Various embodiments described herein relate to a composite heat exchanger shell and buoyancy system and method. The composite heat exchanger shell and buoyancy system and method is used as part of a floating Ocean Thermal Energy Conversion (“OTEC”) system. It can also be used in floating thermal desalination plants and in other marine and land-based applications.
An increase in worldwide population has led to the increase in demand for fresh water for human consumption and irrigation. Over 99% of the world's fresh water comes from tapping a diminishing source of the world's rivers, lakes, and groundwater locations that are becoming less dependable as some are reaching maximum capacities. With only 1% of the world's water supply available for human use in a constantly expanding worldwide population, clean water is becoming the most important commodity in water-stressed regions. The increase in demand for fresh water has been most evident in dry areas where rainwater is scarce and groundwater sources are drying up such as: the Middle East, Australia, and the American West and Southwest, to name a few.
Clean water is necessary for irrigation in arid regions where occupants rely on importing most of their food because agriculture is too expensive or not possible. Although clean water is basic utility in water-rich and developed regions, the arid and less developed regions of the world do not have access to clean water.
Most of the earth's surface, about 71%, is covered with water. However, most of the water is in saltwater oceans. Of course, salt water is unfit for human consumption. Water can be desalinated. The two most common options for water production include non-thermal/pressure/membrane processes, and thermal processes. The non-thermal/pressure/membrane processes include reverse osmosis (“RO”), filtration, sludge, and the like. The thermal processes include multi-stage flash, multi-effect distillation, and low-temp thermal desalination. Generally, water treatment and desalination methods require capital intensive equipment and facilities that become more expensive in regions that are arid and underdeveloped.
Each of the thermal processes includes a heat exchanger which is generally used to transfer heat from steam or humid air to cooler seawater. By transferring heat from the steam or humid air, freshwater condenses onto the heat transfer surfaces of the heat exchanger. As in the case of OTEC, expensive materials drive up heat exchanger capital costs and often eliminate the thermal desalination process from consideration.
Large heat exchangers are required for Ocean Thermal Energy Conversion (OTEC) for producing power based on the temperature difference between deep seawater and seawater near the surface of the ocean. A closed Rankine cycle using ammonia as the working fluid is commonly used in OTEC. Warm seawater is used to transfer heat to the boil liquid ammonia in the evaporator of the Rankine cycle. The cold seawater is used to remove heat from ammonia gas during a substantially constant pressure transfer of heat from the ammonia gas as it condenses in the condenser. Both the evaporator and the condenser each comprise one or more heat exchangers.
Expensive corrosion resistant metals are normally required for these heat exchangers since sea water is corrosive. The ammonia working fluid is used in the discussed application, but is incompatible with alloys containing copper, and titanium has been cited as the baseline material in past studies for OTEC plants but this idea is not restricted to ammonia as the working fluid. Many of the heat exchangers employ shell and tube technology; while others incorporate more compact plate-fin geometries. The expensive materials drive up the capital expenditure associated with OTEC heat exchangers to largely restrict locations where plants can be economically deployed.
Aluminum tubes or extrusions can be used in the heat exchangers. However, when a different metal is used as an exposed end plate or sheet in these heat exchangers a galvanic reaction causes corrosion concerns. Even with an aluminum tubesheet, the traditional fusion welding process (MIG or TIG welding) requires a filler material with a different alloy composition than the base metal. Fusion welding also results in a heat affected zone, where the region around the weld joint has a different grain structure than the surrounding tube or tube sheet material. These negative impacts from fusion welding can produce accelerated corrosion. Other joining techniques introduce aluminum alloys with a different composition than the base metal to weld or braze aluminum tubes or extrusions to adjacent aluminum plates. This too causes corrosion problems based on the formation of a galvanic reaction. In many heat exchangers the aluminum tubes must be isolated from a sheet of dissimilar material by way of an isolating gasket. Even with the gasket isolating dissimilar metals from each other, crevices at the tube end/tube sheet joint can trap chloride ions, resulting in preferential corrosion. Even if a bundle of aluminum tubes can be attached to an aluminum sheet without using a different material, these condensers are generally housed in a structural steel shell. Aluminum sheets and tubes must be isolated from the steel shell to prevent or substantially reduce a galvanic corrosion reaction.
Non-OTEC solutions for production of power are generally land based where weight of the heat exchangers can be easily accommodated. However, economical floating OTEC plants typically require buoyant structures to support the heat exchangers near the surface of the ocean.
In operation, the plurality of axial pumps 250 located in the plurality of shells 240 essentially pump cold water from the inlet end of the cold water pipe 228 up from depths of 1000 meters. The pumps 250 move the cold water into the plenum 224 and through the heat exchangers 230 in the shells 240. The heat exchangers 230 are used to change ammonia gas to ammonia liquid in an OTEC system.
