The present disclosure relates generally to a vehicle body and, more particularly, to a vehicle body made from a composite material.
A vehicle body (e.g., an airplane body, a car body, or a boat body) generally includes an internal skeleton that gives shape to the vehicle, and a skin that overlays the skeleton and provides a smooth outer surface. Modern vehicle bodies are fabricated from a combination of different materials, including composites. For example, the skeleton is typically made of wood, aluminum, or stainless steel, while the skin is typically made of a fiber (e.g., a carbon fiber or fiberglass) embedded within a resin matrix.
Pultrusion is a common way to manufacture straight skeletal parts of a vehicle body (e.g., beams, longerons, etc.). During pultrusion manufacturing, individual fiber strands, braids of strands, and/or woven fabrics are pulled from corresponding spools through a resin bath and through a stationary die. The resin is then allowed to cure and harden. Due to the pulling of the fibers prior to curing, some of the fibers may retain a level of tensile stress after curing is complete. This tensile stress can increase a strength of the skeletal part in the direction in which the fibers were pulled.
A vacuum-assisted resin transfer molding (VARTM) process is commonly used to fabricate the skin of the vehicle body, after the internal skeleton has already been formed. In a VARTM process, sheets of fibrous material are manually pulled over the internal skeleton and then tacked in place. The tacked material is then manually coated with a liquid matrix (e.g., a thermoset resin or a heated thermoplastic), covered with a vacuum bag to facilitate impregnation of the liquid matrix, and allowed to cure and harden.
Although pultrusion manufacturing and VARTM can be an acceptable ways to produce vehicle body parts in some situations, they can also be problematic. In particular, the VARTM-produced skin is often attached to the pultruded skeletal parts and/or reinforced via metallic fasteners (e.g., screws, rivets, and clips). The use of metallic fasteners can drive skeletal design and increase a weight and cost of the vehicle body. In addition, the various vehicle body parts may need to be joined to each other via specially designed hardware, which can also be heavy and costly. Further, electronics (e.g., sensors, heaters, electrical leads, etc.) may need to be added to the vehicle bodies after manufacture, which can further increase the weight, cost, and unreliability. Finally, conventional pultrusion and VARTM manufacturing processes may provide little flexibility in the design and/or use of the vehicle body.
The disclosed composite vehicle body is directed to overcoming one or more of the problems set forth above and/or other problems of the prior art.
In one aspect, the present disclosure is directed to a vehicle body. The vehicle body may have an internal skeleton forming a wing shape and a fuselage shape, and a skin fabricated in-situ over the internal skeleton. The skin may include a matrix material, and a plurality of continuous fibers at least partially coated with the matrix material. The plurality of continuous fibers may extend from the wing shape over the fuselage shape.
In another aspect, the present disclosure is directed to another vehicle body. This vehicle body may include an internal skeleton having at least one of ribs, spars, trusses, stringers, longerons, and bulkheads that together make a fuselage shape and a wing shape. The fuselage shape and the wing shape may be made from a matrix material and a plurality of continuous fibers at least partially coated with the matrix material. The vehicle body may also include a skin fabricated in-situ over the internal skeleton. The plurality of continuous fibers may extend from the internal skeleton into the into the skin.
In another aspect, the present disclosure is directed to another vehicle body. This vehicle body may include an internal skeleton having a matrix material and plurality of continuous fibers at least partially coated with the matrix material. The vehicle body may also have a skin fabricated in-situ over the internal skeleton. The plurality of continuous fibers may include a first plurality of continuous fibers arranged in generally parallel layers, and a second plurality of continuous fibers that extend normal to the generally parallel layers to interlock the generally parallel layers
As shown in
The first additive manufacturing process may be a pultrusion and/or extrusion process that creates hollow tubular structures 20 from a composite material (e.g., a material having a matrix M and at least one continuous fiber F). In particular, one or more heads 22 may be coupled to a support 24 (e.g., to a robotic arm) that is capable of moving head(s) 22 in multiple directions during discharge of structures 20, such that resulting longitudinal axes 26 of structures 20 are three-dimensional. Such a head is disclosed, for example, in U.S. patent application Ser. Nos. 13/975,300 and 15/130,207 and in PCT Application Number 2016042909, all of which are incorporated herein in their entireties by reference.
