Composite sporting equipment

Information

  • Patent Grant
  • 10794650
  • Patent Number
    10,794,650
  • Date Filed
    Thursday, January 25, 2018
    6 years ago
  • Date Issued
    Tuesday, October 6, 2020
    4 years ago
Abstract
A sporting equipment is disclosed. The sporting equipment may include a harness, and a protective plate. The protective plate may be integrally formed with the harness from a plurality of fibers that are continuous from the harness into the protective plate.
Description
TECHNICAL FIELD

The present disclosure relates generally to sporting equipment and, more particularly, to sporting equipment made from a composite material via additive manufacturing.


BACKGROUND

Unique equipment is available for most any sport. For example, a racket may be used to play tennis, a club may be used to play golf, body armor may be used for motocross, a gun may be used for skeet or biathlon events, etc. Often, a quality of the equipment used during a sporting event can affect an outcome of the event. For example, a weight of the equipment, a strength of the equipment, a shape of the equipment, a flexibility of the equipment, a hardness of the equipment, a durability of the equipment, a conformability of the equipment, etc., can directly affect an acceleration, a speed, a distance, a force, an accuracy, a repeatability, a longevity, and other performance parameters. Unfortunately, conventional manufacturing capabilities may limit the available quality of conventional sporting equipment.


Some sporting equipment is manufactured from composite materials, which can enhance the quality of the equipment. For example, the frame of a tennis racket, the handle of a golf club, and the stock of a gun have been made from fiberglass, Kevlar, and carbon fibers using a vacuum-mold technique or a pultrusion process. Thereafter, the composite components are joined to other non-composite components (e.g., to strings, a head, a grip, a barrel, an action, etc.) using conventional techniques (e.g., gluing, welding, mechanical fastening, etc.). Sporting goods made from composite materials may have a reduced weight and/or increased strength or stiffness.


Although sporting equipment having composite components may have improved qualities, the associated benefits may be limited. In particular, the quality may be interrupted because of the conventional joining techniques used to connect the composite components to the associated non-composite components. In addition, conventional vacuum-mold techniques and pultrusion processes may limit the shape, size, and/or configuration possible within the composite components. In addition, it may be beneficial, in some applications, to receive feedback from the sporting equipment; and this may not be possible using conventionally manufactured equipment.


The disclosed sporting equipment is directed to overcoming one or more of the problems set forth above and/or other problems of the prior art.


SUMMARY

In one aspect, the present disclosure is directed to a sporting equipment. The sporting equipment may include a harness, and a protective plate. The protective plate may be integrally formed with the harness from a plurality of fibers that are continuous from the harness into the protective plate.


In another aspect, the present disclosure is directed to a method of fabricating a sporting equipment. This method may include wetting a continuous fiber with a matrix, and discharging a matrix-wetted continuous fiber through a nozzle. The method may also include moving the nozzle during discharging to extend the matrix-wetted continuous fiber from a harness through a protective plate, and curing a matrix in the matrix-wetted continuous fiber.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a diagrammatic illustration of an exemplary system for manufacturing sporting equipment; and



FIG. 2 is an isometric illustration of an exemplary sporting equipment that can be manufactured utilizing the system of FIG. 1.





DETAILED DESCRIPTION


FIG. 1 illustrates an exemplary system 10 for additively manufacturing sporting equipment 12. System 10 may implement any number of different additive processes during manufacture of sporting equipment 12. For example, sporting equipment 12 is shown in FIG. 1 as being manufactured via a first additive process and via a second additive process. It should be noted that the first and second additive processes may be performed simultaneously or consecutively, as desired. It should also be noted that sporting equipment 12 may be manufactured utilizing only one of the first and second additive processes.


The first additive process (represented in the lower-left of FIG. 1) may be a pultrusion and/or extrusion process, which creates hollow tubular structures 14 from a composite material (e.g., a material having a matrix and at least one continuous fiber). One or more heads 16 may be coupled to a support 18 (e.g., to a robotic arm) that is capable of moving head(s) 16 in multiple directions during discharge of structures 14, such that resulting longitudinal axes 20 of structures 14 are three-dimensional. Such a head is disclosed, for example, in U.S. patent application Ser. Nos. 15/130,412 and 15/130,207, all of which are incorporated herein in their entireties by reference.


Head(s) 16 may be configured to receive or otherwise contain the matrix material. The matrix material may include any type of liquid resin (e.g., a zero-volatile organic compound resin) that is curable. Exemplary matrixes include thermosets, single- or multi-part epoxy resins, polyester resins, cationic epoxies, acrylated epoxies, urethanes, esters, thermoplastics, photopolymers, polyepoxides, thiols, alkenes, thiol-enes, and more. In one embodiment, the pressure of the matrix material inside of head(s) 16 may be generated by an external device (e.g., an extruder or another type of pump) that is fluidly connected to head(s) 16 via corresponding conduits (not shown). In another embodiment, however, the pressure may be generated completely inside of head(s) 16 by a similar type of device and/or simply be the result of gravity acting on the matrix material. In some instances, the matrix material inside head(s) 16 may need to be kept cool and/or dark, in order to inhibit premature curing; while in other instances, the matrix material may need to be kept warm for the same reason. In either situation, head(s) 16 may be specially configured (e.g., insulated, chilled, and/or warmed) to provide for these needs.


