Claims
- 1. A two part composition comprising an aqueous base formulation component containing an alkalizing agent, one or more oxidation hair dye intermediates, and a quaternary amine as a first part and an oxidizing solution component as a second part, said first and second part to be mixed just before use and cooperating to give a composition that simultaneously colors and conditions hair and contains:
- (a) from about 0.05 to 5% by weight of a quaternary amine in active form of formula: ##STR4## in which: R.sup.1 and R.sup.2 are long chain aliphatic hydrocarbon radicals having about 10 to 26 carbons;
- R.sup.3 and R.sup.4 are lower akyl radicals having about 1 to 5 carbons; and
- X is an anion;
- (b) sufficient oxidizing agent to develop said oxidation hair dye intermediates;
- (c) sufficient alkalizing agent to give said composition a pH in the range of from about 8 to 11; and
- (d) said composition containing no additives having large anionic groups that tend to deactivate said quaternary amine compound.
- 2. A composition according to claim 1 in which said oxidizing agent is hydrogen peroxide.
- 3. A composition according to claim 1 in which R.sup.1 and R.sup.2 in formula I are long chain alkyl groups.
- 4. A composition according to claim 1 in which the base formulation contains up to about 30% by weight of a neutral surfactant.
- 5. A composition according to claim 1 wherein the alkalizing agent in the base formulation is ethanolamine.
- 6. A composition according to claim 1 wherein the alkalizing agent in the base formulation is ammonium hydroxide.
- 7. A composition according to claim 1 wherein the quaternary amine compound in the base formulation is dilauryl dimethyl ammonium chloride.
- 8. A composition according to claim 1 wherein the quaternary amine compound is distearyl dimethyl ammonium chloride.
- 9. A composition according to claim 1 wherein the quaternary amine compound is dicoco dimethyl ammonium chloride.
- 10. A composition according to claim 1 wherein the quaternary amine compound is di-hydrogenated beef-tallow dimethyl ammonium chloride.
- 11. A composition according to claim 5 wherein the quaternary ammonium compound is dicoco dimethyl ammonium chloride.
- 12. A composition according to claim 1 in which said oxidation dye intermediate comprises an effective amount of para component containing a compound selected from the group consisting of N-ethyl-N-hydroxyethyl-p-phenylenediamine and its hydrochloride; N,N-bis(.beta.-hydroxyethyl)-p-phenylenediamine and its hydrochloride or sulfate; N,N-bis(.beta.-hydroxyethyl)-3-methyl-p-phenylenediamine and its hydrochloride or sulfate; N,3-dimethyl-p-phenylenediamine and its hydrochloride; N-hydroxyethyl-2-methyl-p-phenylenediamine and its hydrochloride; N,2-dimethyl-p-phenylenediamine; N.sup.1 -methyl-3-methoxy-p-phenylenediamine; N.sup.1 -methyl-2-methoxy-p-phenylenediamine; 3-chloro-N.sup.1 -methyl-p-phenylenediamine, N,N-bis(2,3-dihydroxypropyl)-p-phenylenediamine; p-toluenediamine, p-aminophenol, p-aminodiphenylamine, 4,4'-diaminodiphenylamine, p-phenylenediamine, 2,6-dimethyl-p-phenylenediamine, 2,5-diaminopyridine and mixtures thereof.
- 13. A composition according to claim 12 wherein said compound is N,N-bis(.beta.-hydroxyethyl)-p-phenylenediamine and its hydrochloride or sulfate.
- 14. A composition according to claim 12 wherein said compound is p-phenylenediamine.
- 15. A composition according to claim 12 wherein said compound is p-aminophenol.
- 16. A composition according to claim 12 in which said oxidation dye intermediate further comprises as coupling component an effective amount of a phenol which reacts with said para component in the presence of oxidizing agents to produce indophenols.
- 17. A composition according to claim 16 wherein said phenol is resorcinol.
- 18. A composition according to claim 16 wherein said phenol is alpha-naphthol.
