COMPOSITIONS AND METHODS FOR TREATING KERATIN BASED FIBERS

Abstract
Formulations, methods and kits are provided for styling keratinous fiber. The hair can be wet, damp or dry. The formulations and kits allow for lower temperature styling for any of curling, waving and straightening hair.
Description

The example embodiments disclosed herein relate to compositions, formulations, kits and/or methods for styling keratin based fibers (e.g., hair). More specifically, the example embodiments allow one to style hair using temperatures that are lower than currently used styling temperatures.


BACKGROUND

Heat-assisted styling of keratinous fibers (e.g., human hair), particularly using blow dryers, hair straighteners (flat irons), curling devices, heated comb, heated brush (with or without a rotating drum), or other heated styling means (each of which may be referred to herein as a “Hot Tool”), is prevalent amongst consumers. Unfortunately, heat-assisted styling can dry out and damage hair by subjecting the hair to too much heat. For example, hair can become over dried by holding a blow dryer too close to the hair, or by holding a Hot Tool at a particular spot of the hair for too long of a time. The overheating causes moisture to evaporate or be driven out of the hair so that the hair becomes brittle and more susceptible to cracking. In addition, overheating in heat styling can cause physical damage to the hair, particularly by raising the cuticles and/or creating blisters on individual hair fibers, thereby causing increased friction between the hair fibers, making it more difficult to comb, requiring increased force to comb the hair, which in turn can wear the outer surface of the hair and cause cracks or breaks in the hair. For years, researchers assumed that human hair was similar in temperature based properties as wool because both are composed of the keratin protein. Recent research reveals that hair exhibits the following characteristics in response to the application of heat:


Stage 1—at or below about 150° C. (302° F.), loosely bound water and tightly bound water is lost or evaporated from the hair.


Stage 2—at between about 160° C. and 175° C. (320° F.-347° F.), hair undergoes a glass transition phase whereby the hair begins to flow similar to molten/hot glass. At this glass transition temperature, plastic deformation of the hair is possible. In a ‘normal’hydrated state, hair is elastic and can stretch and return back to its original length. Hair exhibits temporary plasticity which is why styles like curls, and twist outs/knot outs can occur. However, at glass transition temperatures, the plasticity of hair is not temporary. Upon cooling, the hair may return to a “normal looking” state, but the hair shaft has been damaged.


Stage 3—at between about 215° C. and 235° C. (419° F.-455° F.), the keratin, which is present in all hair as a natural alpha-helix (α-helix), melts, thereby leaving the hair in a permanently damaged state.


Generally, styling of hair is done using tools emitting relatively high heat operating at temperatures over 300° F. to achieve said glass transition/transformation temperature, causing heat damage to hair in the process of styling. When using heat to style hair (or other keratinous fibers), the required heat to reach a glass transition temperature is believed to be proportional to the water saturation or moisture content (i.e., water content) of the keratin fibers. As the water saturation or moisture content increases, the amount of heat that is required to reach a glass transition temperature decreases. As such, it would be advantageous to use the lowest possible temperature at which styling of the keratinous fibers can be achieved in order to prevent undesirable heat damage, which occurs at temperatures above 300° F., by temporarily increasing the water saturation or moisture (humidity) level in hair.


Persons having naturally curly or wavy hair often desire to alternate, at will, between having a curly or straight (i.e., non-curly) hair style configuration. There is a growing demand for products that can safely and temporarily remove some or all of the natural curl from the hair while at the same time provide the consumer with versatility in styling the hair.


Hair styling or hair setting compositions are widely used by consumers in the cosmetic industry to retain a particular shape or style of the hair. Hair styling compositions can assist in manipulating or styling the hair, providing temporary benefits in holding the shape of the hairstyle (fixing) and/or maintaining the shine or appearance (grooming, restyling) of the hair, e.g., in the evening, during the day, between hair washing periods, or between subsequent hair setting procedures. The inherent problem encountered in hair setting is the natural tendency of the hair to return to its natural shape. For example, the styled or set hair returns to its natural shape almost immediately if moistened. Likewise, high humidity conditions accelerate the tendency of the hair to return to its natural shape. When the hair returns to its natural shape, getting it back to its setting requires repeating the process of styling the hair or a part of, also known as “touching up the hair”. Intensive efforts have been directed toward providing a hair set with sufficient holding power to maintain the designed hair style until at least the next shampoo, and, therefore, giving the styled hair set a degree of permanency. Therefore, investigators have sought to delay the combined action of natural forces and moisture that causes the hair to return to its original state by applying solutions containing naturally-occurring or synthetic polymers after the hair is shaped into a desired configuration. When applied to the shaped hair from aqueous or aqueous/alcoholic solutions (setting lotions), the polymers leave a film on the hair, after drying, to help maintain the hair in the previously shaped configuration. The polymeric film promotes cohesion and gives stability to the hair set to maintain the hold of the hair set. The principal objective of a setting lotion is to cover the previously styled hair with an invisible polymeric film that will give the styled hair a degree of rigidity and protect the hair style against wind and humidity. A problem created by the methods described is the weighing down of hair by the film covering the hair, creating less movement of hair and/or rigidity which are not desired by consumers.


The art of temporarily removing the natural curl from naturally curly hair was practiced, in the early days, by applying pomade to the hair and then straightening the curl by combing the pomade coated hair, under tension, using a heated metal comb, a process commonly referred to as “pressing.” Although pressing leaves the hair shiny, silky and temporarily straightened, the process was cumbersome and caused hair damage from excessive heating. The pomades were cosmetically unaesthetic greases and difficult to remove from the hair. Additionally, the metal combs were heated, either electrically or on a stove, to relatively high temperatures, which posed the risk of burning the unprotected skin and scalp or of singeing the hair. More recently, some progress was made using a hair ironing process employing oily lotions and electrical variable heating devices, known as flat hair irons, and hair irons, some of which are combination hair straightener and curling irons, that can be controllably heated. However, the configuration of hair that has been temporarily straightened by these procedures reverts to its natural curly or wavy configuration readily on exposure to humidity, or perspiration, and especially upon washing the hair, as well as the damage caused by the use of these tools at temperatures over about 300° F. still renders the process as not completely satisfactory.


Permanent waving and straightening of hair are common techniques for beautifying hair or fur by permanently forming or setting the hair or fur into a desired configuration. Various techniques have been practiced for many years in the hair and fur industries, such as in hair salons, and in the home practiced by an individual. Hair and fur is comprised of keratin, which is a polyamide cross-linked by disulfide bonds. The disulfide bonds are responsible for the hair or fur being maintained in a particular configuration. In a conventional hair waving or straightening process, the hair is first softened or relaxed by breaking the disulfide bonds in the keratin with a reducing agent and then hardening the hair or fur in the desired configuration by stopping the reduction reaction and restoring or reforming disulfide bonds by applying an oxidizing agent, generally referred to in the art as a neutralizer.


A “Brazilian” hair straightening treatment has been described that requires the use of a formaldehyde solution in conjunction with a heated flat iron set at a temperature of about 232° C. (449.6° F.), to achieve temporary hair straightening with some resistance to reversion. In this process, solutions of formaldehyde (1.5% to 5%) are used which straighten the hair, which lasts through about two to about three shampoo sessions, or about four weeks, before having to repeat the straightening process. Formaldehyde is known to form cross-links among protein end groups to create a stable, complex matrix. For example, formaldehyde can form cross-links between amide, amino, and tyrosine groups, S—CH2-NH cross-links between N-terminal cysteine and amine groups, NH—CH2-NH cross-links between amine groups, and S—CH2-S cross-links. A variation of this procedure has been used in which the hair is first swollen with a composition, referred to in the trade as a dilator, having a pH of about 8.5, rinsed, then treated with a “no-frizz” lotion containing 0.2% formaldehyde, along with a thermal protector lotion containing silicones, and the hair is then blow dried and flat ironed. The hair treated in this manner required repeating the treatment process weekly to progressively attain some level of discernible straightening over a period of four consecutive weeks. Upon stopping usage of the procedure, however, the configuration of the hair reverts to its original wavy or curly pattern after two to three shampooings.


Cross-links produced by formaldehyde are not stable to acid or alkaline hydrolysis, and in aqueous solution, formaldehyde undesirably forms methylene glycol and can react with oxygen to produce formic acid. Additionally, exposure to formaldehyde solutions raises health concerns to the users and practitioners, because formaldehyde generally is presumed to be a carcinogen (i.e., causes cancer), and can cause contact dermatitis. Thus, a formaldehyde-containing solution is toxicologically unacceptable and, in many countries, including Brazil, the amount permitted to be present in hair and skin care products topically applied to humans is controlled and amounts exceeding the allowable level are prohibited. While hair straightened by the foregoing Brazilian processes was silky, straight and shiny, the amount of formaldehyde used exceeds the permissible amount of 0.1% free formaldehyde in cosmetics in Brazil, making it cosmetically undesirable. In Canada the Brazilian treatment was banned by Canadian health authorities in October, 2010. Another concern for users is that the extremely high heat used in the process as well as the chemicals used causes damage to hair, and many users are unhappy with their long term results using this process. The commercial success of the Brazilian treatment has created a great demand for flat irons working at higher temperatures of up to 232° C. (449° F.), shifting the market and getting most of the flat irons made to reach this high heat, keratin melting, and hair damaging temperatures.


Conventional chemical relaxers (hair straighteners) that are formulated to remove substantially all natural curl from the hair typically contain inorganic or organic bases that convert the disulfide bonds of cysteine in hair to stable, irreversible crosslinks of primarily lanthionine by the action of hydroxide ion. These lanthionizing chemical relaxers generally are highly alkaline, typically in the range of about pH 12 to about pH 14 and, and typically produce a straight textural configuration that is substantially permanent (i.e., irreversible). Some consumers, however, do not wish to be committed to just one texture and some are increasingly hesitant to risk exposing their hair and scalp to possible damage from such high alkalinity. As such, an alternative to lanthionization relaxers is a chemical keratin reduction-oxidation relaxer process. Conventional commercial reduction-oxidation processes typically reduce the disulfide bonds in the hair with thiol salts, usually ammonium thioglycolate in a viscous medium at an alkalinity typically in the range of about 9 to about 9.5. The reduced hair is mechanically straightened with combing, and then oxidized with hydrogen peroxide or sodium bromate to restore the disulfide bonds in the new straightened configuration. The straightening effect lasts through about three to four shampooings, but generally provides a less permanent straightening effect than that achieved by lanthionization, which damages hair by destroying the natural cysteine groups or disulfide bonds that account for hair's strength, and most of its toughness and abrasion resistance. One attempt to avoid conventional lanthionizing chemical relaxer was a multiple-step, heat-assisted, reduction-oxidation process. The hair was chemically reduced with an ammonium thioglycolate cream composition, shampooed, dried with a hair dryer, mechanically straightened with a heated flat iron set at a temperature of about 200° C., then chemically oxidized with a sodium bromate or hydrogen peroxide lotion, dried with a hair drier, and again mechanically straightened with the heated flat iron. This process, however, was tediously long, taking between four and six hours to complete and chemical damage as well as high heat damage was not avoided.


Various methods are used to measure the efficacy of a hair-styling composition. One method commonly employed to objectively test the efficacy of hair styling compositions involves measuring curl retention under humid conditions. Another method involves semi-permanent hair straightening using a flat iron followed by several wash-out steps. Additional methods of subjective evaluation may be employed that include, for examples: visual and tactile sensory methods (e.g., by visual examination and touching) for characteristics such as appearance (shine, cleanliness, naturalness of appearance and texture), feel (stiffness, tackiness, softness), curl memory (bounce, and restylability), straightness memory (flatness), ease of combing and brushing the hair, residue (flaking), static, smoothness, and the like. Also of importance are the aesthetic characteristics and appearance provided by hair styling compositions before, during, and after application to hair. The product viscosity should be non-runny to avoid dripping during application. The product should be easy to spread, have a smooth texture, a non-tacky feel, and be able to dry relatively quickly on the hair.


Providing hair styling compositions that exhibit good high humidity curl and/or straightness retention while maintaining desirable subjective properties, e.g., smooth texture, curl memory, bounce, naturalness of appearance, etc., has been difficult to achieve with conventional hair-setting compositions. If left untreated, hair often becomes tangled when wet and/or dry such that combing and brushing of the hair is difficult. Furthermore, hair frequently exhibits poor electrostatic properties such that it is susceptible to “scattering”, especially in low humidity environments. In addition, conventional hair straightening and conditioning compositions generally contain man-made chemicals that often leave the hair undesirably harsh, dull, and dry. In addition, conventional hair straightening involves high heat temperatures over 300° F., which undesirably damages hair and other keratinous fibers.


More recently, methods, kits and compositions have been used that allow for hair styling, whether straightening, curling, waving or the like, at temperatures between about 212° F. (100° C.) to about 300 F (about 150° C.). While this is an improvement over the use of harsh chemicals and/or the use of relatively high heat temperatures, it would be advantageous to be able to style hair using even lower heat temperatures.


To address the above and other shortcomings, below are provided compositions, kits, and methods for styling hair and other keratin-based fibers using devices at low temperature, for example, between about 149° F. and about 210° F., or about 160° F. and about 200° F., or about 170° F. and about 180° F. and all sub ranges therebetween, which are capable of providing, among other things, high humidity curl and/or straightness retention, versatility in alternating between straight or curly hairstyles from wash to wash so the end user would not need to touch up the hair between washes, but have the ability to change hair style from curly to straight and vice versa at will with hair washing/shampooing as the reset event. The example embodiments below include compositions and methods for achieving high humidity curl and/straightness retention for wet, damp or dry hair and without coating the hair with film, thereby achieving a benefit of hair feeling weightless. The example embodiments may overcome one or more of the limitations and disadvantages in the art of hair care by providing lower temperature thermal hair straightening and conditioning compositions that can be applied before, and during thermal straightening to render the hair smoother, shinier, softer, and more manageable, to minimize static charge, tangling, and scattering of the hair, such that the hair becomes smooth and straight after application. Further, the styling compositions and processes disclosed herein avoid the deleterious action that can be caused by conventional high heat treatments or highly alkaline lanthionization chemical hair relaxer processes, as readily determined by measured changes in the physical, mechanical integrity of the keratin fibers. Measurable changes in the integrity of the hair include desirable changes in tensile strength properties (increased about 5% to 20%), elasticity, porosity, cuticle erosion, fiber breakage, wet and dry combing force and the like, as well as changes in discernible subjective properties, i.e., tactile feel, and visible sheen or appearance.


As a result, the styling compositions and methods may provide substantially increased body to keratinous fibers, especially human hair; provide better uptake of protein monomers or polymers onto the hair; provide a polymer coating with less flaking; provide a more complete attachment of the resulting polymer to the hair, better protect the hair against uptake of humidity; strengthen damaged hair; resist removal through at least several shampooings; prevent leach out of hair colors; provide for higher loading of polymer into and onto the hair and, therefore, better set retention; protect the hair against thermal damage by completely avoiding high heat damaging temperatures typically used for styling hair (i.e., above about 300° F.) and provide for styling hair at temperatures lower than about 212°.







DESCRIPTION OF EXEMPLARY EMBODIMENTS

To the extent necessary to provide descriptive support, the subject matter and/or text of the appended claims is incorporated herein by reference in their entirety. It will be understood by all readers of this written description that the exemplary embodiments described and claimed herein may be suitably practiced in the absence of any recited feature, element or step that is, or is not, specifically disclosed herein.


Except as otherwise expressly provided, the following rules of interpretation apply to this specification (written description, claims and drawings): (a) all words used herein shall be construed to be of such gender or number (singular or plural) as the circumstances require; (b) the singular terms “a”, “an”, and “the”, as used in the specification and the appended claims include plural references, e.g., these terms may be construed to mean or include “one or more” or “at least one”; (c) the antecedent term “about” applied to a recited range or value denotes an approximation within the deviation in the range or value known or expected in the art from the measurements method; (d) the words “herein”, “hereby”, “hereof”, “hereto”, “hereinbefore”, and “hereinafter”, and words of similar import, refer to this specification in its entirety and not to any particular paragraph, claim or other subdivision, unless otherwise specified; (e) descriptive headings are for convenience only and shall not control or affect the meaning or construction of any part of the specification; and (f) “or” and “any” are not exclusive and “include” and “including” are not limiting. Further, The terms “comprising,” “having,” “including,” and “containing” are to be construed as open-ended terms (i.e., meaning “including, but not limited to,”) unless otherwise noted.


To the extent necessary to provide descriptive support, the subject matter and/or text of the appended claims is incorporated herein by reference in their entirety.


Recitation of ranges of values herein are merely intended to serve as a shorthand method of referring individually to each separate possible value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. Where a specific range of values is provided, it is understood that each intervening value, to a hundredth of the unit of the lower limit unless the context clearly dictates otherwise, between the upper and lower limit of that range and any other stated or intervening value in that stated range, is included therein. All smaller sub ranges are also included. The upper and lower limits of these smaller ranges are also included therein, subject to any specifically excluded limit in the stated range.


Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the relevant art. Although any methods and materials similar or equivalent to those described herein can also be used, acceptable methods and materials are now described.


In a general sense, described herein are aqueous based, keratin-protecting, styling compositions and methods that minimize or eliminate the curl configuration in naturally curly hair (including non-hair keratin-based fibers) by loosening or removing some or all of the natural wave or curl pattern, while substantially retaining desirable properties, e.g., strength and sheen. The styling composition could also assist in imparting a wave or curl pattern to straight hair. The exemplary styling composition contains a cuticle penetrating agent, a fixing agent, and a neutralizing agent, as described below, and other cosmetically acceptable solvents, containing a suitable polymerizable protein, oligomer, peptide, or monomer (e.g., silk peptide or hydrolyzed silk) that is applied onto keratin fibers to modify one or more cosmetic properties of the keratinous fibers and mixtures or combinations thereof. The protein or peptide is polymerized, in-situ, while in contact with the hair to modify at least one hair property, such as body, conditioning, shine, set retention, comb-ability, or the like. The protein, oligomer, peptide or monomer can be polymerized, in-situ, while in contact with hair in any known manner, such as by including an initiator, e.g., a heat-activated initiator, or a polymerization catalyst or fixing agent in the styling composition and processing the composition, such as by heating the composition or keratinous fiber with warm water, blow dryer, heated comb, heated brush (with or without a rotating drum), flat iron, curling iron or other heating means or by use of an accelerator or catalyst, or the like, e.g. mechanical force, ultrasound and other energy imparting tools and means and mixtures or combinations thereof.


In an example embodiment, there is provided hair styling composition capable of imparting a firm and silky look and feel to hair and inhibits frizz. The hair styling composition may be used during hot iron and after hot iron straightening of curly hair to impart a smooth and silky feel to hair. In some embodiments, the hair-styling method exhibits at least semi-permanent hair straightening (or curling) after at least about three wash cycles comprising shampoo and conditioner treatments and after exposure for over about 12 hours to a high humidity environment, conditions including 90% Relative Humidity and a temperature of about 75° F. [24° C.].


Heat-assisted hair styling using relatively lower heat (e.g., below about 210° F. and as low as about 140° F., or from about 200° F. to as low as about 176° F., or from about 190° F. to about 195° F., including all sub ranges therebetween) provides a substantially straightened or curled hair fiber that keeps its styled shape until the next hair washing. Thus, the example styling compositions temporarily remove natural hair curls but permit straightened hair to revert to its original natural curl configuration upon discontinuing use of the styling composition and process, e.g., after washing.


The example styling composition embodiments contain an effective and physiologically tolerable amount of a penetrating agent capable of increasing the permeability of keratin fiber cuticles to allow the styling compositions access to or contact with the keratin protein. Without being bound by any theory, the cuticle layer is expected to have a pH of about 5 and is expected to be affected by higher pH. Hence, the penetrating agent is a base selected from a group of physiologically tolerable basic solutions imparting an initial pH of about 7 to 11, or 8 to about 10, or about 9, and any sub ranges therebetween, on the styling composition, to promote “opening” of the cuticle layers. It is expected that the penetrating agent in the styling compositions provide a starting or initial pH of about 7 to about 11, including all subranges therebetween.