The matrix material stored inside head(s) 16 may be used to coat any number of continuous fibers and, together with the fibers make up walls of composite structures 14. The fibers may include single strands, a tow or roving of several strands, or a weave of many strands. The strands may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, metallic wires, ceramic fibers, basalt fibers, etc. The fibers may be coated with the matrix material while the fibers are inside head(s) 16, while the fibers are being passed to head(s) 16, and/or while the fibers are discharging from head(s) 16, as desired. In some embodiments, a filler material (e.g., chopped fibers) may be mixed with the matrix material before and/or after the matrix material coats the fibers. The matrix material, the dry fibers, fibers already coated with the matrix material, and/or the filler may be transported into head(s) 16 in any manner apparent to one skilled in the art. The matrix-coated fibers may then pass over a centralized diverter (not shown) located at a mouth of head(s) 16, where the resin is caused to cure (e.g., from the inside-out, from the outside-in, or both) by way of one or more cure enhancers (e.g., UV lights, ultrasonic emitters, microwave generators, infrared heaters, chillers, etc.) 22.


In embodiments where sporting equipment 12 is made up of multiple structures 14, each structure 14 may be discharged adjacent another structure 14 and/or overlap a previously discharged structure 14. In this arrangement, subsequent curing of the liquid resin within neighboring structures 14 may bond structures 14 together. Any number of structures 14 may be grouped together and have any trajectory, shape, and size required to generate the desired shape of sporting equipment 12.


In some embodiments, a fill material (e.g., an insulator, a conductor, an optic, a surface finish, etc.) could be deposited inside and/or outside of structures 14, while structures 14 are being formed. For example, a hollow shaft (not shown) could extend through a center of and/or over any of the associated head(s) 16. A supply of material (e.g., a liquid supply, a foam supply, a solid supply, a gas supply, etc.) could then be connected with an end of the hollow shaft, and the material forced through the hollow shaft and onto particular surfaces (i.e., interior and/or exterior surfaces) of structure 14. It is contemplated that the same cure enhancer(s) 22 used to cure structure 14 could also be used to cure the fill material, if desired, or that additional dedicated cure enhancer(s) (not shown) could be used for this purpose. The fill materials could allow one or more of structures 14 to function as tanks, passages, conduits, ducts, etc.


The second additive manufacturing process (represented in the upper-right of FIG. 1) may also be a pultrusion and/or extrusion process. However, instead of discharging hollow tubular structures 14, the second additive manufacturing process may be used to discharge tracks, ribbons, and/or sheets of composite material (e.g., over tubular structures 14 and/or over other features of sporting equipment 12). In particular, one or more heads 24 may be coupled to a support 26 (e.g., to an overhead gantry) that is capable of moving head(s) 24 in multiple directions during fabrication of sporting equipment 12, such that resulting contours of sporting equipment 12 are multi-dimensional (e.g., three-dimensional).


Head 24 may be similar to head 16 and configured to receive or otherwise contain a matrix material (e.g., the same matrix material contained within head 16 or a different matrix material). The matrix material stored inside head(s) 24 may be used to coat any number of separate fibers, allowing the fibers to make up centralized reinforcements of the discharging tracks, ribbons, and/or sheets. The fibers may include single strands, a tow or roving of several strands, or a weave of multiple strands. The strands may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, metallic wires, etc. The fibers may be coated with the matrix material while the fibers are inside head(s) 24, while the fibers are being passed to head(s) 24, and/or while the fibers are discharging from head(s) 24, as desired. The matrix material, the dry fibers, and/or fibers already coated with the matrix material may be transported into head(s) 24 in any manner apparent to one skilled in the art. The matrix-coated fibers may then pass through one or more circular orifices, rectangular orifices, triangular orifices, or orifices of another curved or polygonal shape, where the fibers are pressed together and the matrix is caused to cure by way of one or more cure enhancers 22.


As described above, the first and second additive manufacturing processes can be extrusion or pultrusion processes. For example, extrusion may occur when the liquid matrix and the associated continuous fibers are pushed from head(s) 16 and/or head(s) 24 during the movement of supports 18 and/or 26. Pultrusion may occur after a length of matrix-coated fibers is connected to an anchor (not shown) and cured, followed by movement of head(s) 16 and/or head(s) 24 away from the anchor. The movement of head(s) 16 and/or head(s) 24 away from the anchor may cause the fibers to be pulled from the respective head(s), along with the coating of the matrix material.


In some embodiments, pultrusion may be selectively implemented to generate tension in the fibers that make up sporting equipment 12 and that remains after curing. In particular, as the fibers are being pulled from the respective head(s), the fibers may be caused to stretch. This stretching may create tension within the fibers. As long as the matrix surrounding the fibers cures and hardens while the fibers are stretched, at least some of this tension may remain in the fibers and function to increase a strength of the resulting composite structure.