- 19. A composition according to claim 16 wherein said phenol is pyrocatechol.
- 20. A composition according to claim 16 wherein said phenol is pyrogallol.
- 21. A composition according to claim 12 in which said oxidation dye intermediate further comprises an effective amount of m-phenylenediamine selected from the group consisting of m-phenylenediamine and 2,4-diaminoanisole.
- 22. A composition according to claim 12 in which said oxidation dye intermediate further comprises an effective amount of a coupling component selected from the group consisting of 2,4-diaminophenol, m-aminophenol, aminoresorcinol, 1,5-aminohydroxynaphthalene and 1,8-aminohydroxynaphthalene.
- 23. A composition according to claim 22 in which said coupling component is m-aminophenol.
- 24. A composition according to claim 12 in which said oxidation dye intermediate further comprises an effective amount of a coupling component containing an active methylene group and selected from the group consisting of 3-methylpyrazolone-(5), 1-phenyl-3-methylpyrazolone-(5), 1,3-dimethylpyrazolone-(5), acetoacetic acid anilide, benzoylacetotoluide and nicotinoylacetanilide.
- 25. A composition according to claim 12 in which said oxidation dye intermediate further comprises an effective amount of a coupler selected from the group consisting of hydroquinone, catechol, 1,5-naphthalenediol, and o-aminophenol.
- 26. A two part composition comprising an aqueous base formulation component containing an alkalizing agent, one or more oxidation hair dye intermediates, and a first and second quaternary amine as a first part and an oxidizing solution component as a second part, said first and second part to be mixed just before use and cooperating to give a composition that simultaneously colors and conditions hair and contains:
- (a) from about 0.05 to 5% by weight of a first quaternary amine in active form of formula: ##STR5## (b) second quaternary amine in active form of formula: ##STR6## (c) sufficient oxidizing agent to develop said oxidation hair dye intermediates;
- (d) sufficient alkalizing agent to give said composition a pH in the range of from about 8 to 11;
- (e) said composition containing no additives having large anionic groups that tend to deactivate said quaternary amine compounds; and
- wherein:
- R.sup.1 and R.sup.2 are long chain aliphatic hydrocarbon radicals having about 10 to 26 carbons;
- R.sup.3, R.sup.4 and R.sup.10 are lower alkyl radicals having 1 to 5 carbons; and
- X is an anion.
- 27. A composition according to claim 26 wherein said second quaternary amine is soya trimethyl ammonium chloride.
- 28. A composition according to claim 26 in which said oxidizing agent is hydrogen peroxide.
- 29. A composition according to claim 26 in which R.sup.1 and R.sup.2 in formula I are long chain alkyl groups.
- 30. A composition according to claim 26 in which the base formulation contains up to about 30% by weight of a neutral surfactant.
- 31. A composition according to claim 26 wherein the alkalizing agent in the base formulation is ethanolamine.
- 32. A composition according to claim 26 wherein the alkalizing agent in the base formulation is ammonium hydroxide.
- 33. A composition according to claim 26 wherein the first quaternary amine compound in the base formulation is dilauryl dimethyl ammonium chloride.
- 34. A composition according to claim 26 wherein the first quaternary amine compound is distearyl dimethyl ammonium chloride.
- 35. A composition according to claim 26 wherein the first quaternary amine compound is dicoco dimethyl ammonium chloride.
- 36. A composition according to claim 26 wherein the first quaternary amine compound is di-hydrogenated beef-tallow dimethyl ammonium chloride.
- 37. A composition according to claim 31 wherein the first quaternary ammonium compound is dicoco dimethyl ammonium chloride.
