Composite vehicle body

Information

  • Patent Grant
  • 11383819
  • Patent Number
    11,383,819
  • Date Filed
    Tuesday, August 11, 2020
    3 years ago
  • Date Issued
    Tuesday, July 12, 2022
    a year ago
Abstract
A vehicle body may have an internal skeleton forming a wing shape, and a skin formed over the internal skeleton. The skin may include a matrix material, and a plurality of continuous fibers encased within the matrix material. The plurality of continuous fibers may curve from a base end near a fore/aft center of the wing shape outward toward leading and trailing edges of the wing shape at a tip end.
Description
TECHNICAL FIELD

The present disclosure relates generally to a vehicle body and, more particularly, to a vehicle body made from a composite material.


BACKGROUND

A vehicle body (e.g., an airplane body, a car body, or a boat body) generally includes an internal skeleton that gives shape to the vehicle, and a skin that overlays the skeleton and provides a smooth outer surface. Modern vehicle bodies are fabricated from a combination of different materials, including composites. For example, the skeleton is typically made of wood, aluminum, or stainless steel, while the skin is typically made of a fiber (e.g., a carbon fiber or fiberglass) embedded within a resin matrix.


Pultrusion is a common way to manufacture straight skeletal parts of a vehicle body (e.g., beams, longerons, etc.). During pultrusion manufacturing, individual fiber strands, braids of strands, and/or woven fabrics are pulled from corresponding spools through a resin bath and through a stationary die. The resin is then allowed to cure and harden. Due to the pulling of the fibers prior to curing, some of the fibers may retain a level of tensile stress after curing is complete. This tensile stress can increase a strength of the skeletal part in the direction in which the fibers were pulled.


A vacuum-assisted resin transfer molding (VARTM) process is commonly used to fabricate the skin of the vehicle body, after the internal skeleton has already been formed. In a VARTM process, sheets of fibrous material are manually pulled over the internal skeleton and then tacked in place. The tacked material is then manually coated with a liquid matrix (e.g., a thermoset resin or a heated thermoplastic), covered with a vacuum bag to facilitate impregnation of the liquid matrix, and allowed to cure and harden.


Although pultrusion manufacturing and VARTM can be an acceptable ways to produce vehicle body parts in some situations, they can also be problematic. In particular, the VARTM-produced skin is often attached to the pultruded skeletal parts and/or reinforced via metallic fasteners (e.g., screws, rivets, and clips). The use of metallic fasteners can drive skeletal design and increase a weight and cost of the vehicle body. In addition, the various vehicle body parts may need to be joined to each other via specially designed hardware, which can also be heavy and costly. Further, electronics (e.g., sensors, heaters, electrical leads, etc.) may need to be added to the vehicle bodies after manufacture, which can further increase the weight, cost, and unreliability. Finally, conventional pultrusion and VARTM manufacturing processes may provide little flexibility in the design and/or use of the vehicle body.


The disclosed composite vehicle body is directed to overcoming one or more of the problems set forth above and/or other problems of the prior art.


SUMMARY

In one aspect, the present disclosure is directed to a vehicle body. The vehicle body may include an internal skeleton forming a wing shape, and a skin formed over the internal skeleton. The skin may include a matrix material, and a plurality of continuous fibers encased within the matrix material. The plurality of continuous fibers may curve from a base end near a fore/aft center of the wing shape outward toward leading and trailing edges of the wing shape at a tip end.


In another aspect, the present disclosure is directed to another vehicle body. This vehicle body may include an internal skeleton, and a skin fabricated in-situ over the internal skeleton. The internal skeleton and the skin together may form a wing shape. The internal skeleton may include a plurality of continuous fibers that extend into and form a portion of the skin.


In another aspect, the present disclosure is directed to another vehicle body. This vehicle body may include an internal skeleton, and a skin fabricated in-situ over the internal skeleton. The skin may include a matrix material and a plurality of continuous fibers encased within the matrix material. The matrix material may include multiple resins, each deposited at different strategic locations along a length of the plurality of continuous fibers in the skin.


In another aspect, the present disclosure is directed to another vehicle body. This vehicle body may include a skin including matrix material and plurality of continuous fibers at least partially coated with the matrix material. The plurality of continuous fibers may include a first plurality of continuous fibers arranged into a first layer that is generally parallel to an outer surface of the vehicle body, a second plurality of continuous fibers arranged into a second layer overlapping the first layer, and a third plurality of continuous fibers extending normal to the outer surface from the first layer into the second layer to interlock the first and second layers.


In another aspect, the present disclosure is directed to another vehicle body. This vehicle body may include an internal skeleton having a plurality of adjacent tubular structures that together form a wing shape, and a skin formed from a composite material over the internal skeleton.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a diagrammatic illustration of an exemplary vehicle body;



FIG. 2-5 are diagrammatic illustrations of exemplary portions of the vehicle body of FIG. 1 during manufacture;



FIG. 6 is a cross-sectional illustration of an exemplary fiber that may be used to fabricate the vehicle body of FIG. 1; and



FIGS. 7-9 are diagrammatic illustrations of additional exemplary portions of the vehicle body of FIG. 1.





DETAILED DESCRIPTION


FIG. 1 illustrates an exemplary vehicle body (“body”) 10. In the disclosed embodiment, body 10 is an aircraft body (e.g., an airplane body or a drone body). It is contemplated, however, that body 10 could be of another type (e.g., a car body, a boat body, etc.), if desired. Body 10, regardless of its configuration and intended use, may include one or more components (e.g., a fuselage 12, one or more wings 14, etc.) made from an internal skeleton (e.g., spars, ribs, stringers, bulkheads, trusses, longerons, etc.) 16 covered by an external skin 18. In some embodiments, the components of body 10 may be fabricated separately and subsequently joined together (e.g., via threaded fastening, riveting, etc.). In other embodiments, the body components may be fabricated together as an integral monolithic structure (e.g., a structure that cannot be disassembled without at least some destruction).


As shown in FIG. 2, one or more of the components of body 10 may be fabricated via an additive manufacturing process. For example, skeleton 16 may be fabricated from a first additive manufacturing process, while skin 18 may be manufactured from a second and different additive manufacturing process. It is contemplated that both skeleton 16 and skin 18 could be manufactured from the same additive manufacturing process, if desired.


