Claims
- 1. An electrode material comprising:
- a composite oxide of A-site defect perovskite structure represented by the following general formula:
- (A'.sub.1-x A".sub.x).sub.1-.alpha. (B'.sub.1-y B".sub.y)O.sub.3-.delta.
- wherein A' is at least one element selected from the group consisting of La, Nd and Y, and A" is at least one element selected from the group consisting of Ba, Sr and Ca, and B' is Co and B" is at least one element selected from the group consisting of Mn, Fe, Ni and Cu, and 0.1<.alpha.<0.2, 0<.delta..ltoreq.1, 0<x<1 and 0<y<1; and
- - 20parts by weight of a fluorite oxide based on 100 parts by weight of the composite oxide.
- 2. An electrode material according to claim 1, wherein said fluorite oxide is selected from ceria, zirconia and a mixture thereof.
- 3. An electrode material according to claim 1, wherein 0.1<.alpha.<0.15.
- 4. An electrode material according to claim 1, wherein the composite oxide of A-site defect perovskite structure is represented by the following formula:
- (La.sub.1-x Sr.sub.x).sub.1-.alpha. (Co.sub.1-y B".sub.y)O.sub.3-.delta.
- wherein B" is at least one element selected from the group consisting of Mn, Fe, Ni and Cu, and 0.1<.alpha.<0.2, 0<.delta..ltoreq.1, 0<x<1 and 0<y<1.
- 5. An electrode material according to claim 4, wherein the composite oxide of A-site defect perovskite structure is represented by the following formula:
- (La.sub.1-x Sr.sub.x).sub.1-.alpha. (Co.sub.1-y Fe.sub.y)O.sub.3-.delta.
- wherein 0.1<.alpha.<0.2, 0<.delta..ltoreq.1, 0<x<1 and 0<y<1.
- 6. An electrode material according to claim 4, wherein the composite oxide of A-site defect perovskite structure is represented by the following formula:
- (La.sub.1-x Sr.sub.x).sub.1-.alpha. (Co.sub.1-y Mn.sub.y)O.sub.3-.delta.
- wherein 0.1<.alpha.<0.2, 0<.delta..ltoreq.1, 0<x<1 and 0<y<1.
- 7. An electrode material according to claim 4, wherein the composite oxide of A-site defect perovskite structure is represented by the following formula:
- (La.sub.1-x Sr.sub.x).sub.1-.alpha. (Co.sub.1-y Cu.sub.y)O.sub.3-.delta.
- wherein 0.1<.alpha.<0.2, 0<.delta..ltoreq.1, 0<x<1 and 0<y<1.
- 8. An electrode material according to claim 4, wherein the composite oxide of A-site defect perovskite structure is represented by the following formula:
- (La.sub.1-x Sr.sub.x).sub.1-.alpha. (Co.sub.1-y Ni.sub.y)O.sub.3-.delta.
- wherein 0.1<.alpha.<0.2, 0<.delta..ltoreq.1, 0<x<1 and 0<y<1.
- 9. An electrode material according to claim 1, wherein the composite oxide of A-site defect perovskite structure is represented by the following formula:
- (La.sub.1-x Ba.sub.x).sub.1-.alpha. (Co.sub.1-y Fe.sub.y)O.sub.3-.delta.
- wherein 0.1<.alpha.<0.2, 0<.delta..ltoreq.1, 0<x<1and 0<y<1.
Priority Claims (3)
Number |
Date |
Country |
Kind |
6-240106 |
Oct 1994 |
JPX |
|
6-267223 |
Oct 1994 |
JPX |
|
7-178658 |
Jul 1995 |
JPX |
|
Parent Case Info
This application is a divisional of application Ser. No. 08/536,185, filed Sep. 29, 1995 now U.S. Pat. No. 6,060,420.
US Referenced Citations (6)
Foreign Referenced Citations (5)
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JPX |
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7-136518 |
May 1995 |
JPX |
7-196382 |
Aug 1995 |
JPX |
Non-Patent Literature Citations (2)
Entry |
Higuchi et al., Changes in the Phases and Electrical Conduction Properties of (La.sub.1-x Sr.sub.x).sub.1-y MnO.sub.3-67 ,J. Electrochem. Soc. 138(5): 1519-1523 (1991), no month. |
Yoshioka, H. "X-ray Diffraction Analysis for Thin Films of PbTiO.sub.3 -La.sub.2/3 TiO.sub.3 Prepared By The Sol-gel Method", J. Mater. Res., vol. 9(8):2133-2137, (1994), no month. |
Divisions (1)
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Number |
Date |
Country |
Parent |
536185 |
Sep 1995 |
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