Structures fabricated via conventional pultrusion methods may have increased strength in only a single direction (e.g., in the single direction in which fibers were pulled through the corresponding die prior to resin impregnation and curing). However, in the disclosed embodiment, the increased strength in sporting equipment 12 caused by residual tension within the corresponding fibers may be realized in the axial direction of each of the fibers. And because each fiber could be pulled in a different direction during discharge from head(s) 16 and/or 24, the tension-related strength increase may be realized in multiple (e.g., innumerable) different directions.


Structures fabricated via conventional pultrusion methods may have strength increased to only a single level (e.g., to a level proportionate to an amount in which the fibers were stretched by a pulling machine prior to resin impregnation and curing). However, in the disclosed embodiment, because the matrix surrounding each fiber may be cured and harden immediately upon discharge, the force pulling on the fiber may be continuously varied along the length of the fiber, such that different segments of the same fiber are stretched by different amounts. Accordingly, the residual tensile stress induced within each of the different segments of each different fiber may also vary, resulting in a variable strength within different areas of sporting equipment 12. This may be beneficial in variably loaded areas of sporting equipment 12.



FIG. 2 illustrates an exemplary embodiment of sporting equipment 12, which can be manufactured using one or both of the additive processes described above. In this embodiment, sporting equipment 12 is protective gear, such as body armor that can be used for motocross, football, hockey, paintball, etc. It is also contemplated that sporting equipment 12 of FIG. 2 could be used for non-sporting activities (e.g., military or police activities), if desired.


As protective gear, sporting equipment 12 may include, among other things, a harness 28, and any number of protection panels 30 that are interconnected and/or positioned on the user via harness 28. Harness 28 and protection panels 30 may be available in a variety of configurations, shapes, and sizes. For example, harness 28 may resemble clothing (e.g., a shirt, a jacket, trousers, gloves, footwear, etc.), a pack (e.g., a back- or front-pack), webbing or straps, etc. Protection panels 30 may include, among other things, a chest panel, a back panel, side panels, a groin panel, a collar panel, a deltoid panel, a shin panel, an elbow panel, etc. that are configured to protect the user from impacts (e.g., from user-ground impacts, from ballistics, from shrapnel, from other sporting equipment, etc.). Protection panels 30 may be separate from harness 28 (e.g., held within pockets of or otherwise adhered to harness 28) or integral with harness 28, as desired.


Harness 28, in addition to positioning and/or interconnecting protection panels 30, may perform other functions. For example, while perhaps not as capable of absorbing direct impacts as protection panels 30, harness 28 may still be capable of providing some level of protection from abrasion, deflected debris, environmental elements, etc. In addition, harness 28 may be configured to allow flexing between connected panels 30, ventilation between panels 30 and the user (e.g., for heating/cooling), and/or biofeedback.


As described above, harness 28 and one or more of protection panels 30 may be integrally formed. When any two more components of sporting equipment 12 are simultaneously manufactured to form a single monolithic structure, some or all of the fibers discharging from head(s) 16 and/or 24 (referring to FIG. 1) may be continuous through each of these components, such that thousands (if not millions) of fibers extend through intersections between the components, thereby creating strong mechanical connections without requiring the use of specialized hardware, glues, and/or heavy fasteners. It should be noted that, although harness 28 and panels 30 have been described above as being fabricated together as a single monolithic structure, one or more of these components could be fabricated separately and later joined (e.g., via chemical and/or mechanical means) to each other.


Each of these components may be formed via any combination of the first and second additive processes described above, and may consist of any number of different fibers (e.g., fibers of different materials, sizes, colors, and/or cross-sectional shapes) overlapping and/or interweaving with each other in any pattern, at any location, and with any desired density. For example, single fibers F or groupings of fibers F may be coated with matrix and strategically discharged as tracks from head 24 (referring to FIG. 1) to create the general structure of sporting equipment 12, while other fibers or groupings of fibers may be interwoven to create hollow tubes that are coated with matrix and strategically discharged as conduits C from head 16. These conduits C may then be used to provide ventilation, cooling, heating, etc. for the user.


In one exemplary embodiment, some of the fibers within the composite material making up one or more portions of sporting equipment 12 have unique characteristics. For example, while a majority of sporting equipment 12 may comprise a structural type fiber Fs (e.g., carbon fibers, fiberglass, or Kevlar fibers), some portions of sporting equipment 12 may include a functional type of fiber Ff (e.g., electrically conductive fibers, optical fibers, shape memory fibers, etc.). The functional type of fibers Ff may be selectively interwoven with the structural type fibers Fs at strategic locations. For example, electrically conductive fibers Ff may be located at high-stress regions (e.g., within protection panels 30) and used as strain gauges to detect loading conditions of sporting equipment 12.


