, a carbon nanotube secondary structure formed by aggregation of a plurality of carbon nanotube primary particles, or a combination thereof.
The carbon nanotube primary structure may be one carbon nanotube unit. The carbon nanotube unit has a graphite sheet in a cylindrical shape with a nano-size diameter, and has an sp2 binding structure. According to the bending angle and structure of the graphite surface, the characteristics of the conductor or the characteristics of the semiconductor may be exhibited. Carbon nanotube units may be classified as single-walled carbon nanotube (SWCNT), double-walled carbon nanotube (DWCNT), and multi-walled carbon nanotube (MWCN), depending on the number of bonds forming the wall. The thinner the wall thickness of the carbon nanotube unit, the lower the resistance.
Carbon nanotube units may be classified as single-walled carbon nanotube (SWCNT), double-walled carbon nanotube (DWCNT), multi-walled carbon nanotube (MWCN) or a combination thereof. The diameter of the carbon nanotube primary structure may be, for example, 1 nm or more or 2 nm or more. The diameter of the carbon nanotube primary structure may be, for example, 20 nm or less or 10 nm or less. The diameter of the carbon nanotube primary structure may be, for example, about 1 nm to about 20 nm, about 1 nm to about 15 nm, or about 2 nm to about 10 nm. The length of the carbon nanotube primary structure may be, for example, 100 nm or more or 200 nm or more. The length of the carbon nanotube primary structure may be, for example, 2 μm or less, 1 μm or less, 500 nm or less, or 300 nm or less. The length of the carbon nanotube primary structure may be, for example, about 100 nm to about 2 μm, about 100 nm to about 1 μm, about 100 nm to about 500 nm, about 100 nm to about 400 nm, about 100 nm to about 300 nm, or 200 nm to about 300 nm. The diameter and length of the carbon nanotube primary structure may be measured from a scanning electron microscope (SEM) image. Alternatively, the diameter and/or length of the carbon nanotube primary structure may be measured by a laser diffraction method.
The carbon nanotube secondary structure is a structure formed by assembling the carbon nanotube primary structures to form a bundle-type or kind or rope-type or kind carbon nanotube in whole or in part. The carbon nanotube secondary structure may include, for example, a bundle-type or kind carbon nanotube, a rope-type or kind carbon nanotube, or a combination thereof. The diameter of the carbon nanotube secondary structure may be, for example, 2 nm or more or 3 nm or more. The diameter of the carbon nanotube secondary structure may be, for example, 50 nm or less, 30 nm or less, or 10 nm or less. The diameter of the carbon nanotube secondary structure may be, for example, about 2 nm to about 50 nm, about 2 nm to about 30 nm, or about 2 nm to about 20 nm. The length of the carbon nanotube secondary structure may be, for example, 500 nm or more, 700 nm or more, 1 μm or more, or 10 μm or more. The length of the carbon nanotube secondary structure may be, for example, 1000 μm or less, 500 μm or less, or 100 μm or less. The length of the carbon nanotube secondary structure may be, for example, about 500 nm to about 1000 μm, about 500 nm to about 500 μm, about 500 nm to about 200 μm, about 500 nm to about 100 μm, or about 500 nm to about 50 μm. The diameter and length of the carbon nanotube secondary structure may be measured from an image or an optical microscope. Alternatively, the diameter and/or length of the carbon nanotube secondary structure may be measured by a laser diffraction method. In some embodiments, the carbon nanotube secondary structure may be utilized for the preparation of a composite anode active material after being converted into carbon nanotube primary structure by dispersion of the same in a solvent and/or the like.
In one or more embodiments, the amount of the second carbonaceous material may be, for example, about 0.1 wt % to about 50 wt %, about 1 wt % to about 40 wt %, or about 5 wt % to about 30 wt %, based on the total weight of the first carbonaceous material and the second carbonaceous material. Because the composite anode active material includes these amount ranges of the first carbonaceous material and the second carbonaceous material, a conduction path is more effectively secured in the composite positive active material, so that the internal resistance of the composite anode active material may be further reduced. As a result, the cyclic characteristics of the lithium battery including the composite anode active material may be further improved. In some embodiments, the amount of the second carbonaceous material may be, for example, about 0.001 wt % to about 5 wt %, about 0.01 wt % to about 3 wt %, or about 0.01 wt % to about 1 wt %, based on the total weight of the composite anode active material. Because the composite anode active material includes these amount ranges of the second carbonaceous material, a conduction path is secured in the composite anode active material, so that the internal resistance of the composite anode active material may be further reduced. As a result, the cyclic characteristics of the lithium battery including the composite anode active material may be further improved.
In one or more embodiments, the specific surface area of the composite anode active material may be, for example, about 1 m2/g to about 100 m2/g, about 1 m2/g to about 50 m2/g, or about 1 m2/g to about 30 m2/g. Because the composite anode active material has these ranges of specific surface area, cyclic characteristics of a lithium battery utilizing the composite anode active material may be further improved. In one or more embodiments, the average particle diameter (D50) of the composite anode active material may be, for example, about 1 μm to about 30 μm, about 3 μm to about 20 μm, or about 5 μm to about 15 μm. In one or more embodiments, the particle diameter (D10) of the composite anode active material may be, for example, about 0.1 μm to about 10 μm, about 0.5 μm to about 10 μm, or about 1 μm to about 10 μm. In one or more embodiments, the particle diameter (D90) of the composite anode active material may be, for example, about 10 μm to about 50 μm, about 10 μm to about 30 μm, or about 10 μm to about 25 μm. When the composite anode active material has these ranges of an average particle diameter (D50), particle diameter (D10), and/or particle diameter (D90), cyclic characteristics of a lithium battery including the composite anode active material may be further improved.
In one or more embodiments, an anode is provided to include the composite anode active material. When the anode includes the composite anode active material, improved cyclic characteristics and reduced volume change may be provided.
In one or more embodiments, the anode may be prepared by utilizing, for example, a wet method. The anode is manufactured by the following example method, but embodiments of the present disclosure are not necessarily limited to this method and may be adjusted according to required conditions.
First, an anode active material composition is prepared by mixing the composite anode active material, a conductive material, a binder, and a solvent. The prepared anode active material composition is coated directly on a copper current collector and dried to prepare an anode plate having an anode active material layer. In some embodiments, a film obtained by casting the anode active material composition on a separate support and then exfoliating the composition from the support is laminated on a copper current collector to form an anode plate including an anode active material layer.
As the conductive material, carbon black, graphite fine particles, natural graphite, artificial graphite, acetylene black, Ketjen black, carbon fiber; carbon nanotubes; metal powder, metal fiber or metal tube of, for example, copper, nickel, aluminum, or silver; and/or conductive polymers such as polyphenylene derivatives may be utilized, but embodiments of the present disclosure are not limited thereto. Any conductive material may be utilized as long as it is utilized in the art.
As the binder, vinylidene fluoride/hexafluoropropylene copolymer, polyvinylidene fluoride, polyacrylonitrile, polymethyl methacrylate, polytetrafluoroethylene (PTFE), a mixture of these polymers, styrene butadiene rubber-based polymer, polyacrylic acid, lithium-substituted polyacrylic acid, polyamideimide, polyimide, etc. may be utilized, but embodiments of the present disclosure are not limited thereto, and any one utilized in the art may be utilized.
As the solvent, N-methylpyrrolidone (NMP), acetone, water, etc. are utilized, but embodiments of the present disclosure are not limited thereto, and any solvent utilized in the art may be utilized.
In some embodiments, a plasticizer or a pore former may be further added to the anode active material composition to form pores inside the electrode plate.
The amounts of the composite anode active material, the conductive material, the binder, and the solvent utilized in the anode may be such levels that are normally utilized in lithium batteries. Depending on the utilization and configuration of the lithium battery, one or more of the conductive materials, the binder, and the solvent may not be provided.
In one or more embodiments, the amount of the binder included in the anode may be about 0.1 wt % to about 10 wt % or about 0.1 wt % to about 5 wt % based on the total weight of the anode active material layer. In one or more embodiments, the amount of the composite anode active material included in the anode may be about 0.1 wt % to about 99 wt %, about 0.1 wt % to about 90 wt %, about 0.1 wt % to about 50 wt %, about 0.1 wt % to about 30 wt %, about 0.1 wt % to about 20 wt %, or about 0.1 wt % to about 10 wt %, based on the total weight of the anode active material layer.
In one or more embodiments, the anode may additionally include an anode active material of the related art other than the composite anode active material.
The anode active material of the related art may include, for example, at least one selected from among lithium metal, a lithium-alloyable metal, a transition metal oxide, a non-transition metal oxide, and a carbonaceous material, but embodiments of the present disclosure are not limited thereto. Any material may be utilized herein as long as it is utilized as an anode active material for a lithium battery in the art.