Head(s) 22 may be configured to receive or otherwise contain the matrix material M. The matrix material M may include any type of liquid resin (e.g., a zero volatile organic compound resin) that is curable. Exemplary resins include epoxy resins, polyester resins, cationic epoxies, acrylated epoxies, urethanes, esters, thermoplastics, photopolymers, polyepoxides, thermoset acrylates, thermosets, bismaleimides, silicon, and more. In one embodiment, the pressure of the matrix material M inside of head(s) 22 may be generated by an external device (e.g., an extruder or another type of pump) that is fluidly connected to head(s) 22 via corresponding conduits (not shown). In another embodiment, however, the pressure may be generated completely inside of head(s) 22 by a similar type of device and/or simply be the result of gravity acting on the matrix material M. In some instances, the matrix material M inside head(s) 22 may need to be kept cool and/or dark in order to inhibit premature curing; while in other instances, the matrix material M may need to be kept warm for the same reason. In either situation, head(s) 22 may be specially configured (e.g., insulated, chilled, and/or warmed) to provide for these needs.
The matrix material M stored inside head(s) 22 may be used to coat any number of continuous fibers F and, together with the fibers F, make up walls of composite structures 20. The fibers F may include single strands, a tow or roving of several strands, or a weave of many strands. The strands may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, metallic wires, SiC Ceramic fibers, basalt fibers, etc. The fibers F may be coated with the matrix material M while the fibers F are inside head(s) 22, while the fibers F are being passed to head(s) 22, and/or while the fibers F are discharging from head(s) 22, as desired. In some embodiments, a filler material (e.g., chopped fibers) may be mixed with the matrix material M before and/or after the matrix material M coats the fibers F. The matrix material, the dry fibers, fibers already coated with the matrix material M, and/or the filler may be transported into head(s) 22 in any manner apparent to one skilled in the art. The matrix-coated fibers F may then pass over a centralized diverter (not shown) located at a mouth of head(s) 22, where the resin is caused to cure (e.g., from the inside-out, from the outside-in, or both) by way of one or more cure enhancers (e.g., UV lights and/or ultrasonic emitters) 27.
In the example of
In some embodiments, a fill material (e.g., an insulator, a conductor, an optic, a surface finish, etc.) could be deposited inside and/or outside of structures 20 while structures 20 are being formed. For example, a hollow shaft (not shown) could extend through a center of and/or over any of the associated head(s) 22. A supply of material (e.g., a liquid supply, a foam supply, a solid supply, a gas supply, etc.) could then be connected with an end of the hollow shaft, and the material forced through the hollow shaft and onto particular surfaces (i.e., interior and/or exterior surfaces) of structure 20. It is contemplated that the same cure enhancer(s) 27 used to cure structure 20 could also be used to cure the fill material, if desired, or that additional dedicated cure enhancer(s) (not shown) could be used for this purpose. The fill materials could allow one or more of structures 20 to function as fuel tanks, fuel passages, electrical conduits, ventilation ducts, etc.
The second additive manufacturing process used to fabricate the exemplary wing 14 of
Head 28 may be similar to head 22 and configured to receive or otherwise contain a matrix material M (e.g., the same matrix material M contained within head 22). The matrix material M stored inside head(s) 28 may be used to coat any number of separate fibers F, allowing the fibers F to make up centralized reinforcements of the discharging tracks, ribbons, and/or sheets. The fibers F may include single strands, a tow or roving of several strands, or a weave of multiple strands. The strands may include, for example, carbon fibers, vegetable fibers, wood fibers, mineral fibers, glass fibers, metallic wires, etc. The fibers F may be coated with the matrix material M while the fibers F are inside head(s) 28, while the fibers F are being passed to head(s) 28, and/or while the fibers F are discharging from head(s) 28, as desired. The matrix material, the dry fibers, and/or fibers already coated with the matrix material may be transported into head(s) 28 in any manner apparent to one skilled in the art. The matrix-coated fibers F may then pass through one or more circular orifices, rectangular orifices, triangular orifices, or orifices of another curved or polygonal shape, where the fibers F are pressed together and the resin is caused to cure by way of one or more cure enhancers 27.
