Compositions of a hydrofluoroether and a hydrofluorocarbon

Abstract
This invention relates to compositions that include at least one fluoroether and at least one hydrofluorocarbon. Included in this invention are compositions of a cyclic or acyclic hydrofluoroether of the formula CaFbH2a+2−bOc wherein a=2 or 3 and 3≦b≦8 and c=1 or 2 and a hydrofluorocarbon of the formula CnFmH2n+2−m wherein 1≦n≦4 and 1≦m≦8. Such compositions may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.
Description




FIELD OF THE INVENTION




This invention relates to compositions that include at least one fluoroether and at least one hydrofluorocarbon. Such compositions may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, displacement drying agents and as carriers for sterilant gases.




Included in this invention are compositions which include a fluoroether and a hydrofluorocarbon in which the halocarbon global warming potential (HGWP) of the hydrofluorocarbon is lowered by adding the fluoroether to the hydrofluorocarbon. Also included in this invention are compositions a fluoroether and a hydrofluorocarbon that are azeotropic or azeotrope-like.




BACKGROUND OF THE INVENTION




Fluorinated hydrocarbons have many uses, one of which is as a refrigerant. Such refrigerants include dichlorodifluoromethane (CFC-12) and chlorodifluoromethane (HCFC-22).




In recent years it has been suggested that certain chlorofluorocarbon (CFC) and hydrochlorofluorocarbon (HCFC) refrigerants released into the atmosphere may adversely affect the ozone layer. Although this proposition has not yet been completely established, there is a movement toward the control of the use and the production of certain CFCs and HCFCs under an international agreement.




In order to address the potential problem of ozone depletion, it has been suggested that chlorofluorocarbon refrigerants and hydrochlorofluorocarbon refrigerants be replaced with hydrofluorocarbon refrigerants. Since the hydrofluorocarbon (HFC) refrigerants contain no chlorine, they have zero ozone depletion potential.




Another environmental concern is the role of CFCs in the “greenhouse effect”. The greenhouse effect refers to the warming of the Earth's climate that takes place when atmospheric gases, which are relatively transparent to visible light and allow sunshine to reach the Earth, trap heat by absorbing infrared radiation released by the Earth.




There is presently no universally accepted methodology for combining all relevant factors into a singe global warming potential for emissions of gases such as CFCs. One approach is to define the greenhouse effect of a compound in terms of a potential to enhance global warming relative to a known standard. One such definition is known as a halocarbon global warming potential (HGWP), which is the ratio of incremental radiative warming resulting from an emission of a gas, over the lifetime of the gas in the atmosphere, to the calculated warming that would result from a release of the same mass of reference gas CFC-11.




While HFCs may have a zero ozone depletion potential, some HFCs may have an HGWP that may be undesirable and subject to governmental regulation. Accordingly, there is also a demand for the development of refrigerants that have a low ozone depletion potential while at the same time having a low HGWP.




It is preferred that refrigerants that include more than one component be azeotropic or azeotrope-like so that the composition of the refrigerant does not change when leaked or discharged to the atmosphere from refrigeration equipment. A change in composition of a refrigerant may affect its properties, such as performance or flammability.




It is also desirable to use compositions that have a low ozone depletion potential and/or a low HGWP and/or that are azeotropic or azeotrope-like as cleaning agents, blowing agents in the manufacture of closed-cell polyurethane, phenolic and thermoplastic foams, as propellants in aerosols, as heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, such as for heat pumps, inert media for polymerization reactions, fluids for removing particulates from metal surfaces, as carrier fluids that may be used, for example, to place a fine film of lubricant on metal parts, or as buffing abrasive agents to remove buffing abrasive compounds from surfaces such as metal, as displacement drying agents for removing water, such as from jewelry or metal parts, as resist developers in conventional circuit manufacturing techniques including chlorine-type developing agents, and as strippers for photoresists when used with, for example, a chlorohydrocarbon, such as 1,1,1-trichloroethane or trichloroethylene.




SUMMARY OF THE INVENTION




This invention relates to compositions that include a fluoroether and a hydrofluorocarbon. Included in this invention are compositions of a cyclic or acyclic hydrofluoroether of the formula C


a


F


b


H


2a+2−b


O


c


wherein a=2 or 3 and 3≦b≦8 and c=1 or 2 and a hydrofluorocarbon of the formula C


n


F


m


H


2n+2−m


wherein 1≦n≦4 and 1≦m≦8. Such compositions may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.




Another aspect of this invention relates to the discovery that the HGWP of a hydrofluorocarbon can be lowered by adding to the hydrofluorocarbon a fluoroether having a lower HGWP than the HGWP of the hydrofluorocarbon. Accordingly, the present invention relates to a composition of a first component that includes a hydrofluorocarbon and a second component that includes a fluoroether that has an HGWP less than the HGWP of the first component, such that the HGWP of the composition is less than the HGWP of the first component.




Also included in this invention are compositions which include a fluoroether and a hydrofluorocarbon that are azeotropic or azeotrope-like.











DETAILED DESCRIPTION




The present invention relates to compositions that include a fluoroether and a hydrofluorocarbon (HFC). Included in this invention are compositions of a cyclic or acyclic hydrofluoroether of the formula C


a


F


b


H


2a+2−b


O


c


wherein a=2 or 3 and 3≦b≦8 and c=1 or 2 and a hydrofluorocarbon of the formula C


n


F


m


H


2n+2−m


wherein 1≦n≦4 and 1≦m≦8. These compositions may be used as refrigerants, cleaning agents, expansion agents for polyolefins and polyurethanes, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, power cycle working fluids, polymerization media, particulate removal fluids, carrier fluids, buffing abrasive agents, and displacement drying agents.




The fluoroethers that are included in this invention have two or three carbon atoms. Examples of such fluoroethers include the following.




1. Hexafluorodimethyl ether (116E, or CF


3


OCF


3


, boiling point=−59.0° C.),




2. Pentafluorodimethyl ether (125E, or CHF


2


OCF


3


, boiling point=−36.2° C.),




3. Bis(difluoromethyl) ether (134E, or CHF


2


OCHF


2


, boiling point=5° C.),




4. Fluoromethyl trifluoromethyl ether (134aE, or CH


2


FOCF


3


, boiling point=−20.0° C.),




5. Trifluoromethyl methyl ether (143aE, or CH


3


OCF


3


, boiling point=−24.2° C.),




6. Perfluorooxetane (C-216E or











 boiling point=−29.2° C.),




7. 2,2,4,4,5,5-hexafluoro-1,3-dioxolane (C-216E2 or C


3


F


6


O


2


, having a structure of











 boiling point=−22.1° C.),




8. Perfluoromethyl ethyl ether (218E, or CF


3


OCF


2


CF


3


, boiling point=−23.3° C.),




9. Perfluorodimethoxymethane (218E2, or CF


3


OCF


2


OCF


3


, boiling point=−10.2° C.),




10. 2,2,3,4,4-pentafluorooxetane (C-225eEαβ, or C


3


HF


5


O, having a structure of











 boiling point=3.4° C.),




11. 1-trifluoromethoxy-1,1,2,2-tetrafluoroethane (227caEαβ, or CF


3


OCF


2


CHF


2


, boiling point=about −3° C.),




12. Difluoromethoxy pentafluoroethane (227caEβγ, or CHF


2


OCF


2


CF


3


, boiling point=−8.0° C.),




13. 1-trifluoromethoxy-1,2,2,2-tetrafluoroethane (227eaE, or CF


3


OCHFCF


3


, boiling point=−9.4° C.),




14. 2,2,4,4-tetrafluorooxetane (C-234fEαβ, or C


3


H


2


F


4


O, having a structure of











 boiling point=21.2° C.),




15. 2,2,3,3-tetrafluorooxetane (C-234fEβγ, or C


3


H


2


F


4


O, having a structure of











 boiling point=28° C.),




16. 1-difluoromethoxy-1,1,2,2-tetrafluoroethane (236caE, or CHF


2


OCF


2


CHF


2


, boiling point=28.5° C.),




17. 1-difluoromethoxy-1,2,2,2-tetrafluoroethane (236eaEβγ, or CHF


2


OCHFCF


3


, boiling point=23.2° C.),




18. 1-trifluoromethoxy-2,2,2-trifluoroethane (236faE, or CF


3


OCH


2


CF


3


, boiling point=5.6° C.),




19. 1-difluoromethoxy-2,2,2-trifluoroethane (245faEβγ, or CHF


2


OCH


2


CF


3


, boiling point=29° C.).




116E (CAS Reg. No. 1479-49-8) has been prepared by electrochemical fluorination of dimethyl ether as disclosed by Simons in U.S. Pat. No. 2,519,983.




125E (CAS Reg. No. 3822-68-2) has been prepared by electrochemical fluorination of dimethyl ether (CH


3


OCH


3


) as disclosed by Fox, et. al. in U.S. Pat. No. 3,511,760 and by Hutchinson in U.S. Pat. No. 3,887,439.




134E (CAS Reg. No. 1691-17-4) can be prepared by reaction of antimony trifluoride with CHF


2


OCHCl


2


as disclosed by O'Neill in GB 2,248,617.




134aE (CAS Reg. No. 2261-01-0) has been made by the electrochemical fluorination of methyl 2-methoxypropionate as reported by Berenblit, et. al. Zh. Org. Khim., Vol. 12, pp. 767-770 (1976).




143aE (CAS Reg. No. 421-14-7) has been made by the reaction of methyl fluoroformate with sulfur tetrafluoride as reported by Aldrich and Sheppard, J. Am. Chem. Soc., Vol. 29, 11-15 (1964).




C-216E (CAS Reg. No. 425-82-1) can be made by electrochemical fluorination of trimethylene oxide (oxetane) in anhydrous hydrogen fluoride as disclosed by Kauck and Simons in U.S. Pat. No. 2,594,272.




C-216E2 (CAS Reg. No. 21297-65-4) has been prepared by UV irradiation of perfluoro-b-oxa-d-valerolactone in the vapor or liquid phase as reported by Throckmorton in


J. Org. Chem


., Vol. 34, pp. 3438-3440 (1969). The lactone was prepared by the reaction of KF with perfluorooxydiacetyl chloride.




218E (CAS Reg. No. 665-16-7) has been made by direct fluorination of CF


3


OCH


2


CF


3


(prepared by reaction of CF


3


OF. with vinylidene fluoride) as reported by Sekiya and Ueda in Chemistry Letters, pp. 609-612 (1990).




218E2 (CAS Reg. No. 53772-78-4) was made in the electrochemical fluorination of methyl 2-methoxypropionate as reported by Berenblit, et. al. Zh. Org. Khim., Vol. 12, pp. 767-770 (1976).




C-225eEαβ (CAS Reg. No. 144109-03-5) may be prepared by direct fluorination of trimethylene oxide (cyclo-CH


2


CH


2


CH


2


O—) using techniques described by Lagow and Margrave in


Progress in Inorganic Chemistry


, Vol. 26, pp. 161-210 (1979) or by Adcock and Cherry in


Ind. Eng. Chem. Res.


, Vol. 26, pp. 208-215 (1987). The direct fluorination is carried out to the desired level of fluorine incorporation into the starting material, and products receovered by fractional distillation.




227caEαβ (CAS Reg. No. 2356-61-8) has been prepared by reacting difluoroacetyl fluoride with cesium fluoride and carbonyl fluoride followed by treatment with sulfur tetrafluoride as disclosed by Eisemann in U.S. Pat. No. 3,362,190.




227caEβγ (CAS Reg. No. 53997-64-1) has been made by electrochemical fluorination of CHCl


2


OCF


2


CHClF as reported by Okazaki, et. al. J. Fluorine Chem., Vol. 4, pp. 387-397 (1974).




227eaE (CAS Reg. No. 2356-62-9) was prepared by reacting 2-trifluoromethoxy-tetrafluoropropionyl fluoride (CF


3


CF(OCF


3


)COF) with aqueous potassium hydroxide at 230° C. as disclosed by Eisemann in U.S. Pat. No. 3,362,190.




C-234fEαβ may be prepared by direct fluorination of trimethylene oxide (cyclo-CH


2


CH


2


CH


2


O—) using techniques described by Lagow and Margrave in


Progress in Inorganic Chemistry


, Vol. 26, pp. 161-210 (1979) or by Adcock and Cherry in


Ind. Eng. Chem. Res


., Vol. 26, pp. 208-215 (1987). The direct fluorination is carried out to the desired level of fluorine incorporation into the starting material, and products receovered by fractional distillation.




C-234fEβγ (CAS Reg. No. 765-63-9) has been prepared by Weinmayr (


J. Org. Chem


., Vol. 28, pp. 492-494 (1963)) as a by-product from the reaction of TFE with formaldehyde in HF.




236caE (CAS Reg. No. 32778-11-3) has been prepared by fluorination of CHCl


2


OCF


2


CHF


2


(prepared in turn by chlorination of CH


3


OCF


2


CHF


2


) using anhydrous hydrogen fluoride with antimony pentachloride catalyst as reported by Terrell, et. al. in J. Medicinal Chem., Vol. 15, pp. 604-606 (1972).




236eaEβγ (CAS Reg. No. 57041-67-5) has been prepared by chlorination of methoxy acetyl chloride to give the intermediate, CHCl


2


OCHClCOCl, which was isolated and reacted with sulfur tetrafluoride at 150C. to give the product as disclosed by Halpern and Robin in U.S. Pat. No. 4,888,139.




236faE (CAS Reg. No. 20193-67-3) has been prepared by reaction of 2,2,2-trifluoroethanol with carbonyl fluoride to give the intermediate, CF


3


CH


2


OCOF, which was in turn reacted with sulfur tetrafluoride at 150-200° C. to give the product as disclosed by Eisemann in U.S. Pat. No. 3,394,878.




245faEβγ (CAS Reg. No. 1885-48-9) has been prepared by the reaction of chlorodifluoromethane with trifluoroethanol in the presence of potassium hydroxide as disclosed by Croix in U.S. Pat. No. 3,637,477.




The HFCs that may be combined with the fluoroethers include one or more of the following: difluoromethane (HFC-32), fluoromethane (HFC-41), pentafluoroethane (HFC-125), 1,1,2,2-tetrafluoroethane (HFC-134), 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1,2-trifluoroethane (HFC-143), 1,1,1-trifluoroethane (HFC-143a), 1,1-difluoroethane (HFC-152a), fluoroethane (HFC-161), 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca), 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ca), 1,1,1,3,3,3-hexafluoro-propane (HFC-236fa), 1,1,2,2,3,3-hexafluoropropane (HFC-236ca), 1,1,1,2,2,3-hexafluoropropane (HFC-236cb), 1,1,2,2,3-pentafluoropropane (HFC-245ca), 1,1,1,2,2-pentafluoropropane (HFC-245cb), 1,1,2,3,3-pentafluoropropane (HFC-245ea), 1,1,1,3,3-pentafluoropropane (HFC-245 fa), 1,2,2,3-tetrafluoropropane (HFC-254ca), 1,1,2,2-tetrafluoropropane (HFC-254cb), 1,1,1,2-tetrafluoropropane (HFC-254eb), 1,2,2-trifluoropropane (HFC-263ca), 1,1,1-trifluoropropane (HFC-263fb), 2,2-difluoropropane (HFC-272ca), 1,2-difluoropropane (HFC-272ea), 1,1-difluoropropane (HFC-272fb), 2-fluoropropane (HFC-281ea), 1-fluoropropane (HFC-281fa), 1,1,1,3,3,4,4,4-octafluorobutane (HFC-338mf), 1,1,1,4,4,4-hexafluorobutane (HFC-356mff), or (CF


3


)


2


CHCH


3


, (HFC-356 mmz).




The following can be used as refrigerants: compositions of a cyclic or acyclic hydrofluoroether of the formula C


a


F


b


H


2a+2−b


O


c


wherein a=2 or 3 and 3≦b≦8 and c=1 or 2 and a hydrofluorocarbon of the formula C


n


F


m


H


2n+2−m


wherein 1≦n≦4 and 1≦m≦8. Examples of such compositions include the following.




1-99 weight percent 116E and 1-99 weight percent HFC-32, HFC-41, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236ea, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent 125E and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent 134E and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236ea, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, HFC-281fa, HFC-338mf or 356mff.




1-99 weight percent 134aE and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent 143aE and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent C216E, and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent C-216E2 and 1-99 weight percent HFC-32, HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161, or HFC-245cb.




1-99 weight percent 218E and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent 218E2 and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fa, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent C-225eEαβ and 1-99 weight percent HFC-143, HFC-236cb, HFC-236ea, or HFC-245cb.




1-99 weight percent 227caEαβ and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent 227caEβγ and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ca, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent 227eaE and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent C-234fEαβ and 1-99 weight percent HFC-245cb, HFC-245eb, HFC-356mff or HFC-356mmz.




1-99 weight percent C-234fEβγ and 1-99 weight percent HFC-245ca, HFC-245cb, HFC-245ea, HFC-254ca, HFC-356mff or HFC-356mmz.




1-99 weight percent 236eaE and 1-99 weight percent HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent 236caEβγ and 1-99 weight percent HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, HFC-281fa, HFC-338mf, HFC-356mff or HFC-356mmz.




1-99 weight percent 236faE and 1-99 weight percent HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, or HFC-281fa.




1-99 weight percent 245faEβγ and 1-99 weight percent HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a, HFC-161, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236fa, HFC-245ca, HFC-245cb, HFC-245ea, HFC-245fa, HFC-254ca, HFC-254cb, HFC-254eb, HFC-263ca, HFC-263fb, HFC-272ca, HFC-272ea, HFC-272fb, HFC-281ea, HFC-281fa, or HFC-356mff. The present invention also relates to the discovery of azeotropic or azeotrope-like compositions of effective amounts of the following compounds to form an azeotropic or azeotrope-like composition at a specific temperature or pressure:




116E and HFC-32, HFC-41, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a or HFC-161; 125E and HFC-32, HFC-134, HFC-134a, HFC-143, HFC-152a or HFC-161; 134E and HFC-143, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236ea, HFC-236fa, HFC-245cb, HFC-254cb, HFC-254eb, HFC-338mf, or HFC-356mff; 134aE and HFC-32, HFC-134, HFC-143, HFC-152a, HFC-227ca, HFC-227ea or HFC-245cb; 143aE and HFC-32, HFC-134, HFC-143a, HFC-152a, HFC-227ca, HFC-227ea or HFC-245cb; C216E and HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161 or HFC-245cb; C216E2 and HFC-32, HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161 or HFC-245cb; 218E and HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161 or HFC-263fb; 218E2 and HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161, HFC-236fa or HFC-263fb; C-225eEαβ and HFC-143, HFC-236cb, HFC-236ea or HFC-245cb; 227caEαβ and HFC-32, HFC-143, HFC-245cb, HFC-272ca, HFC-281ea or HFC-281fa; 227caEβγ and HFC-32, HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161, HFC-263fb, HFC-272ca, HFC-281ea or HFC-281fa; 227eaE and HFC-32, HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161, HFC-263fb, HFC-272ca, HFC-281ea or HFC-281fa; C-234fEαβ and HFC-245cb, HFC-245eb, HFC-356mff or HFC-356mmz; C-234fEβγ and HFC-245ca, HFC-245cb, HFC-245ea, HFC-254ca, HFC-356mff or HFC-356mmz; 236caE and HFC-143, HFC-245ca, or HFC-254ca; 236eaEβγ and HFC-143, HFC-245ca, HFC-263ca, HFC-338mf, HFC-356mff or HFC-356mmz; or 236faE and HFC-32, HFC-143, HFC-272ca, HFC-272fb or HFC-281fa; 245faEβγ and HFC-356mff.




By “azeotropic” composition is meant a constant boiling liquid admixture of two or more substances that behaves as a single substance. One way to characterize an azeotropic composition is that the vapor produced by partial evaporation or distillation of the liquid has the same composition as the liquid from which it was evaporated or distilled, that is, the admixture distills/refluxes without compositional change. Constant boiling compositions are characterized as azeotropic because they exhibit either a maximum or minimum boiling point, as compared with that of the non-azeotropic mixtures of the same components.




By “azeotrope-like” composition is meant a constant boiling, or substantially constant boiling, liquid admixture of two or more substances that behaves as a single substance. One way to characterize an azeotrope-like composition is that the vapor produced by partial evaporation or distillation of the liquid has substantially the same composition as the liquid from which it was evaporated or distilled, that is, the admixture distills/refluxes without substantial compositional change.




It is recognized in the art that a composition is azeotrope-like if, after 50 weight percent of the composition is removed such as by evaporation or boiling off, the difference in vapor pressure between the original composition and the composition remaining after 50 weight percent of the original composition has been removed is less than 10 percent, when measured in absolute units. By absolute units, it is meant measurements of pressure and, for example, psia, atmospheres, bars, torr, dynes per square centimeter, millimeters of mercury, inches of water and other equivalent terms well known in the art. If an azeotrope is present, there is no difference in vapor pressure between the original composition and composition remaining after 50 weight percent of the original composition has been removed.




Therefore, included in this invention are compositions of effective amounts of a fluoroether and an HFC such that after 50 weight percent of an original composition is evaporated or boiled off to produce a remaining composition, the difference in the vapor pressure between the original composition and the remaining composition is about 10 percent or less. Examples of such compositions include the following:




116E and HFC-32, HFC-41, HFC-125, HFC-134, HFC-134a, HFC-143, HFC-143a, HFC-152a or HFC-161; 125E and HFC-32, HFC-134, HFC-134a, HFC-143, HFC-152a or HFC-161; 134E and HFC-143, HFC-227ca, HFC-227ea, HFC-236ca, HFC-236cb, HFC-236ea, HFC-236fa, HFC-245cb, HFC-254cb, HFC-254eb, HFC-338mf or HFC-356mff; 134aE and HFC-32, HFC-134, HFC-143, HFC-152a, HFC-227ca, HFC-227ea or HFC-245cb; 143aE and HFC-32, HFC-134, HFC-143a, HFC-152a, HFC-227ca, HFC-227ea or HFC-245cb; C216E and HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161 or HFC-245cb; C-216E2 and HFC-32, HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161 or HFC-245cb; 218E and HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161 or HFC-263fb; 218E2 and HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161, HFC-236fa or HFC-263fb; C-225eEαβ and HFC-143, HFC-236cb, HFC-236ea or HFC-245cb; 227caEαβ and HFC-32, HFC-143, HFC-245cb, HFC-272ca, HFC-281ea or HFC-281fa; 227caEβγ and HFC-32, HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161, HFC-263fb, HFC-272ca, HFC-281ea or HFC-281fa; 227eaE and HFC-32, HFC-134, HFC-134a, HFC-143, HFC-152a, HFC-161, HFC-263fb, HFC-272ca, HFC-281ea or HFC-281fa; C-234fEαβ and HFC-245cb, HFC-245eb, HFC-356mff or HFC-356mmz; C-234fEβγ and HFC-245ca, HFC-245cb, HFC-245ea, HFC-254ca, HFC-356mff or HFC-356mmz; 236caE and HFC-143, HFC-245ca or HFC-254ca; 236eaEβγ and HFC-143, HFC-245ca, HFC-263ca, HFC-338mf, HFC-356mff or HFC-356mmz; 236faE and HFC-32, HFC-143, HFC-272ca, HFC-272fb or HFC-281fa; or 245faEβγ and HFC-356mff.




Substantially constant boiling, azeotropic or azeotrope-like compositions of this invention comprise the following (all at 25° C.):














TABLE 1









COMPONENTS




WEIGHT RANGES




PREFERRED











116E/HFC-32




50.0-88.0/12.0-50.0




50.0-88.0/12.0-50.0






116E/HFC-41




5.0-84.0/16.0-95.0




40.0-84.0/16.0-60.0






116E/HFC-125




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






116E/HFC-134




52.0-99.0/1.0-48.0




70.0-99.0/1.0-30.0






116E/HFC-134a




53.0-99.0/1.0-47.0




53.0-99.0/1.0-47.0






116E/HFC-143




60.0-99.0/1.0-40.0




60.0-99.0/1.0-40.0






116E/HFC-143a




1.0-99.0/1.0-99.0




30.0-99.0/1.0-70.0






116E/HFC-152a




60.0-99.0/1.0-40.0




60.0-99.0/1.0-40.0






116E/HFC-161




60.0-99.0/1.0-40.0




60.0-99.0/1.0-40.0






125E/HFC-32




25.0-73.0/27.0-75.0




30.0-70.0/30.0-70.0






125E/HFC-134




37.0-99.0/1.0-63.0




70.0-99.0/1.0-30.0






125E/HFC-134a




1.0-99.0/1.0-99.0




1.0-50.0/50.0-99.0






125E/HFC-143




1.0-43.0/57.0-99.0




1.0-30.0/70.0-99.0






125E/HFC-152a




1.0-61.0/39.0-99.0




1.0-40.0/60.0-99.0






125E/HFC-161




1.0-71.0/29.0-99.0




30.0-50.0/50.0-70.0






134E/HFC-143




1.0-99.0/1.0-99.0




1.0-50.0/50.0-99.0






134E/HFC-227ca




1.0-51.0/49.0-99.0




1.0-40.0/60.0-99.0






134E/HFC-227ea




1.0-49.0/51.0-99.0




1.0-40.0/60.0-99.0






134E/HFC-236ca




1.0-99.0/1.0-99.0




30.0-99.0/1.0-70.0






134E/HFC-236cb




1.0-99.0/1.0-99.0




1.0-70.0/30.0-99.0






134E/HFC-236ea




1.0-99.0/1.0-99.0




30.0-70.0/30.0-70.0






134E/HFC-236fa




1.0-99.0/1.0-99.0




1.0-80.0/20.0-99.0






134E/HFC-245cb




1.0-62.0/38.0-99.0




1.0-50.0/50.0-99.0






134E/HFC-254cb




1.0-99.0/1.0-99.0




1.0-70.0/30.0-99.0






134E/HFC-254eb




1.0-99.0/1.0-99.0




1.0-99.0/1.0-99.0






134E/HFC-338mf




27.0-99.0/1.0-73.0




40.0-80.0/20.0-60.0






134E/HFC-356mff




40.0-99.0/1.0-60.0




40.0-99.0/1.0-60.0






134aE/HFC-32




1.0-55.0/45.0-99.0




1.0-55.0/45.0-99.0






134aE/HFC-134




1.0-99.0/1.0-99.0




20.0-60.0/40.0-80.0






134aE/HFC-143




52.0-99.0/1.0-48.0




52.0-99.0/1.0-48.0






134aE/HFC-152a




1.0-99.0/1.0-99.0




1.0-99.0/1.0-99.0






134aE/HFC-227ca




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






134aE/HFC-227ea




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






134aE/HFC-245cb




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






143aE/HFC-32




1.0-54.0/46.0-99.0




1.0-54.0/46.0-99.0






143aE/HFC-134




1.0-99.0/1.0-99.0




30.0-99.0/1.0-70.0






143aE/HFC-143a




1.0-53.0/47.0-99.0




1.0-53.0/47.0-99.0






143aE/HFC-152a




1.0-99.0/1.0-99.0




20.0-80.0/20.0-80.0






143aE/HFC-227ca




1.0-99.0/1.0-99.0




1.0-80.0/20.0-99.0






143aE/HFC-227ea




1.0-99.0/1.0-99.0




1.0-90.0/10.0-99.0






143aE/HFC-245cb




20.0-99.0/1.0-80.0




20.0-80.0/20.0-80.0






C216E/HFC-134




1.0-99.0/1.0-99.0




50.0-99.0/1.0-50.0






C216E/HFC-134a




1.0-99.0/1.0-99.0




20.0-80.0/20.0-80.0






C216E/HFC-143




61.0-99.0/1.0-39.0




61.0-99.0/1.0-39.0






C216E/HFC-152a




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






C216E/HFC-161




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






C216E/HFC-245cb




1.0-99.0/1.0-99.0




30.0-99.0/1.0-70.0






C216E2/HFC-32




1.0-70.0/30.0-99.0




30.0-70.0/30.0-70.0






C216E2/HFC-134




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






C216E2/HFC-134a




1.0-99.0/1.0-99.0




1.0-80.0/20.0-99.0






C216E2/HFC-143




58.0/99.0/1.0-42.0




58.0-99.0/1.0-42.0






C216E2/HFC-152a




1.0-99.0/1.0-99.0




40.0-99.0/1.0-60.0






C216E2/HFC-161




1.0-84.0/16.0-99.0




20.0-84.0/16.0-80.0






C216E2/HFC-245cb




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






218E/HFC-134




35.0-99.0/1.0-65.0




50.0-80.0/20.0-50.0






218E/HFC-134a




1.0-99.0/1.0-99.0




20.0-80.0/20.0-80.0






218E/HFC-143




57.0-99.0/1.0-43.0




57.0-99.0/1.0-43.0






218E/HFC-152a




41.0-99.0/1.0-59.0




41.0-99.0/1.0-59.0






218E/HFC-161




39.0-84.0/16.0-61.0




39.0-84.0/16.0-61.0






218E/HFC-263fb




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






218E2/HFC-134




1.0-79.0/21.0-99.0




20.0-70.0/30.0-80.0






218E2/HFC-134a




1.0-72.0/28.0-99.0




1.0-60.0/40.0-99.0






218E2/HFC-143




52.0-91.0/9.0-48.0




52.0-91.0/9.0-48.0






218E2/HFC-152a




1.0-81.0/19.0-99.0




20.0-70.0/30.0-80.0






218E2/HFC-161




1.0-77.0/23.0-99.0




20.0-77.0/23.0-80.0






218E2/HFC-236fa




1.0-99.0/1.0-99.0




30.0-99.0/1.0-70.0






218E2/HFC-263fb




1.0-99.0/1.0-99.0




20.0-90.0/10.0-80.0






C225eEαβ/HFC-143




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






C225eEαβ/HFC-236cb




1.0-99.0/1.0-99.0




1.0-80.0/20.0-99.0






C225eEαβ/HFC-236ea




1.0-99.0/1.0-99.0




30.0-99.0/1.0-70.0






C225eEαβ/HFC-245cb




1.0-65.0/35.0-99.0




1.0-65.0/35.0-99.0






227caEαβ/HFC-32




1.0-61.0/39.0-99.0




1.0-61.0/39.0-99.0






227caEαβ/HFC-143




42.0-99.0/1.0-58.0




42.0-95.0/5.0-58.0






227caEαβ/HFC-245cb




1.0-82.0/18.0-99.0




1.0-80.0/20.0-99.0






227caEαβ/HFC-272ca




1.0-99.0/1.0-99.0




30.0-99.0/1.0-70.0






227caEαβ/HFC-281ea




1.0-99.0/1.0-99.0




40.0-99.0/1.0-60.0






227caEαβ/HFC-281fa




1.0-99.0/1.0-99.0




40.0-99.0/1.0-60.0






227caEβγ/HFC-32




1.0-67.0/33.0-99.0




1.0-67.0/33.0-99.0






227caEβγ/HFC-134




1.0-76.0/24.0-99.0




10.0-50.0/50.0-90.0






227caEβγ/HFC-134a




1.0-67.0/33.0-99.0




1.0-67.0/33.0-99.0






227caEβγ/HFC-143




46.0-91.0/9.0-54.0




46-91.0/9.0-54.0






227caEβγ/HFC-152a




1.0-78.0/22.0-99.0




10.0-78.0/22.0-90.0






227caEβγ/HFC-161




1.0-72.0/28.0-99.0




10.0-72.0/28.0-90.0






227caEβγ/HFC-263fb




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






227caEβγ/HFC-272ca




1.0-99.0/1.0-99.0




30.0-99.0/1.0-70.0






227caEβγ/HFC-281ea




1.0-99.0/1.0-99.0




40.0-99.0/1.0-60.0






227caEβγ/HFC-281fa




1.0-99.0/1.0-99.0




40.0-99.0/1.0-60.0






227eaE/HFC-32




1.0-68.0/32.0-99.0




10.0-68.0/32.0-90.0






227eaE/HFC-134




1.0-78.0/22.0-99.0




10.0-60.0/40.0-90.0






227eaE/HFC-134a




1.0-70.0/30.0-99.0




1.0-60.0/40.0-99.0






227eaE/HFC-143




47.0-92.0/8.0-53.0




47.0-92.0/8.0-53.0






227eaE/HFC-152a




1.0-80.0/20.0-99.0




10.0-80.0/20.0-90.0






227eaE/HFC-161




1.0-73.0/27.0-99.0




20.0-73.0/27.0-80.0






227eaE/HFC-263fb




1.0-99.0/1.0-99.0




30.0-99.0/1.0-70.0






227eaE/HFC-272ca




30.0-99.0/1.0-70.0




30.0-99.0/1.0-70.0






227eaE/HFC-281ea




1.0-99.0/1.0-99.0




40.0-99.0/1.0-60.0






227eaE/HFC-281fa




1.0-99.0/1.0-99.0




40.0-99.0/1.0-60.0






C234fEαβ/HFC-245cb




1.0-58.0/42.0-99.0




1.0-58.0/42.0-99.0






C234fEαβ/HFC-245eb




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






C234fEαβ/HFC-356mff




1.0-99.0/1.0-99.0




20.0-80.0/20.0-80.0






C234fEαβ/HFC-356mmz




1.0-99.0/1.0-99.0




20.0-80.0/20.0-80.0






C-234fEβγ/HFC-245ca




1.0-99.0/1.0-99.0




10.0-80.0/20.0-90.0






C-234fEβγ/HFC-245cb




1.0-56.0/46.0-99.0




1.0-40.0/60.0-99.0






C-234fEβγ/HFC-245ea




1.0-99.0/1.0-99.0




10.0-89.0/21.0-90.0






C-234fEβγ/HFC-254ca




1.0-99.0/1.0-99.0




10.0-99.0/1.0-90.0






C-234fEβγ/HFC-356mff




1.0-99.0/1.0-99.0




20.0-80.0/20.0-80.0






C-234fEβγ/HFC-356mmz




1.0-82.0/18.0-99.0




1.0-60.0/40.0-99.0






236caE/HFC-143




1.0-60.0/40.0-99.0




10.0-60.0/40.0-90.0






236caE/HFC-254ca




1.0-99.0/1.0-99.0




1.0-80.0/20.0-99.0






236caE/HFC-245ca




1.0-99.0/1.0-99.0




1.0-80.0/20.0-99.0






236eaEβγ/HFC-143




1.0-66.0/34.0-99.0




10.0-66.0/34.0-90.0






236eaEβγ/HFC-245ca




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






236eaEβγ/HFC-263ca




1.0-99.0/1.0-99.0




1.0-99.0/1.0-99.0






236eaEβγ/HFC-338mf




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






236eaEβγ/HFC-356mff




1.0-99.0/1.0-99.0




20.0-99.0/1.0-80.0






236eaEβγ/HFC-356mmz




1.0-99.0/1.0-99.0




1.0-80.0/20.0-99.0






236faE/HFC-32




1.0-55.0/45.0-99.0




1.0-55.0/45.0-99.0






236faE/HFC-143




28.0-84.0/16.0-72.0




30.0-84.0/16.0-70.0






236faE/HFC-272ca




1.0-99.0/1.0-99.0




10.0-99.0/1.0-90.0






236faE/HFC-272fb




1.0-99.0/1.0-99.0




40.0-99.0/1.0-60.0






236faE/HFC-281fa




1.0-99.0/1.0-99.0




1.0-99.0/1.0-99.0






245faEβγ/HFC-356mff




1.0-99.0/1.0-99.0




1.0-70.0/30.0-99.0














For purposes of this invention, “effective amount” is defined as the amount of each component of the inventive compositions which, when combined, results in the formation of an azeotropic or azeotrope-like composition. This definition includes the amounts of each component, which amounts may vary depending on the pressure applied to the composition so long as the azeotropic or azeotrope-like compositions continue to exist at the different pressures, but with possible different boiling points.