In a similar manner, optical fibers Ff may be located at the same or other high-stress regions, and an energy beam passed therethrough. As these regions flex, the optical fibers Ff may be squeezed and/or closed, thereby generating an optical feedback signal indicative of the flexing. This information may be used to determine an impact location on the user, an impact strength or direction, an impact timing, etc. In some embodiments, a receiving and/or interpreting device (e.g., an interrogator) may be embedded within the sporting equipment 12 to receive, interpret, respond to, and/or remotely transmit the information


The electrically conductive fibers Ff and/or the optical fibers Ff may be coated with another material (e.g., insulation, a strength enhancing layer, etc.), if desired. Additionally, other electrical components (e.g., resistors, capacitors, LEDs, switches, batteries, filters, etc.) 32 may be extruded through heads 16, 24 and/or automatically picked-and-placed (e.g., via attachments associated with heads 16 and/or 24) during discharge of the fibers Ff Operation of these components may then be tuned and monitored to identify the user and/or to determine conditions of sporting equipment 12 and/or the user. For example, heart-rate sensors, blood pressure sensors, oxygen sensors, temperature sensors, etc. may be formed from components 32 and placed at strategic locations to provide the biofeedback (e.g., injury status or health) of the user.


The configuration of fibers within harness 28 and/or panels 30 (and/or the location/orientation relationship between harness 28 and panels 30) may be adjustable and/or user-customizable. For example, the material type, fiber size, color, shape, pattern, location, orientation, and/or density may be selectively adjusted to provide a desired performance of sporting equipment 12. These adjustments may be manually selected by an end-user and/or automatically selected based on characteristics of the user (e.g., based on a body scan of the user, a monitored performance of the user, etc.).


As shown in the enlargement of FIG. 2, because the matrix surrounding each fiber may be cured and harden immediately upon discharge, the fibers may not be required to lie in parallel flat layers on top of each other. Accordingly, the fibers making up harness 28 and/or panels 30 may be oriented in any desired direction. This may allow for interlocking of fiber layers and/or for the creation of unique (e.g., strengthening, rigidity-enhancing, flexibility-enhancing, vibration-dampening, impact-resisting) features.


In the exemplary embodiment shown in FIG. 2, the matrix within the composite material making up one or more portions of sporting equipment 12 has unique characteristics. For example, while a majority of harness 28 may comprise a flexible-type matrix Mf, some portions of sporting equipment 12 (e.g., protection panels 30) may include another type of matrix Mp (e.g., a pyrolized matrix that provides greater impact resistance and/or impact cushioning). The other type of matrix Mp may be selectively used to coat the fibers at strategic locations.


In some applications, it may be beneficial to fabricate one or more protection panels 30 separate from harness 28, and thereafter integrate the pre-fabricated panels 30 into harness 28. For example, when protection panels 30 are to be pyrolized, panels 30 may first need to be fabricated by system 10 using a pre-ceramic type matrix. Thereafter, panels 30 may need to be heated to temperatures that would otherwise damage the matrixes of harness 28. After the conversion of the pre-ceramic type of matrix within panels 30 to the pyrolized ceramic material, panels 30 may then be embedded within harness 28.


Panels 30 may be embedded within harness 28 in multiple ways. In a first example, after a base layer of harness 28 has been fabricated (i.e., after the associated matrix in the base layer has been cured), panels 30 may be positioned adjacent the base layer, and a subsequent layer of harness 28 may be discharged to lock panels 30 in place. In a second example, harness 28 may be almost completely formed, with only strategic portions of the associated matrix being left uncured. After inserting panels 30 into harness 28, those previously uncured portions may be overlapped, wrapped around, and/or interwoven into panels 30 and thereafter cured. In a final example, pockets may be fabricated within harness 28, into which panels 30 are inserted. The pockets could be fully formed and cured during a first step of the process, or only partially formed and/or partially cured prior to panel insertion. After panel insertion, a follow-up step could be implemented, wherein the pocket is closed and cured.


In one example, a unique matrix may be used for accommodating a separately fabricated panel 30. The unique matrix may be, for example, a “click” or reversible resin (e.g., a Triazolinedione, a covalent-adaptable network, a spatioselective reversible resin, etc.). A reversible resin is a photopolymer having controllable molecularization. Specifically, when a reversible resin is exposed to a first wavelength of light (e.g., about 250 nm), the resin is cured during a phase change from a first state (e.g., a liquid state) to a second state (e.g., a solid state). And when the same resin is subsequently exposed to a second wavelength of light (e.g., about 300 nm), the resin reverses phase (e.g., only partially or completely) back to the first state.


In the separate-panel embodiment described above, the first wavelength of light may be provided by cure enhancer 22 during normal fabrication of harness 28 utilizing a reversible resin as the matrix surrounding the continuous fiber reinforcement. In this same embodiment, the second wavelength of light may be provided (e.g., by cure enhancer 22 or a separate and dedicated deactivator—not shown) to soften the harness and allow for insertion of a pre-fabricated panel 30. Thereafter, harness 28 may again be exposed to the first wavelength of light to cause harness 30 to harden and lock panel 30 in place. For example, a flap or pocket could be fabricated that includes a hinge made using the reversible resin. After properly positioning the pre-fabricated panel 30, the hinge could be softened, and the flap or pocket could be pivoted to a locking position, followed by re-hardening of the hinge.


