Claims
- 1. A composition for washing or conditioning keratinous matter consisting essentially of an aqueous medium, 5 to 50% by weight relative to the total weight of the composition of a surface-active agent possessing detergent properties, 0.2 to 30% by weight relative to the total weight of the composition of at least one silicone which is insoluble in the medium and 0.1 to 10% by weight relative to the total weight of the composition of at least one amphoteric copolymer derived from diallyldialkylammonium and an anionic monomer which contains 60 to 99% by weight of units derived from a quaternary diallyldialkylammonium monomer in which the alkyl groups have, independently from each other, 1 to 18 carbon atoms, the corresponding anion being derived from an acid which has an ionization constant higher than 10.sup.-13 and approximately 1 to 40% by weight of units of an anionic monomer selected from the group consisting of acrylic acid and methacrylic acid, having a molecular weight between 50,000 and 10,000,000 determined by gel permeation chromatography, wherein said composition does not contain an alcohol dispersing agent containing 27 to 44 carbon atoms and containing a functional group selected from the group consisting of an ether group, a thioether group and a sulphoxide group.
- 2. The composition according to claim 1 in which the silicone is a polyorganosiloxane which is insoluble in the aqueous medium and is in the form of oil, wax, gum or resin.
- 3. The composition according to claim 2 in which the polyorganosiloxane is a non-volatile silicone selected from the group consisting of a polyalkylsiloxane, a polyalkylarylsiloxane, a polyarylsiloxane, a silicone gum, a silicon resin, an organomodified polysiloxane and mixtures thereof.
- 4. The composition according to claim 3 in which the polyalkylsiloxane is selected from the group consisting of a linear polydimethylsiloxane containing trimethylsilyl end groups with a viscosity between 5.times.10.sup.-6 and 2.5 m.sup.2 /s at 25.degree. C., a linear polydimethylsiloxane containing dimethylsilanol end groups and a poly-C.sub.1 -C.sub.20 -alkylsiloxane.
- 5. The composition according to claim 2 in which the polyorganosiloxane is selected from the group consisting of a linear polyalkylsiloxane containing a trimethylsilyl end group with a viscosity of between 0.2 and 2.5 m.sup.2 /s at 25.degree. C. a mixture of a polydimethylsiloxanes hydroxylated at the end of a chain and a cyclic polydimethylsiloxane, a mixture of two polydimethylsiloxanes consisting of a gum and an oil of different viscosities and a polyorganosiloxane modified with a hydroxyacylamino group.
- 6. The composition according to claim 1 in which the alkyl groups have between 1 and 4 carbon atoms.
- 7. The composition according to claim 1 in which the copolymer is derived from dimethyldiallylammonium or diethyldiallylammonium chloride and acrylic acid.
- 8. The composition according to claim 1 in which the surface-active agent is selected from the group consisting of anionic, amphoteric, zwitterionic and nonionic surface-active agents and mixtures thereof.
- 9. The composition according to claim 8, wherein
- the anionic surface-active agent is selected from the group consisting of alkali metal salts, ammonium salts, amine salts, aminoalcohol salts and magnesium salts of the following compounds: alkyl ether sulphates, alkylamidoether sulphates, alkylarylpolyether sulphates, monoglyceride sulphates, alkylsulphonates, alkylamide sulphonates, alkylarylsulphonates, olefin sulphonates, paraffin sulphonates, alkyl sulphosuccinates,alkyl ether sulphosuccinates, alkylamide sulphosuccinates, alkylsulphosuccinamates, alkyl sulphoacetates, alkyl ether phosphates, acylsarcosinates and N-acyltaurates, in which the alkyl or acyl radical is a carbon chain containing between 12 and 20 carbon atoms; salts of oleic, ricinoleic, palmitic and stearic acids; copra oil and hydrogenated copra oil acids; and acyllactylates in which the acyl radical contains from 8 to 20 carbon atoms;
- the nonionic surface-active agent is selected from the group consisting of polyethoxylated, polypropoxylated and polyglycerolated alcohols, alpha-diols and alkylphenols with a fatty acid chain containing between 8 and 18 carbon atoms, the number of ethylene oxide and propylene oxide groups being between 2 and 50 and the number of glycerol groups being between 2 and 30; copolymers of ethylene and propylene oxides; condensates of ethylene and propylene oxides with fatty alcohols; polyethoxylated fatty amides containing 2 to 30 moles of ethylene oxide; polyglycerolated fatty amides containing 1 to 5 glycerol groups; polyethoxylated fatty amines containing 2 to 30 moles of ethylene oxide; oxyethylenated sorbitan fatty acid esters containing 2 to 30 moles of ethylene oxide; sucrose fatty acid esters; alkylpolyglycosides; C.sub.10 -C.sub.14 -alkylamine oxides and N-acylamidopropylmorpholine oxides; and
- the amphoteric and zwitterionic surface-active agents are selected from the group consisting of derivatives of aliphatic secondary or tertiary amines in which the aliphatic radical is a linear or branched chain containing 8 to 18 carbon atoms and which contains at least one water-solubilizing carboxylate, sulphonate, sulphate, phosphate or phosphonate anionic group; C.sub.8 -C.sub.20 -alkylbetaines, sulphobetaines, C.sub.8 -C.sub.20 -alkylamido-C.sub.1 -C.sub.6 -alkylbetaines or C.sub.8 -C.sub.20 -alkylamido-C.sub.1 -C.sub.5 -alkylbetaines.
