The present application is National Phase of International Application Number PCT/JP2013/062834 filed May 7, 2013 and claims the priority of Japanese patent Application No. 2012-107768 filed May 9, 2012 and of Japanese patent Application No. 2012-107805 filed May 9, 2012.
The present invention relates to a composite stretchable member.
Known in the art is a composite stretchable member which can stretch in a first direction (see PTL 1). This composite stretchable member is provided with a first nonwoven sheet and a second nonwoven sheet which are superposed on each other and a plurality of elastic members which are arranged between the first nonwoven sheet and the second nonwoven sheet. The first nonwoven sheet and the second nonwoven sheet are joined with each other at joined parts which are provided discontinuously in the first direction and a second direction which is perpendicular to the first direction. The elastic members extend in the first direction while separated from each other in the second direction without passing through the joined parts and are fastened to the first nonwoven sheet and the second nonwoven sheet at the two ends of the composite stretchable member in the first direction. As a result, in the contracted state, the first nonwoven sheet parts between two joined parts adjoining each other in the first direction deform in convex shapes outward in the thickness direction at one surface of the composite stretchable member, while the second nonwoven sheet parts between two joined parts adjoining each other in the first direction deform in convex shapes outward in the thickness direction at the other surface of the composite stretchable member. As a result, at one surface of the composite stretchable member, a large number of pleats are formed in the second direction by the first nonwoven sheet, while at the other surface of the composite stretchable member, a large number of pleats are formed in the second direction by the first nonwoven sheet.
PTL 1: Japanese Patent Publication No. 2005-80859A
The above-mentioned composite stretchable member is, for example, used for a member which contacts the skin of the wearer or is visible when worn such as a waist member which is positioned around the waist of the wearer of a disposable diaper.
In this case, from the viewpoint of contacting the skin of the wearer, the composite stretchable member preferably has a higher flexibility.
Further, if the composite stretchable member is high in heat retaining function, the temperature of the body surface of the wearer becomes higher and sweating or skin trouble is liable to occur. Therefore, the composite stretchable member is preferably low in heat retaining function. That is, the composite stretchable member is preferably small in thickness.
Furthermore, from the viewpoint of contacting the skin of the wearer, the composite stretchable member preferably has a more superior feeling. Furthermore, from the viewpoint of the visibility, the composite stretchable member preferably has a better look. That is, the pleats which are formed at the composite stretchable member are preferably smaller or more uniform.
In PTL 1, it may be considered that each first nonwoven sheet part between two joined parts which adjoin each other in the first direction forms a single pleat which is relatively higher, while each second nonwoven sheet part forms a single pleat which is relatively higher. However, it is difficult to form a single pleat between joined parts. In actually, a plurality of pleats which are relatively lower tend to be uniformly formed. That is, parts where the nonwoven sheet is superposed in multiple folds are liable to be formed at the composite stretchable member. Those parts are inferior in flexibility, so it is difficult to obtain uniformly excellent flexibility.
Further, the thickness of the composite stretchable member which is described in PTL 1, generally speaking, corresponds to the total of the height of the pleats which are formed by the first nonwoven sheet at one surface of the composite stretchable member and the height of the pleats which are formed by the second nonwoven sheet at the other surface of the composite stretchable member. Therefore, it is difficult to reduce the thickness of this composite stretchable member. Further, due to the pleats, an air layer is formed between the first nonwoven sheet and the second nonwoven sheet, so the heat retaining function of the composite stretchable member is increased and sweating etc. are liable to easily occur.
Furthermore, in PTL 1, it is considered that the first nonwoven sheet part between two joined parts adjoining each other in the first direction forms a single pleat and the second nonwoven sheet part forms a single pleat. However, it is difficult to form a single pleat between joined parts. In actuality, a plurality of pleats tend to be formed unevenly. That is, it is difficult for uniform pleats to be formed.
On this point, if reducing the intervals between the joined parts in the first direction, uniform pleats may be formed. However, if reducing the intervals, the area and number of joined parts per unit area of the composite stretchable member become greater and the composite stretchable member is liable to fall in flexibility. If reducing the areas of the individual joined parts to suppress a fall in flexibility, the first nonwoven sheet and the second nonwoven sheet will easily peel off from each other.
