The present invention relates to a composite material member, a method for producing a composite material member, and a molding die for the same.
Conventionally, when an object to be fastened is fastened to a member made of fiber-reinforced plastic (hereinafter referred to as FRP member), a method is performed in which a hole is bored in the FRP member, a fastener is inserted in the hole, and the FRP member and the object to be fastened are fastened by the inserted fastener. Japanese Laid-Open Patent Application No. 2016-114139 discloses a related technique.
When the FRP member is subjected to the boring process, there are cases in which peeling of the reinforcing fibers or loss of resin occurs in the periphery of the hole, and this peeling, etc., of the reinforcing fibers in the periphery of the hole may cause cracks in the fastening portion of the FRP member.
An object of the present invention is to suppress the occurrence of peeling of the reinforcing fiber and the loss of resin accompanying the boring process in a composite material member, such as the FRP member.
One aspect of the present invention is a composite material member in which a resin-rich layer, having a lower fiber content than an FRP layer, is formed in at least a partial region of a surface of the FRP layer, and a hole is bored so as to penetrate the FRP layer and the resin-rich layer. By means of the above-described composite material member, it is possible to suppress the occurrence of peeling of the reinforcing fiber and the loss of the resin accompanying the boring process.
Composite material members (hereinafter referred to as member CM) according to several embodiments will be described below with reference to the drawings. Terms that represent directions, such as “up” and “down,” in the description below are defined for the sake of convenience in order to describe the positional relationship of each part, and do not limit the actual attachment attitudes, etc.
As illustrated in
The FRP layer 1 is made of fiber-reinforced plastic, mainly composed of reinforcing fibers F and matrix resin MR. The reinforcing fibers F are made of continuous fibers oriented along a planar direction S of the member CM, having, for example, a stacked structure in which reinforcing fiber bundles are stacked in one direction or at different angles, or a form of a woven fabric. The thickness of the FRP layer 1 is not particularly limited, and can be appropriately set in accordance with the required strength, rigidity, etc., of the member CM.
The reinforcing fibers F are not particularly limited; for example, carbon fiber, glass fiber, polyalamide fiber, alumina fiber, silicon carbide fiber, boron fiber, and carborundum fiber can be used. For example, polyacrylonitrile (PAN type), pitch type, cellulose type, vapor grown carbon fiber by hydrocarbon, graphite fiber, and the like, may be used as the carbon fiber. Two or more types of these fibers may be used in combination as well.
The matrix resin MR is not particularly limited; for example, well-known thermosetting resins and thermoplastic resins, such as epoxy resin, phenol resin, unsaturated polyester resin, vinyl ester resin, polyimide resin, polycarbonate resin, polyamide resin, and polyphenylene sulfide (PPS) resin can be used.
The FRP layer 1 may contain various additives, such as colorants and fillers, as components other than the reinforcing fibers F and the matrix resin MR.
The resin-rich layer 2 is mainly composed of the well-known thermosetting resin and thermoplastic resin exemplified above as the material for the matrix resin MR. The main component resin of the resin-rich layer 2 may be the same resin as the matrix resin MR, a different resin, or a mixture thereof. Like the FRP layer 1, the resin-rich layer 2 may contain reinforcing fibers and various additives as components other than the main component resin.
The resin-rich layer 2 has a lower fiber content than the fiber content of the FRP layer 1. The fiber content of the FRP layer 1 is the volume ratio of the reinforcing fibers F contained in the FRP layer 1 relative to the entire FRP layer 1, and the fiber content of the resin-rich layer 2 is the volume ratio of the reinforcing fibers contained in the resin-rich layer 2 relative to the entire resin-rich layer 2.