The term “base,” includes chemical species that accept protons, such as carbonate bases and trialkylamines and chemical species that are also electron donors, such as Lewis bases. Suitable examples of bases that may serve as a penetrating agent, include, but are not limited to, potassium hydroxide (KOH), sodium hydroxide (NaOH), calcium hydroxide, lithium carbonate, magnesium carbonate, calcium carbonate, potassium carbonate, potassium bicarbonate, strontium carbonate, lanthanum carbonate, sodium carbonate, sodium bicarbonate, barium hydroxide (Ba(OH)2), caesium hydroxide (CsOH), strontium hydroxide (Sr(OH)2), lithium hydroxide (LiOH), rubidium hydroxide (RbOH), ammonia, urea, acetylurea, guanidine, hydroxyurea, semicarbazide, mono-, di-, or tri(alkyl or aryl)urea (in the case of di(alkyl or aryl)urea the alkyl or aryl groups can be on the same or different nitrogen atoms), mono-, di- or trialkyl or hydroxyalkyl amine, specifically including mono-, di- and triethanolamine, O-methyl hydroxyl amine(methoxylamine), aniline, butylamine, ethylamine, ethylenediamine, hydrazine, and polyamines, including (mono or di)alkylaminoalkylacrylate, and (mono or di)alkylaminoalkylmethacrylate. Suitable trialkylamines include trimethylamine, triethylamine (TEA), tributylamine, triisopropylamine, dimethylethylamine, diisopropylethylamine, diethylmethylamine, dimethylisopropylamine, dimethylbutylamine, and the like and mixtures or combinations thereof. Additional non-limiting suitable examples of organic and inorganic bases may be found on pages 8-37 through 8-39 in the “CRC Handbook of Chemistry and Physics,” 72d Edition, CRC Press, (1992), which is incorporated herein by reference.


Example styling composition embodiments contain an effective amount of a physiologically tolerable neutralizing agent capable of neutralizing the pH of styling compositions. Without being bound by any theory, the neutralization agent is expected to neutralize the base, thereby neutralizing the styling composition and returning the cuticle to its biological pH, which is expected to be around pH 5. At this pH, the cuticle layer is expected to effectively close, and thereby trapping the styling compositions inside the cuticle layer. Suitable neutralizing agents that may be included in the exemplary styling compositions include, but are not limited to, ethyl lactate, propyl lactate, butyl lactate, methyl lactate, ethyl acetate, propyl acetate, butyl acetate, cetyl acetate and the like and mixtures or combinations thereof.


In another aspect, example styling composition embodiments contain an effective styling (e.g., straightening, curling or waving) amount of a physiologically tolerable, fixing agent capable of forming or causing cross-links with proteinaceous hair keratin. The effective amount used includes an amount that is effective to retain hair-styling, such as e.g., straightness retention or curl retention, through at least one or more washing cycles. A suitable fixing agent may be selected from the group consisting of (CH3)2CO (a.k.a. dimethyl ketone, β-ketopropane, propanone, 2-propanone, acetone, etc.), butanone, n-butanol, heptanone, ethanol, t-butanol, and the like. Without wishing to be bound by any theory, it is believed that the fixing agent is, in one aspect, a keratin cross-linking agent of low molecular weight capable of causing relatively fast crosslinking of keratin to form cross-linkages. The fixing agent may be capable of initiating an in-situ polymerization of endogenous and exogenous proteins or peptides that are present on the hair shaft or added to the styling composition. Additionally, the crosslink density or number of cross linkages formed in the keratin network may be affected by other factors including a) the concentration of the cross-linking agent in the fixative solution, b) the pH of the fixative solution, and c) any alteration or change in the physical conditions, such as temperature or pressure. In any event, the fixing agent may be present in the styling composition in an amount of about less than 1% to about 45% by weight, including all subranges therebetween.


Example styling composition embodiments may be applied to wet, damp or dried hair, allowed to remain or sit on the hair for an amount of time ranging from about 15 seconds to about 8 minutes or more, and all subranges therebetween. As described above, relatively low heat (e.g., below about 210° F. and as low as 140° F., or from about 200° F. to as low as about 185° F., or from about 190° F. to about 195° F., including all sub ranges therebetween) is then applied to the treated hair to style it. Without being bound to any theory, the application of low heat to the treated hair activates the fixing agent, or increases the rate of activity of the fixing agent. The low heat may also promote dissociation of the neutralizing agent, leading to the production of an acid and an alcohol, and thereby neutralization of the styling compositions and the cuticle. Continued application of the heat may promote further reactions between the keratin and the fixing agent.


The term “peptide” refers to two or more amino acids, or mixtures/combinations thereof, joined to each other by peptide bonds or modified peptide bonds. The term “hair-binding peptide” refers to peptide sequences that bind with high affinity to hair. The peptide or hair-binding peptides are from about 7 amino acids to about 50 amino acids, optionally from about 7 amino acids to about 25 amino acids, optionally from about 7 to about 20 amino acids in length. The term “amino acid” refers to the basic chemical structural unit of a protein or polypeptide. The following abbreviations are used herein to identify specific amino acids:









TABLE 1







Three-Letter and One-Letter Amino Acid Abbreviations












Three letter
One letter



Amino Acid
abbreviation
abbreviation







Alanine
Ala
A



Arginine
Arg
R



Asparagine
Asn
N



Aspartic acid
Asp
D



Cysteine
Cys
C



Glutamine
Gln
Q



Glutamic acid
Glu
E



Glycine
Gly
G



Histidine
His
H



Isoleucine
Ile
I



Leucine
Leu
L



Lysine
Lys
K



Methionine
Met
M



Phenylalanine
Phe
F



Proline
Pro
P



Serine
Ser
S



Threonine
Thr
T



Tryptophan
Trp
W



Tyrosine
Tyr
Y



Valine
Val
V










It is believed that peptides having high concentrations of glutamic acid and aspartic acid may allow more fixing of exogenous protein and provide for hair repair properties due to a condensation reaction that is believed to take place between the carboxylic acid group of the amino acids compounds and an available amine group found in keratin fibers. Examples of peptides that would have high concentrations of glutamic acid and aspartic acid would be corn, soy, nut and seaweed proteins, as well as Porphyra (sea weed) and mixtures or combinations thereof.


Other suitable monomers include but are not limited to acrylic or methacrylic acid esters of Cx-C18 alcohols, such as methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-methyl-1-propanol, 1-pentanol, 2-pentanol, 3-pentanol, 2-methyl-1-butanol, 1-methyl-1-butanol, 3-methyl-1-butanol, 1-methyl-1-pentanol, 2-methyl-1-pentanol, 3-methyl-1-pentanol, t-butanol, cyclohexanol, neodecanol, 2-ethyl-1-butanol, 3-heptanol, benzyl alcohol, 2-octanol, 6-methyl-1-heptanol, 2-ethyl-1-hexanol, 3,5-dimethyl-1-hexanol, 3,5,5-tri-methyl-1-hexanol, 1-decanol, and the like, the alcohols having from about 1-18 carbon atoms with the average number of carbon atoms being from about 4-12; styrene; polystyrene macromer; vinyl acetate; vinyl chloride; vinylidene chloride; vinyl propionate; alpha-methylstyrene; t-butylstyrene; butadiene; cyclohexadiene; ethylene; propylene; vinyl toluene; and methoxy ethyl methacrylate. The polymers hereof can be homopolymers of such hydro-phobic monomers or can be co-, ter-, etc. polymers of hydrophobic monomers, n-butyl methacrylate, isobutyl methacrylate, 2-ethylhexyl methacrylate, methyl methacrylate, t-butylacrylate, t-butyl ethyacrylate, and mixtures or combinations thereof.


In particular, styling can be achieved within a practical time period. For instances, the hair can be contacted with an exemplary styling composition embodiment for any styling-effective amount of time, as desired, e.g. from about 15 seconds to about 10 minutes or more, from about 1 minute to about 8 minutes, from about 2 minutes to about 6 minutes, or from about 5 minutes to about 10 minutes, and all subranges therebetween. The styling compositions retain the desirable properties of the natural intact hair, such as tensile strength, shine, and softness, and substantially maintain the original, natural color or tone of the hair. The styling compositions can be used in heat-assisted procedures either as the primary or sole style—imparting agent or in conjunction with reduction-oxidation processes. The keratin-protectant styling compositions can beneficially provide the user with the ability to alternate between having a substantially straight hair style and a curly or wavy hair style or vice-versa, as desired, over selected periods of time. The keratin-protectant styling compositions can provide temporary or semi-permanent straightening, curling or waving sufficient to withstand one or more exposures to humidity and perspiration. In one useful aspect, washing treated hair will revert the styled hair to its original natural curl or wave pattern. The heat-assisted styling procedure using the exemplary keratin-protective, styling compositions provides a convenient and easy-to-use system for versatility in styling keratinous fibers, such as human hair. The composition may also contain, but is not limited to, as further exemplified herein, amino acids of human hair keratin, bio-extenders, oligomer elements of marine algae, vitamin-E, silicones, water, fragrance, etc and mixtures or combinations thereof. They may also comprise one or more surfactants, one or more emollients, one or more emulsifiers, one or more skin cleansing agents, one or more preservatives, and/or one or more aqueous based diluents. They may also contain one or more thickeners.


In accordance with one example embodiment, heat is applied to wet, damp or dry hair treated with the styling composition with or without an additional conditioning agent. The heat is applied in amount effective to at least semi-permanently style the hair, and the hair is accordingly styled. An effective amount of heat may be applied by contacting the hair with a Hot Tool at a temperature (e.g., the surface temperature of the portion of the device that contacts the hair) below about 210° F. and as low as about 140° or about 149° F., or from about 200° F. to as low as about 185° F., or from about 190° F. to about 195° F., including all subranges therebetween, for an effective time period (e.g., for at least about 15 seconds). The heat also can be applied for an effective time period, for example, by passing or drawing a device (e.g., a flat iron) through a section of hair (e.g., lengthwise and with a combing motion through the hair while the styling surface of the device remains in contact with at least a portion of the hair during each pass) at an appropriate rate, e.g., for from about 2 seconds to about 10 seconds or more. It will be appreciated that the time period required for contacting the hair with a heat-styling device, to semi-permanently style hair or other keratinous fiber, can depend on a number of factors. Such factors can include, e.g., the nature and extent of chemical treatment on the hair, the type and condition of hair involved, the length of the hair (which, of course, may impact the rate and length of time required for each pass for certain styling devices), the temperature of the device, the nature of the device, and other factors. For example, a suitable heat-styling method for straightening hair includes passing the hair through a flat iron at less than about 200° F. over the hair at least one time for 1-10 seconds per pass.


The styling can include contacting the hair with a shaped surface so as to manipulate the hair to conform to the shape of the surface. If desired, heat can be applied directly to the hair by contacting the hair with a heated shaped surface, which can also be used to style and manipulate the hair to conform to the shape of the surface. Thus, in some embodiments, the shaped surface is heated and the heat is applied to the hair with the shaped surface. If desired, the heat application and styling can be performed simultaneously. Heat can also be applied via an indirect heat source such as, for example, blow dryers, hood dryers, heating caps, steamers, and combinations thereof. In some embodiments, it can be desirable to use a combination of direct and indirect heat sources. When using a shaped surface, a straight surface may be used for straightening hair and a curved surface may be used for curling hair, or a combination of such surfaces may be used, if desired. Optionally, the heat can be applied in multiple stages or passes. Such stages or passes can include applying heat to the hair and styling as described herein at least two times, e.g., so as to apply heat and to manipulate the hair to conform to the shape of a surface with intermediate removal of the heat source between stages or passes. Accordingly, in some embodiments, the heat application and styling are performed two or more times. In other embodiments, the heat application and styling are performed three or more times. For example, when using a flat iron to straightening the hair, two passes of the iron over or against the hair can be performed, and in some instances three passes of the iron over or against the hair can be performed.


Carriers. In example embodiments, the styling composition may comprise a carrier component taken alone or in any suitable combination. Suitable carriers can include, for example, aqueous carriers that can include any suitable quantity of water, e.g., from about 25 wt % to about 95 wt % water, from about 30 wt % to about 95 wt % water, or from about 40 wt % to about 60 wt %, and all subranges therebetween. Suitable carriers can include solvents such as alcohols, polyols, or mixtures thereof. Exemplary alcohols include methanol, ethanol, propanol, and butanol. Exemplary polyols include polyalkyl glycols such as ethylene glycol, propylene glycol, butylene glycol, and glycerine. In some embodiments, the carrier is water alone. In some embodiments, the carriers include aqueous solutions of solvents that can be present in either composition used in accordance with the example methods, e.g. in an amount of from about 25 wt % to about 97 wt % solvent, from about 30 wt % to about 95 wt % solvent, or from about 40 wt % to about 60 wt % solvent and all subranges therebetween.


Conditioning Agents. Suitable conditioning agents may be added, and may include, for example, one or more amphoteric copolymers, one or more amphoteric terpolymers, one or more cationic conditioners and the like, and mixtures or combinations thereof.


Suitable conditioning agents can include amphoteric terpolymers of acrylic acid, diallyl dimethyl ammonium chloride, and acrylamide and mixtures or combinations thereof. The styling composition can include one or more additional conditioning agents in an amount, e.g., from about 0.01 wt % to about 20 wt %, e.g., from about 0.01 wt % to about 15 wt %, or, e.g., from about 0.05 wt % to about 10 wt %. An exemplary conditioning agent is polyquaternium-39. Other exemplary products that may serve as conditioning agents include polyquaternium-4 and/or VP/dimethylaminoethyl methacrylate copolymer 845-G, and the like and mixtures or combinations thereof.


Hair conditioners as herein defined are agents which improve the appearance, texture, and sheen of hair as well as increasing hair body or suppleness. Other suitable hair conditioners, include, but are not limited to, styling aids, hair straightening aids, hair strengthening aids, and volumizing agents, such as nanoparticles and mixtures or combinations thereof. Hair conditioners are well known in the art, see for example Green et al., supra, and are available commercially from various sources. More suitable examples of hair conditioners include, but are not limited to, cationic polymers, such as cationized guar gum, diallyl quaternary ammonium salt/acrylamide copolymers, quaternized polyvinylpyrrolidone and derivatives thereof, and various polyquaternium-compounds; long chain alkyl groups; cationic surfactants, such as stearalkonium chloride, centrimonium chloride, and Sapamin hydrochloride; fatty alcohols, such as behenyl alcohol; fatty amines, such as stearyl amine; waxes; esters; nonionic polymers, such as polyvinylpyrrolidone, polyvinyl alcohol, and polyethylene glycol; silicones; siloxanes, such as decamethylcyclopentasiloxane; polymer emulsions, such as amodimethicone; and nanoparticles, such as silica-nanoparticles and polymer nanoparticles and mixtures of the foregoing or combinations thereof. The suitable hair conditioners contain amine or hydroxyl functional groups to facilitate coupling to the hair-binding peptides, as described below. Examples of suitable conditioners are octylamine (CAS No. 111-86-4), stearyl amine (CAS No. 124-30-1), behenyl alcohol (CAS No. 661-19-8, Cognis Corp., Cincinnati, Ohio), vinyl group terminated siloxanes, vinyl group terminated silicone (CAS No. 68083-19-2), vinyl group terminated methyl vinyl siloxanes, vinyl group terminated methyl vinyl silicone (CAS No. 68951-99-5), hydroxyl terminated siloxanes, hydroxyl terminated silicone (CAS No. 80801-30-5), amino-modified silicone derivatives, [(aminoethyl)amino]propyl hydroxyl dimethyl siloxanes, [(aminoethyl)amino]propyl hydroxyl dimethyl silicones, and alpha-tridecyl-omega-hydroxy-poly(oxy-1,2-ethanediyl) (CAS No. 24938-91-8) and mixtures or combinations thereof.


Examples of other suitable conditioning agents that can be incorporated into the exemplary styling composition include, without limitation: a quaternary ammonium salt (e.g., quaternium-80 (i.e, Siloxanes and Silicones, dimethyl, 3-[3-[(3-coco amidopropyl)dimethylammonio]-2-hydroxypropoxy]propyl group-terminated, acetates (salts)) and the like); polysiloxane polyether copolymers; polysiloxane polydimethyl dimethylammonium acetate copolymers; acetylated lanolin alcohols; dimethyl dialkyl ammonium chlorides; modified alkyl dimethyl benzyl ammonium chlorides; lauryl dimethylamine oxide; stearyl dimethyl benzyl ammonium chloride; a lanolin-derived extract of sterol on sterol esters; lanolin alcohol concentrate; an isopropyl ester of lanolin fatty acids; sulfur rich amino acid concentrates; isopropyl ester of lanolin fatty acids; cetyl trimethyl ammonium chloride; oleyl dimethyl benzyl ammonium chloride; oleyl alcohol; stearyl alcohol; stearamidopropyl dimethyl myristyl acetate; a polyol fatty acid; a fatty amido amine; guar hydroxypropyltrimonium chloride; cetyl/stearyl alcohol; quaternized protein; keratin protein derivatives; isostearamidopropyl dimethylamine; stearamidopropyl dimethylamine; cetrimonium bromide; myrtrimonium bromide; stearalkonium chloride; cetyl trimethyl ammonium chloride; laurylpyridinium chloride; tris(oligoxyethyl)alkyl ammonium phosphate; an amino-functional silicone; lapyrium chloride; isopropyl ester of lanolic acids; ethoxylated (30) castor oil; acetylated lanolin alcohol; fatty alcohol fraction of lanolin; a mineral oil and lanolin alcohol mixture; high molecular weight esters of lanolin; quaternium-75; vinylpyrrolidone/dimethylaminoethylmethacrylate copolymer; alkyl trimethyl ammonium chloride; 5 mole ethylene oxide adduct of soya sterol; 10 mole ethylene oxide adduct of soya sterol; stearic acid ester of ethoxylated (20 mole) methyl glucoside; sodium salt of polyhydroxycarboxylic acid; hydroxylated lanolin; cocamidopropyl dimethylamine lactate; cocamidopropyl dimethylamine propionate; cocamidopropyl morpholine lactate; isostearamidopropyl dimethylamine lactate; isostearamidopropyl morpholine lactate; oleamidopropyl dimethylamine lactate; linoleamidopropyl dimethylamine lactate; stearamidopropyl dimethylamine lactate, ethylene glycol monostearate and propylene glycol mixture; stearamidopropyl dimethylamine lactate; acetamide MEA; lactamide MEA; stearamide MEA; behenalkonium chloride; behenyl trimethyl ammonium methosulfate and cetearyl alcohol mixture; cetearyl alcohol; isostearamidopropalkonium chloride; linoleamidopropalkonium chloride; oleyl dimethyl benzyl ammonium chloride; tallow imidazolinum methosulfate; stearyl trimonium methosulfate; mixed ethoxylated and propoxylated long chain alcohols; stearamidopropyl dimethylamine lactate; polonitomine oxide; oleamine oxide; stearamine oxide; soya ethyldimonium ethosulfate; hydroxypropyl bislauryl dimonium chloride; hydroxypropyl biscetyl dimonium chloride; hydroxypropyl bisstearyl dimonium chloride; hydroxypropyl bisbehenyl dimonium chloride; ricinolamidopropyl ethyldimonium ethosulfate; olealkonium chloride; stearalkonium chloride; N-(3-isostearamidopropyl)-N,N-dimethyl amino glycolate; N-(3-isostearamidopropyl)-N,N dimethyl amino gluconate; hydrolyzed animal keratin; ethyl hydrolyzed animal keratin; stearyl ammonium chloride; stearamidoethyl diethylamine; cocamidopropyl dimethylamine; lauramidopropyl dimethylamine; oleamidopropyl dimethylamine; palmitamidopropyl dimethylamine; stearamidopropyl dimethylamine lactate; avocado oil; sweet almond oil, grape seed oil; jojoba oil; apricot kernel oil; sesame oil; hybrid safflower oil; wheat germ oil; cocamidoamine lactate; ricinoleamido amine lactate; stearamido amine lactate; stearamido morpholine lactate; isostearamido amine lactate; isostearamido morpholine lactate; wheat germamido dimethylamine lactate; behenamidopropyl betaine; ricinoleamidopropyl betaine; wheat germamidopropyl dimethylamine oxide; disodium isostearaimido MEA sulfosuccinate; disodium oleamide PEG-2 sulfosuccinate; disodium oleamide MEA sulfosuccinate; disodium ricinoleyl MEA sulfosuccinate; disodium wheat germamido MEA sulfosuccinate; disodium wheat germamido PEG-2 sulfosuccinate; stearamido amine; stearamido morpholine; isostearamido amine; isostearamido morpholine; polyethylene glycol (400) mono and distearates; synthetic calcium silicate; isostearic alkanolamide; ethyl esters of hydrolyzed animal protein; blend of cetyl and stearyl alcohols with ethoxylated cetyl or stearyl alcohols; amido amines; polyamido amines; palmityl amido betaine; propoxylated (1-20 moles) lanolin alcohols; isostearamide DEA; and hydrolyzed collagen protein and mixtures or combinations thereof. The presence of oligomer-reactive group(s) on any of these conditioning agents allows the conditioning agent to react with the oligomer during in-situ polymerization for incorporation into the polymer.