INDUSTRIAL APPLICABILITY

The disclosed arrangement and design of sporting equipment 12 may be used in connection with any sporting event. Sporting equipment 12 may be light-weight and low-cost, due to a reduction in the number of fasteners required to join the various components to each other. In addition, sporting equipment 12 may be light-weight do to the use of composite materials. High-performance may be provided in the unique ways that particular fibers, resins, and functional components are used and laid out within sporting equipment 12.


It will be apparent to those skilled in the art that various modifications and variations can be made to the disclosed sporting equipment. Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the disclosed sporting equipment. For example, although sporting equipment 12 is described above as being fabricated from matrix-wetted reinforcements, it is contemplated that portions (e.g., structurally insignificant areas and/or an outer skin) of sporting equipment 12 may be fabricated from only the matrix, if desired. It is intended that the specification and examples be considered as exemplary only, with a true scope being indicated by the following claims and their equivalents.

Claims
  • 1. A sporting equipment, comprising: a harness configured to be worn on an upper body of a human, the harness having at least a front portion and a back portion and being fabricated from a plurality of fibers; anda protective panel at least partially surrounded and supported by the harness, the protective panel being integrally formed from the plurality of fibers of the harness and configured to protect the human from an impact injury,wherein the plurality of fibers are continuous from the harness into the protective panel, the plurality of fibers are at least partially coated with a first matrix in the harness and a second matrix in the protective panel, and the first and second matrixes are different.
  • 2. The sporting equipment of claim 1, further including a functional component imbedded within at least one of the harness and the protective panel.
  • 3. The sporting equipment of claim 2, wherein the functional component is configured to generate a signal upon impact of the protective panel.
  • 4. The sporting equipment of claim 2, wherein the functional component is configured to generate a signal indicative of biofeedback associated with a user wearing the harness.
  • 5. The sporting equipment of claim 2, wherein the functional component is at least one of a resistor, a capacitor, an LED, a switch, a battery, a filter, and an interrogator.
  • 6. The sporting equipment of claim 1, wherein at least one of the harness and protective panel are fabricated from a plurality of different types of fibers.
  • 7. The sporting equipment of claim 6, wherein the plurality of different types of fibers includes: a structural type of fiber; anda functional type of fiber.
  • 8. The sporting equipment of claim 7, wherein the functional type of fiber includes at least one of an electrically conductive fiber, an optical fiber, and a shape memory fiber.
  • 9. The sporting equipment of claim 7, wherein the structural type of fiber includes at least one of an aramid fiber, a carbon fiber, and a glass fiber.
  • 10. The sporting equipment of claim 6, further including a plurality of conduits interwoven with the plurality of different types of fibers.
  • 11. The sporting equipment of claim 10, wherein each of the plurality of conduits are woven from a plurality of fibers.
  • 12. The sporting equipment of claim 1, wherein: the first matrix includes a structural type of resin that is stiff after curing; andthe second matrix includes a functional type of resin that is flexible after curing.
  • 13. The sporting equipment of claim 1, wherein the plurality of fibers overlap in at least one of different directions and different densities.
  • 14. A sporting equipment, comprising: a harness configured to be worn by a human;a protective panel operatively supported by the harness and configured to protect the human from an impact injury; anda functional component disposed in the protective panel, wherein: the harness and the protective panel are formed from a plurality of fibers;the plurality of fibers includes a structural type of fiber and a functional type of fiber; andthe functional component is connected between ends of the functional type of fiber.
  • 15. The sporting equipment of claim 14, wherein the functional component is configured to at least one of generate a signal upon impact of the protective plate and generate a signal indicative of biofeedback associated with a user wearing the harness.
  • 16. The sporting equipment of claim 15, wherein the functional type of fiber includes at least one of an electrically conductive fiber, an optical fiber, and a shape memory fiber.
  • 17. A sporting equipment, comprising: a harness configured to be worn by a human and fabricated from a plurality of fibers coated in a first matrix; anda protective panel configured to protect the human from an impact injury and integrally formed from the plurality of fibers of the harness, the plurality of fibers in the protective panel being coated in a second matrix different from the first matrix.
  • 18. The sporting equipment of claim 17, further including a functional component imbedded within at least one of the harness and the protective panel and configured to generate a signal upon impact of the protective panel.
  • 19. The sporting equipment of claim 17, wherein: the protective panel is more impact resistant than the harness; andthe harness and protective panel are integrally fabricated.
  • 20. The sporting equipment of claim 17, wherein: the protective panel is a first protective panel;the sporting equipment includes at least a second protective panel integrally formed from the plurality of fibers of the harness; andthe harness is at least one of flexible and ventilated between the first and second protective panels.
RELATED APPLICATIONS

This application is based on and claims the benefit of priority from U.S. Provisional Application No. 62/458,328 that was filed on Feb. 13, 2017, the contents of which are expressly incorporated herein by reference.

