COMPOSITION COMPRISING HF AND 3,3,3-TRIFLUOROPROPENE

Information

  • Patent Application
  • 20160046548
  • Publication Number
    20160046548
  • Date Filed
    February 24, 2014
    10 years ago
  • Date Published
    February 18, 2016
    8 years ago
Abstract
An azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoropropene and one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also, a preferred azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoropropene, and one or more compounds selected from among 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-l-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro, 1,1,1,2-tetrafluoropropane.
Description

The present invention relates to azeotropic or quasi-azeotropic compositions comprising 3,3,3-trifluoropropene and hydrogen fluoride. These compositions may originate from intermediate compositions in the production of 3,3,3-trifluoropropene and are generally useful in processes for recycling hydrogen fluoride.


The manufacture of 3,3,3-trifluoropropene accompanied by a multitude of by-products, having a boiling point close to HFO-1243zf, leads to relatively complex and expensive purification steps. The difficulty encountered during the purification of HFO-1243zf generally implies an appreciable loss of desired product. Furthermore, these by-products may form azeotropic compositions with 1,3,3,3-tetrafluoropropene, making separation by distillation simple, very difficult, or even impossible.


Fluids based on 3,3,3-trifluoropropene have found numerous applications in varied industrial fields, especially as heat-transfer fluid, propellants, foaming agents, swelling agents, gaseous dielectrics, polymerization medium or monomer, support fluids, abrasive agents, drying agents and fluids for power production units.


Particular importance is given to fluids that have a low impact on the environment.


The subject of the present invention is an azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, 3,3,3-trifluoropropene and one or more (hydro)halocarbon compounds comprising between 1 and 3 carbon atoms. According to one embodiment of the invention, the composition is heteroazeotropic or quasi-heteroazeotropic.


A heteroazeotropic or quasi-heteroazeotropic mixture is an azeotropic or quasi-azeotropic mixture in which the condensed liquid forms two immiscible solutions that can be readily separated, for example by decantation.


The term “quasi-azeotropic” or “quasi-heteroazeotropic” has a broad meaning and is intended to include compositions that are strictly azeotropic or strictly heteroazeotropic and those that behave like an azeotropic or heteroazeotropic mixture.


A mixture is azeotropic when the pressure at the dew point is equal to that at the bubble formation point, which means that the vapor composition is equal to that of the condensed liquid.


A mixture is considered as quasi-azeotropic when the pressure at the dew point is substantially equal to that at the bubble formation point, which means that the vapor composition is substantially equal to that of the condensed liquid.


Another way of characterizing a mixture as quasi-azeotropic when the pressure difference between the pressure at the dew point and the pressure at the bubble formation point is low, preferentially less than or equal to 5%, on the basis of the pressure at the bubble formation point.


The compositions according to the invention especially concern the following compounds, the acronyms of which represent:

    • HF: hydrogen fluoride
    • HCC-40: chloromethane, or CH3Cl
    • HCFC-115: chloropentafluoroethane, or C2F5Cl
    • HCFC-124: chlorotetrafluoroethane, or C2HF4Cl
    • HFC-125: pentafluoroethane, or C2HF5
    • HCFC-133a: 1-chloro-2,2,2-trifluoroethane, or C2H2F3Cl
    • HFC-134a: 1,1,1,2-tetrafluoroethane, or C2H2F4
    • HCFC-142b: 1-chloro-1,1-difluoroethane, or C2H3F2Cl
    • HFC-143a: 1,1,1-trifluoroethane, or C2H3F3
    • HFC-152a: 1,1-difluoroethane, or C2H4F2
    • HFO-1132: 1,2-difluoroethylene, or C2H2F2
    • HFO-1141: fluoroethylene, or C2H3F
    • HFO-1234yf: 2,3,3,3-tetrafluoropropene or CH2═CF—CF3
    • HFC-245cb: 1,1,1,2,2-pentafluoropropane or CF3—CF2—CH3
    • HFO-1234zeE: E-1,3,3,3-tetrafluoropropene or E-CF3—CH═CHF
    • HFO-1234zeZ: Z-1,3,3,3-tetrafluoropropene or Z—CF3—CH═CHF
    • HFO-1243zf: 3,3,3-trifluoropropene or CF3—CH═CH2
    • HCFO-1233xf: 3,3,3-trifluoro-2-chloropropene or CF3—CCl═CH2
    • HCFO-1233zdE: E-3,3,3-trifluoro-1-chloropropene or E-CF3—CH═CHCl
    • HCFO-1233zdZ: Z-3,3,3-trifluoro-1-chloropropene or Z—CF3—CH═CHCl
    • HFO-1225yeZ: Z-1,1,1,2,3-pentafluoropropene or Z—CHF═CF—CF3
    • HFO-1225yeE: E-1,1,1,2,3-pentafluoropropene or E-CHF═CF—CF3
    • HFO-1225zc: 1,1,3,3,3-pentafluoropropene or CF2═CH—CF3
    • HFO-1225yc: 1,1,2,3,3-pentafluoropropene or CF2═CF—CF2
    • HCFC-1214: dichlorotetrafluoropropene, or C3F4Cl2
    • HCFO-1215: chloropentafluoropropene, or C3F5Cl
    • HFO-1216: hexafluoropropene, or C3F6
    • HCFO-1223: dichlorotrifluoropropene, or C3HF3Cl2
    • HCFO-1224: chlorotetrafluoropropene, or C3HF4Cl
    • HCFO-1232: dichlorodifluoropropene, or C3H2F2Cl2
    • HCFO-1233xc: 1,1,3-trifluoro-2-chloropropene or CH2F—CCl═CF2
    • HCFO-1233xe: 1,3,3-trifluoro-2-chloropropene or CHF2—CCl═CHF
    • HCFO-1233yb: 1,2,3-trifluoro-1-chloropropene or CH2F—CF═CFCl
    • HCFO-1233yc: 1,1,2-trifluoro-3-chloropropene or CH2Cl—CF═CF2
    • HCFO-1233yd: 2,3,3-trifluoro-1-chloropropene or CHF2—CF═CHCl
    • HCFO-1233ye: 1,2,3-trifluoro-3-chloropropene or CHClF—CF═CHF
    • HCFO-1233yf: 2,3,3-trifluoro-3-chloropropene or CClF2—CF═CH2
    • HCFO-1233zb: 1,3,3-trifluoro-1-chloropropene or CHF2—CH═CFCl
    • HCFO-1233zc: 1,1,3-trifluoro-3-chloropropene or CHClF—CH═CF2
    • HCFO-1233ze: 1,3,3-trifluoro-3-chloropropene or CClF2—CH═CHF
    • HFO-1234yc: 1,2,3-tetrafluoropropene or CF2═CF—CH2F
    • HFO-1234ye: 2,3,3-tetrafluoropropene or CHF═CF—CHF2
    • HFO-1234zc: 1,3,3-tetrafluoropropene or CF2═CH—CHF2
    • HCFO-1242: chlorodifluoropropene, or C3H3F2Cl
    • HFO-1243yc: 1,1,2-trifluoropropene or CH3—CF═CF2
    • HFO-1243ye: 1,2,3-trifluoropropene or CH2F—CF═CHF
    • HFO-1243yf: 2,3,3-trifluoropropene or CHF2—CF═CH2
    • HFO-1243zc: 1,1,3-trifluoropropene or CH2F—CH═CF2
    • HFO-1243ze: 1,3,3-trifluoropropene or CHF2—CH═CHF
    • HCFO-1251: chlorofluoropropene, or C3H4FCl
    • HFO-1252: difluoropropene, or C3H4F2
    • HFO-216: hexafluoropropene, or C3F6Cl2
    • HCFO-217: chloroheptafluoropropane, or C3F7Cl
    • HFC-218: octafluoropropane, or C3F8
    • HCFC-225: dichloropentafluoropropane, or C3HF5Cl2
    • HCFC-226: chlorohexafluoropropane, or C3HF6Cl
    • HFC-227: heptafluoropropane, or C3HF7
    • HCFC-234: dichlorotetrafluoropropane, or C3H2F4Cl2
    • HCFC-235: chloropentafluoropropane, or C3H2F5Cl
    • HFC-236: hexafluoropropane, or C3H2F6
    • HCFC-243: dichlorotrifluoropropane, or C3H3F3Cl2
    • HCFC-244: chlorotetrafluoropropane, or C3H3F4Cl
    • HCFC-244bb: 2-chloro-1,1,1,2-tetrafluoropropane or CF3—CFCl—CH3
    • HFC-245fa: 1,1,1,3,3-pentafluoropropane or CF3—CH2—CHF2
    • HFC-245ea: 1,1,2,3,3-pentafluoropropane or CHF2—CHF—CHF2
    • HFC-245eb: 1,1,1,2,3-pentafluoropropane or CF3—CHF—CH2F
    • HFC-245ca: 1,1,2,2,3-pentafluoropropane or CHF2—CF2—CH2F
    • HCFC-253: chlorotrifluoropropane, or C3H4F3Cl
    • HFC-254: tetrafluoropropane, or C3H4F4
    • HCFC-262: chlorodifluoropropane, or C3H5F2Cl
    • HFC-263: trifluoropropane, or C3H5F3
    • trifluoropropyne: CF3—C≡CH


The composition according to the invention may optionally be a mixture of one or more azeotropes and/or heteroazeotropes of ternary, quaternary, penternary systems, systems with six compounds, systems with seven compounds, systems with eight or more compounds.


The compound(s) containing 1 and/or 2 carbon atoms may be chosen especially from chloromethane, chloropentafluoroethane, 1-chloro-1,2,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, pentafluoroethane, 1-chloro-1,2,2-trifluoroethane, 1-chloro-2,2,2-trifluoroethane, 1,1,2,2-tetrafluoroethane, 1,1,1,2-tetrafluoroethane, 1-chloro-1,2-difluoroethane, 1-chloro-1,1-difluoroethane, 1,1,2-trifluoroethane, 1,1,1-trifluoroethane, 1,1,2-trifluoroethane, 1,1-difluoroethane, 1,2-difluoroethylene and fluoroethylene.


The compound(s) containing 3 carbon atoms may be chosen especially from 1,2-dichloro-1,1,2,3,3,3-hexafluoropropane, 1,3-dichloro-1,1,2,2,3,3-hexafluoropropane, 1,1-dichloro-1,2,2,3,3,3-hexafluoropropane, 2,2-dichloro-1,1,1,3,3,3-hexafluoropropane, 1-chloro-1,1,2,2,3,3,3-heptafluoropropane, 2-chloro-1,1,1,2,3,3,3-heptafluoropropane, octafluoropropane, dichloropentafluoropropane, 2,2-dichloro-1,1,1,3,3-pentafluoropropane, 2,3-dichloro-1,1,1,2,3-pentafluoropropane, 1,2-dichloro-1,1,2,3,3-pentafluoropropane, 3,3-dichloro-1,1,1,2,2-pentafluoropropane, 1,3-dichloro-1,1,2,2,3-pentafluoropropane, 1,1-dichloro-1,2,2,3,3-pentafluoropropane, 1,2-dichloro-1,1,3,3,3-pentafluoropropane, 1,3-dichloro-1,1,2,3,3-pentafluoropropane, 1,1-dichloro-1,2,3,3,3-pentafluoropropane, chlorohexafluoropropane, 2-chloro-1,1,1,2,3,3-hexafluoropropane, 3-chloro-1,1,1,2,2,3-hexafluoropropane, 1-chloro-1,1,2,2,3,3-hexafluoropropane, 2-chloro-1,1,1,3,3,3-hexafluoropropane, 1-chloro-1,1,2,3,3,3-hexafluoropropane, 1,1,2,2,3,3,3-heptafluoropropane, 1,1,1,2,3,3,3-Heptafluoropropane, dichlorotetrafluoropropane, 2,2-dichloro-1,1,3,3-tetrafluoropropane, 2,2-dichloro-1,1,1,3-tetrafluoropropane, 1,2-dichloro-1,2,3,3-tetrafluoropropane, 2,3-dichloro-1,1,1,2-tetrafluoropropane, 1,2-dichloro-1,1,2,3-tetrafluoropropane, 1,3-dichloro-1,2,2,3-tetrafluoropropane, 1,1-dichloro-2,2,3,3-tetrafluoropropane, 1,3-dichloro-1,1,2,2-tetrafluoropropane, 1,1-dichloro-1,2,2,3-tetrafluoropropane, 2,3-dichloro-1,1,1,3-tetrafluoropropane, 1,3-dichloro-1,1,3,3-tetrafluoropropane, 1,3-dichloro-1,1,3,3-tetrafluoropropane, 1,1-dichloro-1,3,3,3-tetrafluoropropane, 1,1-dichloro-2,3,3,3-tetrafluoropropane, 1,3-dichloro-1,1,2,3-tetrafluoropropane, 1,1-dichloro-1,2,3,3-tetrafluoropropane, chloropentafluoropropane, 1-chloro-1,2,2,3,3-pentafluoropropane, 3-chloro-1,1,1,2,3-pentafluoropropane, 1-chloro-1,1,2,2,3-pentafluoropropane, 2-chloro-1,1,1,3,3-pentafluoropropane, 1-chloro-1,1,3,3,3-pentafluoropropane, 1-chloro-1,1,2,3,3-pentafluoropropane, 3-chloro-1,1,1,2,2-pentafluoropropane, 2-chloro-1,1,2,3,3-pentafluoropropane, 2-chloro-1,1,1,2,3-pentafluoropropane, 1,1,1,2,2,3-hexafluoropropane, 1,1,1,2,3,3-hexafluoropropane, 1,1,1,3,3,3-hexafluoropropane, 1,1,2,2,3,3-hexafluoropropane, dichlorotrifluoropropane, 1,1-dichloro-3,3,3-trifluoropropane, 1,3-dichloro-1,1,3-trifluoropropane, 1,1-dichloro-1,3,3-trifluoropropane, 1,3-dichloro-1,2,3-trifluoropropane, 1,1-dichloro-2,3,3-trifluoropropane, 1,3-dichloro-1,1,2-trifluoropropane, 1,1-dichloro-1,2,3-trifluoropropane, 1,2-dichloro-1,3,3-trifluoropropane, 2,3-dichloro-1,1,1-trifluoropropane, 1,2-dichloro-1,1,3-trifluoropropane, 1,3-dichloro-1,2,2-trifluoropropane, 1,1-dichloro-2,2,3-trifluoropropane, 1,1-dichloro-1,2,2-trifluoropropane, 2,3-dichloro-1,1,2-trifluoropropane, 1,2-dichloro-1,2,3-trifluoropropane, 1,2-dichloro-1,1,2-trifluoropropane, 2,2-dichloro-1,1,3-trifluoropropane, 2,2-dichloro-3,3,3-trifluoropropane, chlorotetrafluoropropane, 2-chloro-1,2,3,3-tetrafluoropropane, 2-chloro-1,1,1,2-tetrafluoropropane, 3-chloro-1,1,2,2-tetrafluoropropane, 1-chloro-1,2,2,3-tetrafluoropropane, 1-chloro-1,1,2,2-tetrafluoropropane, 2-chloro-1,1,3,3-tetrafluoropropane, 2-chloro-1,1,1,3-tetrafluoropropane, 3-chloro-1,1,2,3-tetrafluoropropane, 3-chloro-1,1,1,2-tetrafluoropropane, 1-chloro-1,1,2,3-tetrafluoropropane, 3-chloro-1,1,1,3-tetrafluoropropane, 1-chloro-1,1,3,3-tetrafluoropropane, pentafluoropropane, 1,1,2,2,3-pentafluoropropane, 1,1,2,3,3-pentafluoropropane, 1,1,1,2,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, chlorotrifluoropropane, 2-chloro-1,2,3-trifluoropropane, 2-chloro-1,1,2-trifluoropropane, 1-chloro-2,2,3-trifluoropropane, 1-chloro-1,2,2-trifluoropropane, 3-chloro-1,1,2-trifluoropropane, 1-chloro-1,2,3-trifluoropropane, 1-chloro-1,1,2-trifluoropropane, 3-chloro-1,3,3-trifluoropropane, 3-chloro-1,1,1-trifluoropropane, 1-chloro-1,1,3-trifluoropropane, 2-chloro-1,1,3-trifluoropropane, 2-chloro-1,1,1-trifluoropropane, 1,1,2,2-tetrafluoropropane, 1,1,1,3-tetrafluoropropane, 1,1,2,3-tetrafluoropropane, 1,1,1,2-tetrafluoropropane, 1,2,2,3-tetrafluoropropane, 1,1,3,3-tetrafluoropropane, chlorodifluoropropane, 1-chloro-2,2-difluoropropane, 3-chloro-1,1-difluoropropane, 1-chloro-1,3-difluoropropane, 1-chloro-1,1-difluoropropane, 1-chloro-2,3-difluoropropane, 1-chloro-1,2-difluoropropane, 2-chloro-1,3-difluoropropane, 2-chloro-1,1-difluoropropane, 2-chloro-1,2-difluoropropane, trifluoropropane, 1,1,1-trifluoropropane, 1,1,3-trifluoropropane, 1,2,3-trifluoropropane, 1,1,2-trifluoropropane, 1,2,2-trifluoropropane, dichlorotetrafluoropropene, 1,2-dichloro-1,3,3,3-tetrafluoropropene, 1,1-dichloro-2,3,3,3-tetrafluoropropene, 1,3-dichloro-1,2,3,3-tetrafluoropropene, 2,3-dichloro-1,1,3,3-tetrafluoropropene, 3,3-dichloro-1,1,2,3-tetrafluoropropene, chloropentafluoropropene, 1-chloropentafluoropropene, 2-chloropentafluoropropene, 3-chloropentafluoropropene, hexafluoropropene, dichlorotrifluoropropene, 1,1-dichloro-3,3,3-trifluoropropene, 1,2-dichloro-3,3,3-trifluoropropene, 2,3-dichloro-1,3,3-trifluoropropene, 1,3-dichloro-2,3,3-trifluoropropene, 1,2-dichloro-1,3,3-trifluoropropene, 2,3-dichloro-1,1,3-trifluoropropene, 1,1-dichloro-2,3,3-trifluoropropene, 1,3-dichloro-1,2,3-trifluoropropene, 3,3-dichloro-1,1,2-trifluoropropene, 3,3-dichloro-1,2,3-trifluoropropene, 1,3-dichloro-1,3,3-trifluoropropene, 3,3-dichloro-1,1,3-trifluoropropene, 1-chloro-2,3,3,3-tetrafluoropropene, 1-chloro-1,3,3,3-tetrafluoropropene, 2-chloro-1,3,3,3-tetrafluoropropene, 3-chloro-1,2,3,3-tetrafluoropropene, 3-chloro-1,1,3,3-tetrafluoropropene, 2-chloro-1,1,3,3-tetrafluoropropene, 1-chloro-1,2,3,3-tetrafluoropropene, 3-chloro-1,1,2,3-tetrafluoropropene, 1,2,3,3,3-pentafluoropropene, 1,1,3,3,3-pentafluoropropene, 1,1,2,3,3-pentafluoropropene, dichlorodifluoropropene, 2,3-dichloro-3,3-difluoropropene, 1,2-dichloro-1,3-difluoropropene, 2,3-dichloro-1,1-difluoropropene, 1,2-dichloro-3,3-difluoropropene, 2,3-dichloro-1,3-difluoropropene, 1,1-dichloro-2,3-difluoropropene, 1,3-dichloro-1,2-difluoropropene, 1,3-dichloro-2,3-difluoropropene, 3,3-dichloro-1,2-difluoropropene, 3,3-dichloro-2,3-difluoropropene, 1,1-dichloro-3,3-difluoropropene, 1,3-dichloro-1,3-difluoropropene, 3,3-dichloro-1,1-difluoropropene, 1,3-dichloro-3,3-difluoropropene, 3,3-dichloro-1,3-difluoropropene, chlorotrifluoropropene, 2-chloro-1,1,3-trifluoropropene, 2-chloro-1,3,3-trifluoropropene, 1-chloro-1,2,3-trifluoropropene, 3-chloro-1,1,2-trifluoropropene, 1-chloro-2,3,3-trifluoropropene, 3-chloro-1,2,3-trifluoropropene, 3-chloro-2,3,3-trifluoropropene, 1-chloro-1,3,3-trifluoropropene, 3-chloro-1,1,3-trifluoropropene, 3-chloro-1,3,3-trifluoropropene, 1,1,2,3-tetrafluoropropene, 1,2,3,3-tetrafluoropropene, 1,1,3,3-tetrafluoropropene, chlorodifluoropropene, 3-chloro-3,3-difluoropropene, 3-chloro-1,3-difluoropropene, 2-chloro-1,1-difluoropropene, 2-chloro-1,3-difluoropropene, 2-chloro-3,3-difluoropropene, 1-chloro-1,2-difluoropropene, 1-chloro-2,3-difluoropropene, 3-chloro-1,2-difluoropropene, 3-chloro-2,3-difluoropropene, 1-chloro-1,3-difluoropropene, 3-chloro-1,1-difluoropropene, 1-chloro-3,3-difluoropropene, trifluoropropene, 1,1,2-trifluoropropene, 1,2,3-trifluoropropene, 2,3,3-trifluoropropene, 1,1,3-trifluoropropene, 1,3,3-trifluoropropene, chlorofluoropropene, 1-chloro-3-fluoropropene, 1-chloro-1-fluoropropene, 1-chloro-2-fluoropropene, 2-chloro-1-fluoropropene, 2-chloro-3-fluoropropene, 3-chloro-2-fluoropropene, 3-chloro-1-fluoropropene, 3-chloro-3-fluoropropene, difluoropropene, 1,2-difluoropropene, 2,3-difluoropropene, 1,1-difluoropropene, 1,3-difluoropropene, 3,3-difluoropropene, 1,1,1,2,2-pentafluoropropane, E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, Z-3,3,3-trifluoro-1-chloropropene and trifluoropropyne.


A subject of the present invention is also an azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, 3,3,3-trifluoropropene, and one or more compounds chosen from 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


A subject of the present invention is also a composition comprising hydrogen fluoride, 3,3,3-trifluoropropene and at least one or more organic compounds chosen from E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.


According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,2,2-heptafluoropropane and optionally one or more compounds chosen from 2,3,3,3-tetrafluoropropene, E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, E-3,3,3-trifluoro-1-chloropropene and optionally one or more compounds chosen from 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene and optionally one or more compounds chosen from 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropene, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, trifluoropropyne and optionally one or more compounds chosen from 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,3,3-pentafluoropropane and optionally one or more compounds chosen from 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,3,3-pentafluoropropene and optionally one or more compounds chosen from 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,2,3-pentafluoropropene and optionally 2-chloro-1,1,1,2-tetrafluoropropane.