As shown in
In the marine HX application, seawater (first fluid) flows axially through the inside of tubes or extrusions. Other corrosive or non-corrosive fluids can flow through the tubes, depending on the application. On the shell side of the heat exchanger (ie outside of the tubes or extrusions), a second fluid absorbs heat from or rejects heat to the surfaces on outsides of tubes or extrusions. This shell-side fluid can be a gas, liquid or two-phase (boiling or condensing). The fluid can be ammonia, water/water vapor or other liquids and gases depending on the application. The shell-side fluid enters/exits via side ports, or through co-axial ports at the ends of HX.
In the illustrative embodiment, apparatus 1200 is disposed on floating platform 1202, which, in some embodiments, ultimately serves as a part of an OTEC plant (see
Apparatus 1200 comprises fiber supply region 1206 and molding region 1212. Fiber supply region 1206 provides a continuous supply of fiber to the molding region. The fiber used in continuous-fiber composite materials is typically available in a variety of forms, including uni-directional tapes of various widths, plain weave fabric, harness satin fabric, braided fabric, and stitched fabric. Commonly-used fibers include, without limitation, fiber glass, commercially available from Owens Corning Technical fabrics, PPG, AGY and carbon fiber, commercially available from Zoltek and others. For use in conjunction with the present invention, the fiber is typically in the form of a fabric, provided in a convenient width as a function of the intended cross-sectional shape and size of the article (e.g., 1 to 2 meters width for a 10-meter diameter pipe, etc.). Such fabrics as fiberglass are, and as carbon fibers from Zoltek and others.
Fiber supply region 1206 and molding region 1212 are environmentally isolatable, collectively, from the other regions of apparatus 1200. This is illustrated by notional access-way 1207 in fiber supply region 1206 and a seal at the bottom of molding region 1212. The access-way is required to enable core 1214, discussed further below, to be inserted into molding region 1212.
In the illustrative embodiment, fiber in the form of fabric 1210A and 1210B (collectively “fabric 1210”) is disposed on respective rolls 1208A and 1208B (collectively “rolls 1208”). Rolls 1208A and fabric 1210A are disposed radially-outward of rolls 1208B and fabric 1208B. In the illustrative embodiment, there is no difference in material type between fabric 1210A and 1210B. In accordance with the present invention, continuity of fiber is maintained between fabric 1210 in supply region 1206 and fabric 1210 that has been fed to molding region 1212.
The inner portions of apparatus 1200, such as inner fabric rolls 1208B and central inner shell 1213 are stabilized/supported via vertical central member 1205. The central member is, in turn, supported by frame 1204.
In the illustrative embodiment, core 1214 is disposed in molding region 1212. The core material, which in the illustrative embodiment is available as a plurality of plank-like segments, forms a cylindrical shape or ring when assembled and positioned in molding region 1212. This core ring (cylindrical or otherwise) establishes the basic shape for the work piece being produced in molding region 1212. As depicted in
In the illustrative embodiment, core 1214 is lowered into molding region 1212 via overhead traveling crane 1203. In some embodiments, the core comprises hollow planks produced from fiber and polymer via a pultrusion process, some of which may be available at a cost per pound which is generally low compared to other methods of fabricating linear composite shapes, from pultruders such as Glasforms and Strongwell. Other processes can be used to produce a structure suitable for use as core 1214. In some other embodiments, the core can be produced from other materials (e.g., aluminum, etc.) and exhibit other structural arrangements (e.g., foam, sealed honeycomb internal arrangement, etc.).
Up to this point, a substantially aluminum heat exchanger 230 enclosed within a composite shell 640 has been discussed with respect to use in an OTEC application. It should be noted that a substantially aluminum heat exchanger 230 enclosed within a composite shell 640 can also be used as a condenser for desalination projects. The desalination projects can be for removing water from ambient air in humid climates or can be for desalination projects that remove water that use energy to flash or boil water off from seawater, such as multi stage flash (“MSF”) or multi effect distillation (“MED”). The desalination projects could even be conducted in tandem with a project, such as the production of power, that has waste heat generated. It should be noted that desalination projects represent another capital intensive market which can benefit from innovative, low cost heat exchanger/condenser solutions.
A heat exchanger includes a shell made of a composite material, and a heat exchanger housed substantially within the shell. The shell is made of a composite material further comprises planks positioned in the outer periphery of the shell. The planks, in one embodiment, are substantially hollow or include substantially hollow portions. In some embodiments, the planks are formed of pultruded plastic. The shell of the heat exchanger further including layers of fiberglass. The pultruded plastic planks are sandwiched between at least a first layer of fiberglass and a second layer of fiberglass. The layers of fiberglass are infused with resin. In one embodiment, the layers of fiberglass are infused with resin using a Vacuum-Assisted Resin Transfer Molding (VARTM) process. In addition, the shells of the heat exchanger includes a first end and a second end. At least one metal flange is coupled to one of the first end or second end of the shell. The metal flange includes an inner termination ring having inner trap-lock grooves therein, and an outer termination ring having inner trap-lock grooves therein. The shell of composite material can be formed to be buoyant. The shells can be long. For example, the shell can be over 70 meters in length. In some embodiments, the shells can be over 100 meters in length.
