Patent Grant
9371610
This application is the National Phase Application of PCT International Application No. PCT/FR2013/052639, filed Nov. 6, 2013, which is incorporated herein by reference.
An object of the invention is a composition for dry-cleaning textile articles.
Another object of the invention is the use of said composition as a dry-cleaning agent.
The invention also relates to a method for dry cleaning textile articles using said composition.
The technical field of the invention can, generally, be defined as that of the dry cleaning of clothing, textiles, fabrics and similar items.
Dry cleaning is a major industry around the world. Indeed, many types of textile articles such as clothing or others must be dry-cleaned in order to remain clean and presentable without discoloration or shrinking or wrinkling.
Dry cleaning professionals have high-performance machines wherein circulate, in a closed circuit, a cleaning solvent which makes it possible, generally, to remove contaminants such as the fats that have been deposited on the textile articles.
The most widely used solvent until now is perchloroethylene (PERC). For example, in France, 4000 dry-cleaning companies use about 8000 metric tons of PERC per year. This solvent has the advantage of being very effective for dissolving the stains and soilings (fats) that contaminate textile articles. However, the use of PERC gives rise to multiple problems, linked to the environment (destruction of the ozone layer, pollution of the ground water), human health (risk of inhaling carcinogenic substances) and to the safety of the users. Indeed, in the event of frequent and intense exposure, PERC can be toxic for the liver, the kidneys and the nervous system, and cause irritation to the eyes and the respiratory tract, as well as vertigo and nausea. PERC is subjected to substantial regulations which are increasingly aimed to suppress it. Moreover, it is already prohibited in certain regions of the world. Furthermore, as PERC has a high Kauri-Butanol (KB) index, it is a highly aggressive solvent which tends to bleed colored textile articles and to weaken the decorations that are sometimes glued therein.
Another frequent problem that arises with the use of PERC, is that the soilings extracted during dry-cleaning operations, tend to be re-deposited on the cleaned textile articles, which can accentuate the “greying” phenomenon of textiles.
Substitution solutions aimed at replacing PERC in the dry-cleaning technique have been proposed. As examples, the use of the following can be mentioned:
Moreover, the problem of the (re)contamination of the textile articles by the (re)depositing of the liquid or solid particles already extracted during dry-cleaning operations, is not resolved by any of the compositions and methods of prior art.
However, and despite the progress made recently in developing alternative solutions to the use of PERC, there is still a need for compositions and for methods that offer high performance and that are eco-responsible for the dry-cleaning of textiles.
One of the objectives of this invention is to provide a new composition that performs particularly well when it is used as a dry-cleaning solvent.
Another objective of the invention is to provide such a composition that does not pollute, respects the environment and is not dangerous for human or animal health.
The invention further has for objective to propose a composition that is adapted for eliminating both hydrophobic soilings and hydrophilic soilings contaminating the textile articles to be dry-cleaned.
The invention further has for objective to propose a composition that makes it possible to prevent the (re)contamination of the textile articles by the solid or liquid soilings already extracted during cleaning operations.
The invention also aims to achieve all of these objectives at least cost, by proposing a composition with a low cost price, comprising compounds that are inexpensive and available in commerce.
The solution proposed by the invention is a composition for dry-cleaning textile articles, characterized in that it is anhydrous and in that it comprises as active cleaning agent:
The authors of this invention, surprisingly and unexpectedly observed that the methyl ether combination of dipropylene glycol, of amphiphilic solvent A and of at least one dibasic ester B makes it possible to formulate a composition that performs particular well and that is well suited to act as a solvent or liquid for dry cleaning textiles. Without a doubt, this high performance is due to an effect of synergy.
In particular, the composition in accordance with the invention manifests a high cleaning power with respect to hydrophobic soilings (fat in particular), but also with regards to hydrophilic soilings (organic matter or water-soluble minerals) which can appear on textile articles. Indeed, the authors of this invention were able to observe that the composition of the invention is particularly effective on hydrophilic soilings, in particular on colored stains such as coffee stains, wine stains, fruit juice stains, beverage stains and bodily fluids such as blood.