US Referenced Citations (211)
Number Name Date Kind
3286305 Seckel Nov 1966 A
3809514 Nunez May 1974 A
3984271 Gilbu Oct 1976 A
3993726 Moyer Nov 1976 A
4643940 Shaw et al. Feb 1987 A
4671761 Adrian et al. Jun 1987 A
4822548 Hempel Apr 1989 A
4839777 Janko Jun 1989 A
4851065 Curtz Jul 1989 A
5002712 Goldmann et al. Mar 1991 A
5037691 Medney et al. Aug 1991 A
5070436 Alexander Dec 1991 A
5296335 Thomas et al. Mar 1994 A
5340433 Crump Aug 1994 A
5530966 West Jul 1996 A
5590908 Carr Jan 1997 A
5746967 Hoy et al. May 1998 A
5775715 Vandergrift Jul 1998 A
5809861 Hummel Sep 1998 A
5866058 Batchelder et al. Feb 1999 A
5936861 Jang et al. Aug 1999 A
6153034 Lipsker Nov 2000 A
6286145 Welchel Sep 2001 B1
6341384 Hayes Jan 2002 B1
6381482 Jayaraman et al. Apr 2002 B1
6459069 Rabinovich Oct 2002 B1
6501554 Hackney et al. Dec 2002 B1
6595938 Delmore et al. Jul 2003 B1
6769138 Golle Aug 2004 B2
6799081 Hale et al. Sep 2004 B1
6803003 Rigali et al. Oct 2004 B2
6934600 Jang et al. Aug 2005 B2
7039485 Engelbart et al. May 2006 B2
7043766 Foreman et al. May 2006 B1
7080849 Lammer Jul 2006 B2
7555404 Brennan et al. Jun 2009 B2
7795349 Bredt et al. Sep 2010 B2
8221669 Batchelder et al. Jul 2012 B2
8962717 Roth et al. Feb 2015 B2
9126365 Mark et al. Sep 2015 B1
9126367 Mark et al. Sep 2015 B1
9149988 Mark et al. Oct 2015 B2
9156205 Mark et al. Oct 2015 B2
9186846 Mark et al. Nov 2015 B1
9186848 Mark et al. Nov 2015 B2
9327452 Mark et al. May 2016 B2
9327453 Mark et al. May 2016 B2
9370896 Mark Jun 2016 B2
9381702 Hollander Jul 2016 B2
9457521 Johnston et al. Oct 2016 B2
9458955 Hammer et al. Oct 2016 B2
9527248 Hollander Dec 2016 B2
9539762 Durand et al. Jan 2017 B2
9579851 Mark et al. Feb 2017 B2
9688028 Mark et al. Jun 2017 B2
9694544 Mark et al. Jul 2017 B2
9764378 Peters et al. Sep 2017 B2
9770876 Farmer et al. Sep 2017 B2
9782926 Witzel et al. Oct 2017 B2
20010001770 Spangler et al. May 2001 A1
20020009935 Hsiao et al. Jan 2002 A1
20020062909 Jang et al. May 2002 A1
20020113331 Zhang et al. Aug 2002 A1
20020165304 Mulligan et al. Nov 2002 A1
20030044539 Oswald Mar 2003 A1
20030056870 Comb et al. Mar 2003 A1
20030160970 Basu et al. Aug 2003 A1
20030186042 Dunlap et al. Oct 2003 A1
20030192351 Meckley et al. Oct 2003 A1
20030236588 Jang et al. Dec 2003 A1
20040019950 Rast Feb 2004 A1
20040128747 Bumbarger Jul 2004 A1
20050006803 Owens Jan 2005 A1
20050061422 Martin Mar 2005 A1
20050073834 Langley Apr 2005 A1
20050104257 Gu et al. May 2005 A1
20050109451 Hauber et al. May 2005 A1
20050230029 Vaidyanathan et al. Oct 2005 A1
20070003650 Schroeder Jan 2007 A1
20070228592 Dunn et al. Oct 2007 A1
20080150254 Inge Jun 2008 A1
20080176092 Owens Jul 2008 A1
20090095410 Oldani Apr 2009 A1
20090188017 Kruse Jul 2009 A1
20100093241 Medoff Apr 2010 A1
20100100997 Lee Apr 2010 A1
20100122832 Bukshpun May 2010 A1
20100162604 Dubois Jul 2010 A1
20100190586 House Jul 2010 A1
20110032301 Fienup et al. Feb 2011 A1
20110070968 Stites Mar 2011 A1
20110136602 Hsu et al. Jun 2011 A1
20110143108 Fruth et al. Jun 2011 A1
20120060468 Dushku et al. Mar 2012 A1
20120115631 Tseng et al. May 2012 A1
20120159785 Pyles et al. Jun 2012 A1
20120231225 Mikulak et al. Sep 2012 A1
20120233740 Veillet Sep 2012 A1
20120247655 Erb et al. Oct 2012 A1
20120276309 Failing Nov 2012 A1
20130164498 Langone et al. Jun 2013 A1
20130209600 Tow Aug 2013 A1
20130233471 Kappesser et al. Sep 2013 A1
20130292039 Peters et al. Nov 2013 A1
20130337256 Farmer et al. Dec 2013 A1
20130337265 Farmer Dec 2013 A1
20140020192 Jones et al. Jan 2014 A1