When one or more of these water-insoluble conditioning agents is included in the styling composition, optionally in an amount of about 0.5% to about 3% by total weight of the composition, the composition also can include a suspending agent for the conditioning agent, in an amount of about 0.5% to about 5%, by total weight of the composition. Such suspending agents also may be useful for suspending solvent-insoluble oligomers. The particular suspending agent is not critical and can be selected from any materials known to suspend water or solvent-insoluble liquids in shampoo compositions. Suitable suspending agents are for example, distearyl amate (distearyl phthalamic acid); fatty acid alkanolamides; esters of polyols and sugars; polyethylene glycols; the ethoxylated or propoxylated alkylphenols; ethoxylated or propoxylated fatty alcohols; and the condensation products of ethylene oxide with long chain amides and mixtures or combinations thereof. These suspending agents, as well as numerous others not cited herein, are well known in the art and are fully described in the literature, such as McCUTCHEON'S DETERGENTS AND EMULSIFIERS, 1989 Annual, published by McCutcheon Division, MC Publishing Co., which is incorporated herein by reference.


Surfactants. Another ingredient which may be included in these hair styling compositions is one or more surfactants in an amount of from about 0.01 wt % to about 20 wt %, from about 0.01 wt % to about 15 wt %, or, from about 0.05 wt % to about 10 wt % of one or more surfactants. Surfactants are surface-active agents that are able to reduce the surface tension of water and cause the product to slip across or onto the skin. Surfactants also include detergents and soap. In one embodiment, the surfactants are amphoteric. Anionic or cationic surfactants may be used as well. Suitable surfactants can include one or more anionic, nonionic, cationic, and amphoteric surfactants, with nonionic, cationic, and amphoteric surfactants and mixtures or combinations thereof. Exemplary surfactants include PPG-5/Ceteth 20, Oleth-20, polysorbate-20, and cocamidopropyl betaine. Other surfactants that may be used comprise, or alternatively include but are not limited to, 3-aminopropane sulfonic acid, almond amide DEA, almond amidopropyl betaine, almond amidopropylamine oxide, aluminum hydrogenated tallow glutamate, aluminum lanolate, aminoethyl sulfate, aminopropyl lauryl glutamine, ammonium C12-15 alkyl sulfate, ammonium C12-15 pareth sulfate, ammonium C12-16 alkyl sulfate, ammonium C9-10 perfluoroalkylsulfonate, ammonium capryleth sulfate, ammonium capryleth-3 sulfate, ammonium cocomonoglyceride sulfate, ammonium coco sulfate, ammonium cocoyl isethionate, ammonium cocoyl sarcosinate, ammonium cumene sulfonate, ammonium dimethicone copolyol sulfate, ammonium dodecylbenzenesulfonate, ammonium isostearate, ammonium laureth sulfate, ammonium laureth-12 sulfate, ammonium laureth-5 sulfate, ammonium laureth-6 carboxylate, ammonium laureth-7 sulfate, ammonium laureth-8 carboxylate, ammonium laureth-9 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myreth sulfate, ammonium myristyl sulfate, ammonium nonoxynol30 sulfate, ammonium nonoxynol-4 sulfate, ammonium oleate, ammonium palm kernel sulfate, ammonium polyacrylate, ammonium stearate, ammonium tallate, ammonium xylene sulfonate, ammonium xylene sulfonate, amp-isostearoyl gelatin/keratin amino acids/lysine hydroxypropyltrimonium chloride, amp-isostearoyl hydrolyzed collagen, apricot kernel oil PEG-6 esters, apricot amide DEA, apricot amidopropyl betaine, arachideth-20, avocadamide DEA, avocadamidopropyl betaine, babassuamide DEA, babassuamidopropyl betaine, babassuamidopropylamine oxide, behenalkonium chloride, behenamide DEA, behenamide MEA, behenamidopropyl betaine, behenamine oxide, behentrimonium methosulfate, behenyl betaine, buteth-3 carboxylic acid, butyl polyglucose, C10-14 alkyl benzenesulfonic acid, Cl 1-15 pareth-12, Cl 1-15 pareth-20, Cl 1-15 pareth-30, Cl 1-15-pareth-40, Cl 1-15 pareth-7 carboxylic acid, Cl 1-15 pareth-9, Cl 1-21-pareth-10, C12-13 pareth-10 phosphate, C12-13 pareth-5 carboxylic acid, C12-13 pareth-7, C12-15 pareth-11, C12-15 pareth-12, C12-15 pareth-2 phosphate, C12-15 pareth-7 carboxylic acid, C12-15 pareth-9, C12-15 pareth-9 hydrogenated tallowate, C14-15 pareth-13, C14-15 pareth-8 carboxylic acid, C22-24 pareth-33, calcium laurate, calcium myristate, canolamidopropyl betaine, caprylyl/capryl glucoside, caprylyl pyrrolidone, carboxymethyl isostearamidopropyl morpholine, cellulose acetate propionate carboxylate, ceteareth-100, ceteareth-15, ceteareth-17, ceteareth-2 phosphate, ceteareth-20, ceteareth-25, ceteareth-25 carboxylic acid, ceteareth-27, ceteareth-30, ceteareth-4 phosphate, ceteareth-40, ceteareth-5 phosphate, ceteareth-50, ceteareth-55, ceteareth-80, cetearyl polyglucose, ceteth-12, ceteth-14, ceteth-15, ceteth-16, ceteth-20, ceteth-24, ceteth-25, ceteth-45, cetethyl morpholinium ethosulfate, cetethyldimonium bromide, cetoleth-15, cetoleth-24, cetoleth-25, cetoleth-6, cetrimonium tosylate, cetyl betaine, cetyl PPG-2 isodeceth-7 carboxylate, cetylpyridinium chloride, cholesteryl/behenyl/octyldodecyl lauroyl glutamate, cocamide, cocamide DEA, cocamide MEA, cocamide MIPA, cocamidoethyl betaine, cocamidopropyl betaine, cocamidopropyl dimethylamine, cocamidopropyl dimethylamine dihydroxymethylpropionate, cocamidopropyl dimethylamine hydrolyzed collagen, cocamidopropyl dimethylamine lactate, cocamidopropyl dimethylamine propionate, cocamidopropyl dimethylaminohydroxypropyl hydrolyzed collagen, cocamidopropyl dimethylammonium C8-16 isoalkylsuccinyl lactoglobulin sulfonate, cocamidopropyl hydroxysultaine, cocamidopropyl lauryl ether, cocamidopropylamine oxide, cocamidopropyldimonium hydroxypropyl hydrolyzed collagen, cocamine oxide, cocaminobutyric acid, cocaminopropionic acid, coceth-4 polyglucose, coceth-7 carboxylic acid, coco/oleamidopropyl betaine, cocoamphodipropionic acid, cocobetainamido amphopropionate, cocobetaine, cocodimonium hydroxypropyl silk amino acids, coco-ethyldimonium ethosulfate, coco-glucoside, coco-hydroxysultaine, coco-morpholine oxide, coconut acid, coco polyglucose, coco-sultaine, cocotrimonium chloride, cocoyl benzyl hydroxyethyl imidazolinium chloride, cocoyl hydrolyzed collagen, cocoyl hydroxyethyl imidazoline, cocoyl sarcosinamide DEA, cocoyl sarcosine, corn acid, cyclopentane carboxylic acid, DEA-C12-15 alkyl sulfate, DEA-cetyl phosphate, DEA-cetyl sulfate, DEA-cocoamphodipropionate, DEA-cyclocarboxypropyloleate, DEA-dodecylbenzenesulfonate, DEA-isostearate, DEA-laureth sulfate, DEA-lauryl sulfate, DEA-methyl myristate sulfonate, DEA-myreth sulfate, DEA-myristate, DEA-myristyl sulfate, DEA-oleth10 phosphate, DEA-oleth-20 phosphate, DEA-oleth-3 phosphate, DEA-oleth-5 phosphate, deceth-4 phosphate, deceth-7 carboxylic acid, decyl betaine, decyl glucoside, decyl polyglucose, decylamine oxide, diammonium dimethicone copolyol sulfosuccinate, diammonium lauramido-MEA sulfosuccinate, diammonium lauryl sulfosuccinate, diammonium oleamido PEG-2 sulfosuccinate, diamyl sodium sulfosuccinate, dicapryl sodium sulfosuccinate, dicetyldimonium chloride, dicocodimonium chloride, dicyclohexyl sodium sulfosuccinate, didecyldimonium chloride, diethanolaminooleamide DEA, diethylamine laureth sulfate, diethylaminoethyl cocoate, diethylaminoethyl PEG-5 cocoate, diethylaminoethyl stearate, diheptyl sodium sulfosuccinate, dihexyl sodium sulfosuccinate, dihydrogenated Cl6-18 amido benzoic acid, dihydrogenated tallow benzylmonium chloride, dihydrogenated tallow methylamine, dihydrogenated tallow phthalate, dihydroxyethyl Cl2-15 alkoxypropylamine oxide, dihydroxyethyl C8-10 alkoxypropylamine oxide, dihydroxyethyl C9-11 alkoxypropylamine oxide, dihydroxyethyl cocamine oxide, dihydroxyethyl lauramine oxide, dihydroxyethyl soya glycinate, dihydroxyethyl stearamine oxide, dihydroxyethyl tallow glycinate, dihydroxyethyl tallowamine HC1, dihydroxyethyl tallowamine oleate, dihydroxyethyl tallowamine oxide, diisobutyl sodium sulfosuccinate, dilaureth-10 phosphate, dilaureth-4 dimonium chloride, dilauryldimonium chloride, dilinoleamidopropyl dimethylamine dimethicone copolyol phosphate, dimethicone propyl PG-betaine, dimethyl cocamine, dinonoxynol-9 citrate, dioctyl sodium sulfosuccinate, dioctyldodeceth-2 lauroyl glutamate, dioctyldodecyl lauroyl glutamate, dioleth-8 phosphate, dipropylene glycol salicylate, disodium bisethylphenyl triaminotriazine stilbenedisulfonate, disodium C12-15 pareth sulfosuccinate, disodium caproamphodiacetate, disodium caproamphodipropionate, disodium capryloamphodiacetate, disodium capryloamphodipropionate, disodium cetearyl sulfosuccinate, disodium cocamido MEAsulfosuccinate, disodium cocamido MIPA-sulfosuccinate, disodium cocamido PEG-3 sulfosuccinate, disodium cocaminopropyl iminodiacetate, disodium cocoamphocarboxyethylhydroxypropylsulfonate, disodium cocoamphodiacetate, disodium cocoamphodipropionate, disodium cocopolyglucose citrate, disodium cocopolyglucose sulfosuccinate, disodium cocoyl butyl glucefh-10 sulfosuccinate, disodium cocoyl glutamate, disodium deceth-5 sulfosuccinate, disodium deceth-6 sulfosuccinate, disodium dicarboxyethyl cocopropylenediamine, disodium dihydroxyethyl sulfosuccinylundecylenate, disodium dimethicone copolyol sulfosuccinate, disodium distyrylbiphenyl disulfonate, disodium hydrogenated cottonseed glyceride sulfosuccinate, disodium hydrogenated tallow glutamate, disodium hydroxydecyl sorbitol citrate, disodium isodecyl sulfosuccinate, disodium isostearamido MEA-sulfosuccinate, disodium isostearamido MIPA-sulfosuccinate, disodium isostearoamphodiacetate, disodium isostearoamphodipropionate, disodium isostearyl sulfosuccinate, disodium laneth-5 sulfosuccinate, disodium lauramido MEA-sulfosuccinate, disodium lauramido PEG-2 sulfosuccinate, disodium lauramido PEG-5 sulfosuccinate, disodium laureth sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium laureth-5 carboxyamphodiacetate, disodium laureth-6 sulfosuccinate, disodium laureth-7 citrate, disodium laureth-9 sulfosuccinate, disodium lauriminodipropionate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, disodium lauryl sulfosuccinate, disodium myristamido MEA-sulfosuccinate, disodium nonoxynol-10 sulfosuccinate, disodium oleamido MEA-sulfosuccinate, disodium oleamido MIPA-sulfosuccinate, disodium oleamido PEG-2 sulfosuccinate, disodium oleoamphodipropionate, disodium oleth-3 sulfosuccinate, disodium oleyl sulfosuccinate, disodium palmitamido PEG-2 sulfosuccinate, disodium palmitoleamido PEG-2 sulfosuccinate, disodium PEG-10 laurylcitrate sulfosuccinate, disodium PEG-4 cocamido MIPA-sulfosuccinate, disodium PEG-8 glyceryl caprylate/caprate, disodium PEG-8 ricinosuccinate, disodium PPG-2-isodeceth-7 carboxyamphodiacetate, disodium ricinoleamido MEA-sulfosuccinate, disodium sitostereth-14 sulfosuccinate, disodium stearamido MEA-sulfosuccinate, disodium steariminodipropionate, disodium stearoamphodiacetate, disodium stearyl sulfosuccinamate, disodium stearyl sulfosuccinate, disodium succinate, disodium succinoyl glycyrrhetinate, disodium tallamido MEA-sulfosuccinate, disodium tallow sulfosuccinamate, disodium tallow amido MEAsulfosuccinate, disodium tallow amphodiacetate, disodium tallow iminodipropionate, disodium tetrapropenyl succinate, disodium tridecylsulfosuccinate, disodium undecylenamido MEA-sulfosuccinate, disodium undecylenamido PEG-2 sulfosuccinate, disodium wheat germamido MEA-sulfosuccinate, disodium wheat germamido PEG-2 sulfosuccinate, disodium wheat germ amphodiacetate, disoyadimonium chloride, disteareth-2 lauroyl glutamate, disteareth-5 lauroyl glutamate, disteareth-6 dimonium chloride, ditallowamidoethyl hydroxypropylamine, ditallowedimonium chloride, diTEA-oleamido PEG-2 sulfosuccinate, di-TEA-palmitoyl aspartate, ditridecyl sodium sulfosuccinate, dodecylbenzene sulfonic acid, dodecylbenzyltrimonium chloride, dodecylxylylditrimonium chloride, dodoxynol-12, dodoxynol-5, dodoxynol-6, dodoxynol-7, dodoxynol-9, erucamidopropyl hydroxysultaine, ethyl butylacetylaminopropionate, ethyl guiazulene sulfonate, ethyl PEG-15 cocamine sulfate, glycol stearate, hexeth-4 carboxylic acid, hydrogenated castor oil, hydrogenated coconut acid, hydrogenated ditallowamine, hydrogenated menhaden acid, hydrogenated tallow amide, hydrogenated tallow betaine, hydrogenated tallowamide DEA, hydrogenated tallowamine, hydrogenated tallowamine oxide, hydrogenated tallowtrimonium chloride, hydrolyzed beeswax, hydroxyceteth-60, hydroxyethyl carboxymethyl cocamidopropylamine, hydroxyethyl cetyldimonium chloride, hydroxyethyl cetyldimonium phosphate, hydroxyethyl hydroxypropyl Cl2-15 alkoxypropylamine oxide, hydroxy ethylbutylamine laureth sulfate, isoceteth-30, isopropanolamine lanolate, isopropyl hydroxycetyl ether, isopropylamine dodecylbenzenesulfonate, isostearamidomorpholine stearate, isostearamidopropyl betaine, isostearamidopropyl morpholine oxide, isostearamidopropylamine oxide, isosteareth11 carboxylic acid, isosteareth-50, isosteareth-6 carboxylic acid, isostearic acid, isostearoyl hydrolyzed collagen, laneth40, laneth-50, laneth-75, lanolinamide DEA, lauramide/myristamide DEA, lauramidopropyl betaine, lauramidopropylamine oxide, (auramine oxide, laureth-1, laureth-10, laureth-10 carboxylic acid, laureth-11 carboxylic acid, laureth-13 carboxylic acid, laureth-14 carboxylic acid, laureth17 carboxylic acid, laureth-2, laureth-20, laureth-23, laureth25, laureth-3, laureth-3 carboxylic acid, laureth-3 phosphate, laureth-30, laureth-4, laureth-4 carboxylic acid, laureth-40, laureth-5, laureth-5 carboxylic acid, laureth-6, laureth-6 carboxylic acid, laureth-6 citrate, laureth-7, laureth-7 citrate, laureth-7 tartrate, laureth-8 phosphate, lauroamphodipropionic acid, lauroyl hydrolyzed collagen, lauroyl sarcosine, lauryl betaine, lauryl hydroxysultaine, lauryl isoquinolinium bromide, lauryl polyglucose, lauryl pyrrolidone, lauryl sultaine, laurylpyridinium chloride, lysine thiazolidine carboxylate, magnesium cocoate, magnesium coco-sulfate, magnesium lanolate, magnesium laureth sulfate, magnesium laureth-11 carboxylate, magnesium laureth-16 sulfate, magnesium laureth-5 sulfate, magnesium laureth-8 sulfate, magnesium lauryl hydroxypropyl sulfonate, magnesium lauryl sulfate, magnesium myreth sulfate, magnesium oleth sulfate, magnesium PEG-3 cocamide sulfate, magnesium tallowate, mannitan oleate, MEA-dicetearyl phosphate, MEA-laureth sulfate, MEA-laureth-6 carboxylate, MEA-lauryl sulfate, MEA-PPG-6-laureth-7-carboxylate, meroxapol 105, meroxapol 108, meroxapol 171, meroxapol 172, meroxapol 174, meroxapol 178, meroxapol 251, meroxapol 252, meroxapol 254, meroxapol 255, meroxapol 258, meroxapol 311, meroxapol 312, meroxapol 314, methoxy-PEG-7 rutinyl succinate, methyl morpholine oxide, methylpyrrolidone, methylbenzethonium chloride, minkamide DEA, minkamidopropyl betaine, minkamidopropyl dimethylamine, minkamidopropylamine oxide, MIPA C12-15 pareth sulfate, MIPA-dodecylbenzenesulfonate, MIPA-laureth sulfate, MIPA-lauryl sulfate, mixed isopropanolamines lanolate, mixed isopropanolamines lauryl sulfate, mixed isopropanolamines myristate, myreth-2 myristate, myreth-3 carboxylic acid, myreth-3 myristate, myreth-5 carboxylic acid, myristamidopropyl betaine, myristamidopropyl dimethylamine dimethicone copolyol phosphate, myristamidopropyl dimethylamine phosphate, myristamidopropylamine oxide, myristamine oxide, myristaminopropionic acid, myristoyl hydrolyzed collagen, myristoyl sarcosine, myristyl/cetyl amine oxide, myristyl betaine, noneth-8, nonoxynol-10 carboxylic acid, nonoxynol-10 phosphate, nonoxynol-100, nonoxynol-11, nonoxynol-12, nonoxynol-13, nonoxynol-14, nonoxynol-15, nonoxynol-18, nonoxynol-2, nonoxynol-20, nonoxynol-23, nonoxynol-30, nonoxynol-4, nonoxynol-40, nonoxynol-44, nonoxynol-5, nonoxynol-5 carboxylic acid, nonoxynol-50, nonoxynol-6, nonoxynol-6 phosphate, nonoxynol-7, nonoxynol-8, nonoxynol-8 carboxylic acid, nonoxynol-9, nonoxynol-9 phosphate, nonyl nonoxynol-10, nonyl nonoxynol-10 phosphate, nonyl nonoxynol-100, nonyl nonoxynol-15 phosphate, nonyl nonoxynol-150, nonyl nonoxynol-24 phosphate, nonyl nonoxynol-49, nonyl nonoxynol-7 phosphate, nonyl nonoxynol-9 phosphate, octeth-3 carboxylic acid, octoxynol-1, octoxynol-10, octoxynol-11, octoxynol-13, octoxynol-16, octoxynol-20 carboxylic acid, octoxynol-3, octoxynol-30, octoxynol-40, octoxynol-5, octoxynol-7, octoxynol-70, octoxynol-8, octoxynol-9, octoxynol-9 carboxylic acid, oleamidopropyl betaine, oleamidopropyl hydroxysultaine, oleamidopropylamine oxide, oleamine oxide, oleoyl hydrolyzed collagen, oleoyl sarcosine, oleth-10, oleth-10 carboxylic acid, oleth-10 phosphate, olethyl2, oleth-15, oleth-16, oleth-2, oleth-20, oleth-20 phosphate, oleth-23, oleth-25, oleth-3 carboxylic acid, oleth-3 phosphate, oleth-4 phosphate, oleth-44, oleth-5 phosphate, oleth 50, oleth-6 carboxylic acid, oleyl betaine, olivamide DEA, olivamidopropyl betaine, olivamidopropylamine oxide, olive oil PEG-10 esters, palm kernelamide DEA, palm kernelamide MEA, palm kernelamide MIPA, palm kernelamidopropyl betaine, palmamide DEA, palmamide MEA, palmamide MIPA, palmamidopropyl betaine, palmitamidopropyl betaine, palmitamidopropylamine oxide, palmitamine oxide, palmitoyl hydrolyzed collagen, palmitoyl hydrolyzed wheat protein, pea ethyl cocoyl arginate, peanutamide MEA, peanutamide MIPA, PEG/PPG-300/55 copolymer, PEG-10 castor oil, PEG-10 cocamine, PEG-10 coco-benzonium chloride, PEG-10 isostearate, PEG-10 soyamine, PEG-10 stearate, PEG-10 stearyl benzonium chloride, PEG-100 castor oil, PEG-100 hydrogenated castor oil, PEG-100 lanolin, PEG-100 stearate, PEG-11 cocamide, PEG-120 glyceryl stearate, PEG-120 stearate, PEG-15 castor oil, PEG-15 cocamine, PEG-15 cocomonium chloride, PEG-15 hydrogenated tallow amine, PEG-15 oleammonium chloride, PEG-15 soyamine, PEG-15 stearmonium chloride, PEG-150 distearate, PEG-150 laurate, PEG-150 oleate, PEG-150 stearate, PEG-16 hydrogenated castor oil, PEG-175 distearate, PEG-2 castor oil, PEG-2 coco-benzonium chloride, PEG-2 cocomonium chloride, PEG-2 hydrogenated tallow amine, PEG-2 oleammonium chloride, PEG-2 sorbitan isostearate, PEG-2 soyamine, PEG-2 stearamide carboxylic acid, PEG-20 castor oil, PEG-20 cocamine, PEG-20 glyceryl isostearate, PEG-20 hydrogenated castor oil, PEG-20 hydrogenated tallow amine, PEG-20 laurate, PEG-20 myristate, PEG-20 oleate, PEG-20 palmitate, PEG-20 sorbitan beeswax, PEG-20 sorbitan isostearate, PEG-20 stearate, PEG-20 tallate, PEG-200 castor oil, PEG-200 glyceryl stearate, PEG-200 glyceryl tallowate, PEG-200 hydrogenated castor oil, PEG-200 trihydroxystearin, PEG-23 oleate, PEG-25 castor oil, PEG-25 diethylmonium chloride, PEG-25 glyceryl stearate, PEG-25 hydrogenated castor oil, PEG-28 glyceryl tallowate, PEG-29 castor oil, PEG-3 castor oil, PEG-3 cocamide, PEG-3 lauramine oxide, PEG-3 oleamide, PEG-30 castor oil, PEG-30 glyceryl cocoate, PEG-30 glyceryl isostearate, PEG-30 glyceryl oleate, PEG-30 glyceryl stearate, PEG-30 hydrogenated castor oil, PEG-30 hydrogenated tallow amine, PEG-30 oleamine, PEG-30 stearate, PEG-32 laurate, PEG-32 oleate, PEG-32 stearate, PEG-33 castor oil, PEG-35 castor oil, PEG-35 hydrogenated castor oil, PEG-35 stearate, PEG-36 castor oil, PEG-36 oleate, PEG-36 stearate, PEG-4 castor oil, PEG-4 laurate, PEG-4 stearamide, PEG-40 castor oil, PEG-40 hydrogenated castor oil, PEG-40 hydrogenated tallow amine, PEG-40 sorbitan diisostearate, PEG-40 sorbitan perisostearate, PEG-40 sorbitan peroleate, PEG-40 sorbitan stearate, PEG-40 sorbitol hexaoleate, PEG-40 stearate, PEG-44 sorbitan laurate, PEG-45 hydrogenated castor oil, PEG-45 stearate, PEG-45 stearate phosphate, PEG-4-PPG-7 C13/C15 alcohol, PEG-5 castor oil, PEG-5 cocamide, PEG-5 ditridecylmonium chloride, PEG-5 glyceryl stearate, PEG-5 hydrogenated castor oil, PEG-5 hydrogenated corn glycerides, PEG-5 soyamine, PEG-5 stearate, PEG-5 stearyl ammonium chloride, PEG-5 stearyl ammonium lactate, PEG-5 tallow benzonium chloride, PEG-50 castor oil, PEG-50 hydrogenated castor oil, PEG-50 stearamine, PEG-50 stearate, PEG-6 cocamide, PEG-6 oleate, PEG-6 palmitate, PEG-6 sorbitan beeswax, PEG-60 castor oil, PEG-60 glyceryl isostearate, PEG-60 hydrogenated castor oil, PEG-60 sorbitan stearate, PEG-66 trihydroxystearin, PEG-7 cocamide, PEG-7 glyceryl cocoate, PEG-7 hydrogenated castor oil, PEG-7 oleate, PEG75 castor oil, PEG-75 dioleate, PEG-75 lanolin, PEG-75 lanolin oil, PEG-75 lanolin wax, PEG-75 laurate, PEG-75 oleate, PEG-75 sorbitan laurate, PEG-75 stearate, PEG-78 glyceryl cocoate, PEG-8 castor oil, PEG-8 laurate, PEG-8 propylene glycol cocoate, PEG-8 ricinoleate, PEG-8 sorbitan beeswax, PEG-8 soyamine, PEG-8 stearate, PEG-80 glyceryl cocoate, PEG-80 hydrogenated castor oil, PEG-80 jojoba acid, PEG-80 jojoba alcohol, PEG-80 sorbitan laurate, PEG80 sorbitan palmitate, PEG-85 lanolin, PEG-9 castor oil, PEG-9 ricinoleate, PEG-90 stearate, pentaerythrityl tetraisostearate, poloxamer 101, poloxamer 105, poloxamer 108, poloxamer 122, poloxamer 123, poloxamer 124, poloxamer 181, poloxamer 182, poloxamer 183, poloxamer 184, poloxamer 185, poloxamer 188, poloxamer 212, poloxamer 215, poloxamer 217, poloxamer 231, poloxamer 234, poloxamer 235, poloxamer 237, poloxamer 238, poloxamer 282, poloxamer 284, poloxamer 288, poloxamer 331, poloxamer 333, poloxamer 334, poloxamer 335, poloxamer 338, poloxamer 401, poloxamer 402, poloxamer 403, poloxamer 407, polyglyceryl-4-PEG-2 cocamide, polysorbate 20, polysorbate 40, polysorbate 60, polysorbate 65, polysorbate 80, polysorbate 85, potassium abietoyl hydrolyzed collagen, potassium C9-15 alkyl phosphate, potassium castorate, potassium cetyl phosphate, potassium cocoate, potassium cocoyl glutamate, potassium cocoyl hydrolyzed collagen, potassium cornate, potassium cyclocarboxypropyloleate, potassium dihydroxyethyl cocamine oxide phosphate, potassium dodecylbenzenesulfonate, potassium laurate, potassium lauroyl collagen amino acids, potassium lauroyl hydrolyzed collagen, potassium lauroyl hydrolyzed soy protein, potassium lauryl hydroxypropyl sulfonate, potassium lauryl sulfate, potassium methyl cocoyl taurate, potassium myristate, potassium myristoyl hydrolyzed collagen, potassium octoxynol-12 phosphate, potassium oleate, potassium oleoyl hydrolyzed collagen, potassium olivate, potassium palmitate, potassium ricinoleate, potassium stearate, potassium stearoyl hydrolyzed collagen, potassium tallowate, potassium toluenesulfonate, potassium undecylenoyl hydrolyzed collagen, potassium xylene sulfonate, PPG-10 cetyl ether, PPG-10 cetyl ether phosphate, PPG-15-PEG-11 hydrogenated lauryl alcohol ether, PPG-17 butyl ether, PPG-20 butyl ether, PPG24 butyl ether, PPG-25 diethylmonium chloride, PPG-3 hydrogenated castor oil, PPG-30-buteth-30, PPG-4 laureth-5, PPG-40 diethylmonium chloride, PPG-50 cetyl ether, PPG5-ceteth-10 phosphate, PPG-5-ceteth-20, PPG-8-ceteth-10, PPG-8-ceteth-20, PPG-9 diethylmonium chloride, propylene glycol soyate, quaternium-14, quaternium-18, quaternium24, quaternium-52, raffinose oleate, rapeseedamidopropyl benzyldimonium chloride, ricinoleamidopropyl betaine, ricinoleth-40, saponins, sesamide DEA, sesamidopropyl betaine, sesamidopropyl dimethylamine, sesamidopropylamine oxide, sodium/MEA laureth-2 sulfosuccinate, sodium/TEA-lauroyl collagen amino acids, sodium/TEAlauroyl hydrolyzed collagen, sodium/TEA-lauroyl hydrolyzed keratin, sodium/TEA-lauroyl keratin amino acids, sodium/TEA-undecylenoyl collagen amino acids, sodium/TEA-undecylenoyl hydrolyzed collagen, sodium behenoyl lactylate, sodium bisglycol ricinosulfosuccinate, sodium butoxynol-12 sulfate, sodium Cl 1-15 pareth-7 carboxylate, sodium C12-13 pareth sulfate, sodium C12-14 olefin sulfonate, sodium C12-15 alkoxypropyl iminodipropionate, sodium C12-15 alkyl sulfate, sodium C12-15 pareth sulfate, sodium C12-15 pareth-15 sulfonate, sodium Cl2-15 pareth-3 sulfonate, sodiumC12-15 pareth-6 carboxylate, sodiumC1215 pareth-7 carboxylate, sodium C12-15 pareth-7 sulfonate, sodium C12-18 alkyl sulfate, sodium C13-17 alkane sulfonate, sodium C14-16 olefin sulfonate, sodiumC14-17 alkyl sec sulfonate, sodium C14-18 olefin sulfonate, sodium C1618 olefin sulfonate, sodium Cl6-20 alkyl sulfate, sodium C8-16 isoalkylsuccinyl lactoglobulin sulfonate, sodium C9-22 alkyl sec sulfonate, sodium caproamphoacetate, sodium caproamphohydroxypropylsulfonate, sodium caproamphopropionate, sodium caprylate, sodium capryleth-2 carboxylate, sodium capryleth-9 carboxylate, sodium capryloamphoacetate, sodium capryloamphohydroxypropylsulfonate, sodium capryloamphopropionate, sodium caprylyl sulfonate, sodium carboxyethyl tallow polypropylamine, sodium carboxymethyl cocopolypropylamine, sodium carboxymethyl oleyl polypropylamine, sodium carboxymethyl tallow polypropylamine, sodium castorate, sodium cetearyl sulfate, sodium ceteth-13 carboxylate, sodium cetyl sulfate, sodium cocaminopropionate, sodium coceth sulfate, sodium coco/hydrogenated tallow sulfate, sodium cocoamphoacetate, sodium cocoamphohydroxypropylsulfonate, sodium cocoamphopropionate, sodium cocoate, sodium cocoglyceryl ether sulfonate, sodium cocomonoglyceride sulfate, sodium cocomonoglyceride sulfonate, sodium cocopolyglucose tartrate, sodium coco-sulfate, sodium cocoyl collagen amino acids, sodium cocoyl glutamate, sodium cocoyl hydrolyzed collagen, sodium cocoyl hydrolyzed keratin, sodium cocoyl hydrolyzed rice protein, sodium cocoyl hydrolyzed soy protein, sodium cocoyl hydrolyzed wheat protein, sodium cocoyl isethionate, sodium cocoyl lactylate, sodium cocoyl sarcosinate, sodium comamphopropionate, sodium cumenesulfonate, sodium cyclopentane carboxylate, sodium deceth sulfate, sodium deceth-2 carboxylate, sodium decylbenzenesulfonate, sodium dicarboxyethylcoco phosphoethyl imidazoline, sodium diethylaminopropyl cocoaspartamide, sodium dihydroxycetyl phosphate, sodium dilaureth-7 citrate, sodium dodecylbenzenesulfonate, sodium ethyl 2-sulfolaurate, sodium glycereth-1 polyphosphate, sodium glyceryl oleate phosphate, sodium guiazulene sulfonate, sodium hydrogenated tallow glutamate, sodium isostearoamphoacetate, sodium isostearoamphopropionate, sodium laneth sulfate, sodium lauramido diacetate, sodium lauramidopropyl hydroxyphostaine, sodium lauraminopropionate, sodium laurate, sodium laureth sulfate, sodium laureth-11 carboxylate, sodium laureth-12 sulfate, sodium laureth-13 carboxylate, sodium laureth-14 carboxylate, sodium laureth-17 carboxylate, sodium laureth-4 carboxylate, sodium laureth-4 phosphate, sodium laureth-5 carboxylate, sodium laureth-5 sulfate, sodium laureth-6 carboxylate, sodium laureth-7 sulfate, sodium laureth-7 tartrate, sodium laureth-8 sulfate, sodium lauriminodipropionate, sodium lauroampho PG-acetate phosphate, sodium lauroamphoacetate, sodium lauroamphohydroxypropylsulfonate, sodium lauroyl aspartate, sodium lauroyl glutamate, sodium lauroyl hydrolyzed collagen, sodium lauroyl isethionate, sodium lauroyl methylaminopropionate, sodium lauroyl sarcosinate, sodium lauroyl taurate, sodium lauryl phosphate, sodium lauryl sulfate, sodium lauryl sulfoacetate, sodium lignosulfonate, sodium methyl 2-sulfolaurate, sodium methyl cocoyl taurate, sodium methyl lauroyl taurate, sodium methyl myristoyl taurate, sodium methyl oleoyl taurate, sodium methyl palmitoyl taurate, sodium methyl stearoyl taurate, sodium methylnaphthalenesulfonate, sodium myreth sulfate, sodium myristate, sodium myristoamphoacetate, sodium myristoyl glutamate, sodium myristoyl isethionate, sodium myristoyl sarcosinate, sodium myristyl sulfate, sodium nonoxynol-1 sulfate, sodium nonoxynol-10 sulfate, sodium nonoxynol-4 sulfate, sodium nonoxynol-6 phosphate, sodium nonoxynol-9 phosphate, sodium octoxynol-2 ethane sulfonate, sodium octyl sulfate, sodium oleate, sodium oleoamphoacetate, sodium oleoamphohydroxypropylsulfonate, sodium oleoamphopropionate, sodium oleoyl isethionate, sodium oleth-7 phosphate, sodium oleth-8 phosphate, sodium olivate, sodium palm kernelate, sodium palmate, sodium palmitate, sodium PEG-6 cocamide carboxylate, sodium polydimethylglycinophenolsulfonate, sodium polynaphthalenesulfonate, sodium polystyrene sulfonate, sodium ricinoleoamphoacetate, sodium shale oil sulfonate, sodium soya hydrolyzed collagen, sodium stearate, sodium stearoamphoacetate, sodium stearoamphopropionate, sodium stearyl betaine, sodium stearyl sulfate, sodium tallamphopropionate, sodium tallow sulfate, sodium tallowamphoacetate, sodium tallowate, sodium toluenesulfonate, sodium trideceth sulfate, sodium trideceth-12 carboxylate, sodium trideceth-3 carboxylate, sodium trideceth-6 carboxylate, sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium tridecyl sulfate, sodium tridecylbenzenesulfonate, sodium trilaureth-4 phosphate, sodium undecylenoamphoacetate, sodium undecylenoamphopropionate, sodium wheat germamphoacetate, sodium xylenesulfonate, soya hydroxyethyl imidazoline, soyamide DEA, soyamidopropyl betaine, soyamidopropyl dimethylamine, soyamidopropyl ethyldimonium ethosulfate, soytrimonium chloride, stearamidopropyl betaine, stearamidopropyl dimethylamine, stearamidopropylamine oxide, stearamine oxide, steareth-10, steareth-100, steareth-2, steareth-20, steareth21, steareth-25, steareth-27, steareth-30, steareth-40, steareth-50, stearoyl sarcosine, stearyl betaine, sucrose laurate, sucrose palmitate, sulfated castor oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sulfonated castor oil, tallow amide, tallow amine, tallow betaine, tallow dihydroxyethyl betaine, tallow hydroxyethyl imidazoline, tallowalkonium chloride, tallowamidopropyl betaine, tallowamidopropyl dimethylamine, tallowamidopropyl hydroxysultaine, tallowamidopropylamine oxide, tallowamine oxide, tallowedimonium propyltrimonium dichloride, tallowtrimonium chloride, TEA-abietoyl hydrolyzed collagen, TEA-C 10-12 alkyl sulfate, TEA-C 10-14 alkyl benzenesulfonate, TEA-C 10-15 alkyl sulfate, TEA-C12-15 alkyl sulfate, TEAcocoate, TEA-coco-sulfate, TEA-cocoyl glutamate, TEA-cocoyl hydrolyzed collagen, TEA-cocoyl sarcosinate, TEAdodecylbenzenesulfonate, TEA-hydrogenated tallow glutamate, TEA-isostearate, TEA-isostearoyl hydrolyzed collagen, TEA-lauraminopropionate, TEA-laureth sulfate, TEA-lauroyl collagen amino acids, TEA-lauroyl glutamate, TEA-lauroyl hydrolyzed collagen, TEA-lauroyl keratin amino acids, TEA-lauroyl lactylate, TEA-lauroyl sarcosinate, TEA-lauryl sulfate, TEA-myristaminopropionate, TEA-myristate, TEA-myristoyl hydrolyzed collagen, TEAoleate, TEA-oleoyl hydrolyzed collagen, TEA-oleoyl sarcosinate, TEA-oleyl sulfate, TEA-palm kernel sarcosinate, TEA-palmitate, TEA-PEG-3 cocamide sulfate, TEA-stearate, TEA-tallate, TEA-tridecylbenzenesulfonate, TEA-undecylenoyl hydrolyzed collagen, tetrasodium dicarboxyethyl stearyl sulfosuccinamate, TIPA-laureth sulfate, TIPA-lauryl sulfate, TIPA-stearate, tocophereth-10, tocophereth-12, tocophereth-18, tocophereth-5, tocophereth-50, toluene sulfonic acid, triceteareth-4 phosphate, triceteth-5 phosphate, trideceth-12, trideceth-15 carboxylic acid, trideceth-19 carboxylic acid, trideceth-3 carboxylic acid, trideceth-4 carboxylic acid, trideceth-6, trideceth-6 phosphate, trideceth-7 carboxylic acid, trideceth-8, tridecylbenzenesulfonic acid, triheptanoin, trilauryl phosphate, triolein PEG-6 esters, trisodium lauroampho PG-acetate phosphate chloride, tristearyl phosphate, undecyl polyglucose, undecylenamidopropyl betaine, undecylenamidopropylamine oxide, undecylenoyl wheat amino acids, wheat germamide DEA, wheat germamidopropyl betaine, wheat germamidopropyl dimethylamine, wheat germamidopropyl dimethylamine lactate, wheat germamidopropylamine oxide, xylene sulfonic acid, and zinc pentadecene tricarboxylate and mixtures or combinations thereof.