Therefore, effective amount includes the amounts, such as may be expressed in weight percentages, of each component of the compositions of the instant invention which form azeotropic or azeotrope-like compositions at temperatures or pressures other than as described herein.




For the purposes of this discussion, azeotropic or constant-boiling is intended to mean also essentially azeotropic or essentially-constant boiling. In other words, included within the meaning of these terms are not only the true azeotropes described above, but also other compositions containing the same components in different proportions, which are true azeotropes at other temperatures and pressures, as well as those equivalent compositions which are part of the same azeotropic system and are azeotrope-like in their properties. As is well recognized in this art, there is a range of compositions which contain the same components as the azeotrope, which will not only exhibit essentially equivalent properties for refrigeration and other applications, but which will also exhibit essentially equivalent properties to the true azeotropic composition in terms of constant boiling characteristics or tendency not to segregate or fractionate on boiling.




It is possible to characterize, in effect, a constant boiling admixture which may appear under many guises, depending upon the conditions chosen, by any of several criteria:




The composition can be defined as an azeotrope of A, B, C (and D . . . ) since the very term “azeotrope” is at once both definitive and limitative, and requires that effective amounts of A, B, C (and D . . . ) for this unique composition of matter which is a constant boiling composition.




It is well known by those skilled in the art, that, at different pressures, the composition of a given azeotrope will vary at least to some degree, and changes in pressure will also change, at least to some degree, the boiling point temperature. Thus, an azeotrope of A, B, C (and D . . . ) represents a unique type of relationship but with a variable composition which depends on temperature and/or pressure. Therefore, compositional ranges, rather than fixed compositions, are often used to define azeotropes.




The composition can be defined as a particular weight percent relationship or mole percent relationship of A, B, C (and D . . . ), while recognizing that such specific values point out only one particular relationship and that in actuality, a series of such relationships, represented by A, B, C (and D . . . ) actually exist for a given azeotrope, varied by the influence of pressure.




An azeotrope of A, B, C (and D . . . ) can be characterized by defining the compositions as an azeotrope characterized by a boiling point at a given pressure, thus giving identifying characteristics without unduly limiting the scope of the invention by a specific numerical composition, which is limited by and is only as accurate as the analytical equipment available.




The azeotrope or azeotrope-like compositions of the present invention can be prepared by any convenient method including mixing or combining the desired amounts. A preferred method is to weigh the desired component amounts and thereafter combine them in an appropriate container.




There is no universally accepted methodology for combining all relevant factors into a single global warming potential for greenhouse gas emissions. One way to define the greenhouse effect of a compound is to determine its potential to enhance global warming relative to a known standard. In the present invention, the halocarbon global warming potential (HGWP) of several fluoroethers and HFCs were determined using known estimating techniques.




HGWP is defined as the ratio of incremental radiative warming resulting from an emission of a gas, over the lifetime of the gas in the atmosphere, to the calculated warming that would result from a release of the same mass of reference gas CFC-11, which has an HGWP of 1.0. The calculation of HGWP is discussed in Fisher et. al.,


Model Calculations on the Relative Effects of CFCs and their Replacements on Global Warming


, Nature, Volume 344, pp. 513-516 (1990), the text of which is incorporated herein by reference.




It has been discovered that the HGWP of an HFC can be lowered by adding to the HFC a fluoroether having a lower HGWP than the HGWP of the HFC such that the combination of the HFC and the fluoroether has an HGWP lower than the HGWP of the HFC. Therefore, the present invention relates to a composition of a first component that includes a hydrofluorocarbon and a second component that includes a fluoroether that has an HGWP less than the HGWP of the first component, such that the HGWP of the composition is less than the HGWP of the first component.




The scope of this invention includes a single fluoroether compound added to a single HFC, as well as a single fluoroether added to mixtures of two or more HFCs. Further, the invention includes mixtures of one or more fluoroethers added to a single HFC, as well as mixtures of one or more fluoroethers added to mixtures of two or more HFCs.




The HGWP of a composition of components A and B is equal to [fractional composition of A]×[HGWP of A]+[fractional composition of B]×[HGWP of B]. The HGWP of a composition of more than two components is determined in the same way, that is, by multiplying the fractional composition of a component by its HGWP, and then adding together the fractional HGWPs of all the components.




Specific examples illustrating the invention are given below. Unless otherwise stated therein, all percentages are by weight. It is to be understood that these examples are merely illustrative and in no way are to be interpreted as limiting the scope of the invention. All values given in the Examples are +/−5 percent.




EXAMPLE 1




Phase Study




A phase study on the following compositions, wherein the composition is varied and the vapor pressures are measured, at a constant temperature of 25° C., shows that the following compositions are azeotropic.














TABLE 2











Vapor








Press. psia






Weight % Fluoroether




Weight % HFC




(kPa)


























75.2 wt. % 116E




24.8 wt. % HFC-32




490.5




(3382)






58.6 wt. % 116E




41.4 wt. % HFC-41




575.6




(3969)






86.0 wt. % 116E




14.0 wt. % HFC-125




295.6




(2038)






90.2 wt. % 116E




 9.8 wt. % HFC-134




302.7




(2087)






90.0 wt. % 116E




10.0 wt. % HFC-134a




299.5




(2065)






94.9 wt. % 116E




 5.1 wt. % HFC-143




305.9




(2109)






94.8 wt. % 116E




 5.2 wt. % HFC-143a




293.1




(2021)






92.1 wt. % 116E




 7.9 wt. % HFC-152a




305.4




(2106)






87.3 wt. % 116E




12.7 wt. % HFC-161




344.3




(2374)






86.5 wt. % 125E




13.5 wt. % HFC-134




130.7




(901)






92.0 wt % 125E




 8.0 wt % HFC-143




132.0




(910)






84.4 wt % 125E




15.6 wt % HFC-152a




134.1




(925)






66.5 wt % 125E




33.5 wt % HFC-161




171.1




(1179)






37.9 wt % 134E




62.1 wt % HFC-143




34.0




(235)






13.6 wt % 134E




86.4 wt % HFC-227ca




65.9




(454)






 7.3 wt % 134E




92.7 wt. % HFC-227ea




67.2




(463)






78.0 wt % 134E




22.0 wt % HFC-236ca




63.8




(440)






36.3 wt % 134E




63.7 wt % HFC-236cb




36.3




(250)






52.8 wt % 134E




47.2 wt % HFC-236ea




33.3




(229)






14.2 wt. % 134E




85.8 wt. % HFC-236fa




39.8




(274)






28.5 wt % 134E




71.5 wt % HFC-245cb




80.0




(551)






29.7 wt % 134E




70.3 wt % HFC-254cb




34.9




(241)






28.6 wt. % 134E




71.4 wt. % HFC-254eb




35.5




(245)






97.1 wt. % 134E




 2.9 wt. % HFC-356mff




30.4




(210)






65.5 wt % 134E




34.5 wt % HFC-338mf




33.2




(229)






11.5 wt. % 134aE




88.5 wt. % HFC-32




249.2




(1718)






42.6 wt. % 134aE




57.4 wt. % HFC-134




78.3




(540)






98.1 wt. % 134aE




 1.9 wt. % HFC-143




73.9




(510)






19.1 wt. % 134aE




80.9 wt. % HFC-152a




86.0




(593)






65.5 wt % 134aE




34.5 wt % HFC-227ca




76.3




(526)






65.4 wt. % 134aE




34.6 wt. % HFC-227ea




75.4




(520)






57.7 wt. % 134aE




42.3 wt. % HFC-245cb




91.7




(632)






 6.2 wt. % 143aE




93.8 wt. % HFC-32




247.4




(1706)






92.4 wt. % 143aE




 7.6 wt. % HFC-134




127.6




(880)






 8.7 wt. % 143aE




91.3 wt. % HFC-143a




182.2




(1256)






48.6 wt. % 143aE




51.4 wt. % HFC-152a




87.3




(602)






71.5 wt % 143aE




28.5 wt % HFC-227ca




85.9




(592)






75.6 wt. % 143aE




24.4 wt. % HFC-227ea




84.8




(585)






59.6 wt. % 143aE




40.4 wt. % HFC-245cb




102.8




(709)






79.8 wt. % C216E




20.2 wt. % HFC-134




104.4




(720)






61.7 wt. % C216E




38.3 wt. % HFC-134a




108.0




(744)






91.9 wt. % C216E




 8.1 wt. % HFC-143




103.5




(714)






77.6 wt. % C216E




22.4 wt. % HFC-152a




109.1




(752)






58.8 wt. % C216E




41.2 wt. % HFC-161




148.3




(1022)






95.1 wt. % C216E




 4.9 wt. % HFC-245cb




100.6




(693)






36.0 wt. % C216E2




64.0 wt. % HFC-32




272.4




(1878)






60.5 wt. % C216E2




39.5 wt. % HFC-134




88.6




(611)






20.6 wt. % C216E2




79.4 wt. % HFC-134a




99.0




(683)






87.1 wt. % C216E2




12.9 wt. % HFC-143




82.9




(572)






60.5 wt. % C216E2




39.5 wt. % HFC-152a




95.6




(659)






45.7 wt. % C216E2




54.3 wt. % HFC-161




138.3




(954)






74.7 wt. % C216E2




25.3 wt. % HFC-245cb




81.3




(561)






63.3 wt. % 218E




36.7 wt. % HFC-134




116.6




(804)






53.0 wt. % 218E




47.0 wt. % HFC-134a




122.3




(843)






85.3 wt. % 218E




14.7 wt. % HFC-143




103.7




(715)






68.2 wt. % 218E




31.8 wt. % HFC-152a




124.0




(855)






62.6 wt. % 218E




37.4 wt. % HFC-161




170.9




(1178)






96.3 wt. % 218E




 3.7 wt. % HFC-263fb




84.0




(579)






46.1 wt. % 218E2




53.9 wt. % HFC-134




89.6




(617)






24.7 wt. % 218E2




75.3 wt. % HFC-134a




101.1




(697)






78.3 wt. % 218E2




21.7 wt. % HFC-143




72.6




(501)






51.0 wt. % 218E2




49.0 wt. % HFC-152a




98.1




(676)






46.4 wt. % 218E2




53.6 wt. % HFC-161




145.1




(1000)






89.8 wt. % 218E2




10.2 wt. % HFC-236fa




52.6




(363)






60.5 wt. % 218E2




39.5 wt. % HFC-263fb




57.9




(399)






55.9 wt. % C225eEαβ




44.1 wt. % HFC-143




38.0




(2626)






16.7 wt. % C225eEαβ




83.3 wt. % HFC-236cb




33.7




(232)






91.5 wt. % C225eEαβ




 8.5 wt. % HFC-236ea




31.1




(214)






22.4 wt. % C225eEαβ




77.6 wt. % HFC-245cb




70.1




(483)






17.9 wt. % 227caEαβ




82.1 wt. % HFC-32




253.4




(1747)






70.9 wt. % 227caEαβ




29.1 wt. % HFC-143




53.7




(370)






 8.1 wt. % 227caEαβ




91.9 wt. % HFC-245cb




67.4




(465)






94.3 wt. % 227caEαβ




 5.7 wt. % HFC-272ca




41.5




(286)






31.5 wt. % 227caEαβ




68.5 wt. % HFC-281ea




47.3




(326)






84.3 wt. % 227caEαβ




15.7 wt. % HFC-281fa




42.5




(293)






28.4 wt. % 227caEβγ




71.6 wt. % HFC-32




269.7




(1859)






34.8 wt. % 227caEβγ




65.2 wt. % HFC-134




82.7




(570)






 1.9 wt. % 227caEβγ




98.1 wt. % HFC-134a




98.3




(678)






73.8 wt. % 227caEβγ




26.2 wt. % HFC-143




66.2




(456)






38.3 wt. % 227caEβγ




61.7 wt. % HFC-152a




91.4




(630)






34.4 wt. % 227caEβγ




65.6 wt. % HFC-161




137.5




(948)






32.9 wt. % 227caEβγ




67.1 wt. % HFC-263fb




54.6




(376)






89.0 wt. % 227caEβγ




11.0 wt. % HFC-272ca




49.6




(342)






73.1 wt. % 227caEβγ




26.9 wt. % HFC-281ea




54.0




(372)






85.9 wt. % 227caEβγ




14.1 wt. % HFC-281fa




51.1




(352)






30.0 wt. % 227eaE




70.0 wt. % HFC-32




272.2




(1877)






38.2 wt. % 227eaE




61.8 wt. % HFC-134




84.7




(584)






 9.3 wt. % 227eaE




90.7 wt. % HFC-134a




98.6




(680)






74.9 wt. % 227eaE




25.1 wt. % HFC-143




68.9




(475)






42.1 wt. % 227eaE




57.9 wt. % HFC-152a




93.3




(643)






37.5 wt. % 227eaE




62.5 wt. % HFC-161




139.5




(962)






49.3 wt. % 227eaE




50.7 wt. % HFC-263fb




55.7




(384)






90.7 wt. % 227eaE




 9.3 wt. % HFC-272ca




52.1




(359)






76.8 wt. % 227eaE




23.2 wt. % HFC-281ea




56.0




(386)






87.6 wt. % 227eaE




12.4 wt. % HFC-281fa




53.4




(368)






13.5 wt. % C-234fEαβ




86.5 wt. % HFC-245cb




69.9




(482)






49.1 wt. % C-234fEαβ




50.9 wt. % HFC-245eb




17.6




(121)






59.0 wt. % C-234fEαβ




41.0 wt. % HFC-356mff




18.8




(130)






50.1 wt. % C-234fEαβ




49.9 wt. % HFC-356mmz




20.1




(139)






33.6 wt. % C-234fEβγ




66.4 wt. % HFC-245ca




14.5




(100)






10.2 wt. % C-234fEβγ




89.8 wt. % HFC-245cb




69.1




(476)






36.0 wt. % C-234fEβγ




64.0 wt. % HFC-245ea




14.5




(100)






36.0 wt. % C-234fEβγ




64.0 wt. % HFC-254ca




13.8




(95)






43.1 wt. % C-234fEβγ




56.9 wt. % HFC-356mff




17.1




(118)






35.8 wt. % C-234fEβγ




64.2 wt. % HFC-356mmz




18.6




(128)






12.0 wt. % 236caE




88.0 wt. % HFC-143




33.4




(230)






17.6 wt. % 236caE




82.4 wt. % HFC-254ca




13.8




(95)






25.9 wt. % 236eaEβγ




74.1 wt. % HFC-143




34.7




(239)






69.1 wt. % 236eaEβγ




30.9 wt. % HFC-245ca




16.1




(111)






 4.1 wt. % 236eaEβγ




95.9 wt. % HFC-263ca




18.3




(126)






92.6 wt. % 236eaEβγ




 7.49 wt. % HFC-338mf




18.9




(130)






96.9 wt. % 236eaEβγ




 3.1 wt. % HFC-356mff




15.7




(108)






15.1 wt. % 236eaEβγ




84.9 wt. % HFC-356mmz




16.7




(115)






 8.5 wt. % 236faE




91.5 wt. % HFC-32




248.6




(1714)






56.9 wt. % 236faE




43.1 wt. % HFC-143




45.1




(311)






27.8 wt. % 236faE




72.2 wt. % HFC-272ca




34.8




(240)






82.3 wt. % 236faE




17.7 wt. % HFC-272fb




30.2




(208)






 9.3 wt. % 236faE




90.7 wt. % HFC-281fa




37.7




(260)






 4.4 wt. % 245faEβγ




95.6 wt. % HFC-356mff




14.9




(103)














EXAMPLE 2




Impact of Vapor Leakage on Vapor Pressure at 25° C.




A vessel is charged with an initial composition at 25° C., and the vapor pressure of the composition is measured. The composition is allowed to leak from the vessel, while the temperature is held constant at 25° C., until 50 weight percent of the initial composition is removed, at which time the vapor pressure of the composition remaining in the vessel is measured. The results are summarized below.















TABLE 3









Refrigerant




0 wt % evaporated




50 wt % evaporated




% change in






Composition




psia (kPa)




psia (kPa)




vapor pressure




























116E/HFC-32











75.2/24.8




490.6




(3385)




490.6




(3385)




0.0






89/11




484.3




(3341)




434.4




(2297)




10.3






88/12




485.8




(3352)




451.4




(3114)




7.1






70/30




490.4




(3383)




490.0




(3381)




0.6






60/40




489.6




(3378)




488.0




(3367)




0.3






50/50




488.8




(3372)




486.1




(3354)




0.6






80/20




490.2




(3382)




489.1




(3374)




0.2






116E/HFC-41






58.6/41.4




575.6




(3971)




575.6




(3971)




0.0






70/30




572.4




(3949)




566.7




(3910)




1.0






85/15




540.4




(3728)




483.1




(3333)




10.6






84/16




544.9




(3759)




493.7




(3406)




9.3






40/60




571.3




(3942)




558.5




(3853)




2.2






30/70




565.7




(3903)




515.9




(3559)




8.8






28/72




564.1




(3892)




505.8




(3490)




10.3






29/71




564.9




(3897)




510.7




(3523)




9.6






5/95




512.9




(3539)




477.9




(3297)




6.6






116E/HFC-125






86.0/14.0




295.6




(2039)




295.6




(2039)




0.0






99/1




292.7




(2019)




292.6




(2018)




0.0






70/30




292.2




(2016)




291.1




(2008)




0.4






60/40




297.3




(2051)




284.0




(1959)




4.5






50/50




280.6




(1936)




273.9




(1889)




2.4






40/60




272.0




(1876)




260.5




(1797)




4.4






30/70




261.0




(1800)




244.0




(1683)




6.5






10/90




227.3




(1568)




209.5




(1445)




7.2






1/99




202.5




(1397)




199.8




(1378)




1.3






116E/HFC-134






99.0/1.0




294.8




(2033)




294.0




(2027)




0.3






90.2/9.8




302.7




(2087)




302.7




(2087)




0.0






70.0/30.0




293.5




(2024)




285.2




(1967)




2.8






52.0/48.0




283.9




(1957)




258.0




(1779)




9.1






116E/HFC-134a






90.0/10.0




299.5




(2066)




299.5




(2066)




0.0






99/1




293.8




(2027)




293.5




(2025)




0.0






52/48




276.8




(1909)




248.6




(1715)




10.2






53/47




277.5




(1914)




251.8




(1737)




9.3






60/40




282.6




(1949)




267.0




(1842)




5.5






70/30




289.7




(1998)




281.6




(1943)




2.8






80/20




296.2




(2043)




293.7




(2026)




0.8






116E/HFC-143






94.9/5.1




305.9




(2110)




305.9




(2110)




0.0






99/1




300.2




(2071)




295.6




(2039)




1.5






80/20




299.2




(2064)




295.9




(2041)




1.1






70/30




293.5




(2025)




285.2




(1967)




2.8






65/35




290.6




(2005)




280.2




(1933)




3.5






61/39




300.6




(2074)




298.3




(2058)




0.8






60/40




300.6




(2074)




283.6




(1956)




5.6






116E/HFC-143a






94.8/5.2




293.1




(2022)




293.1




(2022)




0.0






70/30




281.6




(1943)




277.4




(1914)




1.5






60/40




273.6




(1887)




265.0




(1828)




3.1






50/50




264.3




(1823)




250.0




(1725)




5.4






40/60




253.7




(1750)




232.3




(1602)




8.4






10/90




206.8




(1426)




186.0




(1283)




10.1






1/99




183.6




(1266)




180.9




(1248)




1.5






99/1




292.5




(2018)




292.5




(2018)




0.0






116E/HFC-152a






92.1/7.9




305.5




(2108)




305.5




(2108)




0.0






99/1




296.4




(2045)




295.1




(2036)




0.4






70/30




292.3




(2016)




280.4




(1934)




4.1






60/40




286.6




(1977)




259.3




(1789)




9.5






116E/HFC-161






87.3/12.7




344.4




(2376)




244.4




(2376)




0.0






99/1




307.4




(2121)




297.5




(2052)




3.2






70/30




337.9




(2331)




330.2




(2278)




2.3






60/40




334.1




(2305)




308.4




(2128)




7.7






95/5




335.6




(2315)




324.8




(2241)




3.2






125E/HFC-32






1.0/99.0




246.2




(1697)




245.9




(1695)




0.1






10.0/90.0




241.2




(1663)




238.8




(1646)




1.0






20.0/80.0




235.0




(1620)




230.0




(1586)




2.1






30.0/70.0




227.8




(1571)




220.1




(1518)




3.4






40.0/60.0




219.4




(1513)




209.3




(1443)




4.6






50.0/50.0




209.5




(1444)




197.4




(1361)




5.8






60.0/40.0




197.9




(1364)




184.7




(1273)




6.7






70.0/30.0




184.4




(1271)




171.2




(1180)




7.2






80.0/20.0




168.5




(1162)




157.2




(1084)




6.7






90.0/10.0




149.9




(1034)




142.8




(985)




4.7






99.0/1.0




130.8




(902)




129.9




(896)




0.7






125E/HFC-134






37.0/63.0




116.3




(802)




105.1




(725)




9.6






70.0/30.0




128.6




(887)




127.6




(880)




0.8






86.5/13.5




130.7




(901)




130.7




(901)




0.0






99.0/1.0




128.9




(889)




128.8




(888)




0.1






125E/HFC-134a






1.0/99.0




98.5




(679)




98.5




(679)




0.0






10.0/90.0




100.9




(696)




100.4




(692)




0.5






20.0/80.0




103.5




(714)




102.6




(707)




0.9






30.0/70.0




106.2




(732)




105.0




(724)




1.1






40.0/60.0




108.9




(751)




107.6




(742)




1.2






50.0/50.0




111.8




(771)




110.4




(761)




1.3






60.0/40.0




114.8




(792)




113.4




(782)




1.2






70.0/30.0




117.9




(813)




116.7




(805)




1.0






80.0/20.0




121.3




(836)




120.3




(829)




0.8






90.0/10.0




124.8




(860)




124.2




(856)




0.5






99.0/1.0




128.1




(883)




128.1




(883)




0.0






125E/HFC-143






57.0/43.0




123.5




(852)




112.1




(773)




9.2






60.0/40.0




124.2




(856)




115.9




(799)




6.7






70.0/30.0




126.9




(875)




122.4




(844)




3.6






92.0/8.0




132.0




(910)




132.0




(190)




0.0






99.0/1.0




129.5




(893)




129.3




(892)




0.2






125E/HFC-152a






39.0/61.0




120.3




(829)




108.6




(747)




9.7






50.0/50.0




125.3




(864)




118.5




(817)




5.4






60.0/40.0




129.0




(889)




125.6




(866)




2.7






84.4/15.6




134.1




(925)




134.1




(925)




0.0






99.0/1.0




129.4




(892)




129.2




(891)




0.2






125E/HFC-161






29.0/71.0




161.6




(1114)




145.8




(1006)




9.8






50.0/50.0




169.0




(1165)




166.3




(1146)




1.6






66.5/33.5




171.1




(1179)




171.1




(1179)




0.0






70.0/30.0




170.9




(1179)




170.8




(1177)




0.1






99.0/1.0




133.2




(919)




130.5




(900)




2.1






134E/HFC-143






1.0/99.0




33.1




(228)




33.1




(228)




0.0






37.9/62.1




34.0




(235)




34.0




(235)




0.0






50.0/50.0




33.9




(234)




33.9




(234)




0.0






70.0/30.0




33.2




(229)




33.1




(228)




0.4






99.0/1.0




30.6




(211)




30.5




(210)




0.1






134E/HFC-227ca






1.0/99.0




64.2




(443)




64.1




(442)




0.1






13.6/86.4




65.9




(454)




65.9




(454)




0.0






30.0/70.0




64.6




(445)




63.5




(438)




1.6






40.0/60.0




63.0




(434)




60.4




(416)




4.1






51.0/49.0




60.9




(420)




55.0




(379)




9.6






134E/HFC-227ea






7.3/92.7




67.2




(463)




67.2




(463)




0.0






1.0/99.0




66.8




(461)




66.8




(461)




0.0






40.0/60.0




62.6




(432)




59.3




(409)




5.3






50.0/50.0




60.3




(416)




54.0




(372)




10.4






49.0/51.0




60.6




(418)




54.6




(376)




9.9






134E/HFC-236ca






78.0/22.0




29.5




(203)




29.5




(203)




0.0






90/10




29.4




(202)




29.4




(202)




0.0






99/1




29.2




(201)




29.2




(201)




0.0






70/30




29.4




(202)




29.4




(202)




0.0






60/40




29.3




(202)




29.2




(201)




0.3






50/50




29.0




(200)




29.0




(200)




0.0






30/70




28.0




(193)




27.7




(191)




1.1






10/90




26.2




(180)




26.0




(179)




0.8






1/99




25.1




(173)




25.0




(172)




0.4






134E/HFC-236cb






1.0/99.0




33.8




(233)




33.8




(233)




0.0






36.3/63.7




36.3




(250)




36.3




(250)




0.0






40.0/60.0




36.3




(250)




36.3




(250)




0.0






70.0/30.0




34.8




(240)




34.3




(236)




1.6






99.0/1.0




30.6




(211)




30.5




(210)




0.3






134E/HFC-236ea






1.0/99.0




28.9




(199)




28.9




(199)




0.0






30.0/70.0




32.6




(225)




32.4




(223)




0.7






52.8/47.2




33.3




(229)




33.3




(229)




0.0






70.0/30.0




32.9




(227)




32.8




(226)




0.3






99.0/1.0




30.6




(211)




30.5




(210)




0.3






134E/HFC-236fa






14.2/85.8




39.8




(274)




39.8




(274)




0.0






1.0/99.0




39.4




(272)




39.4




(272)




0.0






40.0/60.0




38.8




(268)




38.6




(266)




0.5






60.0/40.0




37.1




(256)




36.3




(250)




2.2






80.0/20.0




34.4




(237)




33.3




(230)




3.2






99.0/1.0




30.7




(212)




30.5




(210)




0.7






134E/HFC-245cb






1.0/99.0




69.0




(476)




67.8




(467)




1.7






28.5/71.5




80.0




(551)




80.0




(551)




0.0






40.0/60.0




79.6




(549)




79.0




(545)




0.7






50.0/50.0




78.9




(544)




77.4




(534)




1.9






62.0/38.0




77.9




(537)




71.4




(492)




8.4






134E/HFC-254cb






1.0/99.0




34.2




(236)




34.2




(236)




0.0






29.7/70.3




34.9




(241)




34.9




(241)




0.0






40.0/60.0




34.8




(240)




34.8




(240)




0.0






70.0/30.0




33.6




(232)




33.4




(230)




0.7






99.0/1.0




30.6




(211)




30.5




(210)




0.1






134E/HFC-254eb






28.6/71.4




35.5




(245)




35.5




(245)




0.0






15.0/85.0




35.3




(243)




35.3




(243)




0.0






1.0/99.0




34.8




(240)




34.8




(240)




0.0






60.0/40.0




34.7




(239)




34.5




(238)




0.6






80.0/20.0




33.1




(228)




32.7




(225)




1.2






99.0/1.0




30.6




(211)




30.5




(210)




0.3






134E/HFC-338mf






27.0/73.0




30.5




(210)




27.6




(190)




9.4






40.0/60.0




32.2




(222)




31.1




(214)




3.4






65.5/34.5




33.2




(229)




33.2




(229)




0.0






80.0/20.0




32.9




(227)




32.6




(225)




0.8






99.0/1.0




30.6




(211)




30.5




(210)




0.4






134E/HFC-356mff






97.1/2.9




30.4




(210)




30.4




(210)




0.0






99.0/1.0




30.4




(210)




30.4




(210)




0.0






60.0/40.0




28.7




(198)




27.8




(192)




3.1






40.0/60.0




26.4




(182)




23.9




(165)




9.5






39.0/61.0




26.3




(181)




23.6




(163)




10.3






134aE/HFC-32






11.5/88.5




249.1




(1718)




249.1




(1718)




0.0






1/99




247.2




(1705)




247.1




(1705)




0.0






20/80




248.3




(1713)




247.7




(1709)




0.2






30/70




245.8




(1695)




243.0




(1676)




1.1






56/44




231.1




(1594)




207.6




(1432)




10.2






55/45




232.0




(1600)




210.0




(1449)




9.5






40/60




241.9




(1669)




234.5




(1618)




3.0






134aE/HFC-134






99.0/1.0




74.0




(510)




74.0




(510)




0






60.0/40.0




77.9




(537)




77.9




(537)




0






42.6/57.4




78.3




(540)




78.3




(540)




0






20.0/80.0




77.7




(536)




77.7




(536)




0






1.0/99.0




76.2




(525)




76.2




(525)




0






134aE/HFC-143






99.0/1.0




73.8




(509)




73.8




(509)




0






98.1/1.9




73.9




(510)




73.9




(510)




0






52.0/48.0




65.0




(448)




58.7




(405)




9.7






134aE/HFC-152a






19.1/80.9




86.1




(594)




86.1




(594)




0.0






10/90




86.0




(593)




86.0




(593)




0.0






1/99




85.8




(592)




85.8




(592)




0.0






30/70




86.0




(593)




86.0




(593)




0.0






50/50




85.0




(586)




84.9




(585)




0.1






70/30




82.7




(570)




82.2




(567)




0.6






80/20




80.7




(556)




80.0




(552)




0.9






99/1




74.3




(512)




74.2




(512)




0.1






134aE/HFC-227ca






65.5/34.5




76.2




(525)




76.2




(525)




0.0






80/20




75.8




(523)




75.8




(523)




0.0






90/10




75.0




(517)




74.9




(516)




0.1






99/1




74.0




(510)




73.9




(510)




0.1






50/50




75.7




(522)




75.6




(521)




0.1






40/60




74.8




(516)




