Patent Application
20210360746
The present invention relates to a composite substrate. More specifically, the present invention is concerned with a composite substrate comprising a mesh layer and a composite material layer, wherein said composite substrate can be coated in metal and then used as an electro-thermal heating element for de-icing and anti-icing applications.
In the last decades, the application of composites in different industries, especially the aerospace industry, has been increased significantly due to their specific characteristics, such as a high strength to weight ratio. As polymeric composite materials comprise a high percentage of the structure of modern aircrafts and wind turbines, designing an appropriate de-icing and anti-icing system for such composite structures has a high level of importance. Different methods have been used for de-icing purposes in the aerospace industry, including the following: 1) bleed air de-icing systems, 2) electro-mechanical de-icing systems, 3) electro-thermal de-icing systems, 4) pneumatic boot systems, and 5) weeping wings.
Electro-thermal de-icing systems use electrical resistance heaters in different forms, for example wire, film, or foil for heating and de-icing the components of an airplane or wind-turbine. The electro-thermal heaters start heating the components as soon as an electrical current is applied to them. Electro-thermal de-icers generally have high efficiency as the generated heat in these systems flows directly into the accumulated ice. It also has been reported that using such de-icing systems extracts about 35% less power from the aircraft engines compared to conventional pneumatic systems. In addition, this type of de-icing system typically does not add considerable weight to the airplane, while in bleed air de-icing systems, ducting which is used for passing the pressurized air around the airplane adds hundreds of pounds of weight to the aircraft.
An electro-thermal heating element for composite structures are typically fabricated by addition, or, in other words, the deposition of a thin metallic coating layer on top of the composite structure using thermal spray techniques. Thermal spray techniques are a group of techniques and processes used for the deposition of a metallic or non-metallic coating onto a substrate. Based on the source of energy used for heating up and melting the coating materials (in the form of powder, wire, rod, ceramic, or molten materials), thermal spray processes can be divided into three categories, in which heating and energy is provided by: (1) combustion, (2) dissipation of electrical energy, or (3) high-pressure gases (in the case of cold spray). Once the coating materials are heated up, they are accelerated toward a substrate using process gases and form a bond with the surface. The subsequent particles will bond with the already deposited particles and form a lamellar structure.
Thermal spray processes are widely used for enhancing thermal, physical, mechanical, and tribological properties of metallic substrates. However, the coating of composite materials using thermal spray methods are associated with some serious challenges. First of all, polymeric materials have relatively low service temperatures (usually less than 300° C.), while in a thermal process, like plasma spraying, the substrate temperature might easily exceed 400° C. Furthermore, most of the treatment methods used for preparing and roughening the metallic substrates prior to the coating deposition process cannot be applied directly and without any surface modification to composites. For example, using grit blasting, in which substrates are roughened by the impact of high-velocity abrasive particles, for preparing the surface of a composite substrates, would break the fibers and degrade the mechanical properties of the composite. In addition, polymeric materials generally have very low free surface energy compared to metallic materials, and this deposition of a metallic coating layer with high adhesion strength is very difficult.
Using an appropriate preparation method prior to the coating deposition process typically improves the coating adhesion strength and deposition efficiency during spraying. Different surface treatment methods have been reported for the preparation of composite substrates. For example, grit blasting has been used for preparing the carbon-fiber-reinforced polymer composite (CFRP) substrate prior to the spraying of Zn using a plasma spray technique. After coating of CFRPs and examining their microstructure, it has been found that a lot of fibers were broken due to grit blasting and even some broken fibers penetrated to the coating structure. The shear bond strength of the coatings prepared using grit blasting has also been compared with the coatings prepared using abrasive papers, where it was found that using the latter preparation method results in poor mechanical properties. Chemical treatment is another method that has been used for preparing CFRP substrates prior to the coating deposition process. In this method, the substrates surface energy is increased by exposing them to chemical materials and solutions. Investigations into determining the effects of surface preparation methods on the air-plasma-sprayed Cu coatings' adhesion strength and quality have been performed, where the CFRP substrates were treated mechanically (grit blasting), thermally, and chemically. It has been found that using chemical treatment leads to better coating adhesion strengths, especially in the case of thin film coatings. Other methods, like the incorporation of granular particles on top of the polymeric substrates have been used for roughening and activating the composite substrates. Studies have been done about the metallization of Glass-fiber-reinforced polymer composite GFRPs for use as a heating element and de-icing applications. During such studies, a layer of #220 grit garnet sand and high strength epoxy adhesive mixture was applied manually on top of a [020] ply GFRP sample for increasing the surface roughness and consequently improving the coating adhesion during the deposition of a NiCrAlY coating layer using flame spray technique. The microscopic cross-section of the NiCrAlY-coated composite sample showed that the coating was very non-uniform. After connecting the coated sample to a power source for testing its performance as a heating element, it was observed that the non-uniformity of coating contributes to a non-uniform surface temperature distribution along the coating surface and the formation of hot and cold zones at the same time.
The number of research studies that have been done up to now about the thermal spray coating of composites are very low, and in most cases, low melting-point metallic powders (e.g. Zn and Al) have been used as the coating materials for spraying the composites. For instance, APS techniques have been utilized for the deposition of Al as a bond-coat and Al2O3 as a top-coat onto PMC substrates for enhancing their mechanical properties. The metallic coatings were sprayed onto several composite substrates using different spray parameters (different currents and spray distances). After examining the coated samples, it was found that the spray parameters played a very significant role in determining the microstructure, phase composition, and mechanical properties of the coated samples. The maximum shear adhesion strength achieved for the Al bond-coat was about 5.21 MPa. In another study, plasma spraying was used for the deposition of Zn, Al, Cu, and Ni3Al coatings onto CFRP substrates. After the coating process, the microstructure and shear adhesion strength of the coated samples were analyzed. The results demonstrated that deposition of Ni3Al and Cu leads to the formation of delamination in the interface of the substrate and coating due to the relatively high melting point of coating materials and low surface energy of the CFRP substrate. However, Al and Zn were deposited successfully. In addition, by comparing the plasma-sprayed Al and Zn with arch-sprayed Al and Zn, it was found that using plasma spraying results in the fabrication of a coating with superior mechanical properties. In another study, a combination of plasma spraying and cold spraying was used to deposit an aluminum coating layer onto CFRP substrates for lightning protection applications in aircrafts. In that study, a thin layer of aluminum coating (about 15 μm) was deposited onto the composite surface by using plasma spraying, and after that cold spraying was used for the deposition of a second aluminum layer as a top-coat. The plasma spray process was not used alone for the deposition of the whole coating due to the fact that the gas temperature in this process is high and it would increase the oxidation of sprayed particles, which would consequently increase the electrical resistivity of the coating, which is not desirable in the fabrication of a lightning protector coating. In addition, when the cold spray method was used alone for the coating of CFRPs, the coatings started peeling off once their thickness reached about 30 μm due to damage induced to the CFRPS surface by the impact of high-velocity particles.