According to a first aspect of the present invention, there is provided a composite stretchable member which can stretch in a first direction, the composite stretchable member comprising a first nonwoven sheet part and a second nonwoven sheet part which are superposed each other and a plurality of elastic members which are arranged between the first nonwoven sheet part and the second nonwoven sheet part, the elastic members extending in the first direction while being separated from each other in a second direction perpendicular to the first direction, the first nonwoven sheet part and the second nonwoven sheet part joined with each other by an adhesive which is applied to the elastic members.
According to a second aspect of the present invention, there is provided a composite stretchable member which can stretch in a first direction, the composite stretchable member comprising a first nonwoven sheet part and a second nonwoven sheet part which are superposed each other and a plurality of elastic members which are arranged between the first nonwoven sheet part and the second nonwoven sheet part, the elastic members extending in the first direction while being separated from each other in a second direction perpendicular to the first direction, the first nonwoven sheet part and the second nonwoven sheet part joined with each other by an adhesive which is applied to the elastic members, a thickness when applying 3 gf/cm2 of pressure in the thickness direction to the composite stretchable member in a 50% stretched state being 2.0 mm or less, and a root mean square height of a profile curve in a 50% stretched state being 0.4 mm or less.
According to a third aspect of the present invention, there is provided a composite stretchable member which can stretch in a first direction, the composite stretchable member comprising a first nonwoven sheet part and a second nonwoven sheet part which are superposed each other and a plurality of elastic members which are arranged between the first nonwoven sheet part and the second nonwoven sheet part, the elastic members extending in the first direction while being separated from each other in a second direction perpendicular to the first direction, the first nonwoven sheet part and the second nonwoven sheet part joined with each other by an adhesive which is applied to the elastic members, and a coefficient of variation of length of profile curve elements in a 50% stretched state being 0.2 or less.
According to a fourth aspect of the present invention, there is provided a composite stretchable member which can stretch in a first direction, the composite stretchable member comprising a first nonwoven sheet part and second nonwoven sheet part which are superposed on each other and a plurality of elastic members which are arranged between the first nonwoven sheet part and the second nonwoven sheet part, the elastic members extending in the first direction while being separated from each other in a second direction perpendicular to the first direction, the first nonwoven sheet part and the second nonwoven sheet part joined with each other by an adhesive which is applied to the elastic members, and a heat retaining rate in a 50% stretched state being 40% or less.
According to a fifth aspect of the present invention, there is provided a composite elastic which can stretch in a first direction, the composite stretchable member comprising a first nonwoven sheet part and a second nonwoven sheet part which are superposed on each other and a plurality of elastic members which are arranged between the first nonwoven sheet part and the second nonwoven sheet part, the elastic members extending in the first direction while being separated from each other in a second direction perpendicular to the first direction, the first nonwoven sheet part and the second nonwoven sheet part joined with each other by an adhesive which is applied to the elastic members, and a density of profile curve elements in a 50% stretched state being 8 to 15/cm.
According to a sixth aspect of the present invention, there is provided a composite stretchable member which can stretch in a first direction, the composite stretchable member comprising a first nonwoven sheet part and a second nonwoven sheet part which are superposed on each other and a plurality of elastic members which are arranged between the first nonwoven sheet part and the second nonwoven sheet part, the elastic members extending in the first direction while being separated from each other in a second direction perpendicular to the first direction, the first nonwoven sheet part and the second nonwoven sheet part joined with each other by an adhesive which is applied to the elastic members, a mean compressive pressure when compressing the composite stretchable member in the thickness direction so that the load which is applied to the composite stretchable member in a 50% stretched state changes from 0.5 gf/cm2 to 50 gf/cm2 being less than 15 gf/cm2, and a root mean square height of a profile curve in a 50% stretched state being 0.4 mm or less.
It is possible to provide a composite stretchable member which can reliably maintain the bond between the first nonwoven sheet part and the second nonwoven sheet part while keeping the adhesive from causing the composite stretchable member to fall in flexibility.
It is possible to provide a composite stretchable member with a smaller thickness and more uniform pleats.
It is possible to provide a composite stretchable member with more uniformly excellent flexibility.