In another exemplary embodiment shown in
As described above, the first and second additive manufacturing processes can be extrusion or pultrusion processes. For example, extrusion may occur when the liquid resin matrix M and the associated continuous fibers F are pushed from head(s) 22 and/or head(s) 28 during the movement of supports 24 and/or 30. Pultrusion may occur after a length of resin-coated fibers is connected to an anchor (not shown) and cured, followed by movement of head(s) 22 and/or heads(28) away from the anchor. The movement of head(s) 22 and/or head(s) 28 away from the anchor causes the fibers F to be pulled from the respective head(s) along with the coating of the matrix material M.
In some embodiments, pultrusion may be selectively implemented to generate tension in the fibers F that make up skeleton 16 and/or skin 18 and that remains after curing. In particular, as the fibers F are being pulled from the respective head(s), the fibers F may be caused to stretch. This stretching can create tension within the fibers F. As long as the matrix M surrounding the fibers F cures and hardens while the fibers F are stretched, at least some of this tension remains in the fibers F and functions to increase a strength of the resulting composite structure.
Structures fabricated via conventional pultrusion methods may have increased strength in only a single direction (e.g., in the one direction in which fibers were pulled through the corresponding die prior to manual resin impregnation and curing). However, in the disclosed embodiment, the increased strength in the skeleton 16 and/or skin 18 of body 10 (e.g., within wing 14) caused by residual tension within the corresponding fibers F may be realized in the axial direction of each the fibers F. And because each fiber F could be pulled in a different direction when being discharged by head(s) 22 and/or 28, the tension-related strength increase may be realized in multiple (e.g., innumerable) different directions.
Structures fabricated via conventional pultrusion methods may have strength increased to only a single level (e.g., to a level proportionate to an amount in which the fibrous cloth was stretched by the pulling machine prior to manual resin impregnation and curing). However, in the disclosed embodiment, because the matrix M surrounding each fiber F may be cured and harden immediately upon discharge, the force pulling on the fiber F may be continuously varied along the length of the fiber F, such that different segments of the same fiber F are stretched by different amounts. Accordingly, the tensile stress induced within each of the different segments of each fiber F may also be different, resulting in a variable strength within the different segments of skeleton 16 and/or skin 18 of body 10. This may be beneficial in variably loaded areas of body 10 (e.g., at the intersection of wing 14 and fuselage 12, within a center of wing 14, at the leading edge of wing 14, etc.).
In one exemplary embodiment shown in
Structures fabricated via conventional pultrusion and/or extrusion methods may be limited in the orientation of the associated fibers. That is, the fibers may be generally overlapping and lie in parallel layers. However, in the embodiment illustrated in
As described above and shown in
In the exemplary embodiment shown in
Part 32 may be created following a unique tool path that allows for use of continuous fibers and provides for high-strength in a low-weight configuration. In particular, part 32 may be fabricated using a middle-out strategy.
