Patent Application
20240174418
The disclosure relates to sealing members for sealing the mouth of a container, and more particularly, to sealing members that are compostable.
It is often desirable to seal the opening of a container using a removable or peelable seal, sealing member, or inner seal. Often a cap or other closure is then screwed or placed over the container opening capturing the sealing member therein. In use, a consumer typically removes the cap or other closure to gain access to the sealing member and then removes or otherwise peels the seal from the container in order to dispense or gain access to its contents.
Initial attempts at sealing a container opening utilized an induction- or conduction-type inner seal covering the container's opening where the seal generally conformed to the shape of the opening such that a circular container opening was sealed with a round disk approximately the same size as the opening. These prior seals commonly had a lower heat activated sealing layer to secure a periphery of the seal to a rim or other upper surface surrounding the container's opening. Upon exposing the seal to heat, the lower layer bonded to the container's rim. In many cases, these seals included a foil layer capable of forming induction heat to activate the lower heat seal layer. These prior seals tended to provide good sealing, but were often difficult for a consumer to remove because there was nothing for the consumer to grab onto in order to remove the seal. Often, the consumer needed to pick at the seal's edge with a fingernail because there was little or no seal material to grasp.
Other types of seals for containers include a side tab or other flange that extended outwardly from a peripheral edge of the seal. These side tabs are generally not secured to the container rim and provide a grasping surface for a consumer to hold and peel off the seal.
Yet other types of seals include a sealing member having a tab defined on the top of the seal. One approach of these prior seals includes a partial layer of coated pressure sensitive adhesive to secure the tab to a layer of metal foil. The tab was formed by a full layer extending across the entire surface of the sealing member, but the full layer was only bonded to half of the seal to form the tab. This type of top-tabbed seal offered the advantage of a larger tab, which provided more grasping area for the consumer to hold and peel off the seal, but required a full additional layer of material in order to form the tab. In other approaches, the seal may include a tab formed from the additional full layer of film combined with an additional full layer of adhesive utilizing a part paper or part polymer layer, called a tab stock, to form the tab. This part layer is inserted between the additional full layer of adhesive and lower seal portions to prevent the tab from sticking to the layers below, which formed the tab.
However, oftentimes such sealing members are induction sealed to the container, thereby requiring an induction heating layer, such as a metal foil. Such metal foils complicate recycling or composting efforts as the metal foil would need to be separated from the sealing member. Further, in some instances, a portion of the metal foil may remain on the container, thereby complicating recycling the container itself.
Further, many conventional sealing members typically included one or more plastic material film layers. For example, polypropylene, polyethylene, and the like are included in one or more layers of the upper and/or lower laminates. However, when these and other similar plastic materials are included in the sealing members, the resulting laminate is no longer compostable or as readily compostable as may be desired. Therefore, it may be desirable to provide tabbed sealing members that are more suited for composting, such as providing sealing members that do not include metal foils and/or plastic layers.
Various forms of compostable sealing members are described along with the laminates from which the sealing members are formed. In some forms, the compostable sealing members may generally be formed from materials that may be easily composted and otherwise are substantially free from layers and materials that are not compostable. In one form, the sealing members do not include any metal foils, such as would traditionally be included in induction heated seals. Instead, the seals may be applied in other manners, such as using ultrasonic sealing, high frequency sealing, conduction heating, pressure sensitive adhesives, and the like. Further, in some forms, the sealing members are substantially free of plastic films and materials.
According to one form, a sealing member for sealing to a rim surrounding a container opening is provided. The sealing member includes a multi-layer laminate including an upper laminate portion bonded to a lower laminate portion. The lower laminate portion is positioned below the upper laminate portion and includes at least one film layer and a sealant layer for bonding to the container rim. The upper laminate portion includes a support layer. Further, the compostable sealing member is substantially free of a plastic materials.
In accordance with one form, a laminate for forming a compostable sealing member is provided. The laminate includes an upper laminate portion bonded to a lower laminate portion. The upper laminate portion includes a support layer. The lower laminate portion includes at least one film layer and a sealant layer for bonding to the container rim. The upper laminate portion is bonded to a lower laminate portion. The laminate is substantially free of plastic materials.