In accordance with the present invention, there is provided:
In the appended drawings:
There is provided a composite substrate comprising a mesh layer and a composite material layer, wherein the mesh layer comprises a mesh material and an adhesive, said adhesive permeating the mesh material so as to adhere the mesh material to the composite material layer. There is also provided a method for producing said composite substrate.
The present inventors discovered that a composite substrate comprising a mesh layer makes for an effective substrate on which to apply a metal coating, as the mesh material will protect the underlying composite material layer during the coating process and at the same time will act as an anchor to keep the eventual metal coating on the surface of the composite substrate. Once coated with a metal layer, the composite substrate makes for an effective electro-thermal heating element, such as a de-icer or anti-icer.
The present inventors have also discovered a process of producing the above composite substrate, as well as a process for coating said composite substrate with a metal layer. Specifically, the inventors have discovered effective coating parameters with which the metal layer can be applied to the composite substrate. Said coating parameters allow for the deposition of a metal layer that is of sufficiently uniform thickness, with strong adhesion strength to the composite substrate, with high mechanical strength, high resistance to galvanic corrosion, and/or with high electrical resistivity. This process may also allow for high deposition efficiency.
This composite substrate, the metal-coated composite substrate, and the processes for producing the composite substrate and the metal-coated composite substrate create new opportunities for the design of electro-thermal heating elements, such as a de-icers or anti-icers.
In a first aspect of the invention, a composite substrate comprising a mesh layer and a composite material layer is provided, wherein the mesh layer comprises a mesh material and an adhesive, said adhesive permeating the mesh material and adhering the mesh material directly to a surface of the composite material layer.
As stated, the composite substrate comprises a mesh layer and a composite material layer. As previously stated, the composite substrate of the present invention is intended to be used as a substrate on which to apply a metal coating, as the mesh material will protect the underlying composite material layer during the coating process and at the same time will act as an anchor to keep the metal coating on the surface of the composite substrate.
The dimensions of the composite substrate will largely be determined by the dimensions of the mesh layer and the composite material layer. The skilled person would understand that the composite substrate could come in a variety of sizes and shapes depending on the desired applications thereof. For example, if the composite substrate is intended to be used as part of a blade of a wind turbine, then the composite substrate will be dimensioned and sized for that purpose.
The composite material layer of the composite substrate refers to the layer of material underlying the mesh layer. It is to be understood that the composite material layer may be made of a variety of materials, depending on the desired applications thereof. The shape, size, and thickness of the composite substrate and the composite material layer will also be determined by the intended application of the composite substrate. For example, if the composite substrate is intended to be used as part of a blade of a wind turbine, then the composite material layer can be made of composite polymer materials typically used for such an application; the composite material layer will also be dimensioned and sized to be used as part of a blade of a wind turbine. The composite material layer can also be the surface of an object, for example the surface of the blade of a wind turbine.
In embodiments, the composite material layer comprises polymeric composite materials. Examples of polymeric composite materials include carbon/graphite reinforced composite materials, glass reinforced composite materials, Kevlar reinforced composite materials and boron reinforced composite materials. In preferred embodiments, the composite material layer comprises a thermoplastic composite or a thermoset composite, preferably a thermoset composite.
In preferred embodiments, the composite material layer comprises reinforcing fibers embedded therein, preferably glass fibers, ceramic fibers, or carbon fibers. Said reinforcing fibers are typically used to increase the mechanical strength of such composite materials. The composite material layer can comprise a dispersion of reinforcing fibers in a matrix, preferably a polymer matrix. In a more preferred embodiment, the composite material layer comprises a glass-fiber-reinforced polymer composite (GFRP).
The mesh layer is a layer of the composite substrate that comprises a mesh material that has been adhered to the composite material layer using an adhesive. In order to properly secure the mesh material to the composite material layer, the adhesive permeates the mesh material.
As previously stated, when a metal coating is applied to the composite substrate, the mesh material of the mesh layer will protect the underlying composite material layer during the coating process (namely during grit blasting and other similar surface preparation processes) and at the same time will act as an anchor to keep the metal coating on the surface of the composite substrate. A mesh material is typically made of a woven wire. For the purposes of the present invention, the mesh material is made of sufficiently strong material that can be properly adhered to the composite material layer using an adhesive, and that can properly anchor any intended metal coatings. In embodiments, the mesh material is made of carbon fibers, ceramic fibers, glass fibers, or metal. In preferred embodiments, the mesh material is made of metal, preferably stainless steel.
The mesh size of the mesh material will influence various properties of both the composite substrate and any metal coating that may be deposited thereon (see below for more detail). Mesh size typically refers to the number of openings in the material per one linear inch of material. For example, a mesh material with a mesh size of 100 has 100 openings per linear inch of material. The mesh size of the mesh material should be small enough so as to allow the chosen adhesive to penetrate and permeate the mesh material, as this will help adhere the mesh material to the composite material layer, and it will facilitate the process of producing the composite substrate of the present invention (as the adhesive can be applied to the mesh material after the mesh material has been placed on the top surface of the composite material layer, such that the adhesive will penetrate the mesh material and come into contact with the composite material layer).
In general, the size of the mesh affects the resulting adhesion strength between the mesh layer and the composite material layer. In embodiments, the adhesion strength of the mesh layer to the composite material layer is between about 10 MPa and about 30 MPa, preferably between about 14 MPa to about 22 MPa. In embodiments, the adhesion strength of the mesh layer to the composite material layer is at least about 10 MPa; at least about 12 MPa; at least about 14 MPa; at least about 16 MPa; or at least about 20 MPa; and/or at most about 30 MPa; at most about 28 MPa; at most about 26 MPa; at most about 24 MPa; at most about 23 MPa; or at most about 22 MPa. In preferred embodiments, the adhesion strength of the metal layer to the composite substrate is about 20 MPa or about 22 MPa. For clarity, the above-listed adhesion strength values are measured using a flatwise tensile test, preferably as described in the experimental section below.
While lower mesh sizes generally improve adhesion strength, the mesh size should be sufficiently high to allow the mesh material to better protect the underling composite material layer. For example, if the composite substrate is subjected to abrasive grit blasting in order to roughen the surface thereof, it is important that the mesh hole dimensions be smaller than the grit blasting sand diameter, so as to prevent the sand from easily penetrating the mesh layer and reaching the composite material layer, as this could damage the composite material layer.
In embodiments, the mesh size is at least about 50 and at most about 700, preferably at least about 200 and at most about 400. In embodiments, the mesh material has a mesh size of at least about 50; at least about 100; at least about 150; at least about 175; or at least about 200; and/or at most about 700; at most about 600; at most about 500; or at most about 400.
The adhesive used must sufficiently adhere the mesh material to the composite material layer. In addition, in embodiments, the mesh is completely embedded in the adhesive, such that none of the mesh material is exposed to the environment. In alternative embodiments, the mesh is partially embedded in the adhesive, such that portions of the mesh material opposite the composite layer are exposed to the environment.