The hole 3 is formed so as to penetrate the FRP layer 1 and the resin-rich layers 2 formed on the surfaces 1a, 1b on both sides thereof. As illustrated in
In addition, a metal washer 5 is provided on the lower side surface 1b of the FRP layer 1. The washer 5 is bonded to the FRP layer 1 by the adhesive A provided in a gap G2 between a rear surface 5a thereof and the surface 1b of the FRP layer 1. The resin-rich layer 2 on the lower side is interposed between the surface 1b of the FRP layer 1 and the rear surface 5a of the washer 5 in a state in which the front surface thereof is in contact with the rear surface 5a of the washer 5, prescribing the size of the gap G2. The adhesive A is not particularly limited\; for example, well-known adhesives, such as epoxy, can be used.
A peripheral portion 3X of the hole 3 constitutes a fastening portion FP of the member CM, together with the collar 4 and the washer 5. The fastening portion FP is fastened to an object to be fastened 8 by a fastener (for example, a bolt 6 and a nut 7) that is inserted in the tubular portion 41 of the collar 4. In the present embodiment, it is possible to fasten the member CM and the object to be fastened 8 by superposing the object to be fastened 8 on the washer 5, inserting the bolt 6 in the tubular portion 41 of the collar 4 and a hole 8a of the object to be fastened 8, and tightening the nut 7 on the bolt 6. It is also possible to omit the washer 5 and fasten the member CM and the object to be fastened 8 in a state in which an upper surface 8b of the object to be fastened 8 is brought into contact with a distal end of the tubular portion 41 of the collar 4, or, in a state in which the upper surface 8b of the object to be fastened 8 is brought into contact with the surface 1b of the FRP layer 1.
The action and effect of the present embodiment will be described below.
In general, a drill, an end mill, a water jet, or the like, is used for the boring process of an FRP member. As illustrated in
Thereafter, as illustrated in
Then, when the drill tip Da tries to exit from the surface S2, as illustrated in
There are cases in which the cutting force acts on the reinforcing fibers F in the outermost layer of the hole peripheral portion X in a direction to peel off the reinforcing fibers F, even in a boring process using an end mill or a water jet, such that peeling of the reinforcing fibers F or loss of resin could occur, in the same manner as in the boring process by the drill D.
(A) On the other hand, in the member CM according to the present embodiment, the resin-rich layer 2 is formed on the surfaces 1a, 1b of the FRP layer 1, and the hole 3 is bored so as to penetrate the FRP layer 1 and the resin-rich layer 2. That is, during the boring process, the reinforcing fibers F in the outermost layer in the hole peripheral portion 3X of the FRP layer 1 are supported or restrained by the resin-rich layer 2 that is adjacent in the thickness direction T, thereby suppressing the deformation thereof. For this reason, at the time of the boring process, the force acting in the direction of peeling off the reinforcing fibers F in the outermost layer of the hole peripheral portion 3X becomes smaller compared to when the resin-rich layer 2 is not present.
Additionally, since the resin-rich layer 2 has a lower fiber content than the FRP layer 1, at the time of the boring process, the force that is transmitted from a tool to the reinforcing fibers F of the outermost layer via the resin-rich layer 2 becomes smaller compared to when a layer having a higher fiber content than the FRP layer 1 is employed.
Accordingly, by the configuration of the member CM, the occurrence of the peeling of the reinforcing fibers F in the FRP layer 1 and the loss of the resin accompanying the boring process becomes less likely. It is thereby possible to obtain the member CM in which the strength and reliability of the fastening portion FP are high, with little peeling of the reinforcing fibers F and loss of resin, which can cause cracking of the fastening portion FP in the hole peripheral portion 3X.
(B) In addition, in the member CM, since the resin-rich layer 2 is formed on the surfaces 1a, 1b of the FRP layer 1, it is possible to obtain the above-described effect (A) on the surfaces 1a, 1b on both sides of the FRP layer 1. It is thereby possible to obtain the member CM, in which the strength and reliability of the fastening portion FP are high, with less peeling of the reinforcing fibers F and loss of resin in the hole peripheral portion 3X.