In one form, a method for sealing a container is provided. The method includes the steps of: providing a compostable sealing member, applying the compostable sealing member to a rim of the container, and providing heat to at least one of the compostable sealing member and the container to adhere the sealant layer to the container rim. The compostable sealing member includes a multi-layer laminate including an upper laminate portion bonded to a lower laminate portion. The lower laminate portion includes at least one film layer and a sealant layer. The upper laminate portion includes a support layer. The compostable sealing member is substantially free of a plastic materials.
In accordance with one form, the sealing member contains less than 5 wt. % plastic materials. In some forms, the sealing member contains less than 3 wt. %, and in some forms, less than 1 wt. % plastic.
According to one form, the sealing member contains less than 5 wt. % non-compostable materials. Additionally, or alternatively, the sealing member contains less than 3 wt. %, less than 2 wt. %, or less than 1 wt. % non-compostable materials.
In one form, the sealing member contains less than 2 wt. % of a single non-compostable material. In some forms, the sealing member contains less than 1 wt. % of a single non-compostable material.
In accordance with one form, the sealing member is free of metal foil.
According to one form, the at least one film layer comprises at least one of cellulose film, a compostable adhesive, and combinations thereof.
In one form, the compostable sealing member further comprises a compostable adhesive. In some forms, the compostable adhesive comprises at least one of compostable polyurethane materials and combinations thereof. Exemplary forms include, but are not limited to, MS 255 Eco+CS-95 by Morchem. It should be appreciated that non-compostable adhesives can be used so long as the overall composition of the sealing member does not exceed the non-compostable thresholds.
In accordance with one form, the lower laminate portion further includes a sacrificial layer between the at least one film layer and the sealant layer.
According to one form, at least one of the sealant layer and the sacrificial layer is primarily positioned over the rim area when installed on the container.
In one form, the upper laminate portion is partially bonded to the lower laminate portion to form a gripping tab for removing the sealing member from the container opening.
In accordance with one form, the gripping tab is defined wholly within a perimeter of the sealing member without extending substantially beyond the rim of the container.
According to one form, the gripping tab extends external to the rim when installed on the container.
In one form, the sealant layer is a pressure sensitive adhesive.
In accordance with one form, the upper laminate portion includes a print layer.
These and other aspects may be understood more readily from the following description and the appended drawings.
For the purpose of facilitating an understanding of the subject matter sought to be protected, there are illustrated in the accompanying drawings embodiments thereof, from an inspection of which, when considered in connection with the following description, the subject matter sought to be protected, its construction and operation, and many of its advantages should be readily understood and appreciated.
A sealing member for a container is described herein containing an upper laminate portion bonded to a lower laminate portion capable of being sealed to a container's mouth or opening. Generally, the sealing member is compostable. In this regard, the sealing member includes less than 5 wt. %, non-compostable materials. In some forms, less than 2 wt. %, and in other forms, less than 1 wt. % non-compostable materials. In some forms, the sealing member is free of metal foil layers. However, it should be appreciated that the sealing member may include one or metallized layers for barrier properties, but the metallized portion is relatively minor compared to the layer and the remainder of the sealing member. It should also be appreciated that the sealing member may include non-compostable components, such as non-compostable adhesives, metallized layers, metallized coatings, plastic coatings, and the like so long as the overall composition does not exceed the non-compostable thresholds.
In some forms, the sealing member is substantially free of non-compostable plastic materials. In some forms, the sealing member includes less than 5 wt. %, non-compostable plastic materials. In some forms, the sealing member contains less than 2 wt. %, and in other forms, less than 1 wt. % non-compostable plastic materials.
In some forms, the sealing member may also be free from metal foil, such as aluminum foil, that would typically be used to induction seal to a container. Instead, many of the forms described herein may use alternative sealing technology, such as conduction heating, ultrasonic sealing, high frequency sealing, pressure sensitive adhesives, and the like.
For simplicity, this disclosure generally may refer to a container or bottle, but the sealing members herein may be applied to any type of container, bottle, package or other apparatus having a rim or mouth surrounding an access opening to an internal cavity. In this disclosure, reference to upper and lower surfaces and layers of the components of the sealing member refers to an orientation of the components as generally depicted in figures and when the sealing member is in use with a container in an upright position and having an opening at the top of the container. Different approaches to the sealing member will first be generally described, and then more specifics of the various constructions and materials will be explained thereafter. It will be appreciated that the sealing members described herein, in some cases, function in both a one-piece or two-piece sealing member configuration. A one-piece sealing member generally includes just the sealing member bonded to a container rim. A cap or closure may be also used therewith. A two-piece sealing member includes the sealing member temporarily bonded to a liner. In this construction, the sealing member is bonded to a container's rim, and the liner is configured to separate from the sealing member during heating to be retained in a cap or other closure used on the container. Alternatively, the bond between the liner and the sealing member may be frangible such that it separates when the lid is removed from the container by a user. In a two-piece construction, a wax layer, for example, may be used to temporarily bond the sealing member to a liner. Other types of releasable layers may also be used to provide a temporary bond between the seal and liner.