Referring to
Further, the first nonwoven sheet part 2A and the second nonwoven sheet part 2B are respectively provided with pluralities of convex-concave regions 5A, 5B and at least one non-shaped regions 4A, 4B which separate these convex-concave regions 5A, 5B from each other in the second direction D2. In the embodiment shown in
As shown in
Similarly, the convex-concave regions 5B of the second nonwoven sheet part 2B are provided with convex parts 6B and concave parts 7B which are alternately repeated in the first direction D1 and which continue in the second direction D2. The convex parts 6B respectively stick out from the non-shaped regions 4B in the thickness direction DT. The concave parts 7B respectively reach the non-shaped regions 4B between two mutually adjoining convex parts 6B. The non-shaped regions 4B are not provided with convex parts and concave parts. Further, the non-shaped regions 4B are positioned at one surface of the second nonwoven sheet part 2B, in the embodiment shown in
If considering that the non-shaped regions 4A, 4B respectively extend in a virtual reference plane, the convex parts 6A, 6B stick out from the corresponding reference plane, while the concave parts 7A, 7B reach the corresponding reference plane. Note that, the first nonwoven sheet part 2A and the second nonwoven sheet part 2B is flexible, so the reference plane is not necessarily a flat plane.
Moreover, as shown in
As explained above, the non-shaped regions 4A, 4B are separated from each other in the thickness direction DT. Therefore, as shown in
In other words, the first nonwoven sheet part 2A and the second nonwoven sheet part 2B are indirectly joined via the elastic members 3. Further, there is no adhesive at the convex-concave regions 5A, 5B, therefore the first nonwoven sheet part 2A and the second nonwoven sheet part 2B are not directly joined. By doing this, the bond between the first nonwoven sheet part 2A and the second nonwoven sheet part 2B is reliably maintained while the composite stretchable member 1 is kept from falling in flexibility due to the adhesive.
As a result, the composite stretchable member 1 is given stretch properties in the first direction D1. Further, the composite stretchable member 1 is formed with a large number of pleats which are continuous in the second direction D2 due to the convex parts 6A, 6B and concave parts 7A, 7B.
The first nonwoven sheet part 2A and the second nonwoven sheet part 2B at the non-shaped regions 4A, 4B may include parts which are not joined to the elastic members 3. In this case, at the time of contraction of the composite stretchable member 1, the above parts may rise up. Further, in the non-shaped regions 4A, 4B, at the outside surfaces of the first nonwoven sheet part 2A and the second nonwoven sheet part 2B, i.e., at the surfaces of the opposite sides to the elastic members 3, compared with the inside surfaces of the first nonwoven sheet part 2A and the second nonwoven sheet part 2B, i.e., the surfaces facing the elastic members 3, the fibers which form the nonwoven sheets are relatively free. For this reason, at the time of contraction of the composite stretchable member 1, the fibers at the above outside surfaces may rise up. As a result, in each case, at the time of contraction of the composite stretchable member 1, pleats are formed extending from single convex-concave region 5A, 5B to other convex-concave regions 5A, 5B across the non-shaped regions 4A, 4B.
The diameters of the elastic members 3 are preferably slightly smaller than the heights HSP of the spaces SP. This is because if the diameters of the elastic members 3 are larger than the heights HSP, the elastic members 3 or cured adhesive 8 will stick out at the non-shaped regions 4A, 4B in the thickness direction DT and the wearer is liable to be given an odd feeling.
As shown in
Further, the non-shaped regions 4A of the first nonwoven sheet part 2A and the non-shaped regions 4B of the second nonwoven sheet part 2B are positioned on the same surface of the nonwoven sheet 10, in the embodiment shown in
The non-shaped regions 4A, 4B and convex-concave regions 5A, 5B are, for example, formed by a shaping device 20 shown in
A not yet shaped nonwoven sheet 10N is passed between these continuous gear roll 21 and discontinuous gear roll 22. In this case, the machine direction MD of the nonwoven sheet 10N corresponds to the first direction D1, while the rotational axis 21A, 22A directions of the continuous gear roll 21 and discontinuous gear roll 22 correspond to the second direction D2. As a result, in the region where the teeth 21T of the continuous gear roll 21 and the teeth 22T of the discontinuous gear roll 22 face each other, the nonwoven sheet 10N is partially stretched, that is, is shaped, along the first direction D1. As a result, convex parts 6A, 6B and concave parts 7A, 7B are alternately repeatedly formed. That is, convex-concave regions 5A, 5B are formed. On the other hand, in the region where the teeth 21T of the continuous gear roll 21 and the discontinuous parts 22TL of the discontinuous gear roll 22 face each other, convex parts and concave parts are not formed, therefore non-shaped regions 4A, 4B are formed. In this way, a single shaping treatment enables the first nonwoven sheet part 2A and the second nonwoven sheet part 2B to be simultaneously formed. In another embodiment, the first nonwoven sheet part 2A and the second nonwoven sheet part 2B are formed in different nonwoven sheets and are superposed with each other.