20140034214 Boyer et al. Feb 2014 A1
20140061974 Tyler Mar 2014 A1
20140159284 Leavitt Jun 2014 A1
20140232035 Bheda Aug 2014 A1
20140268604 Wicker et al. Sep 2014 A1
20140291886 Mark et al. Oct 2014 A1
20150136455 Fleming May 2015 A1
20150297973 Beers Oct 2015 A1
20160012935 Rothfuss Jan 2016 A1
20160031155 Tyler Feb 2016 A1
20160046082 Fuerstenberg Feb 2016 A1
20160052208 Debora et al. Feb 2016 A1
20160082641 Bogucki et al. Mar 2016 A1
20160082659 Hickman et al. Mar 2016 A1
20160107379 Mark et al. Apr 2016 A1
20160114532 Schirtzinger et al. Apr 2016 A1
20160136885 Nielsen-Cole et al. May 2016 A1
20160144565 Mark et al. May 2016 A1
20160144566 Mark et al. May 2016 A1
20160192741 Mark Jul 2016 A1
20160200047 Mark et al. Jul 2016 A1
20160243762 Fleming et al. Aug 2016 A1
20160258713 Huang et al. Sep 2016 A1
20160263806 Gardiner Sep 2016 A1
20160263822 Boyd Sep 2016 A1
20160263823 Espiau et al. Sep 2016 A1
20160271876 Lower Sep 2016 A1
20160297104 Guillemette et al. Oct 2016 A1
20160311165 Mark et al. Oct 2016 A1
20160325491 Sweeney et al. Nov 2016 A1
20160332369 Shah et al. Nov 2016 A1
20160339633 Stolyarov et al. Nov 2016 A1
20160341517 Williams Nov 2016 A1
20160346998 Mark et al. Dec 2016 A1
20160361869 Mark et al. Dec 2016 A1
20160368213 Mark Dec 2016 A1
20160368255 Witte et al. Dec 2016 A1
20170007359 Kopelman et al. Jan 2017 A1
20170007360 Kopelman et al. Jan 2017 A1
20170007361 Boronkay et al. Jan 2017 A1
20170007362 Chen et al. Jan 2017 A1
20170007363 Boronkay Jan 2017 A1
20170007365 Kopelman et al. Jan 2017 A1
20170007366 Kopelman et al. Jan 2017 A1
20170007367 Li et al. Jan 2017 A1
20170007368 Boronkay Jan 2017 A1
20170007386 Mason et al. Jan 2017 A1
20170008333 Mason et al. Jan 2017 A1
20170015059 Lewicki Jan 2017 A1
20170015060 Lewicki et al. Jan 2017 A1
20170021565 Deaville Jan 2017 A1
20170028434 Evans et al. Feb 2017 A1
20170028588 Evans et al. Feb 2017 A1
20170028617 Evans et al. Feb 2017 A1
20170028619 Evans et al. Feb 2017 A1
20170028620 Evans et al. Feb 2017 A1
20170028621 Evans et al. Feb 2017 A1
20170028623 Evans et al. Feb 2017 A1
20170028624 Evans et al. Feb 2017 A1
20170028625 Evans et al. Feb 2017 A1
20170028627 Evans et al. Feb 2017 A1
20170028628 Evans et al. Feb 2017 A1
20170028633 Evans et al. Feb 2017 A1
20170028634 Evans et al. Feb 2017 A1
20170028635 Evans et al. Feb 2017 A1
20170028636 Evans et al. Feb 2017 A1
20170028637 Evans et al. Feb 2017 A1
20170028638 Evans et al. Feb 2017 A1
20170028639 Evans et al. Feb 2017 A1
20170028644 Evans et al. Feb 2017 A1
20170030207 Kittleson Feb 2017 A1
20170036403 Ruff et al. Feb 2017 A1
20170050340 Hollander Feb 2017 A1
20170057164 Hemphill et al. Mar 2017 A1
20170057165 Waldrop et al. Mar 2017 A1
20170057167 Tooren et al. Mar 2017 A1
20170057181 Waldrop et al. Mar 2017 A1
20170064840 Espalin et al. Mar 2017 A1
20170066187 Mark et al. Mar 2017 A1
20170087768 Bheda Mar 2017 A1
20170106565 Braley et al. Apr 2017 A1
20170120519 Mark May 2017 A1
20170129170 Kim et al. May 2017 A1
20170129171 Gardner et al. May 2017 A1
20170129176 Waatti et al. May 2017 A1
20170129182 Sauti et al. May 2017 A1
20170129186 Sauti et al. May 2017 A1
20170144375 Waldrop et al. May 2017 A1
20170151728 Kunc et al. Jun 2017 A1
20170157828 Mandel et al. Jun 2017 A1
20170157831 Mandel et al. Jun 2017 A1
20170157844 Mandel et al. Jun 2017 A1
20170157851 Nardiello et al. Jun 2017 A1
20170165908 Pattinson et al. Jun 2017 A1
20170173868 Mark Jun 2017 A1
20170182712 Scribner et al. Jun 2017 A1
20170210074 Ueda et al. Jul 2017 A1
20170217088 Boyd et al. Aug 2017 A1