According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, E-1,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to one embodiment of the invention, the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, Z-1,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene and optionally one or more compounds chosen from E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to one embodiment of the invention, the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, E-3,3,3-trifluoro-1-chloropropene and optionally one or more compounds chosen from 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,2,2-pentafluoropropane and optionally one or more compounds chosen from 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


According to one embodiment of the invention, the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.


Irrespective of the embodiment, the composition preferably comprises from 1% to 95% and advantageously from 5% to 80% by weight of hydrogen fluoride and from 99% to 5% and advantageously from 20% to 95% by weight of the sum of the organic compounds; more particularly, the composition comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of the organic compounds (HFO-1243zf and the (hydro)halocarbon compounds).


Irrespective of the embodiment, the boiling point of the composition according to the invention is between −20° C. and 80° C. and at a pressure between 0.1 and 44 bar absolute, preferentially between 0° C. and 40° C. and preferentially at a pressure of between 0.7 and 18 bar absolute, advantageously between 0.9 and 12.5 bar absolute.


The Applicant has discovered that the compositions according to the invention have advantageous properties in particular for the recycling of HF in the reaction step. Thus, the condensed phase of these compositions, optionally when they are subjected to a distillation step and/or a liquid/liquid separation step, such as by decantation, form two immiscible liquid phases.


By way of example, for the ternary compounds containing hydrogen fluoride, 3,3,3-trifluoropropene and a compound chosen from 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene and E-3,3,3-trifluoro-1-chloropropene, the appearance of a heteroazeotrope characterized by two liquid phases, one rich in HF and the other depleted in HF, depends on the amount of HF in the composition. These decantation ranges as a function of the HF content in the compositions were characterized for at least isotherms at 0° C., 25° C. and 40° C.


Similarly, the decantation ranges for the ternary compounds containing hydrogen fluoride, 3,3,3-trifluoropropene and a compound chosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, Z-1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane are characterized by a phase depleted in HF and a phase enriched in HF for at least isotherms at 0° C., 25° C. and 40° C.


An azeotropic or quasi-azeotropic composition that is preferred according to the invention comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of HFO-1243zf and of HFC-245cb, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.


An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of HFO-1243zf and of HFC-245cb, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.


An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of HFO-1243zf, of HCFC-244bb, of HFC-245fa, of trifluoropropyne, of HFO-1225yeZ and of HFO-1225zc, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.7 and 18 bar absolute.


An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of HFO-1243zf, of HCFC-244bb, of HFC-245fa, of trifluoropropyne, of HFO-1225yeZ and of HFO-1225zc, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.7 and 18 bar absolute.


The pressure characteristics of the mixtures of Examples 1, 4, 7, 10, 13, 16 and 19 were calculated for an isotherm at 25° C.


Examples 2, 5, 8, 11, 14, 17 and 20 represent the boiling point and pressure ranges of the mixtures and Examples 3, 6, 9, 12, 15, 18 and 21 represent the decantation ranges of the mixtures of Examples 1, 4, 7, 10, 13, 16 and 19 as a function of the mass percentage of HF characterized for isotherms at 0° C., 25° C. and 40° C. The decantation ranges of Examples 3, 6, 9, 12, 15, 18 and 21 are calculated for mixtures of organic compounds having equal-mass contents. By way of example, for a ternary mixture, a mixture containing 50% by weight of each of the two organic compounds is considered; for a penternary mixture, a mixture containing 25% by weight of each of the four organic compounds is considered, the mass fraction of HF ranging from 0 to 1. These calculations are performed at the liquid-vapor equilibrium, under azeotropic conditions.







EXAMPLE 1
Ternary Mixtures, Isotherm at 25° C.

HF-HFO-1243zf-HFC-245cb HF-HFO-1234yf-HFO-1243zf














Organics
Organics
Organics


0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +


0.05 F245cb
0.5 F245cb
0.95 F245cb












MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL


FRAC
PRESSURE
FRAC
PRESSURE
FRAC
PRESSURE


HF
bar
HF
bar
HF
bar















0
5.8
0
5.4
0
4.7


0.05
6.7
0.05
6.4
0.05
5.9


0.1
6.8
0.1
6.4
0.1
5.9


0.15
6.8
0.15
6.4
0.15
5.9


0.2
6.8
0.2
6.4
0.2
5.9


0.25
6.8
0.25
6.4
0.25
5.9


0.3
6.8
0.3
6.4
0.3
5.9


0.35
6.8
0.35
6.4
0.35
5.9


0.4
6.8
0.4
6.4
0.4
5.9


0.45
6.8
0.45
6.4
0.45
5.9


0.5
6.7
0.5
6.4
0.5
5.9


0.55
6.7
0.55
6.4
0.55
5.9


0.6
6.7
0.6
6.4
0.6
5.9


0.65
6.7
0.65
6.4
0.65
5.9


0.7
6.6
0.7
6.4
0.7
5.9


0.75
6.4
0.75
6.3
0.75
5.9


0.8
6.1
0.8
6.2
0.8
5.9


0.85
5.6
0.85
5.7
0.85
5.9


0.9
4.8
0.9
4.9
0.9
5.0


0.95
3.4
0.95
3.5
0.95
3.6


1
1.2
1
1.2
1
1.2





















Organics
Organics
Organics


0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +


0.05 F1234yf
0.5 F1234yf
0.95 F1234yf












MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL


FRAC
PRESSURE
FRAC
PRESSURE
FRAC
PRESSURE


HF
bar
HF
bar
HF
bar















0
5.9
0
6.3
0
6.7


0.05
6.8
0.05
7.2
0.05
7.7


0.1
6.9
0.1
7.3
0.1
7.7


0.15
6.9
0.15
7.3
0.15
7.7


0.2
6.8
0.2
7.2
0.2
7.7


0.25
6.8
0.25
7.2
0.25
7.7


0.3
6.8
0.3
7.2
0.3
7.7


0.35
6.8
0.35
7.2
0.35
7.7


0.4
6.8
0.4
7.2
0.4
7.7


0.45
6.8
0.45
7.2
0.45
7.7


0.5
6.8
0.5
7.2
0.5
7.7


0.55
6.8
0.55
7.2
0.55
7.7


0.6
6.8
0.6
7.2
0.6
7.7


0.65
6.7
0.65
7.2
0.65
7.7


0.7
6.6
0.7
7.1
0.7
7.7


0.75
6.5
0.75
7.0
0.75
7.5


0.8
6.2
0.8
6.7
0.8
7.2


0.85
5.7
0.85
6.1
0.85
6.6


0.9
4.8
0.9
5.2
0.9
5.6


0.95
3.4
0.95
3.6
0.95
3.8


1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1243zf HF-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics



0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +



0.05 F1233xf
0.5 F1233xf
0.95 F1233xf














MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL



FRAC
PRES
FRAC
PRES
FRAC
PRES



HF
bar
HF
bar
HF
bar


















0
5.7
0
4.0
0
1.8



0.05
6.6
0.05
5.0
0.05
2.9



0.1
6.7
0.1
5.0
0.1
2.9



0.15
6.6
0.15
5.0
0.15
2.9



0.2
6.6
0.2
5.0
0.2
2.9



0.25
6.6
0.25
5.0
0.25
2.9



0.3
6.6
0.3
5.0
0.3
2.9



0.35
6.6
0.35
5.0
0.35
2.9



0.4
6.6
0.4
5.0
0.4
2.9



0.45
6.6
0.45
5.0
0.45
2.9



0.5
6.6
0.5
5.0
0.5
2.9



0.55
6.6
0.55
5.0
0.55
2.9



0.6
6.6
0.6
5.0
0.6
2.9



0.65
6.5
0.65
4.9
0.65
2.9



0.7
6.4
0.7
4.9
0.7
2.9



0.75
6.3
0.75
4.7
0.75
2.9



0.8
6.0
0.8
4.5
0.8
2.7



0.85
5.5
0.85
4.1
0.85
2.5



0.9
4.7
0.9
3.5
0.9
2.2



0.95
3.3
0.95
2.6
0.95
1.8



1
1.2
1
1.2
1
1.2






















Organics
Organics
Organics


0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +


0.05 F1233zdE
0.5 F1233zdE
0.95 F1233zdE












MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL


FRAC
PRESSURE
FRAC
PRESSURE
FRAC
PRESSURE


HF
bar
HF
bar
HF
bar















0
5.7
0
3.9
0
1.6


0.05
6.6
0.05
5.0
0.05
2.7


0.1
6.6
0.1
4.9
0.1
2.7


0.15
6.6
0.15
4.9
0.15
2.7


0.2
6.6
0.2
4.9
0.2
2.7


0.25
6.6
0.25
4.9
0.25
2.7


0.3
6.6
0.3
4.9
0.3
2.7


0.35
6.6
0.35
4.9
0.35
2.7


0.4
6.6
0.4
4.9
0.4
2.7


0.45
6.6
0.45
4.9
0.45
2.7


0.5
6.6
0.5
4.9
0.5
2.7


0.55
6.6
0.55
4.9
0.55
2.7


0.6
6.6
0.6
4.9
0.6
2.7


0.65
6.5
0.65
4.8
0.65
2.7


0.7
6.4
0.7
4.8
0.7
2.7


0.75
6.3
0.75
4.6
0.75
2.7


0.8
6.0
0.8
4.4
0.8
2.5


0.85
5.5
0.85
4.0
0.85
2.4


0.9
4.6
0.9
3.4
0.9
2.1


0.95
3.3
0.95
2.5
0.95
1.7


1
1.2
1
1.2
1
1.2









HF-HFO-1234zeE-HFO-1243zf HF-HFO-1234zeZ-HFO-1243zf














Organics
Organics
Organics


0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +


0.05 F1234zeE
0.5 F1234zeE
0.95 F1234zeE












MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL


FRAC
PRESSURE
FRAC
PRESSURE
FRAC
PRESSURE


HF
bar
HF
bar
HF
bar















0
5.8
0
5.4
0
4.9


0.05
6.7
0.05
6.3
0.05
5.9


0.1
6.8
0.1
6.4
0.1
5.9


0.15
6.8
0.15
6.4
0.15
5.9


0.2
6.8
0.2
6.4
0.2
5.9


0.25
6.8
0.25
6.4
0.25
5.9


0.3
6.8
0.3
6.4
0.3
5.9


0.35
6.8
0.35
6.4
0.35
5.9


0.4
6.7
0.4
6.4
0.4
5.9


0.45
6.7
0.45
6.4
0.45
5.9


0.5
6.7
0.5
6.3
0.5
5.8


0.55
6.7
0.55
6.3
0.55
5.8


0.6
6.7
0.6
6.3
0.6
5.7


0.65
6.6
0.65
6.2
0.65
5.6


0.7
6.5
0.7
6.1
0.7
5.5


0.75
6.4
0.75
5.8
0.75
5.2


0.8
6.1
0.8
5.5
0.8
4.9


0.85
5.6
0.85
5.0
0.85
4.4


0.9
4.7
0.9
4.2
0.9
3.6


0.95
3.4
0.95
3.0
0.95
2.6


1
1.2
1
1.2
1
1.2





















Organics
Organics
Organics


0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +


0.05 F1234zeZ
0.5 F1234zeZ
0.95 F1234zeZ












MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL


FRAC
PRESSURE
FRAC
PRESSURE
FRAC
PRESSURE


HF
bar
HF
bar
HF
bar















0
5.7
0
4.0
0
2.0


0.05
6.6
0.05
5.0
0.05
3.1


0.1
6.6
0.1
5.0
0.1
3.1


0.15
6.6
0.15
5.0
0.15
3.1


0.2
6.6
0.2
5.0
0.2
3.1


0.25
6.6
0.25
5.0
0.25
3.1


0.3
6.6
0.3
5.0
0.3
3.1


0.35
6.6
0.35
5.0
0.35
3.1


0.4
6.6
0.4
5.0
0.4
3.1


0.45
6.6
0.45
5.0
0.45
3.1


0.5
6.6
0.5
5.0
0.5
3.1


0.55
6.6
0.55
5.0
0.55
3.1


0.6
6.6
0.6
5.0
0.6
3.1


0.65
6.5
0.65
5.0
0.65
3.1


0.7
6.4
0.7
4.9
0.7
3.1


0.75
6.3
0.75
4.8
0.75
3.1


0.8
6.0
0.8
4.5
0.8
3.0


0.85
5.5
0.85
4.2
0.85
2.8


0.9
4.7
0.9
3.6
0.9
2.4


0.95
3.3
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2









EXAMPLE 2
Temperature and Pressure Range of Ternary Mixtures

















Boiling point range












Temperature
Pressure



Ternary
° C.
bar abs







HF-HFO-1243zf-HFC-245cb
0 to 40
~2.5 to ~10.4



HF-HFO-1234yf-HFO-1243zf
0 to 40
~3.0 to ~11.7



HF-HCFO-1233xf-HFO-1243zf
0 to 40
~1.1 to ~10.2



HF-HFO-1234zeE-HFO-1243zf
0 to 40
~2.5 to ~10.4



HF-HFO-1234zeZ-HFO-1243zf
0 to 40
~1.2 to ~10.2



HF-HCFO-1233zdE-HFO-1243zf
0 to 40
~1.1 to ~10.2










EXAMPLE 3
Decantation Range of Ternary Mixtures














Decantation ranges



Mass percentage of HF











Isotherm
Isotherm
Isotherm


Ternary
0° C.
25° C.
40° C.





HF-HFO-1243zf-HFC-245cb
5-75
10-75
40-70


HF-HFO-1234yf-HFO-1243zf
5-70
*
*


HF-HCFO-1233xf-HFO-1243zf
5-75
10-65
20-40


HF-HFO-1234zeE-HFO-1243zf
5-65
*
*


HF-HFO-1234zeZ-HFO-1243zf
5-75
10-65
*


HF-HCFO-1233zdE-HFO-1243zf
5-75
 5-65
15-45









EXAMPLE 4
Quaternary Mixtures, Isotherm at 25° C.

HF-HCFO-1233xf-HFO-1243zf-HFC-245cb















Organics
Organics
Organics
Organics


0.9 F1233xf +
0.4 F1233xf +
0.05 F1233xf +
0.05 F1233xf +


0.05 F1243zf +
0.3 F1243zf +
0.9 F1243zf +
0.05 F1243zf +


0.05 F245cb
0.3 F245cb
0.05 F245cb
0.9 F245cb















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
2.0
0
4.0
0
5.6
0
4.6


0.05
3.1
0.05
5.1
0.05
6.6
0.05
5.7


0.1
3.1
0.1
5.1
0.1
6.6
0.1
5.7


0.15
3.1
0.15
5.1
0.15
6.6
0.15
5.7


0.2
3.1
0.2
5.1
0.2
6.6
0.2
5.7


0.25
3.1
0.25
5.1
0.25
6.6
0.25
5.7


0.3
3.1
0.3
5.1
0.3
6.6
0.3
5.7


0.35
3.1
0.35
5.1
0.35
6.6
0.35
5.7


0.4
3.1
0.4
5.1
0.4
6.6
0.4
5.8


0.45
3.1
0.45
5.1
0.45
6.6
0.45
5.8


0.5
3.1
0.5
5.1
0.5
6.6
0.5
5.8


0.55
3.1
0.55
5.1
0.55
6.6
0.55
6.8


0.6
3.1
0.6
5.1
0.6
6.5
0.6
5.8


0.65
3.1
0.65
5.1
0.65
6.5
0.65
5.8


0.7
3.1
0.7
5.1
0.7
6.4
0.7
5.8


0.75
3.1
0.75
5.1
0.75
6.3
0.75
5.8


0.8
2.9
0.8
4.8
0.8
6.0
0.8
5.8


0.85
2.7
0.85
4.5
0.85
5.5
0.85
5.7


0.9
2.4
0.9
3.8
0.9
4.7
0.9
4.5


0.95
1.9
0.95
2.8
0.95
3.3
0.95
3.5


1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HCFO-1233zdE-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1233zdE +
0.9 F1233zdE +
0.05 F1233zdE +
0.3 F1233zdE +


0.05 F1243zf
0.05 F1243zf
0.3 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
1.8
0
1.6
0
5.5
0
3.0


0.05
2.9
0.05
2.7
0.05
6.4
0.05
4.1


0.1
2.9
0.1
2.7
0.1
6.5
0.1
4.1


0.15
2.9
0.15
2.7
0.15
6.5
0.15
4.1


0.2
2.9
0.2
2.7
0.2
6.5
0.2
4.1


0.25
2.9
0.25
2.7
0.25
6.5
0.25
4.1


0.3
2.9
0.3
2.7
0.3
6.5
0.3
4.1


0.35
2.9
0.35
2.7
0.35
6.5
0.35
4.1


0.4
2.9
0.4
2.7
0.4
6.5
0.4
4.1


0.45
2.9
0.45
2.7
0.45
6.5
0.45
4.1


0.5
2.9
0.5
2.7
0.5
6.4
0.5
4.1


0.55
2.9
0.55
2.7
0.55
6.4
0.55
4.1


0.6
2.9
0.6
2.7
0.6
6.4
0.6
4.0


0.65
2.9
0.65
2.7
0.65
6.4
0.65
4.0


0.7
2.9
0.7
2.7
0.7
6.3
0.7
4.0


0.75
2.9
0.75
2.7
0.75
6.1
0.75
3.9


0.8
2.7
0.8
2.6
0.8
5.8
0.8
3.7


0.85
2.5
0.85
2.4
0.85
5.3
0.85
3.4


0.9
2.2
0.9
2.1
0.9
4.5
0.9
2.9


0.95
1.8
0.95
1.7
0.95
3.2
0.95
2.2


1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234zeE-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +
0.3 F1234zeE +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
2.0
0
4.8
0
5.6
0
4.0


0.05
3.1
0.05
5.7
0.05
6.6
0.05
5.1


0.1
3.1
0.1
5.8
0.1
6.6
0.1
5.1


0.15
3.1
0.15
5.8
0.15
6.6
0.15
5.1


0.2
3.1
0.2
5.8
0.2
6.6
0.2
5.1


0.25
3.1
0.25
5.8
0.25
6.6
0.25
5.1


0.3
3.1
0.3
5.8
0.3
6.6
0.3
5.0


0.35
3.1
0.35
5.7
0.35
6.6
0.35
5.0


0.4
3.1
0.4
5.7
0.4
6.6
0.4
5.0


0.45
3.1
0.45
5.7
0.45
6.6
0.45
5.0


0.5
3.1
0.5
5.7
0.5
6.6
0.5
5.0


0.55
3.1
0.55
5.7
0.55
6.6
0.55
5.0


0.6
3.1
0.6
5.6
0.6
6.5
0.6
5.0


0.65
3.1
0.65
5.5
0.65
6.5
0.65
4.9


0.7
3.0
0.7
5.3
0.7
6.4
0.7
4.8


0.75
3.0
0.75
5.1
0.75
6.2
0.75
4.7


0.8
2.9
0.8
4.8
0.8
5.9
0.8
4.4


0.85
2.6
0.85
4.3
0.85
5.4
0.85
4.0


0.9
2.3
0.9
3.6
0.9
4.6
0.9
3.4


0.95
1.8
0.95
2.6
0.95
3.3
0.95
2.5


1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234zeZ-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
1.8
0
2.0
0
5.5
0
3.1


0.05
2.9
0.05
3.1
0.05
6.4
0.05
4.2


0.1
2.9
0.1
3.1
0.1
6.5
0.1
4.2


0.15
2.9
0.15
3.1
0.15
6.5
0.15
4.2


0.2
2.9
0.2
3.1
0.2
6.5
0.2
4.2


0.25
2.9
0.25
3.1
0.25
6.5
0.25
4.2


0.3
2.9
0.3
3.1
0.3
6.5
0.3
4.2


0.35
2.9
0.35
3.1
0.35
6.5
0.35
4.2


0.4
2.9
0.4
3.1
0.4
6.5
0.4
4.2


0.45
2.9
0.45
3.1
0.45
6.5
0.45
4.2


0.5
2.9
0.5
3.1
0.5
6.4
0.5
4.2


0.55
2.9
0.55
3.1
0.55
6.4
0.55
4.2


0.6
2.9
0.6
3.1
0.5
6.4
0.6
4.1


0.65
2.9
0.65
3.1
0.65
6.4
0.65
4.1


0.7
2.9
0.7
3.1
0.7
6.3
0.7
4.1


0.75
2.9
0.75
3.1
0.75
6.1
0.75
4.0


0.8
2.8
0.8
3.0
0.8
5.8
0.8
3.8


0.85
2.5
0.85
2.7
0.85
5.3
0.85
3.5


0.9
2.2
0.9
2.4
0.9
4.5
0.9
3.0


0.95
1.8
0.95
1.9
0.95
3.2
0.95
2.3


1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +


0.05 F1234yf +
0.9 F1234yf +
0.05 F1234yf +
0.3 F1234yf +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
2.1
0
6.5
0
5.8
0
4.6


0.05
3.2
0.05
7.5
0.05
5.8
0.05
5.6


0.1
3.2
0.1
7.5
0.1
8.8
0.1
5.7


0.15
3.2
0.15
7.5
0.15
5.8
0.15
5.6


0.2
3.2
0.2
7.5
0.2
6.8
0.2
5.6


0.25
3.2
0.25
7.5
0.25
6.8
0.25
5.6


0.3
3.2
0.3
7.5
0.3
6.8
0.3
5.6


0.35
3.2
0.35
7.5
0.35
6.8
0.35
5.6


0.4
3.2
0.4
7.5
0.4
6.8
0.4
5.6


0.45
3.2
0.45
7.5
0.45
6.8
0.45
5.6


0.5
3.2
0.5
7.5
0.5
6.8
0.5
5.6


0.55
3.2
0.55
7.5
0.55
6.7
0.55
5.6


0.6
3.2
0.6
7.5
0.6
6.7
0.6
5.6


0.65
3.2
0.65
7.5
0.65
6.7
0.65
5.6


0.7
3.2
0.7
7.4
0.7
6.6
0.7
5.6


0.75
3.2
0.75
7.3
0.75
6.4
0.75
5.4


0.8
3.0
0.8
7.0
0.8
6.1
0.8
5.1


0.85
2.8
0.85
6.4
0.85
5.6
0.85
4.7


0.9
2.4
0.9
5.4
0.9
4.8
0.9
4.0


0.95
1.9
0.95
3.7
0.95
3.4
0.95
2.9


1
1.2
1
1.2
1
1.2
1
1.2









HF-HFC-245cb-HCFO-1233zdE-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F245cb +
0.05 F245cb +
0.05 F245cb +
0.4 F245cb +


0.05 F1233zdE +
0.9 F1233zdE +
0.05 F1233zdE +
0.3 F1233zdE +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
4.6
0
1.9
0
5.6
0
4.2