Note that, if the above-mentioned such shaping treatment by stretching is performed, the distances between fibers increases at the intermediate parts between the convex parts 6A, 6B and the concave parts 7A, 7B, so the strength of the intermediate parts is weakened. As a result, the nonwoven sheet is increased in flexibility.
Next, while the nonwoven sheet 10 is conveyed, the elastic members 3 are adhered to the nonwoven sheet 10. Specifically, the elastic members 3 to which the adhesive 8 has been applied in advance are arranged in a stretched state at, for example, the non-shaped regions 4B of the second nonwoven sheet part 2B. In this case, the stretch-bond ratio of the elastic members 3 (=(length of elastic member 3 in stretched state adhered to nonwoven fabric sheet 10 with a unit length in the machine direction MD)/(length of elastic member 3 in contracted state)) is, for example, set to 3.
Next, while the nonwoven sheet 10 is conveyed, it is folded generally along the folding line FL shown in
Note that, when folding the nonwoven sheet 10 generally along the folding line FL, one of the first nonwoven sheet part 2A and the second nonwoven sheet part 2B is moved slightly in the first direction D1 with respect to the other so that the convex parts 6A of the first nonwoven sheet part 2A face the concave parts 7B of the second nonwoven sheet part 2B and the convex parts 6B of the second nonwoven sheet part 2B face the concave parts 7A of the first nonwoven sheet part 2A. This movement can be obtained, for example by making the tensions of the first nonwoven sheet part 2A and the second nonwoven sheet part 2B at the time of conveyance different.
As explained above, the convex parts 6A of the first nonwoven sheet part 2A enter into the concave parts 7B of the second nonwoven sheet part 2B, and the convex parts 6B of the second nonwoven sheet part 2B enter into the concave parts 7A of the first nonwoven sheet part 2A. To achieve this, as will be understood from
PP0≧4·tS·ERM=4·(tS0/DR)·ERM (1)
Therefore, the pitch PP0 is determined from the predetermined tS0, DR and ERM so as to satisfy formula (1).
In the embodiment shown in
Further, in the embodiment shown in
Furthermore, in the embodiment shown in
The composite stretchable member according to a first aspect of the present invention is a composite stretchable member which can stretch in a first direction, comprised of a first nonwoven sheet part and a second nonwoven sheet part which are superposed on each other and a plurality of elastic members which are arranged between the first nonwoven sheet part and the second nonwoven sheet part, the elastic members extending in the first direction while being separated from each other in a second direction which is perpendicular to the first direction, the first nonwoven sheet part and the second nonwoven sheet part joined with each other by an adhesive which is applied to the elastic members.
Now, a composite stretchable member according to a second aspect of the present invention has a thickness 5 when applying 3 gf/cm2 (0.3 kPa) of pressure in the thickness direction to the composite stretchable member in a 50% stretched state of 2.0 mm or less and has a root mean square height Pq of a profile curve in a 50% stretched state of 0.4 mm or less.
The composite stretchable member according to the second aspect of the present invention preferably further has a coefficient of variation CV of the length of the profile curve element in a 50% stretched state of 0.2 or less.
The composite stretchable member according to the second aspect of the present invention preferably further has a mean compressive pressure CP, when compressing the composite stretchable member in the thickness direction so that the load which is applied to the composite stretchable member in a 50% stretched state changes from 0.5 gf/cm2 (0.05 kPa) to 50 gf/cm2 (5 kPa), of less than 15 gf/cm2 (1.5 kPa).
The composite stretchable member according to the second aspect of the present invention preferably further has a heat retaining rate HR in a 50% stretched state of 40% or less.
The composite stretchable member according to the second aspect of the present invention preferably further has a density D of the profile curve elements in a 50% stretched state of 8 to 15/cm.