Further, the sealing members described herein may have no tab, may have a top tab, and/or may have an externally extending tab. In the forms where no tab is provided, the sealing member does not have a graspable tab at the top of the sealing member and otherwise does not have large, outwardly extending tab from the rim of the container when installed. Instead, at most, the non-tabbed versions may have a very small amount of material that slightly extends over the edge of the rim of the container and may be engaged by a user's fingernail. In some forms, the non-tabbed versions have no material extending beyond the rim of the container. In top tab versions, the top tab is formed by at least a portion of the upper laminate such that the top tab may be grasped by the user above the sealing member. In some forms, the top tab versions have tabs that do not extend substantially beyond the rim of the container when installed. Examples of such top tab structures and positioning may be found in U.S. Pat. No. 9,028,963, such as shown in
The tabbed compostable sealing members described herein, in some forms, may be prepared such that they do not require a specific tab layer, such as a PET layer, as used in many traditional tabbed seals. This can help keep the sealing members compostable by eliminating PET layers that traditionally are included in the tabs.
Similarly, in some forms, PET layers can be eliminated from the upper laminate portion, as desired. Instead, PET layers in the upper laminate portion can be replaced with other materials, such compostable materials, as described below. This can help improve the compostability of the tabbed sealing member.
As discussed above, tabbed seals can suffer from problems associated with the use of metal foils and/or plastic materials in the tabbed sealing member. This can result in a combination of metal and polymer in the removed sealing member as well as remnant metal and polymer on the container once the sealing member is removed. These combinations of materials can lead to difficulties for recycling.
One form of a compostable sealing member is shown in
As shown in
Details regarding various configurations of compostable sealing members will now be discuss in more detail. More specifically,
The upper laminate portion 24 includes a support layer 32. The upper laminate portion 24 is shown in
As shown in
Yet another form is shown in
Turning now to
The lower laminate portion 422 also includes film layer 428, which in one form, is a 45 micron metallized cellulose layer. The lower laminate may also include an additional layer 429. In one form, additional layer 429 is a 45 micron cellulose film layer that is transparent. Film layer 428 is adhered to the additional layer 429 via a compostable adhesive 430.
Upper laminate portion 424 includes a support layer 432 as well as ink layer 434. The support layer 432 may be a 45 micron transparent cellulose film. Compostable adhesive 436 is partially applied to permit the free portion forming the tab 427.
In use, the lid may be removed whereby upper resealable portion 610 remains in the lid, exposing the lower sealing portion 620. The lower sealing portion 620 may then be removed from the container. When the lid is then replaced on the container, the upper resealable portion 610 may generally reseal the container. As shown in
Further specific details regarding the layers of the sealing members will be described in more detail, along with exemplary configurations. Many of the embodiments described herein are generally substantially free of non-compostable plastic materials such that they are readily compostable. By generally free of non-compostable plastic materials, it is meant less than 5 wt. % non-compostable plastic materials. Further, in some forms, nearly all of the layers in the sealing members are completely free of non-compostable plastic materials. In some instances, certain layers, such as the sealant layer, may include some plastic materials. However, the thickness of the sealant layer, as well as the amount of sealant layer that is provided in or otherwise remains in the sealing member after removal is very low relative to the overall combination of materials such that the sealing member is still compostable.
Further, in some forms, such as described below, one or more of the layers may include a metallized coating to provide membrane properties, such as a moisture barrier, air barrier, and the like. However, the metallized coating is a relatively low amount compared to the remainder of the sealing member such that the sealing member is still compostable. In this regard, the sealing members herein are free from metal foil layers. In some forms, the sealing members include no metallic materials and in other forms, the sealing members may include a metallized coating. In either of these forms, the sealing member would still be free from having a metal foil, as would typically be used in induction heated sealing members, and the sealing members are still compostable.