74.4




(513)




0.5






30/70




73.4




(506)




72.7




(501)




1.0






20/90




71.2




(491)




70.2




(484)




1.4






1/99




64.2




(443)




64.1




(442)




0.3






134aE/HFC-227ea






65.4/34.6




75.5




(521)




75.5




(521)




0.0






80/20




75.2




(518)




75.1




(518)




0.1






90/10




74.6




(514)




74.6




(514)




0.0






99/1




73.9




(509)




73.9




(509)




0.0






50/50




75.1




(518)




75.0




(517)




0.1






30/70




73.4




(506)




73.0




(503)




0.5






10/90




69.6




(480)




69.2




(477)




0.6






1/99




67.0




(462)




67.0




(462)




0.0






134aE/HFC-245cb






57.7/42.3




91.6




(632)




91.6




(632)




0.0






70/30




90.9




(627)




90.1




(621)




0.9






80/20




89.0




(614)




85.9




(592)




3.5






92/8




83.3




(574)




77.4




(534)




7.1






99/1




75.5




(521)




74.1




(511)




1.8






30/70




87.6




(604)




84.3




(581)




3.8






20/80




83.4




(575)




78.4




(541)




6






10/90




76.9




(530)




72.3




(498)




6






1/99




67.7




(467)




67.8




(467)




0.1






143aE/HFC-32






6.2/98.8




247.4




(1707)




247.4




(1707)




0.0






1/99




246.9




(1703)




246.9




(1703)




0.0






20/80




245.1




(1691)




243.9




(1682)




0.5






30/70




241.4




(1665)




237.3




(1637)




1.7






40/60




236.1




(1629)




226.9




(1565)




3.9






50/50




228.8




(1578)




210.9




(1455)




7.8






55/45




224




(1545)




200.1




(1380)




10.6






54/46




225




(1552)




202




(1393)




10.0






143aE/HFC-134






99.0/1.0




127.5




(879)




127.5




(879)




0






92.4/7.6




127.6




(880)




127.6




(880)




0






30.0/70.0




123.4




(851)




123.1




(849)




0.2






1.0/99.0




118.3




(815)




118.2




(815)




0






143aE/HFC-143a






8.7/91.3




182.1




(1256)




182.1




(1256)




0.0






1/99




181.0




(1248)




181.0




(1248)




0.0






20/80




180.5




(1245)




179.7




(1239)




0.4






40/50




172.4




(1189)




165.0




(1138)




4.3






55/45




161.8




(1116)




144.7




(998)




10.6






54/46




162.7




(1122)




146.3




(1009)




10.1






53/47




163.5




(1128)




147.9




(1020)




9.5






143aE/HFC-152a






48.6/51.4




87.4




(603)




87.4




(603)




0.0






40/60




87.3




(602)




87.3




(602)




0.0






30/70




87.2




(601)




87.1




(601)




0.1






10/90




86.3




(595)




86.3




(595)




0.0






1/99




85.8




(592)




85.8




(592)




0.0






60/40




87.2




(601)




87.2




(601)




0.0






70/30




86.9




(599)




86.8




(598)




0.1






90/10




85.2




(587)




85.2




(587)




0.0






99/1




84.0




(579)




84.0




(579)




0.0






143aE/HFC-227ca






71.5/28.5




85.9




(592)




85.9




(592)




0.0






80/20




85.7




(591)




85.7




(591)




0.0






99/1




84.0




(579)




84.0




(579)




0.0






60/40




85.6




(590)




85.4




(589)




0.2






40/60




83.2




(574)




82.1




(566)




1.3






30/70




80.8




(557)




78.9




(544)




2.3






20/80




77.2




(532)




74.5




(514)




3.5






1/99




64.7




(446)




64.3




(443)




0.6






143aE/HFC-227ea






75.6/24.4




84.9




(585)




84.9




(585)




0.0






90/10




84.5




(583)




84.5




(583)




0.0






99/1




83.9




(578)




83.9




(578)




0.0






70/30




84.8




(585)




84.8




(585)




0.0






60/40




84.4




(582)




84.3




(581)




0.1






50/50




83.6




(576)




83.2




(574)




0.5






30/70




80.1




(552)




78.9




(544)




1.5






10/90




72.8




(502)




71.3




(492)




2.1






1/99




67.3




(464)




67.1




(463)




0.3






143aE/HFC-245cb






59.6/40.4




102.8




(709)




102.8




(709)




0.0






70/30




102.2




(705)




101.5




(700)




0.7






80/20




100.5




(693)




96.9




(668)




3.6






99/1




85.8




(592)




84.0




(579)




2.1






40/60




100.7




(694)




98.2




(677)




2.5






30/70




97.4




(672)




91.6




(632)




6.0






20/80




91.8




(633)




82.7




(570)




9.9






19/81




91.0




(627)




81.7




(563)




10.2






C-216E/HFC-134






1.0/99.0




76.9




(530)




76.3




(526)




0.8






50.0/50.0




100.1




(690)




98.0




(676)




2.1






79.8/20.2




104.4




(720)




104.4




(720)




0






99.0/1.0




100.8




(695)




100.7




(694)




0.1






C216E/HFC-134a






61.7/38.3




108.0




(745)




108.0




(745)




0.0






80/20




106.6




(735)




106.4




(734)




0.2






90/10




104.4




(720)




105.0




(724)




0.6






99/1




100.8




(695)




100.7




(694)




0.1






50/50




107.6




(742)




107.4




(741)




0.1






30/70




105.2




(725)




104.6




(721)




0.2






10/90




101.0




(696)




100.4




(692)




0.5






1/99




98.6




(680)




98.5




(679)




0.1






C216E/HFC-143






99.0/1.0




101.2




(698)




101.0




(696)




0.2






91.9/8.1




103.5




(714)




103.5




(714)




0






61.0/39.0




96.6




(666)




87.3




(602)




9.6






C216E/HFC-152a






77.6/22.4




109.1




(752)




109.1




(752)




0.0






90/10




107.2




(739)




106.7




(736)




0.5






99/1




101.4




(699)




101.1




(697)




0.3






70/30




108.7




(759)




108.5




(748)




0.2






60/40




107.2




(739)




106.2




(732)




0.9






30/70




99.2




(684)




94.8




(654)




4.4






20/80




95.4




(658)




91.0




(627)




4.6






10/90




91.0




(627)




87.9




(606)




3.4






1/99




86.3




(595)




86.0




(593)




0.3






C216E/HFC-161






58.8/41.2




148.3




(1023)




148.3




(1023)




0.0






70/30




147.2




(1015)




146.3




(1009)




0.6






80/20




143.3




(988)




139.1




(959)




2.9






99/1




105.4




(727)




102.2




(705)




3.0






50/50




147.8




(1019)




147.4




(1017)




0.3






40/60




146.4




(1010)




144.7




(998)




1.2






30/70




144.1




(994)




140.6




(970)




2.4






20/80




140.8




(971)




136.3




(940)




3.2






1/99




130.9




(903)




130.4




(899)




0.4






C216E/HFC-245cb






95.1/4.9




100.6




(694)




100.6




(694)




0.0






99/1




100.4




(692)




100.4




(692)




0.0






70/30




96.9




(668)




95.6




(659)




1.3






60/40




94.1




(694)




91.8




(633)




2.4






50/50




90.8




(626)




87.4




(603)




3.7






40/60




87.0




(600)




87.9




(606)




1.0






30/70




82.8




(571)




78.3




(540)




5.4






20/80




78.0




(538)




74.1




(511)




5.0






1/99




68.0




(469)




68.0




(469)




0.0






C-216E2/HFC-32






36.0/64.0




272.4




(1878)




272.4




(1878)




0.0






15.0/85.0




269.3




(1857)




256.1




(1766)




4.9






1.0/99.0




250.4




(1726)




246.8




(1702)




1.4






60.0/40.0




269.3




(1857)




261.3




(1802)




3.0






80.0/20.0




250.6




(1728)




179.7




(1239)




28.3






70.0/30.0




263.9




(1820)




238.7




(1646)




9.5






71.0/29.0




263.0




(1813)




235.0




(1620)




10.6






C-216E2/HFC-134






60.5/39.5




88.6




(611)




88.6




(611)




0.0






80.0/20.0




86.7




(598)




85.9




(592)




0.9






99.0/1.0




77.6




(535)




77.3




(533)




0.4






40.0/60.0




87.2




(601)




86.4




(596)




0.9






20.0/80.0




83.2




(574)




81.4




(561)




2.2






1.0/99.0




76.5




(527)




76.3




(526)




0.3






C-216E2/HFC-134a






20.6/79.4




99.0




(683)




99.0




(683)




0.0






1.0/99.0




98.3




(678)




98.3




(678)




0.0






50.0/50.0




97.2




(670)




96.8




(667)




0.4






80.0/20.0




89.6




(618)




87.6




(604)




2.2






99.0/1.0




77.6




(535)




77.3




(533)




0.4






C-216E2/HFC-143






87.1/12.9




82.9




(572)




82.9




(572)




0.0






99.0/1.0




78.1




(538)




77.5




(534)




0.8






50.0/50.0




77.2




(532)




55.6




(383)




28.0






70.0/30.0




80.8




(557)




78.5




(541)




2.8






60.0/40.0




79.0




(545)




73.1




(504)




7.5






58.0/42.0




78.7




(543)




71.2




(491)




9.5






57.0/43.0




78.5




(541)




70.1




(483)




10.7






C-216E2/HFC-152a






60.5/39.5




95.6




(659)




95.6




(659)




0.0






80.0/20.0




93.2




(643)




92.1




(635)




1.2






99.0/1.0




78.4




(541)




77.7




(536)




0.9






40.0/60.0




94.2




(649)




93.5




(645)




0.7






20.0/80.0




90.9




(627)




89.5




(617)




1.5






1.0/99.0




86.1




(594)




85.9




(592)




0.2






C-216E2/HFC-161






45.7/54.3




138.3




(954)




138.3




(954)




0.0






20.0/80.0




135.8




(936)




134.6




(928)




0.9






1.0/99.0




130.6




(900)




130.4




(899)




0.2






60.0/40.0




137.3




(947)




136.4




(940)




0.7






80.0/20.0




129.0




(889)




120.3




(829)




6.7






85.0/15.0




123.7




(853)




111.0




(765)




10.3






84.0/16.0




124.9




(861)




113.1




(780)




9.4






C-216E2/HFC-245cb






74.7/25.3




81.3




(561)




81.3




(561)




0.0






99.0/1.0




77.2




(532)




77.1




(532)




0.1






50.0/50.0




79.3




(547)




78.6




(542)




0.9






20.0/80.0




73.1




(504)




71.8




(495)




1.8






1.0/99.0




67.7




(467)




67.6




(466)




0.1






218E/HFC-134






99.0/1.0




87.3




(602)




84.7




(584)




3.0






80.0/20.0




113.8




(785)




109.9




(758)




3.4






63.3/36.7




116.6




(804)




116.6




(804)




0






50.0/50.0




115.8




(798)




114.5




(789)




1.1






35.0/65.0




113.5




(783)




102.7




(708)




9.5






218E/HFC-134a






53.0/47.0




122.3




(843)




122.3




(843)




0.0






70/30




120.2




(829)




117.8




(812)




2.0






80/20




115.6




(797)




109.1




(752)




5.6






99/1




86.8




(598)




84.7




(584)




2.4






40/60




121.5




(838)




120.3




(830)




1.0






30/70




119.6




(825)




115.6




(797)




3.3






20/80




116.3




(802)




108.0




(745)




7.1






1/99




99.9




(689)




98.4




(679)




1.5






218E/HFC-143






99.0/1.0




90.6




(625)




84.5




(583)




6.7






85.3/14.7




103.7




(715)




103.7




(715)




0






57.0/43.0




102.4




(706)




99.0




(683)




3.3






218E/HFC-152a






68.2/31.8




124.0




(855)




124.0




(855)




0.0






80/20




112.4




(775)




120.0




(828)




6.8






99/1




89.5




(617)




85.1




(587)




4.9






60/40




123.6




(852)




123.0




(848)




0.5






50/50




122.6




(845)




119.5




(824)




2.5






40/60




121.0




(834)




108.5




(748)




10.3






41/59




121.2




(836)




110.3




(761)




9.0






218E/HFC-161






62.6/37.4




170.9




(1179)




170.9




(1179)




0.0






80/20




167.8




(1157)




160.2




(1105)




4.5






85/15




163.8




(1130)




146.4




(1010)




10.6






84/16




164.9




(1137)




149.9




(1034)




9.1






60/40




170.9




(1179)




170.8




(1178)




0.5






38/62




169.4




(1168)




152.3




(1050)




10.1






39/61




169.5




(1169)




156.5




(1079)




7.7






218E/HFC-263fb






96.3/3.7




84.0




(579)




84.0




(579)




0.0






99/1




83.9




(578)




83.9




(578)




0.0






70/30




80.0




(552)




78.5




(541)




1.9






40/60




71.6




(494)




66.1




(456)




7.7






23/77




65.4




(451)




59.1




(407)




9.6






24/76




65.8




(454)




59.4




(409)




9.7






25/75




66.2




(456)




60.2




(415)




9.6






10/90




59.5




(410)




55.5




(383)




6.7






1/99




54.6




(376)




54.1




(373)




0.9






218E2/HFC-134






1.0/99.0




77.1




(532)




76.2




(525)




1.2






20.0/80.0




86.9




(599)




83.1




(573)




4.4






36.1/53.9




89.6




(618)




89.6




(618)




0






70.0/30.0




86.8




(598)




83.0




(572)




4.4






79.0/21.0




83.0




(572)




74.8




(516)




9.9






218E2/HFC-134a






24.7/75.3




101.1




(697)




101.1




(697)




0.0






10/90




100.2




(691)




99.9




(689)




0.3






1/99




98.5




(679)




98.4




(679)




0.1






40/60




100.2




(691)




99.6




(687)




0.6






50/50




98.7




(681)




96.8




(667)




1.9






70/30




92.0




(634)




84.1




(580)




8.6






73/27




90.2




(622)




81.1




(559)




10.1






72/28




90.8




(626)




82.1




(566)




9.6






218E2/HFC-143






91.0/9.0




70.7




(487)




65.0




(448)




8.1






78.3/21.7




72.6




(501)




72.6




(501)




0






52.0/48.0




71.8




(495)




67.5




(465)




6.0






218E2/HFC-152a






51.0/49.0




98.1




(676)




98.1




(676)




0.0






70/30




96.4




(665)




93.9




(647)




2.6






82/18




91.3




(630)




82.0




(565)




10.2






81/19




92.0




(634)




83.5




(576)




9.2






40/60




97.7




(674)




97.1




(670)




0.6






30/70




96.7




(667)




94.5




(652)




2.3






20/80




94.8




(654)




90.5




(624)




4.5






10/90




91.5




(631)




87.3




(602)




4.6






1/99




86.5




(596)




85.9




(592)




0.7






218E2/HFC-161






46.4/53.6




145.1




(1001)




145.1




(1001)




0.0






60/40




144.4




(996)




143.2




(988)




0.8






77/23




139.4




(961)




126.7




(874)




9.1






78/22




138.8




(957)




124.5




(859)




10.3






40/60




145.0




(1000)




144.7




(998)




0.2






30/70




144.3




(995)




142.0




(979)




1.6






20/80




142.7




(984)




135.6




(935)




5.0






10/90




139.1




(959)




131.3




(906)




5.6






1/99




131.5




(907)




130.2




(898)




1.0






218E2/HFC-236fa






89.8/10.2




52.6




(362)




52.6




(362)




0.0






99/1




52.3




(360)




52.4




(361)




0.2






70/30




51.8




(357)




51.6




(356)




0.4






60/40




50.8




(350)




50.3




(347)




1.0






50/50




49.7




(342)




48.8




(336)




1.8






30/70




46.6




(321)




44.9




(309)




3.6






20/80




44.6




(307)




42.9




(296)




3.8






10/90




42.2




(291)




41.0




(282)




2.8






1/99




39.7




(273)




39.5




(272)




0.5






218E2/HFC-263fb






60.5/39.5




57.9




(399)




57.9




(399)




0.0






70/30




57.7




(398)




57.7




(398)




0.0






90/10




55.4




(382)




55.1




(380)




0.5






99/1




52.7




(363)




52.6




(362)




0.2






50/50




57.7




(398)




57.7




(398)




0.0






30/70




56.7




(391)




56.5




(389)




0.4






20/80




56.0




(386)




56.0




(386)




0.0






10/90




55.0




(379)




54.8




(378)




0.4






1/99




54.1




(373)




54.1




(373)




0.0






C-225eEαβ/HFC-143






55.9/44.1




38.0




(262)




38.0




(262)




0.0






80.0/20.0




36.7




(253)




36.1




(249)




1.6






99.0/1.0




31.6




(218)




31.4




(216)




0.6






20.0/80.0




36.1




(249)




35.4




(244)




1.9






1.0/99.0




33.3




(230)




33.2




(229)




0.3






C-225eEαβ/HFC-236cb






16.7/83.3




33.7




(232)




33.7




(232)




0.0






1.0/99.0




33.6




(232)




33.6




(232)




0.0






50.0/50.0




33.3




(230)




33.3




(230)




0.0






80.0/20.0




32.3




(223)




32.2




(222)




0.3






99.0/1.0




31.2




(215)




31.2




(215)




0.0






C-225eEαβ/HFC-236ea






91.5/8.5




31.1




(214)




31.1




(214)




0.0






99.0/1.0




31.1




(214)




31.1




(214)




0.0






60.0/40.0




30.8




(212)




30.8




(212)




0.0






40.0/60.0




30.4




(210)




30.3




(209)




0.3






20.0/80.0




29.7




(205)




29.6




(204)




0.3






1.0/99.0




28.8




(199)




28.8




(199)




0.0






C-225eEαβ/HFC-245cb






22.4/77.6




70.1




(483)




70.1




(483)




0.0






1.0/99.0




67.7




(467)




67.6




(466)




0.1






50.0/50.0




67.7




(467)




65.7




(453)




3.0






60.0/40.0




66.0




(455)




61.7




(425)




6.5






65.0/35.0




65.0




(448)




58.5




(403)




10.0






227caEαβ/HFC-32






17.9/82.1




253.4




(1748)




253.4




(1748)




0.0






10/90




252.8




(1744)




251.8




(1737)




0.4






1/99




247.9




(1710)




247.1




(1705)




0.3






40/60




251.3




(1734)




248.0




(1711)




1.3






60/40




244.7




(1688)




223.4




(1541)




8.7






61/39




244.0




(1683)




221.0




(1524)




9.4






62/38




243.4




(1679)




218.2




(1505)




10.4






227caEαβ/HFC-143






99.0/1.0




43.0




(296)




41.8




(288)




2.8






95.0/5.0




47.6




(328)




44.4




(306)




6.7






70.9/29.1




53.7




(370)




53.7




(370)




0






42.0/58.0




52.0




(359)




46.9




(323)




9.8






227caEαβ/HFC-245cb






8.1/91.9




67.5




(465)




67.5




(465)




0.0






1/99




67.4




(465)




67.4




(465)




0.0






30/70




66.7




(460)




66.5




(458)




0.3






50/50




64.5




(445)




63.4




(437)




1.7






70/30




60.2




(415)




56.8




(391)




5.6






77/23




57.9




(399)




53.2




(367)




8.1






80/20




56.6




(390)




51.5




(355)




9.0






82/18




55.8




(385)




50.3




(347)




9.8






83/17




55.3




(381)




49.7




(342)




10.1






227caEαβ/HFC-272ca






94.3/5.7




41.4




(285)




41.4




(285)




0.0






99/1




41.4




(285)




41.4




(285)




0.0






80/20




41.0




(282)




41.0




(282)




0.0






60/40




39.7




(273)




39.4




(271)




0.8






40/60




38.1




(262)




37.6




(259)




1.3






20/80




36.4




(251)




35.9




(247)




1.4






10/90




35.5




(245)




35.2




(242)




0.8






1/99




34.6




(238)




34.6




(238)




0.0






227caEαβ/HFC-281ea






31.5/68.5




47.4




(327)




47.4




(327)




0.0






20/80




47.3




(326)




47.3




(326)




0.0






10/90




47.2




(325)




47.2




(325)




0.0






1/99




47.1




(325)




47.1




(325)




0.0






50/50




47.2




(325)




47.2




(325)




0.0






70/30




46.5




(320)




46.4




(320)




0.2






90/10




44.2




(305)




43.9




(302)




0.7






99/1




41.7




(287)




41.6




(287)




0.2






227caEαβ/HFC-281fa






84.3/15.7




42.4




(292)




42.4




(292)




0.0






90/10




42.3




(291)




42.3




(291)




0.0






99/1




41.5




(286)




41.5




(286)




0.0






60/40




41.6




(287)




41.4




(285)




0.5






40/60




40.3




(278)




40.0




(276)




0.7






20/80




39.0




(269)




38.7




(267)




0.8






10/90




38.4




(265)




38.2




(263)




0.5






1/99




37.8




(260)




37.8




(260)




0.0






227caβγ/HFC-32






28.4/71.6




269.7




(1860)




269.7




(1860)




0.0






10/90




268.6




(1853)




247.0




(1704)




8.0






1/99




255.3




(1761)




246.7




(1702)




3.4






40/60




269.4




(1858)




268.8




(1854)




0.2






60/40




266.6




(1839)




255.3




(1761)




4.2






67/33




263.7




(1819)




238.6




(1646)




9.5






68/32




263.1




(1815)




235.0




(1621)




10.6






227caEβγ/HFC-134






34.8/65.2




82.7




(571)




82.7




(571)




0.0






10/90




80.0




(552)




78.7




(543)




1.6






5/95




78.4




(541)




77.3




(533)




1.4






1/99




76.6




(529)




76.3




(527)




0.0






50/50




81.9




(565)




81.1




(560)




1.0






60/40




80.3




(554)




77.8




(537)




3.1






70/30




77.3




(533)




72.2




(498)




6.6






77/23




74.1




(511)




66.7




(460)




10.0






76/24




74.6




(515)




67.6




(466)




9.4






227caEβγ/HFC-134a






1.9/98.1




98.3




(678)




98.3




(678)




0.0






1/99




98.3




(678)




98.3




(678)




0.0






20/80




97.2




(670)




96.9




(668)




0.3






30/70




95.8




(661)




94.8




(654)




1.0






50/50




91.0




(627)




87.1




(601)




4.3






68/32




83.3




(574)




74.8




(516)




10.2






67/33




83.8




(578)




75.6




(521)




9.8






227caEβγ/HFC-143






91.0/9.0




63.1




(435)




57.4




(396)




9.0






73.8/26.2




66.2




(456)




66.2




(456)




0






46.0/54.0




65.1




(449)




59.1




(407)




9.2






227caEβγ/HFC-152a






38.3/61.7




91.4




(630)




91.4




(630)




0.0






20/80




90.4




(623)




89.6




(618)




0.9






10/90




88.7




(612)




87.6




(604)




1.2






1/99




86.1




(594)




85.9




(592)




0.2






60/40




89.8




(619)




88.0




(607)




2.0






70/30




87.2




(601)




82.7




(570)




5.2






80/20




82.1




(566)




73.1




(504)




11






78/22




83.4




(575)




75.4




(520)




9.6






79/21




82.8




(571)




74.3




(512)




10.2






227caEβγ/HFC-161






34.4/65.6




137.5




(948)




137.5




(948)




0.0






20/80




136.7




(943)




135.6




(935)




0.8






10/90




134.7




(929)




132.6




(914)




1.6






1/99




130.8




(902)




130.4




(899)




0.3






40/60




134.4




(927)




137.3




(947)




2.2






60/40




135.0




(931)




131.0




(903)




3.0






72/28




130.2




(898)




117.8




(812)




9.5






73/27




129.6




(894)




116.0




(800)




10.4






227caEβγ/HFC-263fb






32.9/67.1




54.6




(376)




54.6




(376)




0.0






20/80




54.5




(376)




54.5




(376)




0.0






10/90




54.3




(374)




54.3




(374)




0.0






1/99




54.0




(372)




54.0




(372)




0.0






50/50




54.4




(375)




54.4




(375)




0.0






70/30




53.4




(368)




53.2




(367)




0.4






90/10




50.9




(351)




50.7




(349)




0.4






99/1




49.0




(338)




48.9




(337)




0.2






227caEβγ/HFC-272ca






89.0/11.0




49.6




(342)




49.6




(342)




0.0






99/1




48.9




(337)




48.9




(337)




0.0






60/40




47.1




(325)




46.0




(317)




2.3






40/60




44.1




(304)




41.3




(285)




6.3






30/70




42.2




(291)




38.9




(268)




7.8






20/80




40.1




(276)




36.9




(254)




8.0






10/90




37.6




(259)




35.4




(244)




5.9






1/99




34.8




(240)




34.6




(238)




0.6






80/20




49.3




(340)




49.2




(339)




0.2






227caEβγ/HFC-281ea






73.1/26.9




54.0




(372)




54.0




(372)




0.0






80/20




53.8




(371)




53.8




(371)




0.0






90/10




52.6




(362)




52.3




(360)




0.0






99/1




49.3




(340)




49.2




(339)




0.6






60/40




53.4




(368)




53.4




(368)




0.2






40/60




52.0




(358)




51.4




(354)




0.0






30/70




51.0




(351)




50.1




(345)




1.8






10/90




48.6




(335)




48.0




(331)




1.2






1/99




47.3




(326)




47.2




(325)




0.2






227caEβγ/HFC-281fa






85.9/14.1




51.0




(351)




51.0




(351)




0.0






90/10




50.9




(351)




50.9




(351)




0.0






99/1




49.1




(338)




49.1




(338)




0.0






70/30




50.0




(345)




49.5




(341)




1.0






40/60




45.9




(316)




43.3




(298)




5.7






30/70




44.2




(305)




41.2




(284)




6.8






20/80




42.3




(291)




39.6




(273)




6.4






10/90




40.1




(276)




38.5




(265)




4.0






1/99




38.0




(262)




37.8




(260)




0.5






227eaE/HFC-32






30.0/70.0




272.3




(1878)




272.3




(1878)




0.0






20/80




272.1




(1877)




270.9




(1869)




0.4






10/90




271.2




(1871)




246.7




(1702)




9.0






1/99




257.1




(1774)




246.7




(1702)




4.0






50/50




271.4




(1872)




268.6




(1853)




1.0






60/40




269.6




(1860)




259.6




(1791)




3.7






68/32




266.4




(1838)




240.8




(1661)




9.6






69/31




265.8




(1834)




237.1




(1636)




10.8






227eaE/HFC-134






1.0/99.0




76.7




(529)




76.3




(526)




0.5






10.0/90.0




80.9




(558)




78.9




(544)




2.5






38.2/61.8




84.7




(584)




84.7




(584)




0






60.0/40.0




82.7




(570)




80.7




(556)




2.4






78.0/22.0




76.4




(527)




69.1




(476)




9.6






227eaE/HFC-134a






9.3/90.7




98.6




(680)




98.6




(680)




0.0






1/99




98.3




(678)




98.3




(678)




0.0






30/70




97.2




(670)




96.5




(665)




0.7






40/60




95.5




(659)




93.8




(647)




1.8






60/40




89.6




(618)




83.9




(578)




6.4






70/30




84.6




(583)




76.2




(525)




9.0






71/29




84.0




(579)




75.3




(519)




10.4






227eaE/HFC-143






92.0/8.0




65.4




(451)




59.1




(408)




9.6






74.9/25.1




68.9




(475)




68.9




(475)




0.0






47.0/53.0




67.7




(469)




61.7




(426)




8.9






80.0/20.0




68.8




(475)




68.4




(472)




0.6






93.0/7.0




64.6




(451)




57.7




(398)




10.7






60.0/40.0




68.4




(446)




67.6




(466)




1.2






50.0/50.0




67.9




(472)




65.2




(450)




4.0






46.0/54.0




67.7




(474)




59.0




(407)




12.8






227eaE/HFC-152a






42.1/57.9




93.2




(643)




93.2




(643)




0.0






20/80




91.6




(632)




90.3




(623)




1.4






10/90




89.4




(616)




87.8




(605)




1.8






1/99




86.2




(594)




85.9




(592)




0.3






60/40




92.0




(634)




90.7




(625)




1.4






70/30




89.7




(618)




85.8




(592)




4.3






80/20




84.9




(585)




76.5




(527)




9.9






81/19




84.2




(581)




75.2




(518)




10.7






30/70




92.8




(640)




92.3




(636)




0.5






227eaE/HFC-161






37.5/62.5




139.5




(962)




139.5




(962)




0.0






20/80




138.3




(954)




136.4




(941)




1.4






10/90




135.8




(937)




132.6




(914)




2.4






1/99




131.0




(903)




130.3




(899)




0.5






60/40




137.5




(948)




134.2




(926)




2.4






70/30




134.2




(926)




124.8




(866)




7.0






73/27




132.6




(914)




120.1




(828)




9.4






74/26




131.9




(910)




118.3




(816)




10.3






30/70




139.3




(961)




139.0




(959)




0.2






227eaE/HFC-263fb






49.3/50.7




55.7




(384)




55.7




(384)




0.0






30/70




55.4




(382)




55.3




(381)




0.2






20/80




55.0




(379)




55.0




(379)




0.0






10/90




54.6




(376)




54.5




(376)




0.2






1/99




54.1




(373)




54.0




(372)




0.2






70/30




55.2




(380)




55.1




(380)




0.2






80/20




54.4




(375)




54.3




(374)




0.2






90/10




53.2




(367)




53.0




(365)




0.4






99/1




51.5




(355)




51.5




(355)




0.0






227eaE/HFC-272ca






90.7/9.3




52.0




(358)




52.0




(358)




0.0






99/1




51.4




(354)




51.4




(354)




0.0






70/30




50.3




(347)




49.6




(342)




1.4






50/50




47.3




(326)




44.7




(308)




5.5






35/65




44.5




(307)




40.4




(278)




9.2






30/70




43.4




(299)




39.1




(269)




9.9






29/71




43.2




(298)




38.8




(267)




10.2






80/20




51.4




(354)




51.2




(353)




0.4






227eaE/HFC-281ea






76.8/23.2




55.9




(385)




55.9




(385)




0.0






90/10




54.9




(378)




54.7




(377)




0.4






99/1




51.8




(357)




51.7




(356)




0.2






60/40




55.2




(380)




54.8




(378)




0.7






40/60




53.2




(367)




52.1




(359)




2.1






30/70




51.9




(358)




50.6




(349)




2.5






20/80




50.4




(347)




49.2




(339)




2.4






10/90




48.9




(337)




48.1




(331)




1.6






1/99




47.3




(326)




47.2




(325)




0.2






227eaE/HFC-281fa






87.6/12.4




53.3




(367)




53.3




(367)




0.0






99/1




51.7




(356)




51.6




(356)




0.2






60/40




50.5




(348)




48.9




(337)




3.2






40/60




47.2




(325)




43.7




(301)




7.4






30/70




45.2




(311)




41.4




(285)




8.4






20/80




43.0




(296)




39.6




(273)




7.9






10/90




40.5




(279)




38.4




(265)




5.2






1/99




38.0




(262)




37.8




(260)




0.5






70/30




51.9




(358)




51.2




(353)




1.3






C-234fEαβ/HFC-245cb






13.5/86.5




69.9




(482)




69.9




(482)




0.0






1.0/99.0




67.9




(468)




67.7




(467)




0.3






40.0/60.0




67.6




(466)




65.6




(452)




3.0






50.0/50.0




66.4




(458)




63.6




(439)




4.2






55.0/45.0




65.9




(454)




62.0




(427)




5.9






57.0/43.0




65.7




(453)




60.7




(419)




7.6






58.0/42.0




65.6




(452)




59.5




(410)




9.3






59.0/41.0




65.5




(452)




57.5




(396)




12.2






C-234fEαβ/HFC-245eb






49.1/50.9




17.6




(121)




17.6




(121)




0.0






20.0/80.0




17.3




(119)




17.3




(119)




0.0






1.0/99.0




16.9




(117)




16.9




(117)




0.0






80.0/20.0




17.3




(119)




17.3




(119)




0.0






99.0/1.0




16.8




(116)




16.8




(116)




0.0






C-234fEαβ/HFC-356mff






59.0/41.0




18.8




(130)




18.8




(130)




0.0






80.0/20.0




18.4




(127)




18.2




(125)




1.1






99.0/1.0




16.9




(117)




16.8




(116)




0.6






40.0/60.0




18.5




(128)




18.3




(126)




1.1






20.0/80.0




17.3




(119)




16.8




(116)




2.9






10.0/90.0




16.2




(112)




15.7




(108)




3.1






1.0/99.0




14.8




(102)




14.8




(102)