The 50% stretched state is the state where the composite stretchable member is stretched in the stretch direction so that the stretch ratio becomes 50%. The stretch ratio is defined by the following formula:
Stretch ratio (%)=(LM−LM0)/LM0·100
Here, LM: stretch direction length of stretched composite stretchable member part
LM0: stretch direction length of the composite stretchable member part in natural state
The thickness t is measured by a thickness measuring device. On the other hand, the root mean square height Pq of the profile curve is found as follows: That is, first, the profile curve along the stretch direction at the convex-concave regions of the composite stretchable member is measured by a shape measuring device. The cross-sectional shape is preferably measured at the substantial center of two mutually adjoining elastic members. Next, from this profile curve, the height Z(x) of the profile curve element at the reference length is found (see
The root mean square height Pq of the profile curve expresses the size of the pleats or uniformity of the pleats formed at the composite stretchable member. Specifically, as the root mean square height Pq becomes smaller, the pleats become smaller and more uniform. Therefore, if the thickness t is 2.0 mm or less and the root mean square height Pq is 0.4 mm or less, a composite stretchable member with a smaller thickness and simultaneously more uniform pleats is provided. If the thickness is smaller, the composite stretchable member becomes lower in heat retaining function and sweating or skin trouble is suppressed. Further, the composite stretchable member is enhanced in flexibility. On the other hand, if the pleats are more uniform, the composite stretchable member is improved in feeling and look. Further, the uniformity of characteristics of the composite stretchable member such as the feel and flexibility is enhanced more.
The coefficient of variation CV of the length of the profile curve elements is found as follows: That is, the length Xs of the profile curve elements at the reference length is found from the above profile curve (see
The length Xs of the profile curve elements expresses the interval or size of the pleats of the composite stretchable member, while the coefficient of variation CV of the length Xs expresses the uniformity of pleats. Specifically, as the coefficient of variation CV becomes smaller, the pleats become more uniform. Therefore, if the coefficient of variation CV is 0.2 or less, a composite stretchable member with more uniform pleats is provided. In other words, a composite stretchable member with better feel and look is provided. Further, the uniformity of characteristics of the composite stretchable member such as touch and flexibility is enhanced more.
The mean compressive pressure CP is found as follows: That is, as shown in
The mean compressive pressure CP expresses the flexibility of the composite stretchable member. Specifically, as the mean compressive pressure CP becomes smaller, the composite stretchable member is improved in flexibility. Therefore, if the mean compressive pressure CP is less than 15 gf/cm2, a composite stretchable member with better flexibility is provided. Further, if the mean compressive pressure CP is less than 15 gf/cm2 and the root mean square height Pq is 0.4 mm or less, a better flexibility can uniformly obtained.
The heat retaining rate HR was found as follows: That is, first, a heated hot plate is prepared. Next, the quantity of heat Qd which is required for maintaining the temperature of the hot plate when arranging a composite stretchable member on the hot plate is measured. Further, the quantity of heat Q0 which is required for maintaining the temperature of the hot plate when not arranging a composite stretchable member on the hot plate is measured. Next, from these Qd, Q0, the heat retaining rate HR is calculated (HR(%)=(Q0−Qd)/Q0·100).
If the heat retaining rate HR is 40% or less, the temperature of the body surface of the wearer is maintained low and sweating or skin trouble is suppressed.
The density D of the profile curve elements is calculated from the mean value PSm of the length Xs of the profile curve elements (D=1/PSm).
The density D of the profile curve elements expresses the magnitude or uniformity of pleats of the composite stretchable member. Specifically, as the density D becomes larger, the pleats become smaller and become more uniform. Therefore, if the density D is 8 to 15/cm, a composite stretchable member with more uniform pleats is provided. In other words, a composite stretchable member with a better feel and look is provided. Further, the uniformity of characteristics of the composite stretchable member such as the feel and flexibility is enhanced more. Furthermore, the pleats are not excessively small, so production of the composite stretchable member is easy.
The composite stretchable member according to a third aspect of the present invention has a coefficient of variation CV of the length Xs of the profile curve elements of 0.2 or less. The composite stretchable member according to the third aspect of the present invention further preferably has a root mean square height Pq of 0.4 mm or less.
The composite stretchable member according to a fourth aspect of the present invention has a heat retaining rate HR of 40% or less. The composite stretchable member according to the fourth aspect of the present invention preferably further has a thickness t of 2.0 mm or less.
The composite stretchable member according to a fifth aspect of the present invention has density D of 8 to 15/cm. The composite stretchable member according to the fifth aspect of the present invention preferably further has a root mean square height Pq of 0.4 mm or less.
