This patent application claims priority from Italian patent application no. 102018000020521 filed on 20 Dec. 2018, the entire disclosure of which is incorporated herein by reference.
The present invention relates to a composite material, in particular for aeronautical applications, to which the following description will make explicit reference, but without any loss of generality.
The present invention also relates to a method for producing the aforementioned composite material.
As is known, composite materials are used in various industrial sectors, including the aviation industry. In particular, fibre-reinforced composite materials, commonly referred to as “pre-impregnated” or “prepreg”, are known, which are generally constituted by a semi-finished product comprising a resin matrix and reinforcing fibres immersed in the matrix. The fibres can be arranged according to different configurations, for example, in a single direction, in two or more mutually different directions, or can be arranged to form a fabric. The matrix is used to fix the fibres to each other and possibly to other components during production.
Prepregs are generally prepared in the form of tapes and wound in rolls; in order to achieve the desired mechanical properties, prepregs must be subjected to a consolidation process through heat and also often under pressure.
The prepregs mainly used in the aviation industry can have a matrix of a thermosetting material or of a thermoplastic material.
In the first case (thermosetting materials), the matrix is constituted by polymers that, in opportune temperature conditions and/or in the presence of certain substances, transform into rigid, insoluble and infusible materials. This transformation occurs following cross-linkage reactions (a process known as curing, through which polymer chains undergo a reaction that creates bonds between different chains at a reactive functional group level), which take place between the polymer chains with the formation of strong (covalent or ionic) bonds.
Before polymerization, thermosetting materials have characteristics of stickiness. These materials can therefore be used to create stratifications, by placing different layers one on top of the other, with an opportune sequence or orienting of the different layers. The stratifications are then subjected to a temperature and pressure cycle (in a vacuum bag and in autoclave, using ovens, moulding presses, etc.) which polymerizes the material, raising the molecular weight and inducing the formation of bonds between the macro-molecules (cross-linking), thus transforming it into a material with structural characteristics and mechanical properties suitable for its intended application.
Some thermosetting polymers are cross-linked by just heat or through a combination of pressure and heat, while others can be cross-linked through chemical reactions at room temperature (cold cross-linking).
The layering can be accomplished with automated methods, which provide significant advantages in terms of cost, productivity and repetitiveness. For flat or moderately curved layering, an Automated Tape Laying (ATL) device is used. Recently, a technique has become popular that allows layering on curved or even closed (cylindrical) surfaces using prepregs tapes of rather small width (known as slits); this technique is called Fibre Placement (FP).
In the second case (thermoplastic materials), the matrix resin has a high molecular weight and therefore, on one hand, it does not need to undergo a polymerization cycle, and on the other, does not have characteristics of stickiness.
In a first approximation, a thermoplastic matrix prepreg can be considered a manufactured product in its final state formed by a single lamina. To be able to form a laminate, it is necessary to heat it so as to cause the melting of at least the contact surfaces of its constituent laminae or layers of thermoplastic prepreg, compress it under pressure and then let it cool. The temperature to be reached for melting is the glass transition temperature Tg for amorphous thermoplastics, and the melting point temperature Tf for semi-crystalline thermoplastics.
Currently, the techniques of automated tape laying (ATL) and fibre placement (FP) are only used for composite parts with a thermosetting matrix. These are also conceptually possible techniques for thermoplastic-matrix prepregs, but have some additional technological requirements; in fact, in this case, the apparatus for producing a laminate based on thermoplastic prepregs must also provide the heat for reaching a temperature (which, depending on the materials, might be excessively high) such as to melt the resin and thus obtain adhesion between the various layers that will constitute the laminate; in addition, for semi-crystalline thermoplastics, cooling that is too rapid might cause amorphisation of the part, with consequent loss of performance characteristics. In compensation, if these problems were solved, the ATL and FP techniques would enable achieving finished parts without a further autoclave process, with a significant reduction in the production costs of the parts.
As previously explained, the processes of consolidation of the prepregs and of bonding the various prepreg layers that form the final component usually take place in an autoclave, in ovens or moulding presses. In the case of very large components, such as, for example, structural components in the aviation sector, naval sector, etc., the known consolidation and bonding processes are excessively expensive and can create numerous undesired constraints.