0.0






C-234fEαβ/HFC-356mmz






50.1/49.9




20.1




(139)




20.1




(139)




0.0






20.0/80.0




19.1




(132)




18.7




(129)




2.1






1.0/99.0




16.8




(116)




16.7




(115)




0.6






80.0/20.0




19.2




(132)




18.7




(129)




2.6






99.0/1.0




16.9




(117)




16.8




(116)




0.6






C-234fEβγ/HFC-245cb






10.2/89.8




69.1




(476)




69.1




(476)




0.0






1.0/99.0




67.8




(467)




67.7




(467)




0.1






40.0/60.0




66.4




(458)




64.4




(444)




3.0






50.0/50.0




65.4




(451)




62.7




(432)




4.1






55.0/45.0




65.0




(448)




61.0




(421)




6.2






58.0/42.0




64.7




(446)




52.6




(363)




18.7






57.0/43.0




64.8




(447)




57.9




(399)




10.6






56.0/44.0




64.9




(447)




60.0




(414)




7.6






C-234fEβγ/HFC-245ca






33.6/66.4




14.5




(100)




14.5




(100)




0.0






15.0/85.0




14.4




(99)




14.4




(99)




0.0






1.0/99.0




14.2




(98)




14.2




(98)




0.0






60.0/40.0




14.3




(99)




14.3




(99)




0.0






80.0/20.0




13.9




(96)




13.9




(96)




0.0






99.0/1.0




13.3




(92)




13.3




(92)




0.0






C-234fEβγ/HFC-245ea






36.0/64.0




14.5




(100)




14.5




(100)




0.0






15.0/85.0




14.4




(99)




14.4




(99)




0.0






1.0/99.0




14.2




(98)




14.2




(98)




0.0






60.0/40.0




14.4




(99)




14.3




(99)




0.7






80.0/20.0




14.0




(97)




13.9




(96)




0.7






99.0/1.0




13.3




(92)




13.3




(92)




0.0






C-234fEβγ/HFC-254ca






36.0/64.0




13.8




(95)




13.8




(95)




0.0






15.0/85.0




13.8




(95)




13.8




(95)




0.0






1.0/99.0




13.7




(94)




13.7




(94)




0.0






60.0/40.0




13.8




(95)




13.8




(95)




0.0






80.0/20.0




13.6




(94)




13.6




(94)




0.0






99.0/1.0




13.3




(92)




13.3




(92)




0.0






C-234fEβγ/HFC-356mff






43.1/56.9




17.1




(118)




17.1




(118)




0.0






20.0/80.0




16.5




(114)




16.3




(112)




1.2






1.0/99.0




14.8




(102)




14.8




(102)




0.0






70.0/30.0




16.5




(114)




16.0




(110)




3.0






90.0/10.0




15.0




(103)




14.0




(97)




6.7






99.0/1.0




13.5




(93)




13.3




(92)




1.5






C-234fEβγ/HFC-356mmz






35.8/64.2




18.6




(128)




18.6




(128)




0.0






15.0/85.0




18.0




(124)




17.8




(123)




1.1






1.0/99.0




16.7




(115)




16.7




(115)




0.0






60.0/40.0




18.1




(125)




17.6




(121)




2.8






80.0/20.0




16.8




(116)




15.3




(105)




8.9






85.0/15.0




16.2




(112)




14.5




(100)




10.5






83.0/17.0




16.5




(114)




14.8




(102)




10.3






82.0/18.0




16.6




(114)




15.0




(103)




9.6






236caE/HFC-143






60.0/40.0




30.4




(210)




27.4




(189)




9.9






12.0/88.0




33.4




(230)




33.4




(231)




0.0






10.0/90.0




33.4




(230)




33.4




(230)




0.0






1.0/99.0




33.1




(228)




33.1




(228)




0.0






5.0/95.0




33.3




(230)




33.3




(230)




0.0






30.0/70.0




33.0




(228)




33.0




(228)




0.0






40.0/60.0




32.4




(224)




31.7




(219)




2.2






61.0/39.0




30.3




(209)




27.1




(187)




10.6






236caE/HFC-245ca






1.0/99.0




14.2




(98)




14.2




(98)




0.0






10.0/90.0




14.1




(97)




14.1




(97)




0.0






20.0/80.0




14.0




(97)




14.0




(97)




0.0






30.0/70.0




13.9




(96)




13.9




(96)




0.0






40.0/60.0




13.8




(95)




13.7




(94)




0.7






50.0/50.0




13.6




(94)




13.6




(94)




0.0






60.0/40.0




13.5




(93)




13.4




(92)




0.7






70.0/30.0




13.3




(92)




13.3




(92)




0.0






80.0/20.0




13.2




(91)




13.2




(91)




0.0






90.0/10.0




13.1




(90)




13.0




(90)




0.8






99.0/1.0




12.9




(89)




12.9




(89)




0.0






236caE/HFC-254ca






17.6/82.4




13.7




(94)




13.7




(94)




0.0






10/90




13.7




(94)




13.7




(94)




0.0






1/99




13.7




(94)




13.7




(94)




0.0






30/70




13.7




(94)




13.7




(94)




0.0






50/50




13.6




(93)




13.6




(93)




0.0






70/30




13.4




(92)




13.4




(92)




0.0






90/10




13.1




(90)




13.1




(90)




0.0






99/1




13.0




(89)




13.0




(89)




0.0






40/60




13.7




(94)




13.7




(94)




0.0






236eaEβγ/HFC-143






66.0/34.0




32.1




(221)




29.1




(201)




9.3






25.9/74.1




34.6




(239)




34.6




(239)




0






10.0/90.0




34.1




(235)




33.9




(234)




0.6






1.0/99.0




33.2




(229)




33.2




(229)




0






236eaEβγ/HFC-245ca






1.0/99.0




14.7




(101)




14.7




(101)




0.0






10.0/90.0




15.0




(103)




15.0




(103)




0.0






20.0/80.0




15.4




(106)




15.3




(105)




0.6






30.0/70.0




15.6




(108)




15.6




(108)




0.0






40.0/60.0




15.8




(109)




15.8




(109)




0.0






50.0/50.0




16.0




(110)




16.0




(110)




0.0






60.0/40.0




16.1




(111)




16.1




(111)




0.0






69.1/30.9




16.1




(111)




16.1




(111)




0.0






80.0/20.0




16.1




(111)




16.1




(111)




0.0






90.0/10.0




15.9




(110)




15.9




(110)




0.0






99.0/1.0




15.7




(108)




15.7




(108)




0.0






236eaEβγ/HFC-263ca






4.1/95.9




18.2




(125)




18.2




(125)




0.0






1/99




18.2




(125)




18.2




(125)




0.0






30/70




18.1




(124)




18.1




(124)




0.0






50/50




17.9




(123)




17.8




(122)




0.6






70/30




17.3




(119)




17.2




(118)




0.6






90/10




16.4




(113)




16.3




(112)




0.6






99/1




15.8




(109)




15.8




(109)




0.0






236eaEβγ/HFC-338mf






92.6/7.4




16.2




(111)




16.1




(111)




0.6






99/1




15.8




(109)




15.7




(108)




0.6






70/30




17.4




(120)




17.2




(118)




1.1






50/50




18.1




(124)




18.0




(124)




0.6






40/60




18.4




(127)




18.4




(127)




0.0






30/70




18.6




(128)




18.6




(128)




0.0






10/90




18.8




(129)




18.8




(129)




0.0






1/99




18.8




(129)




18.8




(129)




0.0






236eaEβγ/HFC-356mff






1.0/99.0




14.9




(103)




14.9




(103)




0.0






10.0/90.0




15.1




(104)




15.1




(104)




0.0






20.0/80.0




15.2




(105)




15.2




(105)




0.0






30.0/70.0




15.3




(106)




15.3




(106)




0.0






40.0/60.0




15.4




(106)




15.4




(106)




0.0






50.0/50.0




15.5




(107)




15.5




(107)




0.0






60.0/40.0




15.6




(108)




15.6




(108)




0.0






70.0/30.0




15.6




(108)




15.6




(108)




0.0






80.0/20.0




15.7




(108)




15.7




(108)




0.0






90.0/10.0




15.7




(108)




15.7




(108)




0.0






96.9/3.1




15.7




(108)




15.7




(108)




0.0






99.0/1.0




15.7




(108)




15.7




(108)




0.0






236eaEβγ/HFC-356mmz






15.1/84.9




16.6




(114)




16.6




(114)




0.0






1/99




16.6




(114)




16.6




(114)




0.0






30/70




16.6




(114)




16.6




(114)




0.0






50/50




16.5




(113)




16.5




(113)




0.0






70/30




16.2




(111)




16.2




(111)




0.0






90/10




15.9




(109)




15.9




(109)




0.0






99/1




15.7




(108)




15.7




(108)




0.0






236faE/HFC-32






8.5/91.5




248.6




(1715)




248.6




(1715)




0.0






1/99




247.2




(1705)




247.0




(1704)




0.1






20/80




247.5




(1707)




246.5




(1700)




0.4






40/60




243.5




(1680)




236.4




(1631)




2.9






50/50




240.0




(1656)




224.0




(1545)




6.7






55/45




237.3




(1637)




213.8




(1475)




9.9






56/44




236.7




(1633)




211.3




(1458)




10.7






236faE/HFC-143






84.0/16.0




42.2




(291)




38.2




(264)




9.5






56.9/43.1




45.1




(311)




45.1




(311)




0.0






30.0/70.0




43.8




(302)




40.4




(279)




7.8






28.0/72.0




43.6




(301)




39.5




(272)




9.4






40.0/60.0




44.6




(308)




43.6




(301)




2.2






27.0/73.0




43.5




(300)




39.0




(269)




10.3






70.0/30.0




44.6




(308)




43.9




(303)




1.6






80.0/20.0




43.2




(298)




40.5




(280)




6.3






86.0/14.0




41.4




(286)




37.0




(255)




10.6






85.0/15.0




41.8




(288)




37.6




(259)




10.0






236faE/HFC-272ca






27.8/72.2




34.8




(240)




34.8




(240)




0.0






10/90




34.7




(239)




34.7




(239)




0.0






1/99




34.5




(238)




34.5




(238)




0.0






40/60




34.7




(239)




34.7




(239)




0.0






60/40




34.2




(236)




34.1




(235)




0.3






70/30




33.7




(232)




33.5




(231)




0.6






90/10




31.6




(218)




31.3




(216)




0.9






99/1




29.8




(205)




29.8




(205)




0.0






236faE/HFC-272fb






82.3/17.7




30.2




(208)




30.2




(208)




0.0






99/1




29.7




(204)




29.7




(204)




0.0






70/30




30.0




(207)




30.0




(207)




0.0






50/50




29.3




(202)




29.2




(201)




0.3






40/60




28.9




(199)




28.6




(197)




1.0






30/70




28.3




(195)




28.0




(193)




1.1






20/80




27.7




(191)




27.5




(189)




0.7






10/90




27.1




(187)




26.9




(185)




0.7






1/99




26.5




(182)




26.5




(182)




0.0






236faE/HFC-281fa






9.3/90.7




37.7




(260)




37.7




(260)




0.0






1/99




37.7




(260)




37.7




(260)




0.0






20/80




37.7




(260)




37.7




(260)




0.0






40/60




37.4




(258)




37.4




(258)




0.0






60/40




36.6




(252)




36.4




(251)




0.5






70/30




35.9




(247)




35.6




(245)




0.8






80/20




34.8




(240)




34.2




(236)




1.7






90/10




32.9




(227)




32.3




(222)




1.8






99/1




30.0




(207)




29.9




(206)




0.3






245faEβγ/HFC-356mff






1.0/99.0




14.9




(103)




14.9




(103)




0.0






4.4/95.6




14.9




(103)




14.9




(103)




0.0






10.0/90.0




14.9




(103)




14.9




(103)




0.0






20.0/80.0




14.8




(102)




14.8




(102)




0.0






30.0/70.0




14.7




(101)




14.7




(101)




0.0






40.0/60.0




14.6




(100)




14.6




(100)




0.0






50.0/50.0




14.4




(99)




14.3




(99)




0.7






60.0/40.0




14.2




(98)




14.1




(97)




0.7






70.0/30.0




13.9




(96)




13.8




(95)




0.7






80.0/20.0




13.6




(93)




13.4




(93)




1.5






90.0/10.0




13.2




(91)




13.1




(90)




0.8






99.0/1.0




12.8




(88)




12.7




(88)




0.8














EXAMPLE 3




Refrigerant Performance




The following table shows the refrigerant performance of various compositions. Except where indicated, the data are based on the following conditions.





















Evaporator temperature




 45.0° F. (7.2° C.)







Condenser temperature




130.0° F. (54.4° C.)







Subcool temperature




 15° F.







Return gas temperature




 65.0° F. (18.3° C.)







Compressor efficiency is




75%.



























TABLE 4











Capacity










Refrig.




Evap.




Cond.






BTU/min




Press.




Press.




Comp. Dis.
















Psia (kPa)




Psia (kPa)




Temp. ° F. (° C.)




COP




(kw)




Comp.























HCFC-22




90.6




(625)




312.6




(2155)




212.8




(100.4)




3.41




351.3




(6.2)






125E/HFC-32






5.0/95.0




146.3




(1009)




502.6




(3465)




250.5




(121.0)




3.14




544.0




(9.6)






40.0/60.0




134.4




(927)




462.2




(3187)




217.3




(102.9)




3.11




474.9




(8.3)






95.0/5.0




82.4




(568)




298.2




(2056)




162.0




(72.2)




3.04




272.7




(4.8)






125E/HFC-125






5.0/95.0




16.2




(112)




70.8




(488)




166.3




(74.6)




3.99




85.8




(1.5)






95.0/5.0*




49.8




(343)




236.8




(1633)




120.5




(49.2)




3.14




209.6




(3.7)











*= Condenser temp. is 80° F., evaporator temp. is 0° F.,






subcool temp. is 25° F. and return gas is 20° F.




















125E/HFC-134















99.0/1.0




74.1




(511)




271.9




(1875)




156.4




(69.1)




2.98




241.6




(4.2)






86.5/13.5




72.3




(498)




266.2




(1835)




158.1




(70.1)




3.06




244.5




(4.3)






37.0/63.0




56.2




(387)




218.2




(1504)




166.9




(74.9)




3.43




228.4




(4.0)






5.0/95.0




44.5




(307)




179.4




(1237)




173.1




(78.4)




3.58




197.6




(3.5)






125E/HFC-134a






5.0/95.0




56.1




(387)




215.9




(1489)




172.0




(77.8)




3.44




228.7




(4.0)






50.0/50.0




63.6




(439)




240.2




(1655)




164.5




(73.6)




3.27




238.6




(4.2)






95.0/5.0




73.0




(503)




268.9




(1854)




157.2




(69.6)




3.00




241.2




(4.2)






125E/HFC-143






5.0/95.0




17.7




(122)




77.8




(536)




190.0




(87.8)




3.87




93.0




(1.6)






92.0/8.0




64.7




(446)




248.4




(1713)




165.0




(73.9)




3.12




231.3




(4.1)






99.0/1.0




76.3




(526)




280.3




(1933)




160.3




(71.3)




3.05




254.9




(4.5)






125E/HFC-143a






5.0/95.0*




110.8




(764)




367.1




(2531)




216.7




(102.6)




3.18




384.5




(6.8)






95.0/5.0+




33.1




(228)




143.5




(989)




119.4




(48.6)




3.40




145.9




(2.6)











*= Subcool temp. is 20° F.






+= Condenser temp. is 80° F., evaporator temp. is 0° F. and return gas temp. is 20° F.




















125E/HFC-152a















5.0/95.0




52.1




(359)




197.2




(1360)




202.1




(94.5)




3.60




227.5




(4.0)






84.4/15.6




75.4




(520)




274.4




(1892)




168.7




(75.9)




3.17




264.0




(4.6)






95.0/5.0




77.6




(535)




282.9




(1951)




163.9




(73.3)




3.07




260.2




(4.6)






125E/HFC-161






5.0/95.0




80.4




(554)




282.6




(1948)




200.3




(93.5)




3.47




317.4




(5.6)






66.5/35.5




89.6




(618)




311.9




(2150)




178.9




(81.6)




3.23




314.7




(5.5)






99.0/1.0




78.9




(544)




288.0




(1986)




162.4




(72.4)




3.02




259.3




(4.6)






125E/HFC-227ca






5.0/95.0




38.2




(263)




149.4




(1030)




143.7




(62.1)




3.22




141.4




(2.5)






95.0/5.0




75.4




(520)




277.1




(1911)




160.9




(71.6)




3.04




250.5




(4.4)






125E/HFC-227ea






5.0/95.0




30.4




(210)




130.4




(899)




140.9




(60.5)




3.24




121.2




(2.1)






95.0/5.0




74.6




(514)




276.0




(1903)




161.0




(71.7)




3.04




249.2




(4.4)






125E/HFC-236cb






5.0/95.0




20.0




(138)




86.2




(594)




146.1




(63.4)




3.57




90.8




(1.6)






95.0/5.0




71.1




(490)




267.4




(1844)




161.7




(72.1)




3.08




244.8




(4.3)






125E/HFC-236fa






5.0/95.0




21.9




(151)




93.2




(643)




145.9




(63.3)




3.53




97.1




(1.7)






95.0/5.0




71.8




(495)




268.8




(1853)




161.5




(71.9)




3.08




245.9




(4.3)






125E/HFC-245ca






5.0/95.0




8.46




(58)




42.6




(294)




156.8




(69.3)




3.97




48.7




(0.9)






95.0/5.0




61.2




(422)




250.5




(1727)




165.9




(74.4)




3.08




226.2




(4.0)






125E/HFC-245cb






5.0/95.0




37.9




(261)




143.0




(986)




139.7




(59.8)




3.33




143.0




(2.5)






95.0/5.0




74.2




(512)




276.8




(1908)




161.5




(71.9)




3.00




246.0




(4.3)






125E/HFC-245ea






5.0/95.0




8.41




(58)




43.2




(298)




161.4




(71.9)




4.00




49.6




(0.9)






95.0/5.0




61.2




(422)




251.0




(1731)




166.2




(74.6)




3.08




226.6




(4.0)






125E/HFC-245fa






5.0/95.0




12.7




((88)




59.7




(412)




154.4




(68.0)




3.80




66.4




(1.2)






95.0/5.0




61.9




(427)




258.4




(1782)




167.6




(75.3)




2.88




216.9




(3.8)






125E/HFC-254ca






5.0/95.0




8.05




(56)




40.5




(279)




160.0




(71.1)




3.99




46.8




(0.8)






95.0/5.0




59.0




(407)




245.6




(1693)




166.7




(74.8)




3.09




222.0




(3.9)






125E/HFC-254cb






5.0/95.0




20.0




(138)




85.0




(586)




154.6




(68.1)




3.67




93.8




(1.6)






95.0/5.0




69.7




(481)




263.2




(1815)




162.1




(72.3)




3.11




243.4




(4.3)






125E/HFC-254eb






5.0/95.0




69.3




(478)




263.5




(1817)




162.5




(72.5)




3.08




241.1




(4.2)






95.0/5.0




67.1




(463)




270.3




(1864)




166.6




(74.8)




2.87




226.9




(4.0)






125E/HFC-263ca






5.0/95.0




10.6




(73)




49.5




(341)




161.5




(71.9)




3.90




57.3




(1.0)






95.0/5.0




61.4




(423)




246.6




(1700)




164.9




(73.8)




3.14




228.5




(4.0)






125E/HFC-263fb






5.0/95.0




31.7




(219)




124.2




(856)




155.0




(68.3)




3.54




134.2




(2.4)






95.0/5.0




72.6




(501)




268.6




(1852)




161.3




(71.8)




3.10




248.1




(4.4)






125E/HFC-272ca






5.0/95.0




20.1




(139)




82.4




(568)




160.4




(71.3)




3.74




94.7




(1.7)






95.0/5.0




67.4




(465)




255.6




(1762)




162.3




(72.4)




3.16




240.8




(4.2)






125E/HFC-272ea






5.0/95.0




11.8




(81)




54.9




(379)




170.0




(76.7)




3.90




64.1




(1.1)






95.0/5.0




61.1




(421)




244.5




(1686)




165.1




(73.9)




3.17




229.2




(4.0)






125E/HFC-272fb






5.0/95.0




15.0




(103)




67.4




(465)




168.1




(75.6)




3.83




78.0




(1.4)






95.0/5.0




64.3




(443)




250.4




(1726)




163.8




(73.2)




3.17




235.5




(4.1)






125E/HFC-281ea






5.0/95.0




27.4




(189)




107.9




(744)




167.8




(75.4)




3.71




124.5




(2.2)






95.0/5.0




69.1




(476)




258.2




(1780)




162.3




(72.4)




3.16




244.6




(4.3)






125E/HFC-281fa






5.0/95.0




21.5




(148)




89.8




(619)




169.0




(76.1)




3.75




103.6




(1.8)






95.0/5.0




66.4




(458)




252.4




(1740)




162.9




(72.7)




3.19




240.1




(4.2)






134E/HFC-227ea






5.0/95.0




35.9




(248)




141.5




(976)




143.9




(62.2)




3.23




134.7




(2.4)






7.3/92.7




36.0




(248)




141.7




(977)




144.5




(62.5)




3.24




135.5




(2.4)






95.0/5.0




16.7




(115)




79.1




(545)




173.0




(78.3)




3.82




89.3




(1.6)






134E/HFC-236fa






14.2/85.8




21.2




(146)




91.1




(628)




148.6




(64.8)




3.50




94.3




(1.7)






5.0/95.0




20.6




(142)




88.6




(611)




146.3




(63.5)




3.48




91.1




(1.6)






95.0/5.0




15.7




(108)




75.9




(523)




174.0




(78.9)




3.74




83.5




(1.5)






134E/HFC-254eb






28.6/71.4




19.0




(131)




82.9




(572)




159.2




(70.7)




3.64




90.4




(1.6)






5.0/95.0




19.0




(131)




81.6




(563)




155.2




(68.4)




3.62




88.7




(1.6)






95.0/5.0




15.5




(107)




74.9




(516)




174.5




(79.2)




3.73




82.2




(1.4)






134E/HFC-356mff






97.1/2.9




15.1




(104)




73.5




(507)




174.4




(79.1)




3.73




80.6




(1.4)






5.0/95.0




8.0




(55)




41.6




(287)




139.4




(59.7)




3.60




41.8




(0.7)






95.0/5.0




15.1




(104)




73.4




(506)




173.4




(78.6)




3.72




80.4




(1.4)






134aE/HFC-32






5.0/95.0




148.4




(1023)




506.8




(3494)




199.1




(92.8)




3.15




511.8




(9.0)






95.0/5.0




51.1




(352)




201.2




(1387)




167.8




(75.4)




3.56




216.6




(3.8)






55/45*




55.4




(382)




227.7




(1571)




153.7




(67.6)




3.50




247.5




(4.4)






11.5/88.5*




77.6




(535)




293.8




(2027)




163.5




(73.1)




3.48




328.8




(5.8)






1/99*




78.9




(544)




299.8




(2068)




166.8




(74.9)




3.49




337.2




(5.9)











*Condenser temp. 90° F., evaporator temp. 10° F., and return gas temp. 30° F.




















134aE/HFC-125















5.0/95.0




113.6




(783)




382.2




(2635)




170.1




(76.7)




2.80




325.1




(5.7)






95.0/5.0




44.6




(308)




178.2




(1229)




164.7




(73.7)




3.45




185.2




(3.3)






134aE/HFC-134






99.0/1.0




41.8




(288)




167.7




(1156)




164.1




(73.4)




3.45




174.7




(3.1)






42.6/57.4




42.9




(296)




171.5




(1183)




174.1




(78.9)




3.53




185.8




(3.3)






1.0/99.0




42.2




(291)




169.6




(1169)




182.2




(83.4)




3.59




188.7




(3.3)






134aE/HFC-134a






5.0/95.0




53.9




(372)




212.0




(1462)




170.8




(77.1)




3.42




221.2




(3.9)






95.0/5.0




42.4




(292)




170.1




(1173)




164.5




(73.6)




3.44




176.8




(3.1)






134aE/HFC-143






5.0/95.0




16.7




(115)




74.9




(516)




192.5




(89.2)




3.81




87.9




(1.5)






95.0/5.0




38.9




(268)




158.7




(1094)




166.0




(74.4)




3.48




166.8




(2.9)






134aE/HFC-143a






5.0/95.0




108.7




(749)




361.3




(2491)




216.8




(102.7)




3.20




381.9




(6.7)






95.0/5.0




45.2




(312)




179.7




(1239)




166.9




(74.9)




3.46




188.3




(3.3)






134aE/HFC-152






99/1




41.9




(289)




168.2




(1160)




164.5




(73.6)




3.45




175.3




(3.1)






19.1/80.9




50.0




(345)




191.4




(1160)




197.6




(73.6)




3.59




218.2




(3.1)






1/99




50.8




(350)




193.2




(1320)




203.8




(92.0)




3.61




223.3




(2.8)






134aE/HFC-152a






5.0/95.0




50.6




(349)




192.8




(1329)




202.5




(94.7)




3.60




222.3




(3.9)






95.0/5.0




42.7




(294)




170.5




(1176)




166.4




(74.7)




3.46




178.8




(3.1)






99/1




41.9




(289)




168.2




(1161)




164.5




(73.6)




3.45




175.3




(3.1)






19.1/80.9




50.0




(345)




191.4




(1161)




197.6




(73.6)




3.59




218.2




(3.1)






1/99




50.8




(351)




193.2




(1321)




203.8




(92.0)




3.61




223.3




(2.8)






134aE/HFC-161






5.0/95.0




79.0




(545)




277.8




(1915)




200.1




(93.4)




3.49




313.7




(5.5)






95.0/5.0




45.5




(314)




180.6




(1245)




167.6




(75.3)




3.45




189.2




(3.3)






134aE/HFC-227ca






5.0/95.0




37.8




(261)




148.1




(1021)




143.9




(62.2)




3.21




140.0




(2.5)






95.0/5.0




42.4




(292)




169.5




(1169)




163.1




(72.8)




3.42




175.0




(3.1)






99/1




41.9




(289)




167.9




(1158)




163.8




(73.2)




3.44




174.5




(3.1)






65.5/34.5




44.7




(308)




174.0




(1200)




156.6




(69.2)




3.33




173.9




(3.1)






1/99




36.8




(253)




143.8




(992)




142.8




(61.6)




3.21




136.1




(2.4)






134aE/HFC-227ea






5.0/95.0




36.9




(254)




145.3




(1002)




143.9




(62.2)




3.22




137.7




(2.4)






95.0/5.0




42.2




(291)




169.3




(1167)




163.1




(72.8)




3.42




174.5




(3.1)






99/1




41.7




(288)




167.5




(1156)




163.7




(73.2)




3.45




174.2




(3.1)






65.4/34.6




39.7




(274)




160.8




(1110)




156.0




(68.9)




3.37




161.3




(2.8)






1/99




28.6




(198)




123.6




(853)




139.8




(59.9)




3.22




114.2




(2.0)






134aE/HFC-236ca






5.0/95.0




14.2




(98)




66.5




(459)




152.1




(66.7)




3.65




70.6




(1.2)






95.0/5.0




39.7




(274)




161.4




(1113)




163.9




(73.3)




3.45




167.8




(3.0)






134aE/HFC-236cb






5.0/95.0




19.5




(134)




84.6




(583)




146.6




(63.7)




3.52




87.9




(1.5)






95.0/5.0




40.7




(281)




164.0




(1131)




163.2




(72.9)




3.45




170.5




(3.0)






134aE/HFC-236fa






5.0/95.0




21.4




(148)




91.6




(632)




146.3




(63.5)




3.49




94.4




(1.7)






95.0/5.0




41.0




(283)




165.1




(1138)




163.3




(72.9)




3.43




170.8




(3.0)






134aE/HFC-245ca






5.0/95.0




7.9




(54)




40.9




(282)




158.2




(70.1)




3.84




45.0




(0.8)






95.0/5.0




36.8




(254)




154.9




(1068)




165.7




(74.3)




3.45




159.8




(2.8)






134aE/HFC-245cb






5.0/95.0




36.6




(252)




139.3




(960)




140.1




(60.1)




3.31




138.5




(2.4)






95.0/5.0




41.7




(288)




166.7




(1149)




162.6




(72.6)




3.44




173.1




(3.0)






99/1




41.8




(288)




167.4




(1155)




163.7




(73.2)




3.45




174.2




(3.1)






57.7/42.3




40.4




(279)




157.8




(1089)




152.7




(67.1)




3.39




161.0




(2.8)






1/99




36.3




(251)




137.6




(949)




139.2




(59.6)




3.31




136.6




(2.4)






134aE/HFC-245ea






5.0/95.0




7.9




(54)




41.5




(286)




163.0




(72.8)




3.86




45.6




(0.8)






95.0/5.0




36.7




(253)




155.2




(1070)




166.1




(74.5)




3.44




159.4




(2.8)






134aE/HFC-245fa






5.0/95.0




12.1




(83)




57.8




(399)




155.4




(68.6)




3.71




62.4




(1.1)






95.0/5.0




38.7




(267)




158.9




(1096)




164.3




(73.5)




3.46




165.4




(2.9)






134aE/HFC-254ca






5.0/95.0




7.6




(52)




39.0




(269)




161.4




(71.8)




3.86




43.2




(0.8)






95.0/5.0




35.9




(248)




152.6




(1052)




166.3




(74.6)




3.45




157.1




(2.8)






134aE/HFC-254cb






5.0/95.0




19.4




(134)




83.1




(573)




155.0




(68.3)




3.63




90.6




(1.6)






95.0/5.0




39.9




(275)




161.5




(1114)




163.8




(73.2)




3.46




168.3




(3.0)






134aE/HFC-254eb






5.0/95.0




19.7




(136)




84.3




(581)




154.9




(68.3)




3.63




91.9




(1.6)






95.0/5.0




39.9




(275)




161.6




(1114)




163.7




(73.2)




3.46




168.6




(3.0)






134aE/HFC-263ca






5.0/95.0




10.1




(70)




48.0




(331)




162.5




(72.5)




3.81




54.1




(1.0)






95.0/5.0




36.8




(254)




153.7




(1060)




165.4




(74.1)




3.47




160.0




(2.8)






134aE/HFC-263fb






5.0/95.0




31.0




(214)




121.9




(840)




155.2




(68.4)




3.53




131.3




(2.3)






95.0/5.0




41.0




(283)




164.5




(1134)




163.4




(73.0)




3.45




171.7




(3.0)






134aE/HFC-272ca






5.0/95.0




19.6




(135)




80.7




(556)




160.8




(71.6)




3.71




91.9




(1.6)






95.0/5.0




39.1




(270)




158.4




(1092)




164.0




(73.3)




3.48




166.7




(2.9)






134aE/HFC-272ea






5.0/95.0




11.3




(78)




53.6




(370)




171.0




(77.2)




3.82




61.1




(1.1)






95.0/5.0




36.7




(253)




153.2




(1056)




165.8




(74.3)




3.48




160.0




(2.8)






134aE/HFC-272fb






5.0/95.0




14.6




(101)




66.0




(455)




168.8




(76.0)




3.77




75.0




(1.3)






95.0/5.0




38.0




(262)




155.9




(1075)




165.0




(73.9)




3.49




163.7




(2.9)






134aE/HFC-281ea






5.0/95.0




26.9




(185)




106.3




(733)




168.0




(75.6)




3.69




122.1




(2.1)






95.0/5.0




39.9




(275)




160.4




(1106)




164.3




(73.5)




3.49




169.2




(3.0)






134aE/HFC-281fa






5.0/95.0




21.1




(145)




88.4




(610)




169.5




(76.4)




3.72




101.0




(1.8)






95.0/5.0




38.9




(268)




157.8




(1088)




164.7




(73.7)




3.49




166.1




(2.9)






143aE/HFC-32






5.0/95.0




147.8




(1019)




504.7




(3480)




199.1




(92.8)




3.16




510.9




(9.0)






95.0/5.0




55.7




(384)




211.3




(1457)




170.0




(76.7)




3.55




230.2




(4.1)






54/46




106.8




(736)




385.7




(2661)




188.3




(86.8)




3.25




391.0




(6.9)






6.2/93.8




147.5




(1017)




502.7




(3468)




198.5




(92.5)




3.17




509.9




(9.0)






1/99




149.2




(1029)




509.7




(3516)




200.0




(93.3)




3.16




518.0




(9.1)






143aE/HFC-125






5.0/95.0




115.3




(795)




385.6




(2659)




170.2




(76.8)




2.80




328.3




(5.8)






95.0/5.0




50.6




(349)




193.4




(1333)




167.5




(75.3)




3.47




205.8




(3.6)






143aE/HFC-134






99.0/1.0




47.9




(33)




183.8




(1267)




167.2




(75.1)




3.48




196.1




(3.4)






92.4/7.6




47.6




(328)




183.3




(1264)




168.1




(75.6)




3.48




196.1




(3.4)






1.0/99.0




42.2




(291)




169.8




(1171)




182.2




(83.4)




3.59




188.9




(3.3)






143aE/HFC-134a






5.0/95.0




54.1




(373)




212.3




(1464)




170.8




(77.1)




3.43




222.0




(3.9)






95.0/5.0




48.2




(332)




185.2




(1277)




167.2




(75.1)




3.47




197.2




(3.5)






143aE/HFC-143






5.0/95.0




16.9




(117)




75.7




(522)




192.3




(89.1)




3.83




89.1




(1.6)






95.0/5.0




44.4




(306)




174.1




(1200)




168.9




(76.1)




3.50




186.8




(3.3)






143aE/HFC-143a






5.0/95.0




108.8




(750)




361.8




(2495)




216.8




(102.7)




3.20




380.8




(6.7)






95.0/5.0




50.5




(348)




194.6




(1342)




170.2




(76.8)




3.44




205.2




(3.6)






53/47




77.4




(534)




275.0




(1897)




189.0




(87.2)




3.37




292.4




(5.1)






8.7/91.3*




106.8




(736)




355.5




(2453)




214.0




(101.1)




3.23




376.8




(6.6)






1/99*




111.7




(770)




368.5




(2542)




219.1




(103.9)




3.19




388.4




(6.8)











*subcool temp. 20° F.




















