Composition comprising HF and 3,3,3-trifluoropropene

The present invention relates to azeotropic or quasi-azeotropic compositions comprising 3,3,3-trifluoropropene and hydrogen fluoride. These compositions may originate from intermediate compositions in the production of 3,3,3-trifluoropropene and are generally useful in processes for recycling hydrogen fluoride.

The manufacture of 3,3,3-trifluoropropene accompanied by a multitude of by-products, having a boiling point close to HFO-1243zf, leads to relatively complex and expensive purification steps. The difficulty encountered during the purification of HFO-1243zf generally implies an appreciable loss of desired product. Furthermore, these by-products may form azeotropic compositions with 1,3,3,3-tetrafluoropropene, making separation by distillation simple, very difficult, or even impossible.

Fluids based on 3,3,3-trifluoropropene have found numerous applications in varied industrial fields, especially as heat-transfer fluid, propellants, foaming agents, swelling agents, gaseous dielectrics, polymerization medium or monomer, support fluids, abrasive agents, drying agents and fluids for power production units.

Particular importance is given to fluids that have a low impact on the environment.

The subject of the present invention is an azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, 3,3,3-trifluoropropene and one or more (hydro)halocarbon compounds comprising between 1 and 3 carbon atoms. According to one embodiment of the invention, the composition is heteroazeotropic or quasi-heteroazeotropic.

A heteroazeotropic or quasi-heteroazeotropic mixture is an azeotropic or quasi-azeotropic mixture in which the condensed liquid forms two immiscible solutions that can be readily separated, for example by decantation.

The term “quasi-azeotropic” or “quasi-heteroazeotropic” has a broad meaning and is intended to include compositions that are strictly azeotropic or strictly heteroazeotropic and those that behave like an azeotropic or heteroazeotropic mixture.

A mixture is azeotropic when the pressure at the dew point is equal to that at the bubble formation point, which means that the vapor composition is equal to that of the condensed liquid.

A mixture is considered as quasi-azeotropic when the pressure at the dew point is substantially equal to that at the bubble formation point, which means that the vapor composition is substantially equal to that of the condensed liquid.

Another way of characterizing a mixture as quasi-azeotropic when the pressure difference between the pressure at the dew point and the pressure at the bubble formation point is low, preferentially less than or equal to 5%, on the basis of the pressure at the bubble formation point.

The compositions according to the invention especially concern the following compounds, the acronyms of which represent:

- HF: hydrogen fluoride
- HCC-40: chloromethane, or CH₃Cl
- HCFC-115: chloropentafluoroethane, or C₂F₅Cl
- HCFC-124: chlorotetrafluoroethane, or C₂HF₄Cl
- HFC-125: pentafluoroethane, or C₂HF₅
- HCFC-133a: 1-chloro-2,2,2-trifluoroethane, or C₂H₂F₃Cl
- HFC-134a: 1,1,1,2-tetrafluoroethane, or C₂H₂F₄
- HCFC-142b: 1-chloro-1,1-difluoroethane, or C₂H₃F₂Cl
- HFC-143a: 1,1,1-trifluoroethane, or C₂H₃F₃
- HFC-152a: 1,1-difluoroethane, or C₂H₄F₂
- HFO-1132: 1,2-difluoroethylene, or C₂H₂F₂
- HFO-1141: fluoroethylene, or C₂H₃F
- HFO-1234yf: 2,3,3,3-tetrafluoropropene or CH₂═CF—CF₃
- HFC-245cb: 1,1,1,2,2-pentafluoropropane or CF₃—CF₂—CH₃
- HFO-1234zeE: E-1,3,3,3-tetrafluoropropene or E-CF₃—CH═CHF
- HFO-1234zeZ: Z-1,3,3,3-tetrafluoropropene or Z—CF₃—CH═CHF
- HFO-1243zf: 3,3,3-trifluoropropene or CF₃—CH═CH₂
- HCFO-1233xf: 3,3,3-trifluoro-2-chloropropene or CF₃—CCl═CH₂
- HCFO-1233zdE: E-3,3,3-trifluoro-1-chloropropene or E-CF₃—CH═CHCl
- HCFO-1233zdZ: Z-3,3,3-trifluoro-1-chloropropene or Z—CF₃—CH═CHCl
- HFO-1225yeZ: Z-1,1,1,2,3-pentafluoropropene or Z—CHF═CF—CF₃
- HFO-1225yeE: E-1,1,1,2,3-pentafluoropropene or E-CHF═CF—CF₃
- HFO-1225zc: 1,1,3,3,3-pentafluoropropene or CF₂═CH—CF₃
- HFO-1225yc: 1,1,2,3,3-pentafluoropropene or CF₂═CF—CF₂
- HCFC-1214: dichlorotetrafluoropropene, or C₃F₄Cl₂
- HCFO-1215: chloropentafluoropropene, or C₃F₅Cl
- HFO-1216: hexafluoropropene, or C₃F₆
- HCFO-1223: dichlorotrifluoropropene, or C₃HF₃Cl₂
- HCFO-1224: chlorotetrafluoropropene, or C₃HF₄Cl
- HCFO-1232: dichlorodifluoropropene, or C₃H₂F₂Cl₂
- HCFO-1233xc: 1,1,3-trifluoro-2-chloropropene or CH₂F—CCl═CF₂
- HCFO-1233xe: 1,3,3-trifluoro-2-chloropropene or CHF₂—CCl═CHF
- HCFO-1233yb: 1,2,3-trifluoro-1-chloropropene or CH₂F—CF═CFCl
- HCFO-1233yc: 1,1,2-trifluoro-3-chloropropene or CH₂Cl—CF═CF₂
- HCFO-1233yd: 2,3,3-trifluoro-1-chloropropene or CHF₂—CF═CHCl
- HCFO-1233ye: 1,2,3-trifluoro-3-chloropropene or CHClF—CF═CHF
- HCFO-1233yf: 2,3,3-trifluoro-3-chloropropene or CClF₂—CF═CH₂
- HCFO-1233zb: 1,3,3-trifluoro-1-chloropropene or CHF₂—CH═CFCl
- HCFO-1233zc: 1,1,3-trifluoro-3-chloropropene or CHClF—CH═CF₂
- HCFO-1233ze: 1,3,3-trifluoro-3-chloropropene or CClF₂—CH═CHF
- HFO-1234yc: 1,2,3-tetrafluoropropene or CF₂═CF—CH₂F
- HFO-1234ye: 2,3,3-tetrafluoropropene or CHF═CF—CHF₂
- HFO-1234zc: 1,3,3-tetrafluoropropene or CF₂═CH—CHF₂
- HCFO-1242: chlorodifluoropropene, or C₃H₃F₂Cl
- HFO-1243yc: 1,1,2-trifluoropropene or CH₃—CF═CF₂
- HFO-1243ye: 1,2,3-trifluoropropene or CH₂F—CF═CHF
- HFO-1243yf: 2,3,3-trifluoropropene or CHF₂—CF═CH₂
- HFO-1243zc: 1,1,3-trifluoropropene or CH₂F—CH═CF₂
- HFO-1243ze: 1,3,3-trifluoropropene or CHF₂—CH═CHF
- HCFO-1251: chlorofluoropropene, or C₃H₄FCl
- HFO-1252: difluoropropene, or C₃H₄F₂
- HFO-216: hexafluoropropene, or C₃F₆Cl₂
- HCFO-217: chloroheptafluoropropane, or C₃F₇Cl
- HFC-218: octafluoropropane, or C₃F₈
- HCFC-225: dichloropentafluoropropane, or C₃HF₅Cl₂
- HCFC-226: chlorohexafluoropropane, or C₃HF₆Cl
- HFC-227: heptafluoropropane, or C₃HF₇
- HCFC-234: dichlorotetrafluoropropane, or C₃H₂F₄Cl₂
- HCFC-235: chloropentafluoropropane, or C₃H₂F₅Cl
- HFC-236: hexafluoropropane, or C₃H₂F₆
- HCFC-243: dichlorotrifluoropropane, or C₃H₃F₃Cl₂
- HCFC-244: chlorotetrafluoropropane, or C₃H₃F₄Cl
- HCFC-244bb: 2-chloro-1,1,1,2-tetrafluoropropane or CF₃—CFCl—CH₃
- HFC-245fa: 1,1,1,3,3-pentafluoropropane or CF₃—CH₂—CHF₂
- HFC-245ea: 1,1,2,3,3-pentafluoropropane or CHF₂—CHF—CHF₂
- HFC-245eb: 1,1,1,2,3-pentafluoropropane or CF₃—CHF—CH₂F
- HFC-245ca: 1,1,2,2,3-pentafluoropropane or CHF₂—CF₂—CH₂F
- HCFC-253: chlorotrifluoropropane, or C₃H₄F₃Cl
- HFC-254: tetrafluoropropane, or C₃H₄F₄
- HCFC-262: chlorodifluoropropane, or C₃H₅F₂Cl
- HFC-263: trifluoropropane, or C₃H₅F₃
- trifluoropropyne: CF₃—C≡CH

The composition according to the invention may optionally be a mixture of one or more azeotropes and/or heteroazeotropes of ternary, quaternary, penternary systems, systems with six compounds, systems with seven compounds, systems with eight or more compounds.

The compound(s) containing 1 and/or 2 carbon atoms may be chosen especially from chloromethane, chloropentafluoroethane, 1-chloro-1,2,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, pentafluoroethane, 1-chloro-1,2,2-trifluoroethane, 1-chloro-2,2,2-trifluoroethane, 1,1,2,2-tetrafluoroethane, 1,1,1,2-tetrafluoroethane, 1-chloro-1,2-difluoroethane, 1-chloro-1,1-difluoroethane, 1,1,2-trifluoroethane, 1,1,1-trifluoroethane, 1,1,2-trifluoroethane, 1,1-difluoroethane, 1,2-difluoroethylene and fluoroethylene.

The compound(s) containing 3 carbon atoms may be chosen especially from 1,2-dichloro-1,1,2,3,3,3-hexafluoropropane, 1,3-dichloro-1,1,2,2,3,3-hexafluoropropane, 1,1-dichloro-1,2,2,3,3,3-hexafluoropropane, 2,2-dichloro-1,1,1,3,3,3-hexafluoropropane, 1-chloro-1,1,2,2,3,3,3-heptafluoropropane, 2-chloro-1,1,1,2,3,3,3-heptafluoropropane, octafluoropropane, dichloropentafluoropropane, 2,2-dichloro-1,1,1,3,3-pentafluoropropane, 2,3-dichloro-1,1,1,2,3-pentafluoropropane, 1,2-dichloro-1,1,2,3,3-pentafluoropropane, 3,3-dichloro-1,1,1,2,2-pentafluoropropane, 1,3-dichloro-1,1,2,2,3-pentafluoropropane, 1,1-dichloro-1,2,2,3,3-pentafluoropropane, 1,2-dichloro-1,1,3,3,3-pentafluoropropane, 1,3-dichloro-1,1,2,3,3-pentafluoropropane, 1,1-dichloro-1,2,3,3,3-pentafluoropropane, chlorohexafluoropropane, 2-chloro-1,1,1,2,3,3-hexafluoropropane, 3-chloro-1,1,1,2,2,3-hexafluoropropane, 1-chloro-1,1,2,2,3,3-hexafluoropropane, 2-chloro-1,1,1,3,3,3-hexafluoropropane, 1-chloro-1,1,2,3,3,3-hexafluoropropane, 1,1,2,2,3,3,3-heptafluoropropane, 1,1,1,2,3,3,3-Heptafluoropropane, dichlorotetrafluoropropane, 2,2-dichloro-1,1,3,3-tetrafluoropropane, 2,2-dichloro-1,1,1,3-tetrafluoropropane, 1,2-dichloro-1,2,3,3-tetrafluoropropane, 2,3-dichloro-1,1,1,2-tetrafluoropropane, 1,2-dichloro-1,1,2,3-tetrafluoropropane, 1,3-dichloro-1,2,2,3-tetrafluoropropane, 1,1-dichloro-2,2,3,3-tetrafluoropropane, 1,3-dichloro-1,1,2,2-tetrafluoropropane, 1,1-dichloro-1,2,2,3-tetrafluoropropane, 2,3-dichloro-1,1,1,3-tetrafluoropropane, 1,3-dichloro-1,1,3,3-tetrafluoropropane, 1,3-dichloro-1,1,3,3-tetrafluoropropane, 1,1-dichloro-1,3,3,3-tetrafluoropropane, 1,1-dichloro-2,3,3,3-tetrafluoropropane, 1,3-dichloro-1,1,2,3-tetrafluoropropane, 1,1-dichloro-1,2,3,3-tetrafluoropropane, chloropentafluoropropane, 1-chloro-1,2,2,3,3-pentafluoropropane, 3-chloro-1,1,1,2,3-pentafluoropropane, 1-chloro-1,1,2,2,3-pentafluoropropane, 2-chloro-1,1,1,3,3-pentafluoropropane, 1-chloro-1,1,3,3,3-pentafluoropropane, 1-chloro-1,1,2,3,3-pentafluoropropane, 3-chloro-1,1,1,2,2-pentafluoropropane, 2-chloro-1,1,2,3,3-pentafluoropropane, 2-chloro-1,1,1,2,3-pentafluoropropane, 1,1,1,2,2,3-hexafluoropropane, 1,1,1,2,3,3-hexafluoropropane, 1,1,1,3,3,3-hexafluoropropane, 1,1,2,2,3,3-hexafluoropropane, dichlorotrifluoropropane, 1,1-dichloro-3,3,3-trifluoropropane, 1,3-dichloro-1,1,3-trifluoropropane, 1,1-dichloro-1,3,3-trifluoropropane, 1,3-dichloro-1,2,3-trifluoropropane, 1,1-dichloro-2,3,3-trifluoropropane, 1,3-dichloro-1,1,2-trifluoropropane, 1,1-dichloro-1,2,3-trifluoropropane, 1,2-dichloro-1,3,3-trifluoropropane, 2,3-dichloro-1,1,1-trifluoropropane, 1,2-dichloro-1,1,3-trifluoropropane, 1,3-dichloro-1,2,2-trifluoropropane, 1,1-dichloro-2,2,3-trifluoropropane, 1,1-dichloro-1,2,2-trifluoropropane, 2,3-dichloro-1,1,2-trifluoropropane, 1,2-dichloro-1,2,3-trifluoropropane, 1,2-dichloro-1,1,2-trifluoropropane, 2,2-dichloro-1,1,3-trifluoropropane, 2,2-dichloro-3,3,3-trifluoropropane, chlorotetrafluoropropane, 2-chloro-1,2,3,3-tetrafluoropropane, 2-chloro-1,1,1,2-tetrafluoropropane, 3-chloro-1,1,2,2-tetrafluoropropane, 1-chloro-1,2,2,3-tetrafluoropropane, 1-chloro-1,1,2,2-tetrafluoropropane, 2-chloro-1,1,3,3-tetrafluoropropane, 2-chloro-1,1,1,3-tetrafluoropropane, 3-chloro-1,1,2,3-tetrafluoropropane, 3-chloro-1,1,1,2-tetrafluoropropane, 1-chloro-1,1,2,3-tetrafluoropropane, 3-chloro-1,1,1,3-tetrafluoropropane, 1-chloro-1,1,3,3-tetrafluoropropane, pentafluoropropane, 1,1,2,2,3-pentafluoropropane, 1,1,2,3,3-pentafluoropropane, 1,1,1,2,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, chlorotrifluoropropane, 2-chloro-1,2,3-trifluoropropane, 2-chloro-1,1,2-trifluoropropane, 1-chloro-2,2,3-trifluoropropane, 1-chloro-1,2,2-trifluoropropane, 3-chloro-1,1,2-trifluoropropane, 1-chloro-1,2,3-trifluoropropane, 1-chloro-1,1,2-trifluoropropane, 3-chloro-1,3,3-trifluoropropane, 3-chloro-1,1,1-trifluoropropane, 1-chloro-1,1,3-trifluoropropane, 2-chloro-1,1,3-trifluoropropane, 2-chloro-1,1,1-trifluoropropane, 1,1,2,2-tetrafluoropropane, 1,1,1,3-tetrafluoropropane, 1,1,2,3-tetrafluoropropane, 1,1,1,2-tetrafluoropropane, 1,2,2,3-tetrafluoropropane, 1,1,3,3-tetrafluoropropane, chlorodifluoropropane, 1-chloro-2,2-difluoropropane, 3-chloro-1,1-difluoropropane, 1-chloro-1,3-difluoropropane, 1-chloro-1,1-difluoropropane, 1-chloro-2,3-difluoropropane, 1-chloro-1,2-difluoropropane, 2-chloro-1,3-difluoropropane, 2-chloro-1,1-difluoropropane, 2-chloro-1,2-difluoropropane, trifluoropropane, 1,1,1-trifluoropropane, 1,1,3-trifluoropropane, 1,2,3-trifluoropropane, 1,1,2-trifluoropropane, 1,2,2-trifluoropropane, dichlorotetrafluoropropene, 1,2-dichloro-1,3,3,3-tetrafluoropropene, 1,1-dichloro-2,3,3,3-tetrafluoropropene, 1,3-dichloro-1,2,3,3-tetrafluoropropene, 2,3-dichloro-1,1,3,3-tetrafluoropropene, 3,3-dichloro-1,1,2,3-tetrafluoropropene, chloropentafluoropropene, 1-chloropentafluoropropene, 2-chloropentafluoropropene, 3-chloropentafluoropropene, hexafluoropropene, dichlorotrifluoropropene, 1,1-dichloro-3,3,3-trifluoropropene, 1,2-dichloro-3,3,3-trifluoropropene, 2,3-dichloro-1,3,3-trifluoropropene, 1,3-dichloro-2,3,3-trifluoropropene, 1,2-dichloro-1,3,3-trifluoropropene, 2,3-dichloro-1,1,3-trifluoropropene, 1,1-dichloro-2,3,3-trifluoropropene, 1,3-dichloro-1,2,3-trifluoropropene, 3,3-dichloro-1,1,2-trifluoropropene, 3,3-dichloro-1,2,3-trifluoropropene, 1,3-dichloro-1,3,3-trifluoropropene, 3,3-dichloro-1,1,3-trifluoropropene, 1-chloro-2,3,3,3-tetrafluoropropene, 1-chloro-1,3,3,3-tetrafluoropropene, 2-chloro-1,3,3,3-tetrafluoropropene, 3-chloro-1,2,3,3-tetrafluoropropene, 3-chloro-1,1,3,3-tetrafluoropropene, 2-chloro-1,1,3,3-tetrafluoropropene, 1-chloro-1,2,3,3-tetrafluoropropene, 3-chloro-1,1,2,3-tetrafluoropropene, 1,2,3,3,3-pentafluoropropene, 1,1,3,3,3-pentafluoropropene, 1,1,2,3,3-pentafluoropropene, dichlorodifluoropropene, 2,3-dichloro-3,3-difluoropropene, 1,2-dichloro-1,3-difluoropropene, 2,3-dichloro-1,1-difluoropropene, 1,2-dichloro-3,3-difluoropropene, 2,3-dichloro-1,3-difluoropropene, 1,1-dichloro-2,3-difluoropropene, 1,3-dichloro-1,2-difluoropropene, 1,3-dichloro-2,3-difluoropropene, 3,3-dichloro-1,2-difluoropropene, 3,3-dichloro-2,3-difluoropropene, 1,1-dichloro-3,3-difluoropropene, 1,3-dichloro-1,3-difluoropropene, 3,3-dichloro-1,1-difluoropropene, 1,3-dichloro-3,3-difluoropropene, 3,3-dichloro-1,3-difluoropropene, chlorotrifluoropropene, 2-chloro-1,1,3-trifluoropropene, 2-chloro-1,3,3-trifluoropropene, 1-chloro-1,2,3-trifluoropropene, 3-chloro-1,1,2-trifluoropropene, 1-chloro-2,3,3-trifluoropropene, 3-chloro-1,2,3-trifluoropropene, 3-chloro-2,3,3-trifluoropropene, 1-chloro-1,3,3-trifluoropropene, 3-chloro-1,1,3-trifluoropropene, 3-chloro-1,3,3-trifluoropropene, 1,1,2,3-tetrafluoropropene, 1,2,3,3-tetrafluoropropene, 1,1,3,3-tetrafluoropropene, chlorodifluoropropene, 3-chloro-3,3-difluoropropene, 3-chloro-1,3-difluoropropene, 2-chloro-1,1-difluoropropene, 2-chloro-1,3-difluoropropene, 2-chloro-3,3-difluoropropene, 1-chloro-1,2-difluoropropene, 1-chloro-2,3-difluoropropene, 3-chloro-1,2-difluoropropene, 3-chloro-2,3-difluoropropene, 1-chloro-1,3-difluoropropene, 3-chloro-1,1-difluoropropene, 1-chloro-3,3-difluoropropene, trifluoropropene, 1,1,2-trifluoropropene, 1,2,3-trifluoropropene, 2,3,3-trifluoropropene, 1,1,3-trifluoropropene, 1,3,3-trifluoropropene, chlorofluoropropene, 1-chloro-3-fluoropropene, 1-chloro-1-fluoropropene, 1-chloro-2-fluoropropene, 2-chloro-1-fluoropropene, 2-chloro-3-fluoropropene, 3-chloro-2-fluoropropene, 3-chloro-1-fluoropropene, 3-chloro-3-fluoropropene, difluoropropene, 1,2-difluoropropene, 2,3-difluoropropene, 1,1-difluoropropene, 1,3-difluoropropene, 3,3-difluoropropene, 1,1,1,2,2-pentafluoropropane, E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, Z-3,3,3-trifluoro-1-chloropropene and trifluoropropyne.

A subject of the present invention is also an azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, 3,3,3-trifluoropropene, and one or more compounds chosen from 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

A subject of the present invention is also a composition comprising hydrogen fluoride, 3,3,3-trifluoropropene and at least one or more organic compounds chosen from E-1,3,3,3-tetrafluoropropene, Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane and 2,3,3,3-tetrafluoropropene.

According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,2,2-heptafluoropropane and optionally one or more compounds chosen from 2,3,3,3-tetrafluoropropene, E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from E-3,3,3-trifluoro-1-chloropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, E-3,3,3-trifluoro-1-chloropropene and optionally one or more compounds chosen from 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene and optionally one or more compounds chosen from 1,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropene, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, trifluoropropyne and optionally one or more compounds chosen from 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,3,3-pentafluoropropane and optionally one or more compounds chosen from 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,3,3-pentafluoropropene and optionally one or more compounds chosen from 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,2,3-pentafluoropropene and optionally 2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, E-1,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from Z-1,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment of the invention, the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, Z-1,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from 3,3,3-trifluoro-2-chloropropene, E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 3,3,3-trifluoro-2-chloropropene and optionally one or more compounds chosen from E-3,3,3-trifluoro-1-chloropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment of the invention, the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, E-3,3,3-trifluoro-1-chloropropene and optionally one or more compounds chosen from 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to another embodiment, the composition according to the invention comprises hydrogen fluoride, 3,3,3-trifluoropropene, 1,1,1,2,2-pentafluoropropane and optionally one or more compounds chosen from 2,3,3,3-tetrafluoropropene, trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

According to one embodiment of the invention, the composition comprises hydrogen fluoride, 3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene and optionally one or more compounds chosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane.