20170232674 Mark Aug 2017 A1
20170259502 Chapiro et al. Sep 2017 A1
20170259507 Hocker Sep 2017 A1
20170266876 Hocker Sep 2017 A1
20170274585 Armijo et al. Sep 2017 A1
20170284876 Moorlag et al. Oct 2017 A1
Foreign Referenced Citations (33)
Number Date Country
4102257 Jul 1992 DE
102006035274 Feb 2008 DE
2589481 Jan 2016 EP
3219474 Sep 2017 EP
3231488 Oct 2017 EP
100995983 Nov 2010 KR
101172859 Aug 2012 KR
2005047801 May 2005 WO
2008149183 Dec 2008 WO
2013017284 Feb 2013 WO
2016088042 Jun 2016 WO
2016088048 Jun 2016 WO
2016092132 Jun 2016 WO
2016110444 Jul 2016 WO
2016159259 Oct 2016 WO
2016196382 Dec 2016 WO
2017006178 Jan 2017 WO
2017006324 Jan 2017 WO
2017051202 Mar 2017 WO
2017081253 May 2017 WO
2017085649 May 2017 WO
2017087663 May 2017 WO
2017108758 Jun 2017 WO
2017122941 Jul 2017 WO
2017122942 Jul 2017 WO
2017122943 Jul 2017 WO
2017123726 Jul 2017 WO
2017124085 Jul 2017 WO
2017126476 Jul 2017 WO
2017126477 Jul 2017 WO
2017137851 Aug 2017 WO
2017142867 Aug 2017 WO
2017150186 Sep 2017 WO
Non-Patent Literature Citations (13)
Entry
International Search Report dated Apr. 19, 2018 for PCT/US2018/015353 to CC3D LLC Filed Jan. 26, 2018.
A. Di. Pietro & Paul Compston, Resin Hardness and Interlaminar Shear Strength of a Glass-Fibre/Vinylester Composite Cured with High Intensity Ultraviolet (UV) Light, Journal of Materials Science, vol. 44, pp. 4188-4190 (Apr. 2009).
A. Endruweit, M. S. Johnson, & A. C. Long, Curing of Composite Components by Ultraviolet Radiation: A Review, Polymer Composites, pp. 119-128 (Apr. 2006).
C. Fragassa, & G. Minak, Standard Characterization for Mechanical Properties of Photopolymer Resins for Rapid Prototyping, 1st Symposium on Multidisciplinary Studies of Design in Mechanical Engineering, Bertinoro, Italy (Jun. 25-28, 2008).
Hyouk Ryeol Choi and Se-gon Roh, In-pipe Robot with Active Steering Capability for Moving Inside of Pipelines, Bioinspiration and Robotics: Walking and Climbing Robots, Sep. 2007, p. 544, I-Tech, Vienna, Austria.
Kenneth C. Kennedy II & Robert P. Kusy, UV-Cured Pultrusion Processing of Glass-Reinforced Polymer Composites, Journal of Vinyl and Additive Technology, vol. 1, Issue 3, pp. 182-186 (Sep. 1995).
M. Martin-Gallego et al., Epoxy-Graphene UV-Cured Nanocomposites, Polymer, vol. 52, Issue 21, pp. 4664-4669 (Sep. 2011).
P. Compston, J. Schiemer, & A. Cvetanovska, Mechanical Properties and Styrene Emission Levels of a UV-Cured Glass-Fibre/Vinylester Composite, Composite Structures, vol. 86, pp. 22-26 (Mar. 2008).
S Kumar & J.-P. Kruth, Composites by Rapid Prototyping Technology, Materials and Design, (Feb. 2009).
S. L. Fan, F. Y. C. Boey, & M. J. M. Abadie, Uv Curing of a Liquid Based Bismaleimide-Containing Polymer System, eXPRESS Polymer Letters, vol. 1, No. 6, pp. 397-405 (2007).
T. M. Llewelly-Jones, Bruce W. Drinkwater, and Richard S. Trask; 3D Printed Components With Ultrasonically Arranged Microscale Structure, Smart Materials and Structures, 2016, pp. 1-6, vol. 25, IOP Publishing Ltd., UK.
Vincent J. Lopata et al., Electron-Beam-Curable Epoxy Resins for the Manufacture of High-Performance Composites, Radiation Physics and Chemistry, vol. 56, pp. 405-415 (1999).
Yugang Duan et al., Effects of Compaction and UV Exposure on Performance of Acrylate/Glass-Fiber Composites Cured Layer by Layer, Journal of Applied Polymer Science, vol. 123, Issue 6, pp. 3799-3805 (May 15, 2012).
Related Publications (1)
Number Date Country
20180229100 A1 Aug 2018 US
Provisional Applications (1)
Number Date Country
62458328 Feb 2017 US