(C) Furthermore, in the member CM, since the reinforcing fibers F of the FRP layer 1 are made of continuous fibers, it is possible to further improve the strength and reliability of the fastening portion FP while ensuring the strength and rigidity of the member CM.
(D) Additionally, in the member CM, the upper side resin-rich layer 2 is interposed between the surface 1a of the FRP layer 1 and the rear surface 42a of the flange 42, and the lower side resin-rich layer 2 is interposed between the surface 1b of the FRP layer 1 and the rear surface 5a of the washer 5, respectively prescribing the sizes of the gaps G1, G2. For this reason, it is possible to control the sizes of the gaps G1, G2, that is, the thickness of the adhesive A, by increasing or decreasing the thickness of the resin-rich layer 2, and to stably obtain the adhesive strength.
Without being particularly limiting, in order to more reliably achieve the above-described effects (A) and (B), the thickness of the resin-rich layer 2 is preferably 0.1 mm or more. The thickness is more preferably 0.5 mm or more, and even more preferably 1.0 mm or more.
The thickness of the resin-rich layer 2 is calculated as the difference between a thickness t2 of the resin layer constituting the surface of the resin-rich layer 2 in the hole peripheral portion 3X, and a thickness t1 of the resin layer constituting the surfaces 1a, 1b in the common portion (portion where the resin-rich layer 2 is not formed) of the FRP layer 1. The thicknesses t1, t2 can be calculated by observing, for example, with an electron microscope, a cross section perpendicular to the planar direction S. Here, the thickness t1 is defined as the average value of a prescribed number of measured values of the distance from the surfaces 1a, 1b of the FRP layer 1 to the reinforcing fibers F of the outermost layer. In addition, the thickness t2 is defined as the average value of a prescribed number of measured values of the distance from the surface of the resin-rich layer 2 to the reinforcing fibers F of the outermost layer.
Additionally, while not particularly limited, in order to more reliably achieve the above-described effects (A) and (B), the fiber content of the resin-rich layer 2 is preferably set to 80% or less of the fiber content of the FRP layer 1. The fiber content is more preferably 60% or less of the fiber content of the FRP layer 1, even more preferably 40% or less of the fiber content of the FRP layer 1, still more preferably 20% or less of the fiber content of the FRP layer 1, and most preferably 5% or less of the fiber content of the FRP layer 1.
The fiber content Vf of the resin-rich layer 2 can be calculated from the following formula (1).
Vf=100×volume of reinforcing fibers (volume of reinforcing fibers+volume of components other than reinforcing fibers) (1)
Specifically, in an example of a method in which components other than reinforcing fibers are removed from a sample of the resin-rich layer 2, the masses of the reinforcing fibers and the other components are determined; these mass values are converted into volumes using the densities of the respective components; and these volume values are applied to formula (1). Examples of methods for removing components other than reinforcing fibers from the sample include a method of removal by combustion (thermal decomposition), and a method of dissolution and removal by chemical substances. The fiber content Vf of the FRP layer 1 can be calculated in the same manner.
In a modified example of the present embodiment, discontinuous fibers, such as long fibers and short fibers, or a combination of continuous fibers and discontinuous fibers, may be employed as the reinforcing fibers F. Furthermore, in another modified example, part or all of the reinforcing fibers F may be randomly oriented. These modified examples are suitable when the shape of the member CM is complex and high formability is required. In addition, by these modified examples, in addition to the above-described effects (A), (B), and (D), it is possible to achieve the effect of further suppressing the peeling of the reinforcing fibers F with the structure of the reinforcing fibers F itself.
Next, the member CM according the second to the fourth embodiments will be described with reference to
In these embodiments, as illustrated in
Additionally, in the second to the fourth embodiments, the second resin-rich layer 22 is provided farther on the outside of the first resin-rich layer 21 in the radial direction of the hole 3. For this reason, it is possible to more accurately control the sizes of the gaps G1, G2, that is, the thickness of the adhesive A, by controlling the thickness of the second resin-rich layer 22, which is in a position away from the hole 3, and to more stably obtain the adhesive strength of the flange 42, the washer 5, and the like.
