Claims
- 1. A composite semipermeable membrane which comprises a porous substrate and an ultrathin dense layer having solute removal structure positioned on said substrate, said ultrathin dense layer consisting essentially of (1) an oligomer composed of polyamine monomer and triazine represented by the general formula: ##STR8## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each represent a hydrogen atom or an alkyl group having 1 to 5 carbon atoms crosslinked with (2) polyamine monomer, as a main component, and with a polyfunctional crosslinking reagent having two or more functional groups capable of reacting with amino groups in oligomer molecules.
- 2. A composite semipermeable membrane according to claim 1, wherein said polyamine monomer of (2) is an aliphatic, alicyclic or aromatic polyamine having 2 to 25 carbon atoms and having two or more primary or secondary amino groups in each molecule.
- 3. A composite semipermeable membrane according to claim 1, wherein said polyfunctional crosslinking reagent is a compound having two or more functional groups selected from acid halide groups, acid anhydride groups, isocyanate groups, halogenosulfonyl groups, haloformate groups and N-haloformyl groups.
- 4. A composite semipermeable membrane according to claim 1, wherein said porous substrate is a porous membrane composed of polysulfone, polyether sulfone, cellulose ester, polypropylene, polyacrylonitrile, polyvinyl chloride, polyvinylidene fluoride, polyimide or polyamide imide.
- 5. A composite semipermeable membrane according to claim 1, wherein said porous substrate defines an asymmetric structure defining surface pore diameters of from 50 to 5000 .ANG. and a pure water flux after one hour at a pressure of 3.5 Kg/cm.sup.2 of from 10.sup.-5 to 1 g/cm.sup.2 -second-atmosphere.
- 6. A composite semipermeable membrane according to claim 1, wherein said ultrathin dense layer defines a thickness of from 50 to 10,000 .ANG..
- 7. A composite semipermeable membrane according to any one of claims 1-6, wherein said oligomer composed of said triazine and polyamine monomer has the general formula: ##STR9## wherein R.sup.1 to R.sup.5 each represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, R.sup.8 and R.sup.9 each represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms and R.sup.8 and R.sup.9 may bond together, A represents an aliphatic, alicyclic or aromatic hydrocarbon group having 2 to 25 carbon atoms which may contain primary or secondary amino groups, k represents 0 to 1, and h represents an integer of 1 to 10.
- 8. The composite semipermeable membrane of claim 1, wherein said polyamine monomer of (2) is present in an amount of 10 to 1,000 parts by weight based on 100 parts by weight of said oligomer.
- 9. The composite semipermeable membrane of claim 1, wherein said porous substrate is an anisotropic ultrafiltration membrane having a dense layer and said ultrathin dense layer is formed on the dense layer.
Priority Claims (1)
Number |
Date |
Country |
Kind |
56-48963 |
Mar 1981 |
JPX |
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Parent Case Info
This is a continuation of application Ser. No. 362,336, filed Mar. 26, 1982, now abandoned.
US Referenced Citations (8)
Continuations (1)
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Number |
Date |
Country |
Parent |
362336 |
Mar 1982 |
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