Non-limiting examples of the lithium-alloyable metal may include silicon (Si), tin (Sn), aluminum (Al), germanium (Ge), lead (Pb), bismuth (Bi), antimony (Sb), an Si—X alloy (X is an alkali metal, an alkali-earth metal, a Group 13 element, a Group 14 element, a transition metal, a rare earth element, or a combination thereof, not Si), and an Sn—X alloy (X is an alkali metal, an alkali-earth metal, a Group 13 element, a Group 14 element, a transition metal, a rare earth element, or a combination thereof, not Sn). Element X may be, for example, magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), radium (Ra), scandium (Sc), yttrium (Y), titanium (Ti), zirconium (Zr), hafnium (Hf), rutherfordium (Rf), vanadium (V), niobium (Nb), tantalum (Ta), dubnium (db), chromium (Cr), molybdenum (Mo), tungsten (W), seaborgium (Sg), technetium (Tc), rhenium (Re), bohrium (Bh), iron (Fe), lead (Pb), ruthenium (Ru), osmium (Os), hassium (Hs), rhodium (Rh), iridium (Ir), palladium (Pd), platinum (Pt), copper (Cu), silver (Ag), gold (Au), zinc (Zn), cadmium (Cd), boron (B), aluminum (Al), gallium (Ga), tin (Sn), indium (In), titanium (Ti), germanium (Ge), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), sulfur (S), selenium (Se), tellurium (Te), polonium (Po), or a combination thereof.
The transition metal oxide may be, for example, lithium titanium oxide, vanadium oxide, lithium vanadium oxide and/or the like.
The non-transition metal oxide may be, for example, SnO2 and/or the like.
The carbonaceous material may be, for example, crystalline carbon, amorphous carbon, or a mixture thereof. The crystalline carbon may be, for example, graphite such as amorphous, plate-like, flake-like, spherical (e.g., substantially spherical), or fibrous natural graphite or artificial graphite. The amorphous carbon may be, for example, soft carbon (low-temperature fired carbon), hard carbon, mesophase pitch carbide, and/or fired coke.
In some embodiments, the total amount of the composite anode active material and the anode active material of the related art included in the anode may be about 80 wt % to about 99 wt %, about 90 wt % to about 99 wt %, or about 90 wt % to about 95 wt %, based on the total weight of the anode active material layer.
In one or more embodiments, the anode may be a dry anode which is prepared by a dry method.
In one or more embodiments, the dry anode may include a dry composite anode active material, a dry conductive material, and a dry binder. The dry composite anode active material may include a core and a shell on (e.g., located on) and conformed to the surface of the core, wherein the core may include a silicon-containing structure, a silicon-containing compound, or a combination thereof, the shell may include at least one first metal oxide represented by Formula MaOb (0<a≤3, 0<b<4, and when a is 1, 2, or 3, b is not an integer) and a first carbonaceous material, and the first metal oxide may be placed in the first carbonaceous material (e.g., in a matrix of the first carbonaceous material), and M is at least one metal selected from among Group 2 to Group 13, Group 15, and Group 16 of the Periodic Table of Elements.
In one or more embodiments, a method of preparing a dry anode may include: preparing a dry mixture by dry mixing the dry composite anode active material, a dry conductive material, and a dry binder; providing an anode current collector; disposing a middle layer on one side of the anode current collector; and placing the dry mixture on the middle layer and roll-pressing the same to arrange the anode active material layer on the one surface of the anode current collector.
First, a dry mixture is prepared by dry mixing a dry composite anode active material, a dry conductive material, and a dry binder. Dry mixing may refer to mixing while a process solvent is not included/provided. The process solvent may be, for example, solvents utilized in the preparation of electrode slurries. The process solvent may be, for example, water, N-Methyl-2-pyrrolidone (NMP), etc., but embodiments of the present disclosure are not limited thereto, and any process solvent that is utilized in the preparation of an electrode slurry, may not be utilized herein. Dry mixing may be performed utilizing a stirrer at the temperature of, for example, 25° C. to 65° C. Dry mixing may be performed utilizing a stirrer at a rotation speed of, for example, about 10 rpm to about 10000 rpm, or about 100 rpm to about 10000 rpm. Dry mixing may be performed utilizing a stirrer, for example, for about 1 minute to about 200 minutes, or about 1 minute to about 150 minutes. The composite anode active material may be a dry composite anode active material.
In some embodiments, dry mixing may be performed, for example, one or more times. First, a first mixture may be prepared by first dry mixing a dry composite anode active material, a dry conductive material, and a dry binder. The first dry mixing may be performed, for example, at a temperature of 25° C. to 65° C., at a rotation speed of 2000 rpm or less, and for 15 minutes or less. The first dry mixing may be performed, for example, at a temperature of about 25° C. to about 65° C., at a rotation speed of about 500 rpm to about 2000 rpm, for about 5 minutes to about 15 minutes. The dry composite anode active material, the dry conductive material, and the dry binder may be uniformly mixed by the first dry mixing. Subsequently, a second mixture may be prepared by second dry mixing a dry composite anode active material, a dry conductive material, and a dry binder. The second dry mixing may be performed, for example, at a temperature of 25° C. to 65° C., at a rotation speed of 4000 rpm or more, and for 10 minutes or more. The second dry mixing may be performed, for example, at a temperature of 25° C. to 65° C., at a rotation speed of about 4000 rpm to about 9000 rpm, for 10 minutes to 60 minutes. In some embodiments, a dry mixture including a fibrillated dry binder may be obtained by second dry mixing.
In some embodiments, the stirrer may be, for example, a kneader. The stirrer may include: for example, a chamber; one or more rotating shafts which are located inside the chamber and rotate; and a blade rotatably coupled to the rotation shafts and located in the longitudinal direction of the rotation shafts. The blade may be, for example, one or more selected from among a ribbon blade, a sigma blade, a jet (Z) blade, a dispersion blade, and a screw blade. By including the blade, it is possible to prepare a dough-like mixture by effectively mixing the dry anode composite active material, the dry conductive material, and the dry binder without a solvent.
In one or more embodiments, the prepared dry mixture may be introduced into an extrusion device and extruded in the form of a sheet. The pressure at the time of extrusion may be, for example, about 4 MPa to about 100 MPa, or about 10 MPa to about 90 MPa. The obtained sheet-form extrudate may be a sheet for an anode active material layer.
As the dry conductive material, carbon black, graphite fine particles, natural graphite, artificial graphite, acetylene black, Ketjen black, carbon fiber; carbon nanotubes; metal powder, metal fiber or metal tube of, for example, copper, nickel, aluminum, or silver; and/or conductive polymers such as polyphenylene derivatives may be utilized, but embodiments of the present disclosure are not limited thereto. Any conductive material may be utilized as long as it is utilized in the art. The conductive material may be, for example, a carbonaceous conductive material. The dry conductive material may be a conductive material that has not been in contact with a process solvent.
Non-limiting examples of the dry binder may include vinylidene fluoride/hexafluoropropylene copolymer, polyvinylidene fluoride, polyacrylonitrile, polymethylmethacrylate, polytetrafluoroethylene (PTFE), mixtures of these polymers, and/or styrene butadiene A rubber-based polymer, but embodiments of the present disclosure are not necessarily limited thereto, and any material that is utilized in the art may be utilized herein. In some embodiments, the dry binder may be, for example, polytetrafluoroethylene (PTFE). A dry binder may be a binder that has not been in contact with a process solvent.
In some embodiments, a plasticizer or a pore former may be further added to the dry mixture to form pores inside the anode active material layer.
In some embodiments, the amounts of the dry composite anode active material, the dry conductive material, and the dry binder utilized in the anode active material layer are in substantially the same ranges as those applied for the wet anode.
Next, an anode current collector is provided. The anode current collector may be, for example, aluminum foil.
Then, a middle layer is disposed on at least one surface of the anode current collector. The middle layer may include a carbonaceous conductive material and a binder. In some embodiments, the middle layer may not be provided.
Then, the prepared anode active material layer sheet is arranged on the middle layer and roll-pressed to dispose the anode active material layer on the at least one surface of the anode current collector, thereby completing the preparation of an anode. The middle layer may be between the anode current collector and the anode active material layer. The roll-pressing may be, for example, a roll press, a flat press, and/or the like, but embodiments of the present disclosure are not necessarily limited thereto. The pressure at the time of roll-pressing may be, for example, about 0.1 ton/cm2 to about 10.0 ton/cm2, but embodiments of the present disclosure are not limited to this range. When the pressure during roll-pressing is excessively increased, the anode current collector may crack. When the pressure during roll-pressing is too low, the binding force between the anode current collector and the anode active material layer may be reduced.
In one or more embodiments, a lithium battery is provided to include an anode including the composite anode active material.
Due to the inclusion of an anode including the composite anode active material, the lithium battery may provide improved cyclic characteristics and reduced volume change.
In one or more embodiments, the lithium battery may be manufactured, for example, by the following exemplary method, but embodiments of the present disclosure are not necessarily limited to this method and may be adjusted according to required conditions.
First, an anode is manufactured according to the method of manufacturing the anode.
Next, a cathode active material composition in which a cathode active material, a conductive material, a binder, and a solvent are mixed, is prepared. The cathode active material composition is coated directly on an aluminum current collector and then dried to prepare a cathode plate. In some embodiments, the cathode active material composition may be cast on a separate support, and then the film exfoliated from the support may be laminated on an aluminum current collector to manufacture a cathode plate.