143aE/HFC-152a















5.0/95.0




50.6




(349)




192.7




(1329)




202.5




(94.7)




3.60




222.4




(3.9)






95.0/5.0




48.0




(331)




184.2




(1270)




169.1




(76.2)




3.49




197.7




(3.5)






99/1




47.9




(330)




183.9




(1268)




167.5




(75.3)




3.47




196.4




(3.5)






48.6/51.4




49.2




(339)




188.3




(1299)




186.9




(86.1)




3.57




211.2




(3.7)






1/99




50.8




(350)




193.2




(1333)




203.8




(95.4)




3.61




223.3




(3.9)






143aE/HFC-161






5.0/95.0




78.9




(544)




277.6




(1914)




200.3




(93.5)




3.48




313.1




(5.5)






95.0/5.0




50.7




(350)




193.7




(1336)




170.0




(76.7)




3.47




206.7




(3.6)






143aE/HFC-227ca






5.0/95.0




38.6




(266)




150.9




(1040)




144.4




(62.4)




3.22




143.0




(2.5)






95.0/5.0




48.5




(334)




186.0




(1282)




166.1




(74.5)




3.45




196.5




(3.5)






99/1




48.0




(331)




184.3




(1271)




166.9




(74.9)




3.47




196.1




(3.5)






71.5/28.5




50.6




(349)




190.7




(1315)




160.5




(71.4)




3.37




195.4




(3.4)






1/99




36.9




(254)




144.6




(997)




142.9




(161)




3.21




136.7




(2.4)






143aE/HFC-227ea






5.0/95.0




37.8




(261)




148.3




(1022)




144.4




(62.4)




3.23




141.0




(2.5)






95.0/5.0




48.5




(334)




185.9




(1282)




166.1




(74.5)




3.45




196.5




(3.5)






99/1




48.0




(331)




184.3




(1271)




166.9




(74.9)




3.47




196.1




(3.5)






75.6/24.4




50.5




(348)




190.4




(1313)




161.4




(71.9)




3.39




196.3




(3.5)






1/99




36.9




(254)




144.6




(997)




142.6




(61.4)




3.21




136.7




(2.4)






143aE/HFC-236ca






5.0/95.0




14.6




(101)




68.4




(472)




152.3




(66.8)




3.67




73.2




(1.3)






95.0/5.0




45.7




(315)




178.3




(1229)




167.1




(75.1)




3.47




188.9




(3.3)






143aE/HFC-236cb






5.0/95.0




19.9




(137)




86.2




(594)




146.9




(63.8)




3.54




90.2




(1.6)






95.0/5.0




46.7




(322)




180.6




(1245)




166.5




(74.7)




3.46




191.2




(3.4)






143aE/HFC-236fa






5.0/95.0




22.0




(152)




93.7




(646)




146.6




(63.7)




3.51




97.2




(1.7)






95.0/5.0




47.1




(325)




181.6




(1252)




166.3




(74.6)




3.46




192.4




(3.4)






143aE/HFC-245ca






5.0/95.0




8.3




(57)




42.3




(292)




158.4




(70.2)




3.88




47.0




(0.8)






95.0/5.0




42.6




(294)




171.3




(1181)




168.8




(76.0)




3.46




180.3




(3.2)






143aE/HFC-245cb






5.0/95.0




37.2




(256)




140.9




(971)




140.3




(60.2)




3.32




140.7




(2.5)






95.0/5.0




47.7




(329)




182.8




(1260)




165.7




(74.3)




3.47




194.2




(3.4)






99/1




48.0




(331)




184.3




(1271)




166.9




(73.3)




3.47




196.1




(3.5)






59.6/40.4




50.9




(351)




190.6




(1315)




157.7




(69.8)




3.33




192.1




(3.4)






20/80




44.3




(305)




169.4




(1168)




148.5




(64.7)




3.25




163.3




(2.9)






143aE/HFC-245ea






5.0/95.0




8.2




(57)




42.7




(294)




163.0




(72.8)




3.90




47.7




(0.8)






95.0/5.0




42.3




(292)




171.3




(1181)




169.5




(76.4)




3.45




179.6




(3.2)






143aE/HFC-245fa






5.0/95.0




12.5




(86)




59.4




(410)




155.0




(68.3)




3.74




65.0




(1.1)






95.0/5.0




44.6




(308)




175.4




(1209)




167.5




(75.3)




3.48




186.2




(3.3)






143aE/HFC-254ca






5.0/95.0




7.8




(54)




40.1




(276)




161.5




(71.9)




3.90




45.1




(0.8)






95.0/5.0




41.5




(286)




168.9




(1165)




169.6




(76.4)




3.45




177.1




(3.1)






143aE/HFC-254cb






5.0/95.0




19.7




(136)




84.3




(581)




155.3




(68.5)




3.64




92.3




(1.6)






95.0/5.0




45.9




(316)




177.8




(1226)




166.8




(74.9)




3.48




189.6




(3.3)






143aE/HFC-254eb






5.0/95.0




20.1




(139)




85.6




(590)




155.2




(68.4)




3.63




93.6




(1.6)






95.0/5.0




45.9




(31.6)




177.9




(1227)




166.7




(74.8)




3.48




189.9




(3.3)






143aE/HFC-263ca






5.0/95.0




10.3




(71)




48.9




(337)




162.6




(72.6)




3.83




55.6




(1.0)






95.0/5.0




42.4




(292)




169.7




(1170)




168.7




(75.9)




3.48




179.9




(3.2)






143aE/HFC-263fb






5.0/95.0




31.3




(216)




122.9




(847)




155.4




(68.6)




3.53




132.5




(2.3)






95.0/5.0




46.9




(323)




180.3




(1243)




166.4




(74.7)




3.48




192.4




(3.4)






143aE/HFC-272ca






5.0/95.0




19.9




(137)




81.6




(563)




160.9




(71.6)




3.71




93.1




(1.6)






95.0/5.0




44.9




(310)




174.3




(1202)




167.0




(75.0)




3.50




187.2




(3.3)






143aE/HFC-272ea






5.0/95.0




11.5




(79)




54.3




(374)




171.0




(77.2)




3.84




62.3




(1.1)






95.0/5.0




42.2




(291)




168.9




(1165)




169.0




(76.1)




3.49




179.8




(3.2)






143aE/HFC-272fb






5.0/95.0




14.8




(102)




66.7




(460)




168.9




(76.1)




3.78




76.1




(1.3)






95.0/5.0




43.5




(300)




171.7




(1184)




168.1




(75.6)




3.50




183.7




(3.2)






143aE/HFC-281ea






5.0/95.0




27.0




(186)




106.7




(736)




168.2




(75.7)




3.69




122.5




(2.2)






95.0/5.0




45.3




(312)




175.2




(1208)




167.3




(75.2)




3.51




188.6




(3.3)






143aE/HFC-281fa






5.0/95.0




21.3




(147)




89.0




(614)




169.5




(76.4)




3.73




101.9




(1.8)






95.0/5.0




44.4




(306)




173.1




(1193)




167.6




(75.3)




3.51




186.0




(3.3)






C216E/HFC-32






5.0/95.0*




156.5




(1079)




525.3




(3622)




197.4




(91.9)




3.30




556.2




(9.8)






95.0/5.0




76.7




(529)




238.9




(1647)




150.5




(65.8)




3.15




252.8




(4.4)











*= subcool temperature of 20.0° F.




















C216E/HFC-125















5.0/95.0*




62.6




(432)




230.8




(1591)




131.3




(55.2)




3.28




233.2




(4.1)






95.0/5.0




58.8




(405)




210.4




(1451)




141.0




(60.0)




2.95




182.0




(3.2)











*= evaporator temperature of 10.0° F., condenser temperature of 90.0° F.






and return gas of 30.0° F.




















C216E/HFC-134















99.0/1.0




60.2




(415)




217.4




(1499)




140.3




(61.2)




2.96




190.1




(3.3)






79.8/20.2




69.3




(478)




245.1




(1690)




146.3




(63.5)




3.01




219.9




(3.9)






1.0/99.0




43.1




(297)




174.9




(1206)




173.9




(78.8)




3.58




192.8




(3.4)






C216E/HFC-134a






5.0/95.0




56.9




(392)




221.2




(1525)




169.4




(76.3)




3.41




229.8




(4.0)






95.0/5.0




59.5




(410)




212.8




(1467)




141.2




(60.7)




2.96




184.1




(3.2)






99/1




58.8




(405)




196.4




(1355)




135.6




(57.6)




3.24




189.3




(3.3)






61.7/38.3




56.2




(387)




202.3




(1395)




139.6




(39.8)




2.93




173.3




(3.1)






1/99




55.1




(380)




215.3




(1485)




170.5




(76.9)




3.44




225.4




(4.0)






C216E/HFC-143






5.0/95.0




18.2




(125)




78.9




(544)




188.7




(87.1)




3.97




97.1




(1.7)






95.0/5.0




54.8




(378)




196.7




(1356)




141.2




(60.7)




3.01




174.1




(3.1)






C216E/HFC-143a






5.0/95.0*




110.9




(765)




365.8




(2522)




215.2




(101.8)




3.18




383.3




(6.7)






95.0/5.0




60.0




(414)




214.1




(1476)




143.2




(61.8)




2.99




188.0




(3.3)











*= subcool temperature of 20.0° F.




















C216E/HFC-152a















5.0/95.0




52.8




(364)




199.0




(1372)




201.0




(93.9)




3.61




230.2




(4.0)






95.0/5.0




61.2




(422)




217.9




(1502)




143.5




(61.9)




2.98




190.9




(3.4)






99/1




57.0




(383)




203.5




(1404)




193.0




(59.4)




2.96




176.5




(3.1)






77.6/22.4




72.4




(499)




250.0




(1725)




155.0




(68.3)




3.08




231.5




(4.1)






1/99




51.0




(351)




195.0




(1345)




204.3




(95.7)




3.58




223.6




(3.9)






C216E/HFC-161






5.0/95.0




81.6




(563)




284.8




(1964)




199.1




(92.8)




3.49




321.2




(5.6)






95.0/5.0




66.8




(461)




237.7




(1639)




145.9




(63.3)




3.00




209.6




(3.7)






99/1




58.4




(403)




207.9




(1434)




140.2




(60.1)




2.99




182.2




(3.2)






58.8/41.2




98.5




(679)




325.5




(2246)




171.2




(77.3)




3.13




315.7




(5.6)






1/99




80.2




(553)




280.6




(1936)




200.8




(93.8)




3.50




318.0




(5.6)






C216E/HFC-227ca






5.0/95.0




37.2




(256)




145.5




(1003)




142.5




(61.4)




3.19




136.5




(2.4)






95.0/5.0




54.3




(374)




196.0




(1351)




139.2




(59.6)




2.95




169.6




(3.0)






C216E/HFC-227ea






5.0/95.0




36.3




(250)




142.5




(983)




142.5




(61.4)




3.20




134.2




(2.4)






95.0/5.0




54.1




(373)




195.6




(1349)




139.3




(59.6)




2.95




169.1




(3.0)






C216E/HFC-236ca






5.0/95.0




14.4




(99)




66.8




(461)




150.3




(65.7)




3.68




71.6




(1.3)






95.0/5.0




51.3




(354)




189.2




(1304)




140.0




(60.0)




2.99




165.6




(2.9)






C216E/HFC-236cb






5.0/95.0




19.4




(138)




84.3




(581)




145.2




(62.9)




3.52




87.3




(1.5)






95.0/5.0




52.4




(361)




191.2




(1318)




139.5




(59.7)




2.98




167.0




(2.9)






C216E/HFC-236fa






5.0/95.0




21.3




(147)




90.9




(627)




144.8




(62.7)




3.48




93.5




(1.6)






95.0/5.0




52.5




(362)




191.7




(1322)




139.6




(59.8)




2.98




167.0




(2.9)






C216E/HFC-245ca






5.0/95.0




8.4




(58)




42.2




(291)




156.5




(69.2)




3.96




48.1




(0.8)






95.0/5.0




48.0




(331)




183.5




(1265)




141.5




(60.8)




2.99




159.9




(2.8)






C216E/HFC-245cb






5.0/95.0




37.1




(256)




140.4




(968)




139.0




(59.4)




3.29




138.6




(2.4)






95.0/5.0




54.8




(378)




196.9




(1358)




139.0




(59.4)




2.95




170.5




(3.0)






99/1




55.5




(382)




198.8




(1371)




139.0




(59.4)




2.94




171.4




(3.0)






95.1/4.9




54.8




(378)




197.0




(1359)




139.0




(59.4)




2.95




170.6




(3.0)






1/99




36.3




(253)




138




(952)




139.0




(59.4)




3.30




136.4




(2.4)






C216E/HFC-245ea






5.0/95.0




8.6




(59)




43.5




(300)




159.4




(70.8)




4.06




50.9




(0.9)






95.0/5.0




49.2




(339)




185.9




(1282)




141.2




(60.7)




2.99




162.2




(2.9)






C216E/HFC-245fa






5.0/95.0




12.5




(86)




58.9




(406)




153.4




(67.4)




3.78




65.1




(1.1)






95.0/5.0




50.6




(349)




187.8




(1295)




140.3




(60.2)




3.00




164.8




(2.9)






C216E/HFC-254ca






5.0/95.0




8.2




(57)




40.7




(281)




158.3




(70.2)




4.04




47.8




(0.8)






95.0/5.0




47.7




(329)




182.5




(1258)




141.6




(60.9)




3.00




159.7




(2.8)






C216E/HFC-254cb






5.0/95.0




19.7




(136)




84.0




(579)




153.7




(67.6)




3.65




92.0




(1.6)






95.0/5.0




52.4




(361)




190.9




(1316)




140.0




(60.0)




2.99




167.8




(2.9)






C216E/HFC-254eb






5.0/95.0




20.1




(139)




85.3




(588)




153.7




(67.6)




3.64




93.2




(1.6)






95.0/5.0




52.5




(362)




191.1




(1318)




139.8




(59.9)




3.00




168.3




(3.0)






C216E/HFC-263ca






5.0/95.0




10.7




(74)




49.6




(342)




160.1




(71.2)




3.93




58.1




(1.0)






95.0/5.0




49.1




(339)




183.8




(1267)




141.0




(60.6)




3.02




163.0




(2.9)






C216E/HFC-263fb






5.0/95.0




31.5




(217)




123.4




(851)




154.3




(67.9)




3.52




132.5




(2.3)






95.0/5.0




54.4




(375)




195.5




(1348)




139.9




(59.9)




2.98




171.7




(3.0)






C216E/HFC-272ca






5.0/95.0 (139)




20.1




(139)




82.2




(567)




159.6




(70.9)




3.74




94.4




(1.7)






95.0/5.0 (361)




52.4




(361)




189.9




(1309)




140.2




(60.1)




3.02




169.1




(3.0)






C216E/HFC-272ea






5.0/95.0




12.3




(85)




56.1




(387)




167.8




(75.4)




4.00




67.6




(1.2)






95.0/5.0




51.2




(353)




187.8




(1295)




140.8




(60.4)




3.03




167.4




(2.9)






C216E/HFC-272fb






5.0/95.0




15.5




(107)




68.4




(472)




166.5




(74.7)




3.89




80.6




(1.4)






95.0/5.0




52.6




(362)




190.9




(1316)




140.5




(60.3)




3.02




169.7




(3.0)






C216E/HFC-281ea






5.0/95.0




27.6




(190)




108.3




(747)




167.0




(75.0)




3.72




125.2




(2.2)






95.0/5.0




55.2




(381)




197.1




(1359)




140.9




(60.5)




3.01




175.1




(3.1)






C216E/HFC-281fa






5.0/95.0




21.9




(151)




90.5




(624)




168.0




(75.6)




3.78




105.3




(1.9)






95.0/5.0




54.2




(374)




194.5




(1341)




141.0




(60.6)




3.01




173.3




(3.1)






C-216E2/HFC-32






5.0/95.0




149.0




(1027)




508.2




(3504)




198.2




(92.3)




3.16




513.2




(9.0)






36.0/64.0*




138.0




(951)




473.4




(3264)




184.7




(84.8)




3.21




475.3




(8.4)






95.0/5.0




56.1




(387)




216.3




(1491)




141.9




(61.1)




3.25




204.7




(3.6)











*20° F. Subcool




















C-216E2/HFC-134















5.0/95.0




42.7




(294)




171.6




(1183)




180.0




(82.2)




3.58




189.6




(3.3)






95.0/5.0




45.4




(313)




174.2




(1201)




136.2




(57.9)




3.11




159.2




(2.8)






60.5/39.5




48.5




(334)




186.1




(1283)




152.3




(66.8)




3.34




186.6




(3.3)






C-216E2/HFC-134a






5.0/95.0




54.8




(378)




214.5




(1479)




169.2




(76.2)




3.42




222.9




(3.9)






20.7/79.4




55.5




(383)




214.9




(1482)




163.8




(73.2)




3.37




219.3




(3.9)






95.0/5.0




46.0




(317)




176.4




(1216)




135.9




(57.7)




3.11




160.9




(2.8)






C-216E2/HFC-143






5.0/95.0




16.7




(115)




74.8




(516)




190.8




(88.2)




3.83




88.1




(1.6)






87.1/12.9




36.4




(251)




146.7




(1011)




142.3




(61.3)




3.30




143.2




(2.5)






95.0/5.0




41.0




(283)




160.5




(1107)




137.0




(58.3)




3.18




149.8




(2.6)






C-216E2/HFC-152a






60.5/39.5




53.8




(371)




200.7




(1384)




164.6




(73.7)




3.42




210.7




(3.7)






5.0/95.0




51.1




(352)




194.3




(1340)




201.3




(94.1)




3.59




223.4




(3.9)






95.0/5.0




46.7




(322)




178.4




(1230)




138.2




(59.0)




3.15




165.3




(2.9)






C-216E2/HFC-161






45.7/54.3




78.8




(543)




275.5




(1900)




178.6




(81.4)




3.39




294.1




(5.2)






5.0/95.0




79.9




(551)




279.8




(1929)




199.1




(92.8)




3.49




315.6




(5.6)






95.0/5.0




51.4




(354)




194.9




(1344)




140.4




(60.2)




3.17




182.1




(3.2)






C-216E2/HFC-245cb






74.7/25.3




41.2




(284)




158.2




(1091)




135.3




(57.4)




3.16




147.4




(2.6)






5.0/95.0




36.4




(251)




138.4




(954)




138.8




(59.3)




3.29




136.7




(2.4)






95.0/5.0




43.5




(300)




167.2




(1153)




134.1




(56.7)




3.09




151.5




(2.7)






218E/HFC-32






5.0/95.0*




155.2




(1070)




523.5




(3609)




197.5




(91.9)




3.30




553.7




(9.7)






95.0/5.0




69.2




(477)




279.5




(1927)




151.1




(66.2)




2.94




227.1




(4.0)











*= subcool temperature of 20.0° F.




















218E/HFC-125















5.0/95.0




62.6




(432)




231.3




(1595)




131.4




(55.2)




3.28




233.0




(4.1)






95.0/5.0




52.1




(359)




203.0




(1400)




140.0




(60.0)




2.83




162.4




(2.9)






218E/HFC-134






99.0/1.0




49.1




(339)




192.4




(1327)




138.2




(59.0)




2.80




152.6




(2.7)






63.3/36.7




63.7




(439)




235.1




(1621)




153.2




(67.3)




3.04




211.5




(3.7)






35.0/65.0




54.8




(378)




213.6




(1473)




167.0




(75.0)




3.34




215.8




(3.8)






5.0/95.0




44.6




(308)




177.3




(1222)




179.4




(81.9)




3.62




198.5




(3.5)






218E/HFC-134a






5.0/95.0




56.5




(390)




220.5




(1520)




169.5




(76.4)




3.41




228.9




(4.0)






95.0/5.0




52.8




(364)




205.7




(1418)




140.4




(60.2)




2.82




164.4




(2.9)






99/1




49.3




(340)




192.8




(1330)




138.0




(53.3)




2.81




153.4




(2.7)






53.0/47.0




70.4




(485)




258.8




(1785)




154.2




(67.9)




3.00




228.7




(4.0)






1/99




55.0




(379)




215.4




(1486)




170.6




(77.0)




3.43




225.2




(4.0)






218E/HFC-143






5.0/95.0




17.9




(123)




78.1




(538)




189.2




(87.3)




3.95




95.3




(1.7)






95.0/5.0




48.1




(332)




187.0




(1289)




139.8




(60.0)




2.90




155.0




(2.7)






218E/HFC-143a






5.0/95.0*




110.8




(764)




366.5




(2527)




215.4




(101.9)




3.18




383.2




(6.7)






95.0/5.0




53.6




(370)




207.7




(1432)




142.5




(61.4)




2.86




169.4




(3.0)











*= subcool temperature of 20.0° F.




















218E/HFC-152a















5.0/95.0




52.5




(362)




198.6




(1369)




201.1




(93.9)




3.61




229.5




(4.0)






95.0/5.0




54.8




(378)




211.7




(1460)




142.8




(61.6)




2.85




172.0




(3.0)






99/1




49.8




(343)




194.4




(1341)




138.6




(59.2)




2.82




155.5




(2.7)






68.2/31.8




69.8




(481)




250.5




(1728)




160.9




(71.6)




3.12




234.9




(4.1)






41/59




63.1




(435)




232.3




(1602)




179.3




(81.8)




3.42




247.4




(4.4)






218E/HFC-161






5.0/95.0




81.5




(562)




284.7




(1963)




199.2




(92.9)




3.49




321.1




(5.7)






95.0/5.0*




61.1




(421)




236.0




(1627)




146.0




(63.3)




3.05




204.6




(3.6)






84/16*




88.3




(609)




275.7




(1907)




146.6




(63.7)




3.74




310.2




(5.5)






62.6/37.4




97.7




(674)




329.2




(2271)




169.3




(76.3)




3.04




307.5




(5.4)






39/61




92.2




(636)




315.8




(2179)




183.2




(84.0)




3.30




329.2




(5.8)











*= subcool temperature of 20.0° F.




















218E/HFC-227ca















5.0/95.0




36.8




(254)




144.7




(998)




142.4




(61.3)




3.18




135.2




(2.4)






95.0/5.0




47.3




(326)




185.9




(1282)




137.8




(58.8)




2.82




148.1




(2.6)






218E/HFC-227ea






5.0/95.0




35.0




(248)




141.8




(978)




142.4




(61.3)




3.20




133.2




(2.3)






95.0/5.0




47.3




(326)




185.7




(1280)




137.7




(58.7)




2.83




149.0




(2.6)






218E/HFC-236ca






5.0/95.0




14.0




(97)




65.7




(453)




150.3




(65.7)




3.65




69.8




(1.2)






95.0/5.0




44.3




(305)




178.3




(1229)




138.3




(59.1)




2.88




145.4




(2.6)






218E/HFC-236cb






5.0/95.0




19.1




(132)




83.0




(572)




145.0




(62.8)




3.51




85.7




(1.5)






95.0/5.0




45.1




(311)




179.8




(1240)




138.0




(58.9)




2.87




146.2




(2.6)






218E/HFC-236fa






5.0/95.0




21.0




(145)




89.8




(619)




144.7




(626)




3.47




92.0




(1.6)






95.0/5.0




45.4




(313)




180.8




(1247)




138.0




(58.9)




2.86




146.6




(2.6)






218E/HFC-245ca






5.0/95.0




8.1




(56)




41.2




(284)




156.0




(68.9)




3.91




56.8




(1.0)






95.0/5.0




41.2




(284)




172.2




(1187)




139.5




(59.7)




2.90




140.4




(2.5)






218E/HFC-245cb






5.0/95.0




36.8




(254)




139.7




(963)




138.9




(59.3)




3.29




137.6




(2.4)






95.0/5.0




47.9




(330)




187.1




(1290)




137.5




(58.6)




2.83




150.4




(2.6)






218E/HFC-245ea






5.0/95.0




8.2




(57)




42.5




(293)




160.1




(71.2)




3.99




48.5




(0.9)






95.0/5.0




42.3




(292)




174.7




(1205)




139.3




(59.6)




2.89




142.4




(2.5)






218E/HFC-245fa






5.0/95.0




12.2




(84)




58.0




(400)




153.6




(67.6)




3.74




63.2




(1.1)






95.0/5.0




43.8




(302)




176.8




(1219)




138.5




(59.2)




2.90




145.0




(2.6)






218E/HFC-254ca






5.0/95.0




7.9




(54)




39.8




(274)




159.0




(70.6)




3.97




45.6




(0.8)






95.0/5.0




40.9




(282)




171.0




(1179)




139.6




(59.8)




2.91




140.4




(2.5)






218E/HFC-254cb






5.0/95.0




19.4




(134)




83.1




(573)




153.7




(67.6)




3.63




90.5




(1.6)






95.0/5.0




45.4




(313)




180.1




(1242)




138.2




(59.0)




2.89




148.0




(2.6)






218E/HFC-254eb






5.0/95.0




19.8




(137)




84.3




(581)




153.5




(67.5)




3.63




91.9




(1.6)






95.0/5.0




45.5




(314)




180.2




(1242)




138.2




(59.0)




2.89




148.2




(2.6)






218E/HFC-263ca






5.0/95.0




10.4




(72)




48.9




(337)




160.5




(71.4)




3.89




56.4




(1.0)






95.0/5.0




42.5




(293)




172.6




(1190)




139.0




(59.4)




2.94




144.0




(2.5)






218E/HFC-263fb






5.0/95.0




31.2




(215)




122.8




(847)




154.2




(67.9)




3.52




131.5




(2.3)






95.0/5.0




47.6




(328)




185.8




(1281)




138.4




(59.1)




2.87




151.8




(2.7)






99/1




48.2




(332)




188.7




(1302)




137.7




(58.7)




2.81




150.2




(2.6)






96.3/3.7




47.8




(329)




186.9




(1289)




138.2




(59.0)




2.85




151.3




(2.7)






1/99




27.9




(192)




120.6




(832)




155.5




(68.6)




3.26




116.9




(2.1)






218E/HFC-272ca






5.0/95.0




19.9




(137)




81.5




(562)




159.6




(70.9)




3.73




93.3




(1.6)






95.0/5.0




45.8




(316)




179.7




(1239)




138.7




(59.3)




2.92




150.1




(2.6)






218E/HFC-272ea






5.0/95.0




12.0




(83)




55.6




(383)




168.4




(75.8)




3.96




65.9




(1.2)






95.0/5.0




44.5




(307)




177.2




(1222)




139.2




(59.6)




2.93




148.3




(2.6)






218E/HFC-272fb






5.0/95.0




15.2




(105)




67.7




(467)




167.0




(75.0)




3.86




78.9




(1.4)






95.0/5.0




45.9




(316)




180.6




(1245)




139.0




(59.4)




2.91




150.5




(2.6)






218E/HFC-281ea






5.0/95.0




27.4




(189)




107.9




(744)




167.0




(75.0)




3.71




124.4




(2.2)






95.0/5.0




48.6




(335)




187.8




(1295)




139.6




(59.8)




2.91




156.6




(2.8)






218E/HFC-281fa






5.0/95.0




21.6




(149)




90.0




(621)




168.3




(75.7)




3.76




104.1




(1.8)






95.0/5.0




47.7




(329)




185.3




(1278)




139.6




(59.8)




2.91




154.7




(2.7)






218E2/HFC-32






5.0/95.0




151.9




(1047)




516.9




(3564)




198.0




(92.2)




2.93




484.2




(8.5)






95.0/5.0




48.6




(335)




211.8




(1460)




140.9




(60.5)




3.43




197.4




(3.5)






218E2/HFC-125






5.0/95.0*




60.8




(419)




228.6




(1576)




131.8




(55.4)




3.26




228.5




(4.0)






95.0/5.0




34.1




(235)




150.5




(1038)




131.9




(55.5)




2.97




123.1




(2.2)











*= evaporator temperature of 10.0° F.,






condenser temperature of 90.0° F., and return gas of 30.0° F.




















218E2/HFC-134















95.0/5.0




33.1




(228)




145.8




(1005)




132.1




(55.6)




2.94




118.9




(2.1)






79.0/21.0




40.1




(276)




169.2




(1167)




140.9




(60.5)




3.06




147.0




(2.6)






46.1/53.9




46.5




(321)




184.9




(1275)




156.6




(69.2)




3.32




183.0




(3.2)






1.0/99.0




42.2




(291)




170.2




(1173)




182.0




(83.3)




3.58




188.8




(3.3)






218E2/HFC-134a






5.0/95.0




54.9




(379)




215.4




(1485)




169.0




(76.1)




3.40




222.7




(3.9)






95.0/5.0




33.6




(232)




148.2




(1022)




132.0




(55.6)




2.94




120.7




(2.1)






72/28




45.8




(316)




189.8




(1309)




143.0




(61.7)




3.07




166.1




(2.9)






24.7/75.3




55.8




(385)




217.6




(1501)




161.1




(71.7)




3.30




215.6




(3.8)






1/99




54.6




(376)




214.3




(1478)




170.6




(77.0)




3.42




223.5




(3.9)






218E2/HFC-143






5.0/95.0




16.6




(114)




174.7




(515)




190.6




(88.1)




3.82




187.7




(1.5)






95.0/5.0




30.2




(208)




133.2




(918)




131.8




(55.4)




2.99




111.2




(2.0)






218E2/HFC-143a






5.0/95.0*




108.9




(751)




363.2




(1067)




215.4




(56.8)




3.18




379.1




(2.3)






95.0/5.0




35.3




(243)




154.7




(1344)




134.3




(93.8)




3.02




129.2




(3.9)











*= subcool temperature of 20.0° F.




















218E2/HFC-152a















5.0/95.0




51.3




(354)




194.9




(1344)




200.9




(93.8)




3.59




223.9




(3.9)






95.0/5.0




35.1




(242)




153.1




(1056)




134.5




(56.9)




2.99




127.5




(2.2)






81/19




45.1




(311)




183.9




(1268)




146.7




(63.7)




3.16




167.7




(3.0)






51.0/49.0




53.4




(368)




203.8




(1406)




168.7




(75.9)




3.38




210.6




(3.7)






1/99




50.9




(351)




193.6




(1335)




203.6




(95.3)




3.60




223.5




(3.9)






218E2/HFC-161






5.0/95.0




80.2




(553)




281.3




(1940)




199.0




(92.8)




3.48




315.9




(5.6)






95.0/5.0




39.9




(275)




173.8




(1198)




137.8




(58.8)




3.05




147.2




(2.6)






78/22




63.2




(436)




246.7




(1702)




156.1




(68.9)




3.11




224.5




(4.0)






46.4/53.6




81.0




(558)




285.4




(1969)




175.4




(80.2)




3.30




293.3




(5.2)






1/99




79.9




(551)




280.0




(1932)




200.8




(93.8)




3.49




316.7




(5.6)






218E2/HFC-227ca






5.0/95.0




36.0




(248)




142.5




(983)




142.0




(61.1)




3.19




133.1




(2.3)






95.0/5.0*




30.6




(211)




135.4




(934)




134.3




(56.8)




2.85




107.3




(1.9)











*= return gas temperature = 70.0° F.




