Irrespective of the embodiment, the composition preferably comprises from 1% to 95% and advantageously from 5% to 80% by weight of hydrogen fluoride and from 99% to 5% and advantageously from 20% to 95% by weight of the sum of the organic compounds; more particularly, the composition comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of the organic compounds (HFO-1243zf and the (hydro)halocarbon compounds).

Irrespective of the embodiment, the boiling point of the composition according to the invention is between −20° C. and 80° C. and at a pressure between 0.1 and 44 bar absolute, preferentially between 0° C. and 40° C. and preferentially at a pressure of between 0.7 and 18 bar absolute, advantageously between 0.9 and 12.5 bar absolute.

The Applicant has discovered that the compositions according to the invention have advantageous properties in particular for the recycling of HF in the reaction step. Thus, the condensed phase of these compositions, optionally when they are subjected to a distillation step and/or a liquid/liquid separation step, such as by decantation, form two immiscible liquid phases.

By way of example, for the ternary compounds containing hydrogen fluoride, 3,3,3-trifluoropropene and a compound chosen from 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoro-2-chloropropene, 1,3,3,3-tetrafluoropropene and E-3,3,3-trifluoro-1-chloropropene, the appearance of a heteroazeotrope characterized by two liquid phases, one rich in HF and the other depleted in HF, depends on the amount of HF in the composition. These decantation ranges as a function of the HF content in the compositions were characterized for at least isotherms at 0° C., 25° C. and 40° C.

Similarly, the decantation ranges for the ternary compounds containing hydrogen fluoride, 3,3,3-trifluoropropene and a compound chosen from trifluoropropyne, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, Z-1,1,1,2,3-pentafluoropropene and 2-chloro-1,1,1,2-tetrafluoropropane are characterized by a phase depleted in HF and a phase enriched in HF for at least isotherms at 0° C., 25° C. and 40° C.

An azeotropic or quasi-azeotropic composition that is preferred according to the invention comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of HFO-1243zf and of HFC-245cb, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of HFO-1243zf and of HFC-245cb, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.9 and 11.6 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 1% to 85% by weight of hydrogen fluoride and from 99% to 15% by weight of the sum of HFO-1243zf, of HCFC-244bb, of HFC-245fa, of trifluoropropyne, of HFO-1225yeZ and of HFO-1225zc, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.7 and 18 bar absolute.

An azeotropic or quasi-azeotropic composition that is preferred according to the invention preferably comprises from 5% to 80% by weight of hydrogen fluoride and from 95% to 20% by weight of the sum of HFO-1243zf, of HCFC-244bb, of HFC-245fa, of trifluoropropyne, of HFO-1225yeZ and of HFO-1225zc, the boiling point of this preferred composition is between 0 and 40° C. at a pressure of between 0.7 and 18 bar absolute.

The pressure characteristics of the mixtures of Examples 1, 4, 7, 10, 13, 16 and 19 were calculated for an isotherm at 25° C.

Examples 2, 5, 8, 11, 14, 17 and 20 represent the boiling point and pressure ranges of the mixtures and Examples 3, 6, 9, 12, 15, 18 and 21 represent the decantation ranges of the mixtures of Examples 1, 4, 7, 10, 13, 16 and 19 as a function of the mass percentage of HF characterized for isotherms at 0° C., 25° C. and 40° C. The decantation ranges of Examples 3, 6, 9, 12, 15, 18 and 21 are calculated for mixtures of organic compounds having equal-mass contents. By way of example, for a ternary mixture, a mixture containing 50% by weight of each of the two organic compounds is considered; for a penternary mixture, a mixture containing 25% by weight of each of the four organic compounds is considered, the mass fraction of HF ranging from 0 to 1. These calculations are performed at the liquid-vapor equilibrium, under azeotropic conditions.

EXAMPLE 1: TERNARY MIXTURES, ISOTHERM AT 25° C.

HF-HFO-1243zf-HFC-245cb HF-HFO-1234yf-HFO-1243zf

Organics
Organics
Organics

0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +

0.05 F245cb
0.5 F245cb
0.95 F245cb

MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL

FRAC
PRESSURE
FRAC
PRESSURE
FRAC
PRESSURE

HF
bar
HF
bar
HF
bar

0
5.8
0
5.4
0
4.7

0.05
6.7
0.05
6.4
0.05
5.9

0.1
6.8
0.1
6.4
0.1
5.9

0.15
6.8
0.15
6.4
0.15
5.9

0.2
6.8
0.2
6.4
0.2
5.9

0.25
6.8
0.25
6.4
0.25
5.9

0.3
6.8
0.3
6.4
0.3
5.9

0.35
6.8
0.35
6.4
0.35
5.9

0.4
6.8
0.4
6.4
0.4
5.9

0.45
6.8
0.45
6.4
0.45
5.9

0.5
6.7
0.5
6.4
0.5
5.9

0.55
6.7
0.55
6.4
0.55
5.9

0.6
6.7
0.6
6.4
0.6
5.9

0.65
6.7
0.65
6.4
0.65
5.9

0.7
6.6
0.7
6.4
0.7
5.9

0.75
6.4
0.75
6.3
0.75
5.9

0.8
6.1
0.8
6.2
0.8
5.9

0.85
5.6
0.85
5.7
0.85
5.9

0.9
4.8
0.9
4.9
0.9
5.0

0.95
3.4
0.95
3.5
0.95
3.6

1
1.2
1
1.2
1
1.2

Organics
Organics
Organics

0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +

0.05 F1234yf
0.5 F1234yf
0.95 F1234yf

MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL

FRAC
PRESSURE
FRAC
PRESSURE
FRAC
PRESSURE

HF
bar
HF
bar
HF
bar

0
5.9
0
6.3
0
6.7

0.05
6.8
0.05
7.2
0.05
7.7

0.1
6.9
0.1
7.3
0.1
7.7

0.15
6.9
0.15
7.3
0.15
7.7

0.2
6.8
0.2
7.2
0.2
7.7

0.25
6.8
0.25
7.2
0.25
7.7

0.3
6.8
0.3
7.2
0.3
7.7

0.35
6.8
0.35
7.2
0.35
7.7

0.4
6.8
0.4
7.2
0.4
7.7

0.45
6.8
0.45
7.2
0.45
7.7

0.5
6.8
0.5
7.2
0.5
7.7

0.55
6.8
0.55
7.2
0.55
7.7

0.6
6.8
0.6
7.2
0.6
7.7

0.65
6.7
0.65
7.2
0.65
7.7

0.7
6.6
0.7
7.1
0.7
7.7

0.75
6.5
0.75
7.0
0.75
7.5

0.8
6.2
0.8
6.7
0.8
7.2

0.85
5.7
0.85
6.1
0.85
6.6

0.9
4.8
0.9
5.2
0.9
5.6

0.95
3.4
0.95
3.6
0.95
3.8

1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1243zf HF-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics

0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +

0.05 F1233xf
0.5 F1233xf
0.95 F1233xf

MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL

FRAC
PRES
FRAC
PRES
FRAC
PRES

HF
bar
HF
bar
HF
bar

0
5.7
0
4.0
0
1.8

0.05
6.6
0.05
5.0
0.05
2.9

0.1
6.7
0.1
5.0
0.1
2.9

0.15
6.6
0.15
5.0
0.15
2.9

0.2
6.6
0.2
5.0
0.2
2.9

0.25
6.6
0.25
5.0
0.25
2.9

0.3
6.6
0.3
5.0
0.3
2.9

0.35
6.6
0.35
5.0
0.35
2.9

0.4
6.6
0.4
5.0
0.4
2.9

0.45
6.6
0.45
5.0
0.45
2.9

0.5
6.6
0.5
5.0
0.5
2.9

0.55
6.6
0.55
5.0
0.55
2.9

0.6
6.6
0.6
5.0
0.6
2.9

0.65
6.5
0.65
4.9
0.65
2.9

0.7
6.4
0.7
4.9
0.7
2.9

0.75
6.3
0.75
4.7
0.75
2.9

0.8
6.0
0.8
4.5
0.8
2.7

0.85
5.5
0.85
4.1
0.85
2.5

0.9
4.7
0.9
3.5
0.9
2.2

0.95
3.3
0.95
2.6
0.95
1.8

1
1.2
1
1.2
1
1.2

Organics
Organics
Organics

0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +

0.05 F1233zdE
0.5 F1233zdE
0.95 F1233zdE

MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL

FRAC
PRESSURE
FRAC
PRESSURE
FRAC
PRESSURE

HF
bar
HF
bar
HF
bar

0
5.7
0
3.9
0
1.6

0.05
6.6
0.05
5.0
0.05
2.7

0.1
6.6
0.1
4.9
0.1
2.7

0.15
6.6
0.15
4.9
0.15
2.7

0.2
6.6
0.2
4.9
0.2
2.7

0.25
6.6
0.25
4.9
0.25
2.7

0.3
6.6
0.3
4.9
0.3
2.7

0.35
6.6
0.35
4.9
0.35
2.7

0.4
6.6
0.4
4.9
0.4
2.7

0.45
6.6
0.45
4.9
0.45
2.7

0.5
6.6
0.5
4.9
0.5
2.7

0.55
6.6
0.55
4.9
0.55
2.7

0.6
6.6
0.6
4.9
0.6
2.7

0.65
6.5
0.65
4.8
0.65
2.7

0.7
6.4
0.7
4.8
0.7
2.7

0.75
6.3
0.75
4.6
0.75
2.7

0.8
6.0
0.8
4.4
0.8
2.5

0.85
5.5
0.85
4.0
0.85
2.4

0.9
4.6
0.9
3.4
0.9
2.1

0.95
3.3
0.95
2.5
0.95
1.7

1
1.2
1
1.2
1
1.2

HF-HFO-1234zeE-HFO-1243zf HF-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics

0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +

0.05 F1234zeE
0.5 F1234zeE
0.95 F1234zeE

MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL

FRAC
PRESSURE
FRAC
PRESSURE
FRAC
PRESSURE

HF
bar
HF
bar
HF
bar

0
5.8
0
5.4
0
4.9

0.05
6.7
0.05
6.3
0.05
5.9

0.1
6.8
0.1
6.4
0.1
5.9

0.15
6.8
0.15
6.4
0.15
5.9

0.2
6.8
0.2
6.4
0.2
5.9

0.25
6.8
0.25
6.4
0.25
5.9

0.3
6.8
0.3
6.4
0.3
5.9

0.35
6.8
0.35
6.4
0.35
5.9

0.4
6.7
0.4
6.4
0.4
5.9

0.45
6.7
0.45
6.4
0.45
5.9

0.5
6.7
0.5
6.3
0.5
5.8

0.55
6.7
0.55
6.3
0.55
5.8

0.6
6.7
0.6
6.3
0.6
5.7

0.65
6.6
0.65
6.2
0.65
5.6

0.7
6.5
0.7
6.1
0.7
5.5

0.75
6.4
0.75
5.8
0.75
5.2

0.8
6.1
0.8
5.5
0.8
4.9

0.85
5.6
0.85
5.0
0.85
4.4

0.9
4.7
0.9
4.2
0.9
3.6

0.95
3.4
0.95
3.0
0.95
2.6

1
1.2
1
1.2
1
1.2

Organics
Organics
Organics

0.95 F1243zf +
0.5 F1243zf +
0.05 F1243zf +

0.05 F1234zeZ
0.5 F1234zeZ
0.95 F1234zeZ

MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL

FRAC
PRESSURE
FRAC
PRESSURE
FRAC
PRESSURE

HF
bar
HF
bar
HF
bar

0
5.7
0
4.0
0
2.0

0.05
6.6
0.05
5.0
0.05
3.1

0.1
6.6
0.1
5.0
0.1
3.1

0.15
6.6
0.15
5.0
0.15
3.1

0.2
6.6
0.2
5.0
0.2
3.1

0.25
6.6
0.25
5.0
0.25
3.1

0.3
6.6
0.3
5.0
0.3
3.1

0.35
6.6
0.35
5.0
0.35
3.1

0.4
6.6
0.4
5.0
0.4
3.1

0.45
6.6
0.45
5.0
0.45
3.1

0.5
6.6
0.5
5.0
0.5
3.1

0.55
6.6
0.55
5.0
0.55
3.1

0.6
6.6
0.6
5.0
0.6
3.1

0.65
6.5
0.65
5.0
0.65
3.1

0.7
6.4
0.7
4.9
0.7
3.1

0.75
6.3
0.75
4.8
0.75
3.1

0.8
6.0
0.8
4.5
0.8
3.0

0.85
5.5
0.85
4.2
0.85
2.8

0.9
4.7
0.9
3.6
0.9
2.4

0.95
3.3
0.95
2.6
0.95
1.9

1
1.2
1
1.2
1
1.2

EXAMPLE 2: TEMPERATURE AND PRESSURE RANGE OF TERNARY MIXTURES

Boiling point range

Temperature
Pressure

Ternary
° C.
bar abs

HF-HFO-1243zf-HFC-245cb
0 to 40
~2.5 to ~10.4

HF-HFO-1234yf-HFO-1243zf
0 to 40
~3.0 to ~11.7

HF-HCFO-1233xf-HFO-1243zf
0 to 40
~1.1 to ~10.2

HF-HFO-1234zeE-HFO-1243zf
0 to 40
~2.5 to ~10.4

HF-HFO-1234zeZ-HFO-1243zf
0 to 40
~1.2 to ~10.2

HF-HCFO-1233zdE-HFO-1243zf
0 to 40
~1.1 to ~10.2

EXAMPLE 3: DECANTATION RANGE OF TERNARY MIXTURES

Decantation ranges

Mass percentage of HF

Isotherm
Isotherm
Isotherm

Ternary
0° C.
25° C.
40° C.

HF-HFO-1243zf-HFC-245cb
5-75
10-75
40-70

HF-HFO-1234yf-HFO-1243zf
5-70
*
*

HF-HCFO-1233xf-HFO-1243zf
5-75
10-65
20-40

HF-HFO-1234zeE-HFO-1243zf
5-65
*
*

HF-HFO-1234zeZ-HFO-1243zf
5-75
10-65
*

HF-HCFO-1233zdE-HFO-1243zf
5-75
5-65
15-45

EXAMPLE 4: QUATERNARY MIXTURES, ISOTHERM AT 25° C.

HF-HCFO-1233xf-HFO-1243zf-HFC-245cb

Organics
Organics
Organics
Organics

0.9 F1233xf +
0.4 F1233xf +
0.05 F1233xf +
0.05 F1233xf +

0.05 F1243zf +
0.3 F1243zf +
0.9 F1243zf +
0.05 F1243zf +

0.05 F245cb
0.3 F245cb
0.05 F245cb
0.9 F245cb

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
2.0
0
4.0
0
5.6
0
4.6

0.05
3.1
0.05
5.1
0.05
6.6
0.05
5.7

0.1
3.1
0.1
5.1
0.1
6.6
0.1
5.7

0.15
3.1
0.15
5.1
0.15
6.6
0.15
5.7

0.2
3.1
0.2
5.1
0.2
6.6
0.2
5.7

0.25
3.1
0.25
5.1
0.25
6.6
0.25
5.7

0.3
3.1
0.3
5.1
0.3
6.6
0.3
5.7

0.35
3.1
0.35
5.1
0.35
6.6
0.35
5.7

0.4
3.1
0.4
5.1
0.4
6.6
0.4
5.8

0.45
3.1
0.45
5.1
0.45
6.6
0.45
5.8

0.5
3.1
0.5
5.1
0.5
6.6
0.5
5.8

0.55
3.1
0.55
5.1
0.55
6.6
0.55
6.8

0.6
3.1
0.6
5.1
0.6
6.5
0.6
5.8

0.65
3.1
0.65
5.1
0.65
6.5
0.65
5.8

0.7
3.1
0.7
5.1
0.7
6.4
0.7
5.8

0.75
3.1
0.75
5.1
0.75
6.3
0.75
5.8

0.8
2.9
0.8
4.8
0.8
6.0
0.8
5.8

0.85
2.7
0.85
4.5
0.85
5.5
0.85
5.7

0.9
2.4
0.9
3.8
0.9
4.7
0.9
4.5

0.95
1.9
0.95
2.8
0.95
3.3
0.95
3.5

1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +

0.05 F1233zdE +
0.9 F1233zdE +
0.05 F1233zdE +
0.3 F1233zdE +

0.05 F1243zf
0.05 F1243zf
0.3 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
1.8
0
1.6
0
5.5
0
3.0

0.05
2.9
0.05
2.7
0.05
6.4
0.05
4.1

0.1
2.9
0.1
2.7
0.1
6.5
0.1
4.1

0.15
2.9
0.15
2.7
0.15
6.5
0.15
4.1

0.2
2.9
0.2
2.7
0.2
6.5
0.2
4.1

0.25
2.9
0.25
2.7
0.25
6.5
0.25
4.1

0.3
2.9
0.3
2.7
0.3
6.5
0.3
4.1

0.35
2.9
0.35
2.7
0.35
6.5
0.35
4.1

0.4
2.9
0.4
2.7
0.4
6.5
0.4
4.1

0.45
2.9
0.45
2.7
0.45
6.5
0.45
4.1

0.5
2.9
0.5
2.7
0.5
6.4
0.5
4.1

0.55
2.9
0.55
2.7
0.55
6.4
0.55
4.1

0.6
2.9
0.6
2.7
0.6
6.4
0.6
4.0

0.65
2.9
0.65
2.7
0.65
6.4
0.65
4.0

0.7
2.9
0.7
2.7
0.7
6.3
0.7
4.0

0.75
2.9
0.75
2.7
0.75
6.1
0.75
3.9

0.8
2.7
0.8
2.6
0.8
5.8
0.8
3.7

0.85
2.5
0.85
2.4
0.85
5.3
0.85
3.4

0.9
2.2
0.9
2.1
0.9
4.5
0.9
2.9

0.95
1.8
0.95
1.7
0.95
3.2
0.95
2.2

1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +

0.05 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +
0.3 F1234zeE +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
2.0
0
4.8
0
5.6
0
4.0

0.05
3.1
0.05
5.7
0.05
6.6
0.05
5.1

0.1
3.1
0.1
5.8
0.1
6.6
0.1
5.1

0.15
3.1
0.15
5.8
0.15
6.6
0.15
5.1

0.2
3.1
0.2
5.8
0.2
6.6
0.2
5.1

0.25
3.1
0.25
5.8
0.25
6.6
0.25
5.1

0.3
3.1
0.3
5.8
0.3
6.6
0.3
5.0

0.35
3.1
0.35
5.7
0.35
6.6
0.35
5.0

0.4
3.1
0.4
5.7
0.4
6.6
0.4
5.0

0.45
3.1
0.45
5.7
0.45
6.6
0.45
5.0

0.5
3.1
0.5
5.7
0.5
6.6
0.5
5.0

0.55
3.1
0.55
5.7
0.55
6.6
0.55
5.0

0.6
3.1
0.6
5.6
0.6
6.5
0.6
5.0

0.65
3.1
0.65
5.5
0.65
6.5
0.65
4.9

0.7
3.0
0.7
5.3
0.7
6.4
0.7
4.8

0.75
3.0
0.75
5.1
0.75
6.2
0.75
4.7

0.8
2.9
0.8
4.8
0.8
5.9
0.8
4.4

0.85
2.6
0.85
4.3
0.85
5.4
0.85
4.0

0.9
2.3
0.9
3.6
0.9
4.6
0.9
3.4

0.95
1.8
0.95
2.6
0.95
3.3
0.95
2.5

1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +

0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
1.8
0
2.0
0
5.5
0
3.1

0.05
2.9
0.05
3.1
0.05
6.4
0.05
4.2

0.1
2.9
0.1
3.1
0.1
6.5
0.1
4.2

0.15
2.9
0.15
3.1
0.15
6.5
0.15
4.2

0.2
2.9
0.2
3.1
0.2
6.5
0.2
4.2

0.25
2.9
0.25
3.1
0.25
6.5
0.25
4.2

0.3
2.9
0.3
3.1
0.3
6.5
0.3
4.2

0.35
2.9
0.35
3.1
0.35
6.5
0.35
4.2

0.4
2.9
0.4
3.1
0.4
6.5
0.4
4.2

0.45
2.9
0.45
3.1
0.45
6.5
0.45
4.2

0.5
2.9
0.5
3.1
0.5
6.4
0.5
4.2

0.55
2.9
0.55
3.1
0.55
6.4
0.55
4.2

0.6
2.9
0.6
3.1
0.5
6.4
0.6
4.1

0.65
2.9
0.65
3.1
0.65
6.4
0.65
4.1

0.7
2.9
0.7
3.1
0.7
6.3
0.7
4.1

0.75
2.9
0.75
3.1
0.75
6.1
0.75
4.0

0.8
2.8
0.8
3.0
0.8
5.8
0.8
3.8

0.85
2.5
0.85
2.7
0.85
5.3
0.85
3.5

0.9
2.2
0.9
2.4
0.9
4.5
0.9
3.0

0.95
1.8
0.95
1.9
0.95
3.2
0.95
2.3

1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F1233xf +
0.05 F1233xf +
0.05 F1233xf +
0.4 F1233xf +

0.05 F1234yf +
0.9 F1234yf +
0.05 F1234yf +
0.3 F1234yf +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
2.1
0
6.5
0
5.8
0
4.6

0.05
3.2
0.05
7.5
0.05
5.8
0.05
5.6

0.1
3.2
0.1
7.5
0.1
8.8
0.1
5.7

0.15
3.2
0.15
7.5
0.15
5.8
0.15
5.6

0.2
3.2
0.2
7.5
0.2
6.8
0.2
5.6

0.25
3.2
0.25
7.5
0.25
6.8
0.25
5.6

0.3
3.2
0.3
7.5
0.3
6.8
0.3
5.6

0.35
3.2
0.35
7.5
0.35
6.8
0.35
5.6

0.4
3.2
0.4
7.5
0.4
6.8
0.4
5.6

0.45
3.2
0.45
7.5
0.45
6.8
0.45
5.6

0.5
3.2
0.5
7.5
0.5
6.8
0.5
5.6

0.55
3.2
0.55
7.5
0.55
6.7
0.55
5.6

0.6
3.2
0.6
7.5
0.6
6.7
0.6
5.6

0.65
3.2
0.65
7.5
0.65
6.7
0.65
5.6

0.7
3.2
0.7
7.4
0.7
6.6
0.7
5.6

0.75
3.2
0.75
7.3
0.75
6.4
0.75
5.4

0.8
3.0
0.8
7.0
0.8
6.1
0.8
5.1

0.85
2.8
0.85
6.4
0.85
5.6
0.85
4.7

0.9
2.4
0.9
5.4
0.9
4.8
0.9
4.0

0.95
1.9
0.95
3.7
0.95
3.4
0.95
2.9

1
1.2
1
1.2
1
1.2
1
1.2

HF-HFC-245cb-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F245cb +
0.05 F245cb +
0.05 F245cb +
0.4 F245cb +

0.05 F1233zdE +
0.9 F1233zdE +
0.05 F1233zdE +
0.3 F1233zdE +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
4.6
0
1.9
0
5.6
0
4.2