As a cathode active material, any lithium-containing metal oxide may be utilized without limitation as long as it is utilized in the art. In some embodiments, the cathode active material may be, for example, one or more types or kinds of a complex oxide of lithium and a metal selected from among cobalt, manganese, nickel, and combinations thereof. In some embodiments, the cathode active material may include, for example, at least one selected from the group consisting of lithium cobalt oxide, lithium nickel cobalt manganese oxide, lithium nickel cobalt aluminum oxide, lithium iron phosphate, lithium manganese oxide, and combinations thereof, but embodiments of the present disclosure are not necessarily limited thereto. Any material that is utilized as the cathode active material for a lithium battery may be utilized herein.
In one or more embodiments, the cathode active material may be, for example, a compound represented by one selected from among the following formulae: LiaA1-bBbD2 (where 0.90≤a≤1.8, and 0≤b≤0.5); LiaE1-bBbO2-cDc (where 0.90≤a≤1.8, 0≤b≤0.5, and 0≤c≤0.05); LiE2-bBbO4-cDc (where 0≤b≤0.5, and 0≤c≤0.05); LiaNi1-b-cCobBcDa (where 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<a≤2); LiaNi1-b-cCobBcO2-aFa (where 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<a<2); LiaNi1-b-cCobBcO2-aF2 (where 0.90≤a≤1.8, 0<5 b<≤0.5, 0≤c≤0.05, and 0<a<2); LiaNi1-b-cMnbBcDa (where 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<a≤2); LiaNi1-b-cMnbBcO2-aFa (where 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<a<2); LiaNi1-b-cMnbBcO2-aF2 (where 0.90≤a≤1.8, 0≤b≤0.5, 0≤c≤0.05, and 0<a<2); LiaNibEcGdO2 (where 0.90≤a≤1.8, 0≤b≤0.9, 0≤c≤0.5, and 0.001≤d 0.1); LiaNibCocMndGeO2 (where 0.90≤a≤1.8, 0≤a≤0.9, 0≤c<≤0.5, 0≤d 50.5, and 0.001≤e 0.1); LiaNiGbO2 (where 0.90≤a≤1.8 and 0.001≤b≤0.1); LiaCoGbO2 (where ≤a≤1.8 and 0.001≤b≤0.1); LiaMnGbO2 (where 0.90≤a≤1.8 and 0.001≤b 0.1); LiaMn2GbO4 (where 0.90≤a≤1.8 and 0.001≤b≤0.1); QO2; QS2; LiQS2; V2O5; LiV2O5; LiIO2; LiNiVO4; Li(3-f)J2(PO4)3 (0≤f≤2); Li(3-f)Fe2(PO4)3 (0≤f≤2); and LiFePO4.
In Formulas above, A may be Ni, Co, Mn, or a combination thereof; B may be Al, Ni, Co, Mn, Cr, Fe, Mg, Sr, V, a rare earth element, or a combination thereof; D may be oxygen (O), fluorine (F), sulfur (S), phosphorous (P), or a combination thereof; E may be Co, Mn, or a combination thereof; F may be fluorine (F), sulfur (S), phosphorous (P), or a combination thereof; G may be Al, Cr, Mn, Fe, Mg, La, Ce, Sr, V, or a combination thereof; Q may be Ti, Mo, Mn, or a combination thereof; I may be Cr, V, Fe, Sc, Y, or a combination thereof; and J may be V, Cr, Mn, Co, Ni, Cu, or a combination thereof.
In some embodiments, a compound in which a coating layer is provided on the surface of the above-described compound may be utilized, and a mixture of the above-described compound and the compound provided with the coating layer may also be utilized. The coating layer provided on the surface of the above-described compound may include a coating element compound such as oxide of a coating element, hydroxide of a coating element, oxyhydroxide of a coating element, oxycarbonate of a coating element, and/or hydroxycarbonate of a coating element. The compound constituting the coating layer is amorphous or crystalline. The coating element included in the coating layer may be Mg, Al, Co, K, Na, Ca, Si, Ti, V, Sn, Ge, Ga, B, As, Zr, or a mixture thereof. The method of forming the coating layer may selected within a range that does not adversely affect the physical properties of the cathode active material. The coating method may be, for example, spray coating, dipping method, and/or the like. A more detailed description of the coating method will not be provided herein because it should be well understood by those in the art.
In one or more embodiments, the cathode active material may be, for example, LiNiO2, LiCoO2, LiMnxO2x (x=1, 2), LiNi1-xMnxO2 (0<x<1), LiNi1-x-yCoxMnyO2 (0≤x≤0.5, 0≤y≤0.5), LiFeO2, V2O5, TiS, MoS, and/or the like.
In one or more embodiments, the cathode active material may be, for example, LiaNixCoyMzO2-bAb (1.0≤a≤1.2, 0≤b≤0.2, 0.8≤x<1, 0≤y≤0.3, 0<z≤0.3, x+y+z=1, M is at least one selected from among manganese (Mn), niobium (Nb), vanadium (V), magnesium (Mg), gallium (Ga), silicon (Si), tungsten (W), molybdenum (Mo), iron (Fe), chromium (Cr), at least one selected from the group consisting of copper (Cu), zinc (Zn), titanium (Ti), aluminum (Al) and boron (B), and A may be fluorine (F), sulfur (S), chlorine (CI), bromine (Br), or a combination thereof), LiNixCoyMnzO2 (0.8≤x≤0.95, 0<y≤0.2, 0<z≤0.2, and x+y+z=1), LiNixCoyAlzO2 (0.8≤x≤0.95, 0<y≤0.2, 0<z≤0.2, and x+y+z=1), LiNixCoyAlvMnwO2 (0.8≤x≤0.95, 0≤y≤0.2, 0<v≤0.2, 0<w≤0.2, and x+y+v+w=1), and/or LiaNixMnyM′zO2-bAb (1.0≤a≤1.2, 0≤b≤0.2, 0<x≤0.3, 0.5≤y<1, 0<z≤0.3, and x+y+z=1, M′ may be cobalt (Co), niobium (Nb), vanadium (V), magnesium (Mg), gallium (Ga), silicon (Si), tungsten (W), molybdenum (Mo), iron (Fe), chromium (Cr), copper (Cu), zinc (Zn), titanium (Ti), aluminum (Al), boron (B), or a combination thereof, and A may be fluorine (F), sulfur (S), chlorine (CI), bromine (Br), or a combination thereof).
In regard to the cathode active material composition, the conductive material, the binder, and the solvent which are utilized for the anode active material, may be utilized herein. In some embodiments, pores may be formed in an electrode plate by further adding a plasticizer to the cathode active material composition and/or the anode active material composition.
The amounts of the cathode active material, the conductive material, the binder, and the solvent are such levels that are normally utilized in lithium batteries. In some embodiments, at least one selected from among the conductive material, the binder, and the solvent may not be provided depending on the utilization and configuration of a lithium battery.
In one or more embodiments, the amount of the binder included in the cathode may be, for example, about 0.1 wt % to about 10 wt % or about 0.1 wt % to about 5 wt %, based on the total weight of the cathode active material layer. In one or more embodiments, the amount of the cathode active material included in the cathode may be, for example, about 70 wt % to about 99 wt %, about 90 wt % to about 99 wt %, or about 95 wt % to about 99 wt %, based on the total weight of the cathode active material layer.
Next, a separator to be inserted between the cathode and the anode is prepared.
Any separator may be utilized as long as it is commonly utilized in lithium batteries. As the separator, for example, a separator having low resistance to ion movement of an electrolyte and an excellent or suitable electrolyte-wetting ability is utilized. In some embodiments, the separator may be a non-woven fabric or a woven fabric including at least one selected from among fiberglass, polyester, Teflon, polyethylene, polypropylene, polytetrafluoroethylene (PTFE), and a combination thereof. For a lithium-ion battery, for example, a rollable separator including polyethylene, polypropylene, and/or the like may be utilized, and for a lithium-ion polymer battery, a separator having excellent or suitable organic electrolyte impregnation ability may be utilized.
The separator is manufactured by the following exemplary method, but embodiments of the present disclosure is not necessarily limited to this method and may be adjusted according to required conditions.
First, a polymer resin, a filler, and a solvent are mixed to prepare a separator composition. The separator composition may be directly applied and dried on an electrode to form a separator. In some embodiments, a film obtained by casting and drying the separator composition on a support and then separating the composition from the support is laminated on the electrode to form a separator.
The polymer utilized for manufacturing the separator is not particularly limited, and any polymer may be utilized as long as it is utilized for the binder of an electrode plate may be utilized. For example, as the polymer, a vinylidene fluoride/hexafluoropropylene copolymer, polyvinylidene fluoride (PVDF), polyacrylonitrile, polymethyl methacrylate, or a mixture thereof may be utilized.
Next, an electrolyte is prepared.
The electrolyte may be, for example, an organic electrolyte. The organic electrolyte is prepared, for example, by dissolving a lithium salt in an organic solvent.
As the organic solvent, any organic solvent may be utilized as long as it is utilized in the art. In some embodiments, the organic solvent may be, for example, propylene carbonate, ethylene carbonate, fluoroethylene carbonate, butylene carbonate, dimethyl carbonate, diethyl carbonate, methyl ethyl carbonate, methyl propyl carbonate, ethyl propyl carbonate, methyl isopropyl carbonate, dipropyl carbonate, dibutyl carbonate, benzonitrile, acetonitrile, tetrahydrofuran, 2-methyltetrahydrofuran, γ-butyrolactone, dioxolane, 4-methyldioxolane, N,N-dimethylformamide, dimethylacetamide, dimethylsulfoxide, dioxane, 1,2-dimethoxyethane, sulfolane, dichloroethane, chlorobenzene, nitrobenzene, diethylene glycol, dimethyl ether, or a mixture thereof.