In some forms, the total percentage of non-compostable materials in the sealing member is less than 5 wt. % based on the total weight. In some forms, the total percentage of non-compostable materials in the sealing member is less than 3 wt. % based on the total weight. In some forms, the percentage of a single non-compostable material in the sealing member is less than 1 wt. %. In some forms, the percentage of a single non-compostable material in the sealing member is less than 0.5 wt. %.
The sealant layers used in the sealing members may include a variety of different materials. Typically the sealant layers can be selected for compatibility with the type of containers they are being used with. Many containers include polyethylene, polypropylene, polyethylene terephthalate, poly vinyl chloride, and other materials. Therefore, the sealant material would be selected for compatibility. The sealant material may also be selected such that it is compostable or otherwise used in such a minimal amount relative to the overall sealing member that the sealant layer does not impact compostability. For example, such sealant materials may include but are not limited to polyurethanes and the like. The sealant layer may also be provided in various thicknesses, such as from about 1 to about 10 microns. In some forms, the sealant layer is provided in a thickness from about 2 to about 5 microns. The sealant layer may be compostable and/or non-compostable. When provided in a non-compostable form, it may be desirable to keep the layer thin so as to decrease the amount of non-compostable materials.
Further, the sealant layer 26 may be especially suited to other forms of sealing besides induction sealing since the tabbed sealing member does not include a foil layer. For example, the sealant layer 26 may be configured for ultrasonic sealing, conduction sealing, high frequency sealing, and the like.
The sealant layer may also be provided as a full layer or as a partial layer, such as only being positioned primarily over the land area of the container rim. In some forms, the sealant layer is less than 1 wt. % of the total sealing member. In some forms, the sealant layer is less than 0.5 wt. % of the total sealing member. In some forms, the sealant layer is applied in an amount of about 0.5 to about 10 g/m2. In some forms, the sealant layer is applied in an amount of about 1 to about 5 g/m2.
In some forms, the sealant layer may be configured as a pressure sensitive adhesive. Such pressure sensitive adhesives may include about 0.2 to about a 0.5 mil (or less) adhesive, such as a coated ethylene vinyl acetate (EVA), polyolefins, 2-component polyurethane, ethylene acrylic acid copolymers, curable two-part urethane adhesives, epoxy adhesives, ethylene methacrylate copolymers, and the like bonding materials.
The lower sealant or heat seal layer may be composed of any material suitable for bonding to the rim of a container, such as, but not limited to, induction, conduction, ultrasonic, or direct bonding methods. Suitable adhesives, hot melt adhesives, or sealants for the heat sealable layer include, but are not limited to, polyesters, polyolefins, ethylene vinyl acetate, ethylene-acrylic acid copolymers, surlyn, and other suitable materials. By one approach, the heat sealable layer may be a single layer or a multi-layer structure of such materials about 0.2 to about 10 mils thick. By some approaches, the heat seal layer is selected to have a composition similar to and/or include the same polymer type as the composition of the container. For instance, if the container includes polyethylene, then the heat seal layer would also contain polyethylene. If the container includes polypropylene, then the heat seal layer would also contain polypropylene. Other similar materials and combinations are also possible.
The at least one film layer in the lower laminate portion typically includes compostable materials. The at least one film layer may include materials such as, but not limited to, cellulose, cellulose films, polylactic acid, casein, and the like. Examples of cellulose materials include, but are not limited to Natureflex by Futamusa.
In some forms, the at least one film layer has a thickness of about 20 to about 100 microns. In other forms, the film layer has a thickness of about 30 to about 50 microns. It should be appreciated that even further film layers may be included in the lower laminate such that the overall thickness of the lower laminate may be modified.
As noted above, the sealing member may be provided without any metal foil layers. Metal foil layers typically provide induction heating performance and also barrier properties. In certain instances, it may be desirable to include improved barrier properties. Such barrier properties include, but are not limited to, oxygen barrier, moisture barrier, and the like. However, in some forms it may be desirable to increase these properties without adding a metal foil layer. In such forms, barrier films and/or coatings may be used on one or more of the layers, such as the at least one film layer in the lower laminate portion. Such materials and coatings include, but are not limited to SiOx, AlOx, EVOH, and combinations thereof. In other forms, metal particles, such as aluminum, are vacuum deposited or lightly coated onto one or more layers.