0.05
5.7
0.05
2.9
0.05
6.6
0.05
5.3

0.1
5.7
0.1
2.9
0.1
5.6
0.1
5.3

0.15
5.7
0.15
2.9
0.15
6.6
0.15
5.3

0.2
5.7
0.2
2.9
0.2
6.6
0.2
5.3

0.25
5.7
0.25
2.9
0.25
6.6
0.25
5.3

0.3
5.7
0.3
2.9
0.3
6.6
0.3
5.3

0.35
5.7
0.35
2.9
0.35
6.6
0.35
5.3

0.4
5.7
0.4
2.9
0.4
6.6
0.4
5.3

0.45
5.7
0.45
2.9
0.45
6.6
0.45
5.3

0.5
5.7
0.5
2.9
0.5
6.6
0.5
5.3

0.55
5.7
0.55
2.9
0.55
6.6
0.55
5.3

0.6
5.7
0.6
2.9
0.6
6.5
0.6
5.3

0.65
5.7
0.65
2.9
0.65
6.5
0.65
5.3

0.7
5.8
0.7
2.9
0.7
6.4
0.7
5.3

0.75
5.8
0.75
2.9
0.75
6.2
0.75
5.3

0.8
5.8
0.8
2.8
0.8
6.0
0.8
5.1

0.85
5.7
0.85
2.6
0.85
5.5
0.85
4.7

0.9
4.9
0.9
2.3
0.9
4.7
0.9
4.1

0.95
3.5
0.95
1.8
0.95
3.3
0.95
2.9

1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F1233zdE +
0.05 F1233zdE +
0.05 F1233zdE +
0.4 F1233zdE +

0.05 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +
0.3 F1234zeE +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

PRES-

PRES-

PRES-

PRES-

SURE

SURE

SURE

SURE

HF
PRES
HF
PRES
HF
PRES
HF
PRES

HF
bar
HF
bar
HF
bar
HF
bar

0
1.8
0
4.8
0
5.6
0
3.9

0.05
2.9
0.05
5.7
0.05
6.6
0.05
5.0

0.1
2.9
0.1
5.7
0.1
6.6
0.1
5.0

0.15
2.9
0.15
5.7
0.15
6.6
0.15
5.0

0.2
2.9
0.2
5.7
0.2
6.6
0.1
5.0

0.25
2.9
0.25
5.7
0.25
6.6
0.25
5.0

0.3
2.9
0.3
5.7
0.3
6.6
0.3
5.0

0.35
2.9
0.35
5.7
0.35
6.6
0.35
5.0

0.4
2.9
0.4
5.7
0.4
6.6
0.4
4.9

0.45
2.9
0.45
5.7
0.45
6.6
0.45
4.9

0.5
2.9
0.5
5.7
0.5
6.6
0.5
4.9

0.55
2.9
0.55
5.6
0.55
6.5
0.55
4.9

0.6
2.9
0.6
5.6
0.6
6.5
0.6
4.9

0.65
2.9
0.65
5.5
0.65
6.5
0.65
4.9

0.7
2.8
0.7
5.3
0.7
6.4
0.7
4.8

0.75
2.8
0.75
5.1
0.75
6.2
0.75
4.6

0.8
2.7
0.8
4.8
0.8
5.9
0.8
4.3

0.85
2.5
0.85
4.3
0.85
5.4
0.85
3.9

0.9
2.2
0.9
3.6
0.9
4.6
0.9
3.3

0.95
1.8
0.95
2.6
0.95
3.3
0.95
2.5

1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F1233zdE +
0.05 F1233zdE +
0.05 F1233zdE +
0.4 F1233zdE +

0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
1.6
0
2.0
0
5.5
0
3.0

0.05
2.7
0.05
3.1
0.05
6.4
0.05
4.1

0.1
2.7
0.1
3.1
0.1
6.5
0.1
4.1

0.15
2.7
0.15
3.1
0.15
6.5
0.15
4.1

0.2
2.7
0.2
3.1
0.2
6.5
0.2
4.1

0.25
2.7
0.25
3.1
0.25
6.5
0.25
4.1

0.3
2.7
0.3
3.1
0.3
6.4
0.3
4.1

0.35
2.7
0.35
3.1
0.35
6.4
0.35
4.1

0.4
2.7
0.4
3.1
0.4
6.4
0.4
4.1

0.45
2.7
0.45
3.1
0.45
6.4
0.45
4.1

0.5
2.7
0.5
3.1
0.5
6.4
0.5
4.1

0.55
2.7
0.55
3.1
0.55
6.4
0.55
4.1

0.6
2.7
0.6
3.1
0.6
6.4
0.6
4.1

0.65
2.7
0.65
3.1
0.65
6.3
0.65
4.0

0.7
2.7
0.7
3.1
0.7
6.3
0.7
4.0

0.75
2.7
0.75
3.1
0.75
6.1
0.75
3.9

0.8
2.6
0.8
3.0
0.8
5.8
0.8
3.7

0.85
2.4
0.85
2.7
0.85
5.3
0.85
3.4

0.9
2.1
0.9
2.4
0.9
4.5
0.9
2.9

0.95
1.7
0.95
1.9
0.95
3.2
0.95
2.2

1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F1234yf +
0.05 F1234yf +
0.05 F1234yf +
0.4 F1234yf +

0.05 F1233zdE +
0.9 F1233zdE +
0.05 F1233zdE +
0.3 F1233zdE +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
6.5
0
1.9
0
5.7
0
5.0

0.05
7.5
0.05
3.0
0.05
6.7
0.05
6.0

0.1
7.5
0.1
3.0
0.1
6.7
0.1
6.0

0.15
7.5
0.15
3.0
0.15
6.7
0.15
6.0

0.2
7.4
0.2
3.0
0.2
6.7
0.2
6.0

0.25
7.4
0.25
3.0
0.25
6.7
0.25
6.0

0.3
7.5
0.3
3.0
0.3
6.7
0.3
6.0

0.35
7.5
0.35
3.0
0.35
6.7
0.35
6.0

0.4
7.5
0.4
3.0
0.4
6.7
0.4
6.0

0.45
7.5
0.45
3.0
0.45
6.7
0.45
6.0

0.5
7.5
0.5
3.0
0.5
6.6
0.5
6.0

0.55
7.5
0.55
3.0
0.55
6.6
0.55
6.0

0.6
7.5
0.6
3.0
0.6
6.6
0.6
6.0

0.65
7.5
0.65
3.0
0.65
6.6
0.65
6.0

0.7
7.4
0.7
3.0
0.7
6.5
0.7
6.0

0.75
7.3
0.75
3.0
0.75
6.3
0.75
5.8

0.8
7.0
0.8
2.8
0.8
6.0
0.8
5.5

0.05
6.4
0.85
2.6
0.85
5.5
0.85
5.1

0.9
5.4
0.9
2.3
0.9
4.7
0.9
4.3

0.95
3.7
0.95
1.8
0.95
3.3
0.95
3.1

1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F1234zeE +
0.05 F1234zeE +
0.05 F1234zeE +
0.4 F1234zeE +

0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
4.8
0
2.2
0
5.6
0
4.3

0.05
5.7
0.05
3.3
0.05
6.6
0.05
5.3

0.1
5.8
0.1
3.3
0.1
6.6
0.1
5.3

0.15
5.8
0.15
3.3
0.15
6.6
0.15
5.3

0.2
5.7
0.2
3.3
0.2
6.6
0.2
5.3

0.25
5.7
0.25
3.3
0.25
6.6
0.25
5.3

0.3
5.7
0.3
3.3
0.3
6.6
0.3
5.3

0.35
5.7
0.35
3.3
0.35
6.6
0.35
5.3

0.4
5.7
0.4
3.3
0.4
6.6
0.4
5.3

0.45
5.7
0.45
3.3
0.45
6.6
0.45
5.3

0.5
5.7
0.5
3.3
0.5
6.6
0.5
5.3

0.55
5.7
0.55
3.3
0.55
6.5
0.55
5.3

0.6
5.6
0.6
3.3
0.6
6.5
0.6
5.3

0.65
5.5
0.65
3.3
0.65
6.5
0.65
5.2

0.7
5.3
0.7
3.3
0.7
6.4
0.7
5.1

0.75
5.1
0.75
3.2
0.75
6.2
0.75
4.9

0.8
4.8
0.8
3.1
0.8
5.9
0.8
4.6

0.85
4.3
0.85
2.8
0.85
5.4
0.85
4.2

0.9
3.6
0.9
2.5
0.9
4.6
0.9
3.6

0.95
2.6
0.95
2.0
0.95
3.3
0.95
2.6

1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F1234yf +
0.05 F1234yf +
0.05 F1234yf +
0.4 F1234yf +

0.05 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +
0.3 F1234zeE +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
6.7
0
5.0
0
5.8
0
5.9

0.05
7.6
0.05
6.0
0.05
6.8
0.05
6.9

0.1
7.6
0.1
6.0
0.1
6.8
0.1
6.9

0.15
7.6
0.15
6.0
0.15
6.8
0.15
6.9

0.2
7.6
0.2
6.0
0.2
6.8
0.2
6.9

0.25
7.5
0.25
6.0
0.25
6.8
0.25
6.9

0.3
7.6
0.3
6.0
0.3
6.8
0.3
6.9

0.35
7.6
0.35
6.0
0.35
6.8
0.35
6.9

0.4
7.6
0.4
6.0
0.4
6.8
0.4
6.9

0.45
7.6
0.45
6.0
0.45
6.8
0.45
6.9

0.5
7.6
0.5
6.0
0.5
6.8
0.5
6.9

0.55
7.6
0.55
5.9
0.55
6.8
0.55
6.9

0.6
7.6
0.6
5.8
0.6
6.7
0.5
6.9

0.65
7.6
0.65
5.7
0.65
6.7
0.65
6.8

0.7
7.6
0.7
5.6
0.7
6.6
0.7
6.7

0.75
7.4
0.75
5.4
0.75
6.4
0.75
6.5

0.8
7.1
0.8
5.0
0.8
6.1
0.8
6.2

0.85
6.5
0.85
4.5
0.85
5.6
0.85
5.7

0.9
5.5
0.9
3.8
0.9
4.8
0.9
4.8

0.95
3.8
0.95
2.7
0.95
3.4
0.95
3.3

1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F1234yf +
0.05 F1234yf +
0.05 F1234yf +
0.4 F1234yf +

0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
6.5
0
2.3
0
5.7
0
5.0

0.05
7.5
0.05
3.4
0.05
6.7
0.05
6.0

0.1
7.5
0.1
3.4
0.1
6.7
0.1
6.1

0.15
7.5
0.15
3.4
0.15
6.7
0.15
6.1

0.2
7.4
0.2
3.4
0.2
6.7
0.2
6.1

0.25
7.4
0.25
3.4
0.25
6.7
0.25
6.1

0.3
7.4
0.3
3.4
0.3
6.7
0.3
6.1

0.35
7.5
0.35
3.4
0.35
6.7
0.35
6.1

0.4
7.5
0.4
3.4
0.4
6.7
0.4
6.1

0.45
7.5
0.45
3.4
0.45
6.7
0.45
6.1

0.5
7.5
0.5
3.4
0.5
6.7
0.5
6.1

0.55
7.5
0.55
3.4
0.55
6.6
0.55
6.1

0.6
7.5
0.6
3.4
0.6
6.6
0.6
6.1

0.65
7.5
0.65
3.4
0.65
6.6
0.55
6.1

0.7
7.4
0.7
3.4
0.7
6.5
0.7
6.0

0.75
7.3
0.75
3.3
0.75
6.3
0.75
5.9

0.8
7.0
0.8
3.2
0.8
6.0
0.8
5.6

0.85
6.4
0.85
3.0
0.85
5.5
0.85
5.1

0.9
5.4
0.9
2.6
0.9
4.7
0.9
4.4

0.95
3.7
0.95
2.0
0.95
3.3
0.95
3.1

1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFO-1243zf-HFC-245cb

Organics
Organics
Organics
Organics

0.9 F1234yf +
0.4 F1234yf +
0.05 F1234yf +
0.05 F1234yf +

0.05 F1243zf +
0.3 F1243zf +
0.9 F1243zf +
0.05 F1243zf +

0.05 F245cb
0.3 F245cb
0.05 F245cb
0.9 F245cb

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
6.7
0
5.9
0
5.8
0
4.9

0.05
7.6
0.05
6.9
0.05
6.8
0.05
6.0

0.1
7.6
0.1
7.0
0.1
6.8
0.1
6.0

0.15
7.6
0.15
6.9
0.15
6.8
0.15
6.0

0.2
7.6
0.2
6.9
0.2
6.8
0.2
6.0

0.25
7.6
0.25
6.9
0.25
6.8
0.25
6.0

0.3
7.6
0.3
6.9
0.3
6.8
0.3
6.0

0.35
7.6
0.35
6.9
0.35
6.8
0.35
6.0

0.4
7.6
0.4
6.9
0.4
6.8
0.4
6.0

0.45
7.6
0.45
6.9
0.45
6.8
0.45
6.0

0.5
7.6
0.5
6.9
0.5
6.8
0.5
6.0

0.55
7.6
0.55
6.9
0.55
6.8
0.55
6.0

0.6
7.6
0.6
6.9
0.6
6.8
0.6
6.0

0.65
7.6
0.65
6.9
0.65
6.7
0.65
6.0

0.7
7.6
0.7
6.9
0.7
6.6
0.7
6.0

0.75
7.5
0.75
6.9
0.75
6.5
0.75
6.0

0.8
7.2
0.8
6.6
0.8
6.2
0.8
6.0

0.85
6.6
0.85
6.1
0.85
5.7
0.85
5.9

0.9
5.5
0.9
5.2
0.9
4.8
0.9
5.1

0.95
3.8
0.95
3.6
0.95
3.4
0.95
3.6

1
1.2
1
1.2
1
1.2
1
1.2

HF-HFC-245th-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F245cb +
0.05 F245cb +
0.05 F245cb +
0.4 F245cb +

0.05 F1234zeE +
0.9 F1234zeE +
0.05 F1234zeE +
0.3 F1234zeE +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
4.8
0
4.9
0
5.8
0
5.2

0.05
5.9
0.05
5.9
0.05
6.7
0.05
6.2

0.1
5.9
0.1
5.9
0.1
6.7
0.1
6.2

0.15
5.9
0.15
5.9
0.15
6.7
0.15
6.2

0.2
5.9
0.2
5.9
0.2
6.7
0.2
6.2

0.25
5.9
0.25
5.9
0.25
6.7
0.25
6.2

0.3
5.9
0.3
5.9
0.3
6.7
0.3
6.2

0.35
5.9
0.35
5.9
0.35
6.7
0.35
6.2

0.4
5.9
0.4
5.9
0.4
6.7
0.4
6.2

0.45
5.9
0.45
5.9
0.45
6.7
0.45
6.2

0.5
5.9
0.5
5.9
0.5
6.7
0.5
6.2

0.55
5.9
0.55
5.8
0.55
6.7
0.55
6.2

0.6
5.9
0.6
5.8
0.6
6.7
0.6
6.2

0.05
5.9
0.65
5.7
0.65
6.6
0.65
6.2

0.7
5.9
0.7
5.5
0.7
6.5
0.7
6.2

0.75
5.9
0.75
5.3
0.75
6.4
0.75
6.1

0.8
5.9
0.8
5.0
0.8
6.1
0.8
5.8

0.85
5.8
0.85
4.5
0.85
5.6
0.85
5.3

0.9
5.0
0.9
3.7
0.9
4.7
0.9
4.5

0.95
3.5
0.95
2.7
0.95
3.4
0.95
3.2

1
1.2
1
1.2
1
1.2
1
1.2

HF-HFC-245cb-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics

0.9 F245cb +
0.05 F245cb +
0.05 F245cb +
0.4 F245cb +

0.05 F1234zeZ +
0.9 F1234zeZ +
0.05 F1234zeZ +
0.3 F1234zeZ +

0.05 F1243zf
0.05 F1243zf
0.9 F1243zf
0.3 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar

0
4.6
0
2.2
0
5.6
0
4.2

0.05
5.7
0.05
3.3
0.05
6.6
0.05
5.3

0.1
5.7
0.1
3.3
0.1
6.6
0.1
5.3

0.15
5.7
0.15
3.3
0.15
6.6
0.15
5.3

0.2
5.7
0.2
3.3
0.2
6.6
0.2
5.3

0.25
5.7
0.25
3.3
0.25
6.6
0.25
5.3

0.3
5.7
0.3
3.3
0.3
6.6
0.3
5.3

0.35
5.7
0.35
3.3
0.35
6.6
0.35
5.3

0.4
5.7
0.4
3.3
0.4
6.6
0.4
5.3

0.45
5.7
0.45
3.3
0.45
6.6
0.45
5.3

0.5
5.7
0.5
3.3
0.5
6.6
0.5
5.3

0.55
5.7
0.55
3.3
0.55
6.6
0.55
5.3

0.6
5.8
0.6
3.3
0.6
6.5
0.6
5.3

0.65
5.8
0.65
3.3
0.65
6.5
0.65
5.3

0.7
5.8
0.7
3.3
0.7
6.4
0.7
5.4

0.75
5.8
0.75
3.3
0.75
6.3
0.75
5.4

0.8
5.8
0.8
3.1
0.8
6.0
0.8
5.2

0.85
5.7
0.85
2.9
0.85
5.5
0.85
4.8

0.9
4.9
0.9
2.6
0.9
4.7
0.9
4.1

0.95
3.5
0.95
2.0
0.95
3.3
0.95
3.0

1
1.2
1
1.2
1
1.2
1
1.2

EXAMPLE 5: TEMPERATURE AND PRESSURE RANGE OF QUATERNARY MIXTURES

Boiling point range

Temperature
Pressure

Quaternary
° C.
bar abs

HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.2 to ~10.1

1243zf

HF-HFO-1234yf-HFC-245cb-HFO-
0 to 40
~2.5 to ~11.6

1243zf

HF-HCFO-1233xf-HFO-1234yf-
0 to 40
~1.3 to ~11.3

HFO-1243zf

HF-HCFO-1233xf-HCFO-1233zdE-
0 to 40
~1.0 to ~9.9

HFO-1243zf

HF-HCFO-1233xf-HFO-1234zeE-
0 to 40
~1.2 to ~10.1

HFO-1243zf

HF-HCFO-1233xf-HFO-1234zeZ-
0 to 40
~1.1 to ~9.9

HFO-1243zf

HF-HFO-1234yf-HFO-1234zeE-
0 to 40
~3.0 to ~11.6

HFO-1243zf

HF-HFO-1234yf-HFO-1234zeZ-
0 to 40
~1.3 to ~11.3

HFO-1243zf

HF-HFC-245cb-HCFO-1233zdE-
0 to 40
~1.1 to ~10.1

HFO-1243zf

HF-HFC-245cb-HFO-1234zeE-
0 to 40
~2.5 to ~10.3

HFO-1243zf

HF-HFC-245cb-HFO-1234zeZ-HFO-
0 to 40
~1.3 to ~10.1

1243zf

HF-HCFO-1233zdE-HFO-1234zeE-
0 to 40
~1.1 to ~10.1

HFO-1243zf

HF-HCFO-1233zdE-HFO-1234zeZ-
0 to 40
~1.0 to ~9.9

HFO-1243zf

HF-HFO-1234zeE-HFO-1234zeZ-
0 to 40
~1.3 to ~10.1

HFO-1243zf

HF-HFO-1234yf-HCFO-1233zdE-
0 to 40
~1.2 to ~11.3

HFO-1243zf

EXAMPLE 6: DECANTATION RANGE OF QUATERNARY MIXTURES

Decantation ranges

Mass percentage of HF

Isotherm
Isotherm
Isotherm

Quaternary
0° C.
25° C.
40° C.

HF-HCFO-1233xf-HFC-245cb-HFO-
5-75
5-70
15-60

1243zf

HF-HFO-1234yf-HFC-245cb-HFO-1243zf
5-75
15-70
45-70

HF-HCFO-1233xf-HFO-1234yf-HFO-
5-75
10-65
*

1243zf

HF-HCFO-1233xf-HCFO-1233zdE-HFO-
5-75
5-70
10-60

1243zf

HF-HCFO-1233xf-HFO-1234zeE-HFO-
5-70
10-60
*

1243zf

HF-HCFO-1233xf-HFO-1234zeZ-HFO-
5-75
5-70
10-55

1243zf

HF-HFO-1234yf-HFO-1234zeE-HFO-
5-65
*
*

1243zf

HF-HFO-1234yf-HFO-1234zeZ-HFO-
5-75
10-65
*

1243zf

HF-HFC-245cb-HCFO-1233zdE-HFO-
5-75
5-70
15-65

1243zf

HF-HFC-245cb-HFO-1234zeE-HFO-
5-75
15-65
*

1243zf

HF-HFC-245cb-HFO-1234zeZ-HFO-
5-75
10-70
20-60

1243zf

HF-HCFO-1233zdE-HFO-1234zeE-HFO-
5-70
10-60
*

1243zf

HF-HCFO-1233zdE-HFO-1234zeZ-HFO-
5-75
5-70
10-55

1243zf

HF-HFO-1234zeE-HFO-1234zeZ-HFO-
5-70
10-60
*

1243zf

HF-HFO-1234yf-HCFO-1233zdE-HFO-
5-75
10-65
*

1243zf

EXAMPLE 7: PENTERNARY MIXTURES, ISOTHERM AT 25° C.

HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +

0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +

0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
1.8
0
1.6
0
4.5
0
5.6
0
3.5

0.05
3.0
0.05
2.8
0.05
5.7
0.05
6.5
0.05
4.6

0.1
3.0
0.1
2.8
0.1
5.7
0.1
6.6
0.1
4.6

0.15
3.0
0.15
2.8
0.15
5.7
0.15
6.6
0.15
4.6

0.2
3.0
0.2
2.8
0.2
5.7
0.2
6.5
0.2
4.6

0.25
3.0
0.25
2.8
0.25
5.7
0.25
6.5
0.25
4.6

0.3
3.0
0.3
2.8
0.3
5.7
0.3
6.5
0.3
4.6

0.35
2.9
0.35
2.8
0.35
5.7
0.35
6.5
0.35
4.6

0.4
2.9
0.4
2.8
0.4
5.7
0.4
6.5
0.4
4.6

0.45
2.9
0.45
2.7
0.45
5.7
0.45
6.5
0.45
4.6

0.5
2.9
0.5
2.7
0.5
5.7
0.5
6.5
0.5
4.6

0.55
2.9
0.55
2.7
0.55
5.7
0.55
6.5
0.55
4.6

0.6
2.9
0.6
2.7
0.6
5.7
0.6
6.5
0.6
4.6

0.65
2.9
0.65
2.7
0.65
5.7
0.65
6.4
0.65
4.6

0.7
2.9
0.7
2.7
0.7
5.7
0.7
6.4
0.7
4.7

0.75
2.9
0.75
2.7
0.75
5.7
0.75
6.2
0.75
4.6

0.8
2.8
0.8
2.6
0.8
5.7
0.8
5.9
0.8
4.4

0.85
2.6
0.85
2.4
0.85
5.6
0.85
5.4
0.85
4.1

0.9
2.3
0.9
2.2
0.9
4.8
0.9
4.6
0.9
3.5

0.95
1.8
0.95
1.8
0.95
3.4
0.95
3.3
0.95
2.6

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +

0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +

0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
2.0
0
4.8
0
4.6
0
5.7
0
4.4

0.05
3.1
0.05
5.8
0.05
5.8
0.05
6.6
0.05
5.4

0.1
3.1
0.1
5.8
0.1
5.8
0.1
6.7
0.1
5.4

0.15
3.1
0.15
5.8
0.15
5.8
0.15
6.6
0.15
5.4

0.2
3.1
0.2
5.8
0.2
5.8
0.2
6.6
0.2
5.4

0.25
3.1
0.25
5.8
0.25
5.8
0.25
6.6
0.25
5.4

0.3
3.1
0.3
5.8
0.3
5.8
0.3
6.6
0.3
5.4

0.35
3.1
0.35
5.8
0.35
5.8
0.35
6.6
0.35
5.4

0.4
3.1
0.4
5.8
0.4
5.8
0.4
6.6
0.4
5.4

0.45
3.1
0.45
5.8
0.45
5.8
0.45
6.6
0.45
5.4

0.5
3.1
0.5
5.7
0.5
5.8
0.5
6.6
0.5
5.4

0.55
3.1
0.55
5.7
0.55
5.8
0.55
6.6
0.55
5.4

0.6
3.1
0.6
5.6
0.6
5.8
0.6
6.6
0.6
5.4

0.65
3.1
0.65
5.5
0.65
5.8
0.65
6.5
0.65
5.4

0.7
3.1
0.7
5.4
0.7
5.8
0.7
6.4
0.7
5.4

0.75
3.0
0.75
5.2
0.75
5.8
0.75
6.3
0.75
5.3

0.8
2.9
0.8
4.8
0.8
5.8
0.8
6.0
0.8
5.0

0.85
2.7
0.85
4.3
0.85
5.7
0.85
5.5
0.85
4.6

0.9
2.3
0.9
3.6
0.9
4.9
0.9
4.7
0.9
3.9

0.95
1.9
0.95
2.6
0.95
3.5
0.95
3.3
0.95
2.8

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +

0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +

0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
1.9
0
2.1
0
4.5
0
5.6
0
3.6

0.05
3.0
0.05
3.2
0.05
5.7
0.05
6.5
0.05
4.7

0.1
3.0
0.1
3.2
0.1
5.7
0.1
6.6
0.1
4.7

0.15
3.0
0.15
3.2
0.15
5.7
0.15
6.6
0.15
4.7

0.2
3.0
0.2
3.2
0.2
5.7
0.2
6.6
0.2
4.7

0.25
3.0
0.25
3.2
0.25
5.7
0.25
6.5
0.25
4.7

0.3
3.0
0.3
3.2
0.3
5.7
0.3
6.5
0.3
4.7

0.35
3.0
0.35
3.2
0.35
5.7
0.35
6.5
0.35
4.7

0.4
3.0
0.4
3.2
0.4
5.7
0.4
6.5
0.4
4.7

0.45
3.0
0.45
3.2
0.45
5.7
0.45
6.5
0.45
4.7

0.5
3.0
0.5
3.2
0.5
5.7
0.5
6.5
0.5
4.7

0.55
3.0
0.55
3.2
0.55
5.7
0.55
6.5
0.55
4.7

0.6
3.0
0.6
3.2
0.6
5.7
0.6
6.5
0.6
4.7

0.65
3.0
0.65
3.2
0.65
5.7
0.65
6.5
0.65
4.7

0.7
3.0
0.7
3.2
0.7
5.7
0.7
6.4
0.7
4.7

0.75
3.0
0.75
3.2
0.75
5.7
0.75
6.2
0.75
4.7

0.8
2.8
0.8
3.0
0.8
5.7
0.8
5.9
0.8
4.5

0.85
2.6
0.85
2.8
0.85
5.6
0.85
5.4
0.85
4.2

0.9
2.3
0.9
2.5
0.9
4.8
0.9
4.6
0.9
3.6

0.95
1.8
0.95
1.9
0.95
3.4
0.95
3.3
0.95
2.6

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +

0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 1234zeE +

0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
1.9
0
4.7
0
1.7
0
5.6
0
3.6

0.05
3.0
0.05
5.7
0.05
2.8
0.05
6.5
0.05
4.7

0.1
3.0
0.1
5.7
0.1
2.8
0.1
6.6
0.1
4.7

0.15
3.0
0.15
5.7
0.15
2.8
0.15
6.6
0.15
4.7

0.2
3.0
0.2
5.7
0.2
2.8
0.2
6.5
0.2
4.7

0.25
3.0
0.25
5.7
0.25
2.8
0.25
6.5
0.25
4.6

0.3
2.9
0.3
5.7
0.3
2.7
0.3
6.5
0.3
4.6

0.35
2.9
0.35
5.7
0.35
2.7
0.35
6.5
0.35
4.6

0.4
2.9
0.4
5.7
0.4
2.7
0.4
6.5
0.4
4.6

0.45
2.9
0.45
5.7
0.45
2.7
0.45
6.5
0.45
4.6

0.5
2.9
0.5
5.6
0.5
2.7
0.5
6.5
0.5
4.6

0.55
2.9
0.55
5.6
0.55
2.7
0.55
6.5
0.55
4.6

0.6
2.9
0.6
5.5
0.6
2.7
0.6
6.5
0.6
4.6

0.65
2.9
0.65
5.4
0.65
2.7
0.65
6.4
0.65
4.5

0.7
2.9
0.7
5.3
0.7
2.7
0.7
6.3
0.7
4.5

0.75
2.9
0.75
5.0
0.75
2.7
0.75
6.2
0.75
4.3

0.8
2.7
0.8
4.7
0.8
2.6
0.8
5.9
0.8
4.1

0.85
2.5
0.85
4.2
0.85
2.4
0.85
5.4
0.85
3.7

0.9
2.2
0.9
3.5
0.9
2.1
0.9
4.6
0.9
3.1

0.95
1.8
0.95
2.5
0.95
1.7
0.95
3.3
0.95
2.3

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +

0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +

0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
1.7
0
1.9
0
1.5
0
5.5
0
2.8

0.05
2.8
0.05
3.0
0.05
2.6
0.05
6.4
0.05
3.9

0.1
2.8
0.1
3.0
0.1
2.6
0.1
6.5
0.1
3.9

0.15
2.8
0.15
3.0
0.15
2.6
0.15
6.5
0.15
3.9

0.2
2.8
0.2
3.0
0.2
2.6
0.2
6.5
0.2
3.9

0.25
2.8
0.25
3.0
0.25
2.6
0.25
6.5
0.25
3.9

0.3
2.8
0.3
3.0
0.3
2.6
0.3
6.5
0.3
3.9

0.35
2.8
0.35
3.0
0.35
2.6
0.35
6.5
0.35
3.9

0.4
2.8
0.4
3.0
0.4
2.6
0.4
6.5
0.4
3.9

0.45
2.8
0.45
3.0
0.45
2.6
0.45
6.4
0.45
3.9

0.5
2.8
0.5
3.0
0.5
2.6
0.5
6.4
0.5
3.9

0.55
2.8
0.55
3.0
0.55
2.6
0.55
6.4
0.55
3.9

0.6
2.8
0.6
3.0
0.6
2.6
0.6
6.4
0.6
3.9

0.65
2.8
0.65
3.0
0.65
2.6
0.65
6.4
0.65
3.8

0.7
2.8
0.7
3.0
0.7
2.6
0.7
6.3
0.7
3.8

0.75
2.8
0.75
3.0
0.75
2.6
0.75
6.1
0.75
3.7

0.8
2.7
0.8
2.9
0.8
2.5
0.8
5.8
0.8
3.6

0.85
2.5
0.85
2.7
0.85
2.3
0.85
5.3
0.85
3.3

0.9
2.2
0.9
2.4
0.9
2.1
0.9
4.5
0.9
2.8

0.95
1.8
0.95
1.9
0.95
1.7
0.95
3.2
0.95
2.2

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +

0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +

0.033 F1234zeZ +
0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
1.9
0
4.7
0
2.1
0
5.6
0
3.7

0.05
3.0
0.05
5.7
0.05
3.2
0.05
6.5
0.05
4.7

0.1
3.0
0.1
5.7
0.1
3.2
0.1
6.6
0.1
4.7

0.15
3.0
0.15
5.7
0.15
3.2
0.15
6.6
0.15
4.7

0.2
3.0
0.2
5.7
0.2
3.2
0.2
6.5
0.2
4.7

0.25
3.0
0.25
5.7
0.25
3.2
0.25
6.5
0.25
4.7

0.3
3.0
0.3
5.7
0.3
3.2
0.3
6.5
0.3
4.7

0.35
3.0
0.35
5.7
0.35
3.2
0.35
6.5
0.35
4.7

0.4
3.0
0.4
5.7
0.4
3.2
0.4
6.5
0.4
4.7

0.45
3.0
0.45
5.7
0.45
3.2
0.45
6.5
0.45
4.7

0.5
3.0
0.5
5.6
0.5
3.2
0.5
6.5
0.5
4.7

0.55
2.9
0.55
5.6
0.55
3.1
0.55
6.5
0.55
4.6

0.6
2.9
0.6
5.5
0.6
3.1
0.6
6.5
0.6
4.6

0.65
2.9
0.65
5.4
0.65
3.1
0.65
6.4
0.65
4.6

0.7
2.9
0.7
5.3
0.7
3.1
0.7
6.3
0.7
4.5

0.75
2.9
0.75
5.0
0.75
3.1
0.75
6.2
0.75
4.4

0.8
2.8
0.8
4.7
0.8
3.0
0.8
5.9
0.8
4.1

0.85
2.6
0.85
4.2
0.85
2.7
0.85
5.4
0.85
3.8

0.0
2.2
0.9
3.5
0.9
2.1
0.9
4.6
0.9
3.2

0.95
1.8
0.95
2.5
0.95
1.9
0.95
3.3
0.95
2.4

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234yf-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +

0.033 F1234yf +
0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.25 F1234yf +

0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
2.0
0
6.5
0
4.7
0
5.7
0
4.8

0.05
3.2
0.05
7.5
0.05
5.8
0.05
6.7
0.05
5.9

0.1
3.2
0.1
7.5
0.1
5.9
0.1
6.7
0.1
5.9

0.15
3.2
0.15
7.5
0.15
5.9
0.15
6.7
0.15
5.9

0.2
3.2
0.2
7.5
0.2
5.9
0.2
6.7
0.2
5.9

0.25
3.2
0.25
7.5
0.25
5.9
0.25
6.7
0.25
5.9

0.3
3.2
0.3
7.5
0.3
5.9
0.3
6.7
0.3
5.9

0.35
3.2
0.35
7.5
0.35
5.9
0.35
6.7
0.35
5.9

0.4
3.2
0.4
7.5
0.4
5.9
0.4
6.7
0.4
5.9

0.45
3.2
0.45
7.5
0.45
5.9
0.45
6.7
0.45
5.9

0.5
3.1
0.5
7.5
0.5
5.9
0.5
6.7
0.5
5.9

0.55
3.1
0.55
7.5
0.55
5.9
0.55
6.7
0.55
5.9

0.6
3.1
0.6
7.5
0.6
5.9
0.6
6.6
0.6
5.9

0.65
3.1
0.65
7.5
0.65
5.9
0.65
6.6
0.65
5.9

0.7
3.1
0.7
7.5
0.7
5.9
0.7
6.5
0.7
5.9

0.75
3.1
0.75
7.4
0.75
5.9
0.75
6.3
0.75
5.9

0.8
3.0
0.8
7.0
0.8
5.9
0.8
6.1
0.8
5.6

0.85
2.7
0.85
6.5
0.85
5.8
0.85
5.6
0.85
5.2

0.9
2.4
0.9
5.4
0.9
5.0
0.9
4.7
0.9
4.4

0.95
1.9
0.95
3.8
0.95
3.5
0.95
3.4
0.95
3.1

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +

0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +

0.033 F1243zf +
0.033 F1243zf +
0.9 F1243zf +
0.033 F1243zf +
0.25 F1243zf +

0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
2.1
0
4.9
0
5.7
0
6.5
0
4.9

0.05
3.2
0.05
5.8
0.05
6.7
0.05
7.5
0.05
5.9

0.1
3.2
0.1
5.9
0.1
6.7
0.1
7.5
0.1
5.9

0.15
3.2
0.15
5.9
0.15
6.7
0.15
7.5
0.15
5.9

0.2
3.2
0.2
5.9
0.2
6.7
0.2
7.5
0.2
5.9

0.25
3.2
0.25
5.9
0.25
6.7
0.25
7.5
0.25
5.9

0.3
3.2
0.3
5.9
0.3
6.7
0.3
7.5
0.3
5.9

0.35
3.2
0.35
5.9
0.35
6.7
0.35
7.5
0.35
5.9

0.4
3.1
0.4
5.8
0.4
6.7
0.4
7.5
0.4
5.9

0.45
3.1
0.45
5.8
0.45
6.7
0.45
7.5
0.45
5.9

0.5
3.1
0.5
5.8
0.5
6.7
0.5
7.5
0.5
5.9

0.55
3.1
0.55
5.8
0.55
6.7
0.55
7.5
0.55
5.9

0.6
3.1
0.6
5.7
0.6
6.6
0.6
7.5
0.6
5.9

0.65
3.1
0.65
5.6
0.65
6.6
0.65
7.5
0.65
5.8

0.7
3.1
0.7
5.4
0.7
6.5
0.7
7.5
0.7
5.7

0.75
3.1
0.75
5.2
0.75
6.3
0.75
7.3
0.75
5.6

0.8
2.9
0.8
4.9
0.8
6.0
0.8
7.0
0.8
5.3

0.85
2.7
0.85
4.4
0.85
5.5
0.85
6.4
0.85
4.8

0.9
2.4
0.9
3.6
0.9
4.7
0.9
5.4
0.9
4.0

0.95
1.9
0.95
2.6
0.95
3.3
0.95
3.7
0.95
2.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +

0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +

0.033 F1243zf +
0.033 F1243zf +
0.9 F1243zf +
0.033 F1243zf +
0.25 F1243zf +

0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
1.9
0
2.1
0
5.6
0
6.4
0
4.1

0.05
3.1
0.05
3.2
0.05
6.6
0.05
7.4
0.05
5.2

0.1
3.1
0.1
3.2
0.1
6.6
0.1
7.4
0.1
5.2

0.15
3.1
0.15
3.2
0.15
6.6
0.15
7.4
0.15
5.2

0.2
3.1
0.2
3.2
0.2
6.6
0.2
7.4
0.2
5.2

0.25
3.1
0.25
3.2
0.25
6.6
0.25
7.4
0.25
5.2

0.3
3.1
0.3
3.2
0.3
6.6
0.3
7.4
0.3
5.2

0.35
3.0
0.35
3.2
0.35
6.6
0.35
7.4
0.35
5.2

0.4
3.0
0.4
3.2
0.4
6.6
0.4
7.4
0.4
5.2

0.45
3.0
0.45
3.2
0.45
6.6
0.45
7.4
0.45
5.2

0.5
3.0
0.5
3.2
0.5
6.6
0.5
7.4
0.5
5.2

0.55
3.0
0.55
3.2
0.55
6.6
0.55
7.4
0.55
5.2

0.5
3.0
0.6
3.2
0.6
6.5
0.6
7.4
0.6
5.2

0.65
3.0
0.65
3.2
0.65
6.5
0.65
7.4
0.65
5.2

0.7
3.0
0.7
3.2
0.7
6.4
0.7
7.4
0.7
5.1

0.75
3.0
0.75
3.2
0.75
6.2
0.75
7.2
0.75
5.0

0.8
2.9
0.8
3.1
0.8
6.0
0.8
6.9
0.8
4.8

0.85
2.6
0.85
2.8
0.85
5.5
0.85
6.3
0.85
4.4

0.9
2.3
0.9
2.5
0.9
4.6
0.9
5.3
0.9
3.7

0.95
1.8
0.95
2.0
0.95
3.3
0.95
3.7
0.95
2.7

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1233xf +
0.033 F1233xf +
0.033 F1233xf +
0.034 F1233xf +
0.25 F1233xf +

0.033 F1243zf +
0.9 F1243zf +
0.033 F1243zf +
0.033 F1243zf +
0.25 F1243zf +

0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +

0.034 F1234yf
0.034 F1234yf
0.034 F1234yf
0.9 F1234yf
0.25 F1234yf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
1.9
0
5.6
0
1.7
0
6.4
0
4.1

0.05
3.0
0.05
6.6
0.05
2.8
0.05
7.4
0.05
5.2

0.1
3.0
0.1
6.6
0.1
2.8
0.1
7.4
0.1
5.2

0.15
3.0
0.15
6.6
0.15
2.8
0.15
7.4
0.15
5.2

0.2
3.0
0.2
6.6
0.2
2.8
0.2
7.4
0.2
5.2

0.25
3.0
0.25
6.6
0.25
2.8
0.25
7.4
0.25
5.2

0.3
3.0
0.3
6.6
0.3
2.8
0.3
7.4
0.3
5.2

0.35
3.0
0.35
6.6
0.35
2.8
0.35
7.4
0.35
5.2

0.4
3.0
0.4
6.6
0.4
2.8
0.4
7.4
0.4
5.2

0.45
3.0
0.45
6.6
0.45
2.8
0.45
7.4
0.45
5.2

0.5
3.0
0.5
6.6
0.5
2.8
0.5
7.4
0.5
5.1

0.55
3.0
0.55
6.6
0.55
2.8
0.55
7.4
0.55
5.1

0.6
3.0
0.6
6.5
0.6
2.8
0.6
7.4
0.6
5.1

0.65
3.0
0.65
6.5
0.65
2.8
0.65
7.4
0.65
5.1

0.7
3.0
0.7
6.4
0.7
2.8
0.7
7.4
0.7
5.1

0.75
3.0
0.75
6.2
0.75
2.8
0.75
7.2
0.75
4.9

0.8
2.8
0.8
6.0
0.8
2.7
0.8
6.9
0.8
4.7

0.85
2.6
0.85
5.5
0.85
2.5
0.85
6.3
0.85
4.3

0.9
2.3
0.9
4.6
0.9
2.2
0.9
5.3
0.9
3.7

0.95
1.8
0.95
3.3
0.95
1.8
0.95
3.7
0.95
2.7

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +

0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +

0.033 F1234zeE +
0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
6.5
0
2.2
0
4.9
0
5.7
0
4.9

0.05
7.5
0.05
3.3
0.05
5.8
0.05
6.7
0.05
5.9

0.1
7.5
0.1
3.3
0.1
5.9
0.1
6.7
0.1
5.9

0.15
7.5
0.15
3.3
0.15
5.8
0.15
6.7
0.15
5.9

0.2
7.5
0.2
3.3
0.2
5.8
0.2
6.7
0.2
5.9

0.25
7.5
0.25
3.3
0.25
5.8
0.25
6.7
0.25
5.9

0.3
7.5
0.3
3.3
0.3
5.8
0.3
6.7
0.3
5.9

0.35
7.5
0.35
3.3
0.35
5.8
0.35
6.7
0.35
5.9

0.4
7.5
0.4
3.3
0.4
5.8
0.4
6.7
0.4
5.9

0.45
7.5
0.45
3.3
0.45
5.8
0.45
6.7
0.45
5.9

0.5
7.5
0.5
3.3
0.5
5.8
0.5
6.7
0.5
5.9

0.55
7.5
0.55
3.3
0.55
5.8
0.55
6.7
0.55
5.9

0.6
7.5
0.6
3.3
0.6
5.7
0.6
6.6
0.6
5.9

0.65
7.5
0.65
3.3
0.65
5.6
0.65
6.6
0.65
5.8

0.7
7.5
0.7
3.3
0.7
5.4
0.7
6.5
0.7
5.7

0.75
7.3
0.75
3.3
0.75
5.2
0.75
6.3
0.75
5.6

0.8
7.0
0.8
3.1
0.8
4.9
0.8
6.0
0.8
5.3

0.85
6.4
0.85
2.9
0.85
4.4
0.85
5.6
0.85
4.8

0.9
5.4
0.9
2.5
0.9
3.7
0.9
4.7
0.9
4.1

0.95
3.7
0.95
2.0
0.95
2.6
0.95
3.3
0.95
2.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +

0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +

0.033 F1234zeE +
0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
6.5
0
1.9
0
4.9
0
5.7
0
4.8

0.05
7.5
0.05
3.0
0.05
5.8
0.05
6.7
0.05
5.8

0.1
7.5
0.1
3.0
0.1
5.9
0.1
6.7
0.1
5.9

0.15
7.5
0.15
3.0
0.15
5.8
0.15
6.7
0.15
5.9

0.2
7.5
0.2
3.0
0.2
5.8
0.2
6.7
0.2
5.9

0.25
7.5
0.25
3.0
0.25
5.8
0.25
6.7
0.25
5.9

0.3
7.5
0.3
3.0
0.3
5.8
0.3
6.7
0.3
5.9

0.35
7.5
0.35
2.9
0.35
5.8
0.35
6.7
0.35
5.9

0.4
7.5
0.4
2.9
0.4
5.8
0.4
6.7
0.4
5.9

0.45
7.5
0.45
2.9
0.45
5.8
0.45
6.7
0.45
5.9

0.5
7.5
0.5
2.9
0.5
5.8
0.5
6.7
0.5
5.8

0.55
7.5
0.55
2.9
0.55
5.8
0.55
6.6
0.55
5.8

0.6
7.5
0.6
2.9
0.6
5.7
0.6
6.6
0.6
5.8

0.65
7.5
0.65
2.9
0.65
5.6
0.65
6.6
0.65
5.8

0.7
7.5
0.7
2.9
0.7
5.4
0.7
6.5
0.7
5.7

0.75
7.3
0.75
2.9
0.75
5.2
0.75
6.3
0.75
5.5

0.8
7.0
0.8
2.7
0.8
4.9
0.8
6.0
0.8
5.2

0.85
6.4
0.85
2.5
0.85
4.4
0.85
5.5
0.85
4.8

0.9
5.4
0.9
2.2
0.9
3.6
0.9
4.7
0.9
4.0

0.95
3.7
0.95
1.8
0.95
2.6
0.95
3.3
0.95
2.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +

0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +

0.033 F1234zeZ +
0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
6.4
0
1.7
0
2.1
0
5.6
0
4.1

0.05
7.4
0.05
2.9
0.05
3.2
0.05
6.6
0.05
5.2

0.1
7.4
0.1
2.9
0.1
3.2
0.1
6.6
0.1
5.2

0.15
7.4
0.15
2.9
0.15
3.2
0.15
6.6
0.15
5.2

0.2
7.4
0.2
2.9
0.2
3.2
0.2
6.6
0.2
5.2

0.25
7.4
0.25
2.8
0.25
3.2
0.25
6.6
0.25
5.2

0.3
7.4
0.3
2.8
0.3
3.2
0.3
6.6
0.3
5.2

0.35
7.4
0.35
2.8
0.35
3.2
0.35
6.6
0.35
5.1

0.4
7.4
0.4
2.8
0.4
3.2
0.4
6.6
0.4
5.1

0.45
7.4
0.45
2.8
0.45
3.2
0.45
6.6
0.45
5.1

0.5
7.4
0.5
2.8
0.5
3.2
0.5
6.6
0.5
5.1

0.55
7.4
0.55
2.8
0.55
3.2
0.55
6.6
0.55
5.1

0.6
7.4
0.6
2.8
0.6
3.2
0.6
6.5
0.6
5.1

0.65
7.4
0.65
2.8
0.65
3.2
0.65
6.5
0.65
5.1

0.7
7.4
0.7
2.8
0.7
3.2
0.7
6.4
0.7
5.1

0.75
7.2
0.75
2.8
0.75
3.2
0.75
6.2
0.75
5.0

0.8
6.9
0.8
2.7
0.8
3.0
0.8
5.9
0.8
4.7

0.85
6.3
0.85
2.5
0.85
2.8
0.85
5.5
0.85
4.3

0.9
5.3
0.9
2.2
0.9
2.5
0.9
4.6
0.9
3.7

0.95
3.7
0.95
1.8
0.95
2.0
0.95
3.3
0.95
2.7

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +

0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +

0.033 F245cb +
0.033 F245cb +
0.09 F245cb +
0.033 F245cb +
0.25 F245cb +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.09 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
6.6
0
5.0
0
4.8
0
5.8
0
5.6