Also, the adhesive should be a material that can be sufficiently roughened or removed without removing or damaging the mesh material. For example, in the event that the composite substrate of the present invention is subjected to abrasive grit blasting, the adhesive should be chosen such that said adhesive can be roughened and partially removed, thereby exposing more of the mesh material.
In embodiments, the mesh layer of the composite substrate of the present invention has been roughened, preferably using abrasive particles, even more preferably using abrasive grit blasting, such that the mesh material is at least partially exposed to the environment (see subsequent section for more details).
The skilled person would understand that the adhesive can be a variety of adhesives known in the art. In embodiments, the adhesive can be different types of thermosetting resin systems in either liquid or film forms, preferably an epoxy resin such as FM300 film adhesive.
The thickness of the mesh layer will generally be about as thick as the mesh material, although the thickness of the layer may increase depending on how much adhesive is used.
The mesh layer is adhered directly to the composite material layer. This means that there are no additional layers of material between the composite material layer and the mesh layer.
In another aspect of the present invention, a metal-coated composite substrate is provided. The metal-coated composite substrate comprises a composite substrate, as defined in the section above, and a metal layer covering a side of the mesh layer opposite the composite layer.
As stated, the composite substrate of the metal-coated composite substrate is as defined in the section above. However, it should be mentioned that, if the mesh layer of the composite substrate has not been roughened, the surface of the mesh layer will preferably be roughened before the metal layer can be applied. The roughening of the mesh layer will expose the mesh material, thereby allowing the mesh material to better anchor the metal layer, thereby allowing for a better adhesion of the metal layer to the composite substrate.
In general, the higher the surface roughness of the mesh layer before the metal layer is applied, the better the adhesion strength of the metal layer to the mesh layer. In embodiments, the surface roughness of the mesh layer before the metal is deposited is between about 4 μm and about 15 μm, preferably about 7 μm and about 11 μm. In embodiments, the surface roughness of the mesh layer before the metal is deposited is at least about 4 μm; at least about 5 μm; at least about 6 μm; at least about 7 μm; or at least about 8 μm; and/or at most about 15 μm; at most about 13 μm; at most about 12 μm; or at most about 11 μm.
The metal layer can be made of a variety of metals. It should be noted that, as the metal-coated composite substrate of the present invention is intended to be used as an electro-thermal heating element, it is preferable that the selected metal has sufficiently high electronic resistivity such that it can more easily generate heat. In addition, the selected metal should be sufficiently resistive to galvanic corrosion and should have sufficient mechanical strength for use as an electro-thermal heating element. However, the skilled person would understand that different metals and alloys may possess different advantages and disadvantages in terms of electronic resistivity, galvanic corrosion, and mechanical strength. Accordingly, while it is preferable that the metal used will have high electronic resistivity, high resistance to galvanic corrosion, and high mechanical strength, the skilled person would understand other metals may be used depending on the intended applications of the metal-coated composite substrate.
In preferred embodiments, the metal layer is a layer of nickel, chromium or alloys thereof (such as FeCrAlY), including mixed NiCr alloys, preferably NiCrAlY, or a layer of stainless steel. In a most preferred embodiment, the metal layer is a layer of NiCrAlY. One advantage of using NiCrAlY is that the electrical resistance of the NiCrAlY layer is almost constant and independent of the coating surface temperature (at least from 25 to 150° C.).
The thickness of the metal layer will affect the properties of the resulting metal-coated composite substrate. In general, if the metal layer is too thick, the metal coating may not sufficiently adhere to the composite substrate. Indeed, in general, the metal layer adhesiveness to the composite substrate decreases with increasing thickness. In addition, a higher thickness will generally lower the electrical resistance of the metal layer.
In embodiments, the metal layer is between about 5 μm and about 150 μm thick, preferably about 30 μm and about 100 μm. In embodiments, the thickness of the metal layer is at least about 5 μm; at least about 10 μm; at least about 20 μm; at least about 30 μm; or at least about 40 μm; and/or at most about 150 μm; at most about 130 μm; at most about 120 μm; at most about 110 μm; at most about 100 μm; or at most about 90 μm.
In preferred embodiments, the metal layer is relatively uniform in thickness. This will allow for more uniform surface temperature distribution in the event that the metal-coated composite substrate is used as an electro-thermal heating element. In embodiments, the uniformity of the thickness of the metal layer is between about ±1% and about ±10%, preferably between about ±2 and about ±8%. In embodiments, the uniformity of the thickness of the metal layer is at least about ±0.5%; at least about ±1%; at least about ±1.5%; at least about ±2%; or at least about ±2.5%; and/or at most about ±15%; at most about ±10%; at most about ±8%; at most about ±6%; or at most about ±4%. In preferred embodiments, the porosity is about ±2.5%.
As mentioned, the presence of the metal mesh layer improves the adhesion of the metal layer to the composite substrate. This is important because it will reduce the likelihood of, and preferably prevent, the metal layer from tearing off when the metal-coated composite substrate is in use, for example as an electro-thermal heating element. In embodiments, the adhesion strength of the metal layer to the composite substrate is between about 10 MPa and about 30 MPa, preferably between about 14 MPa to about 22 MPa. In embodiments, the adhesion strength of the metal layer to the composite substrate is at least about 10 MPa; at least about 12 MPa; at least about 14 MPa; at least about 16 MPa; or at least about 20 MPa; and/or at most about 30 MPa; at most about 28 MPa; at most about 26 MPa; at most about 24 MPa; at most about 23 MPa; or at most about 22 MPa. In preferred embodiments, the adhesion strength of the metal layer to the composite substrate is about 20 MPa or about 22 MPa. For clarity, the above-listed adhesion strength values are measured using a flatwise tensile test, preferably as described in the experimental section below.
As mentioned, it is preferable that the metal layer has high electrical resistivity, as this will allow the metal layer to more effectively generate heat. It should be noted that electrical resistivity is directly proportional to electrical resistance. However, resistivity is an intrinsic property that unlike electrical resistance does not depend on the shape and dimensions of the material in question.
In embodiments, the electrical resistivity of the metal layer is between about 1.5 μΩ·m and about 3 μΩ·m, preferably between about 2 μΩ·m and about 2.3 μΩ·m. In embodiments, the electrical resistivity is at least about 1.5 μΩ·m; at least about 1.7 μΩ·m; at least about 1.8 μΩ·m; at least about 1.9 μΩ·m; or at least about 2.0 μΩ·m; and/or at most about 3.0 μΩ·m; at most about 2.8 μΩ·m; at most about 2.6 μΩ·m; at most about 2.5 μΩ·m; at most about 2.4 μΩ·m; or at most about 2.3 μΩ·m. In preferred embodiments, the electrical resistivity of the metal layer is about 2.3 μΩ·m.