In particular, in the second embodiment, as illustrated in
In addition, in the third embodiment, as illustrated in
Moreover, in the third embodiment, as illustrated in
In addition, the annular protrusion 22a, the island-like protrusions 22b, and the linear protrusions 22c of the second to the fourth embodiments may be used in combinations of two or more.
Next, a method for efficiently producing the member CM will be described with reference to
The method for producing P1 the member CM will be described with reference to
First, a reinforcing fiber body 1f (reinforcing fiber base material) to be the reinforcing fibers F of the member CM is prepared from reinforcing fibers which have not been impregnated with resin, in a so-called dry state. The reinforcing fiber body 1f is formed by stacking reinforcing fiber bundles in one direction or at different angles and binding the bundles with stitch yarns or by retaining the shape by thermal fusion without using stitch yarns, or from a woven fabric of reinforcing fibers, etc. The reinforcing fibers constituting the reinforcing fiber body 1f may be continuous reinforcing fibers, discontinuous reinforcing fibers, or a combination thereof.
Next, as illustrated in
As illustrated in
Next, as illustrated in
Thereafter, the resin MR1 injected in the cavity CV is cured by pressurizing and heating the reinforcing fiber body 1f at the curing temperature (for example, 120-130° C.) of the resin MR1 with the upper die 9A and the lower die 9B. After the resin is cured, the resin MR1 injected into the reinforcing fiber body 1f is integrated with the reinforcing fiber body 1f and becomes the matrix resin MR of the FRP layer 1, and the reinforcing fiber body 1f becomes the reinforcing fibers F of the FRP layer 1. The resin MR1 injected in the gap CV1 becomes the resin-rich layer 2 after curing. Then, as illustrated in
Next, as illustrated in
Next, as illustrated in
As a result, as illustrated in
As described above, in the production method P1, the reinforcing fiber body if is enclosed in the molding die 9, and the molten resin MR1 is injected in the reinforcing fiber body 1f. Since it is thereby possible to precisely form the target shape by the molding surfaces 9a, 9b of the molding die 9, it is possible to efficiently produce a member CM that has a complex surface shape.
Additionally, the protrusions 92 are formed in areas of the upper die 9A and the lower die 9B that correspond to the portions to be bored 3Y, and the protrusions 92 hold the reinforcing fiber body 1f away from the bottom surface 91 of the recess 90 by a prescribed distance, while the resin MR1 spreads throughout the interior of the cavity CV. It is thereby possible to form on the surface layer of the portion to be bored 3Y the resin-rich layer 2 having a lower fiber content than the FRP layer 1 at a height corresponding to the protrusions 92. In addition, when the resin MR1 is injected, it is possible to suppress floating (meandering) of the fibers of the reinforcing fiber body 1f in the portion to be bored 3Y by pressing the fibers with the protrusions 92. It is thereby possible to improve the strength of the fastening portion FP of the member CM.
Although four of the protrusions 92 illustrated in
Next, another method for producing P2 the member CM will be described with reference to
First, a prepreg 1p (first sheet-like molding material) in which a reinforcing fiber base material, which becomes the reinforcing fibers F of the member CM, is impregnated with resin, and a resin-rich sheet 2p (second sheet-like molding material), which has a lower fiber content than the prepreg 1p, are produced. The material of the prepreg 1p is selected from materials to be the FRP layer 1 after the curing of the resin, and the material of the resin-rich sheet 2p is selected from materials to be the resin-rich sheet 2p after the curing of the resin.
