Claims
- 1. A composite structure useful as an implant material in bone, comprising:
- a matrix made of Al.sub.2 O.sub.3 --ZrO.sub.2 --Y.sub.2 O.sub.3 ceramic material having a composition of 10 to 40 mol % of Al.sub.2 O.sub.3, 88 to 58 mol % of ZrO.sub.2 and 0.5 to 2 mol % of Y.sub.2 O.sub.3 ;
- an amorphous surface layer; and
- a bio-active layer covering at least said amorphous layer.
- 2. The composite structure according to claim 1, wherein said matrix comprises an orientated crystal of said ceramic material.
- 3. The composite structure according to claim 1, wherein said ceramic material has eutectic composition.
- 4. The composite structure according to claim 1, wherein said matrix comprises a sintered body of said ceramic material.
- 5. The composite structure according to claim 1, wherein said surface layer has a thickness of 0.1 to 10 .mu.m.
- 6. The composite structure according to claim 1, wherein said bio-active layer is made of at least one material selected from the group consisting of Hench glass, tricalcium phosphate and hydroxyapatite.
- 7. The composite structure according to claim 6, wherein said bio-active layer has a thickness of 2 to 3 .mu.m.
- 8. The composite structure according to claim 1, wherein said amorphous surface layer covers all surface of said matrix.
- 9. The composite structure according to claim 1, wherein said bio-active layer covers all surface of said amorphous surface layer.
- 10. The composite structure according to claim 1, wherein said matrix has at least one side, said at least one side having grooves and projections thereon.
- 11. The composite structure according to claim 10, wherein said matrix has two opposing sides, each of said sides having grooves and projections thereon.
- 12. The composite structure according to claim 1, wherein said matrix has at least one side, and has a plurality of spaced apart projections protruding therefrom along the entire length of said at least one side.
- 13. The composite structure according to claim 12, wherein said matrix has two opposing sides, and has said spaced apart projections protruding from said two opposing sides along the entire length of said two opposing sides.
- 14. The composite structure according to claim 1 wherein said bio-active layer is made of at least one material selected from the group consisting of tricalcium phosphate and hydroxy apatite.
- 15. The composite structure according to claim 10 wherein said bio-active layer has a thickness of 2 to 3 microns.
- 16. The composite structure according to claim 1, wherein a surface layer of said matrix has been irradiated with laser beam to provide said amorphous surface layer.
- 17. A composite structure useful as an implant material in bone, comprising:
- a matrix made of Al.sub.2 O.sub.3 --ZrO.sub.2 --Y.sub.2 O.sub.3 ceramic material having a composition of 10 to 40 mol % of Al.sub.2 O.sub.3, 88 to 58 mol % of ZrO.sub.2 and 0.5 to 2 mol % of Y.sub.2 O.sub.3, a surface layer of said matrix having been amorphitized by irradiation with a laser beam; and
- a bio-active layer covering at least said amorphitized layer of the matrix.
- 18. The composite structure according to claim 17, wherein said laser beam in a carbon dioxide gas laser.
- 19. The composite structure according to claim 17, wherein said matrix comprises an oriented crystal of said ceramic material.
- 20. The composite structure according to claim 17, wherein said ceramic material has a eutectic composition.
- 21. The composite structure according to claim 17, wherein said matrix comprises a sintered body of said ceramic material.
- 22. The composite structure according to claim 17, wherein said surface layer has a thickness of 0.1 to 10 .mu.m.
- 23. The composite structure according to claim 17, wherein said bio-active layer is made of at least one material selected from the group consisting of Hench glass, tricalcium phosphate and hydroxyapatite.
- 24. The composite structure according to claim 23, wherein said bio-active layer has a thickness of 2 to 3 .mu.m.
- 25. The composite structure according to claim 17, wherein said amorphous surface layer covers the whole surface of said matrix.
- 26. The composite structure according to claim 17, wherein said bio-active layer covers the whole surface of said amorphous surface layer.
- 27. The composite structure according to claim 17, wherein said matrix has at least one side, said at least one side having grooves and projections thereon.
- 28. The composite structure according to claim 27, wherein said matrix has two opposing sides, each of said sides having grooves and projections thereon.
- 29. The composite structure according to claim 27, wherein said bio-active layer has a thickness of 2 to 3 microns.
- 30. The composite structure according to claim 17, wherein said bio-active layer is made of at least one material selected from the group consisting of tricalcium phosphate and hydroxy apatite.
Priority Claims (1)
Number |
Date |
Country |
Kind |
60-43927 |
Mar 1985 |
JPX |
|
Parent Case Info
This application is a continuation, of application Ser. No. 834,811, filed Feb. 28, 1986, now abandoned.
US Referenced Citations (9)
Foreign Referenced Citations (1)
Number |
Date |
Country |
59-112908 |
Jun 1984 |
JPX |
Non-Patent Literature Citations (1)
Entry |
Journal of the American Ceramic Society, Sep.-Oct. vol. 60, pp. 428-435 (1977). |
Continuations (1)
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Number |
Date |
Country |
Parent |
834811 |
Feb 1986 |
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