218E2/HFC-227ea















5.0/95.0




35.2




(243)




139.7




(963)




142.0




(61.1)




3.20




131.1




(2.3)






95.0/5.0*




30.5




(210)




135.2




(932)




134.3




(56.8)




2.85




107.2




(1.9)











*= return gas temperature = 70.0° F.




















218E2/HFC-236ca















5.0/95.0




13.4




(92)




63.6




(439)




150.1




(65.6)




3.60




66.5




(1.2)






95.0/5.0




28.2




(194)




128.0




(883)




129.9




(54.4)




2.96




104.5




(1.8)






218E2/HFC-236cb






5.0/95.0




18.5




(128)




81.1




(559)




144.6




(62.6)




3.49




83.1




(1.5)






95.0/5.0




28.9




(215)




129.8




(895)




129.6




(54.2)




2.94




105.6




(1.9)






218E2/HFC-236fa






5.0/95.0




20.4




(141)




88.0




(607)




144.3




(62.4)




3.45




89.4




(1.6)






95.0/5.0*




29.3




(202)




130.8




(902)




134.4




(56.9)




2.89




105.0




(1.8)






99/1




30.1




(207)




134.3




(926)




133.7




(56.5)




2.84




105.8




(1.9)






89.8/10.2




28.3




(195)




126.7




(874)




130.5




(54.7)




2.98




105.1




(1.8)






1/99




20.3




(140)




87.0




(600)




145.0




(62.8)




3.47




89.0




(1.6)











*= return gas temperature = 70.0° F.




















218E2/HFC-245ca















5.0/95.0




7.4




(51)




38.9




(268)




156.6




(69.2)




3.77




41.7




(0.7)






95.0/5.0




26.2




(181)




122.8




(847)




130.9




(54.9)




3.00




100.9




(1.8)






218E2/HFC-245cb






5.0/95.0




35.9




(248)




137.1




(945)




138.5




(59.2)




3.29




135.0




(2.4)






95.0/5.0*




30.7




(212)




135.4




(934)




134.2




(56.8)




2.87




108.0




(1.9)











*= return gas temperature of 70.0° F.




















218E2/HFC-245ea















5.0/95.0




7.4




(51)




39.7




(274)




161.2




(71.8)




3.81




42.8




(0.8)






95.0/5.0




26.6




(183)




123.9




(854)




130.9




(54.9)




2.99




102.0




(1.8)






218E2/HFC-245fa






5.0/95.0




11.5




(79)




55.8




(385)




153.6




(67.6)




3.67




59.4




(1.0)






95.0/5.0




27.7




(191)




126.6




(873)




130.3




(54.6)




2.97




103.7




(1.8)






218E2/HFC-254ca






5.0/95.0




7.2




(50)




37.4




(258)




159.9




(71.1)




3.81




40.8




(0.7)






95.0/5.0




25.9




(179)




121.4




(837)




131.1




(55.1)




3.02




100.6




(1.8)






218E2/HFC-254cb






5.0/95.0




18.9




(130)




81.1




(897)




153.4




(54.6)




3.61




87.7




(1.9)






95.0/5.0




29.1




(201)




130.1




(569)




130.2




(67.4)




2.96




106.5




(1.6)






218E2/HFC-254eb






5.0/95.0




19.2




(132)




82.5




(569)




153.3




(67.4)




3.60




88.9




(1.6)






95.0/5.0




29.1




(201)




130.0




(896)




130.1




(54.5)




2.96




106.8




(1.9)






218E2/HFC-263ca






5.0/95.0




9.7




(67)




46.6




(321)




161.0




(71.7)




3.78




52.1




(0.9)






95.0/5.0




26.9




(185)




123.1




(849)




130.9




(54.9)




3.03




103.2




(1.8)






218E2/HFC-263fb






5.0/95.0




30.6




(211)




120.7




(832)




153.8




(67.7)




3.52




129.1




(2.3)






95.0/5.0




30.5




(210)




134.3




(926)




130.4




(54.7)




2.95




110.3




(1.9)






99/1




30.6




(211)




120.1




(828)




154.0




(67.8)




3.53




129.4




(2.3)






60.5/39.5




30.8




(212.5)




128.0




(883)




140.5




(60.3)




3.28




122.5




(2.2)






1/99




30.6




(211)




120.2




(829)




154.6




(68.1)




3.53




129.4




(2.3)






218E2/HFC-272ca






5.0/95.0




19.3




(133)




79.8




(550)




159.6




(70.9)




3.69




90.2




(1.6)






95.0/5.0




29.1




(201)




129.1




(890)




130.8




(54.9)




3.00




107.9




(1.9)






218E2/HFC-272ea






5.0/95.0




11.2




(77)




52.9




(365)




169.5




(76.4)




3.82




60.2




(1.1)






95.0/5.0




27.9




(192)




125.7




(867)




131.3




(55.2)




3.02




106.0




(1.9)






218E2/HFC-272fb






5.0/95.0




14.4




(99)




65.4




(451)




167.3




(75.2)




3.77




34.2




(1.3)






95.0/5.0




29.0




(200)




129.1




(890)




131.0




(55.0)




3.01




108.1




(1.9)






218E2/HFC-281ea






5.0/95.0




26.8




(185)




105.9




(730)




166.8




(74.9)




3.69




121.5




(2.1)






95.0/5.0




31.0




(214)




135.2




(932)




131.9




(55.5)




2.99




113.5




(2.0)






218E2/HFC-281fa






5.0/95.0




21.0




(145)




87.9




(606)




168.3




(75.7)




3.72




100.4




(1.8)






95.0/5.0




30.1




(208)




132.3




(912)




131.9




(55.5)




3.00




111.4




(2.0)






C-225eEαβ/HFC-143






55.9/44.1




16.9




(117)




75.2




(518)




167.9




(75.5)




3.73




84.6




(1.5)






5.0/95.0




16.1




(111)




72.6




(501)




191.7




(88.7)




3.80




84.8




(1.5)






95.0/5.0




16.8




(116)




74.4




(513)




148.8




(64.9)




3.60




79.6




(1.4)






C-225eEαβ/HFC-236cb






16.7/83.3




18.4




(127)




80.2




(553)




145.4




(63.0)




3.51




83.1




(1.5)






5.0/95.0




18.3




(126)




79.9




(551)




145.5




(63.1)




3.50




82.5




(1.5)






95.0/5.0




16.9




(117)




74.8




(516)




146.3




(63.5)




3.57




79.0




(1.4)






C-225eEαβ/HFC-236ea






91.5/8.5




16.6




(114)




73.9




(510)




146.6




(63.7)




3.58




78.2




(1.4)






5.0/95.0




15.4




(106)




70.5




(486)




150.2




(65.7)




3.57




73.7




(1.3)






95.0/5.0




16.7




(115)




73.9




(510)




146.4




(63.6)




3.58




78.3




(1.4)






C-225eEαβ/HFC-245cb






22.4/77.6




30.8




(212)




122.2




(843)




140.9




(60.5)




3.38




123.6




(2.2)






5.0/95.0




34.9




(241)




133.9




(923)




139.4




(59.7)




3.32




133.2




(2.3)






95.0/5.0




17.5




(121)




76.9




(530)




145.9




(63.3)




3.59




81.7




(1.4)






227caEαβ/HFC-32*






61/39




55.4




(382)




257.2




(1774)




149.6




(65.3)




3.05




230.4




(4.1)






17.9/82.1




84.3




(581)




312.6




(2156)




158.1




(70.1)




3.43




342.4




(6.0)






1/99




79.4




(547.9)




511.6




(3530)




225.3




(107.4)




1.90




262.3




(4.6)











*Condenser temp. 90° F., Evaporator temp. 10° F., and Return gas Temp. 30° F.




















227caEαβ/HFC-125















5.0/95.0




111.8




(771)




384.0




(2648)




170.5




(76.9)




2.75




318.0




(5.6)






95.0/5.0




26.0




(179)




113.8




(785)




135.3




(57.4)




3.28




106.6




(1.9)






227caEαβ/HFC-134






5.0/95.0




42.4




(292)




170.3




(1174)




179.7




(82.1)




3.57




188.0




(3.3)






95.0/5.0




24.7




(170)




109.4




(754)




136.1




(57.8)




3.25




101.5




(1.8)






227caEαβ/HFC-134a






5.0/95.0




54.3




(374)




212.9




(1468)




169.2




(76.2)




3.41




220.8




(3.9)






95.0/5.0




25.1




(173)




111.2




(767)




135.7




(57.6)




3.25




103.0




(1.8)






227caEαβ/HFC-143






5.0/95.0




16.4




(113)




73.8




(509)




190.7




(88.2)




3.10




86.4




(1.5)






95.0/5.0




22.6




(156)




101.0




(696)




136.4




(58.0)




3.27




94.5




(1.7)






227caEαβ/HFC-143a






5.0/95.0




107.2




(739)




359.0




(2475)




216.0




(102.2)




2.30




270.8




(4.8)






95.0/5.0




27.1




(187)




117.8




(812)




137.6




(58.7)




3.31




111.8




(2.0)






227caEαβ/HFC-152a






5.0/95.0




50.9




(351)




193.4




(1333)




201.1




(93.9)




3.60




222.4




(3.9)






95.0/5.0




26.4




(182)




115.4




(796)




138.0




(58.9)




3.28




108.5




(1.9)






227caEαβ/HFC-161






5.0/95.0




79.7




(550)




279.4




(1926)




199.0




(92.8)




3.48




314.7




(5.5)






95.0/5.0




30.8




(212)




131.4




(906)




139.8




(59.9)




3.34




126.1




(2.2)






227caEαβ/HFC-227ca






5.0/95.0




35.5




(245)




141.0




(972)




142.5




(61.4)




3.19




131.7




(2.3)






95.0/5.0




22.8




(157)




102.7




(708)




134.2




(56.8)




3.20




93.1




(1.6)






227caEαβ/HFC-227ea






5.0/95.0




34.7




(239)




138.3




(954)




142.4




(61.3)




3.20




129.8




(2.3)






95.0/5.0




22.8




(157)




102.6




(707)




134.8




(57.1)




3.20




93.1




(1.6)






227caEαβ/HFC-236ca






5.0/95.0




13.3




(92)




62.9




(433)




150.2




(65.7)




3.60




65.8




(1.2)






95.0/5.0




21.5




(148)




97.3




(671)




134.3




(56.8)




3.24




89.6




(1.6)






227caEαβ/HFC-236cb






5.0/95.0




18.4




(127)




80.3




(554)




144.9




(62.7)




3.49




82.4




(1.4)






95.0/5.0




21.9




(151)




99.0




(682)




134.2




(56.8




3.22




90.7




(1.6)






227caEαβ/HFC-236fa






5.0/95.0




20.1




(140)




87.1




(600)




144.5




(62.5)




3.46




88.9




(1.6)






95.0/5.0




22.1




(152)




99.4




(685)




134.1




(56.7)




3.23




91.2




(1.6)






227caEαβ/HFC-245ca






5.0/95.0




7.4




(51)




38.4




(265)




156.6




(69.2)




3.76




41.0




(0.7)






95.0/5.0




20.4




(141)




94.1




(649)




134.9




(57.2)




3.25




86.5




(1.5)






227caEαβ/HFC-245cb






5.0/95.0




35.4




(244)




135.7




(936)




139.0




(59.4)




3.28




133.4




(2.3)






95.0/5.0




22.9




(158)




102.8




(709)




134.1




(56.7)




3.20




93.5




(1.6)






1/99




36.0




(248.4)




136.9




(944)




139.0




(59.4)




3.30




135.6




(2.4)






8.1/91.9




35.0




(241.5)




134.7




(929)




138.8




(59.3)




3.29




132.7




(2.3)






82/18




24.8




(171)




107.8




(1743)




134.8




(57.1)




3.25




100.6




(1.8)






227caEαβ/HFC-245ea






5.0/95.0




7.4




(51)




39.1




(269)




161.3




(71.8)




3.78




41.9




(0.7)






95.0/5.0




20.6




(142)




94.7




(653)




135.1




(57.3)




3.24




87.0




(1.5)






227caEαβ/HFC-245fa






5.0/95.0




11.5




(79)




54.7




(377)




153.2




(67.3)




3.68




58.7




(1.0)






95.0/5.0




21.5




(148)




96.4




(664)




134.0




(56.7)




3.29




90.2




(1.6)






227caEαβ/HFC-254ca






5.0/95.0




7.1




(49)




36.9




(254)




160.0




(71.1)




3.78




40.0




(0.7)






95.0/5.0




20.3




(140)




93.3




(643)




135.1




(57.3)




3.26




86.2




(1.5)






227caEαβ/HFC-254cb






5.0/95.0




18.7




(129)




80.5




(555)




153.6




(67.6)




3.61




87.0




(1.5)






95.0/5.0




22.0




(152)




98.9




(682)




134.7




(57.1




3.24




91.3




(1.6)






227caEαβ/HFC-254eb






5.0/95.0




19.0




(131)




81.7




(563)




153.5




(67.5)




3.60




88.3




(1.6)






95.0/5.0




22.0




(152)




99.0




(683)




134.7




(57.1)




3.24




91.4




(1.6)






227caEαβ/HFC-263ca






5.0/95.0




9.7




(67)




46.2




(318)




161.1




(71.7)




3.77




51.4




(0.9)






95.0/5.0




20.8




(143)




94.5




(651)




135.1




(57.3)




3.27




88.0




(1.5)






227caEαβ/HFC-263fb






5.0/95.0




30.3




(209)




119.6




(825)




154.1




(67.8)




3.52




128.1




(2.3)






95.0/5.0




22.9




(158)




102.3




(706)




135.0




(57.2)




3.23




94.2




(1.7)






227caEαβ/HFC-272ca






5.0/95.0




19.2




(132)




79.3




(54.7)




159.8




(71.0)




3.69




89.6




(1.6)






95.0/5.0




22.2




(153)




98.9




(682)




135.4




(57.4)




3.26




92.4




(1.6)






99/1




22.3




(153)




100.2




(691)




133.8




(56.6)




3.23




91.8




(1.6)






94.3/5.7




22.1




(152)




98.5




(679)




135.5




(57.5)




3.28




92.5




(1.6)






1/99




19.1




(131)




78.6




(542)




160.4




(71.3)




3.70




89.4




(1.6)






227caEαβ/HFC-272ea






5.0/95.0




11.1




(76)




51.5




(355)




168.6




(75.9)




3.84




59.2




(1.0)






95.0/5.0




21.4




(148)




96.5




(665)




135.7




(57.6)




3.28




90.4




(1.6)






227caEαβ/HFC-272fb






5.0/95.0




14.3




(98)




64.6




(445)




167.4




(75.2)




3.76




73.2




(1.3)






95.0/5.0




21.9




(151)




98.5




(679)




135.7




(51.6)




3.27




91.8




(1.6)






227caEαβ/HFC-281ea






5.0/95.0




26.6




(184)




105.3




(726)




167.0




(75.0)




3.69




120.7




(2.1)






95.0/5.0




23.4




(162)




103.3




(712)




136.3




(57.9)




3.28




97.2




(1.7)






99/1




22.5




(155)




101.2




(698)




134.1




(56.7)




3.22




92.6




(1.6)






31.5/68.5




26.8




(184)




107.4




(741)




160.6




(71.4)




3.63




119.7




(2.1)






1/99




26.6




(183)




104.9




(723)




167.8




(75.4)




3.70




120.7




(2.1)






227caEαβ/HFC-281fa






5.0/95.0




20.8




(144)




87.5




(604)




168.6




(75.9)




3.71




99.6




(1.8)






95.0/5.0




22.8




(157)




101.4




(699)




136.3




(57.9)




3.28




95.2




(1.7)






99/1




22.4




(154)




100.7




(694)




134.0




(56.7)




3.20




92.4




(1.6)






84.3/15.7




23.4




(161)




101.3




(699)




141.8




(61.0)




3.39




100.2




(1.8)






1/99




20.7




(142)




86.8




(598)




169.3




(76.3)




3.72




99.4




(1.7)






227caEβγ/HFC-32






5.0/95.0




152.1




(1049)




517.0




(3565)




198.4




(924)




2.92




483.9




(8.5)






95.0/5.0*




42.9




(296)




190.1




(1311)




152.0




(66.7)




3.77




200.3




(3.5)






67/33




98.9




(682)




360.0




(2484)




169.6




(76.4)




3.35




365.6




(6.4)






28.4/71.6*




159.9




(1103)




477.2




(3292)




176.6




(80.3)




3.61




550.1




(9.7)






1/99




150.1




(1035)




512.2




(3534)




199.9




(93.3)




3.16




519.7




(9.1)











*= subcool temperature of 20.0° F.




















227caEβγ/HFC-125















5.0/95.0*




59.7




(412)




226.0




(1558)




132.8




(56.0)




3.27




226.3




(4.0)






95.0/5.0




30.3




(209)




130.7




(901)




141.8




(61.0)




3.31




124.1




(2.2)











*= evaporator temperature of 10.0° F., condenser temperature of 90.0° F.,






and return gas temperature of 30.0° F.




















227caEβγ/HFC-134















95.0/5.0




29.2




(201)




126.5




(872)




142.3




(61.3)




3.27




118.7




(2.1)






76.0/24.0




37.1




(256)




152.2




(1049)




149.9




(65.5)




3.38




151.3




(2.7)






34.8/65.2




44.2




(305)




175.3




(1209)




166.9




(74.9)




3.46




184.2




(3.2)






1.0/99.0




42.2




(291)




170.0




(1172)




182.0




(83.3)




3.59




188.7




(3.3)






227caEβγ/HFC-134a






5.0/95.0




54.7




(377)




214.0




(1475)




169.5




(76.4)




3.41




222.2




(3.9)






95.0/5.0




29.6




(204)




128.5




(886)




142.0




(61.1)




3.27




120.7




(2.1)






67/33




42.7




(294)




175.0




(1207)




152.2




(66.8)




3.31




169.4




(3.0)






1.9/98.1




54.6




(376)




214.0




(1476)




170.3




(76.8)




3.43




223.2




(3.9)






1/99




54.6




(376)




214.0




(1476)




170.7




(77.1)




3.43




223.4




(3.9)






227caEβγ/HFC-143






5.0/95.0




16.5




(114)




74.4




(513)




191.4




(88.6)




3.81




87.2




(1.5)






95.0/5.0




26.9




(185)




116.6




(804)




142.2




(61.2)




3.29




110.9




(2.0)






227caEβγ/HFC-143a






5.0/95.0*




107.8




(743)




360.6




(2486)




216.6




(102.6)




3.18




377.2




(6.6)






95.0/5.0




31.3




(216)




134.3




(926)




144.3




(62.4)




3.35




129.6




(2.3)











*= subcool temperature of 20.0° F.




















227caEβγ/HFC-152a















5.0/95.0




51.0




(352)




194.2




(1339)




201.5




(94.2)




3.59




223.1




(3.9)






95.0/5.0




30.9




(213)




132.6




(914)




144.4




(62.4)




3.31




126.6




(2.2)






78/22




41.4




(285)




167.0




(1152)




157.6




(69.8)




3.39




168.3




(3.0)






38.3/61.7




51.4




(354)




195.1




(1346)




182.2




(83.4)




3.50




213.6




(3.8)






1/99




50.8




(350)




193.4




(1334)




203.6




(95.3)




3.6




223.5




(3.9)






227caEβγ/HFC-161






5.0/95.0




80.0




(552)




280.1




(1931)




199.3




(92.9)




3.48




315.6




(5.6)






95.0/5.0




35.1




(242)




149.6




(1031)




146.9




(63.8)




3.39




146.2




(2.6)






72/28




60.9




(420)




233.8




(1613)




168.0




(75.6)




3.32




234.0




(4.1)






34.4/65.6




54.1




(373)




247.5




(1707)




180.6




(82.6)




2.73




194.7




(3.4)






1/99




79.8




(550)




279.8




(1930)




200.8




(93.8)




3.49




316.7




(5.6)






227caEβγ/HFC-227ca






5.0/95.0




35.8




(247)




141.8




(978)




142.6




(61.4)




3.20




133.1




(2.3)






95.0/5.0




27.2




(188)




118.5




(817)




139.8




(59.9)




3.23




109.8




(1.9)






227caEβγ/HFC-227ea






5.0/95.0




35.0




(241)




139.0




(958)




142.6




(61.4)




3.21




131.0




(2.3)






95.0/5.0




27.2




(188)




118.3




(816)




139.7




(59.8)




3.23




109.7




(1.9)






227caEβγ/HFC-236ca






5.0/95.0




13.4




(92)




63.9




(441)




150.7




(65.9)




3.60




66.4




(1.2)






95.0/5.0




25.5




(176)




112.6




(776)




140.3




(60.2)




3.27




105.5




(1.9)






227caEβγ/HFC-236cb






5.0/95.0




18.5




(129)




80.9




(578)




145.3




(62.9)




3.49




82.9




(1.5)






95.0/5.0




26.1




(180)




114.3




(788)




139.9




(59.9)




3.25




106.7




(1.9)






227caEβγ/HFC-236fa






5.0/95.0




20.4




(141)




87.6




(604)




144.9




(62.7)




3.46




89.5




(1.6)






95.0/5.0




26.3




(181)




114.9




(792)




139.8




(59.9)




3.26




107.3




(1.9)






227caEβγ/HFC-245ca






5.0/95.0




7.4




(51)




38.8




(268)




157.1




(69.5)




3.78




41.7




(0.7)






95.0/5.0




24.0




(165)




108.6




(749)




141.2




(60.7)




3.29




102.0




(1.8)






227caEβγ/HFC-245cb






5.0/95.0




35.7




(246)




136.4




(940)




139.1




(59.5)




3.30




134.7




(2.4)






95.0/5.0




27.3




(188)




118.4




(816)




139.6




(59.8)




3.24




110.1




(1.9)






227caEβγ/HFC-245ea






5.0/95.0




7.4




(51)




39.6




(273)




161.8




(72.1)




3.81




42.7




(0.8)






95.0/5.0




24.3




(168)




109.5




(755)




141.2




(60.7)




3.29




102.8




(1.8)






227caEβγ/HFC-245fa






5.0/95.0




11.5




(79)




55.7




(384)




153.2




(67.3)




3.68




59.5




(1.0)






95.0/5.0




25.2




(174)




111.5




(769)




139.5




(59.7)




3.29




105.1




(1.8)






227caEβγ/HFC-254ca






5.0/95.0




7.2




(50)




37.3




(257)




160.5




(71.4)




3.81




40.6




(0.7)






95.0/5.0




23.8




(164)




107.7




(743)




141.4




(60.8)




3.31




101.6




(1.8)






227caEβγ/HFC-254cb






5.0/95.0




18.8




(130)




81.0




(558)




153.9




(67.7)




3.61




87.7




(1.5)






95.0/5.0




26.1




(180)




114.1




(787)




142.4




(60.2)




3.27




107.4




(1.9)






227caEβγ/HFC-254eb






5.0/95.0




19.2




(132)




82.2




(567)




153.8




(67.7)




3.61




89.0




(1.6)






95.0/5.0




26.2




(181)




114.4




(789)




140.3




(60.2)




3.28




107.8




(1.9)






227caEβγ/HFC-263ca






5.0/95.0




9.7




(67)




46.5




(321)




161.5




(71.9)




3.78




52.0




(0.9)






95.0/5.0




24.5




(169)




109.1




(752)




141.2




(60.7)




3.31




103.4




(1.8)






227caEβγ/HFC-263fb






5.0/95.0




30.5




(210)




120.1




(828)




154.3




(67.9)




3.52




128.9




(2.3)






95.0/5.0




27.2




(188)




117.8




(812)




140.6




(60.3)




3.26




110.6




(1.9)






99/1




26.9




(185)




117.3




(809)




139.7




(59.8)




3.24




109.1




(1.9)






32.9/67.1




29.9




(206)




120.2




(829)




150.9




(66.1)




3.47




125.4




(2.2)






1/99




30.6




(211)




120.1




(828)




154.7




(68.2)




3.53




129.3




(2.3)






227caEβγ/HFC-272ca






5.0/95.0




19.3




(133)




79.5




(548)




159.9




(71.1)




3.70




90.2




(1.6)






95.0/5.0




26.2




(181)




113.7




(784)




140.9




(60.5)




3.30




108.2




(1.9)






99/1




26.7




(184)




116.6




(204)




139.8




(159)




3.25




108.6




(1.9)






89.0/11.0




25.5




(176)




109.7




(756)




142.6




(61.4)




3.36




107.3




(1.9)






1/99




19.1




(131)




78.7




(543)




160.5




(71.4)




3.70




89.5




(1.6)






227caEβγ/HFC-272ea






5.0/95.0




11.1




(77)




52.7




(363)




169.9




(76.6)




3.82




60.0




(1.1)






95.0/5.0




25.3




(174)




111.1




(766)




141.4




(60.8)




3.32




106.1




(1.9)






227caEβγ/HFC-272fb






5.0/95.0




14.4




(99)




65.1




(449)




167.8




(75.4)




3.77




73.9




(1.3)






95.0/5.0




26.0




(179)




113.4




(782)




141.3




(60.7)




3.30




107.9




(1.9)






227caEβγ/HFC-281ea






5.0/95.0




26.7




(184)




105.7




(729)




167.3




(75.2)




3.69




121.1




(2.1)






95.0/5.0




27.7




(191)




118.8




(819)




142.0




(61.1)




3.28




113.0




(2.0)






99/1




27.0




(186)




117.6




(811)




140.0




(60.0)




3.25




109.6




(1.9)






73.1/26.9




28.9




(199)




118.6




(818)




150.6




(65.9)




3.46




122.7




(2.2)






1/99




26.6




(183)




105.0




(724)




167.9




(75.5)




3.69




120.8




(2.1)






227caEβγ/HFC-281fa






5.0/95.0




20.9




(144)




87.8




(605)




168.7




(75.9)




3.72




100.2




(1.8)






95.0/5.0




27.0




(186)




116.5




(803)




141.9




(61.1)




3.30




111.1




(2.0)






99/1




26.9




(185)




117.2




(808)




140.0




(60.0)




3.25




109.3




(1.9)






85.9/14.1




26.8




(184)




113.6




(783)




145.9




(63.2)




3.40




113.3




(2.0)






1/99




20.7




(142)




86.9




(599)




169.4




(76.3)




3.72




99.4




(1.7)






227eaE/HFC-32






5.0/95.0




152.1




(1049)




516.9




(3564)




198.3




(92.4)




2.93




484.1




(8.5)






95.0/5.0*




45.3




(312)




196.1




(1352)




151.3




(66.3)




3.77




208.1




(3.7)






68/32**




51.2




(353)




240.8




(1661)




144.4




(62.4)




3.26




228.0




(4.0)






30.0/70.0




160.9




(1110)




479.0




(3305)




175.8




(79.9)




3.60




549.5




(9.7)






1/99




150.1




(1035)




512.3




(3534)




199.8




(93.2)




3.16




519.7




(9.1)











*Subcool temp. 20.0° F.






**Subcool temp. 20° F., Return gas temp. 30° F.




















227eaE/HFC-125















5.0/95.0*




60.0




(414)




226.5




(1562)




132.6




(55.9)




3.27




227.1




(4.0)






95.0/5.0




31.8




(219)




135.8




(936)




141.8




(61.0)




3.29




128.0




(2.3)











*= evaporator temperature of 10.0° F.,






condenser temperature of 90.0° F., and






return gas temperature of 30.0° F.




















227eaE/HFC-134















95.0/5.0




30.7




(211)




131.9




(909)




142.3




(61.3)




3.24




122.9




(2.2)






78.0/22.0




37.2




(256)




154.6




(1066)




149.9




(65.5)




3.29




148.8




(2.6)






38.2/61.8




44.8




(309)




177.0




(1220)




165.5




(74.2)




3.44




184.5




(3.2)






1.0/99.0




42.2




(291)




170.0




(1172)




182.0




(83.3)




3.59




188.8




(3.3)






227eaE/HFC-134a






5.0/95.0




54.7




(377)




214.3




(1478)




169.5




(76.4)




3.41




222.5




(3.9)






95.0/5.0




31.1




(214)




134.0




(924)




142.1




(61.2)




3.24




124.6




(2.2)






70/30




43.0




(296)




175.6




(1211)




151.0




(66.1)




3.29




168.8




(3.0)






9.3/90.7




54.8




(378)




214.3




(1478)




168.2




(75.7)




3.40




221.1




(3.9)






1/99




54.6




(376)




214.1




(1477)




170.6




(77.0)




3.43




223.5




(3.9)






227eaE/HFC-143






5.0/95.0




16.6




(114)




74.6




(514)




191.3




(88.5)




3.81




87.4




(1.5)






95.0/5.0




28.3




(195)




121.7




(839)




142.2




(61.2)




3.27




115.0




(2.0)






227eaE/HFC-143a






5.0/95.0*




108.1




(745)




361.2




(2490)




216.5




(102.5)




3.18




377.9




(6.7)






95.0/5.0




32.8




(226)




139.6




(963)




144.4




(62.4)




3.32




133.4




(2.3)











*= subcool temperature of 20.0° F.




