Emollients. A further ingredient of the exemplary styling compositions are one or more emollients. As defined herein, an “emollient” is a material that protects against wetness or irritation, softens, soothes, supples, coats, lubricates, moisturizes, protects and/or cleanses the skin. Suitable emollients comprise one or more of: a silicone compound (e.g., dimethicone, cyclomethicone, dimethicone copolyol or a mixture of cyclopentasiloxane and dimethicone/vinyldimethicone cross polymer, cyclopentasiloxane polysilicone), polyols such as sorbitol, glycerin, propylene glycol, ethylene glycol, polyethylene glycol, caprylyl glycol, polypropylene glycol, 1,3-butane diol, hexylene glycol, isoprene glycol, xylitol; ethylhexyl palmitate; a triglyceride such as caprylic/capric triglyceride and fatty acid ester such as cetearyl isononanoate or cetyl palmitate. In a specific embodiment, the emollient is dimethicone, amidodimethicone, dimethiconol, cyclopentasiloxane, potassium dimethicone PEG-7 panthenyl phosphate, cetearyl isononanoate and/or cetyl palmitate and mixtures or combinations thereof. The emollient generally comprises from about 0.5% to about 15% and optionally about 1% to about 10% by weight or more of the hair styling compositions.


Emulsifiers. The styling formulations may also comprise one or more emulsifiers. Suitable emulsifiers comprise a copolymer of an unsaturated ester and styrene sulphonate monomer, cetearyl alcohol, glyceryl ester, polyoxy ethylene glycol ether of cetearyl alcohol, stearic acid, polysorbate-20, ceteareth-20, lecithin, glycol stearate, polysorbate-60 and/or polysorbate-80 and mixtures or combinations thereof. The emulsifier(s) generally comprises from about 0.05-15% by weight and optionally from about 0.1-10% by weight or more of the styling formulations.