As noted above, the additional layer 30 in the lower laminate may perform a variety of different functions. The additional layer may be positioned and otherwise function as an adhesion promoter and/or sacrificing layer between the film layer in the lower laminate and the sealant layer. The additional layer can be used to provide a controlled break of the bond between the sealant layer and the additional layer and/or the remainder of the sealing member, such as a portion of the land area in the upper laminate portion.
The additional layer may include a variety of different materials such as cellulose, polyvinyl butyral, nitrocellulose, acrylics, polyurethane, co-polyesters, and combinations thereof. The additional layer in the lower laminate may have a variety of different thicknesses, such as from about 0.5 to about 50 microns. In some forms, the additional layer has a thickness of about 0.5 to about 1 micron.
The adhesive layer, such as layers 36 and 236, used between the upper and lower laminate portions may be a variety of different materials, including compostable materials. Such materials include, but are not limited to, polyurethane, acrylics, and the like. Examples include, but are not limited to, MS 255 Eco+CS-95 by Morchem. The adhesive layer may also be used in a variety of thicknesses. For example, the adhesive layer may have a thickness between about 1 to about 10 microns. In some forms, the adhesive layer may have a thickness between about 2 to about 5 microns.
The support layer 32 in the upper laminate portion may also include a variety of different materials and different thicknesses. For example, the support layer may include materials such as cellulose films, polylactic acid, casein, and the like. The support layer may be provided in a variety of different thicknesses. In some forms, the support layer may have a thickness of about 20 to about 50 microns.
The print layer may also include a variety of different materials and thicknesses. In general, the print layer can be applied to another layer, such as in the form of printing. Printing inks may be used including, but not limited to, nitrocellulose, PVD (physical vapor deposition) pigments, acrylic, polyurethane, polyvinylbutyral, (PVB) and the like. In some forms, the print layer is applied to one of the layers in the upper laminate portion. In other forms, the print layer may be applied to a different layer which is then combined with one or more of the other layers. In some forms, the ink may be encapsulated between the films and layers described herein and/or may be encapsulated between additional film layers. In some forms, the ink provided is less than about 1 wt. % of the total sealing member.
In some forms, all of the layers of the sealing member, with the exception of the sealant layer, are compostable. As noted above, the sealant layer may be chosen and positioned such that it makes up a very small percentage of the overall sealing member such that the sealing member is still compostable. Further, the sealant layer may be configured so that it is generally over the land area and may remain on the container, as a remnant, such that the sealant is no longer found on the sealing member after removal from the container. Therefore, the removed sealing member may include only compostable materials.
Exemplary forms of a compostable sealing member may include a variety of different combinations of layers, materials, and thicknesses. One exemplary combination may include an upper laminate portion having a 45 micron cellulose film that is transparent and functions as support layer 32. A compostable adhesive, such as compostable polyurethane materials (for example, MS 255 Eco+CS-95 by Morchem) can be partially applied across the surface area of the upper laminate portion in an amount of about 4-5 grams per square meter to partially adhere the upper laminate portion to the lower laminate portion. The lower laminate portion includes a 45 micron metallized cellulose film, such as Natureflex by Futamusa having a vacuum deposited metal coating. In the lower laminate portion 3-4 grams per square meter of a compostable adhesive can be used to adhere the metallized cellulose film to a 45 micron cellulose film. Finally, a PET heat seal lacquer, applied at 3 grams per square meter, is positioned as the lowermost layer and functions as the sealant layer in the lower laminate portion.
In Example 2, a sealing member was generally prepared in accordance with the features shown in
In Example 3, similar materials were used as in Example 2, but the thickness of some of the layers were modified. By modifying the thicknesses, the percentage of compostable materials changes.
In Example 4, a similar material was prepared as in Example 2, but the heatseal covered the entire surface area of the seal and not just in the area above the rim when installed on the container. In this form, the amount of PET heatseal increases, which also changes the percentage of compostable materials.
In Example 5, a similar material was prepared as in Example 3, but the heatseal covered the entire surface area of the seal and not just in the area above the rim when installed on the container. In this form, the amount of PET heatseal increases, which also changes the percentage of compostable materials.
In Example 6, a two-piece sealing member was prepared similar to that shown in
Further general details of the sealing members, tabs, components, and layers are provided below.