As the lithium salt, any lithium salt may be utilized as long as it is utilized in the art. In some embodiments, the lithium salt may be, for example, LiPF6, LiBF4, LiSbF6, LiAsF6, LiClO4, LiCF3SO3, Li(CF3SO2)2N, LiC4F9SO3, LiAlO2, LiAICI4, LiN(CXF2x+1SO2)(CyF2y+1SO2) (1≤x≤20, 1≤y≤20), LiCl, LiI, or a mixture thereof. In some embodiments, the electrolyte may be a solid electrolyte. The solid electrolyte may be, for example, boron oxide or lithium oxynitride, but embodiments of the present disclosure are not limited thereto. Any solid electrolyte may be utilized as long as it is utilized in the art. The solid electrolyte may be formed on the anode by a method such as sputtering, or a separate solid electrolyte sheet is laminated on the anode.
In some embodiments, the solid electrolyte may be, for example, an oxide-based solid electrolyte or a sulfide-based solid electrolyte.
The solid electrolyte may be, for example, an oxide-based solid electrolyte. The oxide-based solid electrolyte may be one or more selected from among Li1+x+yAlxTi2-xSiyP3-yO12 (0<x<2 and 0≤y<3), BaTiO3, Pb(Zr,Ti)O3 (PZT), Pb1-xLaxZr1-y TiyO3 (PLZT) (O≤x<1, O≤y<1), Pb(Mg3Nb2/3)O3—PbTiO3 (PMN-PT), HfO2, SrTiO3, SnO2, CeO2, Na2O, MgO, NiO, CaO, BaO, ZnO, ZrO2, Y2O3, Al2O3, TiO2, SiO2, Li3PO4, LixTiy(PO4)3 (0<x<2 and 0<y<3), LixAlyTiz(PO4)3 (0<x<2, 0<y<1, and 0<z<3), Li1+x+y(Al, Ga)x(Ti, Ge)2-xSiyP3-yO12 (0≤x≤1 and 0≤y≤1), LixLayTiO3 (0<x<2 and 0<y<3), Li2O, LiGH, Li2CO3, LiAlO2, Li2O—Al2O3—SiO2—P2O5—TiO2—GeO2, and Li3+xLa3M2O12 (M=Te, Nb, or Zr, and x is an integer from 1 to 10). The solid electrolyte is manufactured by sintering. For example, the oxide-based solid electrolyte may be a Garnet-type solid electrolyte selected from among Li7La3Zr2O12 (LLZO) and Li3+xLa3Zr2-aMaO12 (M doped LLZO, M=Ga, W, Nb, Ta, or Al, and x is an integer from 1 to 10).
The sulfide-based solid electrolyte may include, for example, lithium sulfide, silicon sulfide, phosphorus sulfide, boron sulfide, or a combination thereof. In some embodiments, sulfide-based solid electrolyte particles may include Li2S, P2S5, SiS2, GeS2, B2S3, or a combination thereof. In some embodiments, the sulfide-based solid electrolyte particles may be Li2S and/or P2S5. Sulfide-based solid electrolyte particles have higher lithium ion conductivity than other inorganic compounds. For example, in some embodiments, the sulfide-based solid electrolyte may include Li2S and P2S5. When a sulfide solid electrolyte material constituting the sulfide-based solid electrolyte includes Li2S—P2S5, the mixing molar ratio of Li2S to P2S5 may be, for example, in the range of about 50:50 to about 90:10. In some embodiments, an inorganic solid electrolyte which is prepared by adding Li3PO4, halogen, a halogen compound, Li2+2xZn1-xGeO4 (“LISICON”, 0≤x<1), Li3+yPO4-xNx (“LIPON”, 0<x<4, 0<y<3), Li3.25Ge0.25P0.75S4 (“ThioLISICON”), and/or Li2O—Al2O3—TiO2—P2O5 (“LATP”) to the inorganic solid electrolyte of Li2S—P2S5, SiS2, GeS2, B2S3, or a combination thereof, may be utilized as a sulfide solid electrolyte. Non-limiting examples of the sulfide solid electrolyte material may include Li2S—P2S5; Li2S—P2S5—LiX (X=halogen element); Li2S—P2S5—Li2O; Li2S—P2S5—Li2O—LiI; Li2S—SiS2; Li2S—SiS2—LiI; Li2S—SiS2—LiBr; Li2S—SiS2—LiCl; Li2S—SiS2—B2S3—LiI; Li2S—SiS2—P2S5—LiI; Li2S—B2S3; Li2S—P2S5—ZmSn (0<m<10, 0<n<10, Z═Ge, Zn, or Ga); Li2S—GeS2; Li2S—SiS2—Li3PO4; and/or Li2S—SiS2-LipMOq (0<p<10, 0<q<10, M=P, Si, Ge, B, Al, Ga, or In). In this regard, the sulfide solid electrolyte material may be prepared by treating the raw starting material (for example, Li2S, P2S5, etc.) of the sulfide solid electrolyte material by a melt quenching method, a mechanical milling method, etc. Also, a calcination process may be performed after the treatment. The sulfide-based solid electrolyte may be amorphous, crystalline, or a mixture thereof.
Referring to
Referring to
Referring to
A pouch-type or kind lithium battery corresponds to a case where a pouch is utilized as a battery case for each of the lithium batteries of
Because the lithium battery has excellent or suitable lifetime characteristics and high-rate characteristics, it is utilized in electric vehicles (EVs). For example, the lithium battery may be utilized in hybrid vehicles such as plug-in hybrid electric vehicles (PHEVs). Further, the lithium battery may be utilized in fields where a large amount of power storage is required. For example, the lithium battery may be utilized in electric bicycles, power tools, and/or the like.
In one or more embodiments, a plurality of lithium batteries may be stacked to form a battery module, and a plurality of battery modules may form a battery pack. Such a battery pack may be utilized in any device requiring high capacity and high output. For example, the battery pack may be utilized in notebooks, smart phones, electric vehicles, and/or the like. The battery module may include, for example, a plurality of batteries and a frame for holding the same. The battery pack may include, for example, a plurality of battery modules and a bus bar connecting the same. The battery module and/or battery pack may further include a cooling device. A plurality of battery packs may be controlled by a battery management system. The battery management system may include a battery pack and a battery control device connected to the battery pack.
In one or more embodiments, a method of preparing a composite anode active material is provided to include: providing a silicon-containing anode active material such as a silicon-containing structure, a silicon-containing compound, or a combination thereof; providing a composite; and mechanically milling a silicon-containing structure, a silicon-containing compound, or a combination thereof and the composite, wherein the composite may include at least one first metal oxide represented by Formula MaOb (0<a≤3, 0<b<4, and when a is 1, 2, or 3, b is not an integer) and a first carbonaceous material, and the first metal oxide is placed within a matrix of the first carbonaceous material, and M is at least one metal selected from among Group 2 to Group 13, Group 15, and Group 16 of the Periodic Table of Elements.
In one or more embodiments, a silicon-containing anode active material is provided. The silicon-containing anode active material may be, for example, a silicon-containing structure, a silicon-containing compound, or a combination thereof. The silicon-containing structure may be, for example, the silicon composite structure described above. Silicon-containing compounds may be, for example, SiOx (0<x<2).
In some embodiments, the providing the composite may include, for example, supplying a reaction gas including a carbon source gas to a second metal oxide represented by Formula MaOc (0<a≤3, 0<c≤4, when a is 1, 2, or 3, c is an integer) and performing heat treatment thereon to form a composite, wherein M is at least one metal selected from among Group 2 to Group 13, Group 15, and Group 16 of the Periodic Table of Elements.
The carbon source gas may be a compound represented by Formula 1, or may be at least one mixed gas selected from among a compound represented by Formula 1, a compound represented by Formula 2, and an oxygen-containing gas represented by Formula 3.
CnH(2n+2−a)[OH]a Formula 1
in Formula 1, n is 1 to 20 and a is 0 or 1;
CnH2n Formula 2
in Formula 2, n is 2 to 6; and
CxHyOz Formula 3
in Formula 3, x is an integer of 0 or 1 to 20, y is an integer of 0 or 1 to 20, and z is 1 or 2.
The compound represented by Formula 1 and the compound represented by Formula 2 may each be at least one selected from among methane, ethylene, propylene, methanol, ethanol, and propanol. The oxygen-containing gas represented by Formula 3 may include, for example, carbon dioxide (CO2), carbon monoxide (CO), water vapor (H2O), or a mixture thereof.
After supplying a reaction gas including a carbon source gas to a second metal oxide represented by MaOc (0<a≤3, 0<c≤4, when a is 1, 2, or 3, c is an integer) and performing heat treatment, a cooling process utilizing at least one inert gas selected from among nitrogen, helium, and argon may be further performed. The cooling process may refer to a process of adjusting temperature to room temperature (about 20° C. to about 25° C.). The carbon source gas may include at least one inert gas selected from among nitrogen, helium, and argon.