0.05
7.6
0.05
5.9
0.05
6.0
0.05
6.8
0.05
6.6

0.1
7.6
0.1
6.0
0.1
6.0
0.1
6.8
0.1
6.6

0.15
7.6
0.15
6.0
0.15
6.0
0.15
6.8
0.15
6.6

0.2
7.6
0.2
6.0
0.2
6.0
0.2
6.8
0.2
6.6

0.25
7.6
0.25
6.0
0.25
6.0
0.25
6.8
0.25
6.6

0.3
7.6
0.3
6.0
0.3
6.0
0.3
6.8
0.3
6.6

0.35
7.6
0.35
6.0
0.35
6.0
0.35
6.8
0.35
6.6

0.4
7.6
0.4
6.0
0.4
6.0
0.4
6.8
0.4
6.6

0.45
7.6
0.45
5.9
0.45
6.0
0.45
6.8
0.45
6.6

0.5
7.6
0.5
5.9
0.5
6.0
0.5
6.8
0.5
6.6

0.55
7.6
0.55
5.9
0.55
6.0
0.55
6.7
0.55
6.6

0.6
7.6
0.6
5.8
0.6
6.0
0.6
6.7
0.6
6.6

0.65
7.6
0.65
5.7
0.65
5.9
0.65
6.7
0.65
6.6

0.7
7.6
0.7
5.6
0.7
5.9
0.7
6.6
0.7
6.6

0.75
7.4
0.75
5.3
0.75
5.9
0.75
6.4
0.75
6.4

0.8
7.1
0.8
5.0
0.8
5.9
0.8
6.1
0.8
6.1

0.85
6.5
0.85
4.5
0.85
5.8
0.85
5.6
0.85
5.6

0.9
5.5
0.9
3.7
0.9
5.0
0.9
4.8
0.9
4.8

0.95
3.8
0.95
2.7
0.95
3.5
0.95
3.4
0.95
3.4

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +

0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +

0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
6.5
0
2.2
0
4.7
0
5.7
0
4.8

0.05
7.5
0.05
3.3
0.05
5.8
0.05
6.7
0.05
5.9

0.1
7.5
0.1
3.3
0.1
5.8
0.1
6.7
0.1
5.9

0.15
7.5
0.15
3.3
0.15
5.8
0.15
6.7
0.15
5.9

0.2
7.5
0.2
3.3
0.2
5.8
0.2
6.7
0.2
5.9

0.25
7.5
0.25
3.3
0.25
5.8
0.25
6.7
0.25
5.9

0.3
7.5
0.3
3.3
0.3
5.8
0.3
6.7
0.3
5.9

0.35
7.5
0.35
3.3
0.35
5.8
0.35
6.7
0.35
5.9

0.4
7.5
0.4
3.3
0.4
5.8
0.4
6.7
0.4
5.9

0.45
7.5
0.45
3.3
0.45
5.8
0.45
6.7
0.45
5.9

0.5
7.5
0.5
3.3
0.5
5.8
0.5
6.7
0.5
5.9

0.55
7.5
0.55
3.3
0.55
5.8
0.55
6.7
0.55
5.9

0.6
7.5
0.6
3.3
0.6
5.8
0.6
6.6
0.6
5.9

0.65
7.5
0.65
3.3
0.65
5.8
0.65
6.6
0.65
5.9

0.7
7.5
0.7
3.3
0.7
5.9
0.7
6.5
0.7
5.9

0.75
7.3
0.75
3.3
0.75
5.9
0.75
6.3
0.75
5.9

0.8
7.0
0.8
3.2
0.8
5.9
0.8
6.1
0.8
5.6

0.85
6.5
0.85
2.9
0.85
5.8
0.85
5.6
0.85
5.2

0.9
5.4
0.9
2.6
0.9
5.0
0.9
4.7
0.9
4.4

0.95
3.8
0.95
2.0
0.95
3.5
0.95
3.4
0.95
3.2

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1234yf +
0.033 F1234yf +
0.033 F1234yf +
0.034 F1234yf +
0.25 F1234yf +

0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +

0.033 F245cb +
0.033 F245cb +
0.9 F245cb +
0.033 F245cb +
0.25 F245cb +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
6.5
0
1.8
0
4.7
0
5.7
0
4.8

0.05
7.5
0.05
2.9
0.05
5.8
0.05
6.7
0.05
5.9

0.1
7.5
0.1
2.9
0.1
5.8
0.1
6.7
0.1
5.9

0.15
7.5
0.15
2.9
0.15
5.8
0.15
6.7
0.15
5.9

0.2
7.5
0.2
2.9
0.2
5.8
0.2
6.7
0.2
5.9

0.25
7.5
0.25
2.9
0.25
5.8
0.25
6.7
0.25
5.9

0.3
7.5
0.3
2.9
0.3
5.8
0.3
6.7
0.3
5.9

0.35
7.5
0.35
2.9
0.35
5.8
0.35
6.7
0.35
5.9

0.4
7.5
0.4
2.9
0.4
5.8
0.4
6.7
0.4
5.9

0.45
7.5
0.45
2.9
0.45
5.8
0.45
6.7
0.45
5.9

0.5
7.5
0.5
2.9
0.5
5.8
0.5
6.7
0.5
5.9

0.55
7.5
0.55
2.9
0.55
5.8
0.55
6.7
0.55
5.9

0.6
7.5
0.6
2.9
0.6
5.8
0.6
6.6
0.6
5.9

0.65
7.5
0.65
2.9
0.65
5.8
0.55
6.6
0.65
5.9

0.7
7.5
0.7
2.9
0.7
5.8
0.7
6.5
0.7
5.9

0.75
7.3
0.75
2.9
0.75
5.8
0.75
6.3
0.75
5.8

0.8
7.0
0.8
2.8
0.8
5.8
0.8
6.1
0.8
5.6

0.85
6.5
0.85
2.6
0.85
5.8
0.85
5.6
0.85
5.1

0.9
5.4
0.9
2.3
0.9
5.0
0.9
4.7
0.9
4.4

0.95
3.8
0.95
1.3
0.95
3.5
0.95
3.4
0.95
3.1

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F245cb +
0.033 F245cb +
0.033 F245cb +
0.034 F245cb +
0.25 F245cb +

0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +

0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +

0.034 F1243zf
0.033 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.6
0
4.8
0
1.8
0
5.7
0
4.3

0.05
5.8
0.05
5.8
0.05
2.9
0.05
6.6
0.05
5.4

0.1
5.8
0.1
5.8
0.1
2.9
0.1
6.6
0.1
5.4

0.15
5.8
0.15
5.8
0.15
2.9
0.15
6.6
0.15
5.4

0.2
5.8
0.2
5.8
0.2
2.9
0.2
6.6
0.2
5.4

0.25
5.8
0.25
5.8
0.25
2.9
0.25
6.6
0.25
5.4

0.3
5.8
0.3
5.8
0.3
2.9
0.3
6.6
0.3
5.4

0.35
5.8
0.35
5.8
0.35
2.9
0.35
6.6
0.35
5.4

0.4
5.8
0.4
5.8
0.4
2.9
0.4
6.6
0.4
5.4

0.45
5.8
0.45
5.8
0.45
2.9
0.45
6.6
0.45
5.4

0.5
5.8
0.5
5.7
0.5
2.9
0.5
6.6
0.5
5.4

0.55
5.8
0.55
5.7
0.55
2.9
0.55
6.6
0.55
5.4

0.6
5.8
0.6
5.6
0.6
2.9
0.6
6.6
0.6
5.4

0.65
5.8
0.65
5.5
0.65
2.8
0.65
6.5
0.65
5.4

0.7
5.8
0.7
5.4
0.7
2.8
0.7
6.4
0.7
5.4

0.75
5.8
0.75
5.2
0.75
5.8
0.75
6.3
0.75
5.2

0.8
5.8
0.8
4.8
0.8
2.7
0.8
6.0
0.8
5.0

0.85
5.7
0.85
4.3
0.85
2.5
0.85
5.5
0.85
4.5

0.9
4.9
0.9
3.6
0.9
2.2
0.9
4.7
0.9
3.9

0.95
3.5
0.95
2.6
0.95
1.8
0.95
3.3
0.95
2.8

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F245cb +
0.033 F245cb +
0.033 F245cb +
0.034 F245cb +
0.25 F245cb +

0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +

0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.5
0
2.0
0
1.7
0
5.6
0
3.5

0.05
5.7
0.05
3.2
0.05
2.8
0.05
6.5
0.05
4.6

0.1
5.7
0.1
3.2
0.1
2.8
0.1
6.6
0.1
4.6

0.15
5.7
0.15
3.2
0.15
2.8
0.15
6.6
0.15
4.6

0.2
5.7
0.2
3.2
0.2
2.8
0.2
6.5
0.2
4.6

0.25
5.7
0.25
3.2
0.25
2.8
0.25
6.5
0.25
4.6

0.3
5.7
0.3
3.2
0.3
2.8
0.3
6.5
0.3
4.6

0.35
5.7
0.35
3.2
0.35
2.8
0.35
6.5
0.35
4.6

0.4
5.7
0.4
3.2
0.4
2.8
0.4
6.5
0.4
4.6

0.45
5.7
0.45
3.2
0.45
2.8
0.45
6.5
0.45
4.6

0.5
5.7
0.5
3.2
0.5
2.8
0.5
6.5
0.5
4.7

0.55
5.7
0.55
3.2
0.55
2.8
0.55
6.5
0.55
4.7

0.6
5.7
0.6
3.2
0.6
2.8
0.6
6.5
0.6
4.7

0.65
5.7
0.65
3.2
0.65
2.8
0.65
6.4
0.65
4.7

0.7
5.7
0.7
3.2
0.7
2.8
0.7
6.4
0.7
4.7

0.75
5.7
0.75
3.1
0.75
2.8
0.75
6.2
0.75
4.7

0.8
5.7
0.8
3.0
0.8
2.6
0.8
5.9
0.8
4.5

0.85
5.6
0.85
2.8
0.85
2.4
0.85
5.4
0.85
4.1

0.9
4.8
0.9
2.5
0.9
2.2
0.9
4.6
0.9
3.5

0.95
3.4
0.95
1.9
0.95
1.8
0.95
3.3
0.95
2.6

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.034 F1234zeE +
0.25 F1234zeE +

0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +

0.033 F1233zdE +
0.033 F1233zdE +
0.9 F1233zdE +
0.033 F1233zdE +
0.25 F1233zdE +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL
MASS-
TOTAL

FRAC
PRES
FRAC
PRES
FRAC
PRES
FRAC
PRES
FRAC
PRES

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.7
0
2.1
0
1.7
0
5.6
0
3.6

0.05
5.7
0.05
3.2
0.05
2.8
0.05
6.5
0.05
4.7

0.1
5.7
0.1
3.2
0.1
2.8
0.1
6.6
0.1
4.7

0.15
5.7
0.15
3.2
0.15
2.8
0.15
6.5
0.15
4.7

0.2
5.7
0.2
3.2
0.2
2.8
0.2
6.5
0.2
4.7

0.25
5.7
0.25
3.2
0.25
2.8
0.25
6.5
0.25
4.7

0.3
5.7
0.3
3.2
0.3
2.8
0.3
6.5
0.3
4.6

0.35
5.7
0.35
3.1
0.35
2.8
0.35
6.5
0.35
4.6

0.4
5.7
0.4
3.1
0.4
2.8
0.4
6.5
0.4
4.6

0.45
5.7
0.45
3.1
0.45
2.7
0.45
6.5
0.45
4.6

0.5
5.6
0.5
3.1
0.5
2.7
0.5
6.5
0.5
4.6

0.55
5.6
0.55
3.1
0.55
2.7
0.55
6.5
0.55
4.6

0.6
5.5
0.6
3.1
0.6
2.7
0.6
6.5
0.6
4.6

0.65
5.4
0.65
3.1
0.65
2.7
0.65
6.4
0.65
4.6

0.7
5.3
0.7
3.1
0.7
2.7
0.7
6.3
0.7
4.5

0.75
5.0
0.75
3.1
0.75
2.7
0.75
6.2
0.75
4.3

0.8
4.7
0.8
3.0
0.8
2.6
0.8
5.9
0.8
4.1

0.85
4.2
0.85
2.7
0.85
2.4
0.85
5.4
0.85
3.7

0.9
3.5
0.9
2.4
0.9
2.1
0.9
4.6
0.0
3.2

0.95
2.5
0.95
1.9
0.95
1.7
0.95
3.3
0.95
2.4

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics

0.9 F245cb +
0.033 F245cb +
0.033 F245cb +
0.034 F245cb +
0.25 F245cb +

0.033 F1234zeE +
0.9 F1234zeE +
0.033 F1234zeE +
0.033 F1234zeE +
0.25 F1234zeE +

0.033 F1234zeZ +
0.033 F1234zeZ +
0.9 F1234zeZ +
0.033 F1234zeZ +
0.25 F1234zeZ +

0.034 F1243zf
0.034 F1243zf
0.034 F1243zf
0.9 F1243zf
0.25 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.6
0
4.8
0
2.2
0
5.7
0
4.4

0.05
5.8
0.05
5.8
0.05
3.3
0.05
6.6
0.05
5.4

0.1
5.8
0.1
5.8
0.1
3.3
0.1
6.7
0.1
5.4

0.15
5.8
0.15
6.8
0.15
3.3
0.15
6.6
0.15
5.4

0.2
5.8
0.2
5.8
0.2
3.3
0.2
6.6
0.2
5.4

0.25
5.8
0.25
5.8
0.25
3.3
0.25
6.6
0.25
5.4

0.3
5.8
0.3
5.8
0.3
3.3
0.3
6.6
0.3
5.4

0.35
5.8
0.35
5.8
0.35
3.3
0.35
6.6
0.35
5.4

0.4
5.8
0.4
5.8
0.4
3.3
0.4
6.6
0.4
5.4

0.45
5.8
0.45
5.8
0.45
3.3
0.45
6.6
0.45
5.4

0.5
5.8
0.5
5.7
0.5
3.3
0.5
6.6
0.5
5.4

0.55
5.8
0.55
5.7
0.55
3.3
0.55
6.6
0.55
5.4

0.6
5.8
0.6
5.6
0.6
3.3
0.6
6.6
0.6
5.4

0.65
5.8
0.65
5.5
0.65
3.3
0.65
6.5
0.65
5.4

0.7
5.8
0.7
5.4
0.7
3.2
0.7
6.4
0.7
5.4

0.75
5.8
0.75
5.2
0.75
3.2
0.75
6.3
0.75
5.3

0.8
5.8
0.8
4.8
0.8
3.1
0.8
6.0
0.8
5.0

0.85
5.7
0.85
4.3
0.85
2.9
0.85
5.5
0.85
4.6

0.9
4.9
0.9
3.6
0.9
2.5
0.9
4.7
0.9
3.9

0.95
3.5
0.95
2.6
0.95
2.0
0.95
3.3
0.95
2.8

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

EXAMPLE 8: TEMPERATURE AND PRESSURE RANGE OF PENTERNARY MIXTURES

Boiling point range

Temperature
Pressure

System with 5 compounds
° C.
bar abs

HF-HCFO-1233xf-HFC-245cb-HCFO-
0 to 40
~1.0 to ~10.0

1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.0 to ~10.2

1234zeE-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.1 to ~10.1

1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.2 to ~11.4

1234yf-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~1.2 to ~11.4

1234zeE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~1.2 to ~11.2

1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HCFO-
0 to 40
~1.0 to ~11.2

1233zdE-HFO-1243zf

HF-HCFO-1233xf-HCFO-1233zdE-HFO-
0 to 40
~1.0 to ~10.1

1234zeE-HFO-1243zf

HF-HCFO-1233xf-HCFO-1233zdE-HFO-
0 to 40
~1.0 to ~9.9

1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234zeE-HFO-
0 to 40
~1.0 to ~10.1

1234zeZ-HFO-1243zf

HF-HFO-1234yf-HFO-1234zeE-HFO-
0 to 40
~1.3 to ~11.4

1234zeZ-HFO-1243zf

HF-HFO-1234yf-HFO-1234zeE-HCFO-
0 to 40
~1.0 to ~11.4

1233zdE-HFO-1243zf

HF-HFO-1234yf-HFO-1234zeZ-HCFO-
0 to 40
~1.1 to ~11.2

1233zdE-HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HFO-
0 to 40
~2.5 to ~11.6

1234zeE-HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HFO-
0 to 40
~1.3 to ~10.3

1234zeZ-HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HCFO-
0 to 40
~1.1 to ~11.4

1233zdE-HFO-1243zf

HF-HFC-245cb-HCFO-1233zdE-HFO-
0 to 40
~1.1 to ~10.2

1234zeE-HFO-1243zf

HF-HFC-245cb-HCFO-1233zdE-HFO-
0 to 40
~1.0 to ~10.1

1234zeZ-HFO-1243zf

HF-HFC-245cb-HFO-1234zeE-HFO-
0 to 40
~1.2 to ~10.2

1234zeZ-HFO-1243zf

HF-HCFO-1233zdE-HFO-1234zeE-HFO-
0 to 40
~1.0 to ~10.1

1234zeZ-HFO-1243zf

EXAMPLE 9: DECANTATION RANGE OF PENTERNARY MIXTURES

Decantation ranges

Mass percentage of HF

Isotherm
Isotherm
Isotherm

System with 5 compounds
0° C.
25° C.
40° C.

HF-HCFO-1233xf-HFC-245cb-HCFO-
5-75
5-70
5-65

1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-
10-75
10-65
*

HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-
5-75
5-70
10-60

HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-1234yf-
5-75
10-70
*

HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFO-
5-70
10-60
*

1234zeE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFO-
5-75
10-65
20-40

1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HCFO-
5-75
5-65
15-45

1233zdE-HFO-1243zf

HF-HCFO-1233xf-HCFO-1233zdE-HFO-
5-75
5-65
15-45

1234zeE-HFO-1243zf

HF-HCFO-1233xf-HCFO-1233zdE-HFO-
5-75
5-70
10-60

1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234zeE-HFO-
5-75
10-65
15-40

1234zeZ-HFO-1243zf

HF-HFO-1234yf-HFO-1234zeE-HFO-
5-70
10-60
*

1234zeZ-HFO-1243zf

HF-HFO-1234yf-HFO-1234zeE-HCFO-
5-70
10-60
*

1233zdE-HFO-1243zf

HF-HFO-1234yf-HFO-1234zeZ-HCFO-
5-75
10-65
15-45

1233zdE-HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-
5-75
15-65
*

HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-
5-75
10-70
*

HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HCFO-
5-75
10-70
*

1233zdE-HFO-1243zf

HF-HFC-245cb-HCFO-1233zdE-HFO-
5-75
10-65
*

1234zeE-HFO-1243zf

HF-HFC-245cb-HCFO-1233zdE-HFO-
5-75
5-70
10-60

1234zeZ-HFO-1243zf

HF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-
5-75
10-65
*

HFO-1243zf

HF-HCFO-1233zdE-HFO-1234zeE-HFO-
5-75
5-65
15-50

1234zeZ-HFO-1243zf

EXAMPLE 10: SYSTEM WITH SIX COMPOUNDS, ISOTHERM AT 25° C.

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.2 F1234yf +
0.01 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.2 F245cb
0.01 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +

0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +

0.2 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.96 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.9
0
1.7
0
6.7
0
4.7
0
4.9
0
5.8

0.05
5.9
0.05
2.8
0.05
7.7
0.05
5.8
0.05
5.8
0.05
6.7

0.1
5.9
0.1
2.8
0.1
7.7
0.1
5.8
0.1
5.9
0.1
6.8

0.15
5.9
0.15
2.8
0.15
7.7
0.15
5.8
0.15
5.8
0.15
6.8

0.2
5.9
0.2
2.8
0.2
7.7
0.2
5.8
0.2
5.8
0.2
6.8

0.25
5.9
0.25
2.8
0.25
7.7
0.25
5.8
0.25
5.8
0.25
6.8

0.3
5.9
0.3
2.8
0.3
7.7
0.3
5.8
0.3
5.8
0.3
6.8

0.35
5.9
0.35
2.8
0.35
7.7
0.35
5.8
0.35
5.6
0.35
6.8

0.4
5.9
0.4
2.8
0.4
7.7
0.4
5.8
0.4
5.8
0.4
6.8

0.45
5.9
0.45
2.8
0.45
7.7
0.45
5.8
0.45
5.8
0.45
6.7

0.5
5.9
0.5
2.8
0.5
7.7
0.5
5.8
0.5
5.8
0.5
6.7

0.55
5.9
0.55
2.8
0.55
7.7
0.55
5.8
0.55
5.7
0.55
6.7

0.6
5.9
0.6
2.8
0.6
7.7
0.6
5.8
0.6
5.7
0.6
6.7

0.65
5.9
0.65
2.8
0.65
7.7
0.65
5.8
0.65
5.6
0.65
6.6

0.7
5.9
0.7
2.8
0.7
7.6
0.7
5.8
0.7
5.4
0.7
6.5

0.75
5.7
0.75
2.8
0.75
7.5
0.75
5.8
0.75
5.2
0.75
6.4

0.8
5.5
0.7
2.7
0.8
7.2
0.8
5.8
0.8
4.8
0.8
6.1

0.85
5.0
0.85
2.5
0.85
6.6
0.85
5.8
0.85
4.3
0.85
5.6

0.9
4.2
0.9
2.2
0.9
5.5
0.9
5.0
0.9
3.6
0.9
4.8

0.95
3.0
0.95
1.8
0.95
3.8
0.95
3.5
0.95
2.6
0.95
3.4

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.2 F1234yf +
0.01 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.2 F245cb
0.01 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +

0.2 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.96 F1234zeZ +
0.01 F1234zeZ +

0.2 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.96 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.2
0
1.7
0
6.7
0
4.6
0
1.9
0
5.8