0.05
5.7
0.05
2.9
0.05
6.6
0.05
5.3


0.1
5.7
0.1
2.9
0.1
5.6
0.1
5.3


0.15
5.7
0.15
2.9
0.15
6.6
0.15
5.3


0.2
5.7
0.2
2.9
0.2
6.6
0.2
5.3


0.25
5.7
0.25
2.9
0.25
6.6
0.25
5.3


0.3
5.7
0.3
2.9
0.3
6.6
0.3
5.3


0.35
5.7
0.35
2.9
0.35
6.6
0.35
5.3


0.4
5.7
0.4
2.9
0.4
6.6
0.4
5.3


0.45
5.7
0.45
2.9
0.45
6.6
0.45
5.3


0.5
5.7
0.5
2.9
0.5
6.6
0.5
5.3


0.55
5.7
0.55
2.9
0.55
6.6
0.55
5.3


0.6
5.7
0.6
2.9
0.6
6.5
0.6
5.3


0.65
5.7
0.65
2.9
0.65
6.5
0.65
5.3


0.7
5.8
0.7
2.9
0.7
6.4
0.7
5.3


0.75
5.8
0.75
2.9
0.75
6.2
0.75
5.3


0.8
5.8
0.8
2.8
0.8
6.0
0.8
5.1


0.85
5.7
0.85
2.6
0.85
5.5
0.85
4.7


0.9
4.9
0.9
2.3
0.9
4.7
0.9
4.1


0.95
3.5
0.95
1.8
0.95
3.3
0.95
2.9


1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F1233zdE +
0.05 F1233zdE +
0.05 F1233zdE +
0.4 F1233zdE +


0.05 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +
0.3 F1234zeE +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















PRES-

PRES-

PRES-

PRES-



SURE

SURE

SURE

SURE


HF
PRES
HF
PRES
HF
PRES
HF
PRES


HF
bar
HF
bar
HF
bar
HF
bar

















0
1.8
0
4.8
0
5.6
0
3.9


0.05
2.9
0.05
5.7
0.05
6.6
0.05
5.0


0.1
2.9
0.1
5.7
0.1
6.6
0.1
5.0


0.15
2.9
0.15
5.7
0.15
6.6
0.15
5.0


0.2
2.9
0.2
5.7
0.2
6.6
0.1
5.0


0.25
2.9
0.25
5.7
0.25
6.6
0.25
5.0


0.3
2.9
0.3
5.7
0.3
6.6
0.3
5.0


0.35
2.9
0.35
5.7
0.35
6.6
0.35
5.0


0.4
2.9
0.4
5.7
0.4
6.6
0.4
4.9


0.45
2.9
0.45
5.7
0.45
6.6
0.45
4.9


0.5
2.9
0.5
5.7
0.5
6.6
0.5
4.9


0.55
2.9
0.55
5.6
0.55
6.5
0.55
4.9


0.6
2.9
0.6
5.6
0.6
6.5
0.6
4.9


0.65
2.9
0.65
5.5
0.65
6.5
0.65
4.9


0.7
2.8
0.7
5.3
0.7
6.4
0.7
4.8


0.75
2.8
0.75
5.1
0.75
6.2
0.75
4.6


0.8
2.7
0.8
4.8
0.8
5.9
0.8
4.3


0.85
2.5
0.85
4.3
0.85
5.4
0.85
3.9


0.9
2.2
0.9
3.6
0.9
4.6
0.9
3.3


0.95
1.8
0.95
2.6
0.95
3.3
0.95
2.5


1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F1233zdE +
0.05 F1233zdE +
0.05 F1233zdE +
0.4 F1233zdE +


0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
1.6
0
2.0
0
5.5
0
3.0


0.05
2.7
0.05
3.1
0.05
6.4
0.05
4.1


0.1
2.7
0.1
3.1
0.1
6.5
0.1
4.1


0.15
2.7
0.15
3.1
0.15
6.5
0.15
4.1


0.2
2.7
0.2
3.1
0.2
6.5
0.2
4.1


0.25
2.7
0.25
3.1
0.25
6.5
0.25
4.1


0.3
2.7
0.3
3.1
0.3
6.4
0.3
4.1


0.35
2.7
0.35
3.1
0.35
6.4
0.35
4.1


0.4
2.7
0.4
3.1
0.4
6.4
0.4
4.1


0.45
2.7
0.45
3.1
0.45
6.4
0.45
4.1


0.5
2.7
0.5
3.1
0.5
6.4
0.5
4.1


0.55
2.7
0.55
3.1
0.55
6.4
0.55
4.1


0.6
2.7
0.6
3.1
0.6
6.4
0.6
4.1


0.65
2.7
0.65
3.1
0.65
6.3
0.65
4.0


0.7
2.7
0.7
3.1
0.7
6.3
0.7
4.0


0.75
2.7
0.75
3.1
0.75
6.1
0.75
3.9


0.8
2.6
0.8
3.0
0.8
5.8
0.8
3.7


0.85
2.4
0.85
2.7
0.85
5.3
0.85
3.4


0.9
2.1
0.9
2.4
0.9
4.5
0.9
2.9


0.95
1.7
0.95
1.9
0.95
3.2
0.95
2.2


1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HCFO-1233zdE-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F1234yf +
0.05 F1234yf +
0.05 F1234yf +
0.4 F1234yf +


0.05 F1233zdE +
0.9 F1233zdE +
0.05 F1233zdE +
0.3 F1233zdE +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
6.5
0
1.9
0
5.7
0
5.0


0.05
7.5
0.05
3.0
0.05
6.7
0.05
6.0


0.1
7.5
0.1
3.0
0.1
6.7
0.1
6.0


0.15
7.5
0.15
3.0
0.15
6.7
0.15
6.0


0.2
7.4
0.2
3.0
0.2
6.7
0.2
6.0


0.25
7.4
0.25
3.0
0.25
6.7
0.25
6.0


0.3
7.5
0.3
3.0
0.3
6.7
0.3
6.0


0.35
7.5
0.35
3.0
0.35
6.7
0.35
6.0


0.4
7.5
0.4
3.0
0.4
6.7
0.4
6.0


0.45
7.5
0.45
3.0
0.45
6.7
0.45
6.0


0.5
7.5
0.5
3.0
0.5
6.6
0.5
6.0


0.55
7.5
0.55
3.0
0.55
6.6
0.55
6.0


0.6
7.5
0.6
3.0
0.6
6.6
0.6
6.0


0.65
7.5
0.65
3.0
0.65
6.6
0.65
6.0


0.7
7.4
0.7
3.0
0.7
6.5
0.7
6.0


0.75
7.3
0.75
3.0
0.75
6.3
0.75
5.8


0.8
7.0
0.8
2.8
0.8
6.0
0.8
5.5


0.05
6.4
0.85
2.6
0.85
5.5
0.85
5.1


0.9
5.4
0.9
2.3
0.9
4.7
0.9
4.3


0.95
3.7
0.95
1.8
0.95
3.3
0.95
3.1


1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F1234zeE +
0.05 F1234zeE +
0.05 F1234zeE +
0.4 F1234zeE +


0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
4.8
0
2.2
0
5.6
0
4.3


0.05
5.7
0.05
3.3
0.05
6.6
0.05
5.3


0.1
5.8
0.1
3.3
0.1
6.6
0.1
5.3


0.15
5.8
0.15
3.3
0.15
6.6
0.15
5.3


0.2
5.7
0.2
3.3
0.2
6.6
0.2
5.3


0.25
5.7
0.25
3.3
0.25
6.6
0.25
5.3


0.3
5.7
0.3
3.3
0.3
6.6
0.3
5.3


0.35
5.7
0.35
3.3
0.35
6.6
0.35
5.3


0.4
5.7
0.4
3.3
0.4
6.6
0.4
5.3


0.45
5.7
0.45
3.3
0.45
6.6
0.45
5.3


0.5
5.7
0.5
3.3
0.5
6.6
0.5
5.3


0.55
5.7
0.55
3.3
0.55
6.5
0.55
5.3


0.6
5.6
0.6
3.3
0.6
6.5
0.6
5.3


0.65
5.5
0.65
3.3
0.65
6.5
0.65
5.2


0.7
5.3
0.7
3.3
0.7
6.4
0.7
5.1


0.75
5.1
0.75
3.2
0.75
6.2
0.75
4.9


0.8
4.8
0.8
3.1
0.8
5.9
0.8
4.6


0.85
4.3
0.85
2.8
0.85
5.4
0.85
4.2


0.9
3.6
0.9
2.5
0.9
4.6
0.9
3.6


0.95
2.6
0.95
2.0
0.95
3.3
0.95
2.6


1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFO-1234zeE-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F1234yf +
0.05 F1234yf +
0.05 F1234yf +
0.4 F1234yf +


0.05 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +
0.3 F1234zeE +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
6.7
0
5.0
0
5.8
0
5.9


0.05
7.6
0.05
6.0
0.05
6.8
0.05
6.9


0.1
7.6
0.1
6.0
0.1
6.8
0.1
6.9


0.15
7.6
0.15
6.0
0.15
6.8
0.15
6.9


0.2
7.6
0.2
6.0
0.2
6.8
0.2
6.9


0.25
7.5
0.25
6.0
0.25
6.8
0.25
6.9


0.3
7.6
0.3
6.0
0.3
6.8
0.3
6.9


0.35
7.6
0.35
6.0
0.35
6.8
0.35
6.9


0.4
7.6
0.4
6.0
0.4
6.8
0.4
6.9


0.45
7.6
0.45
6.0
0.45
6.8
0.45
6.9


0.5
7.6
0.5
6.0
0.5
6.8
0.5
6.9


0.55
7.6
0.55
5.9
0.55
6.8
0.55
6.9


0.6
7.6
0.6
5.8
0.6
6.7
0.5
6.9


0.65
7.6
0.65
5.7
0.65
6.7
0.65
6.8


0.7
7.6
0.7
5.6
0.7
6.6
0.7
6.7


0.75
7.4
0.75
5.4
0.75
6.4
0.75
6.5


0.8
7.1
0.8
5.0
0.8
6.1
0.8
6.2


0.85
6.5
0.85
4.5
0.85
5.6
0.85
5.7


0.9
5.5
0.9
3.8
0.9
4.8
0.9
4.8


0.95
3.8
0.95
2.7
0.95
3.4
0.95
3.3


1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFO-1234zeZ-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F1234yf +
0.05 F1234yf +
0.05 F1234yf +
0.4 F1234yf +


0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
6.5
0
2.3
0
5.7
0
5.0


0.05
7.5
0.05
3.4
0.05
6.7
0.05
6.0


0.1
7.5
0.1
3.4
0.1
6.7
0.1
6.1


0.15
7.5
0.15
3.4
0.15
6.7
0.15
6.1


0.2
7.4
0.2
3.4
0.2
6.7
0.2
6.1


0.25
7.4
0.25
3.4
0.25
6.7
0.25
6.1


0.3
7.4
0.3
3.4
0.3
6.7
0.3
6.1


0.35
7.5
0.35
3.4
0.35
6.7
0.35
6.1


0.4
7.5
0.4
3.4
0.4
6.7
0.4
6.1


0.45
7.5
0.45
3.4
0.45
6.7
0.45
6.1


0.5
7.5
0.5
3.4
0.5
6.7
0.5
6.1


0.55
7.5
0.55
3.4
0.55
6.6
0.55
6.1


0.6
7.5
0.6
3.4
0.6
6.6
0.6
6.1


0.65
7.5
0.65
3.4
0.65
6.6
0.55
6.1


0.7
7.4
0.7
3.4
0.7
6.5
0.7
6.0


0.75
7.3
0.75
3.3
0.75
6.3
0.75
5.9


0.8
7.0
0.8
3.2
0.8
6.0
0.8
5.6


0.85
6.4
0.85
3.0
0.85
5.5
0.85
5.1


0.9
5.4
0.9
2.6
0.9
4.7
0.9
4.4


0.95
3.7
0.95
2.0
0.95
3.3
0.95
3.1


1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFO-1243zf-HFC-245cb















Organics
Organics
Organics
Organics


0.9 F1234yf +
0.4 F1234yf +
0.05 F1234yf +
0.05 F1234yf +


0.05 F1243zf +
0.3 F1243zf +
0.9 F1243zf +
0.05 F1243zf +


0.05 F245cb
0.3 F245cb
0.05 F245cb
0.9 F245cb















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
6.7
0
5.9
0
5.8
0
4.9


0.05
7.6
0.05
6.9
0.05
6.8
0.05
6.0


0.1
7.6
0.1
7.0
0.1
6.8
0.1
6.0


0.15
7.6
0.15
6.9
0.15
6.8
0.15
6.0


0.2
7.6
0.2
6.9
0.2
6.8
0.2
6.0


0.25
7.6
0.25
6.9
0.25
6.8
0.25
6.0


0.3
7.6
0.3
6.9
0.3
6.8
0.3
6.0


0.35
7.6
0.35
6.9
0.35
6.8
0.35
6.0


0.4
7.6
0.4
6.9
0.4
6.8
0.4
6.0


0.45
7.6
0.45
6.9
0.45
6.8
0.45
6.0


0.5
7.6
0.5
6.9
0.5
6.8
0.5
6.0


0.55
7.6
0.55
6.9
0.55
6.8
0.55
6.0


0.6
7.6
0.6
6.9
0.6
6.8
0.6
6.0


0.65
7.6
0.65
6.9
0.65
6.7
0.65
6.0


0.7
7.6
0.7
6.9
0.7
6.6
0.7
6.0


0.75
7.5
0.75
6.9
0.75
6.5
0.75
6.0


0.8
7.2
0.8
6.6
0.8
6.2
0.8
6.0


0.85
6.6
0.85
6.1
0.85
5.7
0.85
5.9


0.9
5.5
0.9
5.2
0.9
4.8
0.9
5.1


0.95
3.8
0.95
3.6
0.95
3.4
0.95
3.6


1
1.2
1
1.2
1
1.2
1
1.2









HF-HFC-245th-HFO-1234zeE-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F245cb +
0.05 F245cb +
0.05 F245cb +
0.4 F245cb +


0.05 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +
0.3 F1234zeE +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
4.8
0
4.9
0
5.8
0
5.2


0.05
5.9
0.05
5.9
0.05
6.7
0.05
6.2


0.1
5.9
0.1
5.9
0.1
6.7
0.1
6.2


0.15
5.9
0.15
5.9
0.15
6.7
0.15
6.2


0.2
5.9
0.2
5.9
0.2
6.7
0.2
6.2


0.25
5.9
0.25
5.9
0.25
6.7
0.25
6.2


0.3
5.9
0.3
5.9
0.3
6.7
0.3
6.2


0.35
5.9
0.35
5.9
0.35
6.7
0.35
6.2


0.4
5.9
0.4
5.9
0.4
6.7
0.4
6.2


0.45
5.9
0.45
5.9
0.45
6.7
0.45
6.2


0.5
5.9
0.5
5.9
0.5
6.7
0.5
6.2


0.55
5.9
0.55
5.8
0.55
6.7
0.55
6.2


0.6
5.9
0.6
5.8
0.6
6.7
0.6
6.2


0.05
5.9
0.65
5.7
0.65
6.6
0.65
6.2


0.7
5.9
0.7
5.5
0.7
6.5
0.7
6.2


0.75
5.9
0.75
5.3
0.75
6.4
0.75
6.1


0.8
5.9
0.8
5.0
0.8
6.1
0.8
5.8


0.85
5.8
0.85
4.5
0.85
5.6
0.85
5.3


0.9
5.0
0.9
3.7
0.9
4.7
0.9
4.5


0.95
3.5
0.95
2.7
0.95
3.4
0.95
3.2


1
1.2
1
1.2
1
1.2
1
1.2









HF-HFC-245cb-HFO-1234zeZ-HFO-1243zf















Organics
Organics
Organics
Organics


0.9 F245cb +
0.05 F245cb +
0.05 F245cb +
0.4 F245cb +


0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +


0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf















TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar

















0
4.6
0
2.2
0
5.6
0
4.2


0.05
5.7
0.05
3.3
0.05
6.6
0.05
5.3


0.1
5.7
0.1
3.3
0.1
6.6
0.1
5.3


0.15
5.7
0.15
3.3
0.15
6.6
0.15
5.3


0.2
5.7
0.2
3.3
0.2
6.6
0.2
5.3


0.25
5.7
0.25
3.3
0.25
6.6
0.25
5.3


0.3
5.7
0.3
3.3
0.3
6.6
0.3
5.3


0.35
5.7
0.35
3.3
0.35
6.6
0.35
5.3


0.4
5.7
0.4
3.3
0.4
6.6
0.4
5.3


0.45
5.7
0.45
3.3
0.45
6.6
0.45
5.3


0.5
5.7
0.5
3.3
0.5
6.6
0.5
5.3


0.55
5.7
0.55
3.3
0.55
6.6
0.55
5.3


0.6
5.8
0.6
3.3
0.6
6.5
0.6
5.3


0.65
5.8
0.65
3.3
0.65
6.5
0.65
5.3


0.7
5.8
0.7
3.3
0.7
6.4
0.7
5.4


0.75
5.8
0.75
3.3
0.75
6.3
0.75
5.4


0.8
5.8
0.8
3.1
0.8
6.0
0.8
5.2


0.85
5.7
0.85
2.9
0.85
5.5
0.85
4.8


0.9
4.9
0.9
2.6
0.9
4.7
0.9
4.1


0.95
3.5
0.95
2.0
0.95
3.3
0.95
3.0


1
1.2
1
1.2
1
1.2
1
1.2









EXAMPLE 5
Temperature and Pressure Range of Quaternary Mixtures














Boiling point range










Temperature
Pressure


Quaternary
° C.
bar abs





HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.2 to ~10.1


1243zf




HF-HFO-1234yf-HFC-245cb-HFO-
0 to 40
~2.5 to ~11.6


1243zf




HF-HCFO-1233xf-HFO-1234yf-
0 to 40
~1.3 to ~11.3


HFO-1243zf




HF-HCFO-1233xf-HCFO-1233zdE-
0 to 40
~1.0 to ~9.9 


HFO-1243zf




HF-HCFO-1233xf-HFO-1234zeE-
0 to 40
~1.2 to ~10.1


HFO-1243zf




HF-HCFO-1233xf-HFO-1234zeZ-
0 to 40
~1.1 to ~9.9 


HFO-1243zf




HF-HFO-1234yf-HFO-1234zeE-
0 to 40
~3.0 to ~11.6


HFO-1243zf




HF-HFO-1234yf-HFO-1234zeZ-
0 to 40
~1.3 to ~11.3


HFO-1243zf




HF-HFC-245cb-HCFO-1233zdE-
0 to 40
~1.1 to ~10.1


HFO-1243zf




HF-HFC-245cb-HFO-1234zeE-
0 to 40
~2.5 to ~10.3


HFO-1243zf




HF-HFC-245cb-HFO-1234zeZ-HFO-
0 to 40
~1.3 to ~10.1


1243zf




HF-HCFO-1233zdE-HFO-1234zeE-
0 to 40
~1.1 to ~10.1


HFO-1243zf




HF-HCFO-1233zdE-HFO-1234zeZ-
0 to 40
~1.0 to ~9.9 


HFO-1243zf




HF-HFO-1234zeE-HFO-1234zeZ-
0 to 40
~1.3 to ~10.1


HFO-1243zf




HF-HFO-1234yf-HCFO-1233zdE-
0 to 40
~1.2 to ~11.3


HFO-1243zf











EXAMPLE 6
Decantation Range of Quaternary Mixtures














Decantation ranges



Mass percentage of HF











Isotherm
Isotherm
Isotherm


Quaternary
0° C.
25° C.
40° C.





HF-HCFO-1233xf-HFC-245cb-HFO-
5-75
 5-70
15-60


1243zf





HF-HFO-1234yf-HFC-245cb-HFO-1243zf
5-75
15-70
45-70


HF-HCFO-1233xf-HFO-1234yf-HFO-
5-75
10-65
*


1243zf





HF-HCFO-1233xf-HCFO-1233zdE-HFO-
5-75
 5-70
10-60


1243zf





HF-HCFO-1233xf-HFO-1234zeE-HFO-
5-70
10-60
*


1243zf





HF-HCFO-1233xf-HFO-1234zeZ-HFO-
5-75
 5-70
10-55


1243zf





HF-HFO-1234yf-HFO-1234zeE-HFO-
5-65
*
*


1243zf





HF-HFO-1234yf-HFO-1234zeZ-HFO-
5-75
10-65
*


1243zf





HF-HFC-245cb-HCFO-1233zdE-HFO-
5-75
 5-70
15-65


1243zf





HF-HFC-245cb-HFO-1234zeE-HFO-
5-75
15-65
*


1243zf





HF-HFC-245cb-HFO-1234zeZ-HFO-
5-75
10-70
20-60


1243zf





HF-HCFO-1233zdE-HFO-1234zeE-HFO-
5-70
10-60
*


1243zf





HF-HCFO-1233zdE-HFO-1234zeZ-HFO-
5-75
 5-70
10-55


1243zf





HF-HFO-1234zeE-HFO-1234zeZ-HFO-
5-70
10-60
*


1243zf





HF-HFO-1234yf-HCFO-1233zdE-HFO-
5-75
10-65
*


1243zf









EXAMPLE 7
Penternary Mixtures, Isotherm at 25° C.

HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
1.8
0
1.6
0
4.5
0
5.6
0
3.5


0.05
3.0
0.05
2.8
0.05
5.7
0.05
6.5
0.05
4.6


0.1
3.0
0.1
2.8
0.1
5.7
0.1
6.6
0.1
4.6


0.15
3.0
0.15
2.8
0.15
5.7
0.15
6.6
0.15
4.6


0.2
3.0
0.2
2.8
0.2
5.7
0.2
6.5
0.2
4.6


0.25
3.0
0.25
2.8
0.25
5.7
0.25
6.5
0.25
4.6


0.3
3.0
0.3
2.8
0.3
5.7
0.3
6.5
0.3
4.6


0.35
2.9
0.35
2.8
0.35
5.7
0.35
6.5
0.35
4.6


0.4
2.9
0.4
2.8
0.4
5.7
0.4
6.5
0.4
4.6


0.45
2.9
0.45
2.7
0.45
5.7
0.45
6.5
0.45
4.6


0.5
2.9
0.5
2.7
0.5
5.7
0.5
6.5
0.5
4.6


0.55
2.9
0.55
2.7
0.55
5.7
0.55
6.5
0.55
4.6


0.6
2.9
0.6
2.7
0.6
5.7
0.6
6.5
0.6
4.6


0.65
2.9
0.65
2.7
0.65
5.7
0.65
6.4
0.65
4.6


0.7
2.9
0.7
2.7
0.7
5.7
0.7
6.4
0.7
4.7


0.75
2.9
0.75
2.7
0.75
5.7
0.75
6.2
0.75
4.6


0.8
2.8
0.8
2.6
0.8
5.7
0.8
5.9
0.8
4.4


0.85
2.6
0.85
2.4
0.85
5.6
0.85
5.4
0.85
4.1


0.9
2.3
0.9
2.2
0.9
4.8
0.9
4.6
0.9
3.5


0.95
1.8
0.95
1.8
0.95
3.4
0.95
3.3
0.95
2.6


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
2.0
0
4.8
0
4.6
0
5.7
0
4.4


0.05
3.1
0.05
5.8
0.05
5.8
0.05
6.6
0.05
5.4


0.1
3.1
0.1
5.8
0.1
5.8
0.1
6.7
0.1
5.4


0.15
3.1
0.15
5.8
0.15
5.8
0.15
6.6
0.15
5.4


0.2
3.1
0.2
5.8
0.2
5.8
0.2
6.6
0.2
5.4


0.25
3.1
0.25
5.8
0.25
5.8
0.25
6.6
0.25
5.4


0.3
3.1
0.3
5.8
0.3
5.8
0.3
6.6
0.3
5.4


0.35
3.1
0.35
5.8
0.35
5.8
0.35
6.6
0.35
5.4


0.4
3.1
0.4
5.8
0.4
5.8
0.4
6.6
0.4
5.4


0.45
3.1
0.45
5.8
0.45
5.8
0.45
6.6
0.45
5.4


0.5
3.1
0.5
5.7
0.5
5.8
0.5
6.6
0.5
5.4


0.55
3.1
0.55
5.7
0.55
5.8
0.55
6.6
0.55
5.4


0.6
3.1
0.6
5.6
0.6
5.8
0.6
6.6
0.6
5.4


0.65
3.1
0.65
5.5
0.65
5.8
0.65
6.5
0.65
5.4


0.7
3.1
0.7
5.4
0.7
5.8
0.7
6.4
0.7
5.4


0.75
3.0
0.75
5.2
0.75
5.8
0.75
6.3
0.75
5.3


0.8
2.9
0.8
4.8
0.8
5.8
0.8
6.0
0.8
5.0


0.85
2.7
0.85
4.3
0.85
5.7
0.85
5.5
0.85
4.6


0.9
2.3
0.9
3.6
0.9
4.9
0.9
4.7
0.9
3.9


0.95
1.9
0.95
2.6
0.95
3.5
0.95
3.3
0.95
2.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
1.9
0
2.1
0
4.5
0
5.6
0
3.6


0.05
3.0
0.05
3.2
0.05
5.7
0.05
6.5
0.05
4.7


0.1
3.0
0.1
3.2
0.1
5.7
0.1
6.6
0.1
4.7


0.15
3.0
0.15
3.2
0.15
5.7
0.15
6.6
0.15
4.7


0.2
3.0
0.2
3.2
0.2
5.7
0.2
6.6
0.2
4.7


0.25
3.0
0.25
3.2
0.25
5.7
0.25
6.5
0.25
4.7


0.3
3.0
0.3
3.2
0.3
5.7
0.3
6.5
0.3
4.7


0.35
3.0
0.35
3.2
0.35
5.7
0.35
6.5
0.35
4.7


0.4
3.0
0.4
3.2
0.4
5.7
0.4
6.5
0.4
4.7


0.45
3.0
0.45
3.2
0.45
5.7
0.45
6.5
0.45
4.7


0.5
3.0
0.5
3.2
0.5
5.7
0.5
6.5
0.5
4.7


0.55
3.0
0.55
3.2
0.55
5.7
0.55
6.5
0.55
4.7


0.6
3.0
0.6
3.2
0.6
5.7
0.6
6.5
0.6
4.7


0.65
3.0
0.65
3.2
0.65
5.7
0.65
6.5
0.65
4.7


0.7
3.0
0.7
3.2
0.7
5.7
0.7
6.4
0.7
4.7


0.75
3.0
0.75
3.2
0.75
5.7
0.75
6.2
0.75
4.7


0.8
2.8
0.8
3.0
0.8
5.7
0.8
5.9
0.8
4.5


0.85
2.6
0.85
2.8
0.85
5.6
0.85
5.4
0.85
4.2


0.9
2.3
0.9
2.5
0.9
4.8
0.9
4.6
0.9
3.6


0.95
1.8
0.95
1.9
0.95
3.4
0.95
3.3
0.95
2.6


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 1234zeE +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
1.9
0
4.7
0
1.7
0
5.6
0
3.6


0.05
3.0
0.05
5.7
0.05
2.8
0.05
6.5
0.05
4.7


0.1
3.0
0.1
5.7
0.1
2.8
0.1
6.6
0.1
4.7


0.15
3.0
0.15
5.7
0.15
2.8
0.15
6.6
0.15
4.7


0.2
3.0
0.2
5.7
0.2
2.8
0.2
6.5
0.2
4.7


0.25
3.0
0.25
5.7
0.25
2.8
0.25
6.5
0.25
4.6


0.3
2.9
0.3
5.7
0.3
2.7
0.3
6.5
0.3
4.6


0.35
2.9
0.35
5.7
0.35
2.7
0.35
6.5
0.35
4.6


0.4
2.9
0.4
5.7
0.4
2.7
0.4
6.5
0.4
4.6


0.45
2.9
0.45
5.7
0.45
2.7
0.45
6.5
0.45
4.6


0.5
2.9
0.5
5.6
0.5
2.7
0.5
6.5
0.5
4.6


0.55
2.9
0.55
5.6
0.55
2.7
0.55
6.5
0.55
4.6


0.6
2.9
0.6
5.5
0.6
2.7
0.6
6.5
0.6
4.6


0.65
2.9
0.65
5.4
0.65
2.7
0.65
6.4
0.65
4.5


0.7
2.9
0.7
5.3
0.7
2.7
0.7
6.3
0.7
4.5


0.75
2.9
0.75
5.0
0.75
2.7
0.75
6.2
0.75
4.3


0.8
2.7
0.8
4.7
0.8
2.6
0.8
5.9
0.8
4.1


0.85
2.5
0.85
4.2
0.85
2.4
0.85
5.4
0.85
3.7


0.9
2.2
0.9
3.5
0.9
2.1
0.9
4.6
0.9
3.1


0.95
1.8
0.95
2.5
0.95
1.7
0.95
3.3
0.95
2.3


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
1.7
0
1.9
0
1.5
0
5.5
0
2.8


0.05
2.8
0.05
3.0
0.05
2.6
0.05
6.4
0.05
3.9


0.1
2.8
0.1
3.0
0.1
2.6
0.1
6.5
0.1
3.9


0.15
2.8
0.15
3.0
0.15
2.6
0.15
6.5
0.15
3.9


0.2
2.8
0.2
3.0
0.2
2.6
0.2
6.5
0.2
3.9


0.25
2.8
0.25
3.0
0.25
2.6
0.25
6.5
0.25
3.9


0.3
2.8
0.3
3.0
0.3
2.6
0.3
6.5
0.3
3.9


0.35
2.8
0.35
3.0
0.35
2.6
0.35
6.5
0.35
3.9


0.4
2.8
0.4
3.0
0.4
2.6
0.4
6.5
0.4
3.9


0.45
2.8
0.45
3.0
0.45
2.6
0.45
6.4
0.45
3.9


0.5
2.8
0.5
3.0
0.5
2.6
0.5
6.4
0.5
3.9


0.55
2.8
0.55
3.0
0.55
2.6
0.55
6.4
0.55
3.9


0.6
2.8
0.6
3.0
0.6
2.6
0.6
6.4
0.6
3.9


0.65
2.8
0.65
3.0
0.65
2.6
0.65
6.4
0.65
3.8


0.7
2.8
0.7
3.0
0.7
2.6
0.7
6.3
0.7
3.8


0.75
2.8
0.75
3.0
0.75
2.6
0.75
6.1
0.75
3.7


0.8
2.7
0.8
2.9
0.8
2.5
0.8
5.8
0.8
3.6


0.85
2.5
0.85
2.7
0.85
2.3
0.85
5.3
0.85
3.3


0.9
2.2
0.9
2.4
0.9
2.1
0.9
4.5
0.9
2.8


0.95
1.8
0.95
1.9
0.95
1.7
0.95
3.2
0.95
2.2


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F1234zeZ +
0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
1.9
0
4.7
0
2.1
0
5.6
0
3.7


0.05
3.0
0.05
5.7
0.05
3.2
0.05
6.5
0.05
4.7


0.1
3.0
0.1
5.7
0.1
3.2
0.1
6.6
0.1
4.7


0.15
3.0
0.15
5.7
0.15
3.2
0.15
6.6
0.15
4.7


0.2
3.0
0.2
5.7
0.2
3.2
0.2
6.5
0.2
4.7


0.25
3.0
0.25
5.7
0.25
3.2
0.25
6.5
0.25
4.7


0.3
3.0
0.3
5.7
0.3
3.2
0.3
6.5
0.3
4.7


0.35
3.0
0.35
5.7
0.35
3.2
0.35
6.5
0.35
4.7


0.4
3.0
0.4
5.7
0.4
3.2
0.4
6.5
0.4
4.7


0.45
3.0
0.45
5.7
0.45
3.2
0.45
6.5
0.45
4.7


0.5
3.0
0.5
5.6
0.5
3.2
0.5
6.5
0.5
4.7


0.55
2.9
0.55
5.6
0.55
3.1
0.55
6.5
0.55
4.6


0.6
2.9
0.6
5.5
0.6
3.1
0.6
6.5
0.6
4.6


0.65
2.9
0.65
5.4
0.65
3.1
0.65
6.4
0.65
4.6


0.7
2.9
0.7
5.3
0.7
3.1
0.7
6.3
0.7
4.5


0.75
2.9
0.75
5.0
0.75
3.1
0.75
6.2
0.75
4.4


0.8
2.8
0.8
4.7
0.8
3.0
0.8
5.9
0.8
4.1


0.85
2.6
0.85
4.2
0.85
2.7
0.85
5.4
0.85
3.8


0.0
2.2
0.9
3.5
0.9
2.1
0.9
4.6
0.9
3.2


0.95
1.8
0.95
2.5
0.95
1.9
0.95
3.3
0.95
2.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFC-245cb-HFO-1234yf-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234yf +
0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.25 F1234yf +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
2.0
0
6.5
0
4.7
0
5.7
0
4.8


0.05
3.2
0.05
7.5
0.05
5.8
0.05
6.7
0.05
5.9


0.1
3.2
0.1
7.5
0.1
5.9
0.1
6.7
0.1
5.9


0.15
3.2
0.15
7.5
0.15
5.9
0.15
6.7
0.15
5.9


0.2
3.2
0.2
7.5
0.2
5.9
0.2
6.7
0.2
5.9


0.25
3.2
0.25
7.5
0.25
5.9
0.25
6.7
0.25
5.9


0.3
3.2
0.3
7.5
0.3
5.9
0.3
6.7
0.3
5.9


0.35
3.2
0.35
7.5
0.35
5.9
0.35
6.7
0.35
5.9


0.4
3.2
0.4
7.5
0.4
5.9
0.4
6.7
0.4
5.9


0.45
3.2
0.45
7.5
0.45
5.9
0.45
6.7
0.45
5.9


0.5
3.1
0.5
7.5
0.5
5.9
0.5
6.7
0.5
5.9


0.55
3.1
0.55
7.5
0.55
5.9
0.55
6.7
0.55
5.9


0.6
3.1
0.6
7.5
0.6
5.9
0.6
6.6
0.6
5.9


0.65
3.1
0.65
7.5
0.65
5.9
0.65
6.6
0.65
5.9


0.7
3.1
0.7
7.5
0.7
5.9
0.7
6.5
0.7
5.9


0.75
3.1
0.75
7.4
0.75
5.9
0.75
6.3
0.75
5.9


0.8
3.0
0.8
7.0
0.8
5.9
0.8
6.1
0.8
5.6


0.85
2.7
0.85
6.5
0.85
5.8
0.85
5.6
0.85
5.2


0.9
2.4
0.9
5.4
0.9
5.0
0.9
4.7
0.9
4.4


0.95
1.9
0.95
3.8
0.95
3.5
0.95
3.4
0.95
3.1


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F1243zf +
0.033 F1243zf +
0.9 F1243zf +
0.033 F1243zf +
0.25 F1243zf +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
2.1
0
4.9
0
5.7
0
6.5
0
4.9


0.05
3.2
0.05
5.8
0.05
6.7
0.05
7.5
0.05
5.9


0.1
3.2
0.1
5.9
0.1
6.7
0.1
7.5
0.1
5.9


0.15
3.2
0.15
5.9
0.15
6.7
0.15
7.5
0.15
5.9


0.2
3.2
0.2
5.9
0.2
6.7
0.2
7.5
0.2
5.9


0.25
3.2
0.25
5.9
0.25
6.7
0.25
7.5
0.25
5.9


0.3
3.2
0.3
5.9
0.3
6.7
0.3
7.5
0.3
5.9


0.35
3.2
0.35
5.9
0.35
6.7
0.35
7.5
0.35
5.9


0.4
3.1
0.4
5.8
0.4
6.7
0.4
7.5
0.4
5.9


0.45
3.1
0.45
5.8
0.45
6.7
0.45
7.5
0.45
5.9


0.5
3.1
0.5
5.8
0.5
6.7
0.5
7.5
0.5
5.9


0.55
3.1
0.55
5.8
0.55
6.7
0.55
7.5
0.55
5.9


0.6
3.1
0.6
5.7
0.6
6.6
0.6
7.5
0.6
5.9


0.65
3.1
0.65
5.6
0.65
6.6
0.65
7.5
0.65
5.8


0.7
3.1
0.7
5.4
0.7
6.5
0.7
7.5
0.7
5.7


0.75
3.1
0.75
5.2
0.75
6.3
0.75
7.3
0.75
5.6


0.8
2.9
0.8
4.9
0.8
6.0
0.8
7.0
0.8
5.3


0.85
2.7
0.85
4.4
0.85
5.5
0.85
6.4
0.85
4.8


0.9
2.4
0.9
3.6
0.9
4.7
0.9
5.4
0.9
4.0


0.95
1.9
0.95
2.6
0.95
3.3
0.95
3.7
0.95
2.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F1243zf +
0.033 F1243zf +
0.9 F1243zf +
0.033 F1243zf +
0.25 F1243zf +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
1.9
0
2.1
0
5.6
0
6.4
0
4.1


0.05
3.1
0.05
3.2
0.05
6.6
0.05
7.4
0.05
5.2


0.1
3.1
0.1
3.2
0.1
6.6
0.1
7.4
0.1
5.2


0.15
3.1
0.15
3.2
0.15
6.6
0.15
7.4
0.15
5.2


0.2
3.1
0.2
3.2
0.2
6.6
0.2
7.4
0.2
5.2


0.25
3.1
0.25
3.2
0.25
6.6
0.25
7.4
0.25
5.2


0.3
3.1
0.3
3.2
0.3
6.6
0.3
7.4
0.3
5.2


0.35
3.0
0.35
3.2
0.35
6.6
0.35
7.4
0.35
5.2


0.4
3.0
0.4
3.2
0.4
6.6
0.4
7.4
0.4
5.2


0.45
3.0
0.45
3.2
0.45
6.6
0.45
7.4
0.45
5.2


0.5
3.0
0.5
3.2
0.5
6.6
0.5
7.4
0.5
5.2


0.55
3.0
0.55
3.2
0.55
6.6
0.55
7.4
0.55
5.2


0.5
3.0
0.6
3.2
0.6
6.5
0.6
7.4
0.6
5.2


0.65
3.0
0.65
3.2
0.65
6.5
0.65
7.4
0.65
5.2


0.7
3.0
0.7
3.2
0.7
6.4
0.7
7.4
0.7
5.1


0.75
3.0
0.75
3.2
0.75
6.2
0.75
7.2
0.75
5.0


0.8
2.9
0.8
3.1
0.8
6.0
0.8
6.9
0.8
4.8


0.85
2.6
0.85
2.8
0.85
5.5
0.85
6.3
0.85
4.4


0.9
2.3
0.9
2.5
0.9
4.6
0.9
5.3
0.9
3.7


0.95
1.8
0.95
2.0
0.95
3.3
0.95
3.7
0.95
2.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +


0.033 F1243zf +
0.9 F1243zf +
0.033 F1243zf +
0.033 F1243zf +
0.25 F1243zf +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
1.9
0
5.6
0
1.7
0
6.4
0
4.1


0.05
3.0
0.05
6.6
0.05
2.8
0.05
7.4
0.05
5.2


0.1
3.0
0.1
6.6
0.1
2.8
0.1
7.4
0.1
5.2


0.15
3.0
0.15
6.6
0.15
2.8
0.15
7.4
0.15
5.2


0.2
3.0
0.2
6.6
0.2
2.8
0.2
7.4
0.2
5.2


0.25
3.0
0.25
6.6
0.25
2.8
0.25
7.4
0.25
5.2


0.3
3.0
0.3
6.6
0.3
2.8
0.3
7.4
0.3
5.2


0.35
3.0
0.35
6.6
0.35
2.8
0.35
7.4
0.35
5.2


0.4
3.0
0.4
6.6
0.4
2.8
0.4
7.4
0.4
5.2


0.45
3.0
0.45
6.6
0.45
2.8
0.45
7.4
0.45
5.2


0.5
3.0
0.5
6.6
0.5
2.8
0.5
7.4
0.5
5.1


0.55
3.0
0.55
6.6
0.55
2.8
0.55
7.4
0.55
5.1


0.6
3.0
0.6
6.5
0.6
2.8
0.6
7.4
0.6
5.1


0.65
3.0
0.65
6.5
0.65
2.8
0.65
7.4
0.65
5.1


0.7
3.0
0.7
6.4
0.7
2.8
0.7
7.4
0.7
5.1


0.75
3.0
0.75
6.2
0.75
2.8
0.75
7.2
0.75
4.9


0.8
2.8
0.8
6.0
0.8
2.7
0.8
6.9
0.8
4.7


0.85
2.6
0.85
5.5
0.85
2.5
0.85
6.3
0.85
4.3


0.9
2.3
0.9
4.6
0.9
2.2
0.9
5.3
0.9
3.7


0.95
1.8
0.95
3.3
0.95
1.8
0.95
3.7
0.95
2.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F1234zeE +
0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
6.5
0
2.2
0
4.9
0
5.7
0
4.9


0.05
7.5
0.05
3.3
0.05
5.8
0.05
6.7
0.05
5.9


0.1
7.5
0.1
3.3
0.1
5.9
0.1
6.7
0.1
5.9


0.15
7.5
0.15
3.3
0.15
5.8
0.15
6.7
0.15
5.9


0.2
7.5
0.2
3.3
0.2
5.8
0.2
6.7
0.2
5.9


0.25
7.5
0.25
3.3
0.25
5.8
0.25
6.7
0.25
5.9


0.3
7.5
0.3
3.3
0.3
5.8
0.3
6.7
0.3
5.9


0.35
7.5
0.35
3.3
0.35
5.8
0.35
6.7
0.35
5.9


0.4
7.5
0.4
3.3
0.4
5.8
0.4
6.7
0.4
5.9


0.45
7.5
0.45
3.3
0.45
5.8
0.45
6.7
0.45
5.9


0.5
7.5
0.5
3.3
0.5
5.8
0.5
6.7
0.5
5.9


0.55
7.5
0.55
3.3
0.55
5.8
0.55
6.7
0.55
5.9


0.6
7.5
0.6
3.3
0.6
5.7
0.6
6.6
0.6
5.9


0.65
7.5
0.65
3.3
0.65
5.6
0.65
6.6
0.65
5.8


0.7
7.5
0.7
3.3
0.7
5.4
0.7
6.5
0.7
5.7


0.75
7.3
0.75
3.3
0.75
5.2
0.75
6.3
0.75
5.6


0.8
7.0
0.8
3.1
0.8
4.9
0.8
6.0
0.8
5.3


0.85
6.4
0.85
2.9
0.85
4.4
0.85
5.6
0.85
4.8


0.9
5.4
0.9
2.5
0.9
3.7
0.9
4.7
0.9
4.1


0.95
3.7
0.95
2.0
0.95
2.6
0.95
3.3
0.95
2.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +


0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.033 F1234zeE +
0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
6.5
0
1.9
0
4.9
0
5.7
0
4.8


0.05
7.5
0.05
3.0
0.05
5.8
0.05
6.7
0.05
5.8


0.1
7.5
0.1
3.0
0.1
5.9
0.1
6.7
0.1
5.9


0.15
7.5
0.15
3.0
0.15
5.8
0.15
6.7
0.15
5.9


0.2
7.5
0.2
3.0
0.2
5.8
0.2
6.7
0.2
5.9


0.25
7.5
0.25
3.0
0.25
5.8
0.25
6.7
0.25
5.9


0.3
7.5
0.3
3.0
0.3
5.8
0.3
6.7
0.3
5.9


0.35
7.5
0.35
2.9
0.35
5.8
0.35
6.7
0.35
5.9


0.4
7.5
0.4
2.9
0.4
5.8
0.4
6.7
0.4
5.9


0.45
7.5
0.45
2.9
0.45
5.8
0.45
6.7
0.45
5.9


0.5
7.5
0.5
2.9
0.5
5.8
0.5
6.7
0.5
5.8


0.55
7.5
0.55
2.9
0.55
5.8
0.55
6.6
0.55
5.8


0.6
7.5
0.6
2.9
0.6
5.7
0.6
6.6
0.6
5.8


0.65
7.5
0.65
2.9
0.65
5.6
0.65
6.6
0.65
5.8


0.7
7.5
0.7
2.9
0.7
5.4
0.7
6.5
0.7
5.7


0.75
7.3
0.75
2.9
0.75
5.2
0.75
6.3
0.75
5.5


0.8
7.0
0.8
2.7
0.8
4.9
0.8
6.0
0.8
5.2


0.85
6.4
0.85
2.5
0.85
4.4
0.85
5.5
0.85
4.8


0.9
5.4
0.9
2.2
0.9
3.6
0.9
4.7
0.9
4.0


0.95
3.7
0.95
1.8
0.95
2.6
0.95
3.3
0.95
2.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +


0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.033 F1234zeZ +
0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
6.4
0
1.7
0
2.1
0
5.6
0
4.1