In the method of manufacturing the composite, a process of growing a carbonaceous material, for example, graphene may be performed under one or more conditions according to a gas phase reaction.
In one or more embodiments, according to a first condition, for example, first, methane is supplied to a reactor provided with the second metal oxide represented by MaOc (0<a≤3, 0<c≤4, when a is 1, 2, or 3, c is an integer), and is heated to heat treatment temperature (T). The heating time up to heat treatment temperature (T) is about 10 minutes to about 4 hours, and the heat treatment temperature (T) is about 700° C. to about 1100° C. Heat treatment is performed at the heat treatment temperature (T) for reaction time. The reaction time is, for example, about 4 hours to about 8 hours. The resultant product of heat treatment is cooled to room temperature to prepare a composite. The time taken to perform the process of cooling the resultant product from the heat treatment temperature to room temperature is, for example, about 1 hour to 5 hours.
In one or more embodiments, according to a second condition, for example, first, hydrogen is supplied to a reactor provided with the second metal oxide represented by MaOc (0<a≤3, 0<c≤4, when a is 1, 2, or 3, c is an integer), and is heated to heat treatment temperature (T). The heating time up to heat treatment temperature (T) is about 10 minutes to about 4 hours, and the heat treatment temperature (T) is about 700° C. to about 1100° C. After heat treatment is performed at the heat treatment temperature (T) for the set or predetermined reaction time, methane gas is supplied, and heat treatment is performed for a residual (remaining) reaction time. The residual reaction time is, for example, about 4 hours to about 8 hours. The resultant product of heat treatment is cooled to room temperature to prepare a composite. Nitrogen is supplied during the process of cooling the resultant product. The time taken to perform the process of cooling the resultant product from the heat treatment temperature to room temperature is, for example, about 1 hour to 5 hours.
In one or more embodiments, according to a third condition, for example, first, hydrogen is supplied to a reactor provided with the second metal oxide represented by MaOc (0<a≤3, 0<c≤4, when a is 1, 2, or 3, c is an integer), and is heated to heat treatment temperature (T). The heating time up to heat treatment temperature (T) is about 10 minutes to about 4 hours, and the heat treatment temperature (T) is about 700° C. to about 1100° C. After heat treatment is performed at the heat treatment temperature (T) for the set or predetermined reaction time, a mixed gas of methane and hydrogen is supplied, and heat treatment is performed for a residual (remaining) reaction time. The residual reaction time is, for example, about 4 hours to about 8 hours. The resultant product of heat treatment is cooled to room temperature to prepare a composite. Nitrogen is supplied during the process of cooling the resultant product. The time taken to perform the process of cooling the resultant product from the heat treatment temperature to room temperature is, for example, about 1 hour to 5 hours.
In the process of preparing the composite, when the carbon source gas includes water vapor, a composite having very excellent or suitable conductivity may be obtained. The amount of water vapor in the gas mixture is not limited, and is, for example, in some embodiments, about 0.01 vol % to about 10 vol % based on 100 vol % of the total carbon source gas. The carbon source gas may be, for example, methane; a mixed gas containing methane and an inert gas; or a mixed gas containing methane and an oxygen-containing gas.
In some embodiments, the carbon source gas may be, for example, methane; a mixed gas of methane and carbon dioxide; or a mixed gas of methane, carbon dioxide, and water vapor. The molar ratio of methane and carbon dioxide in the mixed gas of methane and carbon dioxide may be about 1:0.20 to about 1:0.50, about 1:0.25 to about 1:0.45, or about 1:0.30 to about 1:0.40. In a gas mixture of methane, carbon dioxide, and water vapor, the molar ratio of methane, carbon dioxide, and water vapor may be about 1:0.20 to 0.50:0.01 to 1.45, about 1:0.25 to 0.45:0.10 to 1.35, or about 1:0.30 to 0.40:0.50 to 1.0.
In some embodiments, the carbon source gas may be, for example, carbon monoxide or carbon dioxide. In some embodiments, the carbon source gas may be, for example, a mixed gas of methane and nitrogen. In the mixed gas of methane and nitrogen, the molar ratio of methane and nitrogen may be about 1:0.20 to 1:0.50, about 1:0.25 to 1:0.45, or about 1:0.30 to 1:0.40. In some embodiments, the carbon source gas may not include (e.g., may exclude) an inert gas such as nitrogen.
In one or more embodiments, a heat treatment pressure may be selected in consideration of the heat treatment temperature, the composition of the gas mixture, and the desired or suitable coating amount of carbon. The heat treatment pressure may be controlled by adjusting the amount of the inflowing gas mixture and the amount of the outflowing gas mixture. The heat treatment pressure may be, for example, 0.5 atm or more, 1 atm or more, 2 atm or more, 3 atm or more, 4 atm or more, or 5 atm or more.
In one or more embodiments, a heat treatment time may be selected in consideration of the heat treatment temperature, the heat treatment pressure, the composition of the gas mixture, and the desired or suitable coating amount of carbon. For example, the reaction time at the heat treatment temperature may be, for example, about 10 minutes to about 100 hours, about 30 minutes to about 90 hours, or about 50 minutes to about 40 hours. For example, as the heat treatment time increases, the amount of deposited carbon, for example, graphene (carbon), is increased, and thus the electrical properties of the composite may be improved. However, this tendency may not necessarily be proportional to time. For example, after a predetermined time has elapsed, carbon deposition, for example, graphene deposition, may no longer occur or the deposition rate may be low.
Through the gas phase reaction of the carbon source gas, even at a low temperature, a composite may be obtained by coating a substantially uniform carbonaceous material, for example, graphene on at least one selected from among a second metal oxide represented by MaOc (0<a≤3, 0<c≤4, and when a is 1, 2, or 3, c is an integer) and a reduction product thereof, that is, a first metal oxide represented by MaOb (0<a≤3, 0<b<4, a is 1, 2, or 3, and b is not an integer).
In one or more embodiments, the composite may include: a carbonaceous material matrix having at least one structure selected from among a spherical structure (e.g., a substantially spherical structure), a spiral structure in which a plurality of spherical structures (e.g., substantially spherical structures) are connected to each other, a cluster structure in which a plurality of spherical structures (e.g., substantially spherical structures) are aggregated with each other, and a sponge structure, for example, a graphene matrix; and at least one selected from among a first metal oxide represented by MaOb (0<a≤3, 0<b<4, a is 1, 2, or 3, and b is not an integer) and a second metal oxide represented by MaOc (0<a≤3, 0<c≤4, and when a is 1, 2, or 3, c is an integer), which is placed in the carbonaceous material matrix.
Next, a silicon-containing structure, a silicon-containing compound, or a combination thereof and the composite are mechanically milled. In the mechanically milling, the milling method is not particularly limited, and any method of the related art in which a silicon-containing structure, a silicon-containing compound, or a combination thereof is brought into contact with a composite and the resultant is pressed, may be utilized herein. In some embodiments, a Nobilta mixer may be utilized in the milling. The number of rotations of the mixer at the time of milling may be, for example, 2000 rpm or more, or 3000 rpm or more. The number of rotations of the mixer at the time of milling may be, for example, 4000 rpm or less. The number of rotations of the mixer at the time of milling may be, for example, from about 2000 rpm to about 4000 rpm, or from about 3000 rpm to about 4000 rpm.
When the milling speed is too low, the shear force applied to the silicon-containing structure, the silicon-containing compound, or a combination thereof and the composite is weak, so that it is difficult to make the silicon-containing structure, the silicon-containing compound, or a combination thereof, and the composite in the form of a composite. When the milling speed is too high, the composite may be formed for too short time, so that it is difficult to uniformly coat the composite on the silicon-containing structure and/or the silicon-containing compound to form a substantially uniform and substantially continuous shell. The milling time may be, for example, about 5 minutes to about 100 minutes, about 5 minutes to about 60 minutes, or about 5 minutes to about 30 minutes. When the milling time is too short, it is difficult to uniformly coat the composite on the silicon-containing structure and/or the silicon-containing compound to form a substantially uniform and substantially continuous shell. When the milling time is too long, production efficiency may be lowered. The amount of the composite may be 5 wt % or less, 4 wt % or less, 3 wt % or less, 2 wt % or less, or 1 wt % or less, based on the total weight of the silicon-containing anode active material and the composite. In some embodiments, the amount of the composite may be, for example, about 0.01 to about 5 wt %, about 0.01 to about 4 wt %, about 0.01 to about 3 wt %, about 0.1 to about 2 wt %, or about 0.1 to about 1 wt %, based on the total weight of the silicon-containing anode active material and the composite. For example, in some embodiments, the amount of the composite may be about 0.01 parts by weight to about 5 parts by weight, about 0.01 parts by weight to about 4 parts by weight, about 0.01 parts by weight to about 3 parts by weight, about 0.1 parts by weight to about 3 parts by weight, about 0.1 parts by weight to about 2 parts by weight, or about 0.1 parts by weight to about 1 part by weight, based on the total weight of the silicon-containing anode active material and the composite. The average particle diameter (D50) of the composite utilized for mechanical milling of the silicon-containing anode active material and the composite may be, for example, about 50 nm to about 200 nm, about 100 nm to about 300 nm, or about 200 nm to about 500 nm.
