Patent Application
20060107602
This invention relates to a composite material, a method of making the composite material and a method of making a tool component.
Tool components utilising diamond compacts, also known as PCD, and cubic boron nitride compacts, also known as PcBN, are extensively used in drilling, milling, cutting and other such abrasive applications. The tool component will generally comprise a layer of PCD or PcBN bonded to a support, generally a cemented carbide support. The PCD or PcBN layer may present a sharp cutting edge or point or a cutting or abrasive surface.
PCD cutters are well-known and widely used in drill bit technology as the cutting element in drill bits used in core drilling, oil and gas drilling, and other similar applications. Such cutters generally comprise a PCD table formed on a hard metal substrate by a high temperature and high pressure sintering process. The substrate is then either brazed on an elongated support, or is directly brazed in a pocket of the drill bit, in a manner that exposes the PCD table to the surface for cutting.
It is known that PCD cutters inherently have residual stresses due to the mismatch of the properties of PCD to those of the substrate. The relevant properties in this context are the thermal expansion coefficient and the elastic moduli and compressibilities of the two materials. These stresses are particularly pronounced at the interface, but are present mostly throughout the cutter. These stresses tend to be compressive within the PCD layer and tensile within the substrate. However tensile stresses do exist within the PCD layer, particularly in cases where a non-planar interface is used. These stresses can combine with the applied stresses during the rock drilling process and bring about the fracture of the cutter.
Furthermore, such stresses are known to increase in magnitude during the brazing process used to attach the cutter to the drill bit. This increase in stress can cause fracture of the PCD layer or of the substrate, even without the application of an external stress.
Various solutions have been suggested in the art for modifying the residual stresses in PCD cutters in order to avoid such failures. For example, it has been suggested that configuring the diamond table and/or carbide substrate in a particular way may redistribute the stress such that tensile stresses are reduced, as disclosed in U.S. Pat. No. 5,351,772 to Smith, and U.S. Pat. No. 4,255,165 to Dennis. Other cutter configurations, which reduce residual stresses, are disclosed in U.S. Pat. No. 5,049,164 to Horton; U.S. Pat. No. 5,176,720 to Martell et al.; U.S. Pat. No. 5,304,342 to Hall; and U.S. Pat. No. 4,398,952 to Drake. Methods for relieving residual stresses by back-grinding the substrate, annealing, or by varying the properties of the substrate are disclosed in U.S. Pat. No. 6,220,375.
U.S. Pat. No. 4,604,106 to Hall et al discloses the use of precemented carbide particles in a PCD matrix in order to introduce a graded interface between the PCD table and the carbide substrate. A similar material is also disclosed in U.S. Pat. No. 4,525,178. Although this approach gives efficient grading of properties, it requires the preparation of carbide particles by crushing, which can be an expensive process. Furthermore such materials are known to chip, because the random disposition of the precemented carbide particles in the PCD matrix carries with it the possibility of various agglomerates forming in the body of the material, thus increasing its flaw size, and consequently reducing its strength.
U.S. Pat. No. 5,370,195 discloses drill bit inserts comprising a number of layers positioned between the substrate and the outer PCD layer. These intermediate layers are essentially diamond-carbide composites. Each composite is made out of individual diamond crystals mixed with tungsten carbide, or titanium carbide, or titanium carbonitride particles. Such materials are useful in managing the residual stresses in the drill bit inserts, but possess inferior strength and toughness, due to the poor adhesion of the diamond particles to the binder phases used.
Use of interfaces as a means of managing the residual stresses in a PCD cutter requires that the interface material has good wear resistance, that would be equal or slightly inferior to that of the PCD layer, and equal or better than that of the carbide substrate. This arrangement would ensure that during the cutting action a lip is formed below the PCD table, allowing for the concentration of stress at the cutting point, thus ensuring fracture of the rock being cut. If the wear resistance of the interlayer was less than that of the carbide support, the wear of the interlayer would be excessive, the PCD lip would loose support during the cutting action, and it would break. If the wear resistance of the interlayer is too high, the lip that develops in use is too shallow and the cutting action is not substantially improved. If the wear resistance of the interlayer is too low, the lip that develops is too deep and the PCD layer is not afforded sufficient support and the cutting edge fails prematurely. Therefore, there is an optimum relationship between the wear resistance of the PCD, the interlayer and that of the substrate.
