Patent Application
20240321914
This application claims priority to and the benefit of Korean Patent Application No. 10-2023-0026302 filed in the Korean Intellectual Property Office on Feb. 27, 2023, the entire contents of which are incorporated herein by reference.
Example embodiments relate to compounds, photoelectric devices, light absorption sensors, sensor-embedded display panels, and electronic devices.
Recently, there is an increasing demand for a display device implementing a biometric recognition technology that authenticates the person by extracting specific biometric information or behavioral characteristic information of a person with an automated device, centering on finance, healthcare, and mobile device. Accordingly, research is being conducted on a display device including a sensor capable of biometric recognition.
Such a sensor capable of biometric recognition may be disposed under a display panel of a display device or may be separately manufactured as a separate module and mounted outside the display device. When the sensor is disposed under the display panel, the sensor is configured to recognize an object recognized through the display panel, various films, and/or parts with improved performance and having improved integration overcoming limitations in terms of design and usability that may be associated with sensors manufactured and mounted as separate modules. Accordingly, a sensor-embedded display panel including a sensor capable of improving performance by being integrated with the display panel has been proposed.
The photoelectric device used in the sensor as described above is a device that converts light into an electrical signal using the photoelectric effect, and may include a photodiode and a phototransistor.
A sensor (e.g., an image sensor) including a photodiode has a higher resolution and a smaller pixel size. At present, a silicon photodiode is widely used, but it has a problem of deteriorated sensitivity since silicon photodiode has a smaller absorption area due to small pixels. Accordingly, an organic material that is capable of replacing silicon has been researched.
The organic material has a high extinction coefficient and selectively absorbs light in a particular wavelength region depending on a molecular structure, and thus may simultaneously replace a photodiode and a color filter and resultantly improve sensitivity and contribute to high integration.
Therefore, there is a growing interest in organic materials that can be used in these sensors.
Some example embodiments provide a compound that can selectively absorb light in a visible light region and improve light absorption characteristics of a device.
Some example embodiments provide a photoelectric device that selectively absorbs light in the visible light region and has improved light absorption characteristics of the device.
Some example embodiments provide a (light absorption) sensor including the photoelectric device.
Some example embodiments provide a sensor-embedded display panel including the photoelectric device or (light absorption) sensor.
Some example embodiments provide an electronic device including the photoelectric device or (light absorption) sensor.
According to some example embodiments, a compound represented by any one of Chemical Formulas 1 to 3, and having a molecular packing density of greater than or equal to about 1.55 molecules/nm3, may be provided,
In Chemical Formulas 1 to 3,
In Chemical Formulas 1 to 3, Rx1, Rx2, Ry1, Ry2, and Rz may each independently be an electron donating group selected from a C1 to C6 alkyl group and a C1 to C6 alkoxy group.
In Chemical Formulas 1 to 3, EWG may be a substituted or unsubstituted C6 to C30 hydrocarbon ring group including at least one functional group selected from C═O, C═S, C═Se, C═Te, and C═CRpRq (wherein Rp and Rq may each independently be hydrogen, deuterium, a substituted or unsubstituted C1 to C10 alkyl group, or a cyano group); a substituted or unsubstituted C2 to C30 heterocyclic group including at least one functional group selected from C═O, C═S, C═Se, C═Te, and C═CRpRq (wherein Rp and Rq may each independently be hydrogen, deuterium, a substituted or unsubstituted C1 to C10 alkyl group, or a cyano group); or a fused ring thereof; or a C2 to C20 alkyl group including at least one functional group selected from C═O, C═S, C═Se, C═Te, and C═CRpRq (wherein RP and Rp may each independently be hydrogen, deuterium, a substituted or unsubstituted C1 to C10 alkyl group, or a cyano group).
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by Chemical Formula 4.
In Chemical Formula 4,
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by any one of Chemical Formula 5A to Chemical Formula 5H.
In Chemical Formula 5A,
The compound represented by any one of Chemical Formulas 1 to 3 may have a molecular volume of less than or equal to about 570 Å3.
The compound represented by any one of Chemical Formulas 1 to 3 may have a single film absorption coefficient of greater than or equal to about 1.4×105 cm−1.
The compound represented by any one of Chemical Formulas 1 to 3 may have an oscillator strength value of greater than or equal to about 0.8.
The compound represented by any one of Chemical Formulas 1 to 3 may have an aspect ratio (Z/X) obtained by dividing a length of a shortest axis of the molecule (Z) by a length of a longest axis of the molecule (X) of less than or equal to about 0.41.
The compound may have a maximum absorption wavelength (Amax) in a wavelength range of about 500 nm to about 540 nm in a thin film state.
The compound represented by any one of Chemical Formulas 1 to 3 may have a sublimation temperature of less than or equal to about 280° C.
The compound may exhibit an absorption curve with a full width at half maximum (FWHM) of about 20 nm to about 150 nm in a thin film state.
According to some example embodiments, a photoelectric device (e.g., organic photoelectric device) includes a first electrode and a second electrode facing each other, and
According to some example embodiments, a light absorption sensor including the photoelectric device is provided.
The light absorption sensor may include a semiconductor substrate integrated with a plurality of first photo-sensing devices sensing light in a blue wavelength region and a plurality of second photo-sensing devices sensing light in a red wavelength region, and the photoelectric device on the semiconductor substrate and selectively sensing light in a green wavelength region.
The light absorbing layer may include a p-type semiconductor and an n-type semiconductor, the p-type semiconductor includes the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof, and the n-type semiconductor includes fullerene, a fullerene derivative, sub-phthalocyanine or a sub-phthalocyanine derivative, thiophene or a thiophene derivative, or a compound represented by Chemical Formula 6.
In Chemical Formula 6,
The first photo-sensing device and the second photo-sensing device may be stacked in a vertical direction in the semiconductor substrate.
The light absorption sensor may further include a color filter layer including a blue filter selectively transmitting light in a blue wavelength region and a red filter selectively transmitting light in a red wavelength region.
The light absorption sensor may include the photoelectric device, wherein the photoelectric device is a green photoelectric device configured to sense light in a green wavelength region, and the light absorption sensor may include a stack of the green photoelectric device, a blue photoelectric device configured to selectively absorb light in a blue wavelength region, and a red photoelectric device configured to selectively absorb light in a red wavelength region.
According to some example embodiments, a sensor-embedded display panel may include a substrate, a light emitting element disposed on the substrate and including a light emitting layer, and a light absorption sensor disposed on the substrate and comprising a light absorbing layer, the light absorbing layer being arranged in parallel with the light emitting layer along an in-plane direction of the substrate such that the light absorbing layer and the light emitting layer at least partially overlap in the in-plane direction, wherein the light absorbing layer is configured to absorb light of a red wavelength spectrum, a green wavelength spectrum, a blue wavelength spectrum, an infrared wavelength spectrum, or any combination thereof, the light absorbing layer configured to absorb light of the green wavelength spectrum includes the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof.
The light emitting element may include first, second and third light emitting elements configured to emit light of different wavelength spectra, and the light absorption sensor may be configured to absorb light emitted from at least one of the first, second, or third light emitting elements and then reflected by the recognition target to the light absorption sensor and to convert the absorbed light into an electrical signal.
The light emitting element and the light absorption sensor may each include a separate portion of a common electrode configured to apply a common voltage to the light emitting element and the light absorption sensor, and the sensor-embedded display panel may further include a first common auxiliary layer that is a single piece of material that extends continuously between the light emitting layer and the common electrode and between the light absorbing layer and the common electrode.
A difference between a LUMO energy level of the first common auxiliary layer and a LUMO energy level of the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof may be less than or equal to about 1.2 eV.