0.05
5.3
0.05
2.8
0.05
7.6
0.05
5.8
0.05
3.0
0.05
6.7

0.1
5.3
0.1
2.8
0.1
7.7
0.1
5.8
0.1
3.0
0.1
6.8

0.15
5.3
0.15
2.8
0.15
7.6
0.15
5.8
0.15
3.0
0.15
6.7

0.2
5.3
0.2
2.8
0.2
7.6
0.2
5.8
0.2
3.0
0.2
6.7

0.25
5.3
0.25
2.8
0.25
7.6
0.25
5.8
0.25
3.0
0.25
6.7

0.3
5.3
0.3
2.8
0.3
7.6
0.3
5.8
0.3
3.0
0.3
6.7

0.35
5.3
0.35
2.8
0.35
7.6
0.35
5.8
0.35
3.0
0.35
6.7

0.4
5.3
0.4
2.8
0.4
7.6
0.4
5.8
0.4
3.0
0.4
6.7

0.45
5.3
0.45
2.8
0.45
7.6
0.45
5.8
0.45
3.0
0.45
6.7

0.5
5.3
0.5
2.8
0.5
7.6
0.5
5.8
0.5
3.0
0.5
6.7

0.55
5.3
0.55
2.8
0.55
7.6
0.55
5.8
0.55
3.0
0.55
6.7

0.6
5.3
0.6
2.8
0.6
7.6
0.6
5.8
0.6
3.0
0.6
6.7

0.65
5.3
0.65
2.8
0.65
7.6
0.65
5.8
0.65
3.0
0.65
6.6

0.7
5.3
0.7
2.8
0.7
7.6
0.7
5.8
0.7
3.0
0.7
6.5

0.75
5.3
0.75
2.8
0.75
7.5
0.75
5.8
0.75
3.0
0.75
6.4

0.8
5.1
0.8
2.7
0.8
7.2
0.8
5.8
0.8
2.9
0.8
6.1

0.85
4.7
0.85
2.5
0.85
6.6
0.85
5.8
0.85
2.7
0.85
5.6

0.9
4.0
0.9
2.2
0.9
5.5
0.9
5.0
0.9
2.4
0.9
4.7

0.95
2.9
0.95
1.8
0.95
3.8
0.95
3.5
0.95
1.9
0.95
3.4

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.2 F1234yf +
0.01 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.2 F245cb
0.01 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +

0.2 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.96 F1233zdE +
0.01 F1233zdE +

0.2 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.96 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.2
0
1.7
0
6.7
0
4.6
0
1.5
0
5.8

0.05
5.3
0.05
2.8
0.05
7.6
0.05
5.8
0.05
2.6
0.05
6.7

0.1
5.3
0.1
2.8
0.1
7.7
0.1
5.8
0.1
2.6
0.1
6.8

0.15
5.3
0.15
2.8
0.15
7.6
0.15
5.8
0.15
2.6
0.15
6.7

0.2
5.3
0.2
2.8
0.2
7.6
0.2
5.8
0.2
2.6
0.2
6.7

0.25
5.3
0.25
2.8
0.25
7.6
0.25
5.8
0.25
2.6
0.25
6.7

0.3
5.3
0.3
2.8
0.3
7.6
0.3
5.8
0.3
2.6
0.3
6.7

0.35
5.3
0.35
2.8
0.35
7.6
0.35
5.8
0.35
2.6
0.35
6.7

0.4
5.3
0.4
2.8
0.4
7.6
0.4
5.8
0.4
2.6
0.4
6.7

0.45
5.3
0.45
2.8
0.45
7.6
0.45
5.8
0.45
2.6
0.45
6.7

0.5
5.3
0.5
2.8
0.5
7.6
0.5
5.8
0.5
2.6
0.5
6.7

0.55
5.3
0.55
2.8
0.55
7.6
0.55
5.8
0.55
2.6
0.55
6.7

0.6
5.3
0.6
2.8
0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.7

0.65
5.3
0.65
2.8
0.65
7.6
0.65
5.8
0.65
2.6
0.65
6.6

0.7
5.3
0.7
2.8
0.7
7.6
0.7
5.8
0.7
2.6
0.7
6.5

0.75
5.2
0.75
2.8
0.75
7.5
0.75
5.8
0.75
2.6
0.75
6.4

0.8
5.0
0.8
2.7
0.8
7.2
0.8
5.8
0.8
2.5
0.8
6.1

0.85
4.6
0.85
2.5
0.85
6.6
0.85
5.8
0.85
2.3
0.85
5.6

0.9
3.9
0.9
2.2
0.9
5.5
0.9
5.0
0.9
2.0
0.9
4.7

0.95
2.8
0.95
1.8
0.95
3.8
0.95
3.5
0.95
1.7
0.95
3.4

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.2 F1234yf +
0.01 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.2 F1243zf
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +

0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.3
0
1.7
0
6.7
0
5.8
0
4.8
0
1.9

0.05
5.3
0.05
2.8
0.05
7.6
0.05
6.7
0.05
5.8
0.05
3.0

0.1
5.3
0.1
2.8
0.1
7.6
0.1
6.7
0.1
5.8
0.1
3.0

0.15
5.3
0.15
2.8
0.15
7.6
0.15
6.7
0.15
5.8
0.15
3.0

0.2
5.3
0.2
2.8
0.2
7.6
0.2
6.7
0.2
5.8
0.2
3.0

0.25
5.3
0.25
2.8
0.25
7.6
0.25
6.7
0.25
5.8
0.25
3.0

0.3
5.3
0.3
2.8
0.3
7.6
0.3
6.7
0.3
5.8
0.3
3.0

0.35
5.3
0.35
2.8
0.35
7.6
0.35
6.7
0.35
5.8
0.35
3.0

0.4
5.3
0.4
2.8
0.4
7.6
0.4
6.7
0.4
5.8
0.4
3.0

0.45
5.3
0.45
2.8
0.45
7.6
0.45
6.7
0.45
5.8
0.45
3.0

0.5
5.3
0.5
2.8
0.5
7.6
0.5
6.7
0.5
5.8
0.5
3.0

0.55
5.3
0.55
2.8
0.55
7.6
0.55
6.7
0.55
5.7
0.55
3.0

0.6
5.3
0.6
2.8
0.6
7.6
0.6
6.7
0.6
5.6
0.6
3.0

0.65
5.3
0.65
2.8
0.65
7.6
0.65
6.6
0.65
5.5
0.65
3.0

0.7
5.2
0.7
2.8
0.7
7.6
0.7
6.5
0.7
5.4
0.7
3.0

0.75
5.0
0.75
2.8
0.75
7.5
0.75
6.3
0.75
5.1
0.75
3.0

0.8
4.8
0.8
2.7
0.8
7.1
0.8
6.1
0.8
4.8
0.8
2.9

0.85
4.3
0.85
2.5
0.85
6.5
0.85
5.6
0.85
4.3
0.85
2.7

0.9
3.7
0.9
2.2
0.9
5.5
0.9
4.7
0.9
3.6
0.9
2.4

0.95
2.7
0.95
1.8
0.95
3.8
0.95
3.4
0.95
2.6
0.95
1.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.2 F1234yf +
0.01 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +

0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.3
0
1.7
0
6.7
0
5.8
0
4.8
0
1.5

0.05
5.3
0.05
2.8
0.05
7.6
0.05
6.7
0.05
5.8
0.05
2.6

0.1
5.3
0.1
2.8
0.1
7.6
0.1
6.7
0.1
5.8
0.1
2.6

0.15
5.3
0.15
2.8
0.15
7.6
0.15
6.7
0.15
5.8
0.15
2.6

0.2
5.3
0.2
2.8
0.2
7.6
0.2
6.7
0.2
5.8
0.2
2.6

0.25
5.3
0.25
2.8
0.25
7.6
0.25
6.7
0.25
5.8
0.25
2.6

0.3
5.3
0.3
2.8
0.3
7.6
0.3
6.7
0.3
5.8
0.3
2.6

0.35
5.3
0.35
2.8
0.35
7.6
0.35
6.7
0.35
5.8
0.35
2.6

0.4
5.3
0.4
2.8
0.4
7.6
0.4
6.7
0.4
5.8
0.4
2.6

0.45
5.3
0.45
2.8
0.45
7.6
0.45
6.7
0.45
5.8
0.45
2.6

0.5
5.3
0.5
2.8
0.5
7.6
0.5
6.7
0.5
5.8
0.5
2.6

0.55
5.3
0.55
2.8
0.55
7.6
0.55
6.7
0.55
5.7
0.55
2.6

0.6
5.3
0.6
2.8
0.6
7.6
0.6
6.7
0.6
5.6
0.6
2.6

0.65
5.2
0.65
2.8
0.65
7.6
0.65
6.6
0.65
5.5
0.65
2.6

0.7
5.1
0.7
2.8
0.7
7.6
0.7
6.5
0.7
5.4
0.7
2.6

0.75
5.0
0.75
2.8
0.75
7.5
0.75
6.3
0.75
5.1
0.75
2.6

0.8
4.7
0.8
2.6
0.8
7.1
0.8
6.1
0.8
4.8
0.8
2.4

0.85
4.3
0.85
2.5
0.85
6.5
0.85
5.6
0.85
4.3
0.85
2.3

0.9
3.6
0.9
2.2
0.9
5.5
0.9
4.7
0.9
3.6
0.9
2.0

0.95
2.6
0.95
1.8
0.95
3.8
0.95
3.4
0.95
2.6
0.95
1.7

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.2 F1234yf +
0.01 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.96 F1234zeZ +
0.01 F1234zeZ +

0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
3.6
0
1.7
0
6.6
0
5.7
0
1.9
0
1.4

0.05
4.7
0.05
2.8
0.05
7.6
0.05
6.7
0.05
3.0
0.05
2.6

0.1
4.7
0.1
2.8
0.1
7.6
0.1
6.7
0.1
3.0
0.1
2.6

0.15
4.7
0.15
2.8
0.15
7.6
0.15
6.7
0.15
3.0
0.15
2.6

0.2
4.7
0.2
2.8
0.2
7.6
0.2
6.7
0.2
3.0
0.2
2.6

0.25
4.7
0.25
2.8
0.25
7.6
0.25
6.7
0.25
3.0
0.25
2.6

0.3
4.7
0.3
2.8
0.3
7.6
0.3
6.7
0.3
3.0
0.3
2.6

0.35
4.7
0.35
2.8
0.35
7.6
0.35
6.7
0.35
3.0
0.35
2.5

0.4
4.7
0.4
2.8
0.4
7.6
0.4
6.7
0.4
3.0
0.4
2.5

0.45
4.7
0.45
2.8
0.45
7.6
0.45
6.7
0.45
3.0
0.45
2.5

0.5
4.7
0.5
2.8
0.5
7.6
0.5
6.7
0.5
3.0
0.5
2.5

0.55
4.7
0.55
2.8
0.55
7.6
0.55
6.7
0.55
3.0
0.55
2.5

0.6
4.7
0.6
2.8
0.6
7.5
0.5
6.6
0.6
3.0
0.6
2.5

0.65
4.7
0.65
2.8
0.65
7.6
0.65
6.6
0.65
3.0
0.65
2.5

0.7
4.7
0.7
2.8
0.7
7.6
0.7
6.5
0.7
3.0
0.7
2.5

0.75
4.5
0.75
2.8
0.75
7.4
0.75
6.3
0.75
3.0
0.75
2.5

0.8
4.3
0.8
2.6
0.8
7.1
0.8
6.0
0.8
2.9
0.8
2.4

0.85
3.9
0.85
2.4
0.85
6.5
0.85
5.5
0.85
2.7
0.85
2.3

0.9
3.4
0.9
2.2
0.9
5.5
0.9
4.7
0.9
2.3
0.9
2.0

0.95
2.5
0.95
1.7
0.95
3.8
0.95
3.3
0.95
1.9
0.95
1.7

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.2 F245cb +
0.01 F245cb +
0.96 F245cd +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.2 F1243zf
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +

0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
3.8
0
1.7
0
4.6
0
5.8
0
4.8
0
1.9

0.05
4.9
0.05
2.8
0.05
5.8
0.05
6.7
0.05
5.8
0.05
3.0

0.1
4.9
0.1
2.8
0.1
5.8
0.1
6.7
0.1
5.8
0.1
3.0

0.15
4.9
0.15
2.8
0.15
5.8
0.15
6.7
0.15
5.8
0.15
3.0

0.2
4.9
0.2
2.8
0.2
5.8
0.2
6.7
0.2
5.8
0.2
3.0

0.25
4.9
0.25
2.8
0.25
5.8
0.25
6.7
0.25
5.8
0.25
3.0

0.3
4.9
0.3
2.8
0.3
5.8
0.3
6.7
0.3
5.8
0.3
3.0

0.35
4.9
0.35
2.8
0.35
5.8
0.35
6.7
0.35
5.8
0.35
3.0

0.4
4.9
0.4
2.8
0.4
5.8
0.4
6.7
0.4
5.8
0.4
3.0

0.45
4.9
0.45
2.8
0.45
5.8
0.45
6.7
0.45
5.8
0.45
3.0

0.5
4.9
0.5
2.8
0.5
5.8
0.5
6.7
0.5
5.7
0.5
3.0

0.55
4.9
0.55
2.8
0.55
5.8
0.55
6.7
0.55
5.7
0.55
3.0

0.6
4.9
0.6
2.8
0.6
5.8
0.6
6.6
0.6
5.6
0.6
3.0

0.65
4.9
0.65
2.8
0.65
5.8
0.65
6.6
0.65
5.5
0.65
3.0

0.7
4.9
0.7
2.8
0.7
5.8
0.7
6.5
0.7
5.4
0.7
3.0

0.75
4.8
0.75
2.8
0.75
5.8
0.75
6.3
0.75
5.1
0.75
3.0

0.8
4.6
0.8
2.6
0.8
5.8
0.8
6.0
0.8
4.8
0.0
2.9

0.85
4.2
0.85
2.4
0.85
5.8
0.85
5.6
0.85
4.3
0.85
2.7

0.9
3.6
0.9
2.2
0.9
5.0
0.9
4.7
0.9
3.6
0.9
2.4

0.95
2.6
0.95
1.8
0.95
3.5
0.95
3.4
0.95
2.6
0.95
1.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.2 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +

0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
3.8
0
1.7
0
4.6
0
5.8
0
4.8
0
1.5

0.05
4.9
0.05
2.8
0.05
5.8
0.05
6.7
0.05
5.8
0.05
2.6

0.1
4.9
0.1
2.8
0.1
5.8
0.1
6.7
0.1
5.8
0.1
2.6

0.15
4.9
0.15
2.8
0.15
5.8
0.15
6.7
0.15
5.8
0.15
2.6

0.2
4.9
0.2
2.8
0.2
5.8
0.2
6.7
0.2
5.8
0.2
2.6

0.25
4.9
0.25
2.8
0.25
5.8
0.25
6.7
0.25
5.8
0.25
2.6

0.3
4.9
0.3
2.8
0.3
5.8
0.3
6.7
0.3
5.8
0.3
2.6

0.35
4.9
0.35
2.8
0.35
5.8
0.35
6.7
0.35
5.8
0.35
2.6

0.4
4.9
0.4
2.8
0.4
5.8
0.4
6.7
0.4
5.8
0.4
2.6

0.45
4.9
0.45
2.8
0.45
5.8
0.45
6.7
0.45
5.8
0.45
2.6

0.5
4.9
0.5
2.8
0.5
5.8
0.5
6.7
0.5
5.7
0.5
2.6

0.55
4.9
0.55
2.8
0.55
5.8
0.55
6.7
0.55
5.7
0.55
2.6

0.6
4.9
0.6
2.8
0.6
5.8
0.6
6.6
0.6
5.6
0.6
2.6

0.65
4.9
0.65
2.8
0.65
5.8
0.65
6.6
0.65
5.5
0.65
2.5

0.7
4.9
0.7
2.8
0.7
5.8
0.7
6.5
0.7
5.4
0.7
2.5

0.75
4.7
0.75
2.8
0.75
5.8
0.75
6.3
0.75
5.1
0.75
2.5

0.8
4.5
0.8
2.6
0.8
5.8
0.8
6.0
0.8
4.8
0.8
2.4

0.85
4.1
0.85
2.4
0.85
5.8
0.85
5.6
0.85
4.3
0.85
2.3

0.9
3.5
0.9
2.2
0.9
5.0
0.9
4.7
0.9
3.6
0.9
2.0

0.95
2.6
0.95
1.7
0.95
3.5
0.95
3.3
0.95
2.6
0.95
1.7

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFC-245cb-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.2 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.96 F1234zeZ +
0.01 F1234zeZ +

0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
3.2
0
1.6
0
4.6
0
5.7
0
1.9
0
1.4

0.05
4.3
0.05
2.7
0.05
5.7
0.05
6.7
0.05
3.0
0.05
2.5

0.1
4.3
0.1
2.7
0.1
5.7
0.1
6.7
0.1
3.0
0.1
2.5

0.15
4.3
0.15
2.7
0.15
5.7
0.15
6.7
0.15
3.0
0.15
2.5

0.2
4.3
0.2
2.7
0.2
5.7
0.2
6.7
0.2
3.0
0.2
2.5

0.25
4.3
0.25
2.7
0.25
5.7
0.25
6.7
0.25
3.0
0.25
2.5

0.3
4.3
0.3
2.7
0.3
5.7
0.3
6.7
0.3
3.0
0.3
2.5

0.35
4.3
0.35
2.7
0.35
5.7
0.35
6.7
0.35
3.0
0.35
2.5

0.4
4.3
0.4
2.7
0.4
5.8
0.4
6.7
0.4
3.0
0.4
2.5

0.45
4.3
0.45
2.7
0.45
5.8
0.45
6.7
0.45
3.0
0.45
2.5

0.5
4.3
0.5
2.7
0.5
5.8
0.5
6.7
0.5
3.0
0.5
2.5

0.55
4.3
0.55
2.7
0.55
5.8
0.55
6.7
0.55
3.0
0.55
2.5

0.6
4.3
0.6
2.7
0.6
5.8
0.6
6.6
0.6
3.0
0.6
2.5

0.65
4.3
0.65
2.7
0.65
5.8
0.65
6.6
0.65
3.0
0.65
2.5

0.7
4.3
0.7
2.7
0.7
5.8
0.7
6.5
0.7
3.0
0.7
2.5

0.70
4.3
0.75
2.7
0.75
5.8
0.75
6.3
0.75
3.0
0.75
2.5

0.8
4.1
0.8
2.6
0.8
5.8
0.8
6.0
0.8
2.9
0.8
2.4

0.85
3.8
0.85
2.4
0.85
5.8
0.85
5.5
0.85
2.7
0.85
2.3

0.9
3.3
0.9
2.1
0.9
5.0
0.9
4.7
0.9
2.3
0.9
2.0

0.95
2.4
0.95
1.7
0.95
3.5
0.95
3.3
0.95
1.9
0.95
1.7

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1233xf +
0.96 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.2 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1233zdE
0.01 F1233zdE +
0.01 F1233zdE +
0.96 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +

0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +

0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
3.2
0
1.6
0
5.7
0
1.4
0
4.8
0
1.9

0.05
4.3
0.05
2.7
0.05
6.7
0.05
2.5
0.05
5.7
0.05
3.0

0.1
4.3
0.1
2.7
0.1
6.7
0.1
2.5
0.1
5.8
0.1
3.0

0.15
4.3
0.15
2.7
0.15
6.7
0.15
2.5
0.15
5.8
0.15
3.0

0.2
4.3
0.2
2.7
0.2
6.7
0.2
2.5
0.2
5.8
0.2
3.0

0.25
4.3
0.25
2.7
0.25
6.7
0.25
2.5
0.25
5.8
0.25
3.0

0.3
4.3
0.2
2.7
0.3
6.7
0.3
2.5
0.3
5.8
0.3
3.0

0.35
4.3
0.35
2.7
0.35
6.7
0.35
2.5
0.35
5.8
0.35
3.0

0.4
4.3
0.4
2.7
0.4
6.7
0.4
2.5
0.4
5.8
0.4
3.0

0.45
4.3
0.45
2.7
0.45
6.7
0.45
2.5
0.45
5.7
0.45
3.0

0.5
4.3
0.5
2.7
0.5
6.7
0.5
2.5
0.5
5.7
0.5
3.0

0.55
4.2
0.55
2.7
0.55
6.6
0.55
2.5
0.55
5.7
0.55
3.0

0.6
4.2
0.6
2.7
0.6
6.6
0.6
2.5
0.6
5.6
0.6
3.0

0.65
4.2
0.65
2.7
0.65
6.6
0.65
2.5
0.65
5.5
0.65
3.0

0.7
4.2
0.7
2.7
0.7
6.5
0.7
2.5
0.7
5.3
0.70
3.0

0.75
4.0
0.75
2.7
0.75
6.3
0.75
2.5
0.75
5.1
0.75
3.0

0.8
3.8
0.8
2.6
0.8
6.0
0.8
2.4
0.8
4.7
0.8
2.3

0.85
3.5
0.85
2.4
0.85
5.5
0.85
2.2
0.85
4.3
0.85
2.6

0.9
3.0
0.9
2.1
0.9
4.7
0.9
2.0
0.9
3.6
0.9
2.3

0.95
2.2
0.95
1.7
0.95
3.3
0.95
1.7
0.95
2.6
0.95
1.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.2 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +

0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.8
0
6.7
0
4.7
0
5.8
0
4.9
0
2.0

0.05
5.9
0.05
7.7
0.05
5.8
0.05
6.7
0.05
5.8
0.05
3.1

0.1
5.9
0.1
7.7
0.1
5.8
0.1
6.8
0.1
5.9
0.1
3.1

0.15
5.9
0.15
7.7
0.15
5.8
0.15
6.8
0.15
5.8
0.15
3.1

0.2
5.9
0.2
7.7
0.2
5.8
0.2
6.8
0.2
5.8
0.2
3.1

0.25
5.9
0.25
7.6
0.25
5.8
0.25
6.8
0.25
5.8
0.25
3.1

0.3
5.9
0.3
7.6
0.3
5.8
0.5
6.8
0.3
5.8
0.3
3.1

0.35
5.9
0.35
7.6
0.35
5.8
0.35
6.8
0.35
5.8
0.35
3.1

0.4
5.9
0.4
7.6
0.4
5.8
0.4
6.7
0.4
5.8
0.4
3.1

0.45
5.9
0.45
7.6
0.45
5.8
0.45
6.7
0.45
5.8
0.45
3.1

0.5
5.9
0.5
7.7
0.5
5.8
0.5
6.7
0.5
5.8
0.5
3.1

0.55
5.9
0.55
7.7
0.55
5.8
0.55
6.7
0.55
5.7
0.55
3.1

0.6
5.9
0.6
7.7
0.6
5.8
0.6
6.7
0.6
5.7
0.6
3.1

0.65
5.9
0.65
7.7
0.65
5.8
0.65
6.6
0.65
5.6
0.65
3.1

0.7
5.9
0.7
7.6
0.7
5.8
0.7
6.5
0.7
5.4
0.7
3.1

0.75
5.7
0.75
7.5
0.75
5.8
0.75
6.4
0.75
5.2
0.75
3.1

0.8
5.5
0.3
7.2
0.8
5.8
0.8
6.1
0.8
4.3
0.8
2.9

0.85
5.0
0.85
6.6
0.85
5.8
0.85
5.8
0.85
4.3
0.85
2.7

0.9
4.3
0.9
5.5
0.9
5.0
0.9
4.8
0.9
3.6
0.9
2.4

0.95
3.0
0.95
3.0
0.95
3.5
0.95
3.4
0.95
2.6
0.95
1.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.2 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +

0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.8
0
6.7
0
4.7
0
5.8
0
4.9
0
1.5

0.05
5.9
0.05
7.7
0.05
5.8
0.05
6.7
0.05
5.8
0.05
2.6

0.1
5.9
0.1
7.7
0.1
5.8
0.1
6.8
0.1
5.8
0.1
2.8

0.15
5.9
0.15
7.7
0.15
5.8
0.15
6.8
0.15
5.8
0.15
2.6

0.2
5.9
0.2
7.7
0.2
5.8
0.2
6.8
0.2
5.8
0.2
2.6

0.25
5.9
0.25
7.6
0.25
5.8
0.25
6.8
0.25
5.8
0.25
2.6

0.3
5.9
0.3
7.6
0.3
5.8
0.3
6.8
0.3
5.8
0.3
2.6

0.35
5.9
0.35
7.6
0.35
5.8
0.35
6.8
0.35
5.8
0.35
2.8

0.4
5.9
0.4
7.7
0.4
5.8
0.4
6.7
0.4
5.8
0.4
2.6

0.45
5.9
0.45
7.7
0.45
5.8
0.45
6.7
0.45
5.8
0.45
2.6

0.5
5.9
0.5
7.7
0.5
5.8
0.5
6.7
0.5
5.8
0.5
2.6

0.55
5.9
0.55
7.7
0.55
5.8
0.55
6.7
0.55
5.7
0.55
2.6

0.6
5.9
0.6
7.7
0.6
5.8
0.6
6.7
0.6
5.7
0.6
2.6

0.65
5.9
0.65
7.7
0.65
5.8
0.65
6.6
0.65
5.6
0.65
2.6

0.7
5.9
0.7
7.6
0.7
5.8
0.7
6.5
0.7
5.4
0.7
2.6

0.75
5.7
0.75
7.5
0.75
5.8
0.75
6.4
0.75
5.2
0.75
2.6

0.8
5.4
0.8
7.2
0.8
5.8
0.8
6.1
0.8
4.8
0.8
2.5

0.55
5.0
0.85
6.6
0.85
5.8
0.85
5.8
0.85
4.3
0.85
2.3

0.9
4.2
0.9
5.5
0.9
5.0
0.9
4.8
0.9
3.6
0.9
2.1

0.95
3.0
0.95
3.8
0.95
3.5
0.95
3.4
0.95
2.6
0.95
1.7

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFC-245th-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.2 F245cb +
0.01 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.2 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.96 F1234zeZ +
0.01 F1234zeZ +

0.2 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.01 F1233zdE
0.96 F1233zdE

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.2
0
6.7
0
4.6
0
5.8
0
1.9
0
1.5

0.05
5.3
0.05
7.6
0.05
5.8
0.05
6.7
0.05
3.0
0.05
2.6

0.1
5.3
0.1
7.6
0.1
5.8
0.1
6.7
0.1
3.0
0.1
2.6

0.15
5.3
0.15
7.6
0.15
5.8
0.15
6.7
0.15
3.0
0.15
2.6

0.2
5.3
0.2
7.6
0.2
5.8
0.2
6.7
0.2
3.0
0.2
2.6

0.25
5.3
0.25
7.6
0.25
5.8
0.25
6.7
0.25
3.0
0.25
2.6

0.3
5.3
0.3
7.6
0.3
5.8
0.3
6.7
0.3
3.0
0.3
2.6

0.35
5.3
0.35
7.6
0.35
5.8
0.35
6.7
0.35
3.0
0.35
2.6

0.4
5.3
0.4
7.6
0.4
5.8
0.4
6.7
0.4
3.0
0.4
2.6

0.45
5.3
0.45
7.6
0.45
5.8
0.45
6.7
0.45
3.0
0.45
2.6

0.5
5.3
0.5
7.6
0.5
5.8
0.5
6.7
0.5
3.0
0.5
2.6

0.55
5.3
0.55
7.6
0.55
5.8
0.55
6.7
0.55
3.0
0.55
2.6

0.6
5.3
0.6
7.6
0.6
5.8
0.6
6.7
0.6
3.0
0.6
2.6

0.65
5.3
0.65
7.6
0.65
5.8
0.65
6.6
0.65
3.0
0.65
2.6

0.7
5.3
0.7
7.6
0.7
5.8
0.7
6.5
0.7
3.0
0.7
2.6

0.75
5.2
0.75
7.5
0.75
5.8
0.75
6.4
0.75
3.0
0.75
2.6

0.8
5.0
0.8
7.2
0.8
5.8
0.8
6.1
0.8
2.9
0.8
2.5

0.85
4.6
0.85
6.6
0.85
5.8
0.85
5.6
0.85
2.7
0.85
2.3

0.9
3.9
0.9
5.5
0.9
5.0
0.9
4.7
0.9
2.4
0.9
2.0

0.95
2.9
0.95
3.8
0.95
3.5
0.95
3.4
0.95
1.9
0.95
1.7

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F1234yf +
0.96 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.2 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1233zdE
0.01 F1233zdE +
0.01 F1233zdE +
0.96 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +

0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +

0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.2
0
6.7
0
5.8
0
1.5
0
4.8
0
1.9

0.05
5.3
0.05
7.6
0.05
6.7
0.05
2.6
0.05
5.8
0.05
3.0

0.1
5.3
0.1
7.6
0.1
6.7
0.1
2.6
0.1
5.8
0.1
3.0

0.15
5.3
0.15
7.6
0.15
8.7
0.15
2.6
0.15
5.8
0.15
3.0

0.2
5.3
0.2
7.6
0.2
6.7
0.2
2.6
0.2
5.8
0.2
3.0

0.25
5.3
0.25
7.6
0.25
6.7
0.25
2.6
0.25
5.8
0.25
3.0

0.3
5.3
0.3
7.6
0.3
6.7
0.3
2.6
0.3
5.8
0.3
3.0

0.35
5.3
0.35
7.6
0.35
6.7
0.35
2.6
0.35
5.8
0.35
3.0

0.4
5.3
0.4
7.6
0.4
6.7
0.4
2.6
0.4
5.8
0.4
3.0

0.45
5.3
0.45
7.6
0.45
6.7
0.45
2.6
0.45
5.8
0.45
3.0

0.5
5.3
0.5
7.6
0.5
6.7
0.5
2.6
0.5
5.8
0.5
3.0

0.55
5.2
0.55
7.6
0.55
6.7
0.55
2.6
0.55
5.7
0.55
3.0

0.6
5.2
0.6
7.6
0.6
6.7
0.6
2.6
0.6
5.6
0.6
3.0

0.65
5.2
0.65
7.6
0.65
6.6
0.65
2.6
0.65
5.5
0.65
3.0

0.7
5.2
0.7
7.6
0.7
6.5
0.7
2.6
0.7
5.4
0.7
3.0

0.75
5.0
0.75
7.5
0.75
6.3
0.75
2.6
0.75
5.1
0.75
3.0

0.8
4.7
0.8
7.1
0.8
6.1
0.8
2.5
0.8
4.8
0.8
2.9

0.85
4.3
0.80
6.5
0.85
5.6
0.85
2.3
0.85
4.3
0.85
2.7

0.9
3.7
0.9
5.5
0.9
4.7
0.9
2.0
0.9
3.6
0.9
2.4

0.95
2.7
0.95
3.8
0.95
3.4
0.95
1.7
0.95
2.6
0.95
1.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HCFO-1233zdE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics

0.2 F245cb +
0.96 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.2 F1243zf +
0.01 F1243zf +
0.96 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.2 F1233zdE
0.01 F1233zdE +
0.01 F1233zdE +
0.96 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +

0.2 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.96 F1234zeE +
0.01 F1234zeE +

0.2 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.96 F1234zeZ

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
3.8
0
4.6
0
5.8
0
1.5
0
4.8
0
1.9

0.05
4.9
0.05
5.8
0.05
6.7
0.05
2.6
0.05
5.8
0.05
3.0

0.1
4.9
0.1
5.8
0.1
6.7
0.1
2.6
0.1
5.8
0.1
3.0

0.15
4.9
0.15
5.8
0.15
6.7
0.15
2.6
0.15
5.8
0.15
3.0

0.2
4.9
0.2
5.8
0.2
6.7
0.2
2.6
0.2
5.8
0.2
3.0

0.25
4.9
0.25
5.8
0.25
6.7
0.25
2.6
0.25
5.8
0.25
3.0

0.3
4.9
0.3
5.8
0.3
6.7
0.3
2.6
0.3
5.8
0.3
3.0

0.35
4.9
0.35
5.8
0.35
6.7
0.35
2.6
0.35
5.8
0.35
3.0

0.4
4.9
0.4
5.8
0.4
6.7
0.4
2.6
0.4
5.8
0.4
3.0

0.45
4.9
0.45
5.8
0.45
6.7
0.45
2.6
0.45
5.8
0.45
3.0

0.5
4.9
0.5
5.8
0.5
6.7
0.5
2.6
0.5
5.7
0.5
3.0

0.55
4.9
0.55
5.8
0.55
6.7
0.55
2.6
0.55
5.7
0.55
3.0

0.6
4.9
0.6
5.8
0.6
6.6
0.6
2.6
0.6
5.6
0.6
3.0

0.65
4.9
0.65
5.8
0.65
6.6
0.65
2.6
0.65
5.5
0.65
3.0

0.7
4.9
0.7
5.8
0.7
6.5
0.7
2.6
0.7
5.4
0.7
3.0

0.75
4.8
0.75
5.8
0.75
6.3
0.75
2.6
0.75
5.1
0.75
3.0

0.8
4.5
0.8
5.8
0.8
6.0
0.8
2.4
0.8
4.8
0.8
2.9

0.85
4.2
0.85
5.0
0.85
5.6
0.85
2.3
0.85
4.3
0.85
2.7

0.9
3.5
0.9
5.0
0.9
4.7
0.9
2.0
0.9
3.6
0.9
2.4

0.95
2.6
0.95
3.5
0.95
3.4
0.95
1.7
0.95
2.6
0.95
1.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

EXAMPLE 11: TEMPERATURE AND PRESSURE RANGE OF SYSTEMS WITH 6 COMPOUNDS

Boiling point range

Temperature
Pressure

System with 6 compounds
° C.
bar abs

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.0 to ~11.6

HFO-1234zeE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.0 to ~11.6

HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~0.9 to ~11.6

HCFO-1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~1.0 to ~11.6

1234zeE-HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~0.9 to ~11.6

1234zeE-HCFO-1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFO-
0 to 40
~0.9 to ~11.6

1234zeZ-HCFO-1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.0 to ~10.3

1234zeE-HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~0.9 to ~10.3

1234zeE-HCFO-1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-
0 to 40
~1.0 to ~10.3

1234zeZ-HCFO-1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234zeE-HFO-
0 to 40
~0.9 to ~10.3

1234zeZ-HCFO-1233zdE-HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-
0 to 40
~1.2 to ~11.6

HFO-1234zeZ-HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-
0 to 40
~1.0 to ~11.7

HCFO-1233zdE-HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-
0 to 40
~0.9 to ~11.6

HCFO-1233zdE-HFO-1243zf

HF-HFO-1234yf-HFO-1234zeE-HFO-
0 to 40
~0.9 to ~11.6

1234zeZ-HCFO-1233zdE-HFO-1243zf

HF-HFC-245cb-HFO-1234zeE-HFO-
0 to 40
~0.9 to ~10.3

1234zeZ-HCFO-1233zdE-HFO-1243zf

EXAMPLE 12: DECANTATION RANGE OF SYSTEMS WITH 6 COMPOUNDS

Decantation ranges

Mass percentage of HF

Isotherm
Isotherm
Isotherm

System with 6 compounds
0° C.
25° C.
40° C.

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
10-65
*

HFO-1234zeE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
10-70
15-50

HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
5-70
15-55

HCFO-1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFO-
5-70
10-65
*

1234zeE-HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFO-
5-70
10-75
*

1234zeE-HCFO-1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFO-
5-75
5-70
10-55

1234zeZ-HCFO-1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-
5-75
10-70
15-45

1234zeE-HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-
5-75
5-70
15-50

1234zeE-HCFO-1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HFO-
5-75
5-70
10-65

1234zeZ-HCFO-1233zdE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234zeE-HFO-
5-75
5-65
10-55

1234zeZ-HCFO-1233zdE-HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-
5-75
10-65
*

HFO-1234zeZ-HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HFO-1234zeE-
5-75
10-65
*

HCFO-1233zdE-HFO-1243zf

HF-HFO-1234yf-HFC-245cb-HFO-1234zeZ-
5-75
10-70
15-55

HCFO-1233zdE-HFO-1243zf

HF-HFO-1234yf-HFO-1234zeE-HFO-
5-70
10-65
*

1234zeZ-HCFO-1233zdE-HFO-1243zf

HF-HFC-245cb-HFO-1234zeE-HFO-
5-75
5-70
15-50

1234zeZ-HCFO-1233zdE-HFO-1243zf

EXAMPLE 13: SYSTEMS WITH SEVEN COMPOUNDS, ISOTHERM AT 25° C.

HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics
Organics

0.15 F1233xf +
0.95 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

0.17 F245cb +
0.01 F245cb +
0.95 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.17 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.95 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +

0.17 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.95 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +

0.17 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.95 F1234zeZ +

0.17 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.95 F1243zf
0.01 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
3.5
0
1.7
0
4.5
0
1.5
0
4.8
0
5.7
0
1.9

0.05
4.6
0.05
2.8
0.05
5.7
0.05
2.6
0.05
5.7
0.05
6.7
0.05
3.0

0.1
4.6
0.1
2.8
0.1
5.7
0.1
2.6
0.1
5.8
0.1
6.7
0.1
3.0

0.15
4.6
0.15
2.8
0.15
5.7
0.15
2.6
0.15
5.8
0.15
6.7
0.15
3.0

0.2
4.6
0.2
2.8
0.2
5.7
0.2
2.6
0.2
5.8
0.2
6.7
0.2
3.0

0.25
4.6
0.25
2.8
0.25
5.8
0.25
2.6
0.25
5.8
0.25
6.7
0.25
3.0

0.3
4.6
0.3
2.8
0.3
5.8
0.3
2.6
0.3
5.8
0.3
6.7
0.3
3.0

0.35
4.6
0.35
2.8
0.35
5.8
0.35
2.6
0.35
5.8
0.35
6.7
0.35
3.0

0.4
4.6
0.4
2.8
0.4
5.8
0.4
2.6
0.4
5.8
0.4
6.7
0.4
3.0

0.45
4.6
0.45
2.8
0.45
5.8
0.45
2.6
0.45
5.7
0.45
6.7
0.45
3.0

0.5
4.6
0.5
2.8
0.5
5.8
0.5
2.6
0.5
5.7
0.5
6.7
0.5
3.0

0.55
4.6
0.55
2.8
0.55
5.8
0.55
2.6
0.55
5.7
0.55
6.6
0.55
3.0

0.5
4.6
0.6
2.8
0.6
5.8
0.6
2.6
0.6
5.6
0.6
6.6
0.6
3.0

0.65
4.6
0.55
2.8
0.65
5.8
0.65
2.6
0.65
5.5
0.65
6.6
0.65
3.0

0.7
4.6
0.7
2.8
0.7
5.8
0.7
2.6
0.7
5.3
0.7
6.6
0.7
3.0

0.75
4.5
0.75
2.8
0.75
5.8
0.75
2.6
0.75
5.1
0.75
6.2
0.75
3.0

0.8
4.2
0.8
2.6
0.8
5.8
0.8
2.4
0.8
4.8
0.8
6.0
0.8
2.9

0.85
3.9
0.85
2.4
0.85
5.8
0.85
2.3
0.85
4.3
0.85
5.5
0.85
2.7

0.9
3.3
0.9
2.2
0.9
4.9
0.9
2.0
0.9
3.6
0.9
4.7
0.9
2.4

0.95
2.5
0.95
1.8
0.95
3.5
0.95
1.7
0.95
2.6
0.95
3.3
0.95
1.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics
Organics

0.15 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.95 F1233xf +

0.17 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.17 F245cb +
0.01 F245cb +
0.95 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.17 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.95 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +

0.17 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.95 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +

0.17 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.95 F1243zf
0.01 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.4
0
6.6
0
4.6
0
1.5
0
4.8
0
5.8
0
1.7

0.05
5.4
0.05
7.6
0.05
5.8
0.05
2.6
0.05
5.8
0.05
6.7
0.05
2.8

0.1
5.4
0.1
7.6
0.1
5.8
0.1
2.6
0.1
5.8
0.1
6.7
0.1
2.8

0.15
5.4
0.15
7.6
0.15
5.8
0.15
2.6
0.15
5.8
0.15
6.7
0.15
2.8

0.2
5.4
0.2
7.6
0.2
5.8
0.2
2.6
0.2
5.8
0.2
6.7
0.2
2.8

0.25
5.4
0.25
7.6
0.25
5.8
0.25
2.6
0.25
5.8
0.25
6.7
0.25
2.8

0.3
5.4
0.3
7.6
0.3
5.8
0.3
2.6
0.3
5.8
0.3
6.7
0.3
2.8

0.35
5.4
0.35
7.6
0.35
5.8
0.35
2.6
0.35
5.8
0.35
6.7
0.35
2.8

0.4
5.4
0.4
7.6
0.4
5.8
0.4
2.6
0.4
5.8
0.4
6.7
0.4
2.8

0.45
5.4
0.45
7.6
0.45
5.8
0.45
2.6
0.45
5.8
0.45
6.7
0.45
2.8

0.5
5.4
0.5
7.6
0.5
5.8
0.5
2.6
0.5
5.8
0.5
6.7
0.5
2.8

0.55
5.4
0.55
7.6
0.55
5.8
0.55
2.6
0.55
5.7
0.55
6.7
0.55
2.8

0.6
5.4
0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.6
0.6
6.7
0.6
2.8

0.65
5.4
0.65
7.6
0.65
5.8
0.65
2.6
0.65
5.5
0.65
6.6
0.65
2.8

0.7
5.4
0.7
7.6
0.7
5.8
0.7
2.6
0.7
5.4
0.7
6.5
0.7
2.8

0.75
5.3
0.75
7.4
0.75
5.8
0.75
2.6
0.75
5.1
0.75
6.3
0.75
2.8

0.8
5.0
0.8
7.1
0.8
5.8
0.8
2.5
0.8
4.8
0.8
6.1
0.8
2.7

0.85
4.6
0.85
6.5
0.85
5.8
0.85
2.3
0.85
4.3
0.85
5.6
0.85
2.5

0.9
3.9
0.9
5.5
0.9
5.0
0.9
2.1
0.9
3.6
0.9
4.7
0.9
2.2

0.95
2.8
0.95
3.8
0.95
3.5
0.95
1.7
0.95
2.6
0.95
3.4
0.95
1.8

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics
Organics

0.15 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.95 F1233xf +

0.17 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.17 F245cb +
0.01 F245cb +
0.95 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.17 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.95 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.17 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.95 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +

0.17 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.95 F1234zeZ
0.01 F1234zeZ

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
3.8
0
6.6
0
4.6
0
5.7
0
1.5
0
1.9
0
1.7

0.05
4.9
0.05
7.6
0.05
5.8
0.05
6.7
0.05
2.6
0.05
3.0
0.05
2.8

0.1
4.9
0.1
7.6
0.1
5.8
0.1
6.7
0.1
2.6
0.1
3.0
0.1
2.8

0.15
4.9
0.15
7.6
0.15
5.8
0.15
6.7
0.15
2.6
0.15
3.0
0.15
2.8

0.2
4.9
0.2
7.6
0.2
5.8
0.2
6.7
0.2
2.6
0.2
3.0
0.2
2.8

0.25
4.9
0.25
7.6
0.25
5.8
0.25
6.7
0.25
2.6
0.25
3.0
0.25
2.8

0.3
4.9
0.3
7.6
0.3
5.8
0.3
6.7
0.3
2.6
0.3
3.0
0.3
2.8

0.35
4.9
0.35
7.6
0.35
5.8
0.35
6.7
0.35
2.6
0.35
3.0
0.35
2.8

0.4
4.9
0.4
7.6
0.4
5.8
0.4
6.7
0.4
2.6
0.4
3.0
0.4
2.8

0.45
4.9
0.45
7.6
0.45
5.8
0.45
6.7
0.45
2.6
0.45
3.0
0.45
2.8

0.5
4.9
0.5
7.6
0.5
5.8
0.5
6.7
0.5
2.6
0.5
3.0
0.5
2.8

0.55
4.9
0.55
7.6
0.55
5.3
0.55
6.7
0.55
2.6
0.55
3.0
0.55
2.8

0.6
4.9
0.6
7.6
0.6
5.8
0.6
6.6
0.6
2.6
0.6
3.0
0.6
2.8

0.65
4.9
0.65
7.6
0.65
5.8
0.65
6.6
0.65
2.6
0.65
3.0
0.65
2.8

0.7
4.9
0.7
7.6
0.7
5.8
0.7
6.5
0.7
2.6
0.7
3.0
0.7
2.8

0.75
4.9
0.75
7.4
0.75
5.8
0.75
6.3
0.75
2.6
0.75
3.0
0.75
2.8

0.8
4.7
0.8
7.1
0.8
5.8
0.8
6.0
0.8
2.5
0.8
2.9
0.8
2.7

0.85
4.3
0.85
6.5
0.85
5.8
0.85
5.5
0.85
2.3
0.85
2.7
0.85
2.5

0.9
3.7
0.9
5.5
0.9
5.0
0.9
4.7
0.9
2.0
0.9
2.4
0.9
2.2

0.95
2.7
0.95
3.8
0.95
3.5
0.95
3.3
0.95
1.7
0.95
1.9
0.95
1.8

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics
Organics

0.15 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.95 F1233xf +

0.17 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.17 F245cb +
0.01 F243cb +
0.95 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.17 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.95 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.17 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.95 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +

0.17 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.95 F1234zeZ
0.01 F1234zeZ

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.4
0
6.5
0
4.6
0
5.8
0
4.8
0
2.0
0
1.7

0.05
5.5
0.05
7.6
0.05
5.8
0.05
6.7
0.05
5.8
0.05
3.1
0.05
2.8

0.1
5.5
0.1
7.6
0.1
5.8
0.1
6.7
0.1
5.8
0.1
3.1
0.1
2.8

0.15
5.5
0.15
7.6
0.15
5.8
0.15
6.7
0.15
5.8
0.15
3.1
0.15
2.8

0.2
5.5
0.2
7.6
0.2
5.8
0.2
6.7
0.2
5.8
0.2
3.1
0.2
2.8

0.25
5.5
0.25
7.6
0.25
5.8
0.25
6.7
0.25
5.8
0.25
3.1
0.25
2.8

0.3
5.5
0.3
7.6
0.3
5.8
0.3
6.7
0.3
5.8
0.3
3.1
0.3
2.8

0.35
5.5
0.35
7.6
0.35
5.8
0.35
6.7
0.35
5.8
0.35
3.1
0.35
2.8

0.4
5.5
0.4
7.6
0.4
5.8
0.4
6.7
0.4
5.8
0.4
3.1
0.4
2.8

0.45
5.5
0.45
7.6
0.45
5.8
0.45
6.7
0.45
5.8
0.45
3.1
0.45
2.8

0.5
5.5
0.5
7.6
0.5
5.8
0.5
6.7
0.5
5.8
0.5
3.1
0.5
2.8

0.55
5.5
0.55
7.6
0.55
5.8
0.55
6.7
0.55
5.7
0.55
3.1
0.55
2.8

0.6
5.5
0.6
7.6
0.6
5.8
0.6
6.7
0.6
5.6
0.6
3.1
0.6
2.8

0.65
5.5
0.65
7.6
0.55
5.8
0.65
6.6
0.65
5.5
0.65
3.1
0.65
2.8

0.7
5.5
0.7
7.6
0.7
5.8
0.7
6.5
0.7
5.4
0.7
3.1
0.7
2.8

0.75
5.3
0.75
7.4
0.75
5.8
0.75
6.3
0.75
5.1
0.75
3.1
0.75
2.8

0.8
5.1
0.8
7.1
0.8
5.8
0.8
6.1
0.8
4.8
0.8
2.9
0.8
2.7

0.85
4.6
0.85
6.5
0.85
5.8
0.85
5.6
0.85
4.3
0.85
2.7
0.85
2.5

0.9
3.9
0.9
5.5
0.9
5.0
0.9
4.7
0.9
3.6
0.9
2.4
0.9
2.2

0.95
2.8
0.95
3.8
0.95
3.5
0.95
3.4
0.95
2.6
0.95
1.9
0.95
1.8

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics
Organics

0.15 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.95 F1233xf +

0.17 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.17 F1233zdE +
0.01 F1233zdE +
0.95 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +

0.17 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.95 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.17 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.95 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +

0.17 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.01 F1234zeZ
0.95 F1234zeZ
0.01 F1234zeZ

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
3.9
0
6.6
0
1.9
0
5.7
0
4.8
0
1.9
0
1.7

0.05
5.0
0.05
7.6
0.05
2.6
0.05
6.7
0.05
5.8
0.05
3.0
0.05
2.8

0.1
4.9
0.1
7.6
0.1
2.6
0.1
6.7
0.1
5.8
0.1
3.0
0.1
2.8

0.15
4.9
0.15
7.6
0.15
2.6
0.15
6.7
0.15
5.8
0.15
3.0
0.15
2.8

0.2
4.9
0.2
7.6
0.2
2.6
0.2
6.7
0.2
5.8
0.2
3.0
0.3
2.8

0.25
4.9
0.25
7.6
0.25
2.6
0.25
6.7
0.25
5.8
0.25
3.0
0.25
2.8

0.3
4.9
0.3
7.6
0.3
2.6
0.3
6.7
0.3
5.8
0.3
3.0
0.3
2.8

0.35
4.9
0.35
7.6
0.35
2.6
0.35
6.7
0.35
5.8
0.35
3.0
0.35
2.8

0.4
4.9
0.4
7.6
0.4
2.6
0.4
6.7
0.4
5.8
0.4
3.0
0.4
2.8

0.45
4.9
0.45
7.6
0.45
2.6
0.45
6.7
0.45
5.8
0.45
3.0
0.45
2.8

0.5
4.9
0.5
7.6
0.5
2.6
0.5
6.7
0.5
5.7
0.5
3.0
0.5
2.8

0.55
4.9
0.55
7.6
0.55
2.6
0.55
6.7
0.55
5.7
0.55
3.0
0.55
2.8

0.6
4.9
0.6
7.6
0.6
2.6
0.6
6.6
0.6
5.6
0.6
3.0
0.5
2.8

0.65
4.9
0.65
7.6
0.65
2.6
0.65
6.5
0.65
5.5
0.65
3.0
0.65
2.8

0.7
4.8
0.7
7.6
0.7
2.6
0.7
6.5
0.7
5.3
0.7
3.0
0.7
2.8

0.75
4.7
0.75
7.4
0.75
2.6
0.75
6.3
0.75
5.1
0.75
3.0
0.75
2.8

0.8
4.4
0.8
7.1
0.8
2.5
0.8
6.0
0.8
4.8
0.8
2.9
0.8
2.6

0.85
4.0
0.85
6.5
0.85
2.3
0.85
5.5
0.85
4.3
0.85
2.7
0.85
2.5

0.9
3.4
0.9
5.5
0.9
2.0
0.9
4.7
0.9
3.6
0.9
2.4
0.9
2.2

0.95
2.5
0.95
3.8
0.95
1.7
0.95
3.3
0.95
2.6
0.95
1.9
0.95
1.8

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics
Organics

0.15 F1234yf +
0.95 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

0.17 F245cb +
0.01 F245cb +
0.95 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

0.17 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.95 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +

0.17 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.95 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +

0.17 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.95 F1234zeZ +

0.17 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.95 F1243zf
0.01 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
4.3
0
6.6
0
4.6
0
1.5
0
4.8
0
5.8
0
2.0

0.05
5.3
0.05
7.6
0.05
5.8
0.05
2.6
0.05
5.8
0.05
6.7
0.05
3.1

0.1
5.3
0.1
7.6
0.1
5.8
0.1
2.6
0.1
5.8
0.1
6.7
0.1
3.1

0.15
5.3
0.15
7.6
0.15
5.8
0.15
2.6
0.15
5.8
0.15
6.7
0.15
3.1

0.2
5.3
0.2
7.6
0.2
5.8
0.2
2.6
0.2
5.8
0.2
6.7
0.2
3.1

0.25
5.3
0.25
7.6
0.25
5.8
0.25
2.6
0.25
5.8
0.25
6.7
0.25
3.1

0.3
5.3
0.3
7.6
0.3
5.8
0.3
2.6
0.3
5.8
0.3
6.7
0.3
3.1

0.35
5.3
0.35
7.6
0.35
5.8
0.35
2.6
0.35
5.8
0.35
6.7
0.35
3.1

0.4
5.3
0.4
7.6
0.4
5.8
0.4
2.6
0.4
5.8
0.4
6.7
0.4
3.1

0.45
5.3
0.45
7.6
0.45
5.8
0.45
2.6
0.45
5.8
0.45
6.7
0.45
3.1

0.5
5.3
0.5
7.6
0.5
5.8
0.5
2.6
0.5
5.8
0.5
6.7
0.5
3.1

0.55
5.3
0.55
7.6
0.55
5.8
0.55
2.6
0.55
5.7
0.55
6.7
0.55
3.1

0.6
5.3
0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.6
0.6
6.7
0.5
3.1

0.65
5.3
0.65
7.6
0.65
5.8
0.65
2.6
0.65
5.5
0.65
6.6
0.65
3.1

0.7
5.3
0.7
7.6
0.7
5.8
0.7
2.6
0.7
5.4
0.7
6.5
0.7
3.1

0.75
5.2
0.75
7.4
0.75
5.8
0.75
2.6
0.75
5.1
0.75
6.3
0.75
3.1

0.8
4.9
0.8
7.1
0.8
5.8
0.8
2.5
0.8
4.3
0.8
6.1
0.8
2.9

0.85
4.5
0.85
6.5
0.85
5.8
0.85
2.3
0.85
4.3
0.85
5.6
0.85
2.7

0.9
3.9
0.9
5.5
0.9
5.0
0.9
2.1
0.9
3.6
0.9
4.7
0.9
2.4

0.95
2.8
0.95
3.8
0.95
3.5
0.95
1.7
0.95
2.6
0.95
3.4
0.95
1.9

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

HF-HFF-1243zf-HCFC-244bb-HFC-245fa-Trifluoropropyne-HFO-1225yeZ-HFO-1225zc

Organics
Organics
Organics
Organics
Organics
Organics
Organics

0.15 F1243zf +
0.95 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

0.17 F244bb +
0.01 F244bb +
0.95 F244bb +
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +

0.17 F245fa +
0.01 F245fa +
0.01 F245fa +
0.95 F245fa +
0.01 F245fa +
0.01 F245fa +
0.01 F245fa +

0.17 TFP +
0.01 TFP +
0.01 TFP +
0.01 TFP +
0.95 TFP +
0.01 TFP +
0.01 TFP +

0.17 F1225yeZ +
0.01 F1225yeZ +
0.01 F1225yeZ +
0.01 F1225yeZ +
0.01 F1225yeZ +
0.95 F1225yeZ +
0.01 F1225yeZ +

0.17 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.01 F1225zc
0.95 F1225zc

TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL
TOTAL

MASS-
PRES-
PRES-
PRES-
PRES-
PRES-
PRES-
PRES-

FRAC
SURE
SURE
SURE
SURE
SURE
SURE
SURE

HF
bar
bar
bar
bar
bar
bar
bar

0
5.5
5.8
1.0
1.8
11.3
5.2
5.3

0.05
6.5
6.8
2.1
2.9
12.1
6.2
6.3

0.1
6.5
6.8
2.1
2.9
12.0
6.2
6.3

0.15
6.4
6.8
2.1
2.9
11.9
6.2
6.3

0.2
6.4
6.8
2.1
2.9
11.8
6.2
6.3

0.25
6.4
6.8
2.1
2.9
11.7
6.2
6.3

0.3
6.4
6.8
2.1
2.9
11.6
6.2
6.3

0.35
6.4
6.8
2.1
2.9
11.5
6.2
6.3

0.4
6.4
6.8
2.1
2.9
11.5
6.2
6.3

0.45
6.4
6.8
2.1
2.9
11.5
6.2
6.3

0.5
6.3
6.7
2.1
2.9
11.5
6.2
6.3

0.55
6.3
6.7
2.1
2.9
11.5
6.2
6.2

0.6
6.3
6.7
2.1
2.9
11.6
6.2
6.1

0.65
6.2
6.6
2.1
2.9
11.6
6.2
6.0

0.7
6.2
6.6
2.1
2.9
11.7
6.1
5.9

0.75
6.0
6.4
2.0
2.8
11.6
5.9
5.6

0.8
5.7
6.1
2.0
2.8
11.3
5.6
5.2

0.85
5.2
5.6
2.0
2.6
10.5
5.1
4.7

0.9
4.4
4.8
1.9
2.3
8.9
4.2
3.9

0.95
3.1
3.4
1.6
1.6
6.0
3.0
2.7

1
1.2
1.2
1.2
1.2
1.2
1.2
1.2

EXAMPLE 14: TEMPERATURE AND PRESSURE RANGE OF SYSTEM WITH 7 COMPOUNDS

Boiling point range

Temperature
Pressure

System with 7 compounds
° C.
bar abs

HC-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.0 to ~11.6

HCFO-1233zdE-HFO-1234zeE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~0.9 to ~11.5

HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
0 to 40
~1.1 to ~11.6

HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HCFO-
0 to 40
~0.9 to ~11.5

1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-

1243zf

HF-HCFO-1233xf-HFC-245cb-HCFO-
0 to 40
~0.9 to ~10.3

1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-

1243zf

HF-HFO-1234yf-HFC-245b-HCFO-1233zdE-
0 to 40
~1.0 to ~11.6

HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

HF-HFF-1243zf-HCFC-244bb-HFC-245fa-
0 to 40
~0.7 to ~17.5

Trifluoropropyne-HFO-1225yeZ-HFO-1225zc

EXAMPLE 15: DECANTATION RANGE OF SYSTEMS WITH 7 COMPOUNDS

Decantation ranges

Mass percentage of HF

Temperature

System with 7 compounds
0° C.
25° C.
40° C.

HC-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
10-65
20

HCFO-1233zdE-HFO-1234zeE-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-70
5-70
10-60

HCFO-1233zdE-HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75
10-65
*

HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFO-1234yf-HCFO-1233zdE-
5-75
10-65
15-45

HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

HF-HCFO-1233xf-HFC-245cb-HCFO-1233zdE-
5-75
5-70
10-55

HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

HF-HFO-1234yf-HFC-245b-HCFO-1233zdE-
5-75
10-65
*

HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

HF-HFF-1243zf-HCFC-244bb-HFC-245fa-
5-75
10-70
*

Trifluoropropyne-HFO-1225yeZ-HFO-1225zc

EXAMPLE 16: SYSTEMS WITH 8 COMPOUNDS

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFO-1243zf

Organics
Organics
Organics
Organics
Organics
Organics
Organics

0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.01 F1233xf +
0.16 F1233xf +

0.94 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.14 F1234yf +

0.01 F245cb +
0.94 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.14 F245cb +

0.01 F1233zdE +
0.01 F1233zdE +
0.94 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.14 F1233zdE +

0.01 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.94 F1234zeE +
0.01 F1234zeE +
0.01 F1234zeE +
0.14 F1234zeE +

0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.94 F1234zeZ +
0.01 F1234zeZ +
0.14 F1234zeZ +

0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.01 F1243zf
0.94 F1243zf
0.14 F1243zf

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

TOTAL

MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-
MASS-
PRES-

FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE
FRAC
SURE

HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar
HF
bar

0
6
0
4.6
0
1.5
0
4.8
0
2.0
0
5.7
0
3.9

0.05
7.6
0.05
5.8
0.05
2.6
0.05
5.8
0.05
3.1
0.05
6.7
0.05
5.0

0.1
7.6
0.1
5.8
0.1
2.6
0.1
5.8
0.1
3.1
0.1
6.7
0.1
5.0

0.15
7.6
0.15
5.8
0.15
2.6
0.15
5.8
0.15
3.1
0.15
6.7
0.15
5.0

0.2
7.6
0.2
5.8
0.2
2.6
0.2
5.8
0.2
3.1
0.2
6.7
0.2
5.0

0.25
7.6
0.25
5.8
0.25
2.6
0.25
5.8
0.25
3.1
0.25
6.7
0.25
5.0

0.3
7.6
0.3
5.8
0.3
2.6
0.3
5.8
0.3
3.1
0.3
6.7
0.3
5.0

0.35
7.6
0.35
5.8
0.35
2.6
0.35
5.8
0.35
3.1
0.35
6.7
0.35
5.0

0.4
7.6
0.4
5.8
0.4
2.6
0.4
5.8
0.4
3.1
0.4
6.7
0.4
5.0

0.45
7.6
0.45
5.8
0.45
2.6
0.45
5.8
0.45
3.1
0.45
6.7
0.45
5.0

0.5
7.6
0.5
5.8
0.5
2.6
0.5
5.7
0.5
3.1
0.5
6.7
0.5
5.0

0.55
7.6
0.55
5.8
0.55
2.6
0.55
5.7
0.55
3.1
0.55
6.7
0.55
5.0

0.6
7.6
0.6
5.8
0.6
2.6
0.6
5.6
0.6
3.1
0.6
6.6
0.6
5.0

0.65
7.6
0.65
5.8
0.65
2.6
0.65
5.5
0.65
3.1
0.65
6.6
0.65
5.0

0.7
7.5
0.7
5.8
0.7
2.6
0.7
5.4
0.7
3.1
0.7
6.5
0.7
5.0

0.75
7.4
0.75
5.8
0.75
2.6
0.75
5.1
0.75
3.1
0.75
6.3
0.75
4.9

0.8
7.1
0.8
5.8
0.8
2.5
0.8
4.8
0.8
2.9
0.8
6.0
0.8
4.6

0.85
6.5
0.85
5.8
0.85
2.3
0.85
4.3
0.85
2.7
0.85
5.5
0.85
4.2

0.9
5.5
0.9
5.0
0.9
2.1
0.9
3.6
0.9
2.4
0.9
4.7
0.9
3.9

0.95
3.0
0.95
3.5
0.95
1.7
0.95
2.6
0.95
1.9
0.95
3.3
0.95
2.6

1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2
1
1.2

EXAMPLE 17: TEMPERATURE AND PRESSURE RANGE OF SYSTEM WITH 8 COMPOUNDS

Boiling point range

Temperature
Pressure

System with 8 compounds
° C.
bar abs

HF-HCFO-1233xf-HFO-1234yf-HFC-
0 to 40
~1.0 to ~11.5

245cb-HCFO-1233zdE-HFO-1234zeE-

HFO-1234zeZ-HFO-1243zf

EXAMPLE 18: DECANTATION RANGES OF SYSTEM WITH 8 COMPOUNDS

Decantation ranges

Mass percentage of HF

Temperature

System with 8 compounds
0° C.
25° C.
40° C.

HF-HCFO-1233xf-HFO-1234yf-HFC-245cb-
5-75%
5-70%
15-50%

HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-

HFO-1243zf

EXAMPLE 19: SYSTEMS WITH 13 COMPOUNDS

HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HCFO-1233zdE-HFO-1234zeE-HFO-1234zeZ-HFC-1243zf-HCFC-244bb-TFP-HFC-245fa-HFO-1225yeZ-HFO-1225zc

Organics 0.087
Organics
Organics
Organics
Organics

012346F + 0.087
0.88 F1234yf +
0.01 F1234yf +
0.01 F1234yf +
0.01 F1234yf +

F245cb + 0.083
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +
0.01 F245cb +

F1233xf + 0.083
0.01 F1233xf +
0.89 F1233xf +
0.01 F1233xf +
0.01 F1233xf +

F1233zdE + 0.083
0.01 F1233zdE +
0.01 F1233zdE +
0.01 F1233zdE +
0.89 F1233zdE +

F1234zeE + 0.083
0.01 F1234zeE +
0.01 F1234zeE +
0.89 F1234zeE +
0.01 F1234zeE +

F1234zeZ + 0.083
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +
0.01 F1234zeZ +

F1243zf + 0.083
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +
0.01 F1243zf +

F244bb + 0.083
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +
0.01 F244bb +

F245fa + 0.083
0.01 F245fa +
0.01 F245fa +
0.01 F245fa +
0.01 F245fa +

TFP + 0.083
0.01 TFP + 0.01
0.01 TFP + 0.01
0.01 TFP + 0.01
0.01 TFP + 0.01

F1225yeZ + 0.83
F1225yeZ + 0.1
F1225yeZ + 0.1
F1225yeZ + 0.1
F1225yeZ + 0.1

F1225zc
F1225zc
F1225zc
F1225zc
F1225zc

TOTAL
TOTAL
TOTAL
TOTAL
TOTAL

MASSFRAC
PRESSURE
PRESSURE
PRESSURE
PRESSURE
PRESSURE

HF
bar
bar
bar
bar
bar

0
4.5
6.5
1.0
4.8
1.7

0.05
5.6
7.5
3.0
5.8
2.9

0.1
5.6
7.5
3.0
5.8
2.9

0.15
5.6
7.5
3.0
5.8
2.8

0.2
5.6
7.5
3.0
5.8
2.8

0.25
5.6
7.5
3.0
5.8
2.8

0.3
5.6
7.5
3.0
5.8
2.8

0.35
5.6
7.5
3.0
5.8
2.8

0.4
5.6
7.5
3.0
5.8
2.8

0.45
5.5
7.5
3.0
5.8
2.8

0.5
5.5
7 5
3.0
5.8
2.8

0.55
5.5
7.5
3.0
5.7
2.8

0.6
5.5
7.5
3.0
5.6
2.8

0.65
5.5
7.5
3.0
5.5
2.8

0.7
5.4
7.5
3.0
5.4
2.8

0.75
5.3
7.3
3.0
5.2
2.8

0.8
5.1
7.0
2.8
4.8
2.7

0.85
4.6
6.4
2.8
4.3
2.5

0.9
3.9
5.4
2.3
3.6
2.2

0.95
2.8
3.7
1.8
2.6
1.8

1
1.2
1.2
1.2
1.2
1.2

EXAMPLE 20: TEMPERATURE AND PRESSURE RANGE OF SYSTEM WITH 13 COMPOUNDS

Boiling point range

Temperature
Pressure

System with 13 compounds
° C.
bar abs

HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HCFO-1233zdE-
0 to 40
~0.7 to ~18.0

HFO-1234zeE-HFO-1234zeZ-HFC-1243zf-HCFC-244bb-

TFP-HFC-245fa-HFO-1225yeZ-HFO-1225zc

EXAMPLE 21: DECANTATION RANGES OF SYSTEM WITH 13 COMPOUNDS

Decantation ranges

Mass percentage of HF

Temperature

System with 13 compounds
0° C.
25° C.
40° C.

HF-HFO-1234yf-HFC-245cb-HCFO-1233xf-HCFO-
5-75%
10-70%
15-60%

1233zdE-HFO-1234zeE-HFO-1234zeZ-HFC-1243zf-HCFC-

244bb-TFP-HFC-245fa-HFO-1225yeZ-HFO-1225zc

Number	Name	Date	Kind
6013846	Wismer	Jan 2000	A
6328907	Nakada et al.	Dec 2001	B1
7183448	Nakada et al.	Feb 2007	B2
7423188	Miller et al.	Sep 2008	B2
8075797	Hulse et al.	Dec 2011	B2
8273928	Knapp	Sep 2012	B2
8378158	Hulse et al.	Feb 2013	B2
8450537	Rao	May 2013	B2
8858823	Rached et al.	Oct 2014	B2
9000238	Knapp	Apr 2015	B2
9889416	Bonnet et al.	Feb 2018	B2
10029961	Deur-Bert et al.	Jul 2018	B2
10029963	Bonnet et al.	Jul 2018	B2
10077221	Bonnet et al.	Sep 2018	B2
10252913	Bonnet et al.	Apr 2019	B2
10266465	Bonnet et al.	Apr 2019	B2
10343963	Bonnet et al.	Jul 2019	B2
20070100173	Miller	May 2007	A1
20070100175	Miller	May 2007	A1
20080051612	Knapp	Feb 2008	A1
20090127496	Rao	May 2009	A1
20100072415	Rao	Mar 2010	A1
20100187088	Merkel	Jul 2010	A1
20100237279	Hulse	Sep 2010	A1
20110112340	Smith	May 2011	A1
20110218369	Elsheikh	Sep 2011	A1
20110218370	Elsheikh et al.	Sep 2011	A1
20120010449	Wismer et al.	Jan 2012	A1
20120041239	Suzuki	Feb 2012	A1
20120053369	Hulse	Mar 2012	A1
20120053372	Hulse et al.	Mar 2012	A1
20120056122	Hulse	Mar 2012	A1
20120138841	Hulse	Jun 2012	A1
20120222448	Chaki	Sep 2012	A1
20120305382	Knapp	Dec 2012	A1
20130105296	Chaki	May 2013	A1
20140012052	Pham	Jan 2014	A1
20140024575	Rached	Jan 2014	A1
20150105596	Wang	Apr 2015	A1
20150197467	Pigamo	Jul 2015	A1
20160009555	Bonnet	Jan 2016	A1
20160023176	Bonnet	Jan 2016	A1
20160023974	Bonnet	Jan 2016	A1
20160031773	Bonnet	Feb 2016	A1
20160046548	Bonnet	Feb 2016	A1
20170297982	Deur-Bert et al.	Oct 2017	A1
20180126348	Bonnet et al.	May 2018	A1
20180297919	Deur-Bert et al.	Oct 2018	A1
20180312453	Bonnet et al.	Nov 2018	A1
20180354875	Bonnet et al.	Dec 2018	A1

Number	Date	Country
H11-279088	Oct 1999	JP
2012-516336	Jul 2012	JP
2012-521430	Sep 2012	JP
WO 9727163	Jul 1997	WO
WO 0029361	May 2000	WO
WO 2007053736	May 2007	WO
WO 2008002500	Jan 2008	WO
WO 2009105517	Aug 2009	WO
WO 2010059493	May 2010	WO
WO 2010088196	Aug 2010	WO
WO 2010088196	Aug 2010	WO
WO 2010111067	Sep 2010	WO
WO 2012075283	Jun 2012	WO
WO 2014147310	Sep 2014	WO
WO 2014147311	Sep 2014	WO
WO 2014147312	Sep 2014	WO
WO 2014147313	Sep 2014	WO
WO 2014147314	Sep 2014	WO

Composition comprising HF and 3,3,3-trifluoropropene

Information

Patent Number

Date Filed

Date Issued

Inventors

Original Assignees

Examiners

Agents

CPC

Field of Search

US

International Classifications

Disclaimer

Term Extension

Abstract

Description

Claims

Priority Claims (1)

PCT Information

US Referenced Citations (50)

Foreign Referenced Citations (18)

Non-Patent Literature Citations (6)

Related Publications (1)