The first additive manufacturing process may be a pultrusion and/or extrusion process that creates hollow tubular structures 20 from a composite material (e.g., a material having a matrix M and at least one continuous fiber F). In particular, one or more heads 22 may be coupled to a support 24 (e.g., to a robotic arm) that is capable of moving head(s) 22 in multiple directions during discharge of structures 20, such that resulting longitudinal axes 26 of structures 20 are three-dimensional. Such a head is disclosed, for example, in U.S. patent application Ser. Nos. 13/975,300 and 15/130,207 and in PCT Application Number 2016042909, all of which are incorporated herein in their entireties by reference.


Head(s) 22 may be configured to receive or otherwise contain the matrix material M. The matrix material M may include any type of liquid resin (e.g., a zero volatile organic compound resin) that is curable. Exemplary resins include epoxy resins, polyester resins, cationic epoxies, acrylated epoxies, urethanes, esters, thermoplastics, photopolymers, polyepoxides, thermoset acrylates, thermosets, bismaleimides, silicon, and more. In one embodiment, the pressure of the matrix material M inside of head(s) 22 may be generated by an external device (e.g., an extruder or another type of pump) that is fluidly connected to head(s) 22 via corresponding conduits (not shown). In another embodiment, however, the pressure may be generated completely inside of head(s) 22 by a similar type of device and/or simply be the result of gravity acting on the matrix material M. In some instances, the matrix material M inside head(s) 22 may need to be kept cool and/or dark in order to inhibit premature curing; while in other instances, the matrix material M may need to be kept warm for the same reason. In either situation, head(s) 22 may be specially configured (e.g., insulated, chilled, and/or warmed) to provide for these needs.


The matrix material M stored inside head(s) 22 may be used to coat any number of continuous fibers F and, together with the fibers F, make up walls of composite structures 20. The fibers F may include single strands, a tow or roving of several strands, or a weave of many strands. The strands may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, metallic wires, SiC Ceramic fibers, basalt fibers, etc. The fibers F may be coated with the matrix material M while the fibers F are inside head(s) 22, while the fibers F are being passed to head(s) 22, and/or while the fibers F are discharging from head(s) 22, as desired. In some embodiments, a filler material (e.g., chopped fibers) may be mixed with the matrix material M before and/or after the matrix material M coats the fibers F. The matrix material, the dry fibers, fibers already coated with the matrix material M, and/or the filler may be transported into head(s) 22 in any manner apparent to one skilled in the art. The matrix-coated fibers F may then pass over a centralized diverter (not shown) located at a mouth of head(s) 22, where the resin is caused to cure (e.g., from the inside-out, from the outside-in, or both) by way of one or more cure enhancers (e.g., UV lights and/or ultrasonic emitters) 27.


In the example of FIG. 2, structures 20 extend in a length direction of wing 14 and makeup at least a portion of skeleton 16. Each structure 20 may be discharged adjacent another structure 20 and/or overlap a previously discharged structure 20, and subsequently cured such that the liquid resin within neighboring structures 20 bonds together. Any number of structures 20 may be grouped together and have any trajectory required to generate the desired skeletal shape of wing 14.


In some embodiments, a fill material (e.g., an insulator, a conductor, an optic, a surface finish, etc.) could be deposited inside and/or outside of structures 20 while structures 20 are being formed. For example, a hollow shaft (not shown) could extend through a center of and/or over any of the associated head(s) 22. A supply of material (e.g., a liquid supply, a foam supply, a solid supply, a gas supply, etc.) could then be connected with an end of the hollow shaft, and the material forced through the hollow shaft and onto particular surfaces (i.e., interior and/or exterior surfaces) of structure 20. It is contemplated that the same cure enhancer(s) 27 used to cure structure 20 could also be used to cure the fill material, if desired, or that additional dedicated cure enhancer(s) (not shown) could be used for this purpose. The fill materials could allow one or more of structures 20 to function as fuel tanks, fuel passages, electrical conduits, ventilation ducts, etc.


The second additive manufacturing process used to fabricate the exemplary wing 14 of FIG. 2 may also be a pultrusion and/or extrusion process. However, instead of creating hollow tubular structures 20, the second additive manufacturing process may be used to discharge tracks, ribbons, and/or sheets of composite material over tubular structures 20 (and/or over other features of skeleton 16) to thereby fabricate skin 18. In particular, one or more heads 28 may be coupled to a support 30 (e.g., to an overhead gantry) that is capable of moving head(s) 28 in multiple directions during fabrication of skin 18, such that resulting contours of skin 18 are three-dimensional.


Head 28 may be similar to head 22 and configured to receive or otherwise contain a matrix material M (e.g., the same matrix material M contained within head 22). The matrix material M stored inside head(s) 28 may be used to coat any number of separate fibers F, allowing the fibers F to make up centralized reinforcements of the discharging tracks, ribbons, and/or sheets. The fibers F may include single strands, a tow or roving of several strands, or a weave of multiple strands. The strands may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, metallic wires, etc. The fibers F may be coated with the matrix material M while the fibers F are inside head(s) 28, while the fibers F are being passed to head(s) 28, and/or while the fibers F are discharging from head(s) 28, as desired. The matrix material, the dry fibers, and/or fibers already coated with the matrix material may be transported into head(s) 28 in any manner apparent to one skilled in the art. The matrix-coated fibers F may then pass through one or more circular orifices, rectangular orifices, triangular orifices, or orifices of another curved or polygonal shape, where the fibers F are pressed together and the resin is caused to cure by way of one or more cure enhancers 27.


In another exemplary embodiment shown in FIG. 3, only a single additive manufacturing process is being used to fabricate wing 14. In particular, the second manufacturing process described above is being used to additively build up layers of skeleton 16 (e.g., of spars and/or stringers) with continuous fibers F and matrix material M and to cover skeleton 16 with additively built up layers of skin 18 of the same or different continuous fibers F and matrix material M. The fibers F making up skeleton 16 may continue over an outer surface of skeleton 16 to become part of skin 18, such that a continuous mechanical connection is formed between skeleton 16 and skin 18 by the continuous fibers F. In this way, the number of fasteners required to connect skin 18 to skeleton 16 may be reduced (if not eliminated). It is contemplated that support 24 and/or support 30 may be used to move any number of heads 28 during fabrication of wing 14 (or during fabrication of any other component of body 10).