- 10. The composition according to claim 9 in which the composition also contains a dispersing agent having the formula RX in an amount between 0.1 and 20% by weight of the total weight of the composition, selected from the group consisting of
- (i) RX compounds in which R is a C.sub.11 -C.sub.21 alkyl or alkenyl radical and X is selected from the group consisting of
- (a) COOA where A is a mono- or polyhydroxyalkyl radical derived from a C.sub.2 -C.sub.3 polyol or a radical CH.sub.2 CH.sub.2 SO.sub.3 M where M is an alkali metal, ammonium or a C.sub.1 -C.sub.4 alkanolamine residue;
- (b) CO(OCH.sub.2 CH.sub.2).sub.n --OH where n has a value of between 2 and 150;
- (c) ##STR3## where n has a value of between 2 and 150; (d) CONR.sub.1 R.sub.2 where R.sub.1 and R.sub.2 are hydrogen or C.sub.1 -C.sub.4 hydroxyalkyl with at least one being C.sub.1 -C.sub.4 hydroxyalkyl; and
- (e) OSO.sub.3 M or 1/3 PO.sub.4 M.sub.3 where M is an alkali metal, ammonium or a C.sub.1 -C.sub.4 alkanolamine residue;
- (ii) RX compounds which are esters formed by the reaction of R, where R is a C.sub.11 -C.sub.21 alkyl or alkenyl radical and X is selected from the group consisting of:
- (a) COOA where A is a mono- or polyhydroxyalkyl radical derived from a C.sub.2 -C.sub.3 polyol or a radical CH.sub.2 CH.sub.2 SO.sub.3 M where M is an alkali metal, ammonium or a C.sub.1 -C.sub.4 alkanolamine residue;
- (b) CO(OCH.sub.2 CH.sub.2).sub.n --OH where n has a value of between 2 and 150; and
- (c) ##STR4## where n has a value of between 2 and 150; and (iii) RX compounds in which R is a radical R.sub.3 (OC.sub.2 H.sub.4).sub.i OCH.sub.2 selected from the group consisting of
- (a) R.sub.3 (OC.sub.2 H.sub.4).sub.i OCH.sub.2 compounds in which R.sub.3 is a C.sub.12 -C.sub.14 alkyl radical and i is a whole or decimal number between 2.5 and 10;
- (b) R.sub.3 (OC.sub.2 H.sub.4).sub.i OCH.sub.2 compounds in which R.sub.3 is an oleyl and i is a whole decimal number between 2 to 9; and
- (c) R.sub.3 (OC.sub.2 H.sub.4).sub.i OCH.sub.2 compounds in which R.sub.3 is a C.sub.8 -C.sub.9 alkylphenyl and i is a whole or decimal number between 4 to 8;
- and X is COOM, where M is selected from the group consisting of an alkali metal, an ammonium group and a C.sub.1 -C.sub.4 alkanolamine residue.
- 11. The composition according to claim 1 in which the aqueous medium is water or a mixture of water and a cosmetically acceptable solvent in which the cosmetically acceptable solvent is selected from the group consisting of a C.sub.1 -C.sub.4 lower alcohol, an alkylene glycol, a glycol ether, and mixtures thereof.
- 12. The composition according to claim 1 in which the composition also contains a lustering or opacifying agent present in proportions ranging up to 3% by weight relative to the total weight of the composition.