227eaE/HFC-152a















5.0/95.0




51.1




(352)




194.5




(1341)




201.6




(94.2)




3.59




223.3




(3.9)






95.0/5.0




32.5




(224)




138.1




(952)




144.5




(62.5)




3.28




130.8




(2.3)






80/20




42.1




(290)




169.3




(1168)




156.1




(68.9)




3.36




168.9




(3.0)






42.1/57.9




52.1




(359)




197.3




(1361)




179.9




(82.2)




3.48




213.7




(3.8)






1/99




50.8




(350)




193.5




(1335)




203.7




(95.4)




3.60




223.5




(3.9)






227eaE/HFC-161






5.0/95.0




80.0




(552)




280.3




(1933)




199.3




(92.9)




3.48




315.8




(5.6)






95.0/5.0




36.7




(253)




155.1




(1069)




146.9




(63.8)




3.36




150.1




(2.6)






73/27




61.8




(426)




236.3




(1630)




167.1




(75.1)




3.30




235.0




(4.1)






37.5/62.5




79.3




(547)




278.3




(1920)




185.1




(85.1)




3.38




298.1




(5.2)






1/99




79.8




(550)




279.8




(1930)




200.8




(93.8)




3.49




316.7




(5.6)






227eaE/HFC-227ca






5.0/95.0




35.9




(248)




142.0




(979)




142.6




(61.4)




3.20




133.3




(2.3)






95.0/5.0




28.7




(198)




123.6




(852)




139.7




(59.8)




3.21




113.9




(2.0)






227eaE/HFC-227ea






5.0/95.0




35.1




(242)




139.1




(959)




142.6




(61.4)




3.21




131.1




(2.3)






95.0/5.0




28.6




(197)




123.3




(850)




139.7




(59.8)




3.21




113.7




(2.0)






227eaE/HFC-236ca






5.0/95.0




13.4




(92)




63.5




(438)




150.7




(65.9)




3.60




66.5




(1.2)






95.0/5.0




26.7




(184)




117.4




(809)




140.3




(60.2)




3.25




109.3




(1.9)






227eaE/HFC236cb






5.0/95.0




18.5




(128)




81.0




(558)




145.2




(62.9)




3.49




83.3




(1.5)






95.0/5.0




27.5




(190)




119.3




(823)




139.8




(59.9)




3.24




111.0




(2.0)






227eaE/HFC-236fa






5.0/95.0




20.4




(141)




87.8




(605)




144.9




(62.7)




3.46




89.6




(1.6)






95.0/5.0




27.6




(190)




119.9




(827)




139.8




(59.9)




3.24




111.3




(2.0)






227eaE/HFC-245ca






5.0/95.0




7.5




(52)




38.9




(268)




157.1




(69.5)




3.78




41.9




(0.7)






95.0/5.0




25.2




(174)




113.4




(782)




141.3




(60.7)




3.27




105.6




(1.9)






227eaE/HFC-245cb






5.0/95.0




35.8




(247)




136.6




(942)




139.0




(59.4)




3.30




134.9




(2.4)






95.0/5.0




28.7




(198)




123.5




(852)




139.6




(59.8)




3.22




114.2




(2.0)






227eaE/HFC-245ea






5.0/95.0




7.4




(51)




39.7




(274)




161.9




(72.2)




3.81




42.9




(0.8)






95.0/5.0




25.6




(177)




114.3




(788)




141.2




(60.7)




3.27




106.7




(1.9)






227eaE/HFC-245fa






5.0/95.0




11.6




(80)




55.8




(385)




154.2




(67.9)




3.67




59.6




(1.0)






95.0/5.0




26.4




(182)




116.4




(803)




140.6




(60.3)




3.26




108.6




(1.9)






227eaE/HFC-254ca






5.0/95.0




7.2




(50)




37.4




(258)




160.4




(71.3)




3.81




40.9




(0.7)






95.0/5.0




25.0




(172)




112.4




(775)




141.4




(60.8)




3.28




105.3




(1.9)






227eaE/HFC-254cb






5.0/95.0




18.9




(130)




81.1




(559)




153.9




(67.7)




3.61




87.8




(1.5)






95.0/5.0




27.5




(190)




119.4




(823)




140.5




(60.3)




3.25




111.2




(2.0)






227eaE/HFC-254eb






5.0/95.0




19.2




(132)




82.3




(567)




153.8




(67.7)




3.61




89.1




(1.6)






95.0/5.0




27.5




(190)




119.2




(822)




140.4




(60.2)




3.25




111.4




(2.0)






227eaE/HFC-263ca






5.0/95.0




9.8




(68)




46.7




(322)




161.5




(71.9)




3.78




52.2




(0.9)






95.0/5.0




25.7




(177)




113.8




(785)




141.2




(60.7)




3.29




107.3




(1.9)






227eaE/HFC-263fb






5.0/95.0




30.5




(210)




120.3




(829)




154.3




(67.9)




3.52




129.0




(2.3)






95.0/5.0




28.6




(197)




122.7




(846)




140.6




(60.3)




3.24




114.6




(2.0)






99/1




28.4




(194)




122.7




(846)




139.7




(59.8)




3.22




113.4




(2.0)






49.3/50.7




30.0




(207)




121.8




(840)




148.5




(64.7)




3.42




124.4




(2.2)






1/99




30.6




(211)




120.1




(828)




154.7




(68.2)




3.53




129.3




(2.3)






227eaE/HFC-272ca






5.0/95.0




19.3




(133)




79.5




(548)




159.9




(71.1)




3.70




90.2




(1.6)






95.0/5.0




27.4




(189)




118.1




(814)




141.0




(60.6)




3.27




111.6




(2.0)






99/1




28.2




(194)




121.8




(840)




139.9




(59.9)




3.22




112.6




(2.0)






90.7/9.3




26.7




(184)




114.4




(789)




142.1




(61.2)




3.33




110.8




(2.0)






29/71




20.6




(142)




85.4




(589)




156.1




(68.9)




3.66




95.0




(1.7)






227eaE/HFC-272ea






5.0/95.0




11.2




(77)




52.8




(364)




169.9




(76.6)




3.82




60.2




(1.0)






95.0/5.0




26.6




(183)




116.1




(800)




141.6




(60.9)




3.29




109.8




(1.9)






227eaE/HFC-272fb






5.0/95.0




14.4




(99)




65.2




(450)




167.8




(75.4)




3.77




73.9




(1.3)






95.0/5.0




27.3




(188)




118.3




(816)




141.3




(60.7)




3.28




111.9




(2.0)






227eaE/HFC-281ea






5.0/95.0




26.7




(184)




105.8




(729)




167.3




(75.2)




3.68




121.2




(2.1)






95.0/5.0




29.1




(201)




123.7




(853)




141.9




(61.0)




3.27




117.1




(2.1)






99/1




28.5




(196)




123.0




(848)




140.0




(60.0)




3.23




113.9




(2.0)






76.8/23.2




29.8




(205)




122.1




(842)




149.2




(65.1)




3.43




124.9




(2.2)






1/99




26.6




(183)




105.1




(725)




167.9




(75.5)




3.59




120.8




(2.1)






227eaE/HFC-281fa






5.0/95.0




21.0




(145)




87.9




(606)




168.6




(75.9)




3.72




100.5




(1.8)






95.0/5.0




28.4




(196)




121.5




(838)




141.9




(61.0)




3.28




115.3




(2.0)






99/1




28.4




(196)




122.5




(845)




140.0




(60.0)




3.23




113.6




(2.0)






87.6/12.4




20.7




(142)




86.7




(598)




169.2




(76.2)




3.73




99.6




(1.8)






1/99




20.7




(142)




87.0




(600)




169.4




(76.3)




3.72




99.5




(1.8)






C-234fEαβ/HFC-245cb






13.5/86.5




29.3




(202)




119.3




(823)




142.1




(61.2)




3.38




119.8




(2.1)






5.0/95.0




33.5




(231)




130.5




(900)




140.1




(60.1)




3.33




130.0




(2.3)






95.0/5.0




9.4




(65)




45.5




(314)




151.4




(66.3)




3.76




50.0




(0.9)






C-234fEαβ/HFC-245eb






49.1/50.9




11.6




(80)




55.7




(384)




152.3




(66.8)




3.67




59.5




(1.0)






5.0/95.0




8.6




(59)




43.2




(298)




156.3




(69.1)




3.71




46.2




(0.8)






95.0/5.0




8.6




(59)




41.9




(289)




152.6




(67.0)




3.73




45.5




(0.8)






C-234fEαβ/HFC-356mff






59.0/41.0




9.1




(63)




44.6




(308)




145.3




(62.9)




3.64




46.9




(0.8)






5.0/95.0




7.6




(52)




39.4




(272)




138.4




(59.1)




3.55




39.1




(0.7)






95.0/5.0




8.6




(59)




42.2




(291)




151.5




(66.4)




3.72




45.7




(0.8)






C-234fEαβ/






HFC-356mmz






50.1/49.9




9.9




(68)




47.1




(325)




143.4




(61.9)




3.62




49.5




(0.9)






5.0/95.0




8.7




(60)




43.2




(298)




137.5




(58.6)




3.54




43.4




(0.8)






95.0/5.0




8.7




(60)




42.5




(293)




151.4




(66.3)




3.73




46.2




(0.8)






C-234fEβγ/HFC-245ca






33.6/66.4




7.2




(50)




37.0




(255)




156.3




(69.1)




3.74




39.7




(0.7)






5.0/95.0




7.0




(48)




36.7




(253)




157.8




(69.9)




3.74




39.2




(0.7)






95.0/5.0




6.6




(46)




33.9




(234)




154.5




(68.1)




3.76




36.7




(0.6)






C-234fEβγ/HFC-245cb






10.2/89.8




29.5




(203)




120.8




(833)




142.3




(61.3)




3.36




120.3




(2.1)






5.0/95.0




32.8




(226)




129.0




(889)




140.5




(60.3)




3.33




128.5




(2.3)






95.0/5.0




7.5




(52)




37.7




(260)




153.0




(67.2)




3.89




42.4




(0.7)






C-234fEβγ/HFC-245ea






36.0/64.0




7.0




(48)




36.9




(254)




159.5




(70.8)




3.76




39.6




(0.7)






5.0/95.0




6.9




(48)




37.2




(256)




162.6




(72.6)




3.77




39.7




(0.7)






95.0/5.0




6.6




(46)




33.9




(234)




154.8




(68.2)




3.76




36.7




(0.6)






C-234fEβγ/HFC-254ca






36.0/64.0




6.9




(48)




35.6




(245)




158.6




(70.3)




3.77




38.6




(0.7)






5.0/95.0




6.8




(47)




35.3




(243)




161.1




(71.7)




3.77




38.1




(0.7)






95.0/5.0




6.6




(46)




33.8




(233)




154.7




(68.2)




3.76




36.7




(0.6)






C-234fEβγ/HFC-356mff






43.1/56.9




7.8




(54)




39.7




(274)




143.9




(62.2)




3.63




41.1




(0.7)






5.0/95.0




7.4




(51)




38.8




(268)




138.5




(59.2)




3.55




38.4




(0.7)






95.0/5.0




6.7




(46)




34.3




(236)




153.4




(67.4)




3.76




37.1




(0.7)






C-234fEβγ/






HFC-356mmz






35.8/64.2




8.4




(58)




41.5




(286)




142.4




(61.3)




3.61




43.0




(0.8)






5.0/95.0




8.5




(59)




42.2




(291)




137.6




(58.7)




3.54




42.4




(0.7)






95.0/5.0




6.7




(46)




34.3




(236)




153.3




(67.4)




3.76




37.2




(0.7)






236caE/HFC-245ca






5.0/95.0




7.0




(48)




36.6




(252)




157.7




(69.8)




3.74




39.0




(0.7)






50.0/50.0




6.7




(46)




36.5




(252)




154.4




(68.0)




3.71




37.8




(0.7)






95.0/5.0




6.2




(43)




35.7




(246)




150.9




(66.1)




3.67




35.7




(0.6)






236caE/HFC-254ca






99/1




6.2




(42)




35.5




(245)




150.6




(65.9)




3.67




35.5




(2.0)






17.6/82.4




6.7




(46)




35.4




(244)




159.9




(71.1)




3.76




37.9




(1.8)






1/99




6.7




(46)




35.2




(242)




161.4




(71.9)




3.77




38.0




(1.8)






236eaEβγ/HFC-263ca






99/1




7.7




(53)




42.5




(293)




149.3




(65.2)




3.64




42.6




(0.7)






4.1/95.9




9.3




(64)




44.8




(309)




162.0




(72.2)




3.77




49.8




(0.9)






1/99




9.4




(64)




44.8




(309)




162.3




(72.4)




3.77




49.9




(0.9)






236eaEβγ/HFC-338mf






99/1




7.7




(53)




42.7




(294)




148.9




(64.9)




3.64




42.7




(0.8)






92.6/7.4




8.0




(55)




43.8




(302)




147.5




(64.2)




3.63




43.9




(0.8)






1/99




9.7




(66)




48.3




(333)




131.1




(55.1)




3.39




45.8




(0.8)






236eaEβγ/HFC-356mmz






99/1




7.7




(53)




42.5




(293)




149.0




(65.0)




3.64




42.6




(0.7)






15.1/84.9




8.6




(59)




43.2




(298)




138.3




(59.1)




3.53




43.1




(0.8)






1/99




8.4




(58)




42.0




(289)




136.9




(58.3)




3.53




42.2




(0.7)






236faE/HFC-32






55/45*




80.8




(557)




320.8




(2213)




181.3




(82.9)




3.62




352.9




(6.2)






8.5/91.5




149.2




(1029)




506.5




(3494)




196.7




(91.5)




2.96




479.3




(8.4)






1/99




149.6




(1032)




510.4




(3521)




199.8




(93.2)




3.16




518.3




(9.1)











*Subcool temp. 25° F.




















236faE/HFC-272ca















99/1




15.7




(108)




74.5




(514)




142.3




(61.3)




3.46




73.7




(1.3)






27.8/72.2




18.6




(128)




78.2




(539)




156.9




(69.4)




3.67




87.1




(1.5)






1/99




19.1




(131)




78.5




(541)




160.5




(71.4)




3.70




89.3




(1.6)






236faE/HFC-272fb






99/1




15.6




(107)




74.3




(512)




142.4




(61.3)




3.47




73.6




(1.3)






82.3/17.7




15.7




(108)




73.2




(505)




148.1




(64.5)




3.55




75.4




(1.3)






1/99




14.0




(96)




63.5




(438)




168.7




(75.9)




3.76




72.0




(1.3)






236faE/HFC-281fa






99/1




15.8




(109)




75.1




(517)




142.5




(61.4)




3.47




74.3




(1.3)






9.3/90.7




20.6




(142)




86.7




(598)




167.9




(75.5)




3.72




98.9




(1.7)






1/99




20.7




(142)




86.7




(598)




169.3




(76.3)




3.73




99.3




(1.7)














EXAMPLE 4




The following table shows the refrigerant performance of various compositions. The data are based on the following conditions.





















Evaporator temperature




 40.0° F. (4.4° C.)







Condenser temperature




100.0° F. (37.8° C.)







Compressor efficiency is




75%.







Return gas temperature




 60.0° F.



























TABLE 5











Capacity










Refrig.




Evap.




Cond.






BTU/min




Press.




Press.




Comp. Dis.
















Psia (kPa)




Psia (kPa)




Temp. ° F. (° C.)




COP




(kw)




Comp.























CFC-11




7.1




(49)




23.5




(162)




130.0




(54.4)




5.68




44.2




(0.8)






134E/HFC-32






5.0/95.0




135.9




(937)




483.2




(3331)




202.5




(94.7)




3.17




490.0




(8.6)






95.0/5.0




21.1




(145)




95.6




(659)




175.8




(79.9)




4.08




116.8




(2.1)






134E/HFC-125*






5.0/95.0




107.4




(741)




387.9




(2675)




154.0




(67.8)




2.13




244.0




(4.3)






95.0/5.0




23.7




(163)




63.5




(438)




126.4




(42.4)




7.10




146.9




(2.6)











*= Condenser temp. of 130° F., evaporator temp. of 45° F., and return gas temp. of 65° F.




















134E/HFC-134















5.0/95.0




36.3




(250)




104.9




(723)




127.1




(52.8)




5.38




184.8




(3.2)






95.0/5.0




15.2




(105)




50.5




(348)




119.5




(48.6)




5.53




90.5




(1.6)






134E/HFC-134a






5.0/95.0




46.8




(323)




132.8




(916)




118.5




(48.1)




5.20




222.8




(3.9)






95.0/5.0




15.7




(108)




51.8




(357)




119.9




(48.8)




5.57




93.5




(1.6)






134E/HFC-143






5.0/95.0




14.5




(100)




45.2




(312)




134.5




(56.9)




5.60




84.0




(1.5)






37.9/62.1




14.7




(101)




46.7




(322)




128.9




(53.8)




5.57




85.7




(1.5)






95.0/5.0




14.4




(99)




48.0




(331)




119.0




(48.3)




5.51




85.7




(1.5)






134E/HFC-143a






5.0/95.0




101.0




(696)




247.9




(1709)




149.7




(65.4)




4.84




394.9




(6.9)






95.0/5.0




23.9




(165)




69.4




(479)




133.2




(56.2)




6.54




148.0




(2.6)






134E/HFC-152a






5.0/95.0




44.5




(307)




122.9




(847)




142.8




(61.6




5.39




220.3




(3.9)






95.0/5.0




16.1




(111)




52.8




(364)




121.7




(49.8)




5.57




95.4




(1.7)






134E/HFC-161






5.0/95.0




70.2




(484)




181.9




(1254)




141.2




(60.7)




5.28




317.3




(5.6)






95.0/5.0




18.1




(125)




58.3




(402)




125.4




(51.9)




5.69




108.0




(1.9)






134E/HFC-227ca






5.0/95.0




35.1




(242)




97.7




(674)




102.2




(39.0)




4.88




149.7




(2.6)






13.6/86.4




37.4




(258)




103.4




(713)




99.6




(37.6)




4.92




160.1




(2.8)






134E/HFC-227ea






5.0/95.0




34.3




(237)




95.8




(661)




102.3




(39.1)




4.89




147.5




(2.6)






95.0/5.0




18.9




(130)




57.1




(394)




122.6




(50.3)




6.16




114.7




(2.0)






7.3/92.7*




36.0




(248)




141.7




(977)




144.5




(62.5)




3.24




135.5




(2.4)











*= Condenser = 130° F., evaporator = 45° F., and return gas = 65° F..




















134E/HFC-236ca















5.0/95.0




12.7




(87)




40.6




(280)




105.8




(41.0)




5.41




70.5




(1.2)






95.0/5.0




15.0




(103)




49.8




(343)




117.8




(47.7)




5.52




88.9




(1.6)






99/1




13.5




(93)




44.8




(309)




142.3




(61.3)




5.59




81.5




(1.4)






78.0/22.0




14.2




(98)




46.2




(318)




137.7




(58.7)




5.57




83.5




(1.5)






1/99




11.8




(81)




62.1




(428)




152.1




(66.7)




3.33




58.0




(1.0)






134E/HFC-236cb






5.0/95.0




17.7




(122)




53.5




(369)




101.2




(38.4)




5.28




90.4




(1.6)






36.3/63.7




22.3




(154)




66.2




(456)




104.1




(40.1)




5.26




111.8




(2.0)






95.0/5.0




15.8




(109)




51.6




(356)




118.0




(47.8)




5.61




93.8




(1.7)






134F/HFC-236ea






5.0/95.0




14.7




(101)




46.2




(319)




104.9




(40.5)




5.36




79.4




(1.4)






52.8/47.2




19.1




(132)




59.2




(408)




108.9




(42.7)




5.35




102.2




(1.8)






95.0/5.0




15.2




(105)




50.2




(346)




118.0




(47.8)




5.54




90.0




(1.6)






134E/HFC-236fa






5.0/95.0




19.5




(135)




58.3




(402)




100.7




(38.2)




5.25




97.7




(1.7)






95.0/5.0




16.1




(111)




52.0




(359)




119.1




(48.4)




5.65




95.3




(1.7)






14.2/85.8*




21.2




(146)




91.1




(628)




148.6




(64.8)




3.50




94.3




(1.7)











*= Condenser = 130° F., evaporator = 45° F., and return gas = 65° F..




















134E/HFC-245ca















5.0/95.0




6.9




(47)




23.9




(164)




111.7




(44.3)




5.58




42.7




(0.8)






95.0/5.0




14.4




(99)




47.9




(331)




117.2




(47.3)




5.50




85.2




(1.5)






134E/HFC-245cb






5.0/95.0




33.5




(231)




91.5




(631)




104.4




(40.2)




4.90




142.1




(2.5)






28.5/71.5




32.8




(226)




91.8




(633)




103.6




(39.8)




5.03




147.3




(2.6)






95.0/5.0




16.5




(114)




53.1




(366)




119.5




(48.6)




5.69




97.9




(1.7)






134E/HFC-245ea






5.0/95.0




6.7




(46)




23.7




(164)




115.2




(46.2)




5.59




42.5




(0.7)






95.0/5.0




14.2




(98)




47.6




(328)




117.6




(47.6)




5.49




84.5




(1.5)






134E/HFC-245fa






5.0/95.0




10.7




(74)




35.0




(241)




108.2




(42.3)




5.46




61.5




(1.1)






95.0/5.0




14.6




(101)




49.2




(339)




117.8




(47.7)




5.44




86.4




(1.5)






134E/HFC-254ca






5.0/95.0




6.5




(45)




22.5




(155)




113.5




(45.3)




5.59




40.5




(0.7)






95.0/5.0




14.1




(97)




47.4




(327)




117.6




(47.6)




5.48




84.1




(1.5)






134E/HFC-254cb






5.0/95.0




17.4




(120)




52.0




(359)




107.1




(41.7)




5.39




90.8




(1.6)






29.7/70.3




19.4




(134)




58.0




(400)




108.5




(42.5)




5.39




101.2




(1.8)






95.0/5.0




15.2




(105)




50.4




(347)




118.1




(47.8)




5.53




90.1




(1.6)






134E/HFC-254eb*






28.6/71.4




19.0




(131)




82.9




(572)




159.2




(70.7)




3.64




90.4




(1.6)











*= Condenser = 130° F., evaporator = 45° F., and return gas = 65° F..




















134E/HFC-263ca















5.0/95.0




8.8




(61)




28.6




(197)




113.5




(45.3)




5.57




51.9




(0.9)






95.0/5.0




14.4




(99)




47.8




(330)




117.4




(47.4)




5.50




85.1




(1.5)






134E/HFC-263fb






5.0/95.0




28.0




(193)




78.8




(543)




106.5




(41.4)




5.28




134.1




(2.4)






95.0/5.0




16.1




(111)




52.5




(362)




119.4




(48.6)




5.60




95.2




(1.7)






134E/HFC-272ca






5.0/95.0




17.5




(121)




51.2




(353)




111.7




(44.3)




5.44




91.0




(1.6)






95.0/5.0




15.2




(105)




50.0




(345)




118.0




(47.8)




5.51




89.3




(1.6)






134E/HFC-272ea






5.0/95.0




9.8




(67)




32.1




(221)




119.8




(48.8)




5.52




57.7




(1.0)






95.0/5.0




14.1




(97)




47.3




(326)




118.1




(47.8)




5.50




84.1




(1.5)






134E/HFC-272fb






5.0/95.0




12.7




(88)




40.1




(276)




117.5




(47.5)




5.51




72.3




(1.3)






95.0/5.0




14.4




(100)




48.2




(332)




117.9




(47.7)




5.50




85.8




(1.5)






134E/HFC-281ea






5.0/95.0




24.0




(166)




67.9




(468)




116.7




(47.1)




5.47




121.8




(2.1)






95.0/5.0




15.5




(107)




51.0




(351)




118.8




(48.2)




5.52




91.3




(1.6)






134E/HFC-281fa






5.0/95.0




18.7




(129)




55.3




(381)




117.1




(47.3)




5.50




99.8




(1.8)






95.0/5.0




15.2




(105)




49.6




(342)




118.0




(47.8)




5.57




89.7




(1.6)






134E/HFC-338mf






5.0/95.0




10.5




(72)




34.7




(239)




95.3




(35.2)




5.35




58.5




(1.0)






65.5/34.5




18.8




(130)




59.8




(412)




108.2




(42.3)




5.21




99.7




(1.8)






95.0/5.0




15.7




(108)




51.6




(356)




118.1




(47.8)




5.62




93.1




(1.6)






236caE/HFC-125






5.0/95.0




90.0




(621)




242.9




(1675)




127.5




(53.1)




4.33




330.6




(5.8)






95.0/5.0




9.0




(62)




30.8




(212)




119.3




(48.5)




6.26




61.3




(1.1)






236caE/HFC-134






5.0/95.0




35.3




(243)




103.9




(716)




129.2




(54.0)




5.28




179.7




(3.2)






95.0/5.0




6.9




(48)




25.0




(172)




110.7




(43.7)




5.68




44.9




(0.8)






236caE/HFC-134a






5.0/95.0




44.5




(307)




129.1




(890)




121.1




(49.5)




5.13




213.3




(3.7)






95.0/5.0




7.2




(50)




26.0




(179)




111.8




(44.3)




5.74




47.3




(0.8)






236caE/HFC-143






5.0/95.0




14.1




(97)




44.2




(305)




134.3




(56.8)




5.60




82.1




(1.4)






95.0/5.0




6.1




(42)




22.5




(155)




107.2




(41.8)




5.49




38.9




(0.7)






236caE/HFC-143a






5.0/95.0




90.0




(621)




232.8




(1605)




160.3




(71.3)




4.68




361.3




(6.3)






95.0/5.0




9.6




(66)




33.1




(228)




123.6




(50.9)




6.18




64.9




(1.1)






236caE/HFC-152a






5.0/95.0




43.5




(300)




121.3




(836)




143.5




(61.9)




5.34




215.6




(3.8)






95.0/5.0




7.9




(54)




28.2




(194)




115.9




(46.6)




5.82




51.9




(0.9)






236caE/HFC-161






5.0/95.0




69.0




(476)




180.6




(1245)




142.5




(61.4)




5.22




311.7




(5.5)






95.0/5.0




10.1




(70)




36.1




(249)




126.8




(52.7)




5.90




67.4




(1.2)






236caE/HFC-227ca






5.0/95.0




30.5




(210)




87.5




(603)




99.0




(37.2)




4.93




135.8




(2.4)






95.0/5.0




6.6




(46)




23.8




(164)




107.9




(42.2)




5.67




42.7




(0.8)






236caE/HFC-227ea






5.0/95.0




29.8




(205)




95.7




(591)




98.9




(37.2)




4.95




133.6




(2.3)






95.0/5.0




6.6




(46)




23.7




(163)




107.6




(42.0)




5.67




42.5




(0.7)






236caE/HFC-236ca






5.0/95.0




11.3




(78)




36.9




(254)




104.4




(40.2)




5.37




63.5




(1.1)






95.0/5.0




5.7




(39)




21.4




(147)




104.2




(40.1)




5.44




36.5




(0.6)






236caE/HFC-236cb






5.0/95.0




15.5




(107)




47.9




(330)




100.9




(38.3)




5.25




80.4




(1.4)






95.0/5.0




5.8




(40)




21.7




(149)




104.4




(40.2)




5.46




37.2




(0.7)






236caE/HFC-236fa






5.0/95.0




17.3




(119)




52.8




(364)




100.2




(37.9)




5.21




87.9




(1.5)






95.0/5.0




6.0




(41)




22.2




(153)




105.1




(40.6)




5.50




38.3




(0.7)






236caE/HFC-245cb






5.0/95.0




29.8




(205)




84.4




(582)




100.1




(37.8)




4.96




132.8




(2.3)






95.0/5.0




6.4




(44)




23.4




(161)




106.8




(41.6)




5.59




41.2




(0.7)






236caE/HFC-245ea






5.0/95.0




6.1




(42)




21.9




(151)




112.9




(44.9)




5.53




38.8




(0.7)






95.0/5.0




5.5




(38)




20.7




(143)




104.1




(40.1)




5.42




35.2




(0.6)






236caE/HFC-245fa






5.0/95.0




9.7




(67)




32.3




(223)




107.0




(41.7)




5.38




55.9




(1.0)






95.0/5.0




5.7




(39)




21.2




(146)




104.1




(40.1)




5.43




36.2




(0.6)






236caE/HFC-254ca






5.0/95.0




6.0




(41)




21.0




(145)




111.3




(44.1)




5.54




37.3




(0.7)






95.0/5.0




5.5




(38)




20.6




(142)




104.1




(40.1)




5.43




35.2




(0.6)






236caE/HFC-254cb






5.0/95.0




16.0




(111)




48.8




(336)




107.5




(41.9)




5.37




84.8




(1.5)






95.0/5.0




6.0




(41)




22.1




(152)




105.3




(40.7)




5.47




38.0




(0.7)






236caE/HFC-254eb






5.0/95.0




16.3




(113)




49.6




(342)




107.5




(41.9)




5.37




86.1




(1.5)






95.0/5.0




6.0




(41)




22.1




(153)




105.3




(40.7)




5.47




38.2




(0.7)






236caE/HFC-263ca






5.0/95.0




8.3




(57)




27.8




(187)




112.4




(44.7)




5.53




48.8




(0.9)






95.0/5.0




5.7




(39)




21.1




(145)




104.4




(40.2)




5.44




36.1




(0.6)






236caE/HFC-263fb






5.0/95.0




26.0




(179)




74.5




(514)




108.5




(42.5)




5.26




126.3




(2.2)






95.0/5.0




6.5




(45)




23.6




(163)




107.5




(41.9)




5.57




41.5




(0.7)






236caE/HFC-272ca






5.0/95.0




16.7




(115)




49.0




(338)




112.2




(44.6)




5.46




87.3




(1.5)






95.0/5.0




6.1




(42)




22.5




(155)




106.1




(41.2)




5.49




39.0




(0.7)






236caE/HFC-272ea






5.0/95.0




9.6




(66)




30.7




(211)




117.9




(47.7)




5.68




57.1




(1.0)






95.0/5.0




5.8




(40)




21.6




(149)




105.4




(40.8)




5.44




37.0




(0.7)






236caE/HFC-272fb






5.0/95.0




12.2




(84)




38.9




(268)




117.5




(47.5)




5.48




69.7




(1.2)






95.0/5.0




6.0




(41)




22.1




(152)




105.8




(41.0)




5.46




38.0




(0.7)






236caE/HFC-281ea






5.0/95.0




23.2




(160)




66.2




(456)




117.8




(47.7)




5.46




118.4




(2.1)






95.0/5.0




6.8




(47)




24.4




(169)




109.1




(42.8)




5.58




43.2




(0.8)






236caE/HFC-281fa






5.0/95.0




18.2




(125)




54.5




(376)




117.5




(47.5)




5.51




97.4




(1.7)






95.0/5.0




6.5




(45)




23.4




(163)




107.9




(42.2)




5.53




41.3




(0.7)






236eaEβγ/HFC-125






5.0/95.0




93.0




(641)




245.9




(1695)




125.0




(51.7)




4.39




338.5




(5.9)






95.0/5.0




10.4




(72)




35.5




(245)




116.6




(47.0)




6.00




67.6




(1.2)






236eaEβγ/HFC-134






5.0/95.0




36.1




(249)




104.5




(721)




127.2




(52.9)




5.35




183.1




(3.2)






95.0/5.0




8.3




(58)




29.5




(204)




108.7




(42.6)




5.60




52.3




(0.9)






236eaEβγ/HFC-134a






5.0/95.0




45.5




(314)




130.6




(900)




119.7




(48.7)




5.16




217.2




(3.8)






95.0/5.0




8.6




(59)




30.6




(211)




109.5




(43.1)




5.65




54.3




(1.0)






236eaEβγ/HFC-143






5.0/95.0




14.3




(97)




44.6




(307)




134.4




(56.9)




5.56




82.2




(1.4)






95.0/5.0




7.4




(51)




26.6




(1840)




105.5




(40.8)




5.43




45.8




(0.8)






236eaEβγ/HFC-143a






5.0/95.0




90.0




(621)




232.8




(1605)




160.3




(71.3)




4.68




361.3




(6.3)






95.0/5.0




9.6




(66)




32.8




(226)




123.3




(50.7)




6.23




65.1




(1.1)






236eaEβγ/HFC-152a






5.0/95.0




44.3




(305)




122.5




(844)




142.1




(61.2)




5.38




219.0




(3.8)






95.0/5.0




9.5




(65)




32.8




(226)




113.6




(45.3)




5.72




59.7




(1.0)






236eaEβγ/HFC-161






5.0/95.0




69.6




(480)




181.5




(1251)




141.7




(60.9)




5.23




313.9




(5.5)






95.0/5.0




11.7




(81)




39.8




(274)




121.8




(49.9)




5.91




75.0




(1.3)






236eaEβγ/HFC-227ca






5.0/95.0




30.9




(213)




88.3




(609)




102.1




(38.9)




4.88




135.9




(2.4)






95.0/5.0




7.9




(54)




27.9




(193)




105.6




(40.9)




5.57




49.2




(0.9)






236eaEβγ/HFC-227ea






5.0/95.0




30.3




(209)




86.5




(596)




102.0




(38.9)




4.90




133.7




(2.3)






95.0/5.0




7.9




(54)




27.9




(192)




105.5




(40.8)




5.50




48.9




(0.9)






236eaEβγ/HFC-236ca






5.0/95.0




11.4




(79)




37.3




(257)




104.3




(40.2)




5.32




63.6




(1.1)






95.0/5.0




7.0




(48)




25.7




(177)




103.2




(39.6)




5.32




42.9




(0.8)






236eaEβγ/HFC-236cb






5.0/95.0




15.9




(110)




48.9




(337)




100.0




(37.8)




5.24




81.8




(1.4)






95.0/5.0




7.2




(50)




26.1




(180)




103.2




(39.6)




5.42




44.7




(0.8)






236eaEβγ/HFC-236fa






5.0/95.0




17.6




(121)




53.3




(368)




104.1




(40.1)




5.16




88.1




(1.6)






95.0/5.0




7.3




(51)




26.4




(182)




103.6




(39.8)




5.42




45.3




(0.8)






236eaEβγ/HFC-245ca






5.0/95.0




6.2




(43)




21.9




(151)




109.0




(42.8)




5.50




38.6




(0.7)






95.0/5.0




6.8




(47)




24.7




(170)




102.8




(39.3)




5.39




41.9




(0.7)






236eaEβγ/HFC-245cb






5.0/95.0




30.3




(209)




85.2




(587)




99.8




(37.7)




4.96




134.3




(2.4)






95.0/5.0




7.7




(53)




27.5




(190)




104.7




(40.4)




5.50




47.9




(0.8)






236eaEβγ/HFC-245ea






5.0/95.0




6.2




(42)




22.1




(152)




112.9




(44.9)




5.53




39.0




(0.7)






95.0/5.0




6.8




(47)




24.7




(170)




103.0




(39.4)




5.39




41.9




(0.7)






236eaEβγ/HFC-245fa






5.0/95.0




9.8




(68)




32.5




(224)




106.6




(41.4)




5.41




56.5




(1.0)






95.0/5.0




6.9




(48)




25.3




(175)




103.0




(39.4)




5.36




42.8




(0.8)






236eaEβγ/HFC-254ca






5.0/95.0




6.0




(41)




21.1




(146)




111.3




(44.1)




5.53




37.5




(0.7)






95.0/5.0




6.8




(47)




24.6




(170)




103.0




(39.4)




5.39




41.9




(0.7)






236eaEβγ/HFC-254cb






5.0/95.0




16.2




(112)




49.1




(338)




107.0




(41.7)




5.38




85.6




(1.5)






95.0/5.0




8.2




(57)




26.2




(181)




103.0




(39.4)




6.04




50.9




(0.9)






236eaEβγ/HFC-254eb






5.0/95.0




16.5




(114)




49.9




(344)




106.9




(41.6)




5.38




86.8




(1.5)






95.0/5.0




7.3




(50)




26.3




(181)




103.8




(39.9)




5.42




45.0




(0.8)






236eaEβγ/HFC-263ca






5.0/95.0




8.3




(57)




27.3




(188)




112.2




(44.6)




5.54




49.1




(0.9)






95.0/5.0




6.9




(48)




25.1




(173)




103.2




(39.6)




5.39




42.7




(0.8)






236eaEβγ/HFC-263fb






5.0/95.0




26.3




(181)




75.0




(517)




107.8




(42.1)