Moreover, the composition of the invention also has the advantage of maintaining, in a solution or in a suspension, the liquid or solid soilings extracted during the dry cleaning operation as such preventing them from being re-deposited onto the cleaned textile articles.
Furthermore, the composition of the invention further has the advantage of being able to be prepared solely using compounds that are non-volatile, non-toxic, classified as easily biodegradable, inexpensive and available in commerce.
The composition according to the invention therefore has substantial potential.
Other preferred characteristics of the invention are listed hereinbelow, with each of these characteristics able to be considered independently or in combination with the remarkable characteristics defined hereinabove:
According to another aspect, the invention also relates to the use as an active dry-cleaning agent for textile articles, a composition comprising:
in which n is a whole number ranging between 1 and 9; R and R′ are identical or different, each separately representing an alkyl group having from 1 to 6 carbon atoms, or an alkenyl group having from 2 to 6 carbon atoms, said composition having the anhydrous form.
According to yet another aspect, this invention also relates to a method for dry cleaning textile articles, comprising the following steps:
Other purposes and advantages of this invention shall appear in the following description which is provided only for the purposes of information and which does not have for purpose to limit the scope of it.
In this text:
The percentages, content and ratios used hereinbelow are all given with respect to the total weight of the composition “p/pcomposition”, unless indicated otherwise.
This invention aims firstly an anhydrous composition that is particularly suited to the dry cleaning industry. This composition is based on a combination (synergistic) of dipropylene glycol monomethyl ether (DPM), of amphiphilic solvent A and of at least one dibasic ester B. These components are used as active dry cleaning agents for textile articles.
Anhydrous means a composition that is substantially devoid of water, preferably, a composition in which water can be present at a content less than 8% p/pcomposition, more preferably less than 5% p/pcomposition, further preferably less than 2.5%/p/pcomposition, and better yet less than 0.5% p/pcomposition. This absence of water, or possibly the low content of it, provides the composition with a storage stability that is enough in order to guarantee its effectiveness over time and prevent the formation of hydrolysis products of the dibasic ester B which could reduce its cleaning effectiveness. Indeed, it is known that dibasic esters, in particular methyl esters thereof, are sensitive to the phenomena of hydrolysis in the presence of water. The absence of water, or possibly the low content of it, in the composition of the invention, is also particularly advantageous with respect to the effectiveness of the dry cleaning of textiles. Indeed, the authors of this invention were able to note that the use of a composition according to the invention in the form of an aqueous solution containing more than 8% p/pcomposition of water does not result in optimum dry cleaning.
The dipropylene glycol monomethyl ether (DPM) has for function to confer upon the composition of the invention a de-structuring and solubilizing power of the soilings, while still influencing its compatibility favorably (or miscibility) with water. This makes it possible in particular to be able to easily and quickly solubilize both hydrophobic soilings and hydrophilic soilings contaminating textile articles to be dry cleaned.
DPM is generally available in commerce in the form of a mixture of isomers with the general formula C7H16O3. This is a polar organic compound with a pronounced hydrophilic nature, entirely soluble in water, biodegradable and non-toxic. It is marketed under the name DOWANOL® by the DOW® company.
The quantity of DPM used can vary within wide limits in the sense that it provides a content of at least 30% p/pcomposition of DPM. Advantageously, a quantity of DPM ranging from 40% to 80% p/pcomposition makes it possible to achieve high level of performance in dry cleaning.
The amphiphilic solvent A is chosen from the group consisting of dipropylene glycol mono-n-propyl ether, dipropylene glycol mono-n-butyl ether, dipropylene glycol mono-tert-butyl ether or the mixtures thereof.
The amphiphilic solvent A is included in the composition of the invention in order to reinforce its cleaning action, by favoring the compatibility between the DPM which is highly hydrophilic and the rest of the eminently hydrophobic composition. As the amphiphilic solvent A has a high boiling point (greater than 200° C. at 760 mmHg), it is also included in the composition in order to reduce the probability of the formation azeotropes in particular with the water and the other ingredients, for example during recycling operations by distillation.