Preservatives. One or more preservatives may be included in the hair styling compositions. Examples of such preservatives include one or more glycerin containing compound (e.g., glycerin or ethylhexylglycerin or phenoxyethanol), benzyl alcohol, EDTA, potassium sorbate and/or grapefruit seed extract and mixtures or combinations thereof. The preservative(s) generally comprises from about 0.1-5% by weight and optionally from about 0.3-3% by weight of the hair styling compositions. In another example embodiment, the hair styling compositions are paraben free. The preservative(s) generally comprises from 0.05-15% by weight and optionally from about 0.1-10% by weight or more of the hair styling compositions.


Skin Protecting Agents. The hair styling compositions comprise one or more skin protecting agents. Skin protecting agents comprise one or more agents that prevent the transmission of microbes (e.g., include antibacterial agents), skin cleansing agents (e.g. disinfectants and antiseptic agents) and sunscreen agents and mixtures or combinations thereof. Skin cleansing agents used in the hair styling compositions comprise sodium cocyl amino acids, benzalkonium chloride and/or centrimonium chloride. The skin protecting agent(s) generally comprises from about 0.1-10% by weight or more or more and optionally from about 0.5-5% by weight of the formulations.


Diluents. The term “diluent” as used herein refers to substances that may be used to dilute the active ingredient, the keratin protein fraction and keratin cross-linking agent. Water is an acceptable diluent. The formulations require use of greater than 1% water to be effective. Advantageously, greater than five percent water is used, and optionally, greater than 50%, and even optionally, greater than 80% water is used. Alcohols such as ethyl alcohol and isopropyl alcohol may be used at low concentrations (about 0.5%) to enhance shaft penetration and reduce odor. High concentrations (about 35% and greater) of alcohols are not suitable as they disrupt the effectiveness of the formulations.


Auxiliary Ingredients. The hair styling compositions also comprise one or more thickeners, particularly, when the formulation is in the form of a cream, lotion, mask or gel. Such thickeners comprise polyethylene glycol and/or sodium polyacrylate. The thickeners may be present in an amount of about 0.1-5% by weight and optionally in the amount of about 0.2-1% by weight.


Fragrances may also be added to mask the odor of various other components in the formulation of example embodiments. Examples of such fragrances include but are not limited to caramel, vanilla. The thickener(s) may be present in an amount of about 0.1-10% by weight or more and optionally in the amount of about 0.5-5% by weight.


The hair styling compositions may also contain conventional cosmetic hair conditioning ingredients, botanical products, and other optional cosmetic ingredients, additives, products or materials, and cosmetic adjuvants, well known in the hair care and personal care formulation arts, such as an auxiliary hair protectant, heat protective ingredient, such as a silicone or silicone derivative and mixtures or combinations thereof.


A non-exhaustive list of constituents that may be contained in exemplary styling compositions include those listed in Table 2 and mixtures or combinations thereof:










TABLE 2





CONSTITUENT (INCI Name)
Other Chemical Name







2-AMINOBUTANOL
2-aminobutan-1-ol


2-BROMO-2-NITRO-PROPANE-
Bronopol


1,3-DIOL


2-NITRO-p-PHENYLENE-DIAMINE
2-nitro-p-phenylenediamine (CI 76070)


2-OLEAMIDO-1,3-OCTA-
1,3-octadecanediol, 2-oleamido-


DECANEDIOL



ACER SACCHARINUM

Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Acer saccharinum


ACETAMIDE MEA
N-2-hydroxyethylacetamide


ACETYLATED LANOLIN
Lanolin, acetate


ACETYLATED LANOLIN ALCOHOL
Acetic acid, esters with lanolin alcs



ACHILLEA MILLEFOLIUM

Yarrow, Achillea millefolium, ext.



Extractives and their physically modified derivatives



such as tinctures, concretes, absolutes, essential



oils, oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from Achillea




millefoliu



ACRYLATES/ACRYLA-MIDE
Propenamide, polymer with propenoic acid,


COPOLYMER
butenoic acid, and/or alkyl propenoates


ACRYLATES/C10-30 ALKYL
C10-C30 alkyl propenoate, polymer with propenoic


ACRYLATE CROSSPOLYMER
acid, butenoic acid and/or alkyl propenoates,



product with propenyl sucrose ether or propenyl



2,2-dihydroxymethyl-1,3-propanediol


ACRYLATES/DIMETHICONE


COPOLYMER


ACRYLATES/PVP
2-propenoic acid, 2-methyl-, polymer with 1-


COPOLYMER
ethenyl-2-pyrrolidinone and ethyl 2-methyl-2-



propenoate


ACRYLATES/STEARETH-20
Stearyl alcohol, product with oxirane, butenoate


METHACRYLATE COPOLYMER
ester, polymer with propenoic acid, butenoic acid,



and/or alkyl propenoates


ACRYLATES/t-BUTYL-


ACRYLAMIDE COPOLYMER


ACRYLATES COPOLYMER
2-propenoic acid, 2-methyl-, polymer with ethyl 2-



propenoate and methyl 2-methyl-2-propenoate



ACTINIDIA CHINENSIS


Actinidia chinensis, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc., obtained from Actinidia chinensis,



Actinid



AESCULUS HIPPOCAS-TANUM

Horse chestnut, Aesculus hippocastanum, ext.



Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Aesculus


ALANINE
L-alanine, DL-alanine


ALGAE


ALLANTOIN
Allantoin



ALOE BARBADENSIS


Aloe vera, ext. Extractives and their physically




modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Aloe vera, Liliaceae



ALTHEA OFFICINALIS

Marshmallow (Althaea officinalis), ext. Extractives



and their physically modified derivatives such as



tinctures, concretes, absolutes, essential oils,



oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from Althaea




offici



ALUMINUMDISTEARATE
Hydroxyaluminium distearate


AMINOMETHYL
2-amino-2-methylpropanol


PROPANOL


AMMONIUM BENZOATE 1863-63-4
Ammonium benzoate


AMMONIUM HYDROXIDE
Ammonia, aqueous solution


AMMONIUM LAURYL SULFATE
Ammonium dodecyl sulphate


AMODIMETHICONE


AMODIMETHICONECETRIUM


CHLORIDE


AMP-ISOSTEAROYL HYDROLYZED
Protein hydrolyzates, wheat gluten, isostearoyl-,


WHEAT PROTEIN
product 2-amino-2-methylpropanol



ANTHEMIS NOBILIS


Anthemis nobilis, ext. Extractives and their




physically modified derivatives such as



tinctures, concretes, absolutes, essential



oils, oleoresins, terpenes, terpene-free



fractions, distillates, residues, etc.,



obtained from Anthemis nobilis,



Compositae


AQUA
Water


ARGININE
Arginine, DL-arginine


ASCORBIC ACID
Ascorbic acid


BASIC BLUE 9
Methylthioninium chloride (CI 52015)


BASIC BLUE 99
3-[(4-amino-6-bromo-5,8-dihydro-1-hydroxy-8-



imino-5-oxo-2-naphtyl)amino]-N,N,N-



trimethylanilinium chloride (CI 56059)


BASIC BROWN 16
[8-[(p-aminophenyl)azo]-7-hydroxy-2-



naphthyl]trimethylammonium chloride (CI 12250)


BASIC BROWN 17
[8-[(4-amino-2-nitrophenyl)azo]-7-hydroxy-2-



naphthyl]trimethylammonium chloride (CI 12251)


BASIC RED 2
3,7-diamino-2,8-dimethyl-5-phenyl-



phenazinium chloride (CI 50240)


BASIC RED 76
[7-hydroxy-8-[(2-methoxyphenyl)azo]-2-



naphthyl]trimethylammonium chloride (CI 12245)


BASIC VIOLET 14
(4-(4-aminophenyl)(4-iminocyclohexa-2,5-



dienylidene)methyl)-2-methylanilinehydro-



chloride(CI42510)


BASIC YELLOW 57
3-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-



4-yl)azo]-N,N,N-trimethylanilinium chloride (CI



12719)


BEESWAX ACID
Fatty acids, beeswax


BEHENTRIMONIUM
Docosyltrimethylammonium chloride


CHLORIDE


BEHENTRIMONIUM
Docosyltrimethylammonium methyl sulphate


METHOSULFATE


BENZALKONIUM CHLORIDE
Quaternary ammonium compounds,



benzyl-C8-18-alkyldimethyl, chlorides


BENZOIC ACID
Benzoic acid


BENZOPHENONE-2
2,2′,4,4′-tetrahydroxybenzophenone


BENZOPHENONE-3
Oxybenzone


BENZOPHENONE-4
Sulisobenzone


BENZYL ALCOHOL
Benzyl alcohol



BERTHOLLETIA EXCELSA



BETAINE
Betaine


BHA
Tert-butyl-4-methoxyphenol


BHT
2,6-di-tert-butyl-P-cresol


BISABOLOL
(R*,R*)-a, 4-dimethyl-a-(4-methyl-3-



pentenyl)cyclohex-3-ene-1-methanol


BUTANE
Butane


BUTYL ESTER OF ETHYLENE/


MA COPOLYMER


BUTYL ESTER OF PVM/MA
2-butenedioic acid (Z)-, polymer with


COPOLYMER
methoxyethene, monobutyl ester


BUTYL METHOXYDI-
1-[4-(1,1-dimethylethyl)phenyl]-3-(4-


BENZOYLMETHANE
methoxyphenyl)propane-1,3-dione


BUTYLENE GLYCOL
Butane-1,3-diol


BUTYLPARABEN
Butyl 4-hydroxybenzoate



BUXUS CHINENSIS

Jojoba, ext. Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Simmondsia chinensis N.,



Buxaceae; Extrac


C12-15 ALKYL BENZOATE
Benzoic acid, C12-15-alkyl esters


C13-14 ISOPARAFFIN
Alkanes, iso-, C13-14


C18-36 ACID GLYCOL ESTER
Fatty acids, C18-36, esters with ethylene glycol


C9-11 PARETH-8
Alcohols, C9-11, ethoxylated


CALCIUM CARBONATE
Calcium carbonate


CALCIUM HYDROXIDE
Calcium dihydroxide


CALCIUM PANTOTHENATE
Calcium pantothenate, D-form; Calcium (.+−.)-N-



(2,4-dihydroxy-3,3-dimethyl-1-oxobutyl)-a-



alaninate



CALENDULA


Calendula officinalis, ext. Extractives and their




OFFICINALIS

physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc., obtained from Calendula




officinalis, Com




CAMELIA OLEIFERA

Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Camelia oleifera



CAMELIA SINENSIS

Tea, ext. Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Thea chinensis, Theaceae



CANANGA ODORATA

Ylang-ylang, ext. Extractives and their physically



modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Cananga odorata, Annonaceae


CANDELILLA CERA
Candelilla wax. The wax from Euphorbia




antisiphylitica or Pedilanthus pavonis,




Euphorbiaceae


CAPRYLIC/CAPRIC/STEARIC
Octadecanoic acid, mixed triesters with octanoic


TRIGLYCERIDE
acid, decanoic acid and 1,2,3-propanetriol


CAPRYLIC/CAPRIC
Glycerides, mixed decanoyl and octanoyl


TRIGLYCERIDE


CAPRYLYL PYRROLIDONE
Pyrrolidone, N-octyl-


CARAMEL
Caramel (color). The substance obtained by



controlled heat treatment of food-grade



carbohydrates. Food-grade acids, alkalies, and



salts may be used to assist carmelization. Food-



grade antifoaming agents may be used in an



amount not greater than that re


CARBOMER
Carbomer


CARBOMER 940


CARNAUBA
Carnauba wax. The wax derived from




Copernicia cerifera, Palmae




CARTHAMUS

Safflower oil. Extractives and their physically



TINCTORIUS

modified derivatives. It consists primarily of the



glycerides of the fatty acid linoleic. (Carthamus




tinctorius, Compositae); Extractives and their




physically modified derivatives such as tinctures,



concrete


CELETH-20


CERA ALBA
Beeswax. The wax obtained from the honeycomb of



the bee. It consists primarily of myricyl palmitate,



cerotic acid and esters and some high-carbon



paraffins


CERA MICROCRISTALLINA
Paraffin waxes and Hydrocarbon waxes,



microcryst. A complex combination of long,



branched chain hydrocarbons obtained from



residual oils by solvent crystallization. It consists



predominantly of saturated straight and branched



chain hydrocarbons predomina


CERAMIDE 2


CERESIN
Ceresin. A complex combination of hydrocarbons



produced by the purification of ozocerite with



sulfuric acid and filtration through bone black to



form waxy cakes



CEREUS GRANDIFLORUS


Selenicereus grandiflorus, ext. Extractives and




their physically modified derivatives such as



tinctures, concretes, absolutes, essential oils,



oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from



Selenicereus grandiflo


CETEARETH-12


CETEARETH-20


CETEARETH-25


CETEARETH-30


CETEARETH-6


CETEARYL ALCOHOL
Alcohols, C16-18. This substance is identified by



SDA Substance Name: C16-C18 alkyl alcohol



and SDA Reporting Number: 19-060-00


CETEARYL OCTANOATE
Hexanoic acid, 2-ethyl-, C16-18-alkyl esters


CETETH-20
brij 58, britex c200, hetoxol ca-20, lipocol c-20, peg-



20 cetyl ether, polyethylene glycol (20) cetyl ether,



polyoxyethylene(20) cetyl alcohol ether,



polyoxyethylene (20) cetyl ether, poly(oxy-1,2-



ethanediyl)


CETRIMONIUM BROMIDE
Cetrimonium bromide


CETRIMONIUM CHLORIDE
Cetrimonium chloride


CETYL ACETATE
Hexadecyl acetate


CETYL ALCOHOL
Hexadecan-1-ol



CHAMOMILLA RECUTITA


Matricaria recutita, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc., obtained from Matricaria recutita,



Composi


CHITOSAN
Chitin, deacylated


CHITOSAN FORMATE


CHITOSAN PCA
pyrrolidonecarboxylic acid salt


CHLOROACETAMIDE
2-chloroacetamide


CHLORPHENESIN
Chlorphenesin


CHOLESTEROL
Cholesterol


CI 15510
Sodium 4-[(2-hydroxy-1-



naphthyl)azo]benzenesulphonate; Benzenesulfonic



acid, 4-[(2-hydroxy-1-naphthalenyl)azo]-, Al-lake


CI 15985
Disodium 6-hydroxy-5-[(4-sulphonato-



phenyl)azo]naphthalene-2-sulphonate; Aluminum,



6-hydroxy-5-(4-sulfophenyl)azo2-



naphthalenesulfonic acid complex. This substance



is identified in the Colour Index by Colour Index



Constitution Number, C.I. 159


CI 16035
Disodium 6-hydroxy-5-[(2-methoxy-4-sulphonato-



m-tolyl)azo]naphthalene-2-sulphonate


CI 16185
Trisodium 3-hydroxy-4-(4′-sulphonatonaphthylazo)naphthalene-



2,7-disulphonate;



Aluminum, 3-hydroxy-4-(4-sulfo-1-



naphthalenyl)azo-2,7-naphthalenedisulfonic acid



complex. This substance is identified in the Colour



Index by Colour Index Consti


CI 17200
Disodium 5-amino-4-hydroxy-3-



(phenylazo)naphthalene-2,7-disulphonate; 2,7-



naphthalenedisulfonic acid, 5-amino-4-hydroxy-3-(3-



phenylazo)-, Al-lake


CI 18050
Disodium 5-acetylamino-4-hydroxy-3-



(phenylazo)naphthalene-2,7-disulphonate


CI 19140
Trisodium 5-hydroxy-1-(4-sulphophenyl)-4-(4-



sulphophenylazo)pyrazole-3-carboxylate; Aluminum,



4,5-dihydro-5-oxo-1-(4-sulfo-phenyl)-4-(4-



sulfophenyl)azo-1H-pyrazole-3-carboxylic acid



complex. This substance is identified in the Colour


CI 42051
Bis[hydrogen [4-[4-(diethylamino)-5′-hydroxy-2′,



4′-



disulphonatobenzhydrylidene]cyclohexa-2,5-dien-



1-ylidene]diethylammonium], calcium salt


CI 42090
Diammonio(ethyl)[4-[[4-[ethyl(3-



sulphonatobenzyl)amino]phenyl](2-



sulphonatophenyl)methylene]cyclohexa-2,5-dien-



1-ylidene](3-



sulphonatobenzyl)ammonium; Dihydrogen (ethyl)[4-



[4-[ethyl(3-sulphonato-benzyl)]amino]-2′-



sulphonato-benzhydrylidene]cy


CI 42520
4-[(4-amino-m-tolyl)(4-imino-3-



methylcyclohexa-2,5-dien-1-



ylidene)methyl]-o-toluidine



monohydrochloride


CI 42600


CI 42735
Hydrogen [4-[[4-(diethylamino)phenyl][4-[ethyl[(3-



sulphonatobenzyl)amino]-o-tolyl]methylene]-3-



methylcyclohexa-2,5-dien-1-ylidene](ethyl)(3-



sulphonatobenzyl)ammonium, sodium salt


CI 47000
1,3-Isobenzofurandione, reaction products with



methylquinoline and quinoline. This substance is



identified in the Colour Index by Colour Index



Constitution Number, C.I. 47000


CI 47005
Aluminum, 2-(1,3-dihydro-1,3-dioxo-2H-inden-2-



ylidene)-1,2-dihydro-6,7-quinolin-edisulfonate



complexes


CI 60725
1-hydroxy-4-(p-toluidino)anthraquinone


CI 60730
Sodium 4-[(9,10-dihydro-4-hydroxy-9,10-dioxo-1-



anthryl)amino]toluene-3-sulphonatecolorants


CI 61565
1,4-bis(p-tolylamino)anthraquinone


CI 61570
Disodium 2,2′-(9,10-dioxoanthracene-1,4-



diyldiimino)bis(5-methylsulphonate)


CI 69800
6,15-dihydroanthrazine-5,9,14,18-tetrone


CI 77491
Diiron trioxide


CI 77492
Iron oxide


CI 77499
Triiron tetraoxide


CI 77891
Titanium dioxide


CI 77947
Zinc oxide


CINNAMIDOPROPYL


TRIMONIUM CHLORIDE



CINNAMOMUM CAMPHORA



CITRIC ACID
Citric acid



CITRUS AURANTIFOLIA


Citrus limetta, ext. Extractives and their physically




modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Citrus limetta, Rutaceae



CITRUS AURANTIUM DULCIS




CITRUS DULCIS

Orange, sweet, ext. Extractives and their physically



modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Citrus sinensis, Rutaceae



CITRUS GRANDIS

Grapefruit, ext. Extractives and their physically



modified derivatives such as



tinctures, concretes, absolutes, essential oils,



oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc.,



obtained from Citrus paradisi M., Rutaceae



CITRUS LIMONUM

Lemon, ext. Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Citrus limonum, Rutaceae


COCAMIDE DEA
Amides, coco, N,N-bis(hydroxyethyl)


COCAMIDOPROPYL BETAINE
1-Propanaminium, 3-amino-N-(carboxy-methyl)-



N,N-dimethyl-, N-coco acyl derivs., hydroxides,



inner salts


COCAMIDOPROPYL
1-Propanaminium, N-(3-aminopropyl)-2-hydroxy-


HYDROXYSULTAINE
N,N-dimethyl-3-sulfo-, N-coco acyl derivs.,



hydroxides, inner salts


COCAMIDOPROPYL PG-DIMONIUM
Phosphoric acid, triester with N-(2,3-dihydroxypropyl)-


CHLORIDE PHOSPHATE
N,N-dimethyl-3-[(1-oxococoalkyl)amino-



1-propanaminium chloride


COCO-BETAINE
Betaines, coco alkyldimethyl


COCO-CAPRYLATE/CAPRATE
Alcohols, coco, mixed esters with octanoic and



decanoic acids


COCODIMONIUM HYDROXYPROPYL


HYDROLYZED WHEAT PROTEIN


COCODIMONIUM


HYDROXYPROPYL SILK AMINO


ACIDS



COCOS NUCIFERA

Coconut oil. Extractives and their physically modified



derivatives. It consists primarily of the glycerides



of the fatty acids capric, lauric, myristic, oleic and



palmitic. (Cocos nucifera, Palmae); Extractives and



their physically modified derivatives su


COLLAGEN
Collagens. A fibrous protein comprising one third



of the total protein in mammalian organisms. It is a



polypeptide containing three peptide chains and



rich in proline and hydroxyproline


COLLOIDAL SULFUR
Sulfur and gum arabic



COMMIPHORA MYRRHA 84929-26-


Commiphora myrrha, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc., obtained from Commiphora




myrrha, Burseraceae




COPERNICIA CERIFERA




CORIANDRUM SATIVUM

Coriander, ext. Extractives and their physically



modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Coriandrum sativum,



Umbelliferae


CORN FLOWER EXTRACTS



CUCUMIS SATIVUS

Cucumber, ext. Extractives and their physically



modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Cucumis sativus, Cucurbitaceae



CUPRESSUS

Cypress, Cupressus sempervirens, ext.