As described above, the first and second additive manufacturing processes can be extrusion or pultrusion processes. For example, extrusion may occur when the liquid resin matrix M and the associated continuous fibers F are pushed from head(s) 22 and/or head(s) 28 during the movement of supports 24 and/or 30. Pultrusion may occur after a length of resin-coated fibers is connected to an anchor (not shown) and cured, followed by movement of head(s) 22 and/or heads (28) away from the anchor. The movement of head(s) 22 and/or head(s) 28 away from the anchor causes the fibers F to be pulled from the respective head(s) along with the coating of the matrix material M.


In some embodiments, pultrusion may be selectively implemented to generate tension in the fibers F that make up skeleton 16 and/or skin 18 and that remains after curing. In particular, as the fibers F are being pulled from the respective head(s), the fibers F may be caused to stretch. This stretching can create tension within the fibers F. As long as the matrix M surrounding the fibers F cures and hardens while the fibers F are stretched, at least some of this tension remains in the fibers F and functions to increase a strength of the resulting composite structure.


Structures fabricated via conventional pultrusion methods may have increased strength in only a single direction (e.g., in the one direction in which fibers were pulled through the corresponding die prior to manual resin impregnation and curing). However, in the disclosed embodiment, the increased strength in the skeleton 16 and/or skin 18 of body 10 (e.g., within wing 14) caused by residual tension within the corresponding fibers F may be realized in the axial direction of each the fibers F. And because each fiber F could be pulled in a different direction when being discharged by head(s) 22 and/or 28, the tension-related strength increase may be realized in multiple (e.g., innumerable) different directions.


Structures fabricated via conventional pultrusion methods may have strength increased to only a single level (e.g., to a level proportionate to an amount in which the fibrous cloth was stretched by the pulling machine prior to manual resin impregnation and curing). However, in the disclosed embodiment, because the matrix M surrounding each fiber F may be cured and harden immediately upon discharge, the force pulling on the fiber F may be continuously varied along the length of the fiber F, such that different segments of the same fiber F are stretched by different amounts. Accordingly, the tensile stress induced within each of the different segments of each fiber F may also be different, resulting in a variable strength within the different segments of skeleton 16 and/or skin 18 of body 10. This may be beneficial in variably loaded areas of body 10 (e.g., at the intersection of wing 14 and fuselage 12, within a center of wing 14, at the leading edge of wing 14, etc.).



FIG. 4 illustrates an exemplary way in which the fibers F of skin 18 can be arranged to provide for desired characteristics of wing 14. In this example, the fibers F are arranged organically (e.g., in the way that a tree grows or in the way that blood veins are situated in the body). Specifically, the fibers F placed over structure 16 of wing 14 may be anchored at an intersection with fuselage 12 and in a general fore/aft center. The fibers F may then be pulled toward a distal tip of wing 14, and away from the fore/aft center (e.g., toward a leading or trailing edge of wing 14), with different fibers F extending different distances toward the distal tip. In addition, because the discharging matrix material M may cure immediately upon discharge from head 28 and bond to either structure 16 or previously discharged layers of skin 18, movement of head 28 during discharge may be controlled to create trajectories of the fibers F that curve. It is contemplated that the fibers F may pass completely around wing 14 at its distal termination point, and then be pulled back toward fuselage 12 following a mirror image of its initial trajectory. This arrangement of organically arranged fibers may be located at a top side of wing 14, at a lower side, and/or around a cross-sectional perimeter of wing 14 at multiple locations. With this arrangement, a greater density of fibers F may exist near fuselage 12 than near the distal tip of wing 14. Accordingly, wing 14 may be thicker near fuselage 12 and near the general fore/aft center, and taper toward the distal tip and the leading and trailing edges. Other arrangements and/or fiber distribution schemes may be employed, as desired.


In one exemplary embodiment shown in FIG. 5, some of the fibers F within the composite material making up one or more portions of body 10 have unique characteristics. For example, while a majority of wing 14 may comprise a structural type fiber Fs (e.g., carbon fibers, fiberglass, or Kevlar fibers), some portions of wing 14 may include another type of fiber F (e.g., electrically conductive fibers Fec, optical fibers Fo, shape memory fibers Fsm, etc.). The other type of fibers F may be selectively interwoven with the structural type fibers Fs at strategic locations. For example, electrically conductive fibers Fec may be located at leading edges and/or thinner portions of wing 14 and used as heating electrodes that can be connected to a power source and used to remove ice from wing 14. Alternative, electrically conductive fibers Fec may be located at high-stress regions (e.g., at the intersection of wing 14 and fuselage 12) and used as strain gauges to detect loading of body 10. In a similar manner optical fibers Fo may be located at high-stress regions and an energy beam passed therethrough. As body 10 flexes, the optical fibers Fo may be squeezed and/or closed, thereby generating an optical feedback signal indicative of the flexing. In yet another embodiment, fibers Fsm fabricated from a shape memory alloy (e.g., Nitonol) may be interwoven with the structural type fibers Fs and selectively energized (e.g., via electricity or heat) to cause flexing (e.g., controlled pulling and/or pushing) of body 10 that results in a desired aerodynamic performance (e.g., steering, orientation, elevation control, stability, drag, etc.). As shown in FIG. 6, it is contemplated that the electrically conductive fibers Fec, the optical fibers Fo, and/or the shape memory fibers Fsm may be coated with another material (e.g., insulation, a strength enhancing layer, etc.), if desired. It is also contemplated that other electrical components (e.g., resistors, capacitors, etc.) may be extruded through heads 22, 28 and/or automatically picked-and-placed (e.g., via attachments associated with heads 22 and/or 28) during discharge of fibers Fec, fibers Fo, and/or fibers Fsm. Operation of these components and/or of fibers Fec, fibers Fo, and/or fibers Fsm may be selectively tuned in these instances, for example by adjusting a shape, tension, and/or size of the fibers.


Structures fabricated via conventional pultrusion and/or extrusion methods may be limited in the orientation of the associated fibers. That is, the fibers may be generally overlapping and lie in parallel layers. However, in the embodiment illustrated in FIG. 5, because the matrix M surrounding each fiber F may be cured and harden immediately upon discharge, the fibers F may be caused to extend into free space without additional support. That is, the fibers F may not be required to lie in flat layers on top of each other. Accordingly, the fibers F making up skeleton 16 and/or skin 18 may be oriented in directions that are perpendicular to each other in three dimensions. For example, FIG. 5 illustrates fibers Fn that extend in a direction normal to the surface of wing 14. This may allow for interlocking of fiber layers and/or for the creation of unique (e.g., turbulence enhancing) surface textures.