The sensor-embedded display panel may further include a second common auxiliary layer that is a single piece of material that extends continuously between the light emitting layer and the substrate and between the light absorbing layer and the substrate.
The light emitting element may include first, second, and third light emitting elements configured to emit light of any one wavelength spectrum of the red wavelength spectrum, the green wavelength spectrum, or the blue wavelength spectrum, and the light absorbing layer may be configured to absorb light having a same wavelength spectrum as light emitted from at least one of the first, second, or third light emitting elements.
The sensor-embedded display panel may include a display area configured to display a color and a non-display area excluding the display area, and the light absorption sensor may be in the non-display area.
The display area may include a plurality of first subpixels configured to display light of the red wavelength spectrum and comprising the first light emitting element, a plurality of second subpixels configured to display light of the green wavelength spectrum and comprising the second light emitting element, and a plurality of third subpixels configured to display light of the blue wavelength spectrum and comprising the third light emitting element, and the light absorption sensor may be between at least two subpixels of a first subpixel of the plurality of first subpixels, a second subpixel of the plurality of second subpixels, or a third subpixel of the plurality of third subpixels.
The light absorbing layer may include a p-type semiconductor and an n-type semiconductor, the p-type semiconductor includes the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof, and the n-type semiconductor includes fullerene, fullerene derivative, sub-phthalocyanine or a sub-phthalocyanine derivative, thiophene or a thiophene derivative, or the compound represented by Chemical Formula 6.
According to some example embodiments, an electronic device including the light absorption sensor or a sensor-embedded display panel is provided.
The compound can selectively absorb light in the visible light region and has excellent light absorption characteristics, and thus it can be suitably used in photoelectric devices or light absorption sensors, especially sensor-embedded display panels.
Hereinafter, some example embodiments will be described in detail so that a person skilled in the art would understand the same. However, a structure that is actually applied may be implemented in various different forms and is not limited to the example embodiments described herein.
In the drawings, the thickness of layers, films, panels, regions, etc., are exaggerated for clarity. It will be understood that when an element such as a layer, film, region, or substrate is referred to as being “on” another element, it may be directly on the other element or intervening elements may also be present. In contrast, when an element is referred to as being “directly on” another element, there are no intervening elements present.
In the drawings, parts having no relationship with the description are omitted for clarity of the example embodiments, and the same or similar constituent elements are indicated by the same reference numeral throughout the specification.
As used herein, “at least one of A, B, or C,” “one of A, B, C, or any combination thereof” and “one of A, B, C, and any combination thereof” refer to each constituent element, and any combination thereof (e.g., A; B; C; A and B; A and C; B and C; or A, B, and C).
Hereinafter, the terms “lower” and “upper” are used for better understanding and ease of description, but do not limit the location relationship.
As used herein, when a definition is not otherwise provided, “substituted” refers to replacement of hydrogen of a compound or a functional group by a substituent selected from a halogen (F, Br, Cl, or I), a hydroxy group, a nitro group, a cyano group, an amine group, an azido group, an amidino group, a hydrazino group, a hydrazono group, a carbonyl group, a carbamyl group, a thiol group, an ester group, a carboxyl group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a C1 to C30 alkyl group, a C2 to C30 alkenyl group, a C2 to C30 alkynyl group, a C6 to C30 aryl group, a C7 to C30 arylalkyl group, a C1 to C30 alkoxy group, a C1 to C20 heteroalkyl group, a C3 to C20 heterocyclic group, a C3 to C20 heteroarylalkyl group, a C3 to C30 cycloalkyl group, a C3 to C15 cycloalkenyl group, a C6 to C15 cycloalkynyl group, a C3 to C30 heterocycloalkyl group, or any combination thereof.
As used herein, when a definition is not otherwise provided, “hetero” refers to one including 1 to 4 heteroatoms selected from N, O, S, Se, Te, Si, and P.
As used herein, when a definition is not otherwise provided, “alkyl group” refers to a monovalent linear or branched saturated hydrocarbon group, for example a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, an isobutyl group, a t-butyl group, a pentyl group, a hexyl group, and the like.
As used herein, when a definition is not otherwise provided, “alkoxy group” is expressed as —OR, where R may be the alkyl group described above.
As used herein, when a definition is not otherwise provided, “cycloalkyl group” refers to a monovalent hydrocarbon ring group in which the atoms of the cycle are carbon, for example a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, and the like.
As used herein, when a definition is not otherwise provided, “aryl group” refers to a substituent in which all ring-forming elements have p-orbitals which form conjugation, and it may be a monocyclic, polycyclic or fused-ring polycyclic (e.g., rings sharing adjacent pairs of carbon atoms) functional group.
As used herein, when a definition is not otherwise provided, “cyano-containing group” refers to a monovalent group such as a C1 to C30 alkyl group, a C2 to C30 alkenyl group, or a C2 to C30 alkynyl group where at least one hydrogen is substituted with a cyano group. As used herein, when a definition is not otherwise provided, the cyano-containing group also refers to a divalent group such as ═CRx′—(CRxRy)p—CRy′(CN)2 wherein Rx, Ry, Rx′, and Ry′ may each independently be hydrogen or a C1 to C10 alkyl group and p is an integer of 0 to 10 (or 1 to 10). As a monovalent functional group, specific examples of the cyano-containing group may be a dicyanomethyl group, a dicyanovinyl group, a cyanoethynyl group, and the like. As used herein, the cyano-containing group does not include a functional group including a cyano group (—CN) alone.
As used herein, when a definition is not otherwise provided, “combination” refers to a mixture, a stack, or an alloy of constituting components.
As used herein, when a definition is not otherwise provided, “combination thereof” in the definition of chemical formula refers to at least two substituents bound to each other by a single bond or a C1 to C10 alkylene group, or at least two fused substituents.
As used herein, when a definition is not otherwise provided, “hydrocarbon ring group” may be a C3 to C30 hydrocarbon ring group. The hydrocarbon ring group may be an arene group (e.g., a C6 to C30 arene group, a C6 to C20 arene group, or a C6 to C10 arene group), an alicyclic hydrocarbon ring group (e.g., a C3 to C30 cycloalkyl group, a C5 to C30 cycloalkyl group, a C3 to C20 cycloalkyl group, or a C3 to C10 cycloalkyl group) or a fused ring thereof. For example the fused ring thereof may refer to a fused ring of an aromatic ring (arene ring) and a non-aromatic ring (alicyclic ring), for example a fused ring of at least one aromatic ring (arene ring) such as a C6 to C30 arene group, a C6 to C20 arene group, or a C6 to C10 arene group and at least one non-aromatic ring (alicyclic ring) such as a C3 to C30 cycloalkyl group, a C3 to C20 cycloalkyl group, or a C3 to C10 cycloalkyl group.
As used herein, when a definition is not otherwise provided, “heterocyclic group” may be a C2 to C30 heterocyclic group. The heterocyclic group refers to a cyclic group including 1 to 3 heteroatoms selected from N, O, S, Se, Te, P, and Si instead of carbon atom(s) in a cyclic group selected from an arene group (e.g., a C6 to C30 arene group, a C6 to C20 arene group, or a C6 to C10 arene group), an alicyclic hydrocarbon ring group (e.g., a C3 to C30 cycloalkyl group, a C3 to C20 cycloalkyl group, or a C3 to C10 cycloalkyl group), or a fused ring thereof. At least one carbon atom of the heterocyclic group may also be substituted with a thiocarbonyl group (C═S).