0.05
7.4
0.05
2.9
0.05
3.2
0.05
6.6
0.05
5.2


0.1
7.4
0.1
2.9
0.1
3.2
0.1
6.6
0.1
5.2


0.15
7.4
0.15
2.9
0.15
3.2
0.15
6.6
0.15
5.2


0.2
7.4
0.2
2.9
0.2
3.2
0.2
6.6
0.2
5.2


0.25
7.4
0.25
2.8
0.25
3.2
0.25
6.6
0.25
5.2


0.3
7.4
0.3
2.8
0.3
3.2
0.3
6.6
0.3
5.2


0.35
7.4
0.35
2.8
0.35
3.2
0.35
6.6
0.35
5.1


0.4
7.4
0.4
2.8
0.4
3.2
0.4
6.6
0.4
5.1


0.45
7.4
0.45
2.8
0.45
3.2
0.45
6.6
0.45
5.1


0.5
7.4
0.5
2.8
0.5
3.2
0.5
6.6
0.5
5.1


0.55
7.4
0.55
2.8
0.55
3.2
0.55
6.6
0.55
5.1


0.6
7.4
0.6
2.8
0.6
3.2
0.6
6.5
0.6
5.1


0.65
7.4
0.65
2.8
0.65
3.2
0.65
6.5
0.65
5.1


0.7
7.4
0.7
2.8
0.7
3.2
0.7
6.4
0.7
5.1


0.75
7.2
0.75
2.8
0.75
3.2
0.75
6.2
0.75
5.0


0.8
6.9
0.8
2.7
0.8
3.0
0.8
5.9
0.8
4.7


0.85
6.3
0.85
2.5
0.85
2.8
0.85
5.5
0.85
4.3


0.9
5.3
0.9
2.2
0.9
2.5
0.9
4.6
0.9
3.7


0.95
3.7
0.95
1.8
0.95
2.0
0.95
3.3
0.95
2.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F245cb +
0.033 F245cb +
0.09 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.09 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
6.6
0
5.0
0
4.8
0
5.8
0
5.6


0.05
7.6
0.05
5.9
0.05
6.0
0.05
6.8
0.05
6.6


0.1
7.6
0.1
6.0
0.1
6.0
0.1
6.8
0.1
6.6


0.15
7.6
0.15
6.0
0.15
6.0
0.15
6.8
0.15
6.6


0.2
7.6
0.2
6.0
0.2
6.0
0.2
6.8
0.2
6.6


0.25
7.6
0.25
6.0
0.25
6.0
0.25
6.8
0.25
6.6


0.3
7.6
0.3
6.0
0.3
6.0
0.3
6.8
0.3
6.6


0.35
7.6
0.35
6.0
0.35
6.0
0.35
6.8
0.35
6.6


0.4
7.6
0.4
6.0
0.4
6.0
0.4
6.8
0.4
6.6


0.45
7.6
0.45
5.9
0.45
6.0
0.45
6.8
0.45
6.6


0.5
7.6
0.5
5.9
0.5
6.0
0.5
6.8
0.5
6.6


0.55
7.6
0.55
5.9
0.55
6.0
0.55
6.7
0.55
6.6


0.6
7.6
0.6
5.8
0.6
6.0
0.6
6.7
0.6
6.6


0.65
7.6
0.65
5.7
0.65
5.9
0.65
6.7
0.65
6.6


0.7
7.6
0.7
5.6
0.7
5.9
0.7
6.6
0.7
6.6


0.75
7.4
0.75
5.3
0.75
5.9
0.75
6.4
0.75
6.4


0.8
7.1
0.8
5.0
0.8
5.9
0.8
6.1
0.8
6.1


0.85
6.5
0.85
4.5
0.85
5.8
0.85
5.6
0.85
5.6


0.9
5.5
0.9
3.7
0.9
5.0
0.9
4.8
0.9
4.8


0.95
3.8
0.95
2.7
0.95
3.5
0.95
3.4
0.95
3.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
6.5
0
2.2
0
4.7
0
5.7
0
4.8


0.05
7.5
0.05
3.3
0.05
5.8
0.05
6.7
0.05
5.9


0.1
7.5
0.1
3.3
0.1
5.8
0.1
6.7
0.1
5.9


0.15
7.5
0.15
3.3
0.15
5.8
0.15
6.7
0.15
5.9


0.2
7.5
0.2
3.3
0.2
5.8
0.2
6.7
0.2
5.9


0.25
7.5
0.25
3.3
0.25
5.8
0.25
6.7
0.25
5.9


0.3
7.5
0.3
3.3
0.3
5.8
0.3
6.7
0.3
5.9


0.35
7.5
0.35
3.3
0.35
5.8
0.35
6.7
0.35
5.9


0.4
7.5
0.4
3.3
0.4
5.8
0.4
6.7
0.4
5.9


0.45
7.5
0.45
3.3
0.45
5.8
0.45
6.7
0.45
5.9


0.5
7.5
0.5
3.3
0.5
5.8
0.5
6.7
0.5
5.9


0.55
7.5
0.55
3.3
0.55
5.8
0.55
6.7
0.55
5.9


0.6
7.5
0.6
3.3
0.6
5.8
0.6
6.6
0.6
5.9


0.65
7.5
0.65
3.3
0.65
5.8
0.65
6.6
0.65
5.9


0.7
7.5
0.7
3.3
0.7
5.9
0.7
6.5
0.7
5.9


0.75
7.3
0.75
3.3
0.75
5.9
0.75
6.3
0.75
5.9


0.8
7.0
0.8
3.2
0.8
5.9
0.8
6.1
0.8
5.6


0.85
6.5
0.85
2.9
0.85
5.8
0.85
5.6
0.85
5.2


0.9
5.4
0.9
2.6
0.9
5.0
0.9
4.7
0.9
4.4


0.95
3.8
0.95
2.0
0.95
3.5
0.95
3.4
0.95
3.2


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +


0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
6.5
0
1.8
0
4.7
0
5.7
0
4.8


0.05
7.5
0.05
2.9
0.05
5.8
0.05
6.7
0.05
5.9


0.1
7.5
0.1
2.9
0.1
5.8
0.1
6.7
0.1
5.9


0.15
7.5
0.15
2.9
0.15
5.8
0.15
6.7
0.15
5.9


0.2
7.5
0.2
2.9
0.2
5.8
0.2
6.7
0.2
5.9


0.25
7.5
0.25
2.9
0.25
5.8
0.25
6.7
0.25
5.9


0.3
7.5
0.3
2.9
0.3
5.8
0.3
6.7
0.3
5.9


0.35
7.5
0.35
2.9
0.35
5.8
0.35
6.7
0.35
5.9


0.4
7.5
0.4
2.9
0.4
5.8
0.4
6.7
0.4
5.9


0.45
7.5
0.45
2.9
0.45
5.8
0.45
6.7
0.45
5.9


0.5
7.5
0.5
2.9
0.5
5.8
0.5
6.7
0.5
5.9


0.55
7.5
0.55
2.9
0.55
5.8
0.55
6.7
0.55
5.9


0.6
7.5
0.6
2.9
0.6
5.8
0.6
6.6
0.6
5.9


0.65
7.5
0.65
2.9
0.65
5.8
0.55
6.6
0.65
5.9


0.7
7.5
0.7
2.9
0.7
5.8
0.7
6.5
0.7
5.9


0.75
7.3
0.75
2.9
0.75
5.8
0.75
6.3
0.75
5.8


0.8
7.0
0.8
2.8
0.8
5.8
0.8
6.1
0.8
5.6


0.85
6.5
0.85
2.6
0.85
5.8
0.85
5.6
0.85
5.1


0.9
5.4
0.9
2.3
0.9
5.0
0.9
4.7
0.9
4.4


0.95
3.8
0.95
1.3
0.95
3.5
0.95
3.4
0.95
3.1


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F245cb +
0.033 F245cb +
0.033 F245cb +
0.034 F245cb +
0.25 F245cb +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1243zf
0.033 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
4.6
0
4.8
0
1.8
0
5.7
0
4.3


0.05
5.8
0.05
5.8
0.05
2.9
0.05
6.6
0.05
5.4


0.1
5.8
0.1
5.8
0.1
2.9
0.1
6.6
0.1
5.4


0.15
5.8
0.15
5.8
0.15
2.9
0.15
6.6
0.15
5.4


0.2
5.8
0.2
5.8
0.2
2.9
0.2
6.6
0.2
5.4


0.25
5.8
0.25
5.8
0.25
2.9
0.25
6.6
0.25
5.4


0.3
5.8
0.3
5.8
0.3
2.9
0.3
6.6
0.3
5.4


0.35
5.8
0.35
5.8
0.35
2.9
0.35
6.6
0.35
5.4


0.4
5.8
0.4
5.8
0.4
2.9
0.4
6.6
0.4
5.4


0.45
5.8
0.45
5.8
0.45
2.9
0.45
6.6
0.45
5.4


0.5
5.8
0.5
5.7
0.5
2.9
0.5
6.6
0.5
5.4


0.55
5.8
0.55
5.7
0.55
2.9
0.55
6.6
0.55
5.4


0.6
5.8
0.6
5.6
0.6
2.9
0.6
6.6
0.6
5.4


0.65
5.8
0.65
5.5
0.65
2.8
0.65
6.5
0.65
5.4


0.7
5.8
0.7
5.4
0.7
2.8
0.7
6.4
0.7
5.4


0.75
5.8
0.75
5.2
0.75
5.8
0.75
6.3
0.75
5.2


0.8
5.8
0.8
4.8
0.8
2.7
0.8
6.0
0.8
5.0


0.85
5.7
0.85
4.3
0.85
2.5
0.85
5.5
0.85
4.5


0.9
4.9
0.9
3.6
0.9
2.2
0.9
4.7
0.9
3.9


0.95
3.5
0.95
2.6
0.95
1.8
0.95
3.3
0.95
2.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F245cb +
0.033 F245cb +
0.033 F245cb +
0.034 F245cb +
0.25 F245cb +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
4.5
0
2.0
0
1.7
0
5.6
0
3.5


0.05
5.7
0.05
3.2
0.05
2.8
0.05
6.5
0.05
4.6


0.1
5.7
0.1
3.2
0.1
2.8
0.1
6.6
0.1
4.6


0.15
5.7
0.15
3.2
0.15
2.8
0.15
6.6
0.15
4.6


0.2
5.7
0.2
3.2
0.2
2.8
0.2
6.5
0.2
4.6


0.25
5.7
0.25
3.2
0.25
2.8
0.25
6.5
0.25
4.6


0.3
5.7
0.3
3.2
0.3
2.8
0.3
6.5
0.3
4.6


0.35
5.7
0.35
3.2
0.35
2.8
0.35
6.5
0.35
4.6


0.4
5.7
0.4
3.2
0.4
2.8
0.4
6.5
0.4
4.6


0.45
5.7
0.45
3.2
0.45
2.8
0.45
6.5
0.45
4.6


0.5
5.7
0.5
3.2
0.5
2.8
0.5
6.5
0.5
4.7


0.55
5.7
0.55
3.2
0.55
2.8
0.55
6.5
0.55
4.7


0.6
5.7
0.6
3.2
0.6
2.8
0.6
6.5
0.6
4.7


0.65
5.7
0.65
3.2
0.65
2.8
0.65
6.4
0.65
4.7


0.7
5.7
0.7
3.2
0.7
2.8
0.7
6.4
0.7
4.7


0.75
5.7
0.75
3.1
0.75
2.8
0.75
6.2
0.75
4.7


0.8
5.7
0.8
3.0
0.8
2.6
0.8
5.9
0.8
4.5


0.85
5.6
0.85
2.8
0.85
2.4
0.85
5.4
0.85
4.1


0.9
4.8
0.9
2.5
0.9
2.2
0.9
4.6
0.9
3.5


0.95
3.4
0.95
1.9
0.95
1.8
0.95
3.3
0.95
2.6


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.034 F1234zeE +
0.25 F1234zeE +


0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf
















MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL


FRAC
PRES
FRAC
PRES
FRAC
PRES
FRAC
PRES
FRAC
PRES


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
4.7
0
2.1
0
1.7
0
5.6
0
3.6


0.05
5.7
0.05
3.2
0.05
2.8
0.05
6.5
0.05
4.7


0.1
5.7
0.1
3.2
0.1
2.8
0.1
6.6
0.1
4.7


0.15
5.7
0.15
3.2
0.15
2.8
0.15
6.5
0.15
4.7


0.2
5.7
0.2
3.2
0.2
2.8
0.2
6.5
0.2
4.7


0.25
5.7
0.25
3.2
0.25
2.8
0.25
6.5
0.25
4.7


0.3
5.7
0.3
3.2
0.3
2.8
0.3
6.5
0.3
4.6


0.35
5.7
0.35
3.1
0.35
2.8
0.35
6.5
0.35
4.6


0.4
5.7
0.4
3.1
0.4
2.8
0.4
6.5
0.4
4.6


0.45
5.7
0.45
3.1
0.45
2.7
0.45
6.5
0.45
4.6


0.5
5.6
0.5
3.1
0.5
2.7
0.5
6.5
0.5
4.6


0.55
5.6
0.55
3.1
0.55
2.7
0.55
6.5
0.55
4.6


0.6
5.5
0.6
3.1
0.6
2.7
0.6
6.5
0.6
4.6


0.65
5.4
0.65
3.1
0.65
2.7
0.65
6.4
0.65
4.6


0.7
5.3
0.7
3.1
0.7
2.7
0.7
6.3
0.7
4.5


0.75
5.0
0.75
3.1
0.75
2.7
0.75
6.2
0.75
4.3


0.8
4.7
0.8
3.0
0.8
2.6
0.8
5.9
0.8
4.1


0.85
4.2
0.85
2.7
0.85
2.4
0.85
5.4
0.85
3.7


0.9
3.5
0.9
2.4
0.9
2.1
0.9
4.6
0.0
3.2


0.95
2.5
0.95
1.9
0.95
1.7
0.95
3.3
0.95
2.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf
















Organics
Organics
Organics
Organics
Organics


0.9 F245cb +
0.033 F245cb +
0.033 F245cb +
0.034 F245cb +
0.25 F245cb +


0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +


0.033 F1234zeZ +
0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +


0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar



















0
4.6
0
4.8
0
2.2
0
5.7
0
4.4


0.05
5.8
0.05
5.8
0.05
3.3
0.05
6.6
0.05
5.4


0.1
5.8
0.1
5.8
0.1
3.3
0.1
6.7
0.1
5.4


0.15
5.8
0.15
6.8
0.15
3.3
0.15
6.6
0.15
5.4


0.2
5.8
0.2
5.8
0.2
3.3
0.2
6.6
0.2
5.4


0.25
5.8
0.25
5.8
0.25
3.3
0.25
6.6
0.25
5.4


0.3
5.8
0.3
5.8
0.3
3.3
0.3
6.6
0.3
5.4


0.35
5.8
0.35
5.8
0.35
3.3
0.35
6.6
0.35
5.4


0.4
5.8
0.4
5.8
0.4
3.3
0.4
6.6
0.4
5.4


0.45
5.8
0.45
5.8
0.45
3.3
0.45
6.6
0.45
5.4


0.5
5.8
0.5
5.7
0.5
3.3
0.5
6.6
0.5
5.4


0.55
5.8
0.55
5.7
0.55
3.3
0.55
6.6
0.55
5.4


0.6
5.8
0.6
5.6
0.6
3.3
0.6
6.6
0.6
5.4


0.65
5.8
0.65
5.5
0.65
3.3
0.65
6.5
0.65
5.4


0.7
5.8
0.7
5.4
0.7
3.2
0.7
6.4
0.7
5.4


0.75
5.8
0.75
5.2
0.75
3.2
0.75
6.3
0.75
5.3


0.8
5.8
0.8
4.8
0.8
3.1
0.8
6.0
0.8
5.0


0.85
5.7
0.85
4.3
0.85
2.9
0.85
5.5
0.85
4.6


0.9
4.9
0.9
3.6
0.9
2.5
0.9
4.7
0.9
3.9


0.95
3.5
0.95
2.6
0.95
2.0
0.95
3.3
0.95
2.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









EXAMPLE 8
Temperature and Pressure Range of Penternary Mixtures














Boiling point range










Temperature
Pressure


System with 5 compounds
° C.
bar abs





HF-HCFO-1233xf-HFC-245cb-HCFO-
0 to 40
~1.0 to ~10.0


1233zdE-HFO-1243zf




HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.0 to ~10.2


1234zeE-HFO-1243zf




HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.1 to ~10.1


1234zeZ-HFO-1243zf




HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.2 to ~11.4


1234yf-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~1.2 to ~11.4


1234zeE-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~1.2 to ~11.2


1234zeZ-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HCFO-
0 to 40
~1.0 to ~11.2


1233zdE-HFO-1243zf




HF-HCFO-1233xf-HCFO-1233zdE-HFO-
0 to 40
~1.0 to ~10.1


1234zeE-HFO-1243zf




HF-HCFO-1233xf-HCFO-1233zdE-HFO-
0 to 40
~1.0 to ~9.9 


1234zeZ-HFO-1243zf




HF-HCFO-1233xf-HFO-1234zeE-HFO-
0 to 40
~1.0 to ~10.1


1234zeZ-HFO-1243zf




HF-HFO-1234yf-HFO-1234zeE-HFO-
0 to 40
~1.3 to ~11.4


1234zeZ-HFO-1243zf




HF-HFO-1234yf-HFO-1234zeE-HCFO-
0 to 40
~1.0 to ~11.4


1233zdE-HFO-1243zf




HF-HFO-1234yf-HFO-1234zeZ-HCFO-
0 to 40
~1.1 to ~11.2


1233zdE-HFO-1243zf




HF-HFO-1234yf-HFC-245cb-HFO-
0 to 40
~2.5 to ~11.6


1234zeE-HFO-1243zf




HF-HFO-1234yf-HFC-245cb-HFO-
0 to 40
~1.3 to ~10.3


1234zeZ-HFO-1243zf




HF-HFO-1234yf-HFC-245cb-HCFO-
0 to 40
~1.1 to ~11.4


1233zdE-HFO-1243zf




HF-HFC-245cb-HCFO-1233zdE-HFO-
0 to 40
~1.1 to ~10.2


1234zeE-HFO-1243zf




HF-HFC-245cb-HCFO-1233zdE-HFO-
0 to 40
~1.0 to ~10.1


1234zeZ-HFO-1243zf




HF-HFC-245cb-HFO-1234zeE-HFO-
0 to 40
~1.2 to ~10.2


1234zeZ-HFO-1243zf




HF-HCFO-1233zdE-HFO-1234zeE-HFO-
0 to 40
~1.0 to ~10.1


1234zeZ-HFO-1243zf









EXAMPLE 9
Decantation Range of Penternary Mixtures














Decantation ranges



Mass percentage of HF











Isotherm
Isotherm
Isotherm


System with 5 compounds
0° C.
25° C.
40° C.





HF-HCFO-1233xf-HFC-245cb-HCFO-
5-75
 5-70
 5-65


1233zdE-HFO-1243zf





HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-
10-75
10-65
*


HFO-1243zf





HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-
5-75
 5-70
10-60


HFO-1243zf





HF-HCFO-1233xf-HFC-245cb-HFO-1234yf-
5-75
10-70
*


HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HFO-
5-70
10-60
*


1234zeE-HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HFO-
5-75
10-65
20-40


1234zeZ-HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HCFO-
5-75
 5-65
15-45


1233zdE-HFO-1243zf





HF-HCFO-1233xf-HCFO-1233zdE-HFO-
5-75
 5-65
15-45


1234zeE-HFO-1243zf





HF-HCFO-1233xf-HCFO-1233zdE-HFO-
5-75
 5-70
10-60


1234zeZ-HFO-1243zf





HF-HCFO-1233xf-HFO-1234zeE-HFO-
5-75
10-65
15-40


1234zeZ-HFO-1243zf





HF-HFO-1234yf-HFO-1234zeE-HFO-
5-70
10-60
*


1234zeZ-HFO-1243zf





HF-HFO-1234yf-HFO-1234zeE-HCFO-
5-70
10-60
*


1233zdE-HFO-1243zf





HF-HFO-1234yf-HFO-1234zeZ-HCFO-
5-75
10-65
15-45


1233zdE-HFO-1243zf





HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-
5-75
15-65
*


HFO-1243zf





HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-
5-75
10-70
*


HFO-1243zf





HF-HFO-1234yf-HFC-245cb-HCFO-
5-75
10-70
*


1233zdE-HFO-1243zf





HF-HFC-245cb-HCFO-1233zdE-HFO-
5-75
10-65
*


1234zeE-HFO-1243zf





HF-HFC-245cb-HCFO-1233zdE-HFO-
5-75
 5-70
10-60


1234zeZ-HFO-1243zf





HF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-
5-75
10-65
*


HFO-1243zf





HF-HCFO-1233zdE-HFO-1234zeE-HFO-
5-75
 5-65
15-50


1234zeZ-HFO-1243zf









EXAMPLE 10
System with Six Compounds, Isotherm at 25° C.