U.K. Pat. No. 2,326,655 discloses the use of PCD granules in a carbide skin. These granules are then used to make a material that has good wear resistance and toughness, which is suitable as a wear part or as an interface material. Such a material relies on the tensile stresses generated in the carbide phase to cause cracking to run through this phase, thus improving this material's fracture toughness. In order to ensure that the crack does indeed run through the carbide phase, the grade chosen is fine grained and relatively brittle. Thus, no major improvement in toughness can be attained.
According to one aspect of the invention, a composite material comprises a plurality of cores of material selected from the group comprising carbides, nitrides, carbonitrides, cemented carbides, cemented nitrides, cemented carbonitrides and mixtures thereof, dispersed in a matrix, the matrix comprising the components for making an ultra-hard material and a suitable binder.
The ultra-hard material is polycrystalline in nature and is typically PCD or PcBN.
The cores are typically provided as individual particles or in the form of granules.
According to a further aspect of the invention, a method of producing a composite material as described above includes the steps of:
According to yet another aspect of the invention, a method of producing a tool component includes the steps of:
According to yet another aspect of the invention, a method of producing a tool component includes the steps of:
The cores are typically provided as granules coated with the components for making an ultra-hard material and the binder.
The granules may be further coated with a second coating comprising material selected from the group comprising carbides, nitrides, carbonitrides, cemented carbides, cemented nitrides, cemented carbonitrides, and mixtures thereof, or the components for making an ultra-hard material of a different grade to that of the first coating.
The composite may be a moulded composite which takes on the shape of the surface of the substrate on which it is placed and/or the shape of a surface of the ultra-hard material layer. In this regard, the composite may be pre-cast in the appropriate form or, alternatively, moulded in situ.
The composite material typically takes on a honeycomb structure of a hard material and cores within the pores of the honeycomb structure bonded to the honeycomb structure. The pores of the honeycomb structure may be ordered or random.
The components necessary to produce an ultra-hard material may comprise a mass of ultra-hard abrasive particles and optionally a second phase comprising a solvent/catalyst or a precursor to a solvent/catalyst, in particulate form, for the ultra-hard abrasive particle. Such components may include the superalloys, such as the Nimonic® and Stellite® alloys, and high temperature brazes.
The sintering conditions in step (iv) or step (v), as the case may be, are such that the ultra-hard abrasive particles are crystallographically stable.
The particles in the core and, where appropriate, in the coating, are provided in a suitable binder such as an organic binder. This binder will preferably be removed prior to the sintering of step (iv) or (v). Examples of suitable binders include but are not limited to camphor, methyl cellulose and polyethylene glycol.
The plurality of granules may be consolidated by applying pressure to the granules, for example, in a confined space such as a die. The consolidated composite is a green state product which has coherency, but which may also be severed, for example, by cutting. A piece which may be severed and removed from the consolidated or coherent composite has flexibility and may be applied to surfaces which are flat or profiled, e.g. a curved surface. The die for consolidating the granules may be provided with one or both punches profiled such that the green state product has at least one surface that has a shape complementary to the substrate upon which it is to be placed. In this case, the composite layer presents a working surface or a cutting edge. The other surface thereof may also be profiled to accommodate a further layer such as an ultra-hard material layer or another layer of a similar composite material but of a different composition, for instance in terms of the ultra-hard material content or in the grade of the ultra-hard material, presenting a working surface or cutting edge. In this case, the composite material provides an interlayer between the substrate and the cutting layer. In order to provide for a grading of properties, several interlayers of composite material having different compositions may be provided.
Where the cores of the composite material are formed from carbide particles, these will typically be tungsten carbide particles, titanium carbide particles, tantalum carbide particles or molybdenum carbide particles. The metal binder may be any metal binder known in the art such as iron, nickel, cobalt or an alloy containing one or more of these metals.
The substrate will typically be a cemented carbide substrate.
The granules may be produced by providing a core and then coating the core with an ultra-hard material in the presence of an organic binder. Coating may take place by fluidising the cores and spraying the coating thereon or by pelletising in a pan.
The invention will now be described in more detail, by way of example only, with reference to the accompanying drawings in which:
Referring to
The core 12 comprises a mixture of carbide particles and binder metal in particulate form.