Next, as illustrated in
Next, as illustrated in
Thereafter, the hole 3 is bored so as to penetrate the FRP layer 1 made of the cured prepreg 1p and the resin-rich layer 2 made of the cured resin-rich sheet 2p, and the collar 4 and the washer 5 are attached to the hole 3. The step for boring the hole 3 and the step for attaching the collar 4, and the like, are the same as the steps in the production method P1 described with reference to
As described above, in the production method P2, the resin-rich sheet 2p is superposed on the surface of the prepreg 1p, which are then pressure-molded by the molding die 10. In the production method P2, since the molten resin is not injected into the molding die 10, floating of the reinforcing fibers F does not occur in the portion to be bored 3Y. It is thereby possible to improve the strength of the fastening portion FP of the member CM.
Next, another method for producing P3 the member CM will be described with reference to
First, an FRP member 1m made of fiber-reinforced plastic and a resin-rich sheet member 2m (sheet member) having a lower fiber content than the FRP member 1m, are produced. The FRP member 1m can be made of the same material as the material of the FRP layer 1 of the member CM, and the resin-rich sheet member 2m can be made of the same material as the material of the resin-rich layer 2 of the member CM.
Next, as illustrated in
Thereafter, with respect to the bonded structure M3, the hole 3 is bored so as to penetrate the FRP member 1m and the resin-rich sheet member 2m, and the collar 4 and the washer 5 are attached to the hole 3. The step for boring the hole 3 and the step for attaching the collar 4, and the like, are the same as the steps in the production method P1 described with reference to
As described above, in the production method P3, since the hole 3 is formed in the bonded structure M3 obtained by adhering the resin-rich sheet member 2m on the surface of the FRP member 1m, molding using a molding die is not necessary, so that the number of steps is smaller than a method that uses a molding die, and thus the productivity is good.
Additionally, in the production method P3, since the molten resin is not injected into the reinforcing fiber base material, meandering of the reinforcing fibers F does not occur in the portion to be bored 3Y, and it is possible to improve the strength of the fastening portion FP of the member CM, in the same manner as the production method P2.
Other than the production methods P1-P3 described above, it is also possible to employ an autoclave method, an SMC method, a hand lay-up method, a spray-up method, or the like, as the method for producing the member CM.
Several embodiments were described above, but these embodiments are merely examples described in order to facilitate comprehension of the invention. The technical scope of the invention is not limited to the specific technical matters disclosed in the above-described embodiments and modified examples, and includes various modifications, changes, and alternatives that can be easily derived therefrom.
For example, in the above-described embodiments and modified examples, the FRP layer 1 is composed of fiber-reinforced plastic, but in order to increase the rigidity of the member CM, the FRP layer 1 may also include one or more core material made of other materials (for example, resin foam) as an intermediate layer. In addition, for example, a skin material for decoration may be provided on the surfaces 1a, 1b of the FRP layer 1.
Additionally, in the above-described embodiments and the modified examples, the resin-rich layer 2 is formed in the areas of the surface of the FRP layer 1 covered by the flange 42 and the washer 5, but the resin-rich layer 2 may be formed over a wider range, such as an area that includes the entire fastening portion FP.
Furthermore, in the above-described embodiments and the modified examples, the resin-rich layer 2 is formed on the surfaces 1a, 1b on both sides of the FRP layer 1, but the resin-rich layer 2 may be formed only on the surface 1a or 1b on one side of the FRP layer 1. Additionally, the cross-sectional shape of the hole 3 is not limited to a circle, and may be an oval, a rectangle, or the like.
The composite material member CM can be applied to components of vehicles such as automobiles, for example, hoods, door panels, bumpers, trunk lids, rear gates, fender panels, side body panels, and roof panels. In addition, the composite material member CM can be utilized as component members of transport vehicles, such as aircraft, ships, railcars, etc., domestic electric appliances, power generation facilities, production machines, housing equipment, furniture, leisure goods, or etc.
This application is a U.S. national stage application of International Application No. PCT/JP2017/009740, filed on Mar. 10, 2017.
Filing Document | Filing Date | Country | Kind |
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PCT/JP2017/009740 | 3/10/2017 | WO | 00 |