5.27




127.6




(2.2)






95.0/5.0




7.8




(54)




27.8




(192)




105.5




(40.8)




5.49




48.2




(0.8)






236eaEβγ/HFC-272ca






5.0/95.0




16.8




(116)




49.3




(340)




111.6




(44.2)




5.47




88.2




(1.5)






95.0/5.0




7.5




(52)




26.8




(184)




104.6




(40.3)




5.43




46.0




(0.8)






236eaEβγ/HFC-272ea






5.0/95.0




9.5




(66)




31.1




(214)




118.6




(48.1)




5.57




56.6




(1.0)






95.0/5.0




7.1




(49)




25.6




(176)




103.9




(39.9)




5.41




43.8




(0.8)






236eaEβγ/HFC-272fb






5.0/95.0




12.4




(85)




39.1




(269)




117.1




(47.3)




5.51




70.4




(1.2)






95.0/5.0




7.3




(50)




26.2




(181)




104.3




(40.2)




5.41




44.8




(0.8)






236eaEβγ/HFC-281ea






5.0/95.0




23.4




(162)




66.6




(459)




117.3




(47.4)




5.46




119.2




(2.1)






95.0/5.0




8.1




(56)




28.6




(197)




107.0




(41.7)




5.50




49.9




(0.9)






236eaEβγ/HFC-281fa






5.0/95.0




18.3




(126)




54.3




(375)




117.4




(47.4)




5.49




98.0




(1.7)






95.0/5.0




7.8




(54)




27.8




(192)




106.0




(41.1)




5.46




48.0




(0.8)






236faE/HFC-125






5.0/95.0




99.6




(687)




252.9




(1743)




119.9




(48.8)




4.49




354.1




(6.2)






95.0/5.0




17.4




(120)




54.6




(377)




103.8




(39.9)




5.51




95.4




(1.7)






236faE/HFC-134






5.0/95.0




37.6




(259)




108.1




(745)




125.3




(51.8)




5.33




188.4




(3.3)






95.0/5.0




15.8




(109)




50.6




(349)




100.6




(38.1)




5.29




85.0




(1.5)






236faE/HFC-134a






5.0/95.0




48.2




(332)




135.5




(934)




116.5




(46.9)




5.19




226.2




(4.0)






95.0/5.0




16.2




(112)




51.7




(356)




101.1




(38.4)




5.33




87.4




(1.5)






236faE/HFC-143






5.0/95.0




14.5




(100)




45.5




(314)




133.6




(56.4)




5.58




84.1




(1.5)






95.0/5.0




14.5




(100)




46.6




(321)




103.5




(39.7)




5.17




76.7




(1.3)






236faE/HFC-143a






5.0/95.0




96.7




(667)




241.0




(1662)




152.6




(67.0)




4.81




382.2




(6.7)






95.0/5.0




18.3




(126)




56.9




(392)




106.6




(41.4)




5.58




101.1




(1.8)






236faE/HFC-152a






5.0/95.0




45.7




(315)




125.1




(863)




140.1




(60.1)




5.39




224.3




(3.9)






95.0/5.0




17.1




(118)




54.2




(374)




103.9




(39.9)




5.37




92.6




(1.6)






236faE/HFC-161






5.0/95.0




72.2




(498)




185.7




(1280)




138.9




(59.4)




5.27




322.7




(5.7)






95.0/5.0




20.6




(142)




63.3




(436)




110.6




(43.7)




5.65




113.9




(2.0)






236faE/HFC-227ca






5.0/95.0




31.9




(220)




90.1




(621)




101.5




(30.6)




4.87




138.3




(2.4)






95.0/5.0




14.8




(1020)




47.7




(329)




101.5




(38.6)




5.16




78.0




(1.4)






236faE/HFC-227ea






5.0/95.0




31.1




(215)




88.3




(609)




101.6




(38.7)




4.88




135.8




(2.4)






95.0/5.0




14.7




(101)




47.6




(328)




101.5




(38.6)




5.16




77.8




(1.4)






236faE/HFC-236ca






5.0/95.0




11.8




(81)




38.1




(263)




103.7




(39.8)




5.35




65.4




(1.1)






95.0/5.0




13.8




(95)




45.0




(310)




102.1




(38.9)




5.12




73.1




(1.3)






236faE/HFC-236cb






5.0/95.0




16.3




(112)




49.8




(343)




104.2




(40.1)




5.17




82.5




(1.4)






95.0/5.0




14.1




(97)




45.8




(316)




101.8




(38.8)




5.12




74.3




(1.3)






236faE/HFC-236fa






5.0/95.0




18.0




(124)




54.3




(375)




104.0




(40.0)




5.13




89.1




(1.6)






95.0/5.0




14.2




(98)




46.0




(317)




101.8




(38.8)




5.12




74.6




(1.3)






236faE/HFC-245ca






5.0/95.0




6.4




(44)




22.5




(155)




109.1




(42.8)




5.51




39.7




(0.7)






95.0/5.0




13.2




(91)




43.3




(299)




102.3




(39.1)




5.18




71.1




(1.2)






236faE/HFC-245cb






5.0/95.0




31.6




(218)




87.4




(603)




109.0




(42.8)




4.84




134.4




(2.4)






95.0/5.0




14.8




(102)




47.5




(328)




106.5




(41.4)




5.09




76.9




(1.4)






236faE/HFC-245ea






5.0/95.0




6.4




(44)




22.7




(157)




113.1




(45.1)




5.54




40.3




(0.7)






95.0/5.0




13.3




(92)




43.6




(301)




102.4




(39.1)




5.17




71.6




(1.3)






236faE/HFC-245fa






5.0/95.0




10.1




(70)




33.3




(230)




106.3




(41.3)




5.40




57.9




(1.0)






95.0/5.0




13.7




(94)




44.6




(308)




102.0




(38.9)




5.16




72.9




(1.3)






236faE/HFC-254ca






5.0/95.0




6.2




(43)




21.6




(149)




111.5




(44.2)




5.55




38.6




(0.7)






95.0/5.0




13.2




(91)




43.3




(299)




102.6




(39.2)




5.17




70.9




(1.2)






236faE/HFC-254cb






5.0/95.0




16.6




(114)




50.2




(346)




106.1




(41.2)




5.37




87.1




(1.5)






95.0/5.0




14.1




(97)




45.8




(316)




102.2




(39.0)




5.14




74.6




(1.3)






236faE/HFC-254eb






5.0/95.0




16.9




(117)




51.0




(352)




106.0




(41.1)




5.36




88.4




(1.6)






95.0/5.0




14.1




(97)




45.9




(316)




102.3




(39.1)




5.13




74.7




(1.3)






236faE/HFC-263ca






5.0/95.0




8.5




(59)




28.0




(193)




112.5




(44.7)




5.49




49.9




(0.9)






95.0/5.0




13.5




(93)




43.9




(303)




102.6




(39.2)




5.17




72.0




(1.3)






236faE/HFC-263fb






5.0/95.0




27.0




(186)




76.9




(530)




106.6




(41.4)




5.22




129.2




(2.3)






95.0/5.0




14.8




(102)




47.6




(328)




102.3




(39.1)




5.16




77.8




(1.4)






236faE/HFC-272ca






5.0/95.0




17.2




(119)




50.1




(345)




110.8




(43.8)




5.47




89.6




(1.6)






95.0/5.0




14.3




(99)




46.1




(318)




102.8




(39.3)




5.14




75.3




(1.3)






236faE/HFC-272ea






5.0/95.0




9.7




(67)




31.8




(219)




118.9




(48.3)




5.52




57.4




(1.0)






95.0/5.0




13.8




(95)




44.8




(309)




103.2




(39.6)




5.15




73.3




(1.3)






236faE/HFC-272fb






5.0/95.0




12.6




(87)




39.8




(274)




116.6




(47.0)




5.52




71.8




(1.3)






95.0/5.0




14.1




(97)




45.5




(314)




103.0




(39.4)




5.15




74.6




(1.3)






236faE/HFC-281ea






5.0/95.0




23.9




(165)




67.6




(466)




116.3




(48.0)




5.45




120.9




(2.1)






95.0/5.0




15.2




(105)




48.4




(334)




103.3




(39.6)




5.19




79.9




(1.4)






236faE/HFC-281fa






5.0/95.0




18.7




(129)




55.1




(380)




116.6




(47.0)




5.50




99.4




(1.7)






95.0/5.0




14.8




(102)




47.4




(327)




103.3




(39.6)




5.18




78.0




(1.4)






245faEβγ/HFC-125






5.0/95.0




88.9




(613)




240.9




(1661)




128.2




(53.4)




4.33




328.4




(5.8)






95.0/5.0




8.9




(61)




30.1




(208)




121.1




(49.5)




6.35




60.9




(1.1)






245faEβγ/HFC-134






5.0/95.0




34.6




(239)




101.7




(701)




129.6




(54.2)




5.32




177.2




(3.1)






95.0/5.0




6.6




(46)




23.9




(165)




111.6




(44.2)




5.68




43.0




(0.8)






245faEβγ/HFC-134a






5.0/95.0




43.4




(299)




127.2




(877)




122.3




(50.2)




5.11




209.7




(3.7)






95.0/5.0




6.9




(48)




24.8




(171)




112.7




(44.8)




5.75




45.2




(0.8)






245faEβγ/HFC-143






5.0/95.0




13.9




(96)




44.3




(305)




135.4




(57.4)




5.50




80.7




(1.4)






95.0/5.0




5.9




(41)




21.7




(150)




108.6




(42.6)




5.51




37.9




(0.7)






245faEβγ/HFC-143a






5.0/95.0




89.2




(615)




231.5




(1596)




161.1




(71.7)




4.66




359.0




(6.3)






95.0/5.0




9.4




(65)




31.9




(220)




124.7




(51.5)




6.31




64.2




(1.1)






245faEβγ/HFC-152a






5.0/95.0




42.8




(295)




120.1




(828)




144.4




(62.4)




5.33




213.0




(3.7)






95.0/5.0




7.5




(52)




26.7




(184)




116.5




(46.9)




5.81




49.2




(0.9)






245faEβγ/HFC-161






5.0/95.0




67.9




(468)




178.9




(1233)




143.5




(61.9)




5.20




307.8




(5.4)






95.0/5.0




9.6




(66)




33.1




(228)




126.0




(52.2)




6.06




64.3




(1.1)






245faEβγ/HFC-227ca






5.0/95.0




30.5




(210)




87.6




(604)




98.9




(37.2)




4.93




136.0




(2.4)






95.0/5.0




6.5




(45)




23.4




(161)




109.9




(43.3)




5.76




42.7




(0.8)






245faEβγ/HFC-227ea






5.0/95.0




29.9




(206)




85.8




(592)




98.8




(37.1)




4.95




133.9




(2.4)






95.0/5.0




6.5




(45)




23.3




(161)




109.8




(43.2)




5.74




42.5




(0.7)






245faEβγ/HFC-236ca






5.0/95.0




11.2




(77)




37.1




(256)




104.8




(40.4)




5.29




62.9




(1.1)






95.0/5.0




5.6




(39)




20.9




(144)




106.0




(41.1)




5.47




36.1




(0.6)






245faEβγ/HFC-236cb






5.0/95.0




15.7




(108)




48.4




(334)




100.2




(37.9)




5.25




81.3




(1.4)






95.0/5.0




5.8




(40)




21.5




(148)




106.7




(41.5)




5.52




37.4




(0.7)






245faEβγ/HFC-236fa






5.0/95.0




17.3




(119)




52.6




(363)




100.3




(37.9)




5.22




87.7




(1.5)






95.0/5.0




5.8




(40)




21.6




(149)




106.9




(41.6)




5.52




37.6




(0.7)






245faEβγ/HFC-245ca






5.0/95.0




6.2




(43)




21.8




(150)




109.0




(42.8)




5.51




38.4




(0.7)






95.0/5.0




5.4




(37)




20.2




(139)




105.7




(40.9)




5.45




34.7




(0.6)






245faEβγ/HFC-245cb






5.0/95.0




29.7




(205)




84.0




(579)




100.1




(37.8)




4.97




132.6




(2.3)






95.0/5.0




6.3




(43)




22.8




(157)




108.5




(42.5)




5.64




40.7




(0.7)






245faEβγ/HFC-245ea






5.0/95.0




6.1




(42)




21.9




(151)




112.9




(44.9)




5.53




38.8




(0.7)






95.0/5.0




5.4




(37)




20.2




(139)




105.8




(41.0)




5.45




34.7




(0.6)






245faEβγ/HFC-245fa






5.0/95.0




9.7




(67)




32.3




(223)




107.0




(41.7)




5.38




55.9




(1.0)






95.0/5.0




5.5




(38)




20.9




(144)




106.4




(41.3)




5.37




35.2




(0.6)






245faEβγ/HFC-254ca






5.0/95.0




6.0




(41)




21.0




(1450)




111.3




(44.1)




5.54




37.3




(0.7)






95.0/5.0




5.4




(37)




20.2




(139)




105.7




(40.9)




5.46




34.7




(0.6)






245faEβγ/HFC-254cb






5.0/95.0




16.0




(110)




48.7




(336)




107.6




(42.0)




5.37




84.6




(1.5)






95.0/5.0




5.8




(40)




21.5




(148)




107.0




(41.7)




5.51




37.5




(0.7)






245faEβγ/HFC-254eb






5.0/95.0




16.3




(112)




49.4




(341)




107.4




(41.9)




5.38




86.0




(1.5)






95.0/5.0




5.8




(40)




21.6




(149)




107.1




(41.7)




5.51




37.6




(0.7)






245faEβγ/HFC-263ca






5.0/95.0




8.3




(57)




27.2




(188)




112.5




(44.7)




5.50




48.7




(0.9)






95.0/5.0




5.5




(38)




20.7




(143)




106.4




(41.3)




5.41




35.2




(0.6)






245faEβγ/HFC-263fb






5.0/95.0




25.9




(179)




74.2




(512)




108.7




(42.6)




5.26




126.0




(2.2)






95.0/5.0




6.3




(43)




22.9




(158)




109.1




(42.8)




5.62




40.8




(0.7)






245faEβγ/HFC-272ca






5.0/95.0




16.4




(113)




49.4




(341)




113.0




(45.0)




5.31




85.7




(1.5)






95.0/5.0




6.0




(41)




22.0




(152)




107.9




(42.2)




5.53




38.5




(0.7)






245faEβγ/HFC-272ea






5.0/95.0




9.4




(65)




30.9




(213)




118.9




(48.3)




5.55




56.0




(1.0)






95.0/5.0




5.6




(39)




21.2




(146)




107.5




(41.9)




5.40




35.7




(0.6)






245faEβγ/HFC-272fb






5.0/95.0




12.2




(84)




38.9




(268)




117.8




(47.7)




5.46




69.4




(1.2)






95.0/5.0




5.8




(40)




21.5




(148)




107.3




(41.8)




5.50




37.2




(0.7)






245faEβγ/HFC-281ea






5.0/95.0




23.1




(159)




65.9




(454)




118.1




(47.8)




5.45




117.8




(2.1)






95.0/5.0




6.5




(45)




23.6




(163)




110.5




(43.6)




5.60




42.0




(0.7)






245faEβγ/HFC-281fa






5.0/95.0




18.1




(125)




53.9




(372)




117.9




(47.7)




5.48




97.0




(1.7)






95.0/5.0




6.3




(43)




22.9




(158)




109.3




(42.9)




5.55




40.2




(0.7)














EXAMPLE 5




The following table shows the refrigerant performance of various compositions. The data are based on the following conditions.





















Evaporator temperature




10.0° F. (−12.2° C.)







Condenser temperature




90.0° F. (32.2° C.)







Return gas temperature




30.0° F. (−1.1° C.)







Compressor efficiency is




75%.



























TABLE 6











Capacity










Refrig.




Evap.




Cond.






BTU/min




Press.




Press.




Comp. Dis.
















Psia (kPa)




Psia (kPa)




Temp. ° F. (° C.)




COP




(kw)




Comp.























HCFC-22




47.9




(330)




183.6




(1266)




179.1




(81.7)




3.62




217.7




(3.8)






116E/HFC-32






88/12




85.4




(589)




312.7




(2157)




127.7




(53.2)




3.01




283.6




(5.0)






75.2/24.8




79.4




(547)




296.6




(2046)




135.7




(57.6)




3.24




294.9




(5.2)






50/50




76.2




(525)




289.2




(1995)




149.0




(65.0)




3.39




308.3




(5.4)






116E/HFC-41*






84/16




39.6




(273)




206.2




(1422)




127.4




(53.0)




3.05




182.9




(3.2)






58.6/41.4




52.8




(364)




219.6




(1515)




149.6




(65.3)




3.32




237.7




(4.2)






30/70




68.9




(475)




274.0




(1890)




179.7




(82.1)




3.15




294.4




(5.2)











*Condenser temp. 50.0° F., Evaporator temp. −30.0° F., and Return gas temp. −10.0° F.




















116E/HFC-125















99/1*




82.2




(567)




304.0




(2097)




101.4




(38.6)




2.87




254.9




(4.5)






86.0/14.0




96.5




(665)




338.9




(2338)




121.4




(49.7)




2.73




273.5




(4.8)






1/99




64.8




(447)




237.2




(750)




132.5




(55.8)




3.28




240.1




(4.2)






5.0/95.0




66.5




(458)




242.1




(1669)




131.7




(55.4)




3.27




243.8




(4.3)






95.0/5.0




98.5




(679)




319.1




(2200)




113.8




(45.4)




2.21




211.7




(3.7)











*Condenser temp. 80.0° F., Evaporator temp. 0.0° F., and Return gas temp. 10.0° F.




















116E/HFC-134















90.2/9.8




103.9




(716)




319.9




(2206)




112.1




(44.5)




3.24




314.2




(5.5)






116E/HFC-134a






99/1*




82.8




(571)




306.1




(2112)




110.2




(43.4)




2.75




247.3




(4.4)






90.0/10.0




103.0




(710)




332.4




(2293)




115.0




(46.1)




3.00




299.7




(5.3)






53/47




63.1




(435)




265.2




(1829)




121.2




(49.6)




2.78




215.4




(3.8)






5.0/95.0




34.9




(241)




138.2




(953)




129.7




(54.3)




4.04




172.6




(3.0)






95.0/5.0




101.9




(702)




356.2




(2456)




120.7




(49.3)




2.62




274.5




(4.8)











*Condenser temp. 80° F., Evaporator temp. 0.0° F., and Return gas temp. 20.0° F.




















116E/HFC-143















99/1




98.2




(677)




345.7




(2385)




120.2




(49.0)




2.66




270.3




(4.8)






94.9/5.1




43.3




(298)




241.2




(1664)




139.7




(59.8)




2.38




155.0




(2.7)






60/40




27.3




(188)




112.9




(779)




131.0




(55.0)




4.28




169.5




(3.0)






116E/HFC-143a






99/1*




82.2




(567)




304.1




(2098)




110.5




(43.6)




2.76




247.5




(4.4)






94.8/5.2*




81.8




(564)




301.6




(2081)




112.8




(44.9)




2.81




250.8




(4.4)






40/60




75.9




(523)




270.0




(1863)




155.6




(68.7)




3.29




283.4




(5.0)






5.0/95.0




62.4




(430)




226.2




(1559)




182.0




(83.3)




3.42




255.2




(4.5)






95.0/5.0




98.7




(681)




318.9




(2199)




115.6




(46.4)




2.32




223.7




(3.9)











*Condenser temp. 80.0° F., Evaporator temp. 0.0° F., and Return gas temp. 20.0° F.




















116E/HFC-152a















99/1




100.2




(691)




315.8




(2179)




111.6




(44.2)




3.19




303.7




(5.3)






92.1/7.9




102.9




(710)




320.1




(2208)




114.7




(45.9)




3.23




314.4




(5.5)






60/40




60.0




(414)




250.1




(1725)




148.5




(64.7)




3.39




256.5




(4.5)






5.0/95.0




32.4




(224)




123.9




(854)




161.5




(71.9)




4.16




167.0




(2.9)






95.0/5.0




102.6




(707)




335.9




(2316)




117.4




(47.4)




2.76




278.2




(4.9)






116E/HFC-161*






99/1




57.4




(396)




243.5




(1680)




102.4




(39.1)




2.92




206.7




(3.6)






87.3/12.7




32.4




(223)




149.6




(1032)




91.5




(33.1)




3.79




166.8




(2.9)






60/40




22.1




(152)




126.1




(870)




151.7




(66.5)




3.33




119.3




(2.1)











*Condenser temp. 70.0° F., Evaporator temp. −10.0° F., and Return gas temp. 10.0° F.




















116E/HFC-227ca















5.0/95.0




20.9




(143)




89.9




(620)




108.0




(42.2)




3.69




97.7




(3.5)






95.0/5.0




92.3




(636)




331.4




(2285)




119.9




(48.8)




2.67




259.8




(4.6)






116E/HFC-227ea






5.0/95.0




16.7




(115)




78.3




(540)




104.4




(40.2)




3.67




82.2




(1.4)






95.0/5.0




92.3




(636)




333.0




(2296)




119.9




(48.8)




2.66




259.2




(4.6)






116E/HFC-236ca






5.0/95.0*




16.2




(112)




72.9




(503)




149.7




(65.4)




3.93




84.2




(1.5)






95.0/5.0




70.9




(489)




301.7




(2080)




127.3




(52.9)




2.71




233.8




(4.1)











*= Condenser temp. of 130° F., evaporator temp. of 45° F., and return gas temp. of




















65° F.















116E/HFC-236cb






5.0/95.0




11.5




(79)




53.1




(366)




110.8




(43.8)




3.97




62.0




(1.1)






95.0/5.0




86.0




(593)




321.4




(2216)




121.4




(49.7)




2.66




249.2




(4.4)






116E/HFC-236ea






5.0/95.0




10.4




(72)




48.7




(335)




114.0




(45.6)




4.20




60.1




(1.1)






95.0/5.0




85.4




(589)




321.7




(2218)




122.1




(50.1)




2.64




247.8




(4.4)






116E/HFC-236fa






5.0/95.0




12.5




(86)




57.1




(394)




110.5




(43.6)




3.92




65.8




(1.2)






95.0/5.0




87.2




(601)




322.8




(2226)




121.0




(49.4)




2.67




251.6




(4.4)






116E/HFC-245ca*






5.0/95.0




9.9




(68)




47.0




(324)




153.9




(67.7)




4.30




59.1




(1.0)






95.0/5.0




54.0




(372)




279.2




(1925)




136.3




(57.9)




2.58




195.5




(3.4)











*= Condenser temp. of 130° F., evaporator temp. of 45° F., and return gas temp. of






65° F.




















116E/HFC-245cb















5.0/95.0




21.3




(146)




88.3




(609)




104.3




(40.2)




3.63




96.0




(1.7)






95.0/5.0




93.2




(642)




331.4




(2285)




119.1




(48.4)




2.69




262.0




(4.6)






116E/HFC-245ea






5.0/95.0*




9.9




(68)




47.8




(330)




157.9




(69.9)




4.35




60.8




(1.1)






95.0/5.0




37.3




(257)




318.6




(2196)




165.8




(74.3)




1.61




112.2




(2.0)











*= Condenser temp. of 130° F., evaporator temp. of 45° F., and return gas temp. of






65° F.




















116E/HFC-245fa















5.0/95.0*




14.1




(97)




64.1




(442)




152.5




(66.9)




4.03




76.2




(1.3)






95.0/5.0




65.4




(451)




292.5




(2017)




129.6




(54.2)




2.70




223.6




(3.9)











*= Condenser temp. of 130° F., evaporator temp. of 45° F., and return gas temp. of






65° F.




















116E/HFC-254ca















5.0/95.0*




9.4




(65)




44.7




(308)




156.9




(69.4)




4.32




56.8




(1.0)






95.0/5.0




50.1




(345)




273.7




(1887)




139.2




(59.6)




2.54




185.1




(3.3)











*= Condenser temp. of 130° F., evaporator temp. of 45° F., and return gas temp. of






65° F.




















116E/HFC-254cb















5.0/95.0




12.1




(83)




53.7




(370)




118.9




(48.3)




4.14




67.0




(1.2)






95.0/5.0




86.1




(594)




318.7




(2197)




121.2




(49.6)




2.68




250.5




(4.4)






116E/HFC-263ca






5.0/95.0




9.4




(65)




44.8




(309)




114.8




(46.0)




4.28




56.0




(1.0)






95.0/5.0




83.1




(573)




317.9




(2192)




122.6




(50.3)




2.62




242.9




(4.3)






116E/HFC-263fb






5.0/95.0




18.1




(125)




76.3




(526)




120.3




(49.1)




3.89




90.4




(1.6)






95.0/5.0




91.0




(628)




326.1




(2248)




120.0




(48.9




2.71




260.4




(4.6)






116E/HFC-272ca






5.0/95.0*




21.2




(146)




85.6




(590)




159.4




(70.8)




3.85




101.7




(1.8)






95.0/5.0




68.7




(474)




284.5




(1962)




125.8




(52.1)




2.89




237.4




(4.2)











*= Condenser temp. of 130° F., evaporator temp. of 45° F., and return gas temp. of






65° F.




















116E/HFC-272ea















5.0/95.0*




13.0




(90)




58.3




(402)




167.4




(75.2)




4.11




72.6




(1.3)






95.0/5.0




54.7




(377)




222.1




(1531)




120.4




(49.1)




3.46




228.0




(4.0)











*= Condenser temp. of 130° F., evaporator temp. of 45° F., and return gas temp. of






65° F.




















116E/HFC-272fb















5.0/95.0*




16.2




(112)




70.8




(488)




166.3




(74.6)




3.99




85.8




(1.5)






95.0/5.0+




49.8




(343)




236.8




(1633)




120.5




(49.2)




2.90




193.4




(3.4)











*= Condenser temp. of 130° F., evaporator temp. of 45° F., and return gas temp. of






65° F.






+= Return gas temp. 20° F.




















116E/HFC-281ea















5.0/95.0




16.7




(115)




68.0




(469)




132.1




(55.6)




4.17




88.8




(1.6)






95.0/5.0




89.7




(618)




287.7




(1983)




103.1




(39.5)




3.08




266.6




(4.7)






116E/HFC-281fa






5.0/95.0




14.0




(96)




57.7




(398)




129.9




(54.4)




4.39




78.9




(1.4)






95.0/5.0




85.8




(591)




273.8




(1887)




110.5




(43.6)




2.99




249.5




(4.4)














EXAMPLE 6




Refrigerant Performance




The following table shows the refrigerant performance of various compositions. Except where indicated, the data are based on the following conditions.





















Evaporator temperature




 40.0° F. (4.4° C.)







Condenser temperature




100.0° F. (37.8° C.)







Subcool temperature




 0° F. (−17.8° C.)







Return gas temperature




 40.0° F. (12.8° C.)







Compressor efficiency is




75%.



























TABLE 7











Capacity










Refrig.




Evap.




Cond.






BTU/min




Press.




Press.




Comp. Dis.
















Psia (kPa)




Psia (kPa)




Temp. ° F. (° C.)




COP




(kw)




Comp.























236eaEβγ/HFC-245ca















69.1/30.9




6.8




(47)




25.2




(174)




101.5




(38.6)




5.32




42.1




(0.7)






236caE/HFC-245ca






16.1/83.9




6.1




(42)




23.3




(161)




108.3




(42.3)




5.41




39.6




(0.7)






236eaEβγ/HFC-356mff*






96.9/3.1




6.8




(47)




25.2




(174)




113.4




(45.2)




5.11




40.4




(0.7)











*return gas temp. = 55.0° F. (12.8° C.)




















245faEβγ/HFC-356mff*















4.4/95.6




6.5




(45)




23.2




(160)




108.5




(42.5)




5.04




36.8




(0.6)











*return gas temp. = 55.0° F. (12.8° C.)














The following compounds have the indicated HGWPs (all HGWP values are relative to CFC-11=1.0). The HGWPs were estimated relative to the HGWP of CFC-11 as follows:






HGWP=(IR abs (


A


)/IR abs. (CFC-11))×(


t


(


A


)/


t


(CFC-11))×(mass (CFC-11)/mass (


A


))






where




A is the gas being analyzed;




IR abs. is the total infrared absorption cross section in the region of interest, that is, where H


2


O and CO


2


do not absorb;




t=atmospheric lifetime; and




mass=atomic mass.



















COMPOUND




HGWP



























HFC-125




0.84







HFC-134




≈0.28







HFC-134a




0.28







HFC-143a




1.1







FC-218




>10







134E




≈0.1







143aE




≈0.2















A composition of a fluoroether and an HFC are prepared, and have the indicated HGWPs.



















COMPOSITION








(wt. %/wt/%)




HGWP



























134E/HFC-125




0.25







(80.0/20.0)







134E/HFC-125




0.5







(46.0/54.0)







134E/HFC-134




0.14







(80.0/20.0)







134E/HFC-134a




0.14







(80.0/20.0)







134E/HFC-143a




0.3







(80.0/20.0)







143aE/HFC-125




0.33







(80.0/20.0)







143aE/HFC-143a




0.38







(80.0/20.0)







143aE/HFC-125




0.5







(53.0/47.0)







143aE/HFC-134




0.22







(80.0/20.0)







143aE/HFC-134a




0.22







(80.0/20.0)















The novel compositions of this invention, including the azeotropic or azeotrope-like compositions, may be used to produce refrigeration by condensing the compositions and thereafter evaporating the condensate in the vicinity of a body to be cooled. The novel compositions may also be used to produce heat by condensing the refrigerant in the vicinity of the body to be heated and thereafter evaporating the refrigerant.




In addition to refrigeration applications, the novel constant boiling or substantially constant boiling compositions of the invention are also useful as aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes and power cycle working fluids.




Additives such as lubricants, corrosion inhibitors, stabilizers, dyes and other appropriate materials may be added to the novel compositions of the invention for a variety of purposes provided they do not have an adverse influence on the composition for its intended application. Preferred lubricants include esters having a molecular weight of greater than 250.



Claims
  • 1. An azeotropic or azeotrope-like composition consisting essentially of effective amounts of HFC-32 (CH2F2) and HFE-236faE (CF3OCH2CF3) to form an azeotropic or azeotrope-like composition, wherein after 50 weight percent of said composition has evaporated, the difference in vapor pressure between the original composition and the remaining composition is less than 10 percent.
  • 2. An azeotropic or azeotrope-like composition consisting essentially of HFC-32 (CH2F2) and HFE-236faE (CF3OCH2CF3), wherein said HFC-32 and HFE-236faE composition has a vapor pressure of from about 237.3 to about 248.6 psia at 25° C.; and wherein after 50 weight percent of said composition has evaporated, the difference in vapor pressure between the original composition and the remaining composition is less than 10 percent.
  • 3. An azeotropic or azeotrope-like composition consisting essentially of from about 45.0 to about 99.0 weight percent weight percent HFC-32 (CH2F2) and from about 1.0 to about 55.0 weight percent HFE-236faE (CF3OCH2CF3) having a vapor pressure of from about 237.3 to about 248.6 psia at 25° C., and wherein after 50 weight percent of said composition has evaporated, the difference in vapor pressure between the original composition and the remaining composition is less than 10 percent.
  • 4. A process of heating comprising the step of condensing a composition of claim 1, 2 or 3 in the vicinity of an object to be heated.
  • 5. A process of refrigeration comprising the step of evaporating a composition of claim 1, 2 or 3 in the vicinity of an object to be cooled.
Parent Case Info

This application is a divisional of U.S. patent application Ser. No. 10/455,040, filed Jun. 5, 2003 which is a divisional of U.S. patent application Ser. No. 10/126,033 now U.S. Pat. No. 6,632,376 filed 19 Apr. 2002 and granted 14 Oct. 2003, which is a divisional of U.S. patent application Ser. No. 09/533,557 now U.S. Pat. No. 6,416,683 filed 16 Apr. 1998 and granted 9 Jul. 2002, which is a divisional of application Ser. No. 08/871,312 now U.S. Pat. No. 5,779,931 filed 9 Jun. 1997 and granted 14 Jul. 1998, which is a divisional of Ser. No. 08/476,821 now U.S. Pat. No. 5,648,016 filed 7 Jun. 1995 and granted Jul. 15, 1997, which is a divisional of application Ser. No. 08/026,714 now U.S. Pat. No. 5,605,882 filed on Mar. 5, 1993 and granted 25 Feb. 1997, which is a continuation-in-part of application Ser. No. 07/954,999 filed 1 Oct. 1992 now abandoned, which is a continuation-in-part of application Ser. No. 07/890,508 filed 28 May 1992 now abandoned.

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Continuation in Parts (2)
Number Date Country
Parent 07/954999 Oct 1992 US
Child 08/026714 US
Parent 07/890508 May 1992 US
Child 07/954999 US