For example, in a first layer, head 28 may be controlled to start discharging and curing one or more continuous resin-coated fibers at a lower-left corner (e.g., adjacent an internal intersection of a lower support surface 34 and a left brace 36), and continue discharging and curing the same resin-coated fiber(s) during travel upward to an adjacent upper-left corner. Head 28 may then move diagonally inward toward a general center of part 32, and then double back prior to reaching the center to move toward the upper-left corner following a generally parallel trajectory. During this doubling-back maneuver, head 28 may be spaced apart a distance from its original trajectory (e.g., spaced more toward the right of part 32), such that an empty space will exist along a diagonal of part 32 and a box shape is formed at internal ends of the diagonal parallel tracks. Head 28 may then move rightward to an upper-right corner of part 32, followed by about a 90° turn downward upon reaching an internal edge of part 32. The same general pattern may be repeated at the lower-right corner of part 32 that was made at the upper-left corner, such that a mirror image across a virtual diagonal dividing line is created. Head 28 may then move leftward and stop short of its starting point, after which head 28 may turn through about 45° clockwise and travel diagonally completely across part 32 to the upper-right corner. Head 28 may then double back toward the lower-left corner along a spaced-apart parallel track, such that head 28 is near its starting point (e.g., radially outward and slightly lower than the starting point). During this doubling-back maneuver, head 28 may be spaced apart a distance from its original trajectory (e.g., spaced more toward the left of part 32), such that an empty space will exist along a diagonal of part 32. As head 28 moves towards the upper-right corner, it may deviate from its trajectory at a turn-around point and head into the corner, such that an arrow-head shape is formed at internal ends of the parallel tracks. The arrow-head shape may bond to the hardened fibers laid down previously at this corner location. The diagonally laid fiber(s) may bond to the box shape previously laid down at the center of part 32. The entire process may be repeated any number of times to add a corresponding number of material tracks to the first layer and thereby increase a cross-sectional area of the first layer. During repetition, part 32 may grow outward and the empty spaces described above as being located between the parallel tracks may be filled in. It should be noted that, during formation of any one layer, the fibers discharging from head 28 may not overlap other fibers such that all fibers are laid down within the same plane. When head 28 reaches an endpoint of a particular layer, the fiber(s) may be cut from head 28, such that head 28 may be repositioned for start of a new layer.
A second layer may be formed directly on top of the first layer, for example by rotating the pattern of the first layer through a desired angle (e.g., through about 90°). By rotating the pattern through about 90°, the fibers extending diagonally completely across part 32 in the second layer may overlap the fibers that doubled back at the center of part 32 in the first layer. This overlapping of different portions of the repeating pattern may help to increase a strength of part 32. It is contemplated that any number of fibers may be deposited at any location and oriented generally normal to the overlapping layers (e.g., fibers Fn like those shown in
Any number of additional layers may be formed on top of the first two layers in alternating orientations and/or in orientations of incremental rotating angles (e.g., when the angle is not a multiple of 90°). This may continue until a desired thickness of part 32 is achieved. In one example, an entire fuselage 12 and/or wing 14 could be fabricated in this manner. For example, skin 18 could be simultaneously fabricated over part 32 when using the middle-out approach. In particular, an empty space may be created inside of fuselage 12 and/or wing 14 and between adjacent parts 32, by only creating outer portions of supports 34 and/or braces 36.
The disclosed arrangements and designs of skeleton 16 and skin 18 may be used in connection with any type of vehicle body 10. For example, skeleton 16 and skin 18 may be used in connection with an airplane body, a drone body, a car body, a boat body, or any other type of vehicle body where light-weight, low-cost, and high-performance are important. Vehicle body 10 may be light-weight and low-cost due to the reduction in the number of fasteners required to secure skin 18 to skeleton 16 and/or to secure components of vehicle body 10 to each other. In addition, vehicle body 10 may be light-weight do to the use of composite materials used to make both of skeleton 16 and skin 18. The high-performance may be provided in the unique ways that particular fibers and resins are used and laid out within skeleton 16 and skin 18.
It will be apparent to those skilled in the art that various modifications and variations can be made to the disclosed vehicle body. Other embodiments will be apparent to those skilled in the art from consideration of the specification and practice of the disclosed vehicle body. It is intended that the specification and examples be considered as exemplary only, with a true scope being indicated by the following claims and their equivalents.
This application is based on and claims the benefit of priority from U.S. Provisional Application No. 62/417,056 that was filed on Nov. 3, 2016, the contents of which are expressly incorporated herein by reference.