SEMPERVIRENS

Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Cupressus semper


CYCLOHEXYLAMINE


CYCLOMETHICONE
Octamethylcyclotetrasiloxane/decamethyl-



cyclopentasiloxane


CYCLOMETHICONE


DIMETHICONOL


CYCLOPENTASILOXANE



CYMBOPOGON CITRATUS




DAUCUS CAROTA

Carrot, ext. Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Daucus carota, Umbelliferae


DEA-OLETH-10 PHOSPHATE
Ethanol, 2,2′-iminobis-, compd. with (Z)-, a-9-



octadecenyl-, β-hydroxypoly(oxy-1,2-ethanediyl),



phosphate


DEA-OLETH-3 PHOSPHATE
Ethanol, 2,2′-iminobis-, compd. with (Z)-, a-9-



octadecenyl-, β-hydroxypoly(oxy-1,2-ethanediyl),



phosphate


DECYL GLUCOSIDE
Decyl D-glucoside


DENATONIUM BENZOATE
Denatonium benzoate


DIAZOLIDINYL UREA
1-[1,3-bis(hydroxymethyl)-2,5-dioxoimida-zolidin-4-



yl]-1,3-bis(hydroxymethyl)urea


DIISOBUTYL ADIPATE
Diisobutyl adipate


DIISOPROPYL ADIPATE
Diisopropyl adipate


DIISOPROPYL DIMER


DILINOLEATE


DIISOSTEAROYL


TRIMETHYLOLPROPANE SILOXY


SILICATE


DIMETHICONAL


DIMETHICONE
Dimethicone


DIMETHICONE BISAMINO


HYDROXYPROPYL COPOLYOL/


ALGAE/ALOE BARBADENSIS/


CHAMOMILE/HENNA/JOJOBA/


ROSEMARY/DIMETHICONE


COPOLYOL


DIMETHICONE BISAMINO


HYDROXYPROPYL COPOLYOL/


GLUTAMINE/TYROSINE/


LEUCINE/CYSTEINE/GLYSINE/


COMFREY/PLANTAIN/


HYDROLYZED WHEAT PROTEIN/


DIMETHICONE COPOLYOL


DIMETHICONE BISAMINO


HYDROXYPROPYL COPOLYOL/


WHITE GINGER/


DIMETHICONE COPOLYOL


DIMETHICONE COPOLYOL
Siloxanes and silicones, di-me, hydroxy-



terminated, ethoxylated propoxylated


DIMETHICONE COPOLYOL


ACETATE


DIMETHICONE PROPYL PG-


BETAINE


DIMETHICONOL
Poly[oxy(dimethylsilylane)], a-hydro-ω-hydroxy-


DIMETHYL ETHER
Dimethyl ether


DIMETHYL LAURAMINE
Isooctadecanoic acid, compound with N,N-


ISOSTEARATE
dimethyldodecylamine (1:1)


DIPENTAERYTHRITYL
Decanoic acid, ester with 2,2′-


HEXACAPRYLATE/
[oxybis(methylene)]bis[2-(hydroxymethyl)-1,3-


HEXACAPRATE
propanediol] octanoate pentanoate


DIPHENYL DIMETHICONE


DIPOTASSIUM GLYCYRRHIZATE
a-d-Glucopyranosiduronic acid, (3a,20a)-20-



carboxy-11-oxo-30-norolean-12-en-3-yl 2-O-a-d-



glucopyranuronosyl-, dipotassium salt


DIPROPYLENE GLYCOL
1,1′-oxydipropan-2-ol


DISODIUM COCO-
Imidazolium compounds, 1-[2-(2-carboxy-


AMPHODIPROPIONATE
ethoxy)ethyl]-1(or 3)-(2-carboxyethyl)-4,5-dihydro-2-



norcoco alkyl, hydroxides, disodium salts


DISODIUM EDTA
Disodium dihydrogen



ethylenediaminetetraacetate


DISTEAROYLETHYL


HYDROXYETHYLMONIUM


METHOSULFATE


DISTEARYLDIMONIUM CHLORIDE
Dimethyldioctadecylammonium chloride


DMDM HYDANTOIN
1,3-bis(hydroxymethyl)-5,5-dimethylimida-zolidine-



2,4-dione


EDTA
Edetic acid


EMULSIFYING WAX NF



EQUISETUM ARVENSE


Equisetum arvense, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc., obtained from Equisetum arvense,



Equisetacea


ESTER CAPRYLIC


ETHOXYDIGLYCOL
2-(2-ethoxyethoxy)ethanol


ETHYL ESTER OF


HYDROLYZED SILK


ETHYL ESTER OF PVM/MA
2-butanedioic acid (Z)-, monoethyl ester, polymer


COPOLYMER
with methoxyethene


ETHYLHEXYL METHOXY-


CINNAMATE


ETHYLHEXYL STEARATE


ETHYLPARABEN
Ethyl 4-hydroxybenzoate



EUCALYPTUS GLOBULUS


Eucalyptus globulus, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc.,



obtained from Eucalyptus globulus,



Myrtace


FACTOR 12


FLAVOUR


GLUCOSAMINE HCl
Glucosamine hydrochloride


GLUTAMIC ACID
Glutamic acid; DL-glutamic acid



monohydrate


GLYCERIN
Glycerol


GLYCERYL STEARATE
Stearic acid, monoester with glycerol


GLYCINE
Glycine



GLYCINE SOJA

Soybean oil. Extractives and their physically modified



derivatives. It consists primarily of the glycerides



of the fatty acids linoleic, oleic, palmitic and stearic.



(Soja hispida, Leguminosae)


GLYCYRRHIZIC ACID
Glycyrrhizic acid


GLYOXYLIC ACID
Glyoxylic acid


GUAR
Guar gum, 2-hydroxy-3-(trimethylammonio)propyl


HYDROXYPROPYL-TRIMONIUM
ether, chloride


CHLORIDE



HAMAMELIS VIRGINIANA


Hamamelis virginiana, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc.,



obtained from Hamamelis virginiana, Hamam


HC RED NO. 3
2-(4-amino-2-nitroanilino)ethanol


HC YELLOW NO. 5
2-(2-amino-4-nitroanilino)ethanol



HELIANTHUS ANNUUS

Extractives and their physically modified derivatives



such as tinctures, concretes, absolutes, essential



oils, oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from Helianthus




annuus; Oils, sunflower, unsaponifiables fr



HEXAMIDINE PARABEN
P-hydroxybenzoic acid, compound with p,p′-



[hexane-1,6-diylbis(oxy)]bis(benzamidine) (2:1)


HEXYLENE GLYCOL
2-methylpentane-2,4-diol


HOPS EXTRACT


HYALURONIC ACID
Hyaluronic acid



HYDRASTIS CANADENSIS

Golden seal, Hydrastis canadensis, ext. Extractives



and their physically modified derivatives such as



tinctures, concretes, absolutes, essential oils,



oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from Hydrastis




cana



HYDROABIETYL ALCOHOL
[1R-(1a,4aa,4ba,10aa)]-dodecahydro-7-isopropyl-



1,4a-dimethylphenanthren-1-methanol


HYDROFLUOROCARBON 152A
1,1-difluoroethane


HYDROGEN PEROXIDE
Hydrogen peroxide


HYDROGENATED BUTYLENE/


ETHYLENE/STYRENE


COPOLYMER


HYDROGENATED CASTOR
Castor oil, hydrogenated


OIL


HYDROGENATED
Coconut oil, hydrogenated


COCONUT OIL


HYDROGENATED ETHYLENE/


PROPYLENE/STYRENE


COPOLYMER


HYDROGENATED
Paraffin waxes and Hydrocarbon waxes,


MICROCRYSTALLINE WAX
microcryst., hydrotreated. A complex combination



of hydrocarbons obtained from residual oils by



solvent crystallisation and treated with hydrogen in



the presence of a catalyst. It consists



predominantly of saturated s


HYDROGENATED ROSIN


HYDROGENATED TAL-LOWETH-60


MYRISTYL GLYCOL


HYDROLYZED COLLAGEN
Collagens, hydrolyzates. Substance obtained by



acidic, alkaline, or enzymatic hydrolysis of hoofs



and horns composed primarily of amino acids,



peptides, and proteins. It may contain impurities



consisting chiefly of carbohydrates and lipids



along with small


HYDROLYZED KERATIN
Keratins, hydrolyzates. A biological material



consisting predominantly of partially hydrolyzed



keratin


HYDROLYZED MUCO-


POLYSACCHARIDES


HYDROLYZED PROTEIN


HYDROLYZED SILK
Protein hydrolyzates, silk


HYDROLYZED SOY PROTEIN
Protein hydrolyzates, soya. Substance obtained by



acidic, alkaline, or enzymatic hydrolysis of soya



composed primarily of amino acids, peptides, and



proteins. It may contain impurities consisting chiefly



of carbohydrates and lipids along with smaller quan


HYDROLYZED VEGETABLE
Protein hydrolyzates, vegetable. Substance obtained


PROTEIN
by acidic, alkaline, or enzymatic hydrolysis of



mixed vegetables composed primarily of amino



acids, peptides, and proteins. It may contain



impurities consisting chiefly of carbohydrates



and lipids along


HYDROLYZED WHEAT GLUTEN


HYDROLYZED WHEAT PROTEIN
Protein hydrolyzates, wheat germ. Substance



obtained by acidic, alkaline, or enzymatic



hydrolysis of wheat germ composed primarily of



amino acids, peptides, and proteins. It may



contain impurities consisting chiefly of



carbohydrates and lipids along with


HYDROLYZED WHEAT PROTEIN/


PVP CROSS-POLYMER


HYDROLYZED WHEAT STARCH


HYDROXYETHYL
Hexadecyl(2-


CETYLDIMONIUM
hydroxyethyl)dimethylammonium dihydrogen


PHOSPHATE
phosphate


HYDROXYETHYLCELLULOSE
Cellulose, 2-hydroxyethyl ether


HYDROXYLATED LANOLIN
Lanolin, hydroxylated


HYDROXYPROPYL
1,3-propanediaminium, 2-hydroxy-N,N′-


BISSTEARYLDIMONIUM CHLORIDE
bis(octadecyl)-N,N,N′,N′-tetramethyl-, chloride


HYDROXYPROPYL GUAR
Guar gum, 2-hydroxypropyl ether,


HYDROXYPROPYL GUAR


HYDROXYPROPYLTRIMONIUM


CHLORIDE


HYDROXYPROPYL
Cellulose, 2-hydroxypropyl methyl ether


METHYLCELLULOSE


HYDROXYPROPYLCELLULOSE
Cellulose, 2-hydroxypropyl ether


HYDROXYPROPYLTRIMONIUM


HYDROLYZED WHEAT


PROTEIN


HYDROXYSTEARIC ACID
12-hydroxystearic acid



HYPERICUM PERFORATUM

St.-John's-wort, Hypericum perforatum, ext.



Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Hypericu


I.P.M.


IMIDAZOLIDINYL UREA
N,N″-methylenebis[N′-[3-(hydroxymethyl)-



2,5-dioxoimidazolidin-4-yl]urea]


INOSITOL
Myo-inositol


IODOPROPYNYL BUTYL-
3-iodo-2-propynyl butylcarbamate


CARBAMATE


IRON OXIDE
Diiron trioxide (CI 77489, 77491, 77492, 77499);



Magnesium oxide (CI 77489, 77491, 77492,



77499); Triiron tetraoxide (CI 77489, 77491, 77492,



77499)


ISOBUTANE
Isobutane


ISOBUTYLPARABEN
Isobutyl 4-hydroxybenzoate


ISOCETETH-20


ISODODECANE
Isododecane


ISOHEXADECANE
2,2,4,4,6,8,8-heptamethylnonane


ISOLAURETH-6


ISOPENTANE
2-methylbutane


ISOPROPYL ALCOHOL
Propan-2-ol


ISOPROPYL C12-15-PARETH-9


CARBOXYLATE


ISOPROPYL LANOLATE
Fatty acids, lanolin, iso-Pr esters


ISOPROPYL MYRISTATE
Isopropyl myristate


ISOPROPYL STEARATE
Isopropyl stearate


ISOPROPYLPARABEN
Isopropyl 4-hydroxybenzoate


ISOSTEARETH-10
Poly(oxy-1,2-ethanediyl), a-isooctadecyl-ωhydroxy-


ISOSTEARETH-20
Poly(oxy-1,2-ethanediyl), a-isooctadecyl-ω-hydroxy-


ISOSTEARYL PALMITATE
Isooctadecyl palmitate



JUNIPERUS COMMUNIS

Juniper, Juniperus communis, ext. Extractives



and their physically modified derivatives such as



tinctures, concretes, absolutes, essential oils,



oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from Juniperus




communis,



KAOLIN
Naturally occurring substances, kaolin (CI 77004)


KAWA EXTRACT


KERATIN
Keratins. Natural, fibrous proteins occurring in



vertebrates. They contain all of the common amino



acids and are characterized by high cystine



content


KERATIN AMINO ACIDS
Keratins, hydrolyzates


LACTAMIDE MEA
N-2-hydroxyethyllactamide


LACTIC ACID
Lactic acid


LAMINARIA DIGITATE


LANETH-10
Alcohols, lanolin, ethoxylated


LANOLIN
Lanolin. Fat-like substance derived from sheep



wool. Contains a complex combination of esters



and polyesters, consisting chiefly of cholesteryl



and isocholesteryl esters of the higher fatty acids


LANOLIN ALCOHOL
Alcohols, lanolin. A complex combination of



organic alcohols obtained by the hydrolysis of



lanolin


LANOLIN CERA
Lanolin, wax. Wax obtained by fractionation of



anhydrous lanolin


LAURETH-23
Poly(oxy-1,2-ethanediyl), α-dodecyl-ω-hydroxy-


LAURETH-4
3,6,9,12-tetraoxatetracosan-1-ol


LAURETH-7
3,6,9,12,15,18,21-heptaoxatritriacontanol


LAURYL ALCOHOL
Dodecan-1-ol


LAURYL METHYL GLUCETH-10


HYDROXYPROPYLDIMONIUM


CHLORIDE


LAURYLDIMONIUM
Lamanequat L


HYDROXYPROPYL


HYDROLYZED COLLAGEN



LAVANDULA ANGUSTI-FOLIA

Lavender, Lavandula angustifolia, ext. Extractives



and their physically modified derivatives such as



tinctures, concretes, absolutes, essential oils,



oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from Lavandula



angus



LAWSONIA INERMIS


Lawsonia inermis, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc.,



obtained from Lawsonia inermis, Lythraceae


LECITHIN
Lecithins. The complex combination of



diglycerides of fatty acids linked to the choline



ester of phosphoric acid


LEMONGRASS EXTRACT


LINOLEAMIDOPROPYL
1-propanaminium, N-ethyl-N,N-dimethyl-3-antistatic [1-


ETHYLDIMONIUM ETHOSULFATE
oxo-9,12-octadecadienylamino]-, ethyl



sulfate (salt)


LINOLEAMIDOPROPYL PG-
1-propanaminium, 2,3-dihydroxy-N,N-dimethyl-


DIMONIUM
N-[3-(1-oxo-9,12-octadecadienyl-


CHLORIDE PHOSPHATE
amino)propyl]-, 3-phosphate triester, trichloride


LINOLEIC ACID
Linoleic acid


LINOLENIC ACID
Linolenic acid


LUVISKOL


LYSINE
L-lysine


MAGNESIUM ALUMINUM
Silicic acid, aluminum magnesium salt


SILICATE


MAGNESIUM CHLORIDE7786-30-3
Magnesium chloride


MAGNESIUM NITRATE
Magnesium nitrate



MALVA SYLVESTRIS

Mallow, Malva sylvestris, ext. Extractives and



their physically modified derivatives such as



tinctures, concretes, absolutes, essential oils,



oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from Malva




sylvestris, Malva



MEADOWFOAM SEED OIL



MELISSA OFFICINALIS


Melissa officinalis, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc., obtained from Melissa officinalis,



Labiata


METHACRYLOYL ETHYL BETAINE/
Amersette


ACRYLATES COPOLYMER


METHYL GLUCETH-10
Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-,



ether with methyl a-d-glucopyranoside (4:1)


METHYL GLUCETH-20
Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-,



ether with methyl a-d-glucopyranoside (4:1)


METHYL HYDROGENATED
Resin acids and Rosin acids, hydrogenated, Me


ROSINATE
esters


METHYLAL
Dimethoxymethane


METHYLCHLOROISOTHI26172-55-4
5-chloro-2-methyl-2H-isothiazol-3-one


AZOLINONE


METHYLDIBROMO GLU-
2-bromo-2-(bromomethyl)pentanedinitrile


TARONITRILE


METHYLDIHYDRO-
Methyl (1R-trans)-3-oxo-2-pentylcyclopentaneacetate


JASMONATE


METHYLISOTHIAZOLIN ONE
2-methyl-2H-isothiazol-3-one


METHYLPARABEN
Methyl 4-hydroxybenzoate


MICA
Mica-group minerals (CI 77019)


MICROWAX 80


MINERAL OIL


MUSK KETONE


MYRISTAMINE OXIDE
N,N-dimethyltetradecylamine N-oxide


MYRISTOYL HYDROLYZED
Gelatins, hydrolyzates, myristoyl derivativesantistatic


COLLAGEN


NETTLE EXTRACT


NIACINAMIDE
Nicotinamide


NIPASEPT SODIUM


NITROMETHANE
Nitromethane


NONOXYNOL-10
29-(nonylphenoxy)-3,6,9,12,15,18,21,24,27-



nonaoxanonacosanol


NONOXYNOL-14
Poly(oxy-1,2-ethanediyl), α-(nonylphenyl)-ω-hydroxy-



OCIMUM BASILICUM


Ocimum basilicum, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc.,



obtained from Ocimum basilicum,



Labiatae


OCTOXYNOL-40
Poly(oxy-1,2-ethanediyl), α-[4-(1,1,3,3-



tetramethylbutyl)phenyl]-ω-hydroxy-


OCTYL METHOXYCINNAMATE
2-ethylhexyl 4-methoxycinnamate


OCTYL PALMITATE
2-ethylhexyl palmitate


OCTYL SALICYLATE
2-ethylhexyl salicylate


OCTYL STEARATE
2-ethylhexyl stearate


OCTYLACRYLAMIDE/ACRYLATES/


BUTYLAMINOETHYL


METHACRYLATE


COPOLYMER


OCTYLDODECANOL
2-octyldodecan-1-ol


OCTYLDODECYL
Propanoic acid, 2,2-dimethyl-, 2-


NEOPENTANOATE
octyldodecyl ester



OENOTHERA BIENNIS

Evening primrose, Oenothera biennis, ext.



Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Oenothera bi



OLEA EUROPAEA

Olive oil. Extractives and their physically modified



derivatives. It consists primarily of the glycerides



of the fatty acids linoleic, oleic and palmitic. (Olea




europaea, Oleaceae)



OLEAMIDOPROPYL PG-
1-propanaminium, 3-[(1-oxo-9-octa-decenyl)amino]-


DIMONIUM CHLORIDE
N-(2,3-dihydroxypropyl)-N,N-dimethyl-, chloride


OLETH-10
Poly(oxy-1,2-ethanediyl), α-9-octadecenyl-ω-hydroxy-


OLETH-2
Poly(oxy-1,2-ethanediyl), α-9-octadecenyl-ω-hydroxy-


OLETH-20
Poly(oxy-1,2-ethanediyl), α-9-octadecenyl-ω-hydroxy-


OLETH-3
Poly(oxy-1,2-ethanediyl), α-9-octadecenyl-ω-hydroxy-


OLETH-3 PHOSPHATE
Poly(oxy-1,2-ethanediyl), α-9-octadecenyl-ω-hydroxy-



(Z)-, phosphate


OLETH-5
Poly(oxy-1,2-ethanediyl), α-9-octadecenyl-ω-hydroxy-


OLEYL ALCOHOL
(Z)-octadec-9-enol


ORANGE PEEL WAX
Waxes, orange peel



ORYZA SATIVA

Starch. High-polymeric carbohydrate material



usually derived from cereal grains such as corn,



wheat and sorghum, and from roots and tubers



such as potatoes and tapioca. Includes starch



which has been pregelatinized by heating in the



presence of water


ORYZANOL
(Γ)-oryzanol


OZOKERITE
Hydrocarbon waxes (petroleum), chemically



neutralized. A complex combination of



hydrocarbons produced by a treating process to



remove acidic materials. It consists predominantly



of saturated straight chain hydrocarbons having



carbon numbers predominantly


PABA
4-aminobenzoic acid



PANAX GINSENG


Ginseng, Panax pseudoginseng, ext. Extractives




and their physically modified derivatives such as



tinctures, concretes, absolutes, essential oils,



oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from Panax




pseudoginseng



PANTHENOL
Dexpanthenol


PANTHENYL ETHYL ETHER
(+)-N-(3-ethoxypropyl)-2,4-dihydroxy-3,3-



dimethylbutyramide


PANTHENYL HYDROXY-PROPYL
1-octadecanaminium, N,N-dimethyl-N-[2-hydroxy-


STEARDIMONIUM CHLORIDE
3-[2,2-dimethyl-3-hydroxy-4-oxo-4-(3-



hydroxypropyl)amino]butyl]-, chloride


PARAFFIN
Paraffin waxes and Hydrocarbon waxes. A complex



combination of hydrocarbons obtained from



petroleum fractions by solvent crystallization



(solvent deoiling) or by the sweating process. It



consists predominantly of straight chain



hydrocarbons having carbon


PARAFFINUM LIQUIDUM
Paraffin oils. Liquid hydrocarbons from petroleum


PERFUME


PCA
Pidolic acid


PEG/PPG 25/25 DIMETHICONE/


ACRYLATES COPOLYMER


PEG/PPG-14/4


DIMETHICONE


PEG-10 SOYA STEROL


PEG-100 STEARATE
Poly(oxy-1,2-ethanediyl), α-(1-



oxooctadecyl)-ω-hydroxy-


PEG-12
3,6,9,12,15,18,21,24,27,30,33-



undecaoxapentatriacontane-1, 35-diol


PEG-15 COCOPOLYAMINE


PEG-150/STEARYL ALCOHOL/


SMDI COPOLYMER


PEG-150 DISTEARATE
Poly(oxy-1,2-ethanediyl), α-(1-oxooctadecyl)-ω-



[(1-oxooctadecyl)oxy]-


PEG-150 PENTAERYTHRITYL


TETRASTEARATE


PEG-192 APRICOT KERNEL


GLYCERIDES


PEG-2 DIMEADOWFOAM


AMIDOETHYLMONIUM


METHOSULFATE


PEG-2 OLEAMMONIUM CHLORIDE
Bis(hydroxyethyl)methyloleylammonium chloride


PEG-20 STEARATE
Poly(oxy-1,2-ethanediyl), α-(1-



oxooctadecyl)-ω-hydroxy-


PEG-25
Castor oil, hydrogenated, ethoxylated


HYDROGENATED CASTOR


OIL


PEG-25 PABA


PEG-32
Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-humectants


PEG-4
3,6,9-trioxaundecane-1, 11-diol


PEG-40
Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-humectants


PEG-40 CASTOR OIL
Castor oil, ethoxylated


PEG-40
Castor oil, hydrogenated, ethoxylated


HYDROGENATED CASTOR


OIL


PEG-40 SORBITAN LANOLATE
G 1441


PEG-45 PALM KERNEL


GLYCERIDES


PEG-45M
Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-


PEG-5 OCTANOATE


PEG-5M
Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-


PEG-6 CAPRYLIC/CAPRIC


GLYCERIDES


PEG-6 COCAMIDE
Fatty acids, coco, reaction products with



ethanolamine, ethoxylated


PEG-60
Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-


PEG-60 ALMOND GLYCERIDES


PEG-60
Castor oil, hydrogenated, ethoxylated


HYDROGENATED CASTOR


OIL


PEG-7 GLYCERYL COCOATE
Glycerides, coco mono-and di-, ethoxylated


PEG-70 MANGO GLYCERIDES


PEG-75
Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-


PEG-75 LANOLIN
Lanolin, ethoxylated


PEG-75 SHEA BUTTER


GLYCERIDES


PEG-8
3,6,9,12,15,18,21-heptaoxatricosane-1, 23-diol


PEG-8 BEESWAX


PEG-9 COCOGLYCERIDES


PEG-90M
Poly(oxy-1,2-ethanediyl), α-hydro-ω-hydroxy-



PELVETIA DIGITATA



PENTAERYTHRITYL TETRACAPRYLATE/
Decanoic acid, mixed esters with octanoic acid and


CAPRATE
pentaerythritol


PENTANE
Pentane


PENTASODIUM PENTETATE
Pentasodium (carboxylatomethyl)iminobis(ethylenenitrilo)tetraacetate



PERSEA GRATISSIMA

Oils, avocado. Extractives and their physically



modified derivatives. It consists primarily of the



glycerides of the fatty acids linoleic, oleic, and



palmitic. (Persea americana, Lauraceae)


PETROLATUM
Petrolatum. A complex combination of



hydrocarbons obtained as a semi-solid from



dewaxing paraffinic residual oil. It consists



predominantly of saturated



crystalline and liquid hydrocarbons having carbon



numbers predominantly greater than C25


PHENOXYETHANOL
2-phenoxyethanol


PHENYL TRIMETHICONE
1,1,5,5,5-hexamethyl-3-phenyl-3-



[(trimethylsilyl)oxy]trisiloxane


PHOSPHATE


PHYTANTRIOL
3,7,11,15-tetramethylhexadecane-1,2,3-triol



POGOSTEMON CABLIN


Patchouli, ext. Extractives and their physically




modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Pogostemon cablin (Pogostemon



patchoul


POLYACRYLAMIDE
2-propenamide, homopolymer


POLYACRYLAMIDO-


METHYLPROPANE SULFONIC


ACID


POLYBUTENE
polybutene-1, poly(1-butene), PB-1.


POLYISOBUTENE
1-propene, 2-methyl-, homopolymer


POLYLENE GLYCOL


POLYOXYL 40


POLYQUATERNIUM


POLYQUATERNIUM-10
Cellulose, 2-(2-hydroxy-3-(trimethylammonium)propoxy)ethyl



ether, chloride


POLYQUATERNIUM-11
2-propenoic acid, 2-methyl-, 2-(dimethyl-



amino)ethyl ester, polymer with 1-ethenyl-2-



pyrrolidinone, compd. with diethyl sulfate


POLYQUATERNIUM-16


POLYQUATERNIUM-37


POLYQUATERNIUM-4


POLYQUATERNIUM-46


POLYQUATERNIUM-7
2-propen-1-aminium, N,N-dimethyl-N-2-propenyl-,



chloride, polymer with 2-propenamide


POLYSILICONE-11


POLYSILICONE-8


POLYSILOXAN


POLYSORBATE 20
Sorbitan, monododecanoate, poly(oxy-1,2-



ethanediyl) derivs


POLYSORBATE 40
Sorbitan, monohexadecanoate, poly(oxy-1,2-



ethanediyl) derivs


POLYSORBATE 60
Sorbitan, monooctadecanoate, poly(oxy-1,2-



ethanediyl) derivs


POLYSORBATE 80
Sorbitan, mono-9-octadecenoate, poly(oxy-1,2-



ethanediyl) derivs., (Z)-


POLYSTYRENE
Benzene, ethenyl-, homopolymer


POLYVINYL ALCOHOL
Ethenol, homopolymer


POLYVINYL CAPRO-LACTAM


POTASSIUM
Potassium hydroxide


HYDROXIDE


POTASSIUM SORBATE
Potassium (E,E)-hexa-2,4-dienoate


POTATO FLAKES


POTATO STARCH MODIFIED


PPG-1 TRIDECETH-6


PPG-10 METHYL GLUCOSE
Poly[oxy(methyl-1,2-ethanediyl)], α-hydro-ω-hydroxy-,


ETHER
ether with methyl D-glucopyranoside (4:1)


PPG-12-PEG-50 LANOLIN
Lanolin, ethoxylated, propoxylated


PPG-20 METHYL GLUCOSE
Poly[oxy(methyl-1,2-ethanediyl)], α-hydro-ω-hydroxy-,


ETHER
ether with methyl D-glucopyranoside (4:1)


PPG-3 METHYL ETHER
1-[2-(2-methoxy-1-methylethoxy)-1-



methylethoxy]propan-2-ol


PPG-3 MYRISTYL ETHER
Poly[oxy(methyl-1,2-ethanediyl)], α-tetradecyl-



ω-hydroxy-


PPG-5-CETETH-20
Oxirane, methyl-, polymer with oxirane, hexadecyl



ether


PROLINE
L-proline


PROPANE
Propane


PROPYLENE GLYCOL
Propane-1,2-diol


PROPYLENE GLYCOL
Decanoic acid, mixed diesters with octanoic


DICAPRYLATE/DICAPRATE
acid and propylene glycol


PROPYLPARABEN
Propyl 4-hydroxybenzoate



PRUNUS DULCIS

Almond, sweet, ext. Extractives and their physically



modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Prunus amygdalus sativa,



Rosaceae;


PVM/MA DECADIENE


CROSSPOLYMER


PVP
2-pyrrolidinone, 1-ethenyl-, homopolymer


PVP/DIMETHYLAMINO-30581-59-0


ETHYLMETHACRYLATE


COPOLYMER


PVP/VA


PVP/VA COPOLYMER
Acetic acid, ethenyl ester, polymer with 1-ethenyl-



2-pyrrolidinone


PVP/VINYLCAPROLACTUM/


DMAPA ACRYLATES


COPOLYMER


PVP COPOLYMER



PYRUS MALUS

Apple, Malus pumila, ext. Extractives and their



physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc., obtained from Malus pumila,



Rosaceae


QUATERNIUM-26
1-Propanaminium, 3-amino-N-(2-hydroxy-ethyl)-N,



N-dimethyl-, N-mink-oil acyl derivs., chlorides


QUATERNIUM-27
Imidazolium compounds, 4,5-dihydro-1-methyl-2-



nortallow alkyl-1-(2-tallow amidoethyl), Me sulfates


QUATERNIUM-52
Poly(oxy-1,2-ethanediyl), a,a′,a″-[(octade-



cylnitrilio)tri-2,1-ethanediyl)tris(?-hydroxy)-, phosphate



(1:1) (salt)


QUATERNIUM-70
Dimethyl[3-[(1-oxooctadecyl)amino]propyl][2-oxo-2-



(tetradecyloxy)ethyl]ammonium chloride


QUATERNIUM-79 HYDROLYZED


KERATIN


QUATERNIUM-79


HYDROLYZED SILK


QUATERNIUM-79 HYDROLYZED


SOY PROTEIN


QUATERNIUM-87



QUILLAIA SAPONARIA


Quillaja saponaria, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc.,



obtained from Quillaja saponaria, Rosaceae


RETINYL PALMITATE
Retinyl palmitate



RHUS SUCCEDANEA


Rhus succedanea, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc.,



obtained from Rhus succedanea,



Anacardiaceae



RICINUS COMMUNIS

Castor oil. Extractives and their physically modified



derivatives. It consists primarily of the glycerides of



the fatty acid ricinoleic. (Ricinus communis,



Euphorbiaceae)



ROSA CANINA

Rose, Rosa canina, ext. Extractives and their



physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc.,



obtained from Rosa canina, Rosaceae



ROSMARINUS OFFICINALIS

Rosemary, ext. Extractives and their physically



modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Rosmarinus officinalis, Labiatae



SACCHAROMYCES/COPPER



FERMENT



SACCHAROMYCES/IRON



FERMENT



SACCHAROMYCES/MAGNESIUM



FERMENT



SACCHAROMYCES/SILICON



FERMENT



SACCHAROMYCES/ZINC



FERMENT



SACCHARUM OFFICINARUM

Sugarcane, ext. Extractives and their physically



modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Saccharum officinarum,



Gramineae



SALVIA OFFICINALIS

Sage, Salvia officinalis, ext. Extractives and their



physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc.,



obtained from Salvia officinalis, Lab



SANTALUM ALBUM

Sandalwood, ext. Extractives and their physically



modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Santalum album, Santalaceae



SERENOA SERRULATA


Sabal serrulatum, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc., obtained from Sabal serrulatum,



Palmae


SERINE
L-serine



SESAMUM INDICUM

Oils, sesame. Extractives and their physically



modified derivatives. It consists primarily of the



glycerides of the fatty acids linoleic, oleic, palmitic



and stearic. (Sesamum indicum, Pedaliaceae)


SHEA BUTTER


SILICA
Silicon dioxide


SILK AMINO ACIDS
Protein hydrolyzates, silk


SIMENTHICON


SIMETHICONE


SODIUM ACRYLOYLDIMETHYLTAURATE


COPOLYMER


SODIUM BENZOATE
Sodium benzoate


SODIUM BISULFITE
Sodium hydrogensulphite


SODIUM CHLORIDE
Sodium chloride


SODIUM COCOYL HYDROLYZED


SOY PROTEIN


SODIUM HYDROXIDE
Sodium hydroxide


SODIUM HYDROXY-
Sodium N-(hydroxymethyl)glycinate


METHYLGLYCINATE


SODIUM LAURYL SULFATE
Sodium dodecyl sulphate


SODIUM METABISULFITE
Disodium disulphite


SODIUM METHYLPARABEN
Sodium 4-(methoxycarbonyl)phenolate


SODIUM PALMITATE
Sodium palmitate


SODIUM PCA
Sodium 5-oxo-L-prolinate


SODIUM POLYSTYRENE
Benzenesulfonic acid, ethenyl-,


SULFONATE
homopolymer, sodium salt


SODIUM STYRENE/


ACRYLATES


COPOLYMER


SODIUM STYRENE/PEG-10


MALEATE/NONOXYNOL-10


MALEATE/ACRYLATES


COPOLYMER


SOLUBLE COLLAGEN


SORBIC ACID
Hexa-2,4-dienoic acid


SORBITAN OLEATE
Sorbitan oleate


SORBITAN STEARATE
Sorbitan stearate


SORBITOL
D-glucitol


SOYALECITHIN


SQUALENE
2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,



18,22-hexaene


STEARALKONIUM CHLORIDE
Benzyldimethyl(octadecyl)ammonium chloride


STEARDIMONIUM


HYDROXYPROPYL HYDROLYZED


WHEAT PROTEIN


STEARETH-10 ALLYL ETHER/


ACRYLATES COPOLYMER


STEARETH-20
Poly(oxy-1,2-ethanediyl), α-octadecyl-ω-hydroxy


STEARETH-21
Poly(oxy-1,2-ethanediyl), α-octadecyl-ω-hydroxy


STEARIC ACID
Stearic acid


STEARYL ALCOHOL
Octadecan-1-ol


STEARYL CAPRYLATE
Octadecyl octanoate


STEARYL HEPTANOATE
Octadecyl heptanoate


STYRENE/ACRYLATES


COPOLYMER


STYRENE/PVP COPOLYMER
2-pyrrolidinone, 1-ethenyl-, polymer with



ethenylbenzene


SUCROSE
Sucrose


SULFUR
Sulphur


TALLOWTRIMONIUM CHLORIDE
Quaternary ammonium compounds,



trimethyltallow alkyl, chlorides


t-BUTYL ALCOHOL
2-methylpropan-2-ol


TEA-CARBOMER


TETRAHYDROXYPROPYL
1,1′,1″,1′″-ethylenedinitrilotetrapropan-2-ol


ETHYLENEDIAMINE


TETRASODIUM EDTA
Tetrasodium ethylenediaminetetraacetate


THIAMINE HCl
Thiamine hydrochloride


THREONINE
L-threonine


THYMUS HYDROLYSATE
Protein hydrolyzates, thymus gland. Substance



obtained by acidic, alkaline, or enzymatic



hydrolysis of thymus gland composed primarily



of amino acids, peptides, and proteins. It may



contain impurities consisting chiefly of carbohydrates



and lipids along w



THYMUS VULGARIS

Thyme, Thymus vulgaris, ext. Extractives and



their physically modified derivatives such as



tinctures, concretes, absolutes, essential oils,



oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from Thymus




vulgaris, Labiatae



TITANIUM DIOXIDE
Titanium dioxide (CI 77891)


TOCOPHEROL
a-tocopherol; 3,4-dihydro-2,5,7,8-tetra-methyl-2-



(4,8,12-trimethyltridecyl)-2Hbenzopyran-6-ol


TOCOPHERYL ACETATE
a-tocopheryl acetate, 3,4-dihydro-2,5,7,8-



tetramethyl-2-(4,8,12-trimethyltridecyl)-2H-



benzopyran-6-yl acetate


TRIACETIN
Triacetin


TRIBEHENIN
Propane-1,2,3-triyl tridocosanoate


TRIDECETH-10
Poly(oxy-1,2-ethanediyl), α-tridecyl-ω-hydroxy


TRIDECETH-12
Poly(oxy-1,2-ethanediyl), α-tridecyl-ω-hydroxy


TRIDECETH-3 CARBOXYLIC


ACID


TRIDECETH-7


TRIDECETH-9
Poly(oxy-1,2-ethanediyl), α-tridecyl-ω-hydroxy


TRIDECYL STEARATE
Tridecyl stearate


TRIETHANOLAMINE
2,2′,2″-nitrilotriethanol


TRIETHYL CITRATE
Triethyl citrate


TRIETHYLENE GLYCOL
2,2′-(ethylenedioxy)diethanol


TRILAURETH-4 PHOSPHATE
Poly(oxy-1,2-ethanediyl), a,a′,a″-



phosphinylidynetris-?-(dodecyloxy)-


TRIMETHYLOLPROPANE


TRIMETHYLSILYLAMODI


METHICONE



TRITICUM SATIVUM VULGARE




TRITICUM VULGARE

Starch. High-polymeric carbohydrate material



usually derived from cereal grains such as corn,



wheat and sorghum, and from roots and tubers



such as potatoes and tapioca. Includes starch



which has been pregelatinized by heating in the



presence of water; Oi


TUMERIC ROOT



TUSSILAGO FARFARA


Tussilago farfara, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc.,



obtained from Tussilago farfara,



Compositae



URTICA DIOICA


Urtica dioica, ext. Extractives and their physically




modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Urtica dioica, Urticaceae


VA/CROTONATES/


NEODECANOATE


COPOLYMER


VA/CROTONATES/VINYL
Neodecanoic acid, ethenyl ester, polymer with 2-


NEODECANOATE COPOLYMER
butenoic acid and ethenyl acetate


VA/CROTONATES
2-butenoic acid, polymer with ethenyl acetate


COPOLYMER


VA/CROTONIC ACID


COPOLYMER


VA/VINYL BUTYL BENZOATE/


CROTONATES COPOLYMER



VACCINIUM MYRTILLUS


Vaccinium myrtillus, ext. Extractives and their




physically modified derivatives such as tinctures,



concretes, absolutes, essential oils, oleoresins,



terpenes, terpene-free fractions, distillates,



residues, etc.,



obtained from Vaccinium myrtillus, Ericace


VINYL CAPROLACTAM/PVP/


DIMETHYLAMINO-5 ETHYL


METHACRYLATE COPOLYMER


VINYLPYRROLIDONE


VISCOCITY CONTROLLING


AGENT



VISCUM ALBUM


Viscum album, ext. Extractives and their physically




modified derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Viscum album, Loranthaceae



VITIS VINIFERA

Grape, red, ext. Extractives and their physically



modified derivatives such as tinctures, concretes,



absolutes, essential



oils, oleoresins, terpenes, terpene-free fractions,



distillates, residues, etc., obtained from Vitis




vinifera, Vitaceae; Extractives



WATERCRESS EXTRACT


WHEAT AMINO ACIDS
Amino acids, wheat


WHEAT GERM EXTRACT


WHEAT GERM GLYCERIDES
Glycerides, wheat germ-oil mono-, di-and tri-


HEAT GERMAMIDOPROPYLAMINE
Amides, wheat germ, N-(3-dimethylamino-propyl)-


OXIDE
N-oxides


WHEAT GERMAMIDOPROPYLDIMONIUM


HYDROXYPROPYL


HYDROLYZED WHEAT PROTEIN


WHEATGERMAMIDOPROPYL
1-propanaminium, N-ethyl-N,N-dimethyl-3-antistatic


ETHYLDIMONIUM ETHOSULFATE
amino-, N-wheat germ acyl derivs., ethyl



sulfates


XANTHAN GUM
Xanthan gum


YOGURT
Naturally occurring substances, milk prepa-biological



rations, yogurt



ZINGIBER OFFICINALIS

Ginger, ext. Extractives and their physically modified



derivatives such as tinctures, concretes,



absolutes, essential oils, oleoresins, terpenes,



terpene-free fractions, distillates, residues, etc.,



obtained from Zingiber officinalis, Zingiberaceae









In certain embodiments, the hair styling compositions are formulated as a spray. The spray typically includes the active hair care ingredient (fixing agent) and a carrier or propellant. In certain embodiments, the carrier is a water and alcohol mixture. In other embodiments, the spray composition also optionally includes a preservative, antioxidant, sunscreen agent, vitamin, protein, peptide, plant extract, humectant, oil, emollient, lubricant, thickener, hair conditioning agent, polymer, or surfactant. In certain other embodiments, the composition includes oil, a polymer, a humectant, or a fragrance and mixtures or combinations thereof. In certain particular embodiments, the composition comprises water, an alcohol, oil, fragrance, and an active hair care ingredient and mixtures or combinations thereof. In certain particular embodiments, the composition comprises water, an alcohol, oil, a polymer, fragrance, and an active hair care ingredient. In certain particular embodiments, the composition comprises water, an alcohol, an anti-static agent, fragrance, and an active hair care ingredient and mixtures or combinations thereof. In certain particular embodiments, the composition comprises water, an alcohol, a hair-conditioning agent, fragrance, and an active hair care ingredient. In certain particular embodiments, the composition comprises water, an alcohol, a surfactant, fragrance, and an active hair care ingredient. In certain particular embodiments, the composition comprises water, an alcohol, an emollient, fragrance, and an active hair care ingredient. Hair spray compositions are dispensed from containers that are aerosol dispensers or pump spray dispensers. Such dispensers are known in the art and are commercially available from a variety of manufacturers.