The disclosure will be described in more detail through the following examples and comparative examples. However, these examples are only for illustrative purposes, and the scope of the present disclosure is not limited thereto.
Al2O3 particles (average particle diameter: about 20 nm) were placed in the reactor, and then, CH4 was supplied into the reactor at about 300 sccm (i.e., standard cubic centimeters per minute) and 1 atm for about 30 minutes, and the temperature inside the reactor was raised up to 1000° C. at a temperature increase rate of about 23° C./min.
Then, the heat treatment was performed by maintaining the temperature for 7 hours. Then, the supply of CH4 was stopped, and the temperature inside the reactor was adjusted to room temperature (25° C.) to obtain a composite in which Al2O3 particles and Al2Oz (0<z<3) particles as a reduction product thereof were embedded in graphene.
The amount of alumina contained in the composite was 60 wt %.
A composite was prepared in substantially the same manner as in Preparation Example 1, except that Al2O3 particles (average particle diameter: about 200 nm) were utilized instead of Al2O3 particles (average particle diameter: about 20 nm).
SiO2 particles (average particle diameter: about 15 nm) were placed in the reactor, and then, CH4 was supplied into the reactor at about 300 sccm and 1 atm for about 30 minutes, and the temperature inside the reactor was raised up to 1000° C. at a temperature increase rate of about 23° C./min.
Then, the heat treatment was performed by maintaining the temperature for 7 hours. Then, the supply of CH4 was stopped, and the temperature inside the reactor was adjusted to room temperature (25° C.) to obtain a composite in which SiO2 particles and SiOy (0<y<2) particles as a reduction product thereof were embedded in graphene.
Needle-shaped silicon was pulverized to obtain plate-shaped and needle-shaped silicon particles with a length of about 125 nm and a thickness of about 40 nm having the surface on which about 0.1 nm thick silicon suboxide (SiOx, 0<x<2) was formed.
A composition including 30 parts by weight of plate-shaped and needle-shaped silicon particles, 10 parts by weight of stearic acid, and 60 parts by weight of isopropyl alcohol was prepared. The prepared composition was spray-dried and dried to obtain porous silicon secondary particles having an average particle diameter of about 5 μm.
Spray drying was performed utilizing a spray dryer (Micro Mist Spray Dryers, Fujisaki electric). In a nitrogen atmosphere, the spray nozzle size was about 5 μm, the pressure during spray drying was about 0.4 MPa, and the powder spraying atmosphere temperature was about 200° C. The prepared composition was sprayed under these spray-drying conditions to remove isopropyl alcohol, thereby obtaining porous silicone secondary particles.
The prepared porous silicon secondary particles were placed in a reactor. Under the condition that CH4 was supplied into the reactor at about 300 sccm and 1 atm, the temperature inside the reactor was raised up to 1000° C. at a temperature increase rate of about 23° C./min.
Then, the heat treatment was performed by maintaining the temperature for 5 hours. Then, the supply of CH4 was stopped, and the internal temperature of the reactor was adjusted to room temperature (25° C.) to obtain a porous silicon composite structure.
The porous silicon composite structure included porous silicon secondary particles and highly crystalline first graphene flakes located on the porous silicon secondary particles, wherein the porous silicon secondary particles included an aggregate of two or more silicon composite primary particles, and the silicon composite primary particles included silicon and silicon suboxide (SiOx, 0<x<2) located on the silicon and a second graphene flake located on the silicon suboxide.
The amount of the first graphene flake and the second graphene flake in the silicon-containing composite structure was about 25 parts by weight based on 100 parts by weight of the total weight of the porous silicon composite. The silicon-containing composite structure was porous.
60 parts by weight of the silicon-containing composite structure prepared according to Preparation Example 3, 40 parts by weight of coal tar pitch, and 10 parts by weight of N-methylpyrrolidone were added to a planetary mixer, and a mixing process was performed.
The coal tar pitch was infiltrated between the pores of the porous silicon secondary particles included in the silicon composite structure by the mixing process. The mixing process for the infiltration of coal tar pitch was carried out for a total of 15 minutes each for 5 minutes in the order of stirring-defoaming-stirring, and the cycle of stirring-defoaming-stirring was determined as one cycle, and a total of 4 cycles were performed. In the stirring, the revolution speed was 1000 rpm, the rotation speed was 1000 rpm, and in the defoaming, the revolution speed was 2000 rpm, the rotation speed was 64 rpm, and 40 parts by weight of the coal tar pitch was divided into 4 portions, and each portion was added to each cycle. The mixing temperature was controlled to be about 70° C. The mixing result was heat-treated in a nitrogen gas atmosphere at about 1,000° C. for 4 hours.
As a result, a silicon composite structure was prepared in which a carbonaceous coating film containing a first amorphous carbon was disposed on the surface of the silicon composite structure, and a second amorphous carbon was disposed in an inner portion the silicon composite structure. The second amorphous carbon is located in the pores of the porous silicon secondary particles included in the silicon composite structure. The weight ratio of first amorphous carbon to second amorphous carbon was 1:2. The weight ratio of carbon in graphene flakes to amorphous carbon in the prepared silicon composite structure was 2:8. The graphene flake is a combination of both the first graphene flake and the second graphene flake. The amorphous carbon is a combination of both the first amorphous carbon and the second amorphous carbon.
The silicon composite structure prepared according to Preparation Example 3 and the composite prepared according to Preparation Example 1 were milled utilizing a Nobilta Mixer (Nobilta Mixer, Hosokawa, Japan) at a rotation speed of about 2000 rpm to about 4000 rpm for about 5 minutes to 30 minutes to obtain a composite anode active material. The composite anode active material had a structure in which a shell including a composite and/or a milling result thereof was coated on a silicon-based anode active material core.
The mixing weight ratio of the silicon composite structure obtained according to Preparation Example 3 and the composite obtained according to Preparation Example 1 was 99:1.
A composite anode active material was prepared in substantially the same manner as in Example 1, except that the weight ratio of the silicon composite structure obtained according to Preparation Example 3 and the composite obtained according to Preparation Example 1 was changed to 99.9:0.1.
A composite anode active material was prepared in substantially the same manner as in Example 1, except that the weight ratio of the silicon composite structure obtained according to Preparation Example 3 and the composite obtained according to Preparation Example 1 was changed to 99.5:0.5.
A composite anode active material was prepared in substantially the same manner as in Example 1, except that the weight ratio of the silicon composite structure obtained according to Preparation Example 3 and the composite obtained according to Preparation Example 1 was changed to 95:5.
A composite anode active material was prepared in substantially the same manner as in Example 1, except that the weight ratio of the silicon composite structure obtained according to Preparation Example 3, the composite obtained according to Preparation Example 1, and carbon nanotubes (CNT) was changed to 98.9:1.0:0.1.
In addition to the silicon composite structure obtained according to Preparation Example 3 and the composite obtained according to Preparation Example 1, carbon nanotubes (CNT) were additionally utilized.
The length of the CNT was 200 nm to 300 nm, and the diameter of the carbon nanotube was about 10 nm.
A composite anode active material was prepared in substantially the same manner as in Example 1, except that the composite obtained according to Preparation Example 2 was utilized instead of the composite obtained according to Preparation Example 1.
A composite anode active material was prepared in substantially the same manner as in Example 1, except that the amorphous carbon-coated silicon composite structure obtained according to Preparation Example 4 was utilized instead of the silicon composite structure obtained according to Preparation Example 3.
A composite anode active material was prepared in substantially the same manner as in Example 1, except that, as a silicon-based anode active material, SiOx (0<x<2) having an average particle diameter of 6 μm was utilized instead of the silicon composite structure obtained according to Preparation Example.
The silicon composite structure prepared according to Preparation Example 3 was utilized as it is as an anode active material.
A composite anode active material was prepared in substantially the same manner as in Example 1, except that a simple mixture of Al2O3 particles (average particle diameter: about 20 nm) and graphene in a weight ratio of 60:40 was utilized instead of the composite prepared according to Preparation Example 1.
A simple mixture of the silicon composite structure prepared according to Preparation Example 3 and the composite prepared according to Preparation Example 1 in a weight ratio of 99:1 was utilized as the anode active material.
A composite anode active material was prepared in substantially the same manner as in Example 1, except that the composite obtained in Comparative Preparation Example 1 was utilized instead of the composite prepared according to Preparation Example 1.
SiOx with an average particle diameter of 6 μm (0<x<2) was utilized as it is as an anode active material.
A slurry was prepared by mixing the composite anode active material prepared according to Example 1, graphite, carboxymethyl cellulose and styrene-butadiene rubber (CMC/SBR) binder (1:1 weight ratio mixture) and deionized water. The mixing ratio of: the mixture of the composite anode active material and graphite; and the solid content (e.g., amount) of CMC/SBR binder was 97.5:2.5 weight ratio. The weight ratio of the composite anode active material and the graphite in the mixture of the composite anode active material and graphite prepared according to Example 1 was 2:98.
The slurry was bar-coated to a thickness of 100 μm on a copper foil current collector, dried at room temperature, vacuum dried again under vacuum condition at 120° C., and roll-pressed to prepare an anode.