As described above and shown in FIG. 5, body 10 may be fabricated as an integral monolithic structure, in some embodiments. For example, wings 14 may be fabricated together with (e.g., at the same time as and without separation from) fuselage 12. In particular, as support(s) 24 and/or 30 move any number of head(s) 28 over skeleton 16 to create skin 18 (referring to FIG. 2), head(s) 28 may pass from one wing 14, over or under fuselage 12, and continue across the opposing wing 14. In this instance, the fibers F discharging from head(s) 28 may be continuous over wings 14 and fuselage 12. This process may be repeated any number of times, such that millions (if not hundreds of millions) of fibers F extend through the intersection between wings 14 and fuselage 12, thereby creating a strong mechanical connection without requiring the use of specialized hardware and/or heavy fasteners.


In the exemplary embodiment shown in FIG. 5, the matrix M within the composite material making up one or more portions of body 10 has unique characteristics. For example, while a majority of wing 14 may comprise a structural type matrix Ms (e.g., a conventional UV curable liquid resin such as an acrylated epoxy), some portions of wing 14 may include another type of matrix M (e.g., a pyrolized matrix Mp, a matrix that remains somewhat flexible Mf, etc.). The other type of matrix M may be selectively used to coat the fibers F at strategic locations. For example, the pyrolized matrix Mp may be fed into head 28 as head 28 nears the leading edge of wing 14 and/or a nose of fuselage 12, such that the resulting composite material may function as a heat shield in these areas. In another example, the flexible matrix Mf may be fed into head 28 as head 28 nears the trailing edge of wing 14 (e.g., where the shape memory fibers Fsm are placed, such that the resulting composite material may be more flexible and selectively warped or twisted to provide for the desired aerodynamic properties described above.



FIG. 7 illustrates an exemplary part 32 of skeleton 16 that may be fabricated through the use of head 28 and support 30. Although depicted and described as a rib of wing 14, part 32 could be another skeletal component of wing 14 and/or fuselage 12. In this example, part 32 includes opposing outer support surfaces 34, opposing internal braces 36, and a plurality of cross-pieces 38 that interconnect support surfaces 34 and/or braces 36. It should be noted that outer support surfaces 34 and/or internal braces 36 could have any desired shape, for example curved, flat, stepped, etc. It is also contemplated that outer support surfaces 34 and internal support surfaces 34 could form one or more continuous surfaces, if desired. For example, one or more of support surfaces 34 could be curved and generally tangential with one or more of braces 36 (e.g., at a leading and/or trailing end of the rib). And although cross-pieces 38 are shown as generally straight and oriented at about 45° relative to support surfaces 34 and braces 36, it is contemplated that cross-pieces 38 could also be curved and/or oriented at another angle. It should be noted that, although seven adjacent and nearly identical parts 32 are shown to make up the disclosed rib, any number of the same or different parts 32 (e.g., only one part 32) may be used for this purpose.


Part 32 may be created following a unique tool path that allows for use of continuous fibers and provides for high-strength in a low-weight configuration. In particular, part 32 may be fabricated using a middle-out strategy. FIG. 8 illustrates use of this strategy during fabrication using multiple different and overlapping layers.


For example, in a first layer, head 28 may be controlled to start discharging and curing one or more continuous resin-coated fibers at a lower-left corner (e.g., adjacent an internal intersection of a lower support surface 34 and a left brace 36), and continue discharging and curing the same resin-coated fiber(s) during travel upward to an adjacent upper-left corner. Head 28 may then move diagonally inward toward a general center of part 32, and then double back prior to reaching the center to move toward the upper-left corner following a generally parallel trajectory. During this doubling-back maneuver, head 28 may be spaced apart a distance from its original trajectory (e.g., spaced more toward the right of part 32), such that an empty space will exist along a diagonal of part 32 and a box shape is formed at internal ends of the diagonal parallel tracks. Head 28 may then move rightward to an upper-right corner of part 32, followed by about a 90° turn downward upon reaching an internal edge of part 32. The same general pattern may be repeated at the lower-right corner of part 32 that was made at the upper-left corner, such that a mirror image across a virtual diagonal dividing line is created. Head 28 may then move leftward and stop short of its starting point, after which head 28 may turn through about 45° clockwise and travel diagonally completely across part 32 to the upper-right corner. Head 28 may then double back toward the lower-left corner along a spaced-apart parallel track, such that head 28 is near its starting point (e.g., radially outward and slightly lower than the starting point). During this doubling-back maneuver, head 28 may be spaced apart a distance from its original trajectory (e.g., spaced more toward the left of part 32), such that an empty space will exist along a diagonal of part 32. As head 28 moves towards the upper-right corner, it may deviate from its trajectory at a turn-around point and head into the corner, such that an arrow-head shape is formed at internal ends of the parallel tracks. The arrow-head shape may bond to the hardened fibers previously laid down at this corner location. The diagonally laid fiber(s) may bond to the box shape previously laid down at the center of part 32. The entire process may be repeated any number of times to add a corresponding number of material tracks to the first layer and thereby increase a cross-sectional area of the first layer. During repetition, part 32 may grow outward and the empty spaces described above as being located between the parallel tracks may be filled in. It should be noted that, during formation of any one layer, the fibers discharging from head 28 may not overlap other fibers such that all fibers are laid down within the same plane. When head 28 reaches an endpoint of a particular layer, the fiber(s) may be cut from head 28, such that head 28 may be repositioned for start of a new layer.


A second layer may be formed directly on top of the first layer, for example by rotating the pattern of the first layer through a desired angle (e.g., through about 90°). By rotating the pattern through about 90°, the fibers extending diagonally completely across part 32 in the second layer may overlap the fibers that doubled back at the center of part 32 in the first layer. This overlapping of different portions of the repeating pattern may help to increase a strength of part 32. It is contemplated that any number of fibers may be deposited at any location and oriented generally normal to the overlapping layers (e.g., fibers Fn like those shown in FIG. 5) to interlock the layers, if desired. Additionally or alternatively, discharged but uncured portions of a previous layer could be wrapped over subsequently formed layers and then cured to improve an interlock strength.


Any number of additional layers may be formed on top of the first two layers in alternating orientations and/or in orientations of incremental rotating angles (e.g., when the angle is not a multiple of 90°). This may continue until a desired thickness of part 32 is achieved. In one example, an entire fuselage 12 and/or wing 14 could be fabricated in this manner. For example, skin 18 could be simultaneously fabricated over part 32 when using the middle-out approach. In particular, an empty space may be created inside of fuselage 12 and/or wing 14 and between adjacent parts 32, by only creating outer portions of supports 34 and/or braces 36.