Number | Name | Date | Kind |
---|---|---|---|
3286305 | Seckel | Nov 1966 | A |
3809514 | Nunez | May 1974 | A |
3984271 | Gilbu | Oct 1976 | A |
3993726 | Moyer | Nov 1976 | A |
4643940 | Shaw et al. | Feb 1987 | A |
4671761 | Adrian et al. | Jun 1987 | A |
4822548 | Hempel | Apr 1989 | A |
4838346 | Camarda | Jun 1989 | A |
4851065 | Curtz | Jul 1989 | A |
5002712 | Goldmann et al. | Mar 1991 | A |
5037691 | Medney et al. | Aug 1991 | A |
5296335 | Thomas et al. | Mar 1994 | A |
5340433 | Crump | Aug 1994 | A |
5440193 | Barrett | Aug 1995 | A |
5746967 | Hoy et al. | May 1998 | A |
5866058 | Batchelder et al. | Feb 1999 | A |
5936861 | Jang et al. | Aug 1999 | A |
6153034 | Lipsker | Nov 2000 | A |
6459069 | Rabinovich | Oct 2002 | B1 |
6501554 | Hackney et al. | Dec 2002 | B1 |
6799081 | Hale et al. | Sep 2004 | B1 |
6803003 | Rigali et al. | Oct 2004 | B2 |
6934600 | Jang et al. | Aug 2005 | B2 |
7039485 | Engelbart et al. | May 2006 | B2 |
7093638 | Bonaventura | Aug 2006 | B2 |
7555404 | Brennan et al. | Jun 2009 | B2 |
7795349 | Bredt et al. | Sep 2010 | B2 |
8221669 | Batchelder et al. | Jul 2012 | B2 |
8322656 | Pahl | Dec 2012 | B2 |
8962717 | Roth et al. | Feb 2015 | B2 |
9126365 | Mark et al. | Sep 2015 | B1 |
9126367 | Mark et al. | Sep 2015 | B1 |
9149988 | Mark et al. | Oct 2015 | B2 |
9156205 | Mark et al. | Oct 2015 | B2 |
9186846 | Mark et al. | Nov 2015 | B1 |
9186848 | Mark et al. | Nov 2015 | B2 |
9327452 | Mark et al. | May 2016 | B2 |
9327453 | Mark et al. | May 2016 | B2 |
9370896 | Mark | Jun 2016 | B2 |
9381702 | Hollander | Jul 2016 | B2 |
9457521 | Johnston et al. | Oct 2016 | B2 |
9458955 | Hammer et al. | Oct 2016 | B2 |
9527248 | Hollander | Dec 2016 | B2 |
9539762 | Durand et al. | Jan 2017 | B2 |
9579851 | Mark et al. | Feb 2017 | B2 |
9688028 | Mark et al. | Jun 2017 | B2 |
9694544 | Mark et al. | Jul 2017 | B2 |
9764378 | Peters et al. | Sep 2017 | B2 |
9770876 | Farmer et al. | Sep 2017 | B2 |
9782926 | Witzel et al. | Oct 2017 | B2 |
9981421 | Marcoe | May 2018 | B2 |
10076876 | Mark | Sep 2018 | B2 |
20020009935 | Hsiao et al. | Jan 2002 | A1 |
20020062909 | Jang et al. | May 2002 | A1 |
20020113331 | Zhang et al. | Aug 2002 | A1 |
20020165304 | Mulligan et al. | Nov 2002 | A1 |
20030044539 | Oswald | Mar 2003 | A1 |
20030056870 | Comb et al. | Mar 2003 | A1 |
20030160970 | Basu et al. | Aug 2003 | A1 |
20030186042 | Dunlap et al. | Oct 2003 | A1 |
20030236588 | Jang et al. | Dec 2003 | A1 |
20050006803 | Owens | Jan 2005 | A1 |
20050061422 | Martin | Mar 2005 | A1 |
20050104257 | Gu et al. | May 2005 | A1 |
20050109451 | Hauber et al. | May 2005 | A1 |
20050230029 | Vaidyanathan et al. | Oct 2005 | A1 |
20070003650 | Schroeder | Jan 2007 | A1 |
20070228592 | Dunn et al. | Oct 2007 | A1 |
20080176092 | Owens | Jul 2008 | A1 |
20090095410 | Oldani | Apr 2009 | A1 |