A mixture in which LiNi0.91Co0.05Al0.04O2 (hereinafter referred to as NCA91) composite cathode active material, a carbon conductive material (Denka Black), and polyvinylidene fluoride (PVdF) were mixed in a weight ratio of 96:2:2, was mixed with N-methylpyrrolidone (NMP) in an agate mortar to prepare slurry.
The slurry was bar-coated to a thickness of 40 μm on an aluminum current collector, dried at room temperature, dried again under a vacuum condition at 120° C., and roll-pressed to prepare a positive electrode.
Coin cells were manufactured utilizing the cathodes and the anodes, which were prepared as described above, a polypropylene separator (Celgard 3510), and, as an electrolyte, a solution of 1.15M LiPF6 and 1.5 wt % of vinylene carbonate (VC) dissolved in ethylene carbonate (EC)+ethylmethyl carbonate (EMC)+dimethyl carbonate (DMC) (a volume ratio of 2:4:4).
Coin cells were manufactured in substantially the same manner as in Example 9, except that each of the composite anode active materials prepared according to Examples 2 to 8 was utilized instead of the composite anode active material prepared according to Example 1.
Coin cells were manufactured in substantially the same manner as in Example 9, except that each of the anode active materials prepared according to Comparative Examples 1 to 5 was instead of the composite anode active material prepared according to Example 1.
The composite anode active material prepared according to Example 1, which is the dry first anode active material, graphite, which is the dry second anode active material, carbon conductive material (Denka Black), which is the dry conductive material, and polytetrafluoroethylene (PTFE), which is the dry binder, were added into a blade mixer in a weight ratio of 1.8:90.2:4:4, and then, a first dry mixing was performed at 25° C. at a speed of 1000 rpm for 10 minutes to prepare a first mixture in which the first anode active material, the second anode active material, the conductive material, and the binder were uniformly mixed.
Then, in order to allow the binder to be fibrillated, the first mixture was subjected to a secondary mixing at 25° C. at a speed of 1000 rpm for 10 minutes to prepare a second mixture. A separate solvent was not utilized in the preparation of the first mixture and the second mixture.
The prepared second mixture was put into an extruder and extruded to prepare a self-standing film of the anode active material layer in the form of a sheet. The pressure at the time of extrusion was 50 MPa.
A carbon layer, which is an interlayer, was located on one surface of a 12 μm-thick copper thin film to prepare a first laminate in which an interlayer was located on one surface of a second cathode current collector.
The interlayer was prepared by coating a composition including a carbon conductive material (Danka black) and polyvinylidene fluoride (PVDF) on an aluminum thin film and then drying. The thickness of the interlayer located on one surface of the aluminum thin film was about 1 μm.
An anode active material layer self-standing film was placed on the interlayer of the prepared first laminate and roll-pressed to prepare an anode.
A mixture in which LiNi0.91Co0.05Al0.04O2 (hereinafter referred to as NCA91) composite cathode active material, a carbon conductive material (Denka Black), and polyvinylidene fluoride (PVdF) were mixed in a weight ratio of 96:2:2, was mixed with N-methylpyrrolidone (NMP) in an agate mortar to prepare slurry.
The slurry was bar-coated to a thickness of 40 μm on an aluminum current collector, dried at room temperature, dried again under a vacuum condition at 120° C., and roll-pressed to prepare a positive electrode (i.e., cathode).
Coin cells were manufactured utilizing the cathodes and the anodes, which were prepared as described above, a polypropylene separator (Celgard 3510), and, as an electrolyte, a solution of 1.15M LiPF6 and 1.5 wt % of vinylene carbonate (VC) dissolved in ethylene carbonate (EC)+ethylmethyl carbonate (EMC)+dimethyl carbonate (DMC) (a volume ratio of 2:4:4).
A coin cell was manufactured in substantially the same manner as in Example 17, except that the anode active material prepared according to Comparative Example 1 was utilized instead of the composite anode active material prepared according to example 1 as the dry first anode active material.
The specific surface area and the particle diameter of each of the silicon composite structure prepared according to Preparation Example 3, the composite anode active material prepared according to Example 1, and SiOx (0<x<1) prepared according to Comparative Example 5, and the composite anode active material prepared according to Example 8 were measured. Results thereof are shown in Table 1.
The specific surface area was measured by a nitrogen adsorption method. The particle diameter was measured utilizing a laser scattering particle size distribution meter.
As shown in Table 1, the composite anode active material prepared according to Example 1 had a larger specific surface area and smaller D10, D50, and D90 particle diameters than the silicon composite structure prepared according to Preparation Example 3.
In addition, the composite anode active material prepared according to Example 8 a larger specific surface area and smaller D10, D50, and D90 particle diameters than SiOx (0<x<2) prepared according to Comparative Example 5.
In the process of preparing the composite prepared according to Preparation Example 1, XPS spectra were measured utilizing Quantum 2000 (Physical Electronics) over time. Before heating, XPS spectra of C 1s orbitals and Al 2p orbitals of samples were measured after 1 minute, after 5 minutes, after 30 minutes, after 1 hour, and after 4 hours, respectively. At the initial heating, only the peak for the Al 2p orbital appeared, and the peak for the C 1s orbital did not appear. After 30 minutes, the peak for the C 1s orbital appeared clearly, and the size of the peak for the Al 2p orbital was significantly reduced.
After 30 minutes, near 284.5 eV, peaks for C—C bonds due to graphene growth and C 1s orbitals due to C═C bonds appeared clearly.
As reaction time elapsed, the oxidation number of aluminum decreased, and thus the peak position of the Al 2p orbital was shifted toward a lower binding energy (eV).
Accordingly, it was found that, as the reaction proceeded, graphene was grown on Al2O3 particles, and Al2Ox (0<x<3), which is a reduction product of Al2O3, was produced.
The average amounts of carbon and aluminum were measured through XPS analysis results in 10 regions of the composite sample prepared according to Preparation Example 1. With respect to the measurement results, a deviation of the aluminum amount for each region was calculated. The deviation of the aluminum amount was expressed as a percentage of the average value, and this percentage was referred to as uniformity. The percentage of the average value of the deviation of the aluminum content (e.g., amount), that is, the uniformity of the aluminum amount was 1%. Therefore, it was found that alumina was uniformly distributed in the composite prepared according to Preparation Example 1.
XPS spectra of the silicon composite structure prepared according to Preparation Example 3, the composite anode active material prepared according to Example 1 (Al2O3@Gr composite-coated silicon composite structure), and SiOx (0<x<2) prepared according to Comparative Example 5, and the composite anode active material prepared according to Example 8 (Al2O3@Gr composite-coated SiOx (0<x<2)) are shown in
As shown in
As shown in
The amounts of elements obtained from the XPS spectra of the silicon composite structure prepared according to Preparation Example 3, the composite anode active material prepared according to Example 1, SiOx (0<x<2) prepared according to Comparative Example 5, and the composite anode active material prepared according to Example 8 are shown in Table 2.
As shown in Table 2, the silicon composite structure prepared according to Preparation Example 3 and SiOx prepared according to Comparative Example 5 did not contain an aluminum (Al) element.
In contrast, in Examples 1 and 8, the amount of aluminum (Al) element of the composite anode active material was 1.2 at % and 3.3 at %, respectively.
The composite anode active material prepared according to Example 1 (Al2O3@Gr composite-coated silicon composite structure) and the composite anode active material prepared according to Example 8 (Al2O3@Gr composite-coated SiOx (0<x<2)) were analyzed utilizing a scanning electron microscope (SEM), a high-resolution transmission electron microscope, and SEM-energy-dispersive X-ray spectroscopy (EDS). For SEM-EDS analysis, Philips' FEI Titan 80-300 was utilized.
The composite prepared according to Preparation Example 1 shows a structure in which Al2O3 particles and Al2Oz (0<z<3) particles, which are reduction products thereof, are embedded in graphene. It was found that a graphene layer was located on the outside of one or more particles selected from among Al2O3 particles and Al2Oz (0<z<3) particles. One or more particles selected from among Al2O3 particles and Al2Oz (0<z<3) particles were uniformly distributed. At least one selected from among Al2O3 particles and Al2Oz (0<z<3) particles has a particle diameter of about 20 nm. The particle diameter of the composite prepared according to Preparation Example 1 was about 50 nm to about 200 nm.
It was confirmed that, in the composite anode active materials prepared according to Example 1 and Example 8, the shell formed by the composite including graphene was arranged on the silicon composite structure core or the SiOx (0<x<2) core.
The SEM-EDS mapping analysis was performed on the composite anode active materials prepared according to Examples 1 and 8.
As shown in
As shown in
It was confirmed that, in the composite anode active materials prepared according to Examples 1 and 8, the composite prepared according to Preparation Example 1 was uniformly coated on the silicon composite structure core or the SiOx (0<x<2) core to form a shell.
Each of the lithium batteries manufactured in Examples 9 to 16 and Comparative Examples 6 to 10 was charged with a constant current of 0.1 C rate at 25° C. until a voltage reached 4.5 V (vs. Li), and was then cut-off at a current of 0.02 C rate while maintaining the voltage at 4.5 V in a constant voltage mode. Subsequently, each of the lithium batteries was discharged at a constant current of 0.1 C rate until the voltage reached 2.75 V (vs. Li) (formation cycle).