FIG. 9 illustrates an alternative method for fabricating skeleton 16 and/or skin 18 of wing 14. In this embodiment, instead of using the middle-out strategy of FIG. 8, different serpentine-patterned layers may be used in alternating and overlapping fashion. For example, when fabricating skeleton 16 of wing 14, head 28 (referring to FIG. 7) may be controlled to start discharging and curing one or more continuous resin-coated fibers at a right-most or trailing end of a rib cross-section, and continue discharging and curing the same resin-coated fiber(s) during arcuate travel upward and to left. Head 28 may move completely around a top support surface 34 and a leading end of the rib cross-section, and then move back to the starting point in a generally straight trajectory across a lower support surface 34 of the rib cross-section. Upon making a complete circumference of the rib cross-section, head 28 may double back and follow a reverse trajectory during a second lap around the perimeter of the rib. It should be noted that the second lap may be completed radially inside of or outside of the first lap, as desired, as long as both laps remain within the same general plane and immediately adjacent (e.g., bonded to) each other. Although Layer-1 shown in FIG. 9 includes two complete laps of material, it is contemplated that only a single lap or more than two laps may be used. During fabrication of the first and/or second laps of Layer-1, head 28 may not pass through a center of the rib cross-section, such that the center remains free of cross-pieces and bracing. That is, only a perimeter of the rib cross-section may be formed by Layer-1.


After completion of Layer-1, the fibers trailing from head 28 may be severed, and head 28 may move toward the leading end of the rib cross-section for fabrication of Layer-2. Head 28 may be controlled to start discharging and curing one or more continuous resin-coated fibers at top surface 34 of the leading end, and continue discharging and curing the same resin-coated fiber(s) during arcuate travel upward and to right (e.g., toward the trailing end). After forming top support surface 34 and reaching the trailing end of the rib cross-section, head 28 may move back toward the leading end in a generally straight trajectory along lower support surface 34 and then curve around the leading end to the starting point of the first lap of Layer-2. During this Layer-2, first lap of head 28 around the perimeter of the rib cross-section, head 28 may not pass through the center of the rib, such that the center still remains free of cross-pieces and bracing.


Head 28 may pass through the center of the rib cross-section during the second lap of Layer-2, such that cross-pieces 38 are created in free-space between opposing nodes in top and lower support surfaces 34. In particular, after returning to the starting point of the first lap, head 28 may double back and follow the same general trajectory around the curved leading end at a radial location inside of the first lap. After moving around the curved leading end, head 28 may move away from the first lap and angle upward and to the right (i.e., toward the trailing end), passing through the center of the rib cross-section and toward the starting point. In the disclosed embodiment, the angle of cross-piece 38 relative to top and/or lower support surfaces 34 may be about 25-65°. After the material discharging from head 28 engages an inner side of the first lap, head 28 may generally follow the trajectory of the first lap for a short distance, such that a segment of material is laid down adjacent (e.g., at the inside) of the first lap at top support surface 34 of the rib cross-section. In one embodiment, the segment is about ⅓ to ⅙ of the length of the rib cross-section. Thereafter, head 28 may move away from the first lap and angle downward and to the right, again passing through the center of the rib cross-section. After the material discharging from head 28 again engages an inner side of the first lap, head 28 may generally follow the trajectory of the first lap for a short distance, such that another segment of material is laid down adjacent (e.g., at the inside) of the first lap at lower support surface 34 of the rib cross-section. This serpentine pattern of passing through the rib-center and segment-creation may continue until head 28 reaches the trailing end of the rib cross-section. It should be noted that, in the embodiment of FIG. 9, cross-pieces 38 within any one the layer of the rib cross-section are only one-sided. That is, a complete “X” through the center of the rib cross-section may be created only by two different layers.


Odd layers of the rib cross-section may all be substantially identical to each other, while even layers may be identical to or iterations of each other. For example, Layers-1, 3, 5, 7, etc. may all be identical. Likewise, Layers-2 and 8; Layers-4 and 10; and Layers-6 and 12 may be identical pairs. However, Layers-2, 4, and 6 may be different iterations of each other. Specifically, the locations of cross-pieces 38 and the top and lower support segments may alternate between the even layers, such that cross-pieces 38 overlap each other and thereby form complete “Xs” and the top and lower support segments line up sequentially to form a complete perimeter around the rib cross-section. It should be noted that, while Layers-1 through 6 are shown in FIG. 9 as forming a complete set that can be repeated any number of times during formation of wing 14, any number of layers may form a set that can be repeated to form wing 14.


In some embodiments, after formation of Layers-1 through 6 (and/or after multiples of these layers), wing 14 may be complete. That is, the inner lap of each layer may form skeleton 16, while the outer layer may form skin 18. In other embodiments, however, a separate skin 18 may be laid over skeleton 16 after formation of Layers-1 through 6, if desired. In this embodiment, skin 18 may be laid by hand or by the disclosed system(s). If laid by the disclosed system(s), the second additive process described above (but using sheets of pre-fabricated material instead of individual fibers or tows) may be implemented.


INDUSTRIAL APPLICABILITY

The disclosed arrangements and designs of skeleton 16 and skin 18 may be used in connection with any type of vehicle body 10. For example, skeleton 16 and skin 18 may be used in connection with an airplane body, a drone body, a car body, a boat body, or any other type of vehicle body where light-weight, low-cost, and high-performance are important. Vehicle body 10 may be light-weight and low-cost due to the reduction in the number of fasteners required to secure skin 18 to skeleton 16 and/or to secure components of vehicle body 10 to each other. In addition, vehicle body 10 may be light-weight do to the use of composite materials used to make both of skeleton 16 and skin 18. The high-performance may be provided in the unique ways that particular fibers and resins are used and laid out within skeleton 16 and skin 18.


It will be apparent to those skilled in the art that various modifications and variations can be made to the disclosed vehicle body. Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the disclosed vehicle body. It is intended that the specification and examples be considered as exemplary only, with a true scope being indicated by the following claims and their equivalents.