An apparatus for forming elongated tubes of composite material includes a floating base, a molding region attached to the base, a fiber supply region, and a resin infusion apparatus for infusing the fiber with resin. The molding region including a core ring for receiving a core material. The fiber supply region provides a substantially continuous supply of a fiber to the molding region. The fiber supply region supplies fiber to an inner region of the core ring and an outer region of the core ring. The apparatus for forming elongated tubes also includes a supply of a core material that is inserted into the core ring. A plurality of elongated planks are positioned around the ring core in forming the elongated tubes. The core material is inserted into the core ring, the core material including elongated planks of plastic. In one embodiment, the core material includes elongated planks of pultruded plastic having hollow portions therein. A vacuum assisted resin infusion apparatus can also be added to the apparatus to apply a vacuum to a portion of the molding chamber. In one embodiment, The apparatus for forming elongated tubes of composite material wherein the molding process is performed at a site where the elongated tubes of composite material are used to form a floating heat exchanger for an Ocean Thermal Energy System. The apparatus for forming elongated can also include apparatus for applying a metal flange to at least one of the ends of the elongated tube.
A floating portion of an Ocean Thermal Energy System includes a platform, a plenum attached to the platform, a cold seawater intake attached to the plenum, and a plurality of heat exchangers attached to the plenum. The heat exchangers include pumps for moving the cold seawater from the plenum through the heat exchangers. The heat exchangers include shells made of composite material. The cold seawater intake can also be an elongated tube of composite material.
A heat exchanger shell can comprise composite sandwich wall construction. The wall, in one embodiment, include pultruded plastic core “planks” sandwiched between layers of fiberglass, infused with resin. The process used to infuse the fiberglass with resin can be Vacuum-Assisted Resin Transfer Molding (VARTM). This type of construction can be used to form The heat exchanger shell can be produced using a vertical molding apparatus). It is contemplated that the heat exchanger shell can also be produced using a horizontal molding apparatus. In one embodiment, the molding apparatus can be used to form shells on site, such as on a platform floating in the ocean during construction of an OTEC system, such as shown in
Metal flanges can be attached to the ends of the composite shells or tubes. The metal flanges are ASME Code-compliant metalic flanges made of aluminum, steel, stainless steel or other metals, The metal flanges are attached to the ends of the composite shell using a fiber entrapment approach.
Condenser Heat Exchangers with composite shell can be made buoyant in water by adjusting the tube-tube pitch, tube wall thickness and number of tubes in tube bundle, to form a buoyant structure. The combined operating weight (dry weight plus water in tubes and condensing vapor outside of tubes, plus the composite shell weight) is less than the weight of surrounding water that is displaced. As a result, the floating portion 200 floats, as shown in
The buoyant composite shell heat exchanger can support other elements in a floating OTEC or desalination plant, such as a central cold water pipe/riser (used to pump cold, deep ocean water to the OTEC plant), or the OTEC platform containing power generation and transmission equipment.
The buoyancy of composite shell heat exchanger can be adjusted in-situ by controlling the level of liquid (i.e. ammonia or other working fluid) on the outside of heat exchanger tubes (surrounded the composite shell).
This has been a detailed description of some exemplary embodiments of the invention(s) contained within the disclosed subject matter. Such invention(s) may be referred to, individually and/or collectively, herein by the term “invention” merely for convenience and without intending to limit the scope of this application to any single invention or inventive concept if more than one is in fact disclosed. The detailed description refers to the accompanying drawings that form a part hereof and which shows by way of illustration, but not of limitation, some specific embodiments of the invention, including a preferred embodiment. These embodiments are described in sufficient detail to enable those of ordinary skill in the art to understand and implement the inventive subject matter. Other embodiments may be utilized and changes may be made without departing from the scope of the inventive subject matter. Thus, although specific embodiments have been illustrated and described herein, any arrangement calculated to achieve the same purpose may be substituted for the specific embodiments shown. This disclosure is intended to cover any and all adaptations or variations of various embodiments. Combinations of the above embodiments, and other embodiments not specifically described herein, will be apparent to those of skill in the art upon reviewing the above description.
This application claims the benefit of U.S. Provisional Patent Application Ser. No. 61/570,733, filed on Dec. 14, 2011, which is incorporated by reference herein.
Number | Date | Country | |
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61570733 | Dec 2011 | US |