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.2 F1234yf +
0.01 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.2 F245cb
0.01 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +


0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


0.2 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.96 F1243zf



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
4.9
0
1.7
0
6.7
0
4.7
0
4.9
0
5.8


0.05
5.9
0.05
2.8
0.05
7.7
0.05
5.8
0.05
5.8
0.05
6.7


0.1
5.9
0.1
2.8
0.1
7.7
0.1
5.8
0.1
5.9
0.1
6.8


0.15
5.9
0.15
2.8
0.15
7.7
0.15
5.8
0.15
5.8
0.15
6.8


0.2
5.9
0.2
2.8
0.2
7.7
0.2
5.8
0.2
5.8
0.2
6.8


0.25
5.9
0.25
2.8
0.25
7.7
0.25
5.8
0.25
5.8
0.25
6.8


0.3
5.9
0.3
2.8
0.3
7.7
0.3
5.8
0.3
5.8
0.3
6.8


0.35
5.9
0.35
2.8
0.35
7.7
0.35
5.8
0.35
5.6
0.35
6.8


0.4
5.9
0.4
2.8
0.4
7.7
0.4
5.8
0.4
5.8
0.4
6.8


0.45
5.9
0.45
2.8
0.45
7.7
0.45
5.8
0.45
5.8
0.45
6.7


0.5
5.9
0.5
2.8
0.5
7.7
0.5
5.8
0.5
5.8
0.5
6.7


0.55
5.9
0.55
2.8
0.55
7.7
0.55
5.8
0.55
5.7
0.55
6.7


0.6
5.9
0.6
2.8
0.6
7.7
0.6
5.8
0.6
5.7
0.6
6.7


0.65
5.9
0.65
2.8
0.65
7.7
0.65
5.8
0.65
5.6
0.65
6.6


0.7
5.9
0.7
2.8
0.7
7.6
0.7
5.8
0.7
5.4
0.7
6.5


0.75
5.7
0.75
2.8
0.75
7.5
0.75
5.8
0.75
5.2
0.75
6.4


0.8
5.5
0.7
2.7
0.8
7.2
0.8
5.8
0.8
4.8
0.8
6.1


0.85
5.0
0.85
2.5
0.85
6.6
0.85
5.8
0.85
4.3
0.85
5.6


0.9
4.2
0.9
2.2
0.9
5.5
0.9
5.0
0.9
3.6
0.9
4.8


0.95
3.0
0.95
1.8
0.95
3.8
0.95
3.5
0.95
2.6
0.95
3.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.2 F1234yf +
0.01 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.2 F245cb
0.01 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +


0.2 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.96 F1234zeZ +
0.01 F1234zeZ +


0.2 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.96 F1243zf



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
4.2
0
1.7
0
6.7
0
4.6
0
1.9
0
5.8


0.05
5.3
0.05
2.8
0.05
7.6
0.05
5.8
0.05
3.0
0.05
6.7


0.1
5.3
0.1
2.8
0.1
7.7
0.1
5.8
0.1
3.0
0.1
6.8


0.15
5.3
0.15
2.8
0.15
7.6
0.15
5.8
0.15
3.0
0.15
6.7


0.2
5.3
0.2
2.8
0.2
7.6
0.2
5.8
0.2
3.0
0.2
6.7


0.25
5.3
0.25
2.8
0.25
7.6
0.25
5.8
0.25
3.0
0.25
6.7


0.3
5.3
0.3
2.8
0.3
7.6
0.3
5.8
0.3
3.0
0.3
6.7


0.35
5.3
0.35
2.8
0.35
7.6
0.35
5.8
0.35
3.0
0.35
6.7


0.4
5.3
0.4
2.8
0.4
7.6
0.4
5.8
0.4
3.0
0.4
6.7


0.45
5.3
0.45
2.8
0.45
7.6
0.45
5.8
0.45
3.0
0.45
6.7


0.5
5.3
0.5
2.8
0.5
7.6
0.5
5.8
0.5
3.0
0.5
6.7


0.55
5.3
0.55
2.8
0.55
7.6
0.55
5.8
0.55
3.0
0.55
6.7


0.6
5.3
0.6
2.8
0.6
7.6
0.6
5.8
0.6
3.0
0.6
6.7


0.65
5.3
0.65
2.8
0.65
7.6
0.65
5.8
0.65
3.0
0.65
6.6


0.7
5.3
0.7
2.8
0.7
7.6
0.7
5.8
0.7
3.0
0.7
6.5


0.75
5.3
0.75
2.8
0.75
7.5
0.75
5.8
0.75
3.0
0.75
6.4


0.8
5.1
0.8
2.7
0.8
7.2
0.8
5.8
0.8
2.9
0.8
6.1


0.85
4.7
0.85
2.5
0.85
6.6
0.85
5.8
0.85
2.7
0.85
5.6


0.9
4.0
0.9
2.2
0.9
5.5
0.9
5.0
0.9
2.4
0.9
4.7


0.95
2.9
0.95
1.8
0.95
3.8
0.95
3.5
0.95
1.9
0.95
3.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.2 F1234yf +
0.01 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.2 F245cb
0.01 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +


0.2 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.96 F1233zdE +
0.01 F1233zdE +


0.2 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.96 F1243zf



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
4.2
0
1.7
0
6.7
0
4.6
0
1.5
0
5.8


0.05
5.3
0.05
2.8
0.05
7.6
0.05
5.8
0.05
2.6
0.05
6.7


0.1
5.3
0.1
2.8
0.1
7.7
0.1
5.8
0.1
2.6
0.1
6.8


0.15
5.3
0.15
2.8
0.15
7.6
0.15
5.8
0.15
2.6
0.15
6.7


0.2
5.3
0.2
2.8
0.2
7.6
0.2
5.8
0.2
2.6
0.2
6.7


0.25
5.3
0.25
2.8
0.25
7.6
0.25
5.8
0.25
2.6
0.25
6.7


0.3
5.3
0.3
2.8
0.3
7.6
0.3
5.8
0.3
2.6
0.3
6.7


0.35
5.3
0.35
2.8
0.35
7.6
0.35
5.8
0.35
2.6
0.35
6.7


0.4
5.3
0.4
2.8
0.4
7.6
0.4
5.8
0.4
2.6
0.4
6.7


0.45
5.3
0.45
2.8
0.45
7.6
0.45
5.8
0.45
2.6
0.45
6.7


0.5
5.3
0.5
2.8
0.5
7.6
0.5
5.8
0.5
2.6
0.5
6.7


0.55
5.3
0.55
2.8
0.55
7.6
0.55
5.8
0.55
2.6
0.55
6.7


0.6
5.3
0.6
2.8
0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.7


0.65
5.3
0.65
2.8
0.65
7.6
0.65
5.8
0.65
2.6
0.65
6.6


0.7
5.3
0.7
2.8
0.7
7.6
0.7
5.8
0.7
2.6
0.7
6.5


0.75
5.2
0.75
2.8
0.75
7.5
0.75
5.8
0.75
2.6
0.75
6.4


0.8
5.0
0.8
2.7
0.8
7.2
0.8
5.8
0.8
2.5
0.8
6.1


0.85
4.6
0.85
2.5
0.85
6.6
0.85
5.8
0.85
2.3
0.85
5.6


0.9
3.9
0.9
2.2
0.9
5.5
0.9
5.0
0.9
2.0
0.9
4.7


0.95
2.8
0.95
1.8
0.95
3.8
0.95
3.5
0.95
1.7
0.95
3.4


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.2 F1234yf +
0.01 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.2 F1243zf
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
4.3
0
1.7
0
6.7
0
5.8
0
4.8
0
1.9


0.05
5.3
0.05
2.8
0.05
7.6
0.05
6.7
0.05
5.8
0.05
3.0


0.1
5.3
0.1
2.8
0.1
7.6
0.1
6.7
0.1
5.8
0.1
3.0


0.15
5.3
0.15
2.8
0.15
7.6
0.15
6.7
0.15
5.8
0.15
3.0


0.2
5.3
0.2
2.8
0.2
7.6
0.2
6.7
0.2
5.8
0.2
3.0


0.25
5.3
0.25
2.8
0.25
7.6
0.25
6.7
0.25
5.8
0.25
3.0


0.3
5.3
0.3
2.8
0.3
7.6
0.3
6.7
0.3
5.8
0.3
3.0


0.35
5.3
0.35
2.8
0.35
7.6
0.35
6.7
0.35
5.8
0.35
3.0


0.4
5.3
0.4
2.8
0.4
7.6
0.4
6.7
0.4
5.8
0.4
3.0


0.45
5.3
0.45
2.8
0.45
7.6
0.45
6.7
0.45
5.8
0.45
3.0


0.5
5.3
0.5
2.8
0.5
7.6
0.5
6.7
0.5
5.8
0.5
3.0


0.55
5.3
0.55
2.8
0.55
7.6
0.55
6.7
0.55
5.7
0.55
3.0


0.6
5.3
0.6
2.8
0.6
7.6
0.6
6.7
0.6
5.6
0.6
3.0


0.65
5.3
0.65
2.8
0.65
7.6
0.65
6.6
0.65
5.5
0.65
3.0


0.7
5.2
0.7
2.8
0.7
7.6
0.7
6.5
0.7
5.4
0.7
3.0


0.75
5.0
0.75
2.8
0.75
7.5
0.75
6.3
0.75
5.1
0.75
3.0


0.8
4.8
0.8
2.7
0.8
7.1
0.8
6.1
0.8
4.8
0.8
2.9


0.85
4.3
0.85
2.5
0.85
6.5
0.85
5.6
0.85
4.3
0.85
2.7


0.9
3.7
0.9
2.2
0.9
5.5
0.9
4.7
0.9
3.6
0.9
2.4


0.95
2.7
0.95
1.8
0.95
3.8
0.95
3.4
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.2 F1234yf +
0.01 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
4.3
0
1.7
0
6.7
0
5.8
0
4.8
0
1.5


0.05
5.3
0.05
2.8
0.05
7.6
0.05
6.7
0.05
5.8
0.05
2.6


0.1
5.3
0.1
2.8
0.1
7.6
0.1
6.7
0.1
5.8
0.1
2.6


0.15
5.3
0.15
2.8
0.15
7.6
0.15
6.7
0.15
5.8
0.15
2.6


0.2
5.3
0.2
2.8
0.2
7.6
0.2
6.7
0.2
5.8
0.2
2.6


0.25
5.3
0.25
2.8
0.25
7.6
0.25
6.7
0.25
5.8
0.25
2.6


0.3
5.3
0.3
2.8
0.3
7.6
0.3
6.7
0.3
5.8
0.3
2.6


0.35
5.3
0.35
2.8
0.35
7.6
0.35
6.7
0.35
5.8
0.35
2.6


0.4
5.3
0.4
2.8
0.4
7.6
0.4
6.7
0.4
5.8
0.4
2.6


0.45
5.3
0.45
2.8
0.45
7.6
0.45
6.7
0.45
5.8
0.45
2.6


0.5
5.3
0.5
2.8
0.5
7.6
0.5
6.7
0.5
5.8
0.5
2.6


0.55
5.3
0.55
2.8
0.55
7.6
0.55
6.7
0.55
5.7
0.55
2.6


0.6
5.3
0.6
2.8
0.6
7.6
0.6
6.7
0.6
5.6
0.6
2.6


0.65
5.2
0.65
2.8
0.65
7.6
0.65
6.6
0.65
5.5
0.65
2.6


0.7
5.1
0.7
2.8
0.7
7.6
0.7
6.5
0.7
5.4
0.7
2.6


0.75
5.0
0.75
2.8
0.75
7.5
0.75
6.3
0.75
5.1
0.75
2.6


0.8
4.7
0.8
2.6
0.8
7.1
0.8
6.1
0.8
4.8
0.8
2.4


0.85
4.3
0.85
2.5
0.85
6.5
0.85
5.6
0.85
4.3
0.85
2.3


0.9
3.6
0.9
2.2
0.9
5.5
0.9
4.7
0.9
3.6
0.9
2.0


0.95
2.6
0.95
1.8
0.95
3.8
0.95
3.4
0.95
2.6
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.2 F1234yf +
0.01 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.96 F1234zeZ +
0.01 F1234zeZ +


0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
3.6
0
1.7
0
6.6
0
5.7
0
1.9
0
1.4


0.05
4.7
0.05
2.8
0.05
7.6
0.05
6.7
0.05
3.0
0.05
2.6


0.1
4.7
0.1
2.8
0.1
7.6
0.1
6.7
0.1
3.0
0.1
2.6


0.15
4.7
0.15
2.8
0.15
7.6
0.15
6.7
0.15
3.0
0.15
2.6


0.2
4.7
0.2
2.8
0.2
7.6
0.2
6.7
0.2
3.0
0.2
2.6


0.25
4.7
0.25
2.8
0.25
7.6
0.25
6.7
0.25
3.0
0.25
2.6


0.3
4.7
0.3
2.8
0.3
7.6
0.3
6.7
0.3
3.0
0.3
2.6


0.35
4.7
0.35
2.8
0.35
7.6
0.35
6.7
0.35
3.0
0.35
2.5


0.4
4.7
0.4
2.8
0.4
7.6
0.4
6.7
0.4
3.0
0.4
2.5


0.45
4.7
0.45
2.8
0.45
7.6
0.45
6.7
0.45
3.0
0.45
2.5


0.5
4.7
0.5
2.8
0.5
7.6
0.5
6.7
0.5
3.0
0.5
2.5


0.55
4.7
0.55
2.8
0.55
7.6
0.55
6.7
0.55
3.0
0.55
2.5


0.6
4.7
0.6
2.8
0.6
7.5
0.5
6.6
0.6
3.0
0.6
2.5


0.65
4.7
0.65
2.8
0.65
7.6
0.65
6.6
0.65
3.0
0.65
2.5


0.7
4.7
0.7
2.8
0.7
7.6
0.7
6.5
0.7
3.0
0.7
2.5


0.75
4.5
0.75
2.8
0.75
7.4
0.75
6.3
0.75
3.0
0.75
2.5


0.8
4.3
0.8
2.6
0.8
7.1
0.8
6.0
0.8
2.9
0.8
2.4


0.85
3.9
0.85
2.4
0.85
6.5
0.85
5.5
0.85
2.7
0.85
2.3


0.9
3.4
0.9
2.2
0.9
5.5
0.9
4.7
0.9
2.3
0.9
2.0


0.95
2.5
0.95
1.7
0.95
3.8
0.95
3.3
0.95
1.9
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.2 F245cb +
0.01 F245cb +
0.96 F245cd +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.2 F1243zf
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
3.8
0
1.7
0
4.6
0
5.8
0
4.8
0
1.9


0.05
4.9
0.05
2.8
0.05
5.8
0.05
6.7
0.05
5.8
0.05
3.0


0.1
4.9
0.1
2.8
0.1
5.8
0.1
6.7
0.1
5.8
0.1
3.0


0.15
4.9
0.15
2.8
0.15
5.8
0.15
6.7
0.15
5.8
0.15
3.0


0.2
4.9
0.2
2.8
0.2
5.8
0.2
6.7
0.2
5.8
0.2
3.0


0.25
4.9
0.25
2.8
0.25
5.8
0.25
6.7
0.25
5.8
0.25
3.0


0.3
4.9
0.3
2.8
0.3
5.8
0.3
6.7
0.3
5.8
0.3
3.0


0.35
4.9
0.35
2.8
0.35
5.8
0.35
6.7
0.35
5.8
0.35
3.0


0.4
4.9
0.4
2.8
0.4
5.8
0.4
6.7
0.4
5.8
0.4
3.0


0.45
4.9
0.45
2.8
0.45
5.8
0.45
6.7
0.45
5.8
0.45
3.0


0.5
4.9
0.5
2.8
0.5
5.8
0.5
6.7
0.5
5.7
0.5
3.0


0.55
4.9
0.55
2.8
0.55
5.8
0.55
6.7
0.55
5.7
0.55
3.0


0.6
4.9
0.6
2.8
0.6
5.8
0.6
6.6
0.6
5.6
0.6
3.0


0.65
4.9
0.65
2.8
0.65
5.8
0.65
6.6
0.65
5.5
0.65
3.0


0.7
4.9
0.7
2.8
0.7
5.8
0.7
6.5
0.7
5.4
0.7
3.0


0.75
4.8
0.75
2.8
0.75
5.8
0.75
6.3
0.75
5.1
0.75
3.0


0.8
4.6
0.8
2.6
0.8
5.8
0.8
6.0
0.8
4.8
0.0
2.9


0.85
4.2
0.85
2.4
0.85
5.8
0.85
5.6
0.85
4.3
0.85
2.7


0.9
3.6
0.9
2.2
0.9
5.0
0.9
4.7
0.9
3.6
0.9
2.4


0.95
2.6
0.95
1.8
0.95
3.5
0.95
3.4
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.2 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
3.8
0
1.7
0
4.6
0
5.8
0
4.8
0
1.5


0.05
4.9
0.05
2.8
0.05
5.8
0.05
6.7
0.05
5.8
0.05
2.6


0.1
4.9
0.1
2.8
0.1
5.8
0.1
6.7
0.1
5.8
0.1
2.6


0.15
4.9
0.15
2.8
0.15
5.8
0.15
6.7
0.15
5.8
0.15
2.6


0.2
4.9
0.2
2.8
0.2
5.8
0.2
6.7
0.2
5.8
0.2
2.6


0.25
4.9
0.25
2.8
0.25
5.8
0.25
6.7
0.25
5.8
0.25
2.6


0.3
4.9
0.3
2.8
0.3
5.8
0.3
6.7
0.3
5.8
0.3
2.6


0.35
4.9
0.35
2.8
0.35
5.8
0.35
6.7
0.35
5.8
0.35
2.6


0.4
4.9
0.4
2.8
0.4
5.8
0.4
6.7
0.4
5.8
0.4
2.6


0.45
4.9
0.45
2.8
0.45
5.8
0.45
6.7
0.45
5.8
0.45
2.6


0.5
4.9
0.5
2.8
0.5
5.8
0.5
6.7
0.5
5.7
0.5
2.6


0.55
4.9
0.55
2.8
0.55
5.8
0.55
6.7
0.55
5.7
0.55
2.6


0.6
4.9
0.6
2.8
0.6
5.8
0.6
6.6
0.6
5.6
0.6
2.6


0.65
4.9
0.65
2.8
0.65
5.8
0.65
6.6
0.65
5.5
0.65
2.5


0.7
4.9
0.7
2.8
0.7
5.8
0.7
6.5
0.7
5.4
0.7
2.5


0.75
4.7
0.75
2.8
0.75
5.8
0.75
6.3
0.75
5.1
0.75
2.5


0.8
4.5
0.8
2.6
0.8
5.8
0.8
6.0
0.8
4.8
0.8
2.4


0.85
4.1
0.85
2.4
0.85
5.8
0.85
5.6
0.85
4.3
0.85
2.3


0.9
3.5
0.9
2.2
0.9
5.0
0.9
4.7
0.9
3.6
0.9
2.0


0.95
2.6
0.95
1.7
0.95
3.5
0.95
3.3
0.95
2.6
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.2 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.96 F1234zeZ +
0.01 F1234zeZ +


0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
3.2
0
1.6
0
4.6
0
5.7
0
1.9
0
1.4


0.05
4.3
0.05
2.7
0.05
5.7
0.05
6.7
0.05
3.0
0.05
2.5


0.1
4.3
0.1
2.7
0.1
5.7
0.1
6.7
0.1
3.0
0.1
2.5


0.15
4.3
0.15
2.7
0.15
5.7
0.15
6.7
0.15
3.0
0.15
2.5


0.2
4.3
0.2
2.7
0.2
5.7
0.2
6.7
0.2
3.0
0.2
2.5


0.25
4.3
0.25
2.7
0.25
5.7
0.25
6.7
0.25
3.0
0.25
2.5


0.3
4.3
0.3
2.7
0.3
5.7
0.3
6.7
0.3
3.0
0.3
2.5


0.35
4.3
0.35
2.7
0.35
5.7
0.35
6.7
0.35
3.0
0.35
2.5


0.4
4.3
0.4
2.7
0.4
5.8
0.4
6.7
0.4
3.0
0.4
2.5


0.45
4.3
0.45
2.7
0.45
5.8
0.45
6.7
0.45
3.0
0.45
2.5


0.5
4.3
0.5
2.7
0.5
5.8
0.5
6.7
0.5
3.0
0.5
2.5


0.55
4.3
0.55
2.7
0.55
5.8
0.55
6.7
0.55
3.0
0.55
2.5


0.6
4.3
0.6
2.7
0.6
5.8
0.6
6.6
0.6
3.0
0.6
2.5


0.65
4.3
0.65
2.7
0.65
5.8
0.65
6.6
0.65
3.0
0.65
2.5


0.7
4.3
0.7
2.7
0.7
5.8
0.7
6.5
0.7
3.0
0.7
2.5


0.70
4.3
0.75
2.7
0.75
5.8
0.75
6.3
0.75
3.0
0.75
2.5


0.8
4.1
0.8
2.6
0.8
5.8
0.8
6.0
0.8
2.9
0.8
2.4


0.85
3.8
0.85
2.4
0.85
5.8
0.85
5.5
0.85
2.7
0.85
2.3


0.9
3.3
0.9
2.1
0.9
5.0
0.9
4.7
0.9
2.3
0.9
2.0


0.95
2.4
0.95
1.7
0.95
3.5
0.95
3.3
0.95
1.9
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.2 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1233zdE
0.01 F1233zdE +
0.01 F1233zdE +
0.96 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +


0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
3.2
0
1.6
0
5.7
0
1.4
0
4.8
0
1.9


0.05
4.3
0.05
2.7
0.05
6.7
0.05
2.5
0.05
5.7
0.05
3.0


0.1
4.3
0.1
2.7
0.1
6.7
0.1
2.5
0.1
5.8
0.1
3.0


0.15
4.3
0.15
2.7
0.15
6.7
0.15
2.5
0.15
5.8
0.15
3.0


0.2
4.3
0.2
2.7
0.2
6.7
0.2
2.5
0.2
5.8
0.2
3.0


0.25
4.3
0.25
2.7
0.25
6.7
0.25
2.5
0.25
5.8
0.25
3.0


0.3
4.3
0.2
2.7
0.3
6.7
0.3
2.5
0.3
5.8
0.3
3.0


0.35
4.3
0.35
2.7
0.35
6.7
0.35
2.5
0.35
5.8
0.35
3.0


0.4
4.3
0.4
2.7
0.4
6.7
0.4
2.5
0.4
5.8
0.4
3.0


0.45
4.3
0.45
2.7
0.45
6.7
0.45
2.5
0.45
5.7
0.45
3.0


0.5
4.3
0.5
2.7
0.5
6.7
0.5
2.5
0.5
5.7
0.5
3.0


0.55
4.2
0.55
2.7
0.55
6.6
0.55
2.5
0.55
5.7
0.55
3.0


0.6
4.2
0.6
2.7
0.6
6.6
0.6
2.5
0.6
5.6
0.6
3.0


0.65
4.2
0.65
2.7
0.65
6.6
0.65
2.5
0.65
5.5
0.65
3.0


0.7
4.2
0.7
2.7
0.7
6.5
0.7
2.5
0.7
5.3
0.70
3.0


0.75
4.0
0.75
2.7
0.75
6.3
0.75
2.5
0.75
5.1
0.75
3.0


0.8
3.8
0.8
2.6
0.8
6.0
0.8
2.4
0.8
4.7
0.8
2.3


0.85
3.5
0.85
2.4
0.85
5.5
0.85
2.2
0.85
4.3
0.85
2.6


0.9
3.0
0.9
2.1
0.9
4.7
0.9
2.0
0.9
3.6
0.9
2.3


0.95
2.2
0.95
1.7
0.95
3.3
0.95
1.7
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.2 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
4.8
0
6.7
0
4.7
0
5.8
0
4.9
0
2.0


0.05
5.9
0.05
7.7
0.05
5.8
0.05
6.7
0.05
5.8
0.05
3.1


0.1
5.9
0.1
7.7
0.1
5.8
0.1
6.8
0.1
5.9
0.1
3.1


0.15
5.9
0.15
7.7
0.15
5.8
0.15
6.8
0.15
5.8
0.15
3.1


0.2
5.9
0.2
7.7
0.2
5.8
0.2
6.8
0.2
5.8
0.2
3.1


0.25
5.9
0.25
7.6
0.25
5.8
0.25
6.8
0.25
5.8
0.25
3.1


0.3
5.9
0.3
7.6
0.3
5.8
0.5
6.8
0.3
5.8
0.3
3.1


0.35
5.9
0.35
7.6
0.35
5.8
0.35
6.8
0.35
5.8
0.35
3.1


0.4
5.9
0.4
7.6
0.4
5.8
0.4
6.7
0.4
5.8
0.4
3.1


0.45
5.9
0.45
7.6
0.45
5.8
0.45
6.7
0.45
5.8
0.45
3.1


0.5
5.9
0.5
7.7
0.5
5.8
0.5
6.7
0.5
5.8
0.5
3.1


0.55
5.9
0.55
7.7
0.55
5.8
0.55
6.7
0.55
5.7
0.55
3.1


0.6
5.9
0.6
7.7
0.6
5.8
0.6
6.7
0.6
5.7
0.6
3.1


0.65
5.9
0.65
7.7
0.65
5.8
0.65
6.6
0.65
5.6
0.65
3.1


0.7
5.9
0.7
7.6
0.7
5.8
0.7
6.5
0.7
5.4
0.7
3.1


0.75
5.7
0.75
7.5
0.75
5.8
0.75
6.4
0.75
5.2
0.75
3.1


0.8
5.5
0.3
7.2
0.8
5.8
0.8
6.1
0.8
4.3
0.8
2.9


0.85
5.0
0.85
6.6
0.85
5.8
0.85
5.8
0.85
4.3
0.85
2.7


0.9
4.3
0.9
5.5
0.9
5.0
0.9
4.8
0.9
3.6
0.9
2.4


0.95
3.0
0.95
3.0
0.95
3.5
0.95
3.4
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.2 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
4.8
0
6.7
0
4.7
0
5.8
0
4.9
0
1.5