Claims
  • 1. A vehicle body, comprising: an internal skeleton; anda skin fabricated in-situ over the internal skeleton,wherein: the internal skeleton and the skin together form a wing shape; andthe internal skeleton includes a plurality of continuous fibers that extend into and form a portion of the skin.
  • 2. The vehicle body of claim 1, wherein the plurality of continuous fibers includes at least one of carbon fibers and glass fibers at least partially coated in a UV-curable thermoset resin.
  • 3. The vehicle body of claim 2, wherein the plurality of continuous fibers additionally includes at least one of a metallic wire and an optical fiber at least partially coated in the UV-curable thermoset resin.
  • 4. A vehicle body, comprising: an internal skeleton; anda skin fabricated in-situ over the internal skeleton, the skin including: a matrix material; anda plurality of continuous fibers encased within the matrix material,wherein the matrix material includes multiple resins each deposited at different strategic locations along a length of the plurality of continuous fibers in the skin.
  • 5. The vehicle body of claim 4, wherein: the internal skeleton forms a wing shape; andthe multiple resins includes: a flexible resin at a trailing edge of the wing shape; anda stiffer resin used away from the trailing edge.
  • 6. The vehicle body of claim 4, wherein: the internal skeleton forms a wing shape; andthe multiple resins includes: a pyrolized resin at a leading edge of the wing shape; andan acrylated resin at locations away from the leading edge.
  • 7. The vehicle body of claim 4, wherein: the plurality of continuous fibers includes at least one of carbon fibers and glass fibers; andthe matrix material includes a UV-curable thermoset resin.
  • 8. The vehicle body of claim 7, wherein the plurality of continuous fibers additionally includes at least one of a metallic wire and an optical fiber.
  • 9. A vehicle body, comprising a skin including matrix material and plurality of continuous fibers at least partially coated with the matrix material, wherein the plurality of continuous fibers includes: a first plurality of continuous fibers arranged into a first layer that is generally parallel to an outer surface of the vehicle body;a second plurality of continuous fibers arranged into a second layer overlapping the first layer; anda third plurality of continuous fibers extending normal to the outer surface from the first layer into the second layer to interlock the first and second layers.
  • 10. The vehicle body of claim 9, wherein: the plurality of continuous fibers includes at least one of carbon fibers and glass fibers; andthe matrix material includes a UV-curable thermoset resin.
  • 11. The vehicle body of claim 10, wherein the plurality of continuous fibers additionally includes at least one of a metallic wire and an optical fiber.
  • 12. A vehicle body, comprising: an internal skeleton having a plurality of adjacent tubular structures that together form a wing shape; anda skin formed from a composite material over the internal skeleton;wherein the plurality of adjacent tubular structures are formed from the composite material forming the skin.
  • 13. The vehicle body of claim 12, wherein the plurality of adjacent tubular structures extend in a lengthwise direction of the wing shape.
  • 14. The vehicle body of claim 12, wherein at least one of the plurality of adjacent tubular structures is coated to function as at least one of a fuel tank and a fuel passage.
  • 15. The vehicle body of claim 12, wherein at least one of the plurality of adjacent tubular structures is coated to function as at least one of an electrical conduit and a ventilation duct.
  • 16. The vehicle body of claim 12, wherein at least one of the plurality of adjacent tubular structures has a polygonal cross-section.
RELATED APPLICATIONS

This application is a continuation application of U.S. States application Ser. No. 15/682,818 that was filed on Aug. 22, 2017, which is based on and claims the benefit of priority from U.S. Provisional Application No. 62/417,056 that was filed on Nov. 3, 2016, the contents of all of which are expressly incorporated herein by reference.