In one aspect, the tab may be formed by a full layer or partial layer of material combined with a partial width composite adhesive structure. This partial composite adhesive structure bonds the upper laminate to the lower laminate to form the gripping tab.
In other aspects of this disclosure, the upper laminate of the seal does not extend the full width of the sealing member in order to define the gripping tab. To this end, the pull tab sealing members herein may also combine the advantages of a tabbed sealing member with a large gripping tab defined completely within the perimeter of the seal, but achieve such functionality with less material (in view of the part layers of the upper laminate) and permit such a tab structure to be formed on many different types of pre-formed lower laminates. The partial upper laminate structure is advantageous, in some approaches, for use with a seal configured for large or wide mouth containers, such as containers with an opening from about 30 to about 100 mm (in other approaches, about 60 to about 100 mm). These seals may also be used with 38 mm or 83 mm container openings, or can be used with any sized container.
In further aspects of this disclosure, the sealing members herein may include a pull or grip tab defined in the upper laminate portion wholly within a perimeter or circumference of the sealing member wherein an upper surface of the sealing member is partially defined by the upper laminate portion and partially defined by the lower laminate portion. In one approach of this aspect, the top surface of the sealing member is provided by a minor portion of the upper laminate and a major portion of the lower laminate. In other approaches of this aspect, the lower laminate is partially exposed at a top surface of the seal with about 50 percent to about 75 percent (or more) of the lower laminate exposed at the top surface of the entire seal. The seals of this aspect allow consumers to remove the sealing member using the tab (as in a conventional pull tab seal) and/or puncture the sealing member by piercing the exposed lower laminate portion to provide push/pull functionality depending on the preference of the consumer.
In the various embodiments, the seals of the present disclosure defining a tab wholly within a perimeter or circumference of the seal (formed by a full or partial layer) also provide an improved ability for the tabbed sealing member to function in a two-piece seal and liner combination. In a two-piece seal and liner combination, the tabbed sealing member is temporarily adhered across its top surface to a liner. After container opening and removal of a cap or closure, the sealing member stays adhered to the container mouth and the liner separates and remains in the container's cap.
In some prior versions of two-piece seal and linear assemblies, the bottom layer of the sealing member is a heat seal layer that is activated by heating, such as by induction or conduction heating, in order to adhere or bond an outer periphery of the sealing member to a rim surrounding the mouth of a container. In the two-piece seal and liner combination, an upper surface of the sealing member is temporarily adhered to a lower surface of the liner by a release layer, which is often a heat-activated release layer, such as an intervening wax layer. During heating to bond the sealing member to the container, heat not only activates the lower heat seal layer, but also travels upwardly through the seal to melt the intervening wax across the entire surface of the sealing member to separate the liner from the sealing member. Often, the melted wax is absorbed by the liner in order to permit easy liner separation from the sealing member. As can be appreciated, for this sealing member and liner combination to function properly, the intervening wax layer needs to be melted across the entire surface of the sealing member. If the wax is not melted evenly all the way across the sealing member upper surface, the liner may not properly separate from the lower seal portion.
The various layers of the sealing member may be assembled via coating adhesives, applying films, and/or a heat lamination process forming a sheet of the described layers. Extrusion lamination may also be used. The resulting laminate sheet of the sealing members can be cut into appropriate sized disks or other shapes as needed to form a vessel closing assembly or tabbed sealing member. The cut sealing member is inserted into a cap or other closure which, in turn, is applied to the neck of a container to be sealed. The screw cap can be screwed onto the open neck of the container, thus sandwiching the sealing member between the open neck of the container and the top of the cap. The sealing layer may be a pressure sensitive adhesive, the force of attaching the closure to the container can activate the adhesive.
One form of assembling tabbed sealing members is shown in
The matter set forth in the foregoing description and accompanying drawings is offered by way of illustration only and not as a limitation. While particular embodiments have been shown and described, it will be apparent to those skilled in the art that changes and modifications may be made without departing from the broader aspects of Applicant's contribution. The actual scope of the protection sought is intended to be defined in the following claims when viewed in their proper perspective based on the prior art.
This application claims benefit of U.S. Provisional Application No. 63/163,139, filed Mar. 19, 2021, which is hereby incorporated herein by reference in its entirety.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/US2022/020718 | 3/17/2022 | WO |
| Number | Date | Country | |
|---|---|---|---|
| 63163139 | Mar 2021 | US |