- 38. A composition according to claim 26 in which said oxidation dye intermediate comprises an effective amount of para component containing a compound selected from the group consisting of N-ethyl-N-hydroxyethyl-p-phenylene-diamine and its hydrochloride; N,N-bis(beta-hydroxyethyl)-p-phenylenediamine and its hydrochloride or sulfate; N,N-bis(beta-hydroxyethyl)-3-methyl-p-phenylenediamine and its hydrochloride or sulfate; N,3-dimethyl-p-phenylenediamine and its hydrochloride; N-hydroxyethyl-2-methyl-p-phenylenediamine and its hydrochloride; N,2-dimethyl-p-phenylenediamine; N.sup.1 -methyl-3-methoxy-p-phenylenediamine; N.sup.1 -methyl-2-methoxy-p-phenylenediamine; 3-chloro-N.sup.1 -methyl-p-phenylenediamine, N,N-bis(2,3-di-hydroxypropyl)-p-phenylenediamine; p-toluenediamine, p-aminophenol, p-aminodiphenylamine, 4,4'-diaminodiphenylamine, p-phenylenediamine, 2,6-dimethyl-p-phenylenediamine, 2,5-diamino-pyridine and mixtures thereof.
- 39. A composition according to claim 38 wherein said compound is N,N-bis(beta-hydroxyethyl)-p-phenylenediamine and its hydrochloride or sulfate.
- 40. A composition according to claim 38 wherein said compound is p-phenylenediamine.
- 41. A composition according to claim 38 wherein said compound is p-aminophenol.
- 42. A composition according to claim 38 in which said oxidation dye intermediate further comprises as coupling component an effective amount of a phenol which reacts with said para component in the presence of oxidizing agents to produce indophenols.
- 43. A composition according to claim 42 wherein said phenol is resorcinol.
- 44. A composition according to claim 42 wherein said phenol is alpha naphthol.
- 45. A composition according to claim 42 wherein said phenol is pyrocatechol.
- 46. A composition according to claim 42 wherein said phenol is pyrogallol.
- 47. A composition according to claim 38 in which said oxidation dye intermediate further comprises an effective amount of m-phenylenediamine selected from the group consisting of m-phenylenediamine and 2,4-diaminoanisole.
- 48. A composition according to claim 38 in which said oxidation dye intermediate further comprises an effective amount of a coupling component selected from the group consisting of 2,4-diaminophenol, m-aminophenol, aminoresorcinol, 1,5-aminohydroxynaphthalene and 1,8-aminohydroxynaphthalene.
- 49. A composition according to claim 48 in which said coupling component is m-aminophenol.
- 50. A composition according to claim 38 in which said oxidation dye intermediate further comprises an effective amount of a coupling component containing an active methylene group and selected from the group consisting of 3-methylpyrazolone-(5), 1-phenyl-3-methyl-pyrazolone-(5), 1,3-dimethylpyrazolone-(5), acetoacetic acid anilide, benzoylacetotoluide and nicotinoylacetanilide.
- 51. A composition according to claim 38 in which said oxidation dye intermediate further comprises an effective amount of a coupler selected from the group consisting of hydroquinone, catechol, 1,5-naphthalenediol, and o-aminophenol.
Parent Case Info
This is a division, of application Ser. No. 796,115, filed May 11, 1977, now U.S. Pat. No. 4,119,399, which is in turn a continuation of application Ser. No. 656,503 filed Feb. 9, 1976 now U.S. Pat. No. 4,096,243.
US Referenced Citations (18)
Foreign Referenced Citations (11)
Number |
Date |
Country |
726665 |
Oct 1942 |
DE2 |
2207979 |
Aug 1972 |
DEX |
2190406 |
Feb 1974 |
FRX |
6913123 |
Mar 1970 |
NLX |
7202292 |
Aug 1972 |
NLX |
7202293 |
Aug 1972 |
NLX |
7310827 |
Feb 1974 |
NLX |
7413406 |
Oct 1974 |
NLX |
758762 |
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GBX |
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Apr 1969 |
GBX |
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GBX |
Non-Patent Literature Citations (1)
Entry |
Chemical Abstracts, vol. 83: 209324s, (1975). |
Divisions (1)
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Number |
Date |
Country |
Parent |
796115 |
May 1977 |
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Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
656503 |
Feb 1976 |
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