US Referenced Citations (227)
Number Name Date Kind
2791386 Howard May 1957 A
2934317 Warnken Apr 1960 A
2995777 Warnken Aug 1961 A
3028292 Hinds Apr 1962 A
3286305 Seckel Nov 1966 A
3779487 Ashton et al. Dec 1973 A
3809514 Nunez May 1974 A
3984271 Gilbu Oct 1976 A
3993726 Moyer Nov 1976 A
4079903 Ashton et al. Mar 1978 A
4538780 Roe Sep 1985 A
4565595 Whitener Jan 1986 A
4612241 Howard, Jr. Sep 1986 A
4643940 Shaw et al. Feb 1987 A
4671761 Adrian et al. Jun 1987 A
4822548 Hempel Apr 1989 A
4838346 Camarda et al. Jun 1989 A
4845357 Brennan Jul 1989 A
4851065 Curtz Jul 1989 A
5002712 Goldmann et al. Mar 1991 A
5037691 Medney et al. Aug 1991 A
5296335 Thomas et al. Mar 1994 A
5340433 Crump Aug 1994 A
5440193 Barrett Aug 1995 A
5746967 Hoy et al. May 1998 A
5866058 Batchelder et al. Feb 1999 A
5936861 Jang et al. Aug 1999 A
6153034 Lipsker Nov 2000 A
6314630 Munk et al. Nov 2001 B1
6459069 Rabinovich Oct 2002 B1
6501554 Hackney et al. Dec 2002 B1
6513757 Amaoka et al. Feb 2003 B1
6743504 Allen et al. Jun 2004 B1
6799081 Hale et al. Sep 2004 B1
6803003 Rigali et al. Oct 2004 B2
6889937 Simpson et al. May 2005 B2
6934600 Jang et al. Aug 2005 B2
7039485 Engelbart et al. May 2006 B2
7093638 Bonaventura Aug 2006 B2
7555404 Brennan et al. Jun 2009 B2
7681835 Simpson et al. Mar 2010 B2
7795349 Bredt et al. Sep 2010 B2
7828246 Ashton et al. Nov 2010 B2
7887734 Sanderson Feb 2011 B2
8221669 Batchelder et al. Jul 2012 B2
8322656 Pahl Dec 2012 B2
8962717 Roth et al. Feb 2015 B2
9108366 Pulnikov Aug 2015 B2
9126365 Mark et al. Sep 2015 B1
9126367 Mark et al. Sep 2015 B1
9149988 Mark et al. Oct 2015 B2
9156205 Mark et al. Oct 2015 B2
9186846 Mark et al. Nov 2015 B1
9186848 Mark et al. Nov 2015 B2
9289949 Kismarton Mar 2016 B2
9327452 Mark et al. May 2016 B2
9327453 Mark et al. May 2016 B2
9370896 Mark Jun 2016 B2
9381702 Hollander Jul 2016 B2
9457521 Johnston et al. Oct 2016 B2
9458955 Hammer et al. Oct 2016 B2
9511543 Tyler Dec 2016 B2
9527248 Hollander Dec 2016 B2
9527575 Moselage, III Dec 2016 B2
9539762 Durand et al. Jan 2017 B2
9579851 Mark et al. Feb 2017 B2
9688028 Mark et al. Jun 2017 B2
9694544 Mark et al. Jul 2017 B2
9764378 Peters et al. Sep 2017 B2
9770876 Farmer et al. Sep 2017 B2
9782926 Witzel et al. Oct 2017 B2
9815268 Mark et al. Nov 2017 B2
9981421 Marcoe et al. May 2018 B2
10076876 Mark et al. Sep 2018 B2
10086571 Hawley et al. Oct 2018 B2
10107257 Yarbrough et al. Oct 2018 B2
10155373 Nino et al. Dec 2018 B2
10232551 Tyler Mar 2019 B2
10272613 Boyd Apr 2019 B2
20020009935 Hsiao et al. Jan 2002 A1
20020062909 Jang et al. May 2002 A1
20020113331 Zhang et al. Aug 2002 A1
20020165304 Mulligan et al. Nov 2002 A1
20030044539 Oswald Mar 2003 A1
20030056870 Comb et al. Mar 2003 A1
20030146346 Chapman, Jr. Aug 2003 A1
20030160970 Basu et al. Aug 2003 A1
20030186042 Dunlap et al. Oct 2003 A1
20030236588 Jang et al. Dec 2003 A1
20050006803 Owens Jan 2005 A1
20050061422 Martin Mar 2005 A1
20050104257 Gu et al. May 2005 A1
20050109451 Hauber et al. May 2005 A1
20050230029 Vaidyanathan et al. Oct 2005 A1
20070003650 Schroeder Jan 2007 A1
20070175583 Mosallam Aug 2007 A1
20070228592 Dunn et al. Oct 2007 A1
20080176092 Owens Jul 2008 A1
20090095410 Oldani Apr 2009 A1
20100319838 Booher Dec 2010 A1
20110032301 Fienup et al. Feb 2011 A1
20110143108 Fruth et al. Jun 2011 A1
20120060468 Dushku et al. Mar 2012 A1
20120159785 Pyles et al. Jun 2012 A1
20120164907 Restuccia et al. Jun 2012 A1
20120231225 Mikulak et al. Sep 2012 A1
20120247655 Erb et al. Oct 2012 A1
20130149521 Nelson et al. Jun 2013 A1
20130164498 Langone et al. Jun 2013 A1
20130209600 Tow Aug 2013 A1
20130233471 Kappesser et al. Sep 2013 A1
20130292039 Peters et al. Nov 2013 A1
20130337256 Farmer et al. Dec 2013 A1
20130337265 Farmer Dec 2013 A1
20140034214 Boyer et al. Feb 2014 A1
20140061974 Tyler Mar 2014 A1
20140072740 Zaiser et al. Mar 2014 A1
20140159284 Leavitt Jun 2014 A1
20140232035 Bheda Aug 2014 A1
20140268604 Wicker et al. Sep 2014 A1
20140291886 Mark et al. Oct 2014 A1
20150136455 Fleming May 2015 A1
20150141234 Sander et al. May 2015 A1
20160009030 Mark et al. Jan 2016 A1
20160012935 Rothfuss Jan 2016 A1
20160031155 Tyler Feb 2016 A1
20160046082 Fuerstenberg Feb 2016 A1
20160052208 Debora et al. Feb 2016 A1
20160082641 Bogucki et al. Mar 2016 A1
20160082659 Hickman et al. Mar 2016 A1
20160107379 Mark et al. Apr 2016 A1
20160114532 Schirtzinger et al. Apr 2016 A1
20160136885 Nielsen-Cole et al. May 2016 A1
20160144565 Mark et al. May 2016 A1
20160144566 Mark et al. May 2016 A1
20160159465 Koppelman et al. Jun 2016 A1
20160192741 Mark Jul 2016 A1
20160200047 Mark et al. Jul 2016 A1
20160243762 Fleming et al. Aug 2016 A1
20160263806 Gardiner Sep 2016 A1
20160263822 Boyd Sep 2016 A1
20160263823 Espiau et al. Sep 2016 A1
20160271876 Lower Sep 2016 A1
20160297104 Guillemette et al. Oct 2016 A1
20160311165 Mark et al. Oct 2016 A1
20160325491 Sweeney et al. Nov 2016 A1
20160332369 Shah et al. Nov 2016 A1
20160339633 Stolyarov et al. Nov 2016 A1
20160346998 Mark et al. Dec 2016 A1
20160361869 Mark et al. Dec 2016 A1
20160368213 Mark Dec 2016 A1
20160368255 Witte et al. Dec 2016 A1
20170007359 Kopelman et al. Jan 2017 A1
20170007360 Kopelman et al. Jan 2017 A1
20170007361 Boronkay et al. Jan 2017 A1
20170007362 Chen et al. Jan 2017 A1
20170007363 Boronkay Jan 2017 A1
20170007365 Kopelman et al. Jan 2017 A1
20170007366 Kopelman et al. Jan 2017 A1
20170007367 Li et al. Jan 2017 A1
20170007368 Boronkay Jan 2017 A1
20170007386 Mason et al. Jan 2017 A1
20170008333 Mason et al. Jan 2017 A1
20170015059 Lewicki Jan 2017 A1
20170015060 Lewicki et al. Jan 2017 A1