- 13. The composition according to claim 1 in which the composition also contains a viscosity modifier selected from the group consisting of an electrolyte, a hydrotropic agent and a thickening agent; said modifier being present in proportions ranging up to 10% by weight relative to the total weight of the composition.
- 14. The composition according to claim 1 in which the composition also contains an agent to improve the cosmetic properties of hair or skin selected from the group consisting of a cationic surface-active agent, a polymer other than the copolymer derived from diallyldialkylammonium and an anionic monomer, a protein and a silicone which is soluble in the composition.
- 15. A process for washing or conditioning keratinous matter consisting essentially of applying a composition which comprises an aqueous medium, 5 to 50% by weight relative to the total weight of the composition of a surface-active agent possessing detergent properties, 0.2 to 30% by weight relative to the total weight of the composition of at least one silicone which is insoluble in the medium and 0.1 to 10% by weight relative to the total weight of the composition of at least one amphoteric copolymer derived from diallyldialkylammonium and an anionic monomer which contains 60 to 99% by weight of units derived from a quaternary diallyldialkylammonium monomer in which the alkyl groups have, independently from each other, 1 to 18 carbon atoms, the corresponding anion being derived from an acid which has an ionization constant higher than 10.sup.-13 and approximately 1 to 40% by weight of units of an anionic monomer selected from the group consisting of acrylic acid and methacrylic acid, having a molecular weight between 50,000 and 10,000,000 determined by gel permeation chromatography, wherein said composition does not contain an alcohol dispersing agent containing 27 to 44 carbon atoms and containing a functional group selected from the group consisting of an ether group, a thioether group and a sulphoxide group.
- 16. A composition for washing or conditioning keratinous matter consisting essentially of an aqueous medium, 5 to 50% by weight relative to the total weight of the composition of a surface-active agent possessing detergent properties, 0.2 to 30% by weight relative to the total weight of the composition of at least one polyalkylsiloxane which is insoluble in the medium and 0.1 to 10% by weight relative to the total Weight of the composition of at least one amphoteric copolymer derived from diallyldialkylammonium and an anionic monomer which contains 60 to 99% by weight of units derived from a quaternary diallyldialkylammonium monomer in which the alkyl groups have, independently from each other, 1 to 18 carbon atoms, the corresponding anion being derived from an acid which has an ionization constant higher than 10.sup.-13 and approximately 1 to 40% by weight of units of an anionic monomer selected from the group consisting of acrylic acid and methacrylic acid, having a molecular weight between 50,000 and 10,000,000 determined by gel permeation chromatography, wherein said composition does not contain an alcohol dispersing agent containing 27 to 44 carbon atoms and containing a functional group selected from the group consisting of an ether group, a thioether group and a sulphoxide group.
- 17. The composition according to claim 16 in which the composition further consists essentially of a dispersing agent having a formula RX, selected from the group consisting of
- (i) RX compounds in which R is a C.sub.11 -C.sub.21 alkyl or alkenyl radical and X is selected from the group consisting of
- (a) COOA where A is a mono- or polyhydroxyalkyl radical derived from a C.sub.2 -C.sub.3 polyol or a radical CH.sub.2 CH.sub.2 SO.sub.3 M where M is an alkali metal, ammonium or a C.sub.1 -C.sub.4 alkanolamine residue;
- (b) CO(OCH.sub.2 CH.sub.2).sub.n --OH where n has a value of between 2 and 150;
- (c) ##STR5## where n has a value of between 2 and 150; (d) CONR.sub.1 R.sub.2 where R.sub.1 and R.sub.2 are hydrogen or C.sub.1 -C.sub.4 hydroxyalkyl with at least one being C.sub.1 -C.sub.4 hydroxyalkyl; and
- (e) OSO.sub.3 M or 1/3 PO.sub.4 M.sub.3 where M is an alkali metal, ammonium or a C.sub.1 -C.sub.4 alkanolamine residue;