0.05
5.9
0.05
7.7
0.05
5.8
0.05
6.7
0.05
5.8
0.05
2.6


0.1
5.9
0.1
7.7
0.1
5.8
0.1
6.8
0.1
5.8
0.1
2.8


0.15
5.9
0.15
7.7
0.15
5.8
0.15
6.8
0.15
5.8
0.15
2.6


0.2
5.9
0.2
7.7
0.2
5.8
0.2
6.8
0.2
5.8
0.2
2.6


0.25
5.9
0.25
7.6
0.25
5.8
0.25
6.8
0.25
5.8
0.25
2.6


0.3
5.9
0.3
7.6
0.3
5.8
0.3
6.8
0.3
5.8
0.3
2.6


0.35
5.9
0.35
7.6
0.35
5.8
0.35
6.8
0.35
5.8
0.35
2.8


0.4
5.9
0.4
7.7
0.4
5.8
0.4
6.7
0.4
5.8
0.4
2.6


0.45
5.9
0.45
7.7
0.45
5.8
0.45
6.7
0.45
5.8
0.45
2.6


0.5
5.9
0.5
7.7
0.5
5.8
0.5
6.7
0.5
5.8
0.5
2.6


0.55
5.9
0.55
7.7
0.55
5.8
0.55
6.7
0.55
5.7
0.55
2.6


0.6
5.9
0.6
7.7
0.6
5.8
0.6
6.7
0.6
5.7
0.6
2.6


0.65
5.9
0.65
7.7
0.65
5.8
0.65
6.6
0.65
5.6
0.65
2.6


0.7
5.9
0.7
7.6
0.7
5.8
0.7
6.5
0.7
5.4
0.7
2.6


0.75
5.7
0.75
7.5
0.75
5.8
0.75
6.4
0.75
5.2
0.75
2.6


0.8
5.4
0.8
7.2
0.8
5.8
0.8
6.1
0.8
4.8
0.8
2.5


0.55
5.0
0.85
6.6
0.85
5.8
0.85
5.8
0.85
4.3
0.85
2.3


0.9
4.2
0.9
5.5
0.9
5.0
0.9
4.8
0.9
3.6
0.9
2.1


0.95
3.0
0.95
3.8
0.95
3.5
0.95
3.4
0.95
2.6
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFC-245th-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.2 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.96 F1234zeZ +
0.01 F1234zeZ +


0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
4.2
0
6.7
0
4.6
0
5.8
0
1.9
0
1.5


0.05
5.3
0.05
7.6
0.05
5.8
0.05
6.7
0.05
3.0
0.05
2.6


0.1
5.3
0.1
7.6
0.1
5.8
0.1
6.7
0.1
3.0
0.1
2.6


0.15
5.3
0.15
7.6
0.15
5.8
0.15
6.7
0.15
3.0
0.15
2.6


0.2
5.3
0.2
7.6
0.2
5.8
0.2
6.7
0.2
3.0
0.2
2.6


0.25
5.3
0.25
7.6
0.25
5.8
0.25
6.7
0.25
3.0
0.25
2.6


0.3
5.3
0.3
7.6
0.3
5.8
0.3
6.7
0.3
3.0
0.3
2.6


0.35
5.3
0.35
7.6
0.35
5.8
0.35
6.7
0.35
3.0
0.35
2.6


0.4
5.3
0.4
7.6
0.4
5.8
0.4
6.7
0.4
3.0
0.4
2.6


0.45
5.3
0.45
7.6
0.45
5.8
0.45
6.7
0.45
3.0
0.45
2.6


0.5
5.3
0.5
7.6
0.5
5.8
0.5
6.7
0.5
3.0
0.5
2.6


0.55
5.3
0.55
7.6
0.55
5.8
0.55
6.7
0.55
3.0
0.55
2.6


0.6
5.3
0.6
7.6
0.6
5.8
0.6
6.7
0.6
3.0
0.6
2.6


0.65
5.3
0.65
7.6
0.65
5.8
0.65
6.6
0.65
3.0
0.65
2.6


0.7
5.3
0.7
7.6
0.7
5.8
0.7
6.5
0.7
3.0
0.7
2.6


0.75
5.2
0.75
7.5
0.75
5.8
0.75
6.4
0.75
3.0
0.75
2.6


0.8
5.0
0.8
7.2
0.8
5.8
0.8
6.1
0.8
2.9
0.8
2.5


0.85
4.6
0.85
6.6
0.85
5.8
0.85
5.6
0.85
2.7
0.85
2.3


0.9
3.9
0.9
5.5
0.9
5.0
0.9
4.7
0.9
2.4
0.9
2.0


0.95
2.9
0.95
3.8
0.95
3.5
0.95
3.4
0.95
1.9
0.95
1.7


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.2 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1233zdE
0.01 F1233zdE +
0.01 F1233zdE +
0.96 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +


0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
4.2
0
6.7
0
5.8
0
1.5
0
4.8
0
1.9


0.05
5.3
0.05
7.6
0.05
6.7
0.05
2.6
0.05
5.8
0.05
3.0


0.1
5.3
0.1
7.6
0.1
6.7
0.1
2.6
0.1
5.8
0.1
3.0


0.15
5.3
0.15
7.6
0.15
8.7
0.15
2.6
0.15
5.8
0.15
3.0


0.2
5.3
0.2
7.6
0.2
6.7
0.2
2.6
0.2
5.8
0.2
3.0


0.25
5.3
0.25
7.6
0.25
6.7
0.25
2.6
0.25
5.8
0.25
3.0


0.3
5.3
0.3
7.6
0.3
6.7
0.3
2.6
0.3
5.8
0.3
3.0


0.35
5.3
0.35
7.6
0.35
6.7
0.35
2.6
0.35
5.8
0.35
3.0


0.4
5.3
0.4
7.6
0.4
6.7
0.4
2.6
0.4
5.8
0.4
3.0


0.45
5.3
0.45
7.6
0.45
6.7
0.45
2.6
0.45
5.8
0.45
3.0


0.5
5.3
0.5
7.6
0.5
6.7
0.5
2.6
0.5
5.8
0.5
3.0


0.55
5.2
0.55
7.6
0.55
6.7
0.55
2.6
0.55
5.7
0.55
3.0


0.6
5.2
0.6
7.6
0.6
6.7
0.6
2.6
0.6
5.6
0.6
3.0


0.65
5.2
0.65
7.6
0.65
6.6
0.65
2.6
0.65
5.5
0.65
3.0


0.7
5.2
0.7
7.6
0.7
6.5
0.7
2.6
0.7
5.4
0.7
3.0


0.75
5.0
0.75
7.5
0.75
6.3
0.75
2.6
0.75
5.1
0.75
3.0


0.8
4.7
0.8
7.1
0.8
6.1
0.8
2.5
0.8
4.8
0.8
2.9


0.85
4.3
0.80
6.5
0.85
5.6
0.85
2.3
0.85
4.3
0.85
2.7


0.9
3.7
0.9
5.5
0.9
4.7
0.9
2.0
0.9
3.6
0.9
2.4


0.95
2.7
0.95
3.8
0.95
3.4
0.95
1.7
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

















Organics
Organics
Organics
Organics
Organics
Organics


0.2 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.2 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.2 F1233zdE
0.01 F1233zdE +
0.01 F1233zdE +
0.96 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +


0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +


0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ



















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar





















0
3.8
0
4.6
0
5.8
0
1.5
0
4.8
0
1.9


0.05
4.9
0.05
5.8
0.05
6.7
0.05
2.6
0.05
5.8
0.05
3.0


0.1
4.9
0.1
5.8
0.1
6.7
0.1
2.6
0.1
5.8
0.1
3.0


0.15
4.9
0.15
5.8
0.15
6.7
0.15
2.6
0.15
5.8
0.15
3.0


0.2
4.9
0.2
5.8
0.2
6.7
0.2
2.6
0.2
5.8
0.2
3.0


0.25
4.9
0.25
5.8
0.25
6.7
0.25
2.6
0.25
5.8
0.25
3.0


0.3
4.9
0.3
5.8
0.3
6.7
0.3
2.6
0.3
5.8
0.3
3.0


0.35
4.9
0.35
5.8
0.35
6.7
0.35
2.6
0.35
5.8
0.35
3.0


0.4
4.9
0.4
5.8
0.4
6.7
0.4
2.6
0.4
5.8
0.4
3.0


0.45
4.9
0.45
5.8
0.45
6.7
0.45
2.6
0.45
5.8
0.45
3.0


0.5
4.9
0.5
5.8
0.5
6.7
0.5
2.6
0.5
5.7
0.5
3.0


0.55
4.9
0.55
5.8
0.55
6.7
0.55
2.6
0.55
5.7
0.55
3.0


0.6
4.9
0.6
5.8
0.6
6.6
0.6
2.6
0.6
5.6
0.6
3.0


0.65
4.9
0.65
5.8
0.65
6.6
0.65
2.6
0.65
5.5
0.65
3.0


0.7
4.9
0.7
5.8
0.7
6.5
0.7
2.6
0.7
5.4
0.7
3.0


0.75
4.8
0.75
5.8
0.75
6.3
0.75
2.6
0.75
5.1
0.75
3.0


0.8
4.5
0.8
5.8
0.8
6.0
0.8
2.4
0.8
4.8
0.8
2.9


0.85
4.2
0.85
5.0
0.85
5.6
0.85
2.3
0.85
4.3
0.85
2.7


0.9
3.5
0.9
5.0
0.9
4.7
0.9
2.0
0.9
3.6
0.9
2.4


0.95
2.6
0.95
3.5
0.95
3.4
0.95
1.7
0.95
2.6
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









EXAMPLE 11
Temperature and Pressure Range of Systems with 6 Compounds














Boiling point range










Temperature
Pressure


System with 6 compounds
° C.
bar abs





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.0 to ~11.6


HFO-1234zeE-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.0 to ~11.6


HFO-1234zeZ-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~0.9 to ~11.6


HCFO-1233zdE-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~1.0 to ~11.6


1234zeE-HFO-1234zeZ-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~0.9 to ~11.6


1234zeE-HCFO-1233zdE-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~0.9 to ~11.6


1234zeZ-HCFO-1233zdE-HFO-1243zf




HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.0 to ~10.3


1234zeE-HFO-1234zeZ-HFO-1243zf




HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~0.9 to ~10.3


1234zeE-HCFO-1233zdE-HFO-1243zf




HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.0 to ~10.3


1234zeZ-HCFO-1233zdE-HFO-1243zf




HF-HCFO-1233xf-HFO-1234zeE-HFO-
0 to 40
~0.9 to ~10.3


1234zeZ-HCFO-1233zdE-HFO-1243zf




HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-
0 to 40
~1.2 to ~11.6


HFO-1234zeZ-HFO-1243zf




HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-
0 to 40
~1.0 to ~11.7


HCFO-1233zdE-HFO-1243zf




HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-
0 to 40
~0.9 to ~11.6


HCFO-1233zdE-HFO-1243zf




HF-HFO-1234yf-HFO-1234zeE-HFO-
0 to 40
~0.9 to ~11.6


1234zeZ-HCFO-1233zdE-HFO-1243zf




HF-HFC-245cb-HFO-1234zeE-HFO-
0 to 40
~0.9 to ~10.3


1234zeZ-HCFO-1233zdE-HFO-1243zf









EXAMPLE 12
Decantation Range of Systems with 6 Compounds














Decantation ranges



Mass percentage of HF











Isotherm
Isotherm
Isotherm


System with 6 compounds
0° C.
25° C.
40° C.





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
10-65
*


HFO-1234zeE-HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
10-70
15-50


HFO-1234zeZ-HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
 5-70
15-55


HCFO-1233zdE-HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HFO-
5-70
10-65
*


1234zeE-HFO-1234zeZ-HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HFO-
5-70
10-75
*


1234zeE-HCFO-1233zdE-HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HFO-
5-75
 5-70
10-55


1234zeZ-HCFO-1233zdE-HFO-1243zf





HF-HCFO-1233xf-HFC-245cb-HFO-
5-75
10-70
15-45


1234zeE-HFO-1234zeZ-HFO-1243zf





HF-HCFO-1233xf-HFC-245cb-HFO-
5-75
 5-70
15-50


1234zeE-HCFO-1233zdE-HFO-1243zf





HF-HCFO-1233xf-HFC-245cb-HFO-
5-75
 5-70
10-65


1234zeZ-HCFO-1233zdE-HFO-1243zf





HF-HCFO-1233xf-HFO-1234zeE-HFO-
5-75
 5-65
10-55


1234zeZ-HCFO-1233zdE-HFO-1243zf





HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-
5-75
10-65
*


HFO-1234zeZ-HFO-1243zf





HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-
5-75
10-65
*


HCFO-1233zdE-HFO-1243zf





HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-
5-75
10-70
15-55


HCFO-1233zdE-HFO-1243zf





HF-HFO-1234yf-HFO-1234zeE-HFO-
5-70
10-65
*


1234zeZ-HCFO-1233zdE-HFO-1243zf





HF-HFC-245cb-HFO-1234zeE-HFO-
5-75
 5-70
15-50


1234zeZ-HCFO-1233zdE-HFO-1243zf












EXAMPLE 13
Systems with Seven Compounds, Isotherm at 25° C.

HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf


















Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf +
0.95 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +


0.17 F245cb +
0.01 F245cb +
0.95 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.17 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.95 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +


0.17 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.95 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +


0.17 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.95 F1234zeZ +


0.17 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.95 F1243zf
0.01 F1243zf





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar























0
3.5
0
1.7
0
4.5
0
1.5
0
4.8
0
5.7
0
1.9


0.05
4.6
0.05
2.8
0.05
5.7
0.05
2.6
0.05
5.7
0.05
6.7
0.05
3.0


0.1
4.6
0.1
2.8
0.1
5.7
0.1
2.6
0.1
5.8
0.1
6.7
0.1
3.0


0.15
4.6
0.15
2.8
0.15
5.7
0.15
2.6
0.15
5.8
0.15
6.7
0.15
3.0


0.2
4.6
0.2
2.8
0.2
5.7
0.2
2.6
0.2
5.8
0.2
6.7
0.2
3.0


0.25
4.6
0.25
2.8
0.25
5.8
0.25
2.6
0.25
5.8
0.25
6.7
0.25
3.0


0.3
4.6
0.3
2.8
0.3
5.8
0.3
2.6
0.3
5.8
0.3
6.7
0.3
3.0


0.35
4.6
0.35
2.8
0.35
5.8
0.35
2.6
0.35
5.8
0.35
6.7
0.35
3.0


0.4
4.6
0.4
2.8
0.4
5.8
0.4
2.6
0.4
5.8
0.4
6.7
0.4
3.0


0.45
4.6
0.45
2.8
0.45
5.8
0.45
2.6
0.45
5.7
0.45
6.7
0.45
3.0


0.5
4.6
0.5
2.8
0.5
5.8
0.5
2.6
0.5
5.7
0.5
6.7
0.5
3.0


0.55
4.6
0.55
2.8
0.55
5.8
0.55
2.6
0.55
5.7
0.55
6.6
0.55
3.0


0.5
4.6
0.6
2.8
0.6
5.8
0.6
2.6
0.6
5.6
0.6
6.6
0.6
3.0


0.65
4.6
0.55
2.8
0.65
5.8
0.65
2.6
0.65
5.5
0.65
6.6
0.65
3.0


0.7
4.6
0.7
2.8
0.7
5.8
0.7
2.6
0.7
5.3
0.7
6.6
0.7
3.0


0.75
4.5
0.75
2.8
0.75
5.8
0.75
2.6
0.75
5.1
0.75
6.2
0.75
3.0


0.8
4.2
0.8
2.6
0.8
5.8
0.8
2.4
0.8
4.8
0.8
6.0
0.8
2.9


0.85
3.9
0.85
2.4
0.85
5.8
0.85
2.3
0.85
4.3
0.85
5.5
0.85
2.7


0.9
3.3
0.9
2.2
0.9
4.9
0.9
2.0
0.9
3.6
0.9
4.7
0.9
2.4


0.95
2.5
0.95
1.8
0.95
3.5
0.95
1.7
0.95
2.6
0.95
3.3
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf


















Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.95 F1233xf +


0.17 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.17 F245cb +
0.01 F245cb +
0.95 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.17 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.95 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +


0.17 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.95 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +


0.17 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.95 F1243zf
0.01 F1243zf





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar























0
4.4
0
6.6
0
4.6
0
1.5
0
4.8
0
5.8
0
1.7


0.05
5.4
0.05
7.6
0.05
5.8
0.05
2.6
0.05
5.8
0.05
6.7
0.05
2.8


0.1
5.4
0.1
7.6
0.1
5.8
0.1
2.6
0.1
5.8
0.1
6.7
0.1
2.8


0.15
5.4
0.15
7.6
0.15
5.8
0.15
2.6
0.15
5.8
0.15
6.7
0.15
2.8


0.2
5.4
0.2
7.6
0.2
5.8
0.2
2.6
0.2
5.8
0.2
6.7
0.2
2.8


0.25
5.4
0.25
7.6
0.25
5.8
0.25
2.6
0.25
5.8
0.25
6.7
0.25
2.8


0.3
5.4
0.3
7.6
0.3
5.8
0.3
2.6
0.3
5.8
0.3
6.7
0.3
2.8


0.35
5.4
0.35
7.6
0.35
5.8
0.35
2.6
0.35
5.8
0.35
6.7
0.35
2.8


0.4
5.4
0.4
7.6
0.4
5.8
0.4
2.6
0.4
5.8
0.4
6.7
0.4
2.8


0.45
5.4
0.45
7.6
0.45
5.8
0.45
2.6
0.45
5.8
0.45
6.7
0.45
2.8


0.5
5.4
0.5
7.6
0.5
5.8
0.5
2.6
0.5
5.8
0.5
6.7
0.5
2.8


0.55
5.4
0.55
7.6
0.55
5.8
0.55
2.6
0.55
5.7
0.55
6.7
0.55
2.8


0.6
5.4
0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.6
0.6
6.7
0.6
2.8


0.65
5.4
0.65
7.6
0.65
5.8
0.65
2.6
0.65
5.5
0.65
6.6
0.65
2.8


0.7
5.4
0.7
7.6
0.7
5.8
0.7
2.6
0.7
5.4
0.7
6.5
0.7
2.8


0.75
5.3
0.75
7.4
0.75
5.8
0.75
2.6
0.75
5.1
0.75
6.3
0.75
2.8


0.8
5.0
0.8
7.1
0.8
5.8
0.8
2.5
0.8
4.8
0.8
6.1
0.8
2.7


0.85
4.6
0.85
6.5
0.85
5.8
0.85
2.3
0.85
4.3
0.85
5.6
0.85
2.5


0.9
3.9
0.9
5.5
0.9
5.0
0.9
2.1
0.9
3.6
0.9
4.7
0.9
2.2


0.95
2.8
0.95
3.8
0.95
3.5
0.95
1.7
0.95
2.6
0.95
3.4
0.95
1.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf


















Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.95 F1233xf +


0.17 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.17 F245cb +
0.01 F245cb +
0.95 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.17 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.95 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.17 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.95 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +


0.17 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.95 F1234zeZ
0.01 F1234zeZ





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar























0
3.8
0
6.6
0
4.6
0
5.7
0
1.5
0
1.9
0
1.7


0.05
4.9
0.05
7.6
0.05
5.8
0.05
6.7
0.05
2.6
0.05
3.0
0.05
2.8


0.1
4.9
0.1
7.6
0.1
5.8
0.1
6.7
0.1
2.6
0.1
3.0
0.1
2.8


0.15
4.9
0.15
7.6
0.15
5.8
0.15
6.7
0.15
2.6
0.15
3.0
0.15
2.8


0.2
4.9
0.2
7.6
0.2
5.8
0.2
6.7
0.2
2.6
0.2
3.0
0.2
2.8


0.25
4.9
0.25
7.6
0.25
5.8
0.25
6.7
0.25
2.6
0.25
3.0
0.25
2.8


0.3
4.9
0.3
7.6
0.3
5.8
0.3
6.7
0.3
2.6
0.3
3.0
0.3
2.8


0.35
4.9
0.35
7.6
0.35
5.8
0.35
6.7
0.35
2.6
0.35
3.0
0.35
2.8


0.4
4.9
0.4
7.6
0.4
5.8
0.4
6.7
0.4
2.6
0.4
3.0
0.4
2.8


0.45
4.9
0.45
7.6
0.45
5.8
0.45
6.7
0.45
2.6
0.45
3.0
0.45
2.8


0.5
4.9
0.5
7.6
0.5
5.8
0.5
6.7
0.5
2.6
0.5
3.0
0.5
2.8


0.55
4.9
0.55
7.6
0.55
5.3
0.55
6.7
0.55
2.6
0.55
3.0
0.55
2.8


0.6
4.9
0.6
7.6
0.6
5.8
0.6
6.6
0.6
2.6
0.6
3.0
0.6
2.8


0.65
4.9
0.65
7.6
0.65
5.8
0.65
6.6
0.65
2.6
0.65
3.0
0.65
2.8


0.7
4.9
0.7
7.6
0.7
5.8
0.7
6.5
0.7
2.6
0.7
3.0
0.7
2.8


0.75
4.9
0.75
7.4
0.75
5.8
0.75
6.3
0.75
2.6
0.75
3.0
0.75
2.8


0.8
4.7
0.8
7.1
0.8
5.8
0.8
6.0
0.8
2.5
0.8
2.9
0.8
2.7


0.85
4.3
0.85
6.5
0.85
5.8
0.85
5.5
0.85
2.3
0.85
2.7
0.85
2.5


0.9
3.7
0.9
5.5
0.9
5.0
0.9
4.7
0.9
2.0
0.9
2.4
0.9
2.2


0.95
2.7
0.95
3.8
0.95
3.5
0.95
3.3
0.95
1.7
0.95
1.9
0.95
1.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf


















Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.95 F1233xf +


0.17 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.17 F245cb +
0.01 F243cb +
0.95 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.17 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.95 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.17 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.95 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +


0.17 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.95 F1234zeZ
0.01 F1234zeZ