20170021565 Deaville Jan 2017 A1
20170028434 Evans et al. Feb 2017 A1
20170028588 Evans et al. Feb 2017 A1
20170028617 Evans et al. Feb 2017 A1
20170028619 Evans et al. Feb 2017 A1
20170028620 Evans et al. Feb 2017 A1
20170028621 Evans et al. Feb 2017 A1
20170028623 Evans et al. Feb 2017 A1
20170028624 Evans et al. Feb 2017 A1
20170028625 Evans et al. Feb 2017 A1
20170028627 Evans et al. Feb 2017 A1
20170028628 Evans et al. Feb 2017 A1
20170028633 Evans et al. Feb 2017 A1
20170028634 Evans et al. Feb 2017 A1
20170028635 Evans et al. Feb 2017 A1
20170028636 Evans et al. Feb 2017 A1
20170028637 Evans et al. Feb 2017 A1
20170028638 Evans et al. Feb 2017 A1
20170028639 Evans et al. Feb 2017 A1
20170028644 Evans et al. Feb 2017 A1
20170030207 Kittleson Feb 2017 A1
20170036403 Ruff et al. Feb 2017 A1
20170050340 Hollander Feb 2017 A1
20170057164 Hemphill et al. Mar 2017 A1
20170057165 Waldrop et al. Mar 2017 A1
20170057167 Tooren et al. Mar 2017 A1
20170057181 Waldrop et al. Mar 2017 A1
20170064840 Espalin et al. Mar 2017 A1
20170066187 Mark et al. Mar 2017 A1
20170087768 Bheda Mar 2017 A1
20170106565 Braley et al. Apr 2017 A1
20170120519 Mark May 2017 A1
20170129170 Kim et al. May 2017 A1
20170129171 Gardner et al. May 2017 A1
20170129176 Waatti et al. May 2017 A1
20170129182 Sauti et al. May 2017 A1
20170129186 Sauti et al. May 2017 A1
20170144375 Waldrop et al. May 2017 A1
20170151728 Kunc et al. Jun 2017 A1
20170157828 Mandel et al. Jun 2017 A1
20170157831 Mandel et al. Jun 2017 A1
20170157844 Mandel et al. Jun 2017 A1
20170157851 Nardiello et al. Jun 2017 A1
20170165908 Pattinson et al. Jun 2017 A1
20170173868 Mark Jun 2017 A1
20170182712 Scribner et al. Jun 2017 A1
20170210074 Ueda et al. Jul 2017 A1
20170217088 Boyd et al. Aug 2017 A1
20170232674 Mark Aug 2017 A1
20170259502 Chapiro et al. Sep 2017 A1
20170259507 Hocker Sep 2017 A1
20170266876 Hocker Sep 2017 A1
20170274585 Armijo et al. Sep 2017 A1
20170284876 Moorlag et al. Oct 2017 A1
20180117841 Tyler May 2018 A1
20180207850 Stockett et al. Jul 2018 A1
20180229430 Tyler et al. Aug 2018 A1
20190009472 Mark Jan 2019 A1
20190202117 Alfson et al. Jul 2019 A1
20190202118 Alfson et al. Jul 2019 A1
20190202130 Alfson et al. Jul 2019 A1
20190202131 Alfson et al. Jul 2019 A1
Foreign Referenced Citations (29)
Number Date Country
4102257 Jul 1992 DE
2589481 Jan 2016 EP
3219474 Sep 2017 EP
100995983 Nov 2010 KR
101172859 Aug 2012 KR
2008147754 Dec 2008 WO
2013017284 Feb 2013 WO
2016088042 Jun 2016 WO
2016088048 Jun 2016 WO
2016110444 Jul 2016 WO
2016159259 Oct 2016 WO
2016196382 Dec 2016 WO
2017006178 Jan 2017 WO
2017006324 Jan 2017 WO
2017051202 Mar 2017 WO
2017081253 May 2017 WO
2017085649 May 2017 WO
2017087663 May 2017 WO
2017108758 Jun 2017 WO
2017122941 Jul 2017 WO
2017122942 Jul 2017 WO
2017122943 Jul 2017 WO
2017123726 Jul 2017 WO
2017124085 Jul 2017 WO
2017126476 Jul 2017 WO
2017126477 Jul 2017 WO
2017137851 Aug 2017 WO
2017142867 Aug 2017 WO
2017150186 Sep 2017 WO
Non-Patent Literature Citations (13)
Entry
A. Di. Pietro & Paul Compston, Resin Hardness and Interlaminar Shear Strength of a Glass-Fibre/Vinylester Composite Cured with High Intensity Ultraviolet (UV) Light, Journal of Materials Science, vol. 44, pp. 4188-4190 (Apr. 2009).
A. Endruweit, M. S. Johnson, & A. C. Long, Curing of Composite Components by Ultraviolet Radiation: A Review, Polymer Composites, pp. 119-128 (Apr. 2006).
C. Fragassa, & G. Minak, Standard Characterization for Mechanical Properties of Photopolymer Resins for Rapid Prototyping, 1st Symposium on Multidisciplinary Studies of Design in Mechanical Engineering, Bertinoro, Italy (Jun. 25-28, 2008).
Hyouk Ryeol Choi and Se-gon Roh, In-pipe Robot with Active Steering Capability for Moving Inside of Pipelines, Bioinspiration and Robotics: Walking and Climbing Robots, Sep. 2007, p. 544, I-Tech, Vienna, Austria.
International Search Report dated Mar. 26, 2018 for PCT/US2017/059778 to CC3D LLC Filed Feb. 11, 2017.
Kenneth C. Kennedy II & Robert P. Kusy, UV-Cured Pultrusion Processing of Glass-Reinforced Polymer Composites, Journal of Vinyl and Additive Technology, vol. 1, Issue 3, pp. 182-186 (Sep. 1995).
M. Martin-Gallego et al., Epoxy-Graphene UV-Cured Nanocomposites, Polymer, vol. 52, Issue 21, pp. 4664-4669 (Sep. 2011).
P. Compston, J. Schiemer, & A. Cvetanovska, Mechanical Properties and Styrene Emission Levels of a UV-Cured Glass-Fibre/Vinylester Composite, Composite Structures, vol. 86, pp. 22-26 (Mar. 2008).
S Kumar & J.-P. Kruth, Composites by Rapid Prototyping Technology, Materials and Design, (Feb. 2009).
S. L. Fan, F. Y. C. Boey, & M. J. M. Abadie, UV Curing of a Liquid Based Bismaleimide-Containing Polymer System, eXPRESS Polymer Letters, vol. 1, No. 6, pp. 397-405 (2007).
T. M. Llewelly-Jones, Bruce W. Drinkwater, and Richard S. Trask; 3D Printed Components With Ultrasonically Arranged Microscale Structure, Smart Materials and Structures, 2016, pp. 1-6, vol. 25, IOP Publishing Ltd., UK.
Vincent J. Lopata et al., Electron-Beam-Curable Epoxy Resins for the Manufacture of High-Performance Composites, Radiation Physics and Chemistry, vol. 56, pp. 405-415 (1999).
Yugang Duan et al., Effects of Compaction and UV Exposure on Performance of Acrylate/Glass-Fiber Composites Cured Layer by Layer, Journal of Applied Polymer Science, vol. 123, Issue 6, pp. 3799-3805 (May 15, 2012).
Related Publications (1)
Number Date Country
20200369360 A1 Nov 2020 US
Provisional Applications (1)
Number Date Country
62417056 Nov 2016 US
Divisions (1)
Number Date Country
Parent 15682818 Aug 2017 US
Child 16947661 US