In certain embodiments, when the hair spray composition is dispensed from a pressurized aerosol container, a propellant is used to force the composition out of the container. Suitable propellants are described herein. In certain embodiments, the propellant is a liquefiable gas. In certain embodiments, the propellant is a halogenated propellant. In other embodiments, the composition does not contain any fluorinated or chlorinated propellants. Generally, the amount of propellant in the composition is from about 10% to about 60% by weight. In certain embodiments, the amount of propellant in the composition ranges from about 15% to about 50% by weight. In certain embodiments, the propellant is separated from the hair spray composition as in a two compartment container. Other suitable aerosol dispensers are those characterized by the propellant being compressed air which can be filled into the dispenser using a pump or equivalent device prior to use. Such dispensers are described in U.S. Pat. Nos. 4,077,441 and 4,850,577, both of which are entirely incorporated by reference herein, and in U.S. patent application Ser. No. 07/839,648, filed Feb. 21, 1992, also entirely incorporated by reference herein.


Conventional non-aerosol pump spray dispensers, i.e., atomizers, may also be used to apply hair spray compositions.


In certain embodiments, the cosmetic hair care composition is a cream. The inventive cream typically includes the active hair care ingredient, a carrier, an oil, a hair conditioning agent, and a thickening agent. In certain embodiments, the cream also includes a fragrance. In certain embodiments, the cream also includes a plant extract. In certain embodiments, the cream also includes a surfactant. In certain embodiments, the cream also includes a polymer. The example cream may be packaged in a tube, tub, bottle, or other suitable container.


Example 1

By way of example, a suitable exemplary styling kit or composition may comprises the following formulation, shown as weight percent, except for the base: Water 30-98%; 2-Propanone 10-25%; Sodium hydroxide, to provide a starting pH of about pH 7 to about pH 11, or about pH 8 to about pH 10, or about pH 9; Ethanol 1-5%; Ethyl lactate 1-10%; Phenyl Trimethicone 0-10%; Capric/Capryllic Triglyceride 0-10%; Silk Protein Powder 0-10%; Cetyl Alcohol 0-10%; Stearyl Alcohol 0-10%; Cetrimonium Chloride 0-10%; Glyceryl Stearate 0-10%; PEG-150 Distearate 0-10%; Polysorbate-80 0-10%; DL-Panthenol 0-10%; Cyclopentasiloxane and Dimethicone 0-10%; Quaternium-80 1-10%; Glycerine 0-10%; Ricinus communis (Castor) Seed Oil 0-10%; Cannibis sativa (Hemp) Seed Oil 0-10%; Silk Protein 0-10% Urtica dioica (Nettle) Extract 0-10%; Matricaria recutita (Chamomile) Flower 0-10%; Extract Simmondsia chinensis (Jojoba) Seed Oil 0-10%; PropyleneGlycol 0-10%; Iodopropynyl Butylcarbamate, Diazolidinyl Urea Fragrance 0-10%; and Triethanolamine 0-10% and mixtures or combinations thereof. Before use, the formulation may be stored at temperatures below 50° C.


Example 2

By way of example, a suitable exemplary two part styling kit comprises the following Formulations A and Formulation B, shown as weight percent, except for the base:


Formulation A


Cuticle Penetrating and Keratinous Fiber Fixing Formulation. Water 30-98%; Propanone 20-50%; Potassium hydroxide, to provide a starting pH of about 11.5 to 13.5; Phenyl Trimethicone 0-10%; Capric/Capryllic Triglyceride 0-10%; Silk Protein Powder 0-10%; Cetyl Alcohol 0-10%; Stearyl Alcohol 0-10%; Cetrimonium Chloride 0-10%; Glyceryl Stearate 0-10%; PEG-150 Distearate 0-10%; Polysorbate-80 0-10%; DL-Panthenol 0-10%; Cyclopentasiloxane and Dimethicone 0-10%; Quaternium-80 1-10%; Glycerine 0-10%; Ricinus communis (Castor) Seed Oil 0-10%; Cannibis sativa (Hemp) Seed Oil 0-10%; Silk Protein 0-10%; Urtica dioica (Nettle) Extract 0-10%; Matricaria recutita (Chamomile) Flower 0-10%; Extract Simmondsia chinensis (Jojoba) Seed Oil 0-10%; Propylene Glycol 0-10%; Iodopropynyl Butylcarbamate, Diazolidinyl Urea Fragrance 0-10%; and Triethanolamine 0-10% and mixtures or combinations thereof.


Formulation B


Neutralizing Formulation. Water 30-98%; Ethanol 2-10%; Ethyl lactate 2-20%; Phenyl Trimethicone 0-10%; Capric/Capryllic Triglyceride 0-10%; Silk Protein Powder 0-10%; Cetyl Alcohol 0-10%; Stearyl Alcohol 0-10%; Cetrimonium Chloride 0-10%; Glyceryl Stearate 0-10%; PEG-150 Distearate 0-10%; Polysorbate-80 0-10%; DL-Panthenol 0-10%; Cyclopentasiloxane and Dimethicone 0-10%; Quaternium-80 1-10%; Glycerine 0-10%; Ricinus communis (Castor) Seed Oil 0-10%; Cannibis sativa (Hemp) Seed Oil 0-10%; Silk Protein 0-10%; Urtica dioica (Nettle) Extract 0-10%; Matricaria recutita (Chamomile) Flower 0-10%; Extract Simmondsia chinensis (Jojoba) Seed Oil 0-10%; PropyleneGlycol 0-10%; Iodopropynyl Butylcarbamate, Diazolidinyl Urea Fragrance 0-10%; and Triethanolamine 0-10% and mixtures or combinations thereof.


Formulation A and Formulation B are mixed prior to use to provide a solution of about pH 7 to about pH 11, or about pH 8 to about pH 10, or about pH 9. The keratinous fiber is treated with the resulting formulation at a low heat temperature for about 15 seconds to about 8 minutes or any sub range therebetween.


Example 3

By way of example, a suitable exemplary three part styling kit comprises the following formulations shown as weight percent, except for the base:


Formulation C


Cuticle Penetrating Formulation. Water 30-98%; Lithium hydroxide, to provide a starting pH of about 11.5 to 12.5; Phenyl Trimethicone 0-10%; Quaternium-80 1-10%; Capric/Capryllic Triglyceride 0-10%; Silk Protein Powder 0-10%; Cetyl Alcohol 0-10%; Stearyl Alcohol 0-10%; Cetrimonium Chloride 0-10%; Glyceryl Stearate 0-10%; PEG-150 Distearate 0-10%; Polysorbate-80 0-10%; DL-Panthenol 0-10%; Cyclopentasiloxane and Dimethicone 0-10%; Glycerine 0-10%; Ricinus communis (Castor) Seed Oil 0-10%; Cannibis sativa (Hemp) Seed Oil 0-10%; Silk Protein 0-10%; Urtica dioica (Nettle) Extract 0-10%; Matricaria recutita (Chamomile) Flower 0-10%; Extract Simmondsia chinensis (Jojoba) Seed Oil 0-10%; Propylene Glycol 0-10%; Iodopropynyl Butylcarbamate, Diazolidinyl Urea Fragrance 0-10%; and Triethanolamine 0-10% and mixtures or combinations thereof.


Formulation D


Fixing Formulation Water 30-98%; 2-Propanone 30-75%; Propanone 1-45%; Phenyl Trimethicone 0-10%; Capric/Capryllic Triglyceride 0-10%; Silk Protein Powder 0-10%; Cetyl Alcohol 0-10%; Stearyl Alcohol 0-10%; Cetrimonium Chloride 0-10%; Glyceryl Stearate 0-10%; PEG-150 Distearate 0-10%; Polysorbate-80 0-10%; DL-Panthenol 0-10%; Cyclopentasiloxane and Dimethicone 0-10%; Quaternium-80 1-10%; Glycerine 0-10%; Ricinus communis (Castor) Seed Oil 0-10%; Cannibis sativa (Hemp) Seed Oil 0-10%; Silk Protein 0-10%; Urtica dioica (Nettle) Extract 0-10%; Matricaria recutita (Chamomile) Flower 0-10%; Extract Simmondsia chinensis (Jojoba) Seed Oil 0-10%; Propylene Glycol 0-10%; Iodopropynyl Butylcarbamate, Diazolidinyl Urea Fragrance 0-10%; and Triethanolamine 0-10% and mixtures or combinations thereof.


Formulation E


Neutralizing Formulation. Water 30-98%; Ethanol 3-15%; Phenyl Trimethicone 0-10%; Capric/Capryllic Triglyceride 0-10%; Silk Protein Powder 0-10%; Cetyl Alcohol 0-10%; Stearyl Alcohol 0-10%; Cetrimonium Chloride 0-10%; Glyceryl Stearate 0-10%; PEG-150 Distearate 0-10%; Polysorbate-80 0-10%; DL-Panthenol 0-10%; Cyclopentasiloxane and Dimethicone 0-10%; Quaternium-80 1-10%; Glycerine 0-10%; Ricinus communis (Castor) Seed Oil 0-10%; Cannibis sativa (Hemp) Seed Oil 0-10%; Silk Protein 0-10%; Urtica dioica (Nettle) Extract 0-10%; Matricaria recutita (Chamomile) Flower 0-10%; Extract Simmondsia chinensis (Jojoba) Seed Oil 0-10%; PropyleneGlycol 0-10%; Iodopropynyl Butylcarbamate, Diazolidinyl Urea Fragrance 0-10%; and Triethanolamine 0-10% and mixtures or combinations thereof.


Formulations C, D and E are mixed prior to use to provide a solution of about pH 7 to about pH 11, or about pH 8 to about pH 10, or about pH 9. The keratinous fiber is treated with the resulting formulation at a low heat temperature for about 15 seconds to about 8 minutes or any sub range therebetween.


Example 4

By way of example, a suitable exemplary method for styling hair comprises the following:


washing, wetting, rinsing or otherwise providing undried, wet hair;


treating the undried hair with a composition comprising the following formulation, shown as weight percent, with the exception of the base: Water 30-98%; 2-Propanone 10-25%; Sodium hydroxide, to provide a starting pH of about pH 7 to about pH 11, or about pH 8 to about pH 10, or about pH 9; Ethanol 1-5%; Ethyl lactate 1-10%; Phenyl Trimethicone 0-10%; Capric/Capryllic Triglyceride 0-10%; Silk Protein Powder 0-10%; Cetyl Alcohol 0-10%; Stearyl Alcohol 0-10%; Cetrimonium Chloride 0-10%; Glyceryl Stearate 0-10%; PEG-150 Distearate 0-10%; Polysorbate-80 0-10%; DL-Panthenol 0-10%; Cyclopentasiloxane and Dimethicone 0-10%; Quaternium-80 1-10%; Glycerine 0-10%; Ricinus communis (Castor) Seed Oil 0-10%; Cannibis sativa (Hemp) Seed Oil 0-10%; Silk Protein 0-10% Urtica dioica (Nettle) Extract 0-10%; Matricaria recutita (Chamomile) Flower 0-10%; Extract Simmondsia chinensis (Jojoba) Seed Oil 0-10%; PropyleneGlycol 0-10%; Iodopropynyl Butylcarbamate, Diazolidinyl Urea Fragrance 0-10%; and Triethanolamine 0-10%; and mixtures or combinations thereof and


heating the hair with heated styling plates (e.g., flat iron) at a temperature between about 140° F. to about 210° F., or about 176° F. to about 210° F.


Example 5

By way of example, a suitable exemplary method of styling hair comprises the following:


providing dry hair;


treating the dry hair with a composition comprising the following formulation, shown as weight percent, with the exception of the base: Water 30-98%; 2-Propanone 10-25%; Sodium hydroxide, to provide a starting pH of about pH 7 to about pH 11, or about pH 8 to about pH 10, or about pH 9; Ethanol 1-5%; Ethyl lactate 1-10%; Phenyl Trimethicone 0-10%; Capric/Capryllic Triglyceride 0-10%; Silk Protein Powder 0-10%; Cetyl Alcohol 0-10%; Stearyl Alcohol 0-10%; Cetrimonium Chloride 0-10%; Glyceryl Stearate 0-10%; PEG-150 Distearate 0-10%; Polysorbate-80 0-10%; DL-Panthenol 0-10%; Cyclopentasiloxane and Dimethicone 0-10%; Quaternium-80 1-10%; Glycerine 0-10%; Ricinus communis (Castor) Seed Oil 0-10%; Cannibis sativa (Hemp) Seed Oil 0-10%; Silk Protein 0-10% Urtica dioica (Nettle) Extract 0-10%; Matricaria recutita (Chamomile) Flower 0-10%; Extract Simmondsia chinensis (Jojoba) Seed Oil 0-10%; PropyleneGlycol 0-10%; Iodopropynyl Butylcarbamate, Diazolidinyl Urea Fragrance 0-10%; and Triethanolamine 0-10% and mixtures or combinations thereof;


and styling the keratinous fiber at a temperature between about 140° F. to about 210° F., or about 176° F. to about 210° F. or about 85° C. (185° F.).


All methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context. The use of any and all examples, or exemplary language (e.g., “such as”) provided herein, is intended merely to better illuminate the example embodiments and does not pose a limitation on the scope of the appended claims unless otherwise claimed. No language in the specification should be construed as indicating any non-claimed element as essential. Advantages of the exemplary embodiments described herein may be realized and attained by means of the instrumentalities and combinations particularly pointed out in this written description. It is to be understood that the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the claims below. While example embodiments have been described in detail, the foregoing description is in all aspects illustrative and not restrictive. It is understood that numerous other modifications, combinations, mixtures and variations can be devised without departing from the scope of the example embodiments.


While example embodiments have been described in connection with what is presently considered to be an example of a possible most practical and/or suitable embodiments, it is to be understood that the descriptions are not to be limited to the disclosed embodiments, but on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the example embodiments. Those skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, many equivalents to the specific example embodiments specifically described herein. Such equivalents are intended to be encompassed in the scope of the claims, if appended hereto or subsequently filed.

Claims
  • 1. A composition for styling a keratinous fiber comprising: a cuticle penetrating agent; a protein fixing agent; a neutralizing agent; and a cosmetically suitable carrier.
  • 2. The composition according to claim 1, wherein the cuticle penetrating agent is selected from a member of the group consisting of: potassium hydroxide, sodium hydroxide, calcium hydroxide, barium hydroxide, caesium hydroxide, strontium hydroxide, lithium hydroxide, rubidium hydroxide, lithium carbonate, magnesium carbonate, calcium carbonate, potassium carbonate, potassium bicarbonate, strontium carbonate, lanthanum carbonate, sodium carbonate, sodium bicarbonate, ammonia, urea, acetylurea, guanidine, hydroxyurea, semicarbazide, mono-, di-, or tri(alkyl or aryl)urea, mono-, di- or trialkyl or hydroxyalkyl amine, O-methyl hydroxyl amine(methoxylamine), aniline, butylamine, ethylamine, ethylenediamine, hydrazine, polyamines, (mono or di)alkylaminoalkylacrylate, (mono or di)alkylaminoalkylmethacrylate, trimethylamine, triethylamine (TEA), tributylamine, triisopropylamine, dimethylethylamine, diisopropylethylamine, diethylmethylamine, dimethylisopropylamine, dimethylbutylamine and mixtures thereof.
  • 3. The composition according to claim 1, wherein the protein fixing agent is selected from a member of the group consisting of propanone, butanone, heptanone, and mixtures thereof.
  • 4. The composition according to claim 1, wherein the neutralizing agent is selected from a member of the group consisting of ethyl lactate, propyl lactate, butyl lactate, ethyl acetate, propyl acetate butyl acetate, and mixtures thereof.
  • 5. The composition according to claim 1, further comprising a quaternary ammonium salt.
  • 6. The composition according to claim 1, further comprising a polymerizable monomer.
  • 7. The composition according to claim 1, wherein the initial pH is about pH 8 to about pH 10.
  • 8. A kit for styling keratinous fiber comprising: a vessel containing a cuticle penetrating and keratinous fiber fixing formulation; and a vessel containing neutralizing formulation.
  • 9. The kit according to claim 8, wherein the cuticle penetrating and keratinous fiber fixing formulation has an initial pH of about 11.5 to 13.5 and the neutralizing formulation is selected to reduce the pH to about pH 7 to about pH 11.
  • 10. A method for styling keratinous fibers, comprising: i) treating the keratinous fibers with a formulation comprising a cuticle penetrating agent; a protein fixing agent; a neutralizing agent; and a cosmetically suitable carrier; andii) applying heat to the keratinous fiber at between about 140° F. and about 210° F.
  • 11. The method according to claim 10, further comprising drying the keratinous fibers of the subject before treating.
  • 12. The method according to claim 10, wherein the heat is applied by a member of the group consisting of: flat iron, blow dryer, heated brush, heated brush with a rotating drum and curling iron.
  • 13. The method according to claim 10, wherein the heat is applied to the keratinous fiber at about 176° F. to about 210° F.
  • 14. A method for styling keratinous fibers, comprising: i) mixing a cuticle penetrating formulation and a keratinous fiber fixing formulation with a neutralizing formulation to provide a treatment formulation having an initial pH of about 7;ii) treating the keratinous fibers with the treatment formulation; andiii) applying heat to the keratinous fiber at between about 140° F. and about 210° F.
  • 15. The method according to claim 14, further comprising drying the keratinous fibers of the subject before treating.
  • 16. The method according to claim 14, wherein the heat is applied by a member of the group consisting of: flat iron, blow dryer, heated brush, heated brush with a rotating drum and curling iron.
  • 17. The method according to claim 14, wherein the heat is applied to the keratinous fiber at about 176° F. to about 210° F.
  • 18. The method according to claim 10, further comprising a step of wetting or washing the keratinous fiber before treating.
  • 19. The method according to claim 18, wherein heat is applied to the keratinous fiber at about 176° F. to about 210° F. with heated plates.
  • 20. The method according to claim 13, wherein the cuticle penetrating agent is sodium hydroxide, the protein fixing agent is propanone and the neutralizing agent is ethyl lactate.
  • 21. The method according to claim 20, wherein the formulation further comprises a member selected from the group consisting of exogenous protein, polypeptide, peptide, amino acid, silk protein and silk protein powder.
  • 22. The method according to claim 10, wherein the keratinous fiber is treated with the cuticle penetrating formulation and the keratinous fiber fixing formulation; the neutralizing formulation is added; and heat is applied to the treated keratinous fiber about 176° F. to about 210° F.
  • 23. The method according to claim 22, wherein the formulation further comprises a triglyceride, unsaturated oil, Ricinus communis seed oil or Cannibis sativa seed oil.
  • 24. A kit for styling keratinous fiber comprising: a vessel containing a cuticle penetrating formulation; a vessel containing a keratinous fiber fixing formulation; and a vessel containing a neutralizing formulation.
  • 25. Compositions, formulations, kits and/or methods for treating or styling keratinous fibers substantially as described in the specification, written description, example embodiments, and/or Examples.
CROSS-REFERENCES TO RELATED APPLICATIONS

This application is related to, and claims the benefit of, U.S. Provisional Patent Application No. 61/791,754, filed Mar. 15, 2013, which is incorporated herein by reference in its entirety.

Provisional Applications (1)
Number Date Country
61791754 Mar 2013 US