- (ii) RX compounds which are esters formed by the reaction of R, where R is a C.sub.11 -C.sub.21 alkyl or alkenyl radical and X is selected from the group consisting of:
- (a) COOA where A is a mono- or polyhydroxyalkyl radical derived from a C.sub.2 -C.sub.3 polyol or a radical CH.sub.2 CH.sub.2 SO.sub.3 M where M is an alkali metal, ammonium or a C.sub.1 -C.sub.4 alkanolamine residue;
- (b) CO(OCH.sub.2 CH.sub.2).sub.n --OH where n has a value of between 2 and 150; and
- (c) ##STR6## where n has a value of between 2 and 150; and (iii) RX compounds in which R is a radical R.sub.3 (OC.sub.2 H.sub.4).sub.i OCH.sub.2 selected from the group consisting of
- (a) R.sub.3 (OC.sub.2 H.sub.4).sub.i OCH.sub.2 compounds in which R.sub.3 is a C.sub.12 -C.sub.14 alkyl radical and i is a whole or decimal number between 2.5 and 10;
- (b) R.sub.3 (OC.sub.2 H.sub.4).sub.i OCH.sub.2 compounds in which R.sub.3 is an oleyl and i is a whole decimal number between 2 to 9; and
- (c) R.sub.3 (OC.sub.2 H.sub.4).sub.i OCH.sub.2 compounds in which R.sub.3 is a C.sub.8 -C.sub.9 alkylphenyl and i is a whole or decimal number between 4 to 8;
- and X is COOM, where M is selected from the group consisting of an alkali metal, an ammonium group and a C.sub.1 -C.sub.4 alkanolamine residue,
- and in which the surface active agent is selected from a group consisting of (i) an anionic surface-active agent selected from the group consisting of alkali metal salts, ammonium salts, amine salts, aminoalcohol salts and magnesium salts of the following compounds: alkyl ether sulphates, alkylamidoether sulphates, alkylarylpolyether sulphates, monoglyceride sulphates, alkylsulphonates, alkylamide sulphonates, alkylarylsulphonates, olefin sulphonates, paraffin sulphonates, alkyl sulphosuccinates, alkyl ether sulphosuccinates, alkylamidesulphosuccinates, alkylsulphosuccinamates, alkylsulphoacetates, alkyl ether phosphates, acylsarcosinates and N-acyltaurates, in which the alkyl or acyl radical is a carbon chain containing between 12 and 20 carbon atoms; salts of oleic, ricinoleic, palmitic and stearic acids; copra oil and hydrogenated copra oil acids; and acyl-lactylates in which the acyl radical contains from 8 to 20 carbon atoms; (ii) a nonionic surface-active agent selected from the group consisting of polyethoxylated, polypropoxylated and polyglycerolated alcohols, alpha-diols and alkylphenols with a fatty acid chain containing between 8 and 18 carbon atoms, the number of ethylene oxide and propylene oxide groups being between 2 and 50 and the number of glycerol groups being between 2 and 30; copolymers of ethylene and propylene oxides; condensates of ethylene and propylene oxides with fatty alcohols; polyethoxylated fatty amides containing 2 to 30 moles of ethylene oxide; polyglycerolated fatty amides containing 1 to 5 glycerol groups; polyethoxylated fatty amines containing 2 to 30 moles of ethylene oxide; oxyethlenated sorbitan fatty acid esters containing 2 to 30 moles of ethylene oxide; sucrose fatty acid esters; alkylpolyglycosides; C.sub.10 -C.sub.14 -alkylamine oxides and N-acylamidopropylmorpholine oxides; and (iii) amphoteric and zwitterionic surface-active agents selected from the group consisting of derivatives of aliphatic secondary or tertiary amines in which the aliphatic radical is a linear or branched chain containing 8 to 18 carbon atoms and which contains at least one water-solubilizing carboxylate, sulphonate, sulphate, phosphate or phosphonate anionic group; C.sub.8 -C.sub.20 -alkylbetaines, sulphobetaines, C.sub.8 -C.sub.20 -alkylamido-C.sub.1 -C.sub.6 -alkylbetaines or C.sub.8 -C.sub.20 -alkylamido-C.sub.1 -C.sub.5 -alkylbetaines.
Priority Claims (1)
Number |
Date |
Country |
Kind |
9107677 |
Jun 1991 |
FRX |
|
Parent Case Info
This application is a continuation of application Ser. No. 07/900,562, filed on Jun. 18, 1992 now abandoned.
US Referenced Citations (14)
Foreign Referenced Citations (6)
Number |
Date |
Country |
401867 |
Nov 1984 |
EPX |
203750 |
May 1986 |
EPX |
269243 |
Oct 1987 |
EPX |
392320 |
Apr 1990 |
EPX |
2548019 |
Jun 1984 |
FRX |
2058103 |
Aug 1980 |
GBX |
Continuations (1)
|
Number |
Date |
Country |
Parent |
900562 |
Jun 1992 |
|