The composite stretchable member according to a sixth aspect of the present invention has a mean compressive pressure, when compressing the composite stretchable member in the thickness direction so that the load which is applied to the composite stretchable member in a 50% stretched state changes from 0.5 gf/cm2 to 50 gf/cm2, of less than 15 gf/cm2 and has a root mean square height of a profile curve in a 50% stretched state of 0.4 mm or less.
The composite stretchable member according to the sixth aspect of the present invention preferably further has thickness t, when applying 3 gf/cm2 (0.3 kPa) of pressure to the composite stretchable member in a 50% stretched state in the thickness direction, of 2.0 mm or less.
The composite stretchable member according to the sixth aspect of the present invention preferably further has a coefficient of variation CV of length of the profile curve elements in a 50% stretched state of 0.2 or less.
The composite stretchable member according to the sixth aspect of the present invention preferably further has a heat retaining rate HR in a 50% stretched state of 40% or less.
The composite stretchable member according to the sixth aspect of the present invention preferably further has a density D of profile curve elements in a 50% stretched state of 8 to 15/cm.
Examples 1 to 9 were prepared according to Table 1. Examples 1 to 8 were provided with constitutions corresponding to the embodiment shown in
Comparative Example 1 was prepared according to Table 1. Comparative Example 1 was provided with a constitution corresponding to the composite stretchable member which is described in the above-mentioned PTL 1. That is, Comparative Example 1, as shown in
Comparative Example 2 was prepared in accordance with Table 1. Comparative Example 2 was provided with a mutually superposed, unshaped first nonwoven sheet part and the second nonwoven sheet part and a plurality of elastic members which are arranged between the first nonwoven sheet part and the second nonwoven sheet part. Adhesive was applied to the circumferential surfaces of the elastic members, so the first nonwoven sheet part and the second nonwoven sheet part were fastened with each other through the elastic members.
(Measurement)
The thickness t was measured by a thickness measuring device FS-60DS made by Daiei Kagaku Seiki Manufacturing. The area of the pressing plate was 20 cm2 (circular shape), while the measurement load was 3 gf/cm2 (0.3 kPa). A sample of the composite stretchable member (width 120 mm, length 1000 mm) was measured 10 times. The arithmetic mean of the measured data was found whereby the thickness t was obtained.
The profile curve was measured by a shape measuring system KS-1100, a laser sensor LK-G30 (spot diameter 30 μm), and a controller LK-GD500 made by Keyence Co., Ltd. The measurement range was 0 to 30000 μm, the measurement pitch was 5 μm, the number of measurement points was 6001, the contact probe movement direction was made the stretching direction, and the contact probe movement speed was 50 μm/sec. Later explained test pieces were prepared from the sample (width 120 mm, length 200 mm). Next, the test pieces were measured. A ±12 moving average was taken once, whereby profile curve data was obtained. Further, from the profile curve data, the root mean square height Pq, arithmetic mean PSm of the length Xs, standard deviation σ and coefficient of variation CV of the profile curve elements, and the density D of profile curve elements were calculated.
The test pieces were prepared as follows: That is, as shown in
Next, as shown in
The mean compressive pressure PC was measured by an automatic compression tester KES-FB3-AUTO-A made by KATO TECH Co., Ltd. The compression distance was from a thickness T0 to a thickness Tm, the area of the pressing plate was 2 cm2 (circular shape), the compression speed was 0.02 mm/sec, and the amp setting was SENS2. A test piece was prepared from the sample (width 120 mm, length 200 mm) (see
The heat retaining rate HR was measured by a precise and fast thermal property measuring instrument KES-F7-Thermo Lab II made by KATO TECH Co., Ltd. The hot plate had dimensions of 10 cm by 10 cm. A test piece was prepared from the sample (width 120 mm, length 200 mm) (see
(Results)
Table 2 shows the measurement results.
Further,
Furthermore,
From these, in Examples 1 to 9, it is learned that compared with Comparative Examples 1 and 2, the pleats are smaller and more uniform.
Further, as shown in
Furthermore, as shown in
Furthermore, as shown in
Furthermore, as shown in
Furthermore, as shown in
The present invention is defined as follows.
Number | Date | Country | Kind |
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2012-107768 | May 2012 | JP | national |
2012-107805 | May 2012 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2013/062834 | 5/7/2013 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2013/168701 | 11/14/2013 | WO | A |
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Number | Date | Country | |
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20150140278 A1 | May 2015 | US |