20100319838 | Booher | Dec 2010 | A1 |
20110032301 | Fienup et al. | Feb 2011 | A1 |
20110143108 | Fruth et al. | Jun 2011 | A1 |
20120060468 | Dushku et al. | Mar 2012 | A1 |
20120159785 | Pyles et al. | Jun 2012 | A1 |
20120164907 | Restuccia et al. | Jun 2012 | A1 |
20120231225 | Mikulak et al. | Sep 2012 | A1 |
20120247655 | Erb et al. | Oct 2012 | A1 |
20130149521 | Nelson et al. | Jun 2013 | A1 |
20130164498 | Langone et al. | Jun 2013 | A1 |
20130209600 | Tow | Aug 2013 | A1 |
20130233471 | Kappesser et al. | Sep 2013 | A1 |
20130292039 | Peters et al. | Nov 2013 | A1 |
20130337256 | Farmer et al. | Dec 2013 | A1 |
20130337265 | Farmer | Dec 2013 | A1 |
20140034214 | Boyer et al. | Feb 2014 | A1 |
20140061974 | Tyler | Mar 2014 | A1 |
20140159284 | Leavitt | Jun 2014 | A1 |
20140232035 | Bheda | Aug 2014 | A1 |
20140268604 | Wicker et al. | Sep 2014 | A1 |
20140291886 | Mark et al. | Oct 2014 | A1 |
20150136455 | Fleming | May 2015 | A1 |
20160012935 | Rothfuss | Jan 2016 | A1 |
20160031155 | Tyler | Feb 2016 | A1 |
20160046082 | Fuerstenberg | Feb 2016 | A1 |
20160052208 | Debora et al. | Feb 2016 | A1 |
20160082641 | Bogucki et al. | Mar 2016 | A1 |
20160082659 | Hickman et al. | Mar 2016 | A1 |
20160107379 | Mark et al. | Apr 2016 | A1 |
20160114532 | Schirtzinger et al. | Apr 2016 | A1 |
20160136885 | Nielsen-Cole et al. | May 2016 | A1 |
20160144565 | Mark et al. | May 2016 | A1 |
20160144566 | Mark et al. | May 2016 | A1 |
20160192741 | Mark | Jul 2016 | A1 |
20160200047 | Mark et al. | Jul 2016 | A1 |
20160243762 | Fleming et al. | Aug 2016 | A1 |
20160263806 | Gardiner | Sep 2016 | A1 |
20160263822 | Boyd | Sep 2016 | A1 |
20160263823 | Espiau et al. | Sep 2016 | A1 |
20160271876 | Lower | Sep 2016 | A1 |
20160297104 | Guillemette et al. | Oct 2016 | A1 |
20160311165 | Mark et al. | Oct 2016 | A1 |
20160325491 | Sweeney et al. | Nov 2016 | A1 |
20160332369 | Shah et al. | Nov 2016 | A1 |
20160339633 | Stolyarov et al. | Nov 2016 | A1 |
20160346998 | Mark et al. | Dec 2016 | A1 |
20160361869 | Mark et al. | Dec 2016 | A1 |
20160368213 | Mark | Dec 2016 | A1 |
20160368255 | Witte et al. | Dec 2016 | A1 |
20170007359 | Kopelman et al. | Jan 2017 | A1 |
20170007360 | Kopelman et al. | Jan 2017 | A1 |
20170007361 | Boronkay et al. | Jan 2017 | A1 |
20170007362 | Chen et al. | Jan 2017 | A1 |
20170007363 | Boronkay | Jan 2017 | A1 |
20170007365 | Kopelman et al. | Jan 2017 | A1 |
20170007366 | Kopelman et al. | Jan 2017 | A1 |
20170007367 | Li et al. | Jan 2017 | A1 |
20170007368 | Boronkay | Jan 2017 | A1 |
20170007386 | Mason et al. | Jan 2017 | A1 |
20170008333 | Mason et al. | Jan 2017 | A1 |
20170015059 | Lewicki | Jan 2017 | A1 |
20170015060 | Lewicki et al. | Jan 2017 | A1 |
20170021565 | Deaville | Jan 2017 | A1 |
20170028434 | Evans et al. | Feb 2017 | A1 |
20170028588 | Evans et al. | Feb 2017 | A1 |
20170028617 | Evans et al. | Feb 2017 | A1 |
20170028619 | Evans et al. | Feb 2017 | A1 |
20170028620 | Evans et al. | Feb 2017 | A1 |
20170028621 | Evans et al. | Feb 2017 | A1 |
20170028623 | Evans et al. | Feb 2017 | A1 |
20170028624 | Evans et al. | Feb 2017 | A1 |
20170028625 | Evans et al. | Feb 2017 | A1 |
20170028627 | Evans et al. | Feb 2017 | A1 |
20170028628 | Evans et al. | Feb 2017 | A1 |
20170028633 | Evans et al. | Feb 2017 | A1 |
20170028634 | Evans et al. | Feb 2017 | A1 |
20170028635 | Evans et al. | Feb 2017 | A1 |
20170028636 | Evans et al. | Feb 2017 | A1 |
20170028637 | Evans et al. | Feb 2017 | A1 |
20170028638 | Evans et al. | Feb 2017 | A1 |
20170028639 | Evans et al. | Feb 2017 | A1 |
20170028644 | Evans et al. | Feb 2017 | A1 |
20170030207 | Kittleson | Feb 2017 | A1 |
20170036403 | Ruff et al. | Feb 2017 | A1 |
20170050340 | Hollander | Feb 2017 | A1 |
20170057164 | Hemphill et al. | Mar 2017 | A1 |
20170057165 | Waldrop et al. | Mar 2017 | A1 |
20170057167 | Tooren et al. | Mar 2017 | A1 |
20170057181 | Waldrop et al. | Mar 2017 | A1 |
20170064840 | Espalin et al. | Mar 2017 | A1 |
20170066187 | Mark et al. | Mar 2017 | A1 |
20170087768 | Bheda | Mar 2017 | A1 |
20170106565 | Braley et al. | Apr 2017 | A1 |
20170120519 | Mark | May 2017 | A1 |
20170129170 | Kim et al. | May 2017 | A1 |
20170129171 | Gardner et al. | May 2017 | A1 |
20170129176 | Waatti et al. | May 2017 | A1 |
20170129182 | Sauti et al. | May 2017 | A1 |
20170129186 | Sauti et al. | May 2017 | A1 |
20170144375 | Waldrop et al. | May 2017 | A1 |
20170151728 | Kunc et al. | Jun 2017 | A1 |
20170157828 | Mandel et al. | Jun 2017 | A1 |
20170157831 | Mandel et al. | Jun 2017 | A1 |
20170157844 | Mandel et al. | Jun 2017 | A1 |
20170157851 | Nardiello et al. | Jun 2017 | A1 |
20170165908 | Pattinson et al. | Jun 2017 | A1 |
20170173868 | Mark | Jun 2017 | A1 |
20170182712 | Scribner et al. | Jun 2017 | A1 |
20170210074 | Ueda et al. | Jul 2017 | A1 |
20170217088 | Boyd et al. | Aug 2017 | A1 |
20170232674 | Mark | Aug 2017 | A1 |
20170259502 | Chapiro et al. | Sep 2017 | A1 |
20170259507 | Hocker | Sep 2017 | A1 |
20170266876 | Hocker | Sep 2017 | A1 |
20170274585 | Armijo et al. | Sep 2017 | A1 |
20170284876 | Moorlag et al. | Oct 2017 | A1 |
Number | Date | Country |
---|---|---|
4102257 | Jul 1992 | DE |
2589481 | Jan 2016 | EP |
3219474 | Sep 2017 | EP |
100995983 | Nov 2010 | KR |
101172859 | Aug 2012 | KR |
2008147754 | Dec 2008 | WO |
2013017284 | Feb 2013 | WO |
2016088042 | Jun 2016 | WO |
2016088048 | Jun 2016 | WO |
2016110444 | Jul 2016 | WO |
2016159259 | Oct 2016 | WO |
2016196382 | Dec 2016 | WO |
2017006178 | Jan 2017 | WO |
2017006324 | Jan 2017 | WO |
2017051202 | Mar 2017 | WO |
2017081253 | May 2017 | WO |
2017085649 | May 2017 | WO |
2017087663 | May 2017 | WO |