Dipropylene glycol mono-n-propyl ether (C9H20O3), dipropylene glycol mono-n-butyl ether (C10H22O3) and, dipropylene glycol mono-tert-butyl ether (C10H22O3) are available in commerce in the form of mixtures of isomers. In particular, dipropylene glycol n-propyl ether, dipropylene glycol mono-n-butyl ether are respectively marketed under the name DOWANOL® DPNP DOWANOL® DPNB by the DOW® company. Dipropylene glycol mono-tert-butyl ether is marketed under the name ARCOSolv® DPTB by the LyonDellBasell company.
Preferentially, the amphiphilic solvent A is dipropylene glycol mono-n-butyl ether. The authors of this invention were able to observe that textile articles cleaned using a composition of the invention of which the amphiphilic solvent A is dipropylene glycol mono-n-butyl ether, had a slight odor which is not unpleasant.
Excellent dry cleaning results were obtained when the composition in accordance with the invention comprises from 1% to 50% p/pcomposition, preferably from 5% to 40% p/pcomposition amphiphilic solvent A.
Dibasic ester B (or a mixture of dibasic esters) is represented by the following general formula (I):
R—O—C(═O)—(CH2)n—C(═O)—O—R′ (I)
in which n is a whole number between 1 and 9; R and R′ are identical or different, each separately representing an alkyl or alkenyl group.
The term “alkyl”, in the sense of this invention, means any linear or branched alkyl group, preferably, alkyl groups containing 1 to 6 carbon atoms, in particular the following groups: methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl, isopropyl, isobutyl, isopentyl, s-butyl, t-butyl, t-amyl, 1-ethyl-propyl, 1,2-dimethyl-propyl, 2,2-dimethyl-propyl, 2-methyl-pentyl, 3-methyl-pentyl, 4-methyl-pentyl, 1,1-dimethyl-butyl, 1,2-dimethyl-butyl, 1,3-dimethyl-butyl, 2,2-dimethyl-butyl, 3,3-dimethyl-butyl, 1-ethyl-butyl, 2-ethyl-butyl, 1,1,2-trimethyl-propyl, 1,2,2-trimethyl-propyl, 1-ethyl-1-methyl-propyl or 1-ethyl-2-methyl-propyl.
The term “alkenyl”, in the sense of this invention, means the alkenyl groups containing preferably 2 to 6 carbon atoms, in particular the alkenyl groups chosen from among the group comprised of: 1-propenyl, 1-methyl-1-propenyl, 2-methyl-1-propenyl, 2,2-dimethyl-1-propenyl, 1-butenyl, 2-butenyl, 1-pentenyl, 2-pentenyl, 1-hexenyl, 2-hexenyl or 3-hexenyl.
The chain —(CH2)n— of the formula (I) carries, according to a preferred embodiment, at least one methyl group. The dibasic esters comprising such a chain substituted by at least one methyl group can be optical isomers and/or positional isomers.
The dibasic ester B (or a mixture of dibasic esters) is added to the other components in order to confer upon the composition of the invention the hydrophobic nature required for the solubilization and elimination of the soilings, in particular hydrophobic soilings contaminating textile articles to be dry cleaned.
Examples of dibasic ester B that can be used in the composition of the invention include dimethyl succinate, diethyl succinate, dimethyl glutarate, diethyl glutarate, dimethyl-2-methyl glutarate, dimethyl 3-methyl-glutarate, dimethyl adipate, diethyl adipate and the mixtures thereof. Advantageously, the dibasic ester B is a mixture of dimethyl succinate, of dimethyl glutarate and of dimethyl adipate.
The dibasic esters B to be used in the framework of this invention, are today available on the market. In particular, dibasic ester consisting of a mixture of dimethyl succinate (15% p/pdibasic ester), of dimethyl glutarate (62% p/pdibasic ester) and of dimethyl adipate (23% p/pdibasic ester) is in particular marketed by the “Rhodia®” company under the name “RPDE®”. This mixture of dibasic esters is also known under the acronym “DBE”, and is used under this acronym (DBE) in what follows.
Dibasic esters are liquids with a high boiling point (boiling point greater than 195° C.) and high flash points (greater than 85). They have low volatility, have no or very little toxicity and are easily biodegradable.