The coating 14 comprises ultra-hard abrasive particles such as diamond or cubic boron nitride and optionally a metal or precursor in particulate form. Such metal may be a solvent/catalyst or another metal which will sinter under the applied conditions of temperature and pressure.
An organic binder such as methyl cellulose is present in both the core 12 and the coating 14 and provides both the core 12 and the coating 14 and the granule 10 as a whole with coherency. Other non-limiting examples of the organic binder include camphor and polyethylene glycol.
A plurality of the granules 16, as illustrated by
Although so-called uniaxial compression is described in this embodiment pressure may be applied from above and below the granules 16 or isostatically.
In an alternative embodiment of the invention, as shown in
A layer or portion 28 of the composite material is severed along line 30, as shown in
The portion or layer 28 has flexibility and may be placed on the surface 32, in this case an irregular surface, of a substrate 34, preferably a cemented carbide substrate, or between the surface 32 of the substrate 34 and a surface 36, in this case an irregular surface, of an abrasive layer 38, as shown in
The green state product of
Although the use of coated granules to form the composite material is preferred, any appropriate method may be used, such as mixing the various components, provided the cores are dispersed in the resultant matrix and do not form agglomerates.
The tool components of the invention can be used in a wide range of applications, but find particular application in drill bit applications, typically in roller cone bits and drag bits.
The composite material manufactured in accordance with the invention has several advantages over the prior art materials described earlier. The carbide cores are bonded to the PCD matrix via a strong mechanical keying arrangement, thus overcoming the problem of weak bonding of individual diamond particles to a cobalt matrix. Due to the properties mismatch between carbide and PCD, the carbide cores will be in a state of tension, while the PCD matrix will be in compression. The compressive stresses experienced by the PCD continuous matrix will increase the strength of the resulting material, compared to the strength of conventional PCD material. The carbide cores will be in tension. Cracks propagating through this material will be attracted to these regions. If the carbide grade used is a particularly tough one, then the propagation of this crack through this phase will be energetically costly. Thus crack propagation within the resulting material will be more difficult than it would be within conventional PCD. By using granules to create the composite carbide—PCD material, the danger of generating agglomerates of the carbide phase, or very large continuous fillets of PCD, are largely avoided. This allows for a tighter control of the defect size in such materials, thus ensuring more reproducible properties for them.
The combination of these advantages provides a material with good toughness, strength and wear resistance. These critical properties can be tailored to lie between those of substrate and PCD. By varying the grade of PCD as well as the volume fraction of this component in the composite cermet, both the wear resistance, as well as the elastic properties and the thermal expansion coefficient of the resulting composite can be varied to suit the purpose of a particular drill insert design.
Where the composite material of the invention is used as an interlayer, it allows for the production of tool components with much thicker PCD layers, due to the reduced stresses at the interface between the PCD layer and the intermediate layer as compared to the much higher stresses at the interface between the PCD layer and the substrate of a conventional tool component.
The invention will now be described further with reference to the following non-limiting examples.
A solvent based slurry of tungsten carbide powder was prepared with approximately 5 wt % organic binder. The WC powder was of the size 0 to 5 microns and contained 11% cobalt. The slurry was dried and crushed with pestle and mortar to produce green WC particles screened to about 200 to 300 microns in size. The granules were placed into a pan granulator and rolled while small additions of 2 micron diamond powder with an organic binder was added to effect coating. Volume % of WC granules to diamond coating was in the ratio of 1:1. The coated WC particles are depicted in
The same procedure as in Example 1 was followed except that the granule compact was not placed over a diamond powder bed. The resultant tool had a WC/PCD cutting table 50 on a WC substrate 52, as shown in the photograph of
In Example 1, the WC granule shape was uncontrolled leading to irregular shaped granules. As granules can be of any shape, the WC granules of Example 3 were made spherical before coating with diamond powder. The spherical shapes were achieved by rolling irregular shaped granules in a granulator with additions of WC powder to coat them. The granules were then sieved to achieve 200 to 300 micron sized pellets. These granules were then coated with diamond powder and a compact was pressed as in Example 1. The coated diamond granules are depicted in the photographs of
| Number | Date | Country | Kind |
|---|---|---|---|
| 2002/8731 | Oct 2002 | ZA | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/IB03/04788 | 10/29/2003 | WO | 10/3/2005 |