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar























0
4.4
0
6.5
0
4.6
0
5.8
0
4.8
0
2.0
0
1.7


0.05
5.5
0.05
7.6
0.05
5.8
0.05
6.7
0.05
5.8
0.05
3.1
0.05
2.8


0.1
5.5
0.1
7.6
0.1
5.8
0.1
6.7
0.1
5.8
0.1
3.1
0.1
2.8


0.15
5.5
0.15
7.6
0.15
5.8
0.15
6.7
0.15
5.8
0.15
3.1
0.15
2.8


0.2
5.5
0.2
7.6
0.2
5.8
0.2
6.7
0.2
5.8
0.2
3.1
0.2
2.8


0.25
5.5
0.25
7.6
0.25
5.8
0.25
6.7
0.25
5.8
0.25
3.1
0.25
2.8


0.3
5.5
0.3
7.6
0.3
5.8
0.3
6.7
0.3
5.8
0.3
3.1
0.3
2.8


0.35
5.5
0.35
7.6
0.35
5.8
0.35
6.7
0.35
5.8
0.35
3.1
0.35
2.8


0.4
5.5
0.4
7.6
0.4
5.8
0.4
6.7
0.4
5.8
0.4
3.1
0.4
2.8


0.45
5.5
0.45
7.6
0.45
5.8
0.45
6.7
0.45
5.8
0.45
3.1
0.45
2.8


0.5
5.5
0.5
7.6
0.5
5.8
0.5
6.7
0.5
5.8
0.5
3.1
0.5
2.8


0.55
5.5
0.55
7.6
0.55
5.8
0.55
6.7
0.55
5.7
0.55
3.1
0.55
2.8


0.6
5.5
0.6
7.6
0.6
5.8
0.6
6.7
0.6
5.6
0.6
3.1
0.6
2.8


0.65
5.5
0.65
7.6
0.55
5.8
0.65
6.6
0.65
5.5
0.65
3.1
0.65
2.8


0.7
5.5
0.7
7.6
0.7
5.8
0.7
6.5
0.7
5.4
0.7
3.1
0.7
2.8


0.75
5.3
0.75
7.4
0.75
5.8
0.75
6.3
0.75
5.1
0.75
3.1
0.75
2.8


0.8
5.1
0.8
7.1
0.8
5.8
0.8
6.1
0.8
4.8
0.8
2.9
0.8
2.7


0.85
4.6
0.85
6.5
0.85
5.8
0.85
5.6
0.85
4.3
0.85
2.7
0.85
2.5


0.9
3.9
0.9
5.5
0.9
5.0
0.9
4.7
0.9
3.6
0.9
2.4
0.9
2.2


0.95
2.8
0.95
3.8
0.95
3.5
0.95
3.4
0.95
2.6
0.95
1.9
0.95
1.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf


















Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.95 F1233xf +


0.17 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.17 F1233zdE +
0.01 F1233zdE +
0.95 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +


0.17 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.95 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +


0.17 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.95 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +


0.17 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.95 F1234zeZ
0.01 F1234zeZ





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar























0
3.9
0
6.6
0
1.9
0
5.7
0
4.8
0
1.9
0
1.7


0.05
5.0
0.05
7.6
0.05
2.6
0.05
6.7
0.05
5.8
0.05
3.0
0.05
2.8


0.1
4.9
0.1
7.6
0.1
2.6
0.1
6.7
0.1
5.8
0.1
3.0
0.1
2.8


0.15
4.9
0.15
7.6
0.15
2.6
0.15
6.7
0.15
5.8
0.15
3.0
0.15
2.8


0.2
4.9
0.2
7.6
0.2
2.6
0.2
6.7
0.2
5.8
0.2
3.0
0.3
2.8


0.25
4.9
0.25
7.6
0.25
2.6
0.25
6.7
0.25
5.8
0.25
3.0
0.25
2.8


0.3
4.9
0.3
7.6
0.3
2.6
0.3
6.7
0.3
5.8
0.3
3.0
0.3
2.8


0.35
4.9
0.35
7.6
0.35
2.6
0.35
6.7
0.35
5.8
0.35
3.0
0.35
2.8


0.4
4.9
0.4
7.6
0.4
2.6
0.4
6.7
0.4
5.8
0.4
3.0
0.4
2.8


0.45
4.9
0.45
7.6
0.45
2.6
0.45
6.7
0.45
5.8
0.45
3.0
0.45
2.8


0.5
4.9
0.5
7.6
0.5
2.6
0.5
6.7
0.5
5.7
0.5
3.0
0.5
2.8


0.55
4.9
0.55
7.6
0.55
2.6
0.55
6.7
0.55
5.7
0.55
3.0
0.55
2.8


0.6
4.9
0.6
7.6
0.6
2.6
0.6
6.6
0.6
5.6
0.6
3.0
0.5
2.8


0.65
4.9
0.65
7.6
0.65
2.6
0.65
6.5
0.65
5.5
0.65
3.0
0.65
2.8


0.7
4.8
0.7
7.6
0.7
2.6
0.7
6.5
0.7
5.3
0.7
3.0
0.7
2.8


0.75
4.7
0.75
7.4
0.75
2.6
0.75
6.3
0.75
5.1
0.75
3.0
0.75
2.8


0.8
4.4
0.8
7.1
0.8
2.5
0.8
6.0
0.8
4.8
0.8
2.9
0.8
2.6


0.85
4.0
0.85
6.5
0.85
2.3
0.85
5.5
0.85
4.3
0.85
2.7
0.85
2.5


0.9
3.4
0.9
5.5
0.9
2.0
0.9
4.7
0.9
3.6
0.9
2.4
0.9
2.2


0.95
2.5
0.95
3.8
0.95
1.7
0.95
3.3
0.95
2.6
0.95
1.9
0.95
1.8


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf


















Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.15 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +


0.17 F245cb +
0.01 F245cb +
0.95 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +


0.17 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.95 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +


0.17 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.95 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +


0.17 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.95 F1234zeZ +


0.17 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.95 F1243zf
0.01 F1243zf





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar























0
4.3
0
6.6
0
4.6
0
1.5
0
4.8
0
5.8
0
2.0


0.05
5.3
0.05
7.6
0.05
5.8
0.05
2.6
0.05
5.8
0.05
6.7
0.05
3.1


0.1
5.3
0.1
7.6
0.1
5.8
0.1
2.6
0.1
5.8
0.1
6.7
0.1
3.1


0.15
5.3
0.15
7.6
0.15
5.8
0.15
2.6
0.15
5.8
0.15
6.7
0.15
3.1


0.2
5.3
0.2
7.6
0.2
5.8
0.2
2.6
0.2
5.8
0.2
6.7
0.2
3.1


0.25
5.3
0.25
7.6
0.25
5.8
0.25
2.6
0.25
5.8
0.25
6.7
0.25
3.1


0.3
5.3
0.3
7.6
0.3
5.8
0.3
2.6
0.3
5.8
0.3
6.7
0.3
3.1


0.35
5.3
0.35
7.6
0.35
5.8
0.35
2.6
0.35
5.8
0.35
6.7
0.35
3.1


0.4
5.3
0.4
7.6
0.4
5.8
0.4
2.6
0.4
5.8
0.4
6.7
0.4
3.1


0.45
5.3
0.45
7.6
0.45
5.8
0.45
2.6
0.45
5.8
0.45
6.7
0.45
3.1


0.5
5.3
0.5
7.6
0.5
5.8
0.5
2.6
0.5
5.8
0.5
6.7
0.5
3.1


0.55
5.3
0.55
7.6
0.55
5.8
0.55
2.6
0.55
5.7
0.55
6.7
0.55
3.1


0.6
5.3
0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.6
0.6
6.7
0.5
3.1


0.65
5.3
0.65
7.6
0.65
5.8
0.65
2.6
0.65
5.5
0.65
6.6
0.65
3.1


0.7
5.3
0.7
7.6
0.7
5.8
0.7
2.6
0.7
5.4
0.7
6.5
0.7
3.1


0.75
5.2
0.75
7.4
0.75
5.8
0.75
2.6
0.75
5.1
0.75
6.3
0.75
3.1


0.8
4.9
0.8
7.1
0.8
5.8
0.8
2.5
0.8
4.3
0.8
6.1
0.8
2.9


0.85
4.5
0.85
6.5
0.85
5.8
0.85
2.3
0.85
4.3
0.85
5.6
0.85
2.7


0.9
3.9
0.9
5.5
0.9
5.0
0.9
2.1
0.9
3.6
0.9
4.7
0.9
2.4


0.95
2.8
0.95
3.8
0.95
3.5
0.95
1.7
0.95
2.6
0.95
3.4
0.95
1.9


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









HF-HFF-1243zf-HCFC-244bb-HFC-245fa-Trifluoropropyne-HFO-1225yeZ-HFO-1225zc




















Organics
Organics
Organics
Organics
Organics
Organics
Organics



0.15 F1243zf +
0.95 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +



0.17 F244bb +
0.01 F244bb +
0.95 F244bb +
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +



0.17 F245fa +
0.01 F245fa +
0.01 F245fa +
0.95 F245fa +
0.01 F245fa +
0.01 F245fa +
0.01 F245fa +



0.17 TFP +
0.01 TFP +
0.01 TFP +
0.01 TFP +
0.95 TFP +
0.01 TFP +
0.01 TFP +



0.17 F1225yeZ +
0.01 F1225yeZ +
0.01 F1225yeZ +
0.01 F1225yeZ +
0.01 F1225yeZ +
0.95 F1225yeZ +
0.01 F1225yeZ +



0.17 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.95 F1225zc



TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL


MASS-
PRES-
PRES-
PRES-
PRES-
PRES-
PRES-
PRES-


FRAC
SURE
SURE
SURE
SURE
SURE
SURE
SURE


HF
bar
bar
bar
bar
bar
bar
bar






















0
5.5
5.8
1.0
1.8
11.3
5.2
5.3


0.05
6.5
6.8
2.1
2.9
12.1
6.2
6.3


0.1
6.5
6.8
2.1
2.9
12.0
6.2
6.3


0.15
6.4
6.8
2.1
2.9
11.9
6.2
6.3


0.2
6.4
6.8
2.1
2.9
11.8
6.2
6.3


0.25
6.4
6.8
2.1
2.9
11.7
6.2
6.3


0.3
6.4
6.8
2.1
2.9
11.6
6.2
6.3


0.35
6.4
6.8
2.1
2.9
11.5
6.2
6.3


0.4
6.4
6.8
2.1
2.9
11.5
6.2
6.3


0.45
6.4
6.8
2.1
2.9
11.5
6.2
6.3


0.5
6.3
6.7
2.1
2.9
11.5
6.2
6.3


0.55
6.3
6.7
2.1
2.9
11.5
6.2
6.2


0.6
6.3
6.7
2.1
2.9
11.6
6.2
6.1


0.65
6.2
6.6
2.1
2.9
11.6
6.2
6.0


0.7
6.2
6.6
2.1
2.9
11.7
6.1
5.9


0.75
6.0
6.4
2.0
2.8
11.6
5.9
5.6


0.8
5.7
6.1
2.0
2.8
11.3
5.6
5.2


0.85
5.2
5.6
2.0
2.6
10.5
5.1
4.7


0.9
4.4
4.8
1.9
2.3
8.9
4.2
3.9


0.95
3.1
3.4
1.6
1.6
6.0
3.0
2.7


1
1.2
1.2
1.2
1.2
1.2
1.2
1.2









EXAMPLE 14
Temperature and Pressure Range of System with 7 Compounds














Boiling point range










Temperature
Pressure


System with 7 compounds
° C.
bar abs





HC-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.0 to ~11.6


HCFO-1233zdE-HFO-1234zeE-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~0.9 to ~11.5


HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.1 to ~11.6


HFO-1234zeE-HFO-1234zeZ-HFO-1243zf




HF-HCFO-1233xf-HFO-1234yf-HCFO-
0 to 40
~0.9 to ~11.5


1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-




1243zf




HF-HCFO-1233xf-HFC-245cb-HCFO-
0 to 40
~0.9 to ~10.3


1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-




1243zf




HF-HFO-1234yf-HFC-245b-HCFO-1233zdE-
0 to 40
~1.0 to ~11.6


HFO-1234zeE-HFO-1234zeZ-HFO-1243zf




HF-HFF-1243zf-HCFC-244bb-HFC-245fa-
0 to 40
~0.7 to ~17.5


Trifluoropropyne-HFO-1225yeZ-HFO-1225zc









EXAMPLE 15
Decantation Range of Systems with 7 Compounds














Decantation ranges



Mass percentage of HF



Temperature










System with 7 compounds
0° C.
25° C.
40° C.





HC-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
10-65
20


HCFO-1233zdE-HFO-1234zeE-HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-70
 5-70
10-60


HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
10-65
*


HFO-1234zeE-HFO-1234zeZ-HFO-1243zf





HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-
5-75
10-65
15-45


HFO-1234zeE-HFO-1234zeZ-HFO-1243zf





HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-
5-75
 5-70
10-55


HFO-1234zeE-HFO-1234zeZ-HFO-1243zf





HF-HFO-1234yf-HFC-245b-HCFO-1233zdE-
5-75
10-65
*


HFO-1234zeE-HFO-1234zeZ-HFO-1243zf





HF-HFF-1243zf-HCFC-244bb-HFC-245fa-
5-75
10-70
*


Trifluoropropyne-HFO-1225yeZ-HFO-1225zc












EXAMPLE 16
Systems with 8 Compounds

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf


















Organics
Organics
Organics
Organics
Organics
Organics
Organics


0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.16 F1233xf +


0.94 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.14 F1234yf +


0.01 F245cb +
0.94 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.14 F245cb +


0.01 F1233zdE +
0.01 F1233zdE +
0.94 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.14 F1233zdE +


0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.94 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.14 F1234zeE +


0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.94 F1234zeZ +
0.01 F1234zeZ +
0.14 F1234zeZ +


0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.94 F1243zf
0.14 F1243zf





















TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL


MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-


FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE


HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar























0
6
0
4.6
0
1.5
0
4.8
0
2.0
0
5.7
0
3.9


0.05
7.6
0.05
5.8
0.05
2.6
0.05
5.8
0.05
3.1
0.05
6.7
0.05
5.0


0.1
7.6
0.1
5.8
0.1
2.6
0.1
5.8
0.1
3.1
0.1
6.7
0.1
5.0


0.15
7.6
0.15
5.8
0.15
2.6
0.15
5.8
0.15
3.1
0.15
6.7
0.15
5.0


0.2
7.6
0.2
5.8
0.2
2.6
0.2
5.8
0.2
3.1
0.2
6.7
0.2
5.0


0.25
7.6
0.25
5.8
0.25
2.6
0.25
5.8
0.25
3.1
0.25
6.7
0.25
5.0


0.3
7.6
0.3
5.8
0.3
2.6
0.3
5.8
0.3
3.1
0.3
6.7
0.3
5.0


0.35
7.6
0.35
5.8
0.35
2.6
0.35
5.8
0.35
3.1
0.35
6.7
0.35
5.0


0.4
7.6
0.4
5.8
0.4
2.6
0.4
5.8
0.4
3.1
0.4
6.7
0.4
5.0


0.45
7.6
0.45
5.8
0.45
2.6
0.45
5.8
0.45
3.1
0.45
6.7
0.45
5.0


0.5
7.6
0.5
5.8
0.5
2.6
0.5
5.7
0.5
3.1
0.5
6.7
0.5
5.0


0.55
7.6
0.55
5.8
0.55
2.6
0.55
5.7
0.55
3.1
0.55
6.7
0.55
5.0


0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.6
0.6
3.1
0.6
6.6
0.6
5.0


0.65
7.6
0.65
5.8
0.65
2.6
0.65
5.5
0.65
3.1
0.65
6.6
0.65
5.0


0.7
7.5
0.7
5.8
0.7
2.6
0.7
5.4
0.7
3.1
0.7
6.5
0.7
5.0


0.75
7.4
0.75
5.8
0.75
2.6
0.75
5.1
0.75
3.1
0.75
6.3
0.75
4.9


0.8
7.1
0.8
5.8
0.8
2.5
0.8
4.8
0.8
2.9
0.8
6.0
0.8
4.6


0.85
6.5
0.85
5.8
0.85
2.3
0.85
4.3
0.85
2.7
0.85
5.5
0.85
4.2


0.9
5.5
0.9
5.0
0.9
2.1
0.9
3.6
0.9
2.4
0.9
4.7
0.9
3.9


0.95
3.0
0.95
3.5
0.95
1.7
0.95
2.6
0.95
1.9
0.95
3.3
0.95
2.6


1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2









EXAMPLE 17
Temperature and Pressure Range of System with 8 Compounds














Boiling point range










Temperature
Pressure


System with 8 compounds
° C.
bar abs





HF-HCFO-1233xf-HFO-1234yf-HFC-
0 to 40
~1.0 to ~11.5


245cb-HCFO-1233zdE-HFO-1234zeE-




HFO-1234zeZ-HFO-1243zf









EXAMPLE 18
Decantation Ranges of System with 8 Compounds














Decantation ranges



Mass percentage of HF



Temperature










System with 8 compounds
0° C.
25° C.
40° C.





HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75%
5-70%
15-50%


HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-





HFO-1243zf









EXAMPLE 19
Systems with 13 Compounds

HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFC-1243zf-HCFC-244bb-TFP-HFC-245fa-HFO-1225yeZ-HFO-1225zc


















Organics 0.087
Organics
Organics
Organics
Organics



012346F + 0.087
0.88 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +



F245cb + 0.083
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +



F1233xf + 0.083
0.01 F1233xf +
0.89 F1233xf +
0.01 F1233xf +
0.01 F1233xf +



F1233zdE + 0.083
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.89 F1233zdE +



F1234zeE + 0.083
0.01 F1234zeE +
0.01 F1234zeE +
0.89 F1234zeE +
0.01 F1234zeE +



F1234zeZ + 0.083
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +



F1243zf + 0.083
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +



F244bb + 0.083
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +



F245fa + 0.083
0.01 F245fa +
0.01 F245fa +
0.01 F245fa +
0.01 F245fa +



TFP + 0.083
0.01 TFP + 0.01
0.01 TFP + 0.01
0.01 TFP + 0.01
0.01 TFP + 0.01



F1225yeZ + 0.83
F1225yeZ + 0.1
F1225yeZ + 0.1
F1225yeZ + 0.1
F1225yeZ + 0.1



F1225zc
F1225zc
F1225zc
F1225zc
F1225zc



TOTAL
TOTAL
TOTAL
TOTAL
TOTAL


MASSFRAC
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE


HF
bar
bar
bar
bar
bar




















0
4.5
6.5
1.0
4.8
1.7


0.05
5.6
7.5
3.0
5.8
2.9


0.1
5.6
7.5
3.0
5.8
2.9


0.15
5.6
7.5
3.0
5.8
2.8


0.2
5.6
7.5
3.0
5.8
2.8


0.25
5.6
7.5
3.0
5.8
2.8


0.3
5.6
7.5
3.0
5.8
2.8


0.35
5.6
7.5
3.0
5.8
2.8


0.4
5.6
7.5
3.0
5.8
2.8


0.45
5.5
7.5
3.0
5.8
2.8


0.5
5.5
7 5
3.0
5.8
2.8


0.55
5.5
7.5
3.0
5.7
2.8


0.6
5.5
7.5
3.0
5.6
2.8


0.65
5.5
7.5
3.0
5.5
2.8


0.7
5.4
7.5
3.0
5.4
2.8


0.75
5.3
7.3
3.0
5.2
2.8


0.8
5.1
7.0
2.8
4.8
2.7


0.85
4.6
6.4
2.8
4.3
2.5


0.9
3.9
5.4
2.3
3.6
2.2


0.95
2.8
3.7
1.8
2.6
1.8


1
1.2
1.2
1.2
1.2
1.2









EXAMPLE 20
Temperature and Pressure Range of System with 13 Compounds














Boiling point range










Temperature
Pressure


System with 13 compounds
° C.
bar abs





HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HCFO-1233zdE-
0 to 40
~0.7 to ~18.0


HFO-1234zeE-HFO-1234zeZ-HFC-1243zf-HCFC-244bb-




TFP-HFC-245fa-HFO-1225yeZ-HFO-1225zc









EXAMPLE 21
Decantation Ranges of System with 13 Compounds














Decantation ranges



Mass percentage of HF



Temperature










System with 13 compounds
0° C.
25° C.
40° C.





HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HCFO-
5-75%
10-70%
15-60%


1233zdE-HFO-1234zeE-HFO-1234zeZ-HFC-1243zf-HCFC-





244bb-TFP-HFC-245fa-HFO-1225yeZ-HFO-1225zc











Claims
  • 1. An azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, 3,3,3-trifluoropropene and one or more (hydro)halocarbon compounds comprising between 1 and 3 carbon atoms.
  • 2. The composition as claimed in claim 1, in which the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, and at least one or more compounds chosen from 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.
  • 3. The composition as claimed in claim 1, in which the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene and at least one or more organic compounds chosen from E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.
  • 4. The composition as claimed in claim 1, in which the composition is heteroazeotropic or quasi-heteroazeotropic.
  • 5. The composition as claimed in claim 1, in which the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, E-1,3,3,3-tetrafluoropropene and optionally one or more organic compounds chosen from Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.
  • 6. The composition as claimed in claim 1, in which the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, Z-1,3,3,3-tetrafluoropropene and optionally one or more organic compounds chosen from 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.
  • 7. The composition as claimed in claim 1, in which the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene and optionally one or more organic compounds chosen from E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.
  • 8. The composition as claimed in claim 1, in which the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, E-3,3,3-trifluoro-1-chloropropene and optionally one or more organic compounds chosen from 1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.
  • 9. The composition as claimed in claim 1, in which the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,2,2-pentafluoropropane and optionally 2,3,3,3-tetrafluoropropene.
  • 10. The composition as claimed in claim 1, in which the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene and 2,3,3,3-tetrafluoropropene.
  • 11. The composition as claimed in claim 1, in which the composition comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of the organic compounds.
  • 12. The composition as claimed in claim 1, in which the composition comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of the organic compounds.
  • 13. The composition as claimed in claim 1, in which the boiling point of said composition is between −20° C. and 80° C., and at a pressure of between 0.1 and 44 bar absolute.
  • 14. The composition as claimed in claim 1, in which the boiling point of said composition is between 0° C. and 40° C. and at a pressure of between 0.7 and 18 bar absolute.
  • 15. The composition as claimed in claim 1, in which the boiling point of said composition is between 0° C. and 40° C. and at a pressure of between 0.9 and 12.5 bar absolute.
Priority Claims (1)
Number Date Country Kind
13.52486 Mar 2013 FR national
PCT Information
Filing Document Filing Date Country Kind
PCT/FR2014/050371 2/24/2014 WO 00