The at least one dibasic ester B is advantageously included in the composition in accordance with this invention in a quantity ranging from 1% to 50% p/pcomposition, preferably from 10% to 40% p/pcomposition.
The respective proportions of the three essential ingredients, namely dipropylene glycol monomethyl ether, the amphiphilic solvent A and the dibasic ester B, were chosen in such a way that the composition of the invention offers an optimum quality of dry cleaning as well as satisfactory safety for textile articles and for colors. Moreover, the authors of this invention were able to observe that the composition of the invention can be adapted to the type of soilings (hydrophobic or hydrophilic) as well as to the type of textile articles to be dry-cleaned by varying the proportions of the three essential ingredients.
The composition can further comprise a propylene glycol monomethyl ether C chosen from the group consisting of propylene glycol monomethyl ether, propylene glycol mono-n-propyl ether, propylene glycol mono-n-butyl ether, propylene glycol mono-tert-butyl ether, propylene glycol mono-n-pentyl ether, or the mixtures thereof. The propylene glycol monomethyl ether C will be advantageously added to the other essential ingredients in order to reinforce the cleaning power of the composition according to the invention.
Examples of particularly preferred compositions include in particular anhydrous compositions comprising: (i) dipropylene glycol monomethyl ether (DPM), dipropylene glycol mono-n-butyl ether (DPnB) and dibasic ester DBE; or (ii) dipropylene glycol monomethyl ether (DPM), dipropylene glycol mono-tert-butyl ether (DPtB) and dibasic ester DBE; or (iii) dipropylene glycol monomethyl ether (DPM), dipropylene glycol mono-n-butyl ether (DPnB), dipropylene glycol mono-n-propyl ether (DPnP), and dibasic ester DBE; or (iii) dipropylene glycol monomethyl ether (DPM), dipropylene glycol mono-n-butyl ether (DPnB), propylene glycol mono-n-butyl ether (PnB), and dibasic ester DBE.
The composition according to the invention can advantageously further comprise any sort of additional components that are usually used in the field of dry cleaning. For example, the additional components can be chosen from among the antioxidants, disinfectants, perfumes and the mixtures thereof. These additional components can be present in the composition according to this invention in a quantity between 0.001% and 10% in p/pcomposition without substantially affecting its advantageous properties.
Antioxidants, when they are included in the composition of the invention, have for role to prevent or reduce or delay any formation of peroxides. Examples of antioxidants (or stabilizers) include 2,6-di-tert-butyl-p-methylphenol (BHT), 2-tertio-butyl-4-hydroxyanisole (2-BHA) and 3-tertio-butyl-4-hydroxyanisole (3-BHA) or the mixtures thereof.
Disinfectants, when they are included in the composition of the invention, have for role to allow for a disinfecting action of the textile articles to be cleaned, in particular household, medical or veterinarian laundry. They can also allow for a sanitation action of the enclosure dedicated for dry cleaning. Examples of disinfectants include quaternary ammonium salts, aldehydes, phenolic derivatives, halogenated compounds (ex. iodinated), alcohols or others.
The composition of the invention is, advantageously, in the form of a limpid and colorless liquid and can be conditioned, in anhydrous state, in any container that can receive a liquid, such as for example, a storage pot made of steel or plastic materials such as polyethylene and polypropylene.
The composition of the invention can be prepared by any method of mixing known to those skilled in the art.
During the compatibility tests with water, the authors of this invention were able to observe that the composition of the invention is able to absorb more than 40% of its weight in water. This characteristic is advantageous as it makes it possible to absorb a large portion of the water still retained in the textile articles during cleaning operations, in particular in thick textile articles (ex. coats, quilts, etc.). This results in that the composition of the invention effectively cleans a large spectrum of stains while still allowing the cleaned textile articles to retain their initial forms and tints.
The compositions in accordance with this invention are particularly suitable as a dry-cleaning solvent or fluid for textiles, and can replace PERC entirely, possibly with an adaptation of the dry cleaning machines that use PERC.
As such, this invention also has for object the use of a composition in accordance with the invention as a dry cleaning agent for textile articles.