2017108758 | Jun 2017 | WO |
2017122941 | Jul 2017 | WO |
2017122942 | Jul 2017 | WO |
2017122943 | Jul 2017 | WO |
2017123726 | Jul 2017 | WO |
2017124085 | Jul 2017 | WO |
2017126476 | Jul 2017 | WO |
2017126477 | Jul 2017 | WO |
2017137851 | Aug 2017 | WO |
2017142867 | Aug 2017 | WO |
2017150186 | Sep 2017 | WO |
Entry |
---|
A. Di. Pietro & Paul Compston, Resin Hardness and Interlaminar Shear Strength of a Glass-Fibre/Vinylester Composite Cured with High Intensity Ultraviolet (UV) Light, Journal of Materials Science, vol. 44, pp. 4188-4190 (Apr. 2009). |
A. Endruweit, M. S. Johnson, & A. C. Long, Curing of Composite Components by Ultraviolet Radiation: A Review, Polymer Composites, pp. 119-128 (Apr. 2006). |
C. Fragassa, & G. Minak, Standard Characterization for Mechanical Properties of Photopolymer Resins for Rapid Prototyping, 1st Symposium on Multidisciplinary Studies of Design in Mechanical Engineering, Bertinoro, Italy (Jun. 25-28, 2008). |
Hyouk Ryeol Choi and Se-gon Roh, In-pipe Robot with Active Steering Capability for Moving Inside of Pipelines, Bioinspiration and Robotics: Walking and Climbing Robots, Sep. 2007, p. 544, I-Tech, Vienna, Austria. |
Kenneth C. Kennedy II & Robert P. Kusy, UV-Cured Pultrusion Processing of Glass-Reinforced Polymer Composites, Journal of Vinyl and Additive Technology, vol. 1, Issue 3, pp. 182-186 (Sep. 1995). |
M. Martin-Gallego et al., Epoxy-Graphene UV-Cured Nanocomposites, Polymer, vol. 52, Issue 21, pp. 4664-4669 (Sep. 2011). |
P. Compston, J. Schiemer, & A. Cvetanovska, Mechanical Properties and Styrene Emission Levels of a UV-Cured Glass-Fibre/Vinylester Composite, Composite Structures, vol. 86, pp. 22-26 (Mar. 2008). |
S Kumar & J.-P. Kruth, Composites by Rapid Prototyping Technology, Materials and Design, (Feb. 2009). |
S. L. Fan, F. Y. C. Boey, & M. J. M. Abadie, UV Curing of a Liquid Based Bismaleimide-Containing Polymer System, eXPRESS Polymer Letters, vol. 1, No. 6, pp. 397-405 (2007). |
T. M. Llewelly-Jones, Bruce W. Drinkwater, and Richard S. Trask; 3D Printed Components With Ultrasonically Arranged Microscale Structure, Smart Materials and Structures, 2016, pp. 1-6, vol. 25, IOP Publishing Ltd., UK. |
Vincent J. Lopata et al., Electron-Beam-Curable Epoxy Resins for the Manufacture of High-Performance Composites, Radiation Physics and Chemistry, vol. 56, pp. 405-415 (1999). |
Yugang Duan et al., Effects of Compaction and UV Exposure on Performance of Acrylate/Glass-Fiber Composites Cured Layer by Layer, Journal of Applied Polymer Science, vol. 123, Issue 6, pp. 3799-3805 (May 15, 2012). |
International Search Report dated Mar. 26, 2018 for PCT/US2017/059778 to CC3D LLC Filed Feb. 11, 2017. |
Number | Date | Country | |
---|---|---|---|
20180118326 A1 | May 2018 | US |
Number | Date | Country | |
---|---|---|---|
62417056 | Nov 2016 | US |