Each of the lithium batteries having undergone the formation cycle was charged with a constant current of 0.2 C rate at 25° C. until a voltage reached 4.5 V (vs. Li), and was then cut-off at a current of 0.02 C rate while maintaining the voltage at 4.5 V in a constant voltage mode. Subsequently, each of the lithium batteries was discharged at a constant current of 0.2 C rate until the voltage reached 2.75 V (vs. Li) (1st cycle). This cycle was repeated (repeat 50 times) under substantially the same conditions until the 50th cycle.
In all charge/discharge cycles, a 10-minute stop time was provided after every charge/discharge cycle. Some of the results of the charging and discharging experiments at room temperature are shown in Table 3 below. The initial efficiency is defined by Equation 1, and the capacity retention ratio is defined by Equation 2.
Initial efficiency[%]=[Discharge capacity in the formation cycle/Charge capacity in the formation cycle]×100 Equation 1
Capacity retention ratio[%]=[discharge capacity in 50th cycle/discharge capacity in 1st cycle]×100 Equation 2
As shown in Table 3, the lithium batteries of Examples 9 to 16 had improved lifespan characteristics compared to the lithium batteries of Comparative Examples 6 to 10.
It was determined that the improved lifespan property was because the formation of a solid electrolyte film (SEI) on the surface and/or inside of the anode active material was suppressed or reduced by the coating with the composite, thereby suppressing or reducing the internal resistance of the lithium battery.
The lithium batteries of Examples 9 to 12 had improved lifespan characteristics by utilizing the composite-coated composite anode active material.
In the case of the lithium battery of Example 13, lifespan characteristics were further improved by utilizing a composite anode active material additionally including carbon nanotubes in addition to the composite.
The lithium battery of Example 14 had relatively poor lifespan characteristics compared to the lithium batteries of Examples 9 to 13 because the thickness of the coating layer was increased by utilizing alumina having a particle diameter of 200 nm.
The lithium battery of Comparative Example 7 included a composite anode active material in which a simple mixture of alumina and graphene was coated on a core, and a uniform coating was not obtained on the core due to aggregation of graphene.
In the lithium battery of Comparative Example 8, due to the utilization of the composite and the silicon composite structure as an anode active material, a coating layer was not formed on the silicon composite structure.
Although not shown in the table, the lithium battery of Example 17 has improved lifespan characteristics compared to the lithium battery of Comparative Example 11.
Each of the lithium batteries manufactured in Examples 9 to 18 and Comparative Examples 6 to 10 was charged with a constant current of 0.1 C rate at 25° C. until a voltage reached 4.5 V (vs. Li), and was then cut-off at a current of 0.02 C rate while maintaining the voltage at 4.5 V in a constant voltage mode. Subsequently, each of the lithium batteries was discharged at a constant current of 0.2 C rate until the voltage reached 2.75 V (vs. Li) (formation cycle).
Each of the lithium batteries having undergone the formation cycle was charged with a constant current of 0.2 C rate at 25° C. until a voltage reached 4.5 V (vs. Li), and was then cut-off at a current of 0.02 C rate while maintaining the voltage at 4.5 V in a constant voltage mode. Subsequently, each of the lithium batteries was discharged at a constant current of 0.2 C rate until the voltage reached 2.75 V (vs. Li) (1st cycle).
Each of the lithium batteries having undergone the 1st cycle was charged with a constant current of 0.5 C rate at 25° C. until a voltage reached 4.5 V (vs. Li), and was then cut-off at a current of 0.02 C rate while maintaining the voltage at 4.5 V in a constant voltage mode. Subsequently, each of the lithium batteries was discharged at a constant current of 0.2 C rate until the voltage reached 2.8 V (vs. Li) (2nd cycle).
Each of the lithium batteries having undergone the 2nd cycle was charged with a constant current of 1.0 C rate at 25° C. until a voltage reached 4.5 V (vs. Li), and was then cut-off at a current of 0.02 C rate while maintaining the voltage at 4.5 V in a constant voltage mode. Subsequently, each of the lithium batteries was discharged at a constant current of 0.2 C rate until the voltage reached 2.8 V (vs. Li) (3rd cycle).
Each of the lithium batteries having undergone the 3rd cycle was charged with a constant current of 2.0 C rate at 25° C. until a voltage reached 4.5 V (vs. Li), and was then cut-off at a current of 0.02 C rate while maintaining the voltage at 4.5 V in a constant voltage mode. Subsequently, each of the lithium batteries was discharged at a constant current of 0.2 C rate until the voltage reached 2.8 V (vs. Li) (4th cycle).
Each of the lithium batteries having undergone the 4th cycle was charged with a constant current of 3.0 C rate at 25° C. until a voltage reached 4.5 V (vs. Li), and was then cut-off at a current of 0.02 C rate while maintaining the voltage at 4.5 V in a constant voltage mode. Subsequently, each of the lithium batteries was discharged at a constant current of 0.2 C rate until the voltage reached 2.8 V (vs. Li) (5th cycle).
In all charge/discharge cycles, a 10-minute stop time was provided after every charge/discharge cycle. Some of the results of the high-rate charging characteristics experiments at room temperature are shown in Table 4. The high rate characteristics are defined by Equation 3 below.
High rate characteristics[%]=[3.0 C rate charging capacity(5th cycle charging capacity)/0.1 C rate charging capacity(Formation cycle charging capacity)]×100 Equation 3
As shown in Table 4, the lithium batteries of Examples 9 and 16 coated with the composite of Preparation Example 1 had improved high-rate characteristics compared to the lithium batteries of Comparative Examples 1 and 10 in which a coating layer was not formed.
Each of the lithium batteries manufactured in Examples 9 to 16 and Comparative Examples 6 to 10 was charged with a constant current of 0.1 C rate at 25° C. until a voltage reached 4.4 V (vs. Li), and was then cut-off at a current of 0.05 C rate while maintaining the voltage at 4.4 V in a constant voltage mode. Subsequently, each of the lithium batteries was discharged at a constant current of 0.1 C rate until the voltage reached 2.8 V (vs. Li) (formation cycle).
The lithium battery that had undergone the formation cycle was charged with a constant current at 25° C. at a rate of 0.7 C until the voltage reached 4.5 V (vs. Li), and then was cut-off.
Then, while the charged lithium battery was subjected to floating charging at a constant voltage of 4.5 V (vs. Li), the expansion ratio of an anode at 55° C. after 7 days, 10 days, 14 days, 17 days, and 20 days has elapsed, was measured. Results thereof are shown in Table 5. The expansion ratio of the anode is represented by Equation 4.
Thickness expansion ratio (%)=[(thickness of anode after storage for 20 days−thickness of anode before assembly)/thickness of anode before assembly]×100 Equation 4
“Thickness of the anode before assembly” refers to the thickness of the anode measured before assembly of the lithium battery.
“Thickness of the anode after storage for 20 days” refers to the thickness of the anode measured after disassembling the lithium battery taken out after storage for 20 days in the oven.
As shown in Table 5, the expansion ratio of the anode of the lithium battery of Example 9 was significantly smaller than the expansion ratio of the anode of the lithium battery of Comparative Example 6.
The expansion ratio of the anode of the lithium battery of Example 16 was significantly smaller than the expansion ratio of the anode of the lithium battery of Example 10.
It was determined that the decrease in the expansion ratio was due to the suppression or reduction of the formation of a thick solid electrolyte film (SEI) caused by the substantial decrease in the side reaction between the composite anode active material and the electrolyte by the composite coating.
According to one or more aspects of embodiments of the present disclosure, because the composite anode active material includes a shell including the first metal oxide and the first carbonaceous material, cyclic characteristics of a lithium battery are improved and a change in volume thereof is suppressed or reduced.
The electronic device, the battery management device/system and/or any other relevant devices or components according to embodiments of the present invention described herein may be implemented utilizing any suitable hardware, firmware (e.g., an application-specific integrated circuit), software, or a combination of software, firmware, and hardware. For example, the various components of the apparatus may be formed on one integrated circuit (IC) chip or on separate IC chips. Further, the various components of the apparatus may be implemented on a flexible printed circuit film, a tape carrier package (TCP), a printed circuit board (PCB), or formed on one substrate. Further, the various components of the apparatus may be a process or thread, running on one or more processors, in one or more computing devices, executing computer program instructions and interacting with other system components for performing the various functionalities described herein. The computer program instructions are stored in a memory which may be implemented in a computing device using a standard memory device, such as, for example, a random access memory (RAM). The computer program instructions may also be stored in other non-transitory computer readable media such as, for example, a CD-ROM, flash drive, or the like. Also, a person of skill in the art should recognize that the functionality of various computing devices may be combined or integrated into a single computing device, or the functionality of a particular computing device may be distributed across one or more other computing devices without departing from the scope of the embodiments of the present disclosure.
It should be understood that embodiments described herein should be considered in a descriptive sense only and not for purposes of limitation. Descriptions of features or aspects within each embodiment should typically be considered as available for other similar features or aspects in other embodiments. While one or more embodiments have been described with reference to the drawings, it will be understood by those of ordinary skill in the art that one or more changes in form and details may be made therein without departing from the spirit and scope of the disclosure as defined by the following claims and equivalents thereof.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2021-0166115 | Nov 2021 | KR | national |