In practice, the composition of the invention can be used at a rate of 60 liters for 18 kg to 20 kg of textile articles.
According to a specific embodiment, the dry cleaning of textile articles is carried out in the following way (or comprises the following steps):
The dry-cleaning process is terminated after cooling and removal of the textile articles from the machine.
In a preferred alternative embodiment, the method according to the invention can, prior to the placing of the textile articles in the washing and drying machine, comprise a step of brushing and/or of pre-destaining using a pre-brushing and/or pre-destaining, for the purpose of eliminating at least partially the soilings fixed on large surfaces of the textile articles. The pre-destaining can in particular be carried out using the composition according to the invention.
In another alternative embodiment, the impregnation of the textile articles by the cleaning composition can be carried out by spraying by the intermediary of nozzles.
A non-restricted embodiment shall now be given of a composition according to the invention.
Using the description that has just been given, multiple alternative embodiments of the composition and of the method of the invention can be designed by those skilled in the art without leaving the scope of the invention defined by the claims. In particular, if the composition considered performs well in the dry cleaning of various textile articles, it is not excluded to add therein other additional components known to those skilled in the art such as:
The compositions I to V in accordance with the invention are prepared using ingredients indicated in the table hereinbelow by any method known to those skilled in the art.
Anhydrous compositions I to V (not containing added water), limpid and colorless, are obtained, which are chemically stable. These compositions can be stored for more than 1 year, or even more than 2 years, at a temperature less than 40° C., in closed containers away from light and air. They contribute, in particular, the following properties:
The effect of the compositions I to V as dry-cleaning solvents, was studied on a panel of fabrics (10 cm×10 cm) constituted of various fibers as well as on buttons frequently encountered on textile articles (e.g. shirts). A first study concerned the observation of deformation of fabrics and the discoloring and the second study on the effectiveness of the cleaning of stains.
In order to carry out these tests, the fabrics were impregnated (by immersion) and mechanically agitated in the compositions I to V for 10 min then dried in an oven at 70° C.
Results:
a—Deformation, Discoloration and Deterioration of the Linings.
The tests carried out on different fabrics of the polyester, cotton, viscose, linen, acrylic, wool, acetate, elastane types have shown that the fabrics were well washed, dried easily and did not contain any odor after drying and correctly retained their measurement even in the case of wool (deformation less than 0.2 mm). The experiment on pieces of textile has shown that with these compositions the fabric comes out much less drier than with perchloroethylene, and procures a good slide which substantially facilitates ironing, and reduces the risk of tangling in the machines. The elastic textiles retained their extensible property. The best dry cleaning results were obtained with the compositions II and IV.
With regards to discoloration, we observed a slight bleeding in the case of the composition III without re-deposition of the latter on the other fabrics. In the case of the other compositions the resistance to discoloration is good and even better than that of perchloroethylene when the dry-cleaned fabrics are compared with the reference samples.
The tests on the trimming (buttons and accessories) have shown that the compositions I to V provide identical and even better results than perchloroethylene with a preference for the compositions I, II and V which respect these elements more.
b—Stain Removal.
The fabrics studied contained soilings caused by the following contaminants: olive oil, chocolate (Nutella®), mayonnaise, lipstick, red wine, ink and were compared with perchloroethylene. These tests were carried out without the use of a booster (surfactant).
The results of these tests showed that:
| Number | Date | Country | Kind |
|---|---|---|---|
| 12 02972 | Nov 2012 | FR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/FR2013/052639 | 11/6/2013 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2014/076388 | 5/22/2014 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 6042617 | Berndt | Mar 2000 | A |
| 6273919 | Hayday | Aug 2001 | B1 |
| 20030050214 | Scheper et al. | Mar 2003 | A1 |
| 20030083220 | Doyel et al. | May 2003 | A1 |
| 20040226581 | Gardner et al. | Nov 2004 | A1 |
| 20050209123 | Laux | Sep 2005 | A1 |
| 20120084928 | Meyer et al. | Apr 2012 | A1 |
| Number | Date | Country | |
|---|---|---|---|
| 20150252519 A1 | Sep 2015 | US |