It should be noted that it is also preferable for the metal layer to have high sheet resistance, which is a parameter used more frequently to characterize thin coatings. One distinction between sheet resistance and electrical resistance is that sheet resistance, much like electrical resistivity, is independent of size, thereby making it easier to compare the effectiveness of layers of differing thicknesses. In embodiments, the sheet resistance of the metal layer is between about 0.01 Ω/square and about 0.08 Ω/square, preferably between about 0.02 Ω/square and about 0.06 Ω/square. In embodiments, the sheet resistance is at least about 0.01 Ω/square; at least about 0.02 Ω/square; at least about 0.025 Ω/square; at least about 0.03 Ω/square; or at least about 0.05 Ω/square; and/or at most about 0.10 Ω/square; at most about 0.09 Ω/square; at most about 0.08 Ω/square; at most about 0.07 Ω/square; or at most about 0.06 Ω/square. In preferred embodiments, the sheet resistance is about 0.058 Ω/square.
For clarity, the above-listed electrical resistance, electrical resistivity, and sheet resistance values are measured using a four-point electrical probe technique, preferably as described in the experimental section below.
The skilled person would understand that various properties of the metal layer will affect its electronic resistivity, mechanical strength, and/or resistance to galvanic corrosion. For example, a higher degree of porosity and a higher degree of oxidation in the metal layer will generally increase electrical resistivity.
In embodiments, the degree of porosity of the metal layer is between about 0.5 and about 40%, preferably between about 0.5 and about 20%, more preferably between about 0.5 and about 10%, even more preferably between about 1% and about 6%. In embodiments, the porosity is at least about 0.5%; at least about 2%; at least about 5%; at least about 8%; or at least about 10%; and/or at most about 40%; at most about 30%; at most about 20%; at most about 15%; or at most about 10%. In preferred embodiments, the porosity is about 6.4%.
In embodiments, the degree of oxidation of the metal layer is between about 5% and about 40%, preferably between about 10% and about 32%. In embodiments, the oxidation is at least about 5%; at least about 7%; at least about 10%; at least about 15%; at least about 20%; or at least about 30%; and/or at most about 60%; at most about 50%; at most about 40%; at most about *35%; or at most about 30%. In preferred embodiments, the oxidation is about 31.6%.
When acting as a heating element, current is passed through the metal layer of the metal-coated composite substrate so as to cause the metal layer to generate heat. In preferred embodiments, when a 6 amp current is passed through the metal layer, the intensity generated in the metal layer is at least about 1.4 KW/m2, preferably at least about 1.6 KW/m2, more preferably at least about 1.8 KW/m2, and most preferably about 4.3 KW/m2. Similarly, in preferred embodiments, when a 9 amp current is passed through the metal layer, the intensity generated in the metal layer is at least about 3.3 KW/m2, preferably at least about 3.6 KW/m2, more preferably at least about 4.1 KW/m2, and most preferably about 9.6 KW/m2. Similarly, in preferred embodiments, when a 12 amp current is passed through the metal layer, the intensity generated in the metal layer is at least about 5.6 KW/m2, preferably at least about 6.5 KW/m2, more preferably at least about 7.2 KW/m2, and most preferably about 17.2 KW/m2.
For clarity, the above-listed intensity values are measured using a four-point electrical probe technique (and the equation
preferably as described in the experimental section below.
Generally, the amount of intensity needed to be provided by the heating elements for de-icing purposes is in the range of 2.1-3.6 kW/m2. Accordingly, the current used to generate heat in the metal layer can be modified depending on the characteristics of the metal layer. In general, though, it is preferable that the electrical resistivity of the metal layer be higher so that less current needs to be used to generate sufficient heat for de-icing or anti-icing purposes.
In embodiments, the metal-coated composite substrate further comprises one or more additional layer(s) on a side of the metal layer opposite the mesh layer. It is preferable that these layers be as thin as possible, preferable between about 5 microns to about 10 microns, in order to avoid adding too much weight to the metal-coated composite substrate, as well as to ensure that the metal layer is as close to the external surface of the metal-coated composite substrate as possible. This is because, if the metal-coated composite substrate is to function as an electrothermal heating element, the portion of the metal-coated composite substrate that will generate heat (i.e. the metal layer) should be as close as possible to where ice is likely to form. If additional layers are too thick, this will prevent heat from reaching the external surface of the metal-coated composite substrate.
In another aspect of the invention, a method for producing the above composite substrate comprising a mesh layer and a composite material layer is provided.
The method for producing the composite substrate thus comprises the step of:
The starting materials can be the composite material layer, the mesh material, and the adhesive as defined in the previous section. It is generally understood that the resulting composite substrate can be modified for use as an electrothermal heating element (by depositing a metal layer thereon). Accordingly, the composite material layer can be provided by manufacturing and dimensioning a composite material layer according to the intended use of the composite substrate.
It is also understood that the above method can be used on existing parts and structures. This means that said existing parts and structures may be used as the composite material layer. However, if the existing part or structure has a preexisting coating (for example, an adhesive film has already been formed on the existing composite material layer), it is preferable that said preexisting coating be removed before the above method is performed to expose a surface of the composite material layer. This removal of the preexisting coating can be done using any known technique in the art (such as sand blasting), as long as it does not damage the underlying composite material layer.
As an example, many existing wind turbine blades are made of composite materials (i.e. a composite material layer), yet they do not comprise the composite substrate of the present invention. The above method can be used to modify said wind turbine blades so as to transform the existing composite material layer into the composite substrate of the present invention. If the existing composite material layer of the wind turbine already has a preexisting coating thereon (for example, an adhesive film), then said layer should be removed (for example, by sand blasting) before the above method is performed. This removal of preexisting coatings will help lighten the resulting composite substrate, and it will enable the mesh layer to be in direct contact with the composite material layer.
It is also understood that each of the composite material layer, the mesh material, and the adhesive can be provided and/or manufactured using any known method in the art.
In this step, the mesh material is adhered to the surface of a composite material layer using an adhesive, thereby forming the mesh layer. As mentioned previously, in order to increase the adhesion strength of the mesh material to the composite material layer, the adhesive should permeate the mesh material as much as possible. This step can be performed using any known method in the art.
In preferred embodiments, the adhering step is performed using vacuum bagging. Vacuum bagging typically consists of four primary items, including peel ply and release film, breather and bleeder cloth, vacuum bagging film, and a vacuum pump. After vacuum bagging, the setup can be transferred to an autoclave for a curing process under the sufficient pressure and temperature.
As mentioned in the previous section, in preferred embodiments, enough adhesive should be used such that the mesh material is completely embedded in the adhesive and none of the mesh material is exposed to the environment.
As mentioned previously, the surface of the mesh layer can be roughened. This can be done using any known technique in the art, preferably abrasive grit blasting, preferably with alumina grit having an average diameter of about 80 μm. The resulting surface roughness of the composite substrate can be as defined in the previous sections.
As mentioned, the roughening of the mesh layer will expose the mesh material, thereby allowing the mesh material to better anchor a metal layer that will be formed, thereby allowing for a better adhesion of the metal layer to the composite substrate. Therefore, it is preferable that the roughening step expose a sufficient amount of the mesh material, without removing or damaging the mesh material.
When abrasive grit blasting is used, it is preferable to optimize the parameters of the abrasive grit blasting. However, the optimal parameters of the abrasive grit blasting will depend on the adhesive used and the mesh material used. For example, when a 200 steel mesh is used with an epoxy resin adhesive, the abrasive grit blasting should ideally be performed with a pressure of about 76 psi and for about 150 seconds. However, a pressure of 76 psi and a time of 200 seconds may damage or remove the steel wires, while a pressure of 50 psi and a time of 90 seconds could not remove enough epoxy to sufficiently expose the mesh material, thereby having a negative impact on coating adhesion and deposition efficiency of a metal layer.
Similarly, when a 400 steel mesh is used with an epoxy resin adhesive, the abrasive grit blasting should ideally be performed with a pressure of about 66 psi and for about 180 seconds. However, a pressure of 76 psi and a time of 90 seconds may damage or remove the steel wires, while a pressure of 60 psi and a time of 80 seconds could not remove enough epoxy to sufficiently expose the mesh material, thereby having a negative impact on coating adhesion and deposition efficiency of a metal layer.
In general, mesh materials with lower mesh sizes are less sensitive and vulnerable to grit blasting, as their wires are thicker and more resistant to the impact of high-velocity particles. In addition, lower mesh sizes generally result in higher surface roughness. This might be due to the relatively larger voids existing on mesh materials with lower mesh sizes. Accordingly, in general, using mesh materials of lower mesh sizes (for example, a mesh size of 200 compared to a mesh size of 400) results in a better coating deposition and adhesion during spraying of a metal layer.
As mentioned in the previous sections, the mesh layer protects the composite material layer during the roughening step. Accordingly, when grit blasting is used, it is preferable that the mesh size be large enough to prevent the sand particles of the grit blasting from easily penetrating the mesh layer, as this would result in damage to the composite material layer.
The skilled person would understand that, in general, increasing the pressure and time of abrasive grit blasting would remove more resin from the mesh layer, while decreasing the pressure and time of abrasive grit blasting will remove less resin.
If another roughening method is used other than abrasive grit blasting, the optimal parameters of said roughening method should be determined so as sufficiently roughen the mesh layer and expose a sufficient amount of the mesh material, without removing or damaging the mesh material.
In another aspect of the invention, a method for producing the above metal-coated composite substrate comprising a metal layer, a mesh layer and a composite material layer is provided.
The method for producing the metal-coated composite substrate thus comprises the step of:
The starting materials can be the composite substrate as defined in the previous section. It is generally understood that the resulting metal-coated composite substrate can be used as an electrothermal heating element. Accordingly, the composite substrate can be provided by manufacturing and dimensioning a composite substrate according to the intended use of the metal-coated composite substrate.
As for the metal layer, the starting material can be any metal defined in the previous sections. As mentioned, the metal chosen will depend on the intended use of the metal-coated composite substrate, but generally it is preferable for the chosen metal to have high electric resistivity, high mechanical strength, and high resistance to galvanic corrosion. Preferably, the starting material for the metal layer is a metal powder, preferably a fine metal powder or a coarse metal powder. In preferred embodiments, the metal powder is a NiCrAlY powder, more preferably a fine NiCrAlY powder (such as Amdry 9624, Oerlikon, size distribution: −37+11 μm) or a coarse NiCrAlY powder (such as Amdry 9625, Oerlikon. size distribution: −74+45 μm).
The choice of starting material for the metal layer (for example, fine vs coarse metal powder) will somewhat affect the resulting metal layer that is formed on the composite substrate (see the following section for more details and examples). In general, using fine metal powders (as opposed to coarse metal powders) tends to result in a metal layer with lower porosity, higher oxidation, lower deposition efficiency (as in, when spray coating techniques are used, more passes are needed to arrive at coatings of similar thickness as those achieve with coarse metal powders), and tends to require fewer passes to achieve a relatively uniform thickness. However, overall, the use of finer metal powders tends to result in a metal layer of lower electronic resistivity (this could be because porosity likely affects resistivity more strongly than oxidation).
In this step, the metal layer is deposited onto the mesh layer of the composite substrate, thereby forming the metal-coated composite substrate. The resulting metal layer is as defined in the sections above. While this step can be performed using any known method in the art, it is preferable to use thermal spray techniques, more preferably Air Plasma Spray (APS) techniques, preferably using a 3 MB plasma spray gun (Sulzer Metco, Westbury, N.Y.).
If ASP techniques are used, the composite substrate (specifically the composite material layer) may be vulnerable to the high-temperature gases used and the impact of high-temperature particles. Accordingly, in preferred embodiments, the gases and particles are advantageously cooled down, such as by using air amplifiers and air blowers to keep the substrates surface temperature as low as possible during spraying (such as below the composite material layer's curing temperature, if said layer is a thermoset composite).
The parameters of the ASP used will naturally affect the resulting metal layer. In general, such parameters include current, voltage, primary gas (including flow rate thereof), secondary gas (including flow rate thereof), powder feed rate, spray distance, robot speed, and number of passes.
In preferred embodiments, the current used is between about 300 and about 500 A, preferably about 400 or about 500 A, more preferably about 400 A; the voltage is about 60 V; the primary gas is Argon; the primary gas flow rate is about 43.8 L/min; the secondary gas is H2; the secondary gas flow rate is about 6.57 L/min; the powder feed rate is between about 30 g/min and about 70 g/min, preferably about 32 g/min or about 64 g/min, more preferably about 64 g/min; the spray distance is between about 12 cm and about 16 cm, preferably about 13 cm or about 15 cm, more preferably about 13 cm; the robot speed is about 1 m/s, and the number of passes is between about 3 and about 20, preferably 3, 4, 5, or 10, more preferably 3 or 4.
The skilled person would understand that the above parameters could be modified, and that said modifications may affect the resulting metal layer. What is important is that the resulting metal layer conforms to the definition provided above, that the metal layer is sufficiently strongly adhered to the composite substrate, and that the composite substrate is not damaged during the deposition process.
For example, if the current is too high, the powder feed rate is too high, or the spray distance is too low, the composite substrate may end up being burnt. However, if the current is high, other parameters can be adjusted (for example, the powder feed rate can be lowered, or the spray distance can be increased) in order to compensate (although this may impact other aspects of the deposition, such as deposition efficiency). What matters is that the surface temperature of the composite substrate does not become so hot so as to damage or burn the composite substrate.
As mentioned previously, the choice of metal powder, as well as the spray parameters, will affect the resulting metal layer. For example, increasing the number of passes will obviously increase the thickness of the resulting metal layer. However, if a coarse metal powder is used, each pass will increase the thickness of the metal layer by a greater amount than if a fine metal powder had been used (meaning the coarse metal powder has higher deposition efficiency). In general, more passes will increase deposition time, and weaken the adhesion strength of the metal layer to the composite substrate.
If a coarse NiCrAlY powder is used with a 400 stainless steel mesh, 5 passes with ASP (current of 400 A, voltage of 60 V, Argon flow rate of 43.8 L/min, H2 flow rate of 6.57 L/min, powder feed rate of 64 g/min, spray distance of 13 cm, robot speed of 1 m/s) may result in the peeling off of the mesh material from the composite material layer.
If a coarse NiCrAlY powder is used, 3 passes with ASP (current of 400 A, voltage of 60 V, Argon flow rate of 43.8 L/min, H2 flow rate of 6.57 L/min, powder feed rate of 64 g/min, spray distance of 13 cm, robot speed of 1 m/s) may result in a metal layer of non-uniform thickness (the thickness may become relatively uniform after at least 4 passes).
In general, use of a fine powder, when compared to a coarse metal powder, general has the following effect on the above method or the resulting metal layer:
As mentioned, one advantage of the method above is that, due to the presence of the mesh layer (and the roughened surface caused by the surface roughening step, including holes created in the mesh material), the resulting metal layer is anchored to the composite substrate, thereby improving adhesion strength between the metal layer and the mesh layer.
In addition, the presence of the mesh layer helps prevent damage to the composite material layer during the deposition step (including when ASP is used).
It is also worth motioning that, using the above-defined method, the metal layer will be deposited directly on the composite substrate, without an intermediate layer.
As mentioned previously, before the metal layer is deposited onto the mesh layer of the composite substrate, it is preferable that the mesh layer be roughened (if it has not already been roughened). This step is as defined in the previous sections.
In embodiments, as previously mentioned, additional layers may be added to the metal layer. These additional layers are as defined in the previous sections, and they can be added using any known technique in the art.
In developing the composite substrate and the metal-coated composite substrate of the present invention, the inventors discovered a composite substrate comprising a mesh layer that makes for an effective substrate on which to apply a metal coating, as the mesh material will protect the underlying composite material layer during the coating process and at the same time will act as an anchor to keep the metal coating on the surface of the composite substrate. Once coated with a metal layer, the composite substrate makes for an effective electro-thermal heating element, such as a de-icer or anti-icer.
In addition to the advantages previously discussed, the composite substrate and the metal-coated composite substrate of the present invention can present one or more of the following advantages:
The methods of the present invention produce the above-defined composite substrate and the metal-coated composite substrate.
The method of producing the composite substrate of the present invention results in a composite substrate where the mesh layer has relatively high adhesion strength with the composite material layer, and the method allows for the mesh layer to be roughened (using, for example, abrasive grit blasting) without damaging the composite material layer.
In addition, the method of producing a metal-coated composite substrate of the present invention may allow for the deposition a metal layer that is of sufficiently uniform thickness, with strong adhesion strength to the composite substrate, with high electrical resistivity, high mechanical strength, and/or resistance to galvanic corrosion. This process may also allow for high deposition efficiency, without damaging the composite material layer during the deposition of the metal layer (using, for example, ASP techniques) or during the roughing of the mesh layer (using, for example, abrasive grit blasting).
As mentioned, the metal-coated composite substrate of the present invention can be used as an electro-thermal heating element, such as a de-icer or anti-icer. This applies to a vast number of structures, such as in the aerospace industry (e.g. aircrafts), and the energy industry (e.g. wind turbines).
In addition, as previously mentioned, the methods of the present invention can be used on both newly constructed and previously existing structures as shown for example in
The use of the terms “a” and “an” and “the” and similar referents in the context of describing the invention (especially in the context of the following claims) are to be construed to cover both the singular and the plural, unless otherwise indicated herein or clearly contradicted by context.
The terms “comprising”, “having”, “including”, and “containing” are to be construed as open-ended terms (i.e., meaning “including, but not limited to”) unless otherwise noted.
Recitation of ranges of values herein are merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. All subsets of values within the ranges are also incorporated into the specification as if they were individually recited herein.
All methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context.
The use of any and all examples, or exemplary language (e.g., “such as”) provided herein, is intended merely to better illuminate the invention and does not pose a limitation on the scope of the invention unless otherwise claimed.
No language in the specification should be construed as indicating any non-claimed element as essential to the practice of the invention.
Herein, the term “about” has its ordinary meaning. In embodiments, it may mean plus or minus 10% or plus or minus 5% of the numerical value qualified.
Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
Other objects, advantages and features of the present invention will become more apparent upon reading of the following non-restrictive description of specific embodiments thereof, given by way of example only with reference to the accompanying drawings.
The present invention is illustrated in further details by the following non-limiting examples.
Specifically, several experiments were performed, during which various substrates were prepared and coated with metal using a variety of parameters. The following section will first detail the methodology used to create the composite substrates that were tested, to create the metal-coated composite substrates that were tested, and to measure various properties thereof. The subsequent section will detail the results of these experiments.
The experiment methodology consists of four steps including, 1) fabrication and preparation of the composite substrate (specifically GFRP composite substrates), 2) deposition of a metal coating by using a plasma spray technique, 3) determination of the coatings adhesion strength, 4) electrical characterizations of the coated samples and analyzing their performance as a heating element.
In the first step, three 30 by 30 cm square plates were made using GFRP (Cytec E773FR, 5 Garret Mountain Plaza, Woodland Park, N.J. 07424 USA) prepreg plies and stainless steel mesh cloths. The GFRP prepregs were taken out of the freezer and left at the room conditions for about three hours. This allows the temperature of prepreg to rise to room temperature and the viscosity is reduced so that the prepregs can be cut into smaller sheets easier. After that, the prepregs were cut into 30 by 30 cm square sheets. For making a 4 mm thick composite plate, 16 unidirectional GFRP plies (i.e. [016] composite) were utilized. In order to protect the composite fibers from the impact of high-velocity particles during preparation and metal spraying (coating deposition step), woven wire #200 and #400 stainless steel mesh cloths (type 316) were incorporated as a top layer to the first and second plates, respectively. The properties of these steel mesh cloths are listed in Table 1 below. After stacking and aligning the prepregs and steel mesh cloths, they were placed on a tool and vacuum bagged. The vacuum bag setup consisted of four primary items, including peel ply and release film, breather and bleeder cloth, vacuum bagging film, and a vacuum pump. After vacuum bagging, the setup was transferred to an autoclave for the curing process under the pressure and temperature of 74.5 kPa and 120° C., respectively.
Once the composite plates were fabricated, they were cut into smaller samples using a diamond saw. In the next step, the composite substrates were roughened and prepared for the coating deposition process using grit blasting. In the grit blasting process, the abrasive particles that are sucked into a nozzle are accelerated toward the substrate surface using a pressurized gas stream. More than 30 samples were grit blasted to find an optimized set of parameters for each type of composite substrate. These substrates include the conventional composite substrate (without addition of any metallic mesh), the plate fabricated by addition of a 200 steel mesh cloth (hereafter will be called the “200 mesh substrate”), and the plate fabricated by addition of a 400 steel mesh cloth (hereafter will be called the “400 mesh substrate”). The optimized grit blasting parameters for each type of composite substrate are shown in Table 2. It should also be mentioned that the alumina grit used in the experiment had an average diameter of about 80 μm. It should be noted that while the term optimized is used both here and throughout this experimental section to refer to parameters, other parameters could be used.
Once the optimized parameters were found for grit blasting of the composite substrates, Air Plasma Spray technique (APS) was used for the deposition of a metallic coating layer onto the composite substrates. Two types of NiCrAlY powders with the fine (Amdry 9624, Oerlikon, size distribution: −37+11 μm) and coarse (Amdry 9625, Oerlikon. size distribution: −74+45 μm) size distributions were utilized for spraying and fabrication of a heating element for the composite substrates. A 3 MB plasma spray gun (Sulzer Metco, Westbury, N.Y.) was also used to spray the NiCrAlY powders. Given that the composite substrates were vulnerable to the high-temperature gases and impact of high-temperature particles, they were cooled down using two air amplifiers and two air blowers to keep the substrates' surface temperature as low as possible during spraying (below the composite curing temperature). In the first step, four experiments were done for finding an appropriate set of spray parameters for the coating of the composite samples using fine NiCrAlY powder (see Table 3 below). It was found that coatings with high quality and adhesion could be generated using Exp 4 spray parameters. It was also found that acceptable coatings could be deposited by using Exp 4 parameters and the coarse NiCrAlY powder. Given that in the case of using coarse NiCrAlY powder, the coating thickness changed significantly with the number of passes, the composites were coated with three different numbers of passes (Exp 5-7 in Table 3). Upon the completion of the coating process, a metallographic technique was used for analyzing the microstructure of the coated samples under a microscope. After finding the proper spray parameters, larger composite samples (2.3-by-10 cm) were coated for the mechanical and electrical characterizations.
In this step, a flatwise tensile test was performed for measuring the adhesion strength (bond strength) of the coated samples. For this purpose, first, a two-component adhesive (Henkel Loctite Hysol EA 9392 AERO Epoxy Adhesive Gray, LOCTITE, Henkel Canada Corporation, Canada) including epoxy and hardener were mixed together with a weight ratio by weight of 100:32. On completion of the mixing, a thin and even layer of the mixture was applied on both sides of the 2.5 by 2.5 cm coated samples. Following this, the samples were sandwiched between two stainless steel blocks and placed in an oven at a temperature of 85° C. and for about 90 minutes for curing the adhesive. Once the curing process was completed, the blocks were connected to two Wyoming flatwise tensile test fixtures by using two pins. The fixtures were then placed in a flatwise tensile machine (with a displacement rate of 0.50 mm/min) for applying tension and measuring the adhesion strength of the coatings. The samples then were analyzed for detecting the failure type.
Given that the amount of heat generated by a coated heating element (de-icing element) for a given current depends directly on the coating electrical resistance, the electrical properties of the coating were determined. For this purpose, the four-point electrical probe technique was used for determining the electrical properties of the specimens. This technique is very useful for eliminating the wire and contact resistances that may cause an error in calculating the resistance of the sample. A schematic view of this method is shown in
Different electrical currents (6, 9, and 12 A) were applied to the samples, and the resulted voltage drop between spots 2 and 3 was measured using a voltmeter at the same time. The electrical resistance R and resistivity ρ of the coatings were then calculated as follows:
Sheet resistance is another electrical term used more for electrical characterization of the relatively thin coatings and paints. By referring to Equation 1, the sheet resistance can be calculated as follows:
Rs is the sheet resistance. The sheet resistance is the resistivity of a specimen divided by its thickness and its unit is ohme Ω. For analyzing the performance of the coatings in generating heat and acting as a heating element, the generated power per unit area (intensity) in each coated sample for a given current was calculated by using the following equation:
in which As is the surface area.
As mentioned, three types of composite substrates were prepared for the deposition of the NiCrAlY coating, which are: conventional composite substrate, 200 mesh substrate, and 400 mesh substrate. Before grit blasting and preparing the substrates for the coating deposition process, the 200 and 400 mesh substrates were characterized and their cross-sections were examined under an optical microscope.
After examination of the cross-section of the composite substrates, the samples were grit-blasted under different grit blasting parameters.
As mentioned earlier, more than 30 composite substrates (200 and 400 mesh substrates) were grit-blasted to obtain an optimized set of grit blasting parameter for each type of substrate.
Globally, by comparing
Four experiments (see Table 3 above) were performed to find an appropriate set of spray parameters for depositing a NiCrAlY coating layer onto composite substrates. In this series of experiments, the NiCrAlY powder with fine size distribution (−37+11 μm) was used as the coating material. In experiment 1, samples were coated using the reference parameters. As shown in
In experiment 2, in which the powder feed rate was decreased from 64 to 30 g/min (compared to experiment 1), the samples were not burnt. However, as shown in
In experiment 4, the plasma current was reduced from 500 A to 400 A. Consequently, the plasma input power decreased about 25% compared to the previous experiments. The maximum surface temperature of the substrates during spraying was about 105° C.
In the second phase of experiments (experiments 5-7), composite substrates were coated using the coarse NiCrAlY powder with a size distribution of −74+45 μm, which allowed for a comparison to be made between the coatings sprayed using the coarse powder and those sprayed using the fine powder. This comparison mainly includes analyzing the coatings microstructure, thickness, amount of oxidation, and electrical resistivity to determine which type of coating might be more proper as a heating element. It was found that experiment 4 spray parameters are also suitable and proper for the deposition of coating using coarse NiCrAlY powder. The coating thickness was changing significantly with the number of passes and the deposition efficiency was higher. The composites were coated with the different number of passes (i.e. 3, 4, and 5 passes).
In experiment 5, samples were coated in three passes. As shown in
In experiment 6, in which the composite samples were coated in 4 passes, the coatings had a relatively uniform thickness (see
Finally, in experiment 7, the coatings were sprayed onto the composite substrates in 5 passes. As shown in
Overall, the results of these seven experiments show that an appropriate and uniform NiCrAlY coating layer could be deposited onto the grit-blasted 200 and 400 mesh substrates by using both fine and coarse NiCrAlY powders. It can also be seen that using the powder with the fine size distribution resulted in the formation of a coating with higher uniformity as the powder particles were significantly smaller compared to those of the coarse powder. The image analysis results also show that in the coatings generated using fine powder, the porosity is very low (0.9±0.1%), and the oxidation is relatively high (31.6±1.6%). On the contrary, in the coating generated by the coarse powder, the porosity is relatively high (6.4±1.2%), and the oxidation is relatively low (11.8±1.4%). It also seems that utilizing the coarse powder contributes to a better deposition efficiency as a 100 μm NiCrAlY coating layer can be fabricated in 5 passes using the coarse powder and in 10 passes using the fine powder while the powder feed rate in both cases is 65 g/min. However, it should be noted that controlling the coating thickness in the case of using fine powder tends to be considerably better and easier. Another interesting observation is that the coating tends to penetrate more into the mesh cloth and substrate when it is sprayed using the coarse powder. This might be explained by the fact that the coarse powder particles are notably heavier than the fine powder particles, and consequently, when they reach the substrate, they have more momentum and penetrate more into the steel mesh cloth. It should also be noted that in all cases, the coatings did not reach and damage the composite fibers.
In order to quantify the adhesion between the substrate and coating, a flatwise tensile test (defined above) was performed. The bonding strength results of the NiCrAlY coatings deposited onto the composite substrate are depicted in
The coated samples were characterized electrically using the four-point probe method (defined above). Currents of 6, 9, 12 A were applied to the coated samples and the resulted voltage was measured. The relationship between the applied currents through the coating and the corresponding voltage for the coated samples with the dimensions of 2.3-by-10 cm is shown in
V-I curves' slope represents the electrical resistance of the coatings. So, the electrical resistance of samples F-10-200, C-5-200, C-4-200, and C-3-200 are 0.091, 0.104, 0.116, and 0.263Ω, respectively. The resistance of the coated samples was also measured at different temperatures (25 to 150° C.). It was found that in that range of temperature, in all the cases, the resistance of the NiCrAlY coating is almost constant and independent of the coating surface temperature. This is one of the advantages of NiCrAlY over other materials used for the fabrication of heating element coatings (e.g. NiCr, FeCrAl). From
the resistance is directly proportional to the electrical resistivity and length and is inversely proportional to the cross-section area. By increasing the number of passes and consequently the coating thickness, the resistance tends to decrease. In addition, by comparing samples C-5-200 and F-10-200 it can be seen that the resistance of the former is a little bit higher, while in both cases, the coating thickness is approximately the same. This is due to the fact that the electrical resistivity of the coatings generated by the coarse powder is about 12% higher than that of the coatings generated by the fine powder (see Table 4 below). By having the resistance of the coatings, the resistivity could be calculated. Resistivity is an intrinsic property that unlike resistance does not depend on the shape and dimensions of the material. So, the resistivity value of two coatings sprayed with the same spray parameters but with a different number of passes should be similar and close to each other. However, as the spray parameter and powder size have a direct impact on the percentage of coating oxidation and porosity, changing them may slightly result in different resistivity values. In addition, since the coatings are always associated with porosity and oxidation, their intrinsic properties like electrical resistivity are usually different from the bulk and pure materials. As mentioned earlier, the image analysis showed that the coatings generated using fine powder have a porosity of 0.9±0.1% and an oxidation of 31.6±1.6%, and the coatings generated using coarse powder have a porosity of 6.4±1.2% and an oxidation of 11.8±1.4%. By comparing the resistivity values of the coatings, it seems that the porosity had a more important role and impact, compared to the oxidation, in increasing the coating resistivity value.
Sheet resistance, which is an electrical term used more for characterizing thin coatings, was calculated using
The sheet resistance values for different types of coatings are shown in Table 4 below. One advantage of sheet resistance over electrical resistance is its independence from the size which makes a comparison between different samples easier. It also shows the capability of a sample in generating heat when a given current is applied to it. The sheet resistance of sample C-3-200 (about 0.058 Ω/square) is noticeably higher than that of the other coated samples due to its lower thickness. This means that this type of coating should generate more power and heat compared to the other coated samples for a given current. The sheet resistance values of the other coated samples are relatively close to each other as there is not a very big difference between their thicknesses and resistivity values.
Once the samples were characterized electrically, their performance in generating power and acting as a heating element was tested. For this purpose, the generated intensity (power per unit area) of the coated composite samples for a given current was calculated using
equation. The amount of generated intensity in the coated samples for 6, 9, and 12 A currents is presented in
The infrared camera pictures (see
In these experiments, a method for the fabrication of a NiCrAlY coating layer on polymer-based composite materials by using a plasma spray technique is tested. Three types of composite substrates were made by using glass fibre reinforced prepreg plies and stainless steel mesh cloths, which were: 1) a conventional composite substrate, 2) a 200 mesh substrate, which was made by incorporating an extra 200 stainless steel mesh cloth on top of the prepregs, and 3) a 400 mesh substrate which was made by incorporating an extra 400 stainless steel mesh cloth on top of the prepregs. After preparing the composite substrates by grit blasting, the samples were coated by fine and coarse NiCrAlY powders. The microscopic images of the coated sample cross-sections revealed that the deposition of a metallic coating onto conventional composites is very limited. In this case, the grit blasting also resulted in breaking and damaging the composite fibers significantly. However, in the cases of 200 and 400 mesh substrates, it was observed that a uniform NiCrAlY coating with high deposition efficiency and uniformity could be deposited by using a proper set of spray parameters. Indeed, the incorporation of the stainless steel mesh cloths to the composite structure not only improved the coating adhesion and deposition efficiency significantly but also played the role of armor for the composite part and protected the composite fibers from the impact of high-velocity particles during grit blasting and spraying. It was also observed that using the fine NiCrAlY powder resulted in the generation of coatings with very high uniformity. Also, the coatings that were deposited in 4 and 5 passes using the coarse powder had adequate uniformity. However, the controllability in the case of using coarse powder was relatively low as the coating thickness was changing significantly with the number of passes. The deposition efficiency of the coarse powder also was higher than the fine powder. The results of the coating adhesion strength showed that the coating bonding strength in the cases in which the 200 mesh composite was used as the substrate is very high. The adhesion strength values obtained for samples C-4-200 and F-10-200 (about 22 MPa) were about 50% higher than the adhesion strength values reported for the coated composites in the literature.
The results of the electrical characterization of the coated samples also indicated that using NiCrAlY powder with the coarse size distribution (compared to the fine powder) tends to result in the formation of coatings with higher resistivity value. After checking the performance of the coated samples as a heating element, it was found that all the coated samples have the capability of generating intensity more than the amount of intensity required for de-icing applications. Sample C-3-200 had the highest capability in generating power for a given current; however, in this case, unlike other samples (F-10-200, C-4-200, and C-5-200), the surface temperature distribution was non-uniform. Based on several factors, like the intended application of heating element, where it is intended to be used, the amount of power needed, the importance of uniformity, and other limitations, each of these heating element coatings might be useful. It is worth noting that the 200 steel mesh cloth used in this study just adds 0.28 kg/m2 to the weight of the substrate, while the equipment used in conventional de-icing systems (like bleed air de-icing systems) adds hundreds of pounds of weight to the aircraft.
The scope of the claims should not be limited by the preferred embodiments set forth in the examples, but should be given the broadest interpretation consistent with the description as a whole.
The present description refers to a number of documents, the content of which is herein incorporated by reference in their entirety. These documents include, but are not limited to, the following:
| Number | Date | Country | |
|---|---|---|---|
| 63025925 | May 2020 | US |