As used herein, “arene group” refers to a hydrocarbon group having an aromatic ring, and includes monocyclic and polycyclic hydrocarbon groups, and the additional ring of the polycyclic hydrocarbon group may be an aromatic ring or a nonaromatic ring. “Heteroarene group” refers to an arene group including 1 to 3 heteroatoms selected from N, O, S, Se, Te, P, and Si in a cyclic group.
In some example embodiments, “ring structure” regarding “linked to each other to form a ring structure” may refer to a C5 to C10 carbocyclic group (e.g., C6 to C10 aryl group or C6 aryl group) providing a conjugated structure or a C2 to C10 heterocyclic group (e.g., C2 to C10 heteroaryl group or C2 to C4 heteroaryl group) providing a conjugated structure.
As used herein, when a definition is not otherwise provided, “aromatic hydrocarbon group” includes a phenyl group, a naphthyl group, a C6 to C30 aryl group, or a C6 to C30 arylene group, but is not limited thereto.
As used herein, when a definition is not otherwise provided, aromatic ring may include a fused ring of an aromatic ring and an alicyclic ring. The “aromatic ring” refers to a C6 to C20 aryl group (e.g., C6 to C10 aryl group) or C2 to C20 heteroaryl group (e.g., C2 to C4 heteroaryl group). The “alicyclic ring” refers to a C3 to C10 cycloalkyl group or a C2 to C10 heterocyroalkyl group.
It will further be understood that when an element is referred to as being “on” another element, it may be above or beneath or adjacent (e.g., horizontally adjacent) to the other element. It will be understood that elements and/or properties thereof (e.g., structures, surfaces, directions, or the like), which may be referred to as being “perpendicular,” “parallel,” “coplanar,” or the like with regard to other elements and/or properties thereof (e.g., structures, surfaces, directions, or the like) may be “perpendicular,” “parallel,” “coplanar,” or the like or may be “substantially perpendicular,” “substantially parallel,” “substantially coplanar,” respectively, with regard to the other elements and/or properties thereof. Elements and/or properties thereof (e.g., structures, surfaces, directions, or the like) that are “substantially perpendicular” with regard to other elements and/or properties thereof will be understood to be “perpendicular” with regard to the other elements and/or properties thereof within manufacturing tolerances and/or material tolerances and/or have a deviation in magnitude and/or angle from “perpendicular,” or the like with regard to the other elements and/or properties thereof that is equal to or less than 10% (e.g., a. tolerance of ±10%). Elements and/or properties thereof (e.g., structures, surfaces, directions, or the like) that are “substantially parallel” with regard to other elements and/or properties thereof will be understood to be “parallel” with regard to the other elements and/or properties thereof within manufacturing tolerances and/or material tolerances and/or have a deviation in magnitude and/or angle from “parallel,” or the like with regard to the other elements and/or properties thereof that is equal to or less than 10% (e.g., a. tolerance of ±10%). Elements and/or properties thereof (e.g., structures, surfaces, directions, or the like) that are “substantially coplanar” with regard to other elements and/or properties thereof will be understood to be “coplanar” with regard to the other elements and/or properties thereof within manufacturing tolerances and/or material tolerances and/or have a deviation in magnitude and/or angle from “coplanar,” or the like with regard to the other elements and/or properties thereof that is equal to or less than 10% (e.g., a. tolerance of ±10%). It will be understood that elements and/or properties thereof may be recited herein as being “identical” to, “the same” or “equal” as other elements and/or properties, and it will be further understood that elements and/or properties thereof recited herein as being “identical” to, “the same” as, or “equal” to other elements and/or properties may be “identical” to, “the same” as, or “equal” to or “substantially identical” to, “substantially the same” as or “substantially equal” to the other elements and/or properties thereof. Elements and/or properties thereof that are “substantially identical” to, “substantially the same” as or “substantially equal” to other elements and/or properties thereof will be understood to include elements and/or properties thereof that are identical to, the same as, or equal to the other elements and/or properties thereof within manufacturing tolerances and/or material tolerances. Elements and/or properties thereof that are identical or substantially identical to and/or the same or substantially the same as other elements and/or properties thereof may be structurally the same or substantially the same, functionally the same or substantially the same, and/or compositionally the same or substantially the same. While the term “same,” “equal” or “identical” may be used in description of some example embodiments, it should be understood that some imprecisions may exist. Thus, when one element or value is referred to as being the same as another element or value, it should be understood that an element or a value is the same as another element or value within a desired manufacturing or operational tolerance range (e.g., ±10%). It will be understood that elements and/or properties thereof described herein as being the “substantially” the same and/or identical encompasses elements and/or properties thereof that have a relative difference in magnitude that is equal to or less than 10%. Further, regardless of whether elements and/or properties thereof are modified as “substantially,” it will be understood that these elements and/or properties thereof should be construed as including a manufacturing or operational tolerance (e.g., ±10%) around the stated elements and/or properties thereof. When the terms “about” or “substantially” are used in this specification in connection with a numerical value, it is intended that the associated numerical value include a tolerance of ±10% around the stated numerical value. Moreover, when the words “about” and “substantially” are used in connection with geometric shapes, it is intended that precision of the geometric shape is not required but that latitude for the shape is within the scope of the inventive concepts. Further, regardless of whether numerical values or shapes are modified as “about” or “substantially,” it will be understood that these values and shapes should be construed as including a manufacturing or operational tolerance (e.g., ±10%) around the stated numerical values or shapes. When ranges are specified, the range includes all values therebetween such as increments of 0.1%.
As used herein, when a definition is not otherwise provided, the energy level is the highest occupied molecular orbital (HOMO) energy level or the lowest unoccupied molecular orbital (LUMO) energy level.
As used herein, when a definition is not otherwise provided, a work function or energy level is expressed as an absolute value from a vacuum level. In addition, when the work function or the energy level is referred to be deep, high, or large, it may have a large absolute value based on “0 eV” of the vacuum level while when the work function or the energy level is referred to be shallow, low, or small, it may have a small absolute value based on “0 eV” of the vacuum level. In addition, a difference between the work function and/or the energy level may be a value obtained by subtracting a small value of the absolute value from a large value of the absolute value.
As used herein, when a definition is not otherwise provided, the HOMO energy level may be evaluated by the amount of photoelectrons emitted according to energy by irradiating UV light onto a thin film using AC-2 (Hitachi) or AC-3 (Riken Keiki Co., LTD.).
As used herein, when a definition is not otherwise provided, the LUMO energy level is obtained as follow: an energy bandgap is obtained using a UV-Vis spectrometer (Shimadzu Corporation), and then the LUMO energy level is calculated from the energy bandgap and the measured HOMO energy level.
Hereinafter, molecular packing density refers to the density of molecules in the deposited film, and is a value calculated using molecular dynamics (MD) simulations (Desmond software).
In addition, the molecular volume is a value calculated using the Gaussian 09 program and the Multiwfn program (T. Lu, F. Chen, J. Comput. Chem. 2012, 33, 580.).
In addition, oscillator strength and aspect ratio are values calculated at the DFT B3LYP/DGDZVP level using the Gaussian 09 program.
In addition, the absorption coefficient of a single film can be obtained by irradiating a thin film sample with ultraviolet-visible light (UV-Vis) using a Cary 5000 UV spectrometer (manufactured by Varian) and dividing the measured absorbance by the thickness of the thin film.
In addition, the sublimation temperature can be confirmed by thermogravimetric analysis (TGA), and may be a temperature at which, for example, a weight loss of 10% compared to the initial weight occurs when thermogravimetric analysis is performed at a pressure of about 10 Pa or less.