The need has thus been felt to develop techniques that allow achieving in-situ consolidation and bonding of parts in a composite material, especially when these are very large.
One of the most promising techniques for composite materials with a thermoplastic matrix is consolidation and bonding by electromagnetic induction, which, unlike other techniques, such as, for example gluing, does not use filler materials, but only the overlapping of two edges of two parts to be bonded (also known as adherends), at least one being electrically conductive, kept in contact with each other.
According to this technique, an inductor, for example a coil, generates a variable electromagnetic field, which in turn causes the induction of parasitic currents in the areas of the adherends to be bonded, at least one of which is electrically conductive; by the Joule effect, these parasitic currents heat the matrix of the adherends, bringing it to the melting or softening point; then, when the adherends have been brought to the temperature considered ideal, mechanical pressure can be applied, known as the consolidation pressure, suitable for inducing the adhesion of the adherends.
In traditional induction bonding systems, bearing in mind a dependence related to the square of the distance from the inductor, the heating action due to parasitic currents tends to be concentrated on the surface directly exposed to the inductor. A consequently steep temperature gradient is thus produced, which causes surface melting of the matrix rather than of the area of adhesion of the adherends: this negatively impacts the quality of the bond and of the mechanical characteristics of the bond thus obtained.
Furthermore, the direction of this temperature gradient, in the direction of the thickness, results in a maximum temperature on the surface facing the inductor and a minimum temperature on the bonding surface. Therefore, in order to reach the ideal temperature on the adhesion surface of the adherends, a temperature in the outermost areas will be excessive and this can lead to degradation of the composite's matrix. The presence of this gradient consequently limits the possible thickness of the adherends quite significantly.
Similarly, there is a large concentration of currents on the edges of the parts to be bonded and, therefore, temperature gradients that are often unacceptable form on them, which can again lead to degradation of the material.
In any case, the temperatures that are reached on the adhesion surface are too low (generally 60-70° C.) with respect to that required for forming the bond (approximately 350° C.)
Ultimately, the main drawback of in-situ consolidation and bonding techniques of composite materials by electromagnetic induction lies in the difficulty of optimizing the temperature distribution through the thickness of the bond.
One object of the present invention is to produce a composite material that enables overcoming the above-described drawbacks.
According to the present invention, a composite material is provided, in particular for aeronautical applications, as claimed in claim 1 and in its dependent claims.
The present invention also relates to a method as claimed in claims 10 and 11 for producing the aforementioned composite material.
The present invention will now be described with reference to the accompanying drawings, which show two different non-limitative embodiments, in which:
The lamina L of composite material comprises a first pre-impregnated layer 2 having a resin-based matrix 3, reinforced with fibres 4 or with a fibre material to give the layer 2 predefined mechanical properties.
It should be noted that the expression “-based” or “based on” means that the matrix 3 can, in addition to the resin, also comprise commonly used additives such as, for example, fillers, stabilizers, etc.
The matrix 3 is preferably based on a semi-crystalline thermoplastic resin having a predetermined melting point Tf. This semi-crystalline thermoplastic resin is, for example, polyether ether ketone, or PEEK, which has a melting point temperature Tf of approximately 340° C. In alternative, this semi-crystalline thermoplastic resin can, for example, be polyetherketoneketone, or PEKK, which has a melting point temperature Tf of approximately 370° C.
The matrix 3 can also be based on an amorphous thermoplastic resin having a predetermined glass transition temperature Tg. This amorphous thermoplastic resin is, for example, polyetherimide, or PEI, which has a glass transition temperature of approximately 215° C.
According to a possible alternative that is not shown, the matrix of the layer 2 could also be based on a thermosetting resin, for example, epoxy, BMI (bismaleimide) or phenolic resin.
The fibres 4 are preferably carbon fibres and can be arranged in one or more unidirectional layers, in several layers having different orientations from each other, or like a fabric.
Carbon fibres 4 have an areal weight preferably comprised between 100 and 300 g/m2.
Preferably, the fibres 4 of the layer 2 are unidirectional; in particular, the unidirectional fibres 4 are used to unidirectionally reinforce the stressed parts of the lamina L, arranging them along the load path.
In alternative, other types of fibres known in the aviation sector can be used for the layer 2, such as, for example, glass fibres or a combination of glass and carbon fibres.
The fibres 4 are preferably continuous or can have a length comprised between 1 mm and 40 cm.
As visible in
The lamina L of composite material further comprises a second layer 6 of magnetic field intensifier material, superimposed and joined to one of the faces 5 of layer 2; electrically conductive fibres 7 having equivalent electrical resistivity and less than 600 μΩm, preferably less than 200 μΩm and even more preferably less than 100 μΩm, so as to facilitate localized heating through electromagnetic induction, are dispersed in layer 6 in at least two directions with different orientations and parallel to the faces 5.
For the significance and calculation of the equivalent electrical resistivity (inverse of equivalent electrical conductivity) of a composite material, reference can, for example, be made to the following publication:
“Calculation of an equivalent electrical conductivity tensor for multidirectional carbon fiber reinforced materials”, 19 Aug. 2012, authors N. Athanasopoulos and V. Kostopoulos.
In the example shown, the layer 6 comprises a matrix 8 based on a semi-crystalline thermoplastic resin, identical to the resin of the matrix 3 of layer 2 or compatible with the latter, in which the fibres 7 are dispersed. More specifically, the fibres 7 are in carbon and are arranged in the matrix 8 in a random manner in a plurality of directions, some of which extend parallel to the faces 5, while others extend transversely to the faces 5.
The fibres 7 extending transversely to the faces 5 have an equivalent electrical resistivity greater than 2,000 μΩm.
The carbon fibres 7 have an areal weight comprised between 10 and 100 g/m2.
The carbon fibres 7 are preferably obtained through the oxidation and pyrolysis of polyacrylonitrile (PAN).
Alternatively, the carbon fibres 7 could be obtained through the distillation of carbon-based materials such as, for example, plants, raw oil and carbon (PITCH); in this case, a viscoelastic material composed of aromatic hydrocarbons.
The fibres 7 can also be made in another electrically conductive material, for example, a metal material.
The fibres 7 are preferably continuous or can have a length comprised between 1 mm and 40 cm.
Advantageously, the layer 6 is in the form of a veil or film and has, in a direction orthogonal to the faces 5, a thickness S2 comprised between 1/10 and 1/100 of the thickness S1 of the layer 2.
The layers 2 and 6 are joined by compression moulding and preferably by continuous compression moulding. This joining can be performed in a known manner in a hot press (known and not shown) or by making the layers 2 and 6 to be joined pass between respective pairs of hot rollers (known and not shown) in a continuous lamination-like process. The temperature at which the joining process of the layers 2 and 6 takes place depends on the kind of thermoplastic matrix used; in the case of semi-crystalline thermoplastic matrices it is higher than the melting point Tf, while in the case of amorphous thermoplastic matrices it is greater than the glass transition temperature Tg.
During this operation, an inductor 11 (known and only schematically shown), for example an electric coil, is fed with electric current so as to generate a variable electromagnetic field E (the flux lines of which are schematically indicated by broken lines in
At the same time, a new lamina L is progressively laid on another already present lamina L, arranged on a supporting surface 12, or, alternatively, on an upper lamina L of a series of already joined or bonded laminae L arranged on the supporting surface 12.
The step of laying the new lamina L is performed by one or more rollers 13 (only one of which is shown in
The electromagnetic field E induces parasitic currents essentially in the layer 6 of the new lamina L which is then joined to the other lamina(e) L lying on the supporting surface 12.
Since the fibres 7 of the layer 6 are electrically conductive and are dispersed in the matrix 8 in at least two different directions, actual “electrical circuits” are created, at least inside layer 6 of the new lamina L, which heat, by the Joule effect, the matrix 8 of layer 6 and the adjacent lamina L.
The localized heating is very efficient and enables reaching temperatures locally, i.e. in the layer 6 and in the areas of the matrices 3 adjacent to this layer, that exceed the melting point temperature Tf or the glass transition temperature Tg.
Instead, in the areas of the matrices 3 furthest away from layer 6, the temperature remains decidedly below the melting point temperature Tf of the resin forming these matrices 3.
The passage of the roller 13, or rollers 13, takes place after the induction of parasitic currents in the new lamina L to be bonded to the other lamina(e) L arranged on the surface of the supporting surface 12.
In this way, pressure is progressively exerted on the areas of the laminae L to be bonded, after the softening obtained at the interface between them following electromagnet induction and during the cooling of these areas.
Preferably, the roller(s) 13 is/are kept cold so as to progressively remove residual heat from the laminae L in the bonding step.
At the end of the bonding operation, the result is that schematized in
As can be seen, the fibres 7 have a substantially isotropic distribution in the matrix 8 of layer 6, with some of the fibres 7 directed transversely with respect to the faces 5 of the layer 2. This enables achieving high resistance/toughness of the bonded material.
In particular, the diagram of
The diagram in
As can be observed, in the first case (
In the second case (
The applicant has observed that, due to the adoption of a thickness for layer 6 comprised between 1/10 and 1/100 of the thickness of the layer 2, it is possible to achieve, on one hand, substantial preservation in the lamina L of the mechanical properties determined by the layer 2 and, on the other, extremely easy in-situ consolidation and bonding of the material by electromagnetic induction.
The above-indicated veil and mat have a semi-crystalline thermoplastic resin based matrix, identical to the resin of the matrix of the UD lamina.
The impregnation level of the above-indicated veil and mat is 34% by weight.
The fibres used in the above-indicated veil and mat are in carbon and are arranged in the respective matrices in a random manner in all directions.
The mechanical properties of the different types of laminae described above have been determined in terms of modulus of elasticity E and tensile strength σ; both quantities have been calculated in the direction parallel to the unidirectional fibres in layer 2 or in the UD lamina.
The thickness of the different laminae considered has been calculated in the direction orthogonal to the laminae and is listed in the table below:
Instead, the table below lists the values of the modulus of elasticity E and tensile strength σ calculated for the above-defined laminae.
The results of this table are summarized as histograms in
In particular, as can be observed both from the previous tables and from
The histograms of
In particular, lamina L′ of composite material differs from lamina L basically in that it comprises a magnetic field intensifier layer 6′ without a resin matrix.
In greater detail, the layer 6′ can be a carbon veil in which the fibres 7 extend in at least two directions having different orientations, preferably in at least three directions of which one is transversal to the faces 5 of the layer 2; in this case, the fibres 7 are held together to form the veil by an adhesive or binder, for example PVA (polyvinyl alcohol) or other substances chemically compatible with the matrix 3 of the layer 2.
Alternatively, the layer 6′ could be a fabric with the fibres 7 extending in at least two directions with different orientations.
According to a further alternative, the layer 6′ could be a non-woven fabric, for example of the Optiveil® type.
From an examination of the characteristics of the composite material produced according to the principles of the present invention, the advantages that can achieved therewith are evident.
In particular, as previously stated, since the fibres 7 of the layer 6, 6′ are electrically conductive and are arranged in at least two directions with different orientations, it is possible to generate actual “electrical circuits” by electromagnetic induction inside at least layer 6, 6′; the creation of these circuits enables achieving effective heating, by the Joule effect, of the layer 6, 6′ and of the adjacent resin matrices 3, reaching the melting point temperature Tf of the resin precisely at the bonding interface of two different laminae L, L′.
In practice, reaching the melting point temperature Tf of the resin at the aforementioned interface does not require generating even higher temperatures in the areas of the resin closest to the inductor 11, with the consequent possible degradation of the matrix of the composite material.
As shown in the diagrams of
Precisely for the reasons set out above, the applicant has also measured a bonding speed between two laminae L, L′ according to the present invention ten times higher than the bonding speed of traditional prepregs.
Since the thickness S2 of the layer 6, 6′ is comprised between 1/10 and 1/100 of the thickness S1 of layer 2, easy in-situ consolidation and bonding of the material according to the present invention is achieved practically without penalising the mechanical properties given to the laminae L, L′ by the orientation and arrangement of the carbon fibres of the layer 2. Finally, it is clear that modifications and variants can be made to the composite material as well as to the method for producing this composite material set forth herein, without departing from the scope defined in the claims.
Number | Date | Country | Kind |
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102018000020521 | Dec 2018 | IT | national |
Filing Document | Filing Date | Country | Kind |
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PCT/IB2019/061196 | 12/20/2019 | WO | 00 |