The present inventors have found that a compound with excellent absorption intensity in a specific wavelength range of the visible light range can be designed when the packing density of the compound is within a specific range to complete the present inventive concepts and to improve the functionality (e.g., improved photoelectric conversion performance and/or efficiency) of a photoelectric device including the compound in an active layer thereof.
Hereinafter, a compound according to some example embodiments will be described. The compound is represented by any one of Chemical Formulas 1 to 3 and has a molecular packing density of greater than or equal to about 1.55 molecules/nm3.
In Chemical Formulas 1 to 3,
The compound represented by Chemical Formula 1 may include an electron donor moiety of arylamine or heteroarylamine, an X1-containing pentagonal ring linker, and an electron acceptor moiety represented by EWG, and the electron donor moiety and the X1-containing pentagonal ring linker are linked by G1. The compound represented by Chemical Formula 2 includes an electron donor moiety of an N-containing fused ring group, an X1-containing pentagonal ring linker, and an electron acceptor moiety represented by EWG. The compound represented by Chemical Formula 3 includes an electron donor moiety of an N-containing fused ring group, an X1-containing pentagonal ring linker, and an electron acceptor moiety represented by EWG, and the electron donor moiety and the X1-containing pentagonal ring linker are linked by G1.
Because the compounds of Chemical Formulas 1 to 3 may have the above structures and substituents, a single film including the compounds can have a high molecular packing density. In the case of having such a high molecular packing density, a high absorption coefficient may be realized, thereby improving the photoelectric conversion efficiency, and thus improving the functionality (e.g., performance and/or power consumption efficiency), of devices including these compounds.
In some example embodiments, the compounds of Chemical Formulas 1 to 3 may have a molecular packing density of greater than or equal to about 1.55 molecules/nm3, for example greater than or equal to about 1.56 molecules/nm3, greater than or equal to about 1.57 molecules/nm3, greater than or equal to about 1.58 molecules/nm3, greater than or equal to about 1.59 molecules/nm3, or greater than or equal to about 1.60 molecules/nm3. The higher the molecular packing density, the better, but considering the molecular structure design, the molecular packing density may be less than or equal to about 2.00 molecules/nm3.
The structures of Chemical Formulas 1 to 3 have a donor-acceptor structure, whereby the absorption wavelength may be adjusted to a wavelength range of the visible light wavelength range (greater than or equal to about 500 nm, for example, greater than or equal to about 505 nm and less than or equal to about 540 nm, for example, less than or equal to about 535 nm, less than or equal to about 534 nm, less than or equal to about 533 nm, less than or equal to about 532 nm, less than or equal to about 531 nm, less than or equal to about 530 nm, less than or equal to about 529 nm, less than or equal to about 528 nm, less than or equal to about 527 nm, less than or equal to about 526 nm, or less than or equal to about 525 nm, for example, greater than or equal to about 500 nm and less than or equal to about 540 nm, for example, greater than or equal to about 500 nm and less than or equal to about 535 nm, greater than or equal to about 500 nm and less than or equal to about 534 nm, greater than or equal to about 500 nm and less than or equal to about 533 nm, greater than or equal to about 500 nm and less than or equal to about 532 nm, greater than or equal to about 500 nm and less than or equal to about 531 nm, greater than or equal to about 500 nm and less than or equal to about 530 nm, greater than or equal to about 500 nm and less than or equal to about 529 nm, greater than or equal to about 500 nm and less than or equal to about 528 nm, greater than or equal to about 500 nm and less than or equal to about 527 nm, greater than or equal to about 500 nm and less than or equal to about 526 nm, or greater than or equal to about 500 nm and less than or equal to about 525 nm), the deposition temperature may be lowered, and the absorption coefficient may be increased.
In Chemical Formulas 1 to 3, when Y1 may be N, intramolecular interactions increase, thereby improving the light absorption characteristics of the compound.
In Chemical Formulas 1 to 3, Rx1, Rx2, Ry1, Ry2, and Rz may each independently be an electron donating group selected from a C1 to C6 alkyl group and a C1 to C6 alkoxy group.
In Chemical Formulas 1 to 3, EWG may be a substituted or unsubstituted C6 to C30 hydrocarbon ring group including at least one functional group selected from C═O, C═S, C═Se, C═Te, and C═CRpRq (wherein Rp and Rq may each independently be hydrogen, deuterium, a C1 to C6 alkyl group, or a cyano group); a substituted or unsubstituted C2 to C30 heterocyclic group including at least one functional group selected from C═O, C═S, C═Se, C═Te, and C═CRpRq (wherein Rp and Rq may each independently be hydrogen, deuterium, a C1 to C6 alkyl group, or a cyano group); or a fused ring thereof; or a C2 to C20 alkyl group including at least one functional group selected from C═O, C═S, C═Se, C═Te, and C═CRpRq (wherein Rp and Rq may each independently be hydrogen, deuterium, a C1 to C6 alkyl group, or a cyano group).
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by Chemical Formula 4.
In Chemical Formula 4,
In some example embodiments, when both Z1 and Z2 are CRaRb, at least one of Z1 or Z2 may include a cyano group.
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by Chemical Formula 5A.
In Chemical Formula 5A,
In some example embodiments, when both Z1 and Z2 of Chemical Formula 5A are CRaRb, at least one of Z1 or Z2 may include a cyano group.
The cyclic group represented by Chemical Formula 5A may be a cyclic group represented by Chemical Formula 5A-1 or Chemical Formula 5A-2.
In Chemical Formula 5A-1 and Chemical Formula 5A-2,
In Chemical Formula 5A, two adjacent groups of R11, R12, and R13 are not linked to each other to form a fused ring. That is, the cyclic group represented by Chemical Formula 5A does not include the cyclic group represented by Chemical Formula 5A-3. If it contains a ring group represented by Chemical Formula 5A-3, the molecular packing density in the desired range cannot be obtained.
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by Chemical Formula 5B.
In Chemical Formula 5B,
The cyclic group represented by Chemical Formula 5B may be, for example, a cyclic group represented by Chemical Formula 5B-1, Chemical Formula 5B-2, or Chemical Formula 5B-3.
In Chemical Formulas 5B-1, 5B-2, and 5B-3,
In some example embodiments, when both Z1 and Z2 of Chemical Formula 5B are CRaRb, at least one of Z1 and Z2 may include a cyano group.
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by Chemical Formula 5C.
In Chemical Formula 5C,
The cyclic group represented by Chemical Formula 5C may be, for example, a cyclic group represented by Chemical Formula 5C-1 or Chemical Formula 5C-2.
In Chemical Formulas 5C-1 and 5C-2,
In some example embodiments, when both Z1 and Z2 of Chemical Formula 5C are CRaRb, at least one of Z1 and Z2 may include a cyano group.
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by Chemical Formula 5D.
In Chemical Formula 5D,
In some example embodiments, when both Z1 and Z2 of Chemical Formula 5D are CRaRb, at least one of Z1 and Z2 may include a cyano group.
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by Chemical Formula 5E.
In Chemical Formula 5E,
In some example embodiments, when both Z1 and Z2 of Chemical Formula 5E are CRaRb, at least one of Z1 and Z2 may include a cyano group.
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by Chemical Formula 5F.
In Chemical Formula 5F,
In some example embodiments, when both Z1 and Z2 of Chemical Formula 5F are CRaRb, at least one of Z1 and Z2 may include a cyano group.
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by Chemical Formula 5G.
In Chemical Formula 5G,
In Chemical Formulas 1 to 3, EWG may be a cyclic group represented by Chemical Formula 5H.
In Chemical Formula 5H,
In some example embodiments, when all Z1 to Z4 of Chemical Formula 5H are CRaRb, at least one of Z1 to Z4 may include a cyano group.
In some example embodiments, when G2 is a single bond, X1 may not be S.
Specific examples of the compound of Chemical Formula 1 may include compounds of Group 1, but are not limited thereto.
In Group 1,
In Group 1, the compounds in which EWG is a cyclic group represented by Chemical Formula 5A, 5B, 5D, 5E, or 5F are exemplified, but compounds in which EWG is a cyclic group represented by Chemical Formulas 5C, 5G, and 5H may also be exemplified in the same way.
Specific examples of the compound of Chemical Formula 2 include compounds of Group 2, but are not limited thereto.
In Group 2,
In Group 2, the compounds in which EWG is a cyclic group represented by Chemical Formula 5B are exemplified, but compounds in which EWG is a cyclic group represented by Chemical Formula 5A, and Chemical Formulas 5C to 5H may also be exemplified in the same way.
Specific examples of the compound of Chemical Formula 3 include compounds of Group 3, but are not limited thereto.
In Group 3,
In Group 3, the compounds in which EWG is a cyclic group represented by Chemical Formula 5A, 5B3, 5D, or 5E are exemplified, but compounds in which EWG is a cyclic group represented by Chemical Formula 5C and Chemical Formulas 5F to 5H may also be exemplified in the same way.
The compounds represented by Chemical Formulas 1 to 3 have a high molecular packing density of greater than or equal to about 1.55 molecules/nm3, which increases the number of molecules present per unit area, and thus the absorption coefficient can be increased when applied to devices, thereby improving functionality thereof (e.g., photoelectric conversion performance and/or efficiency, power consumption efficiency, etc.).
The compounds may also have a molecular volume of less than or equal to about 570 Å3, for example less than or equal to about 565 Å3, less than or equal to about 560 Å3, less than or equal to about 555 Å3, less than or equal to about 550 Å3, less than or equal to about 545 Å3, or less than or equal to about 540 Å3, and greater than or equal to about 500 Å3, for example greater than or equal to about 505 Å3.
When forming a single film, the compound may have a single film absorption coefficient of greater than or equal to about 1.4×105 cm−1, for example greater than or equal to about 1.45×105 cm−1 and less than or equal to about 2.5×105 cm−1, for example less than or equal to about 2.0×105 cm−1.
The compound may have an oscillator strength value of greater than or equal to about 0.8, for example, greater than or equal to about 0.85, or greater than or equal to about 0.90, and less than or equal to about 1.8, for example less than or equal to about 1.7, or less than or equal to about 1.6. When the oscillator strength is in the above range, the absorption coefficient of the compound may be increased.
In the three-dimensional structure of the molecule represented by any one of Chemical Formulas 1 to 3, an aspect ratio (Z/X) obtained by dividing a length of a shortest axis of the molecule (Z) by a length of a longest axis of the molecule (X) may be of less than or equal to about 0.41, for example less than or equal to about 0.40, or of less than or equal to about 0.39 and greater than or equal to about 0.30, for example, greater than or equal to about 0.31, or greater than or equal to about 0.32. Within the above range, the compound can maintain excellent planarity and the charge mobility can be improved.
The compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof may selectively absorb (e.g., may be configured to selectively absorb) light in the green wavelength region, and may have a maximum absorption wavelength (Amax) in a wavelength range of about 500 nm to about 540 nm, for example, about 500 nm to about 535 nm, about 500 nm to about 534 nm, about 500 nm to about 533 nm, about 500 nm to about 532 nm, about 500 nm to about 531 nm, about 500 nm to about 530 nm, about 500 nm to about 529 nm, about 500 nm to about 528 nm, about 500 nm to about 527 nm, about 500 nm to about 526 nm, or about 500 nm to about 525 nm, in a thin film state.
The compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof may exhibit an absorption curve with a full width at half maximum (FWHM) of less than or equal to about 150 nm, for example about 20 nm to about 150 nm, about 20 nm to about 120 nm, about 20 nm to about 110 nm or about 20 nm to about 100 nm, in a thin film state. By having the FWHM in the above range, absorption selectivity for the entire green wavelength range may be increased. The thin film may be a thin film deposited under vacuum conditions.
In some example embodiments, the sublimation temperature (temperature formed by vacuum deposition, also referred to as “deposition temperature”) of the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof may be less than or equal to about 280° C., for example, about 100° C. to about 280° C. Due to the sublimation temperature in the above range, there is little possibility of impurity mixing when forming a thin film by deposition. The sublimation temperature may be confirmed by thermogravimetric analysis (TGA), and may be, for example, a temperature at which a weight loss of 10% relative to an initial weight occurs during thermogravimetric analysis at a pressure of 10 Pa or less.
In addition, a micro lens array (MLA) may be formed to concentrate light after manufacturing an organic photoelectric device during manufacture of an image sensor. Formation of this micro lens array requires a relatively high temperature (greater than or equal to about 160° C., for example greater than or equal to about 170° C., greater than or equal to about 180° C., or greater than or equal to about 190° C.). The performance of the photoelectric devices (e.g., organic photoelectric devices) is required not to be deteriorated in these heat-treatment processes. The performance deterioration of the organic photoelectric device during the heat treatment of MLA may be caused not by chemical decomposition of an organic material but its morphology change. The morphology change is in general caused, when a material starts a thermal vibration due to a heat treatment, but a material having a firm molecule structure may not have the thermal vibration and be prevented from the deterioration by the heat treatment. The compound represented by any one of Chemical Formulas 1 to 3 has a ring structure linked by G1 and/or G2 in the donor moiety and thus may be stably maintained during the MLA heat treatment and secure process stability.
The compound represented by any one of Chemical Formulas 1 to 3 may be a p-type semiconductor. The compound may have a HOMO energy level in the range of about 4.5 eV to about 6.5 eV, and an energy bandgap of greater than or equal to about 2.0 eV, for example, about 2.0 eV to about 3.0 eV. In this case, the LUMO energy level is located between about 2.5 eV and about 4.5 eV. As the HOMO and LUMO energy levels of the compound of any one of Chemical Formulas 1 to 3 are controlled, the compound represented by any one of Chemical Formulas 1 to 3 may be used as a p-type semiconductor.
The n-type semiconductor that can be used with the compound represented by any one of Chemical Formulas 1 to 3 may include fullerene, a fullerene derivative, sub-phthalocyanine or a sub-phthalocyanine derivative, thiophene or a thiophene derivative, the compound represented by Chemical Formula 6, or any combination thereof.
A composition including a p-type semiconductor including the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof and an n-type semiconductor including a fullerene, a fullerene derivative, sub-phthalocyanine or a sub-phthalocyanine derivative, thiophene or a thiophene derivative, or the compound represented by Chemical Formula 6 has excellent absorption in the entire green wavelength range, and the photoelectric conversion efficiency and/or power consumption efficiency of photoelectric devices and light absorption sensors including these may be improved and dark current and remaining charges thereof may be greatly reduced, thereby improving the functionality of such devices and sensors (e.g., improving light sensing and/or image generating performance without compromising power consumption).
The compound represented by Chemical Formula 6 may include a planar core having an imide group or an anhydride group.
In Chemical Formula 6,
Examples of the fullerene may include C60, C70, C76, C78, C80, C82, C84, C90, C96, C240, C540, a mixture thereof, a fullerene nanotube, and the like. The fullerene derivative may refer to compounds of these fullerenes having a substituent thereof. The fullerene derivative may include a substituent such as an alkyl group (e.g., C1 to C30 alkyl group), an aryl group (e.g., C6 to C30 aryl group), a heterocyclic group (e.g., C3 to C30 heterocycloalkyl group), and the like. Examples of the aryl groups and heterocyclic groups may be a benzene ring, a naphthalene ring, an anthracene ring, a phenanthrene ring, a fluorene ring, a triphenylene ring, a naphthacene ring, a biphenyl ring, a pyrrole ring, a furan ring, a thiophene ring, an imidazole ring, an oxazole ring, a thiazole ring, a pyridine ring, a pyrazine ring, a pyrimidine ring, a pyridazine ring, an indolizine ring, an indole ring, a benzofuran ring, a benzothiophene ring, a isobenzofuran ring, a benzimidazole ring, a imidazopyridine ring, a quinolizidine ring, a quinoline ring, a phthalazine ring, a naphthyridine ring, a quinoxaline ring, an isoquinoline ring, a carbazole ring, a phenanthridine ring, an acridine ring, a phenanthroline ring, a thianthrene ring, a chromene ring, an xanthene ring, a phenoxazine ring, a phenoxathiin ring, a phenothiazine ring, or a phenazine ring.
The subphthalocyanine or subphthalocyanine derivative may be represented by Chemical Formula 7.
In Chemical Formula 7,
For example, Z may be a halogen or a halogen-containing group, for example F, C1, an F-containing group, or a Cl-containing group.
The halogen refers to F, Cl, Br, or I and the halogen-containing group refers to alkyl group (C1 to C30 alkyl group) where at least one hydrogen of the alkyl group may be replaced by F, Cl, Br, or I.
The thiophene derivative may be for example represented by Chemical Formula 8 or Chemical Formula 9, but is not limited thereto.
EWG1-T1-T2-T3-EWG3 [Chemical Formula 9]
In Chemical Formulas 8 and 9,
For example, in Chemical Formula 8, at least one of X3 to X8 may be an electron withdrawing group, for example, a cyano group.
For example, specific examples of the compound represented by Chemical Formula 6 include compounds represented by Chemical Formula 6A or 6B.
In Chemical Formulas 6A and 6B,
For example, at least one of Ra1 or Ra2 may include an electron withdrawing group. For example, Ra1 and Ra2 may each include an electron withdrawing group.
For example, at least one of Ra1 or Ra2 may be a halogen; a cyano group; a halogen-substituted C1 to C30 alkyl group; a halogen-substituted C6 to C30 aryl group; a halogen-substituted C3 to C30 heterocyclic group; a cyano-substituted C1 to C30 alkyl group; a cyano-substituted C6 to C30 aryl group; a cyano-substituted C3 to C30 heterocyclic group; a substituted or unsubstituted pyridinyl group; a substituted or unsubstituted pyrimidinyl group; a substituted or unsubstituted triazinyl group; a substituted or unsubstituted pyrazinyl group; a substituted or unsubstituted quinolinyl group; a substituted or unsubstituted isoquinolinyl group; a substituted or unsubstituted quinazolinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted pyridinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted pyridinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted pyrimidinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted pyrimidinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted triazinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted triazinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted pyrazinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted pyrazinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted quinolinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted quinolinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted isoquinolinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted isoquinolinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted quinazolinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted quinazolinyl group; or any combination thereof.
For example, Ra1 and Ra2 may be each a halogen; a cyano group; a halogen-substituted C1 to C30 alkyl group; a halogen-substituted C6 to C30 aryl group; a halogen-substituted C3 to C30 heterocyclic group; a cyano-substituted C1 to C30 alkyl group; a cyano-substituted C6 to C30 aryl group; a cyano-substituted C3 to C30 heterocyclic group; a substituted or unsubstituted pyridinyl group; a substituted or unsubstituted pyrimidinyl group; a substituted or unsubstituted triazinyl group; a substituted or unsubstituted pyrazinyl group; a substituted or unsubstituted quinolinyl group; a substituted or unsubstituted isoquinolinyl group; a substituted or unsubstituted quinazolinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted pyridinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted pyridinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted pyrimidinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted pyrimidinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted triazinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted triazinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted pyrazinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted pyrazinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted quinolinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted quinolinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted isoquinolinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted isoquinolinyl group; a C1 to C30 alkyl group substituted with a substituted or unsubstituted quinazolinyl group; a C6 to C30 aryl group substituted with a substituted or unsubstituted quinazolinyl group; or any combination thereof.
As an example, Ra1 and Ra2 may be the same or different from each other and in some example embodiments, Ra1 and Ra2 may be the same.
The compound represented by Chemical Formula 6 may be selected from, for example, the compounds listed in Group 4, but is not limited thereto.
In Group 4,
Hereinafter, a photoelectric device according to some example embodiments including the compound will be described with reference to the drawings.
Referring to
One of the first electrode 10 or the second electrode 20 is an anode and the other is a cathode. At least one of the first electrode 10 or the second electrode 20 may be a light-transmitting electrode, and the light-transmitting electrode may be made of, for example, a transparent conductor such as indium tin oxide (ITO) or indium zinc oxide (IZO), or a metal thin layer of a single layer or multilayer. When one of the first electrode 10 or the second electrode 20 is a non-light-transmitting electrode, it may include (e.g., may be made of), for example, an opaque conductor such as aluminum (AI).
In some example embodiments, the active layer 30 is a layer including a p-type semiconductor and an n-type semiconductor that form (e.g., establish, define, etc.) a pn junction, and absorbs external (e.g., incident) light to generate excitons and then separates the generated excitons into holes and electrons.
The active layer 30 includes the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof.
As described above, the p-type semiconductor may include the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof, and the n-type semiconductor may include fullerene, a fullerene derivative, subphthalocyanine or a subphthalocyanine derivative, thiophene or a thiophene derivative, or a compound represented by Formula 6. The description of these is the same as described above. When used in these combinations, the external quantum efficiency and remaining charge characteristics of the photoelectric device can be greatly improved. As a result, the photoelectric conversion efficiency, and thus the photoelectric conversion performance and/or the power consumption efficiency, of the photoelectric device 100 may be improved based on including the compound represented by any of Chemical Formulas 1 to 3 in the active layer 30. For example, the photoelectric conversion performance of the photoelectric device 100 may be improved and/or the power consumption by the photoelectric device 100 may be reduced without compromising the photoelectric conversion performance of the photoelectric device 100.
The active layer 30 may have a maximum absorption wavelength (Amax) in a wavelength range of greater than or equal to about 500 nm, for example, greater than or equal to about 505 nm and less than or equal to about 540 nm, for example, less than or equal to about 535 nm, less than or equal to about 534 nm, less than or equal to about 533 nm, less than or equal to about 532 nm, less than or equal to about 531 nm, less than or equal to about 530 nm, less than or equal to about 529 nm, less than or equal to about 528 nm, less than or equal to about 527 nm, less than or equal to about 526 nm, or less than or equal to about 525 nm, for example, about 500 nm to about 540 nm, for example, about 500 nm to about 535 nm, about 500 nm to about 534 nm, about 500 nm to about 533 nm, about 500 nm to about 532 nm, about 500 nm to about 531 nm, about 500 nm to about 530 nm, about 500 nm to about 529 nm, about 500 nm to about 528 nm, about 500 nm to about 527 nm, about 500 nm to about 526 nm, or about 500 nm to about 525 nm.
The active layer 30 may exhibit an absorption curve with a relatively small full width at half maximum (FWHM) of less than or equal to about 150 nm, for example about 20 nm to about 150 nm, about 20 nm to about 120 nm, about 20 nm to about 110 nm, or about 20 nm to about 100 nm. Accordingly, the active layer 30 can have high selectivity for light in the green wavelength range.
The active layer 30 may include a bi-layer including a p-type layer including the aforementioned p-type semiconductor and an n-type layer including the aforementioned n-type semiconductor. In this case, a volume ratio and/or thickness ratio of the p-type layer and the n-type layer may be about 1:9 to about 9:1, and within the above range, for example, about 2:8 to about 8:2, about 3:7 to about 7:3, about 4:6 to about 6:4, or about 5:5.
The active layer 30 may be an intrinsic layer (I layer) in which a p-type semiconductor and an n-type semiconductor are mixed in a bulk heterojunction form. In this case, the p-type semiconductor and n-type semiconductor may be mixed in a volume ratio (or thickness ratio) of about 1:9 to about 9:1, for example, about 2:8 to about 8:2, about 3:7 to about 7:3, about 4:6 to about 6:4, or about 5:5. By having the volume ratio in the above range, an exciton may be effectively produced, and a pn junction may be effectively formed.
The active layer 30 may further include a p-type layer and/or an n-type layer in addition to the intrinsic layer. The p-type layer may include the aforementioned p-type semiconductor, and the n-type layer may include the aforementioned n-type semiconductor. The active layer 30 may be, for example, an intrinsic layer (I layer), a p-type layer/I layer, an I layer/n-type layer, a p-type layer/I layer/n-type layer, a p-type layer/n-type layer, and the like.
The active layer 30 may have a thickness of about 1 nm to about 500 nm and specifically, about 5 nm to about 300 nm. When the active layer 30 has a thickness within the range, the active layer may effectively absorb light, effectively separate holes from electrons, and deliver them, thereby effectively improving photoelectric conversion efficiency. A desirable thickness of the active layer 30 may be, for example, determined by an absorption coefficient of the active layer 30, and may be, for example, a thickness being capable of absorbing light of at least about 70% or more, for example about 80% or more, and for another example about 90% or more.
In the photoelectric device 100, when light enters from the first electrode 10 and/or second electrode 20, and when the active layer 30 absorbs light in a desired and/or alternatively particular (or, alternatively, predetermined) wavelength region, excitons may be produced from the inside. The excitons are separated into holes and electrons in the active layer 30, and the separated holes are transported to an anode that is one of the first electrode 10 or the second electrode 20 and the separated electrons are transported to the cathode that is the other of the first electrode 10 or the second electrode 20 so as to flow a current in the photoelectric device.
Hereinafter, a photoelectric device according to some example embodiments is described with reference to
Referring to
However, the photoelectric device 200 according to some example embodiments, including the example embodiments shown in
The charge auxiliary layers 40 and 45 may be at least one selected from a hole injection layer (HIL) for facilitating hole injection, a hole transport layer (HTL) for facilitating hole transport, an electron blocking layer (EBL) for preventing electron transport, an electron injection layer (EIL) for facilitating electron injection, an electron transport layer (ETL) for facilitating electron transport, and a hole blocking layer (HBL) for preventing hole transport.
The charge auxiliary layers 40 and 45 may include, for example, an organic material, an inorganic material, or an organic/inorganic material. The organic material may be an organic compound having hole or electron characteristics, and the inorganic material may be, for example, a metal oxide such as molybdenum oxide, tungsten oxide, nickel oxide, or the like.
The hole injection layer (HIL) and/or hole transport layer (HTL) may include one selected from, for example, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS), polyarylamine, poly(N-vinylcarbazole), polyaniline, polypyrrole, N,N,N′,N′-tetrakis(4-methoxyphenyl)-benzidine (TPD), 4,4′-bis[N-(1-naphthyl)-N-phenyl-amino]biphenyl (α-NPD), m-MTDATA, 4,4′,4″-tris(N-carbazolyl)-triphenylamine (TCTA), or any combination thereof, but is not limited thereto.
The electron blocking layer (EBL) may include one selected from, for example, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS), polyarylamine, poly(N-vinylcarbazole), polyaniline, polypyrrole, N,N,N′,N′-tetrakis(4-methoxyphenyl)-benzidine (TPD), 4,4′-bis[N-(1-naphthyl)-N-phenyl-amino]biphenyl (α-NPD), m-MTDATA, 4,4′,4″-tris(N-carbazolyl)-triphenylamine (TCTA), or any combination thereof, but is not limited thereto.
The electron injection layer (EIL) and/or electron transport layer (ETL) may include one selected from, for example, 1,4,5,8-naphthalene-tetracarboxylic dianhydride (NTCDA), bathocuproine (BCP), LiF, Alq3, Gaq3, Inq3, Znq2, Zn(BTZ)2, BeBq2, or any combination thereof, but is not limited thereto.
The hole blocking layer (HBL) may include one selected from, for example, 1,4,5,8-naphthalene-tetracarboxylic dianhydride (NTCDA), bathocuproine (BCP), LiF, Alq3, Gaq3, Inq3, Znq2, Zn(BTZ)2, BeBq2, or any combination thereof, but is not limited thereto.
Either one of the charge auxiliary layers 40 or 45 may be omitted.
The photoelectric devices 100 and 200 may be applied to a solar cell, a light absorption sensor (e.g., an image sensor), a photo detector, an optical sensor, and a light emitting element, but is not limited thereto.
Hereinafter, an example of an image sensor including the organic photoelectric device is described referring to drawings. As an example of an image sensor, also referred to herein as a light absorption sensor, an organic CMOS image sensor according to some example embodiments is described, but it will be understood that the example embodiments are not limited thereto.
Referring to
The semiconductor substrate 110 may be a silicon substrate, and is integrated with the photo-sensing devices 50B and 50R, the transmission transistor (not shown), and the charge storage 55. The photo-sensing devices 50B and 50R may be photodiodes.
The photo-sensing devices 50B and 50R, the transmission transistor, and/or the charge storage 55 may be integrated in each pixel, for example may be integrated in the semiconductor substrate 110 such that the photo-sensing devices 50B and 50R are located within a volume space defined by outermost surface of the semiconductor substrate 110 and may be at least partially exposed by the semiconductor substrate 110 or may be enclosed within an interior of the semiconductor substrate 110. As shown in the drawing, the photo-sensing devices 50B and 50R may be respectively included in a blue pixel and a red pixel and the charge storage 55 may be included in a green pixel. The blue photo-sensing device 50B may be configured to sense (e.g., selectively sense, including selectively absorbing and photoelectrically converting) blue light which is light in a blue wavelength region, and the red photo-sensing device 50R may be configured to sense (e.g., selectively sense, including selectively absorbing and photoelectrically converting) red light which is light in a red wavelength region. The photo-sensing devices 50B and 50R may be configured to sense (e.g., selectively sense) light, the information sensed by the photo-sensing devices 50B and 50R may be transferred by the transmission transistor, the charge storage 55 is electrically connected to the photoelectric device 100, and the information of the charge storage 55 may be transferred by the transmission transistor.
In the drawings, the photo-sensing devices 50B and 50R are, for example, arranged in parallel without limitation, and the blue photo-sensing device 50B and the red photo-sensing device 50R may be stacked in a vertical direction.
A metal wire (not shown) and a pad (not shown) are formed on the semiconductor substrate 110. In order to decrease signal delay, the metal wire and pad may be made of a metal having low resistivity, for example, aluminum (Al), copper (Cu), silver (Ag), and alloys thereof, but are not limited thereto. Further, it is not limited to the structure, and the metal wire and pad may be positioned under the photo-sensing devices 50B and 50R.
The lower insulation layer 60 is formed on the metal wire and the pad. The lower insulation layer 60 may be made of an inorganic insulating material such as a silicon oxide and/or a silicon nitride, or a low dielectric constant (low K) material such as SiC, SiCOH, SiCO, and SiOF. The lower insulation layer 60 has a trench exposing the charge storage 55. The trench may be filled with fillers.
A color filter layer 70 is formed on the lower insulation layer 60. The color filter layer 70 includes a blue filter 70B formed in the blue pixel and configured to selectively transmit blue light and a red filter 70R formed in the red pixel and configured to selectively transmit red light. In some example embodiments, a cyan filter and a yellow filter may be disposed instead of the blue filter 70B and red filter 70R. In some example embodiments, including the example embodiments shown in
The color filter layer 70 may be omitted. For example, when the blue photo-sensing device 50B and the red photo-sensing device 50R are stacked in a vertical direction, the blue photo-sensing device 50B and the red photo-sensing device 50R may selectively absorb light in each wavelength region depending on their stack depth, and the color filter layer 70 may not be equipped.
The upper insulation layer 80 is formed on the color filter layer 70. The upper insulation layer 80 eliminates a step caused by the color filter layer 70 and smoothens the surface. The upper insulation layer 80 and the lower insulation layer 60 may include a contact hole (not shown) exposing a pad, and a through-hole 85 exposing the charge storage 55 of the green pixel.
The aforementioned photoelectric device 100 is formed on the upper insulation layer 80. The photoelectric device 100 includes the first electrode 10, the active layer 30, and the second electrode 20 as described above.
The first electrode 10 and the second electrode 20 may be transparent electrodes, and the active layer 30 is the same as described above. The active layer 30 selectively absorbs and/or senses light in a green wavelength region and replaces a color filter of a green pixel.
When light enters from the second electrode 20, the light in a green wavelength region may be mainly absorbed in the active layer 30 and photoelectrically converted, while the light in the rest of the wavelength regions passes through first electrode 10 and may be sensed in the photo-sensing devices 50B and 50R.
As described above, the photoelectric devices selectively absorbing light in a green wavelength region are stacked and thereby a size of an image sensor may be decreased and a down-sized image sensor may be realized.
In addition, as described above, by including the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof as a semiconductor, agglomeration between compounds can be reduced, minimized, or prevented even in a thin film state, and light absorption characteristics depending on the wavelength can be maintained. Accordingly, green wavelength selectivity can be maintained, crosstalk caused by unnecessary absorption of light in wavelength regions other than the green wavelength region can be reduced, and sensitivity can be increased.
In some example embodiments, in
The organic CMOS image sensor with the color filters disposed on the photoelectric device is shown in
In
Referring to
However, the organic CMOS image sensor 500 according to some example embodiments, including the example embodiments shown in
Referring to
However, the organic CMOS image sensor 600 according to some example embodiments includes the blue photo-sensing device 50B and the red photo-sensing device 50R that are stacked in a vertical direction (e.g., perpendicular to a direction in which the upper surface of the semiconductor substrate 110 extends as shown in
As described above, the photoelectric devices selectively absorbing light in a green wavelength region are stacked and the red photo-sensing device and the blue photo-sensing device are stacked, and thereby a size of an image sensor may be decreased and a down-sized image sensor may be realized. As described above, the photoelectric device 100 has improved green wavelength selectivity, and crosstalk caused by unnecessary absorption of light in a wavelength region except green may be decreased while increasing sensitivity. As a result, the photoelectric devices including an active layer 30 including the compound represented by any of Chemical Formulas 1 to 3 may have improved photoelectric performance and/or reduced power consumption without compromising photoelectric conversion performance.
In
Referring to
The organic CMOS image sensor 700 according to some example embodiments includes a semiconductor substrate 110, a lower insulation layer 60, an intermediate insulation layer 65, an upper insulation layer 80, a first device (i.e., photoelectric device, the same below) 100a, a second device 100b, and a third device 100c.
The semiconductor substrate 110 may be a silicon substrate, and a transmission transistor (not shown) and charge storages 155a, 155b, and 155c are integrated therein.
Metal wires (not shown) and pads (not shown) are formed on the semiconductor substrate 110, and the lower insulation layer 60 is formed on the metal wires and the pads.
The first device 100a, the second device 100b, and the third device 100c are sequentially formed on the lower insulation layer 60.
Any one of the first, second, or third devices 100a, 100b, or 100c may be the photoelectric devices 100 and/or 200 (e.g., a green photoelectric device according to some example embodiments) of
The active layer 30 of the first device 100a may selectively absorb light in any one wavelength region of red, blue, or green to photoelectrically convert the light. For example, the first device 100a may be a red photoelectric conversion device configured to selectively sense light in a red wavelength region. The first electrode 10 or the second electrode 20 of the first device 100a may be electrically connected to the first charge storage 155a. A “photoelectric conversion device” may be interchangeably referred to herein as a “photoelectric device.”
The intermediate insulation layer 65 may be formed on the first device 100a and the second device 100b may be formed on the intermediate insulation layer 65.
The active layer 30 of the second device 100b may selectively absorb light in any one wavelength region of red, blue, or green to photoelectrically convert the light. For example, the second device 100b may be a green photoelectric conversion device configured to selectively sense light in a green wavelength region. In another example, the second device 100b may be a blue photoelectric conversion device configured to selectively sense light in a blue wavelength region. The first electrode 10 or the second electrode 20 of the second device 100b may be electrically connected to the second charge storage 155b.
The upper insulation layer 80 is formed on the second device 100b. The lower insulation layer 60, the intermediate insulation layer 65, and the upper insulation layer 80 have a plurality of through-holes 85a, 85b, and 85c exposing the charge storages 155a, 155b, and 155c.
The third device 100c is formed on the upper insulation layer 80. The active layer 30 of the third device 100c may selectively absorb light in any one wavelength region of red, blue, or green to photoelectrically convert the light. For example, the third device 100c may be a blue photoelectric conversion device configured to selectively sense light in a blue wavelength region. In another example, the third device 100c may be a green photoelectric conversion device configured to selectively sense light in a green wavelength region. The first electrode 10 or the second electrode 20 of the third device 100c may be electrically connected to the third charge storage 155c.
A focusing lens (not shown) may be further formed on the third device 100c. The focusing lens may control direction of incident light and gather the light in one region. The focusing lens may have a shape of, for example, a cylinder or a hemisphere, but is not limited thereto.
In the drawing, a structure in which the first device 100a, the second device 100b, and the third device 100c are sequentially stacked is shown, but is not limited thereto, and the stacking order may be variously changed.
As described above, the first device 100a, the second device 100b, and the third device 100c that absorb light in different wavelength regions have a stacked structure, further reducing a size of the image sensor, implementing a down-sized image sensor, and simultaneously increasing sensitivity and reducing a crosstalk.
In the drawing, the green photoelectric device, the blue photoelectric device, and the red photoelectric device are sequentially stacked, but the stack order may be changed without limitation.
The green photoelectric device (G) may be the aforementioned photoelectric device 100 or photoelectric device 200, the blue photoelectric device (B) may include electrodes facing each other and an active layer therebetween and including an organic material selectively absorbing light in a blue wavelength region, and the red photoelectric device (R) may include electrodes facing each other and an active layer therebetween and including an organic material selectively absorbing light in a red wavelength region.
As described above, the green photoelectric device G configured to selectively absorb light in a green wavelength region, the blue photoelectric device B configured to selectively absorb light in a blue wavelength region, and the red photoelectric device R configured to selectively absorb light in a red wavelength region are stacked, and thereby a size of an image sensor may be decreased and a down-sized image sensor may be realized.
Hereinafter, a sensor-embedded display panel having an image sensor (light absorption sensor) embedded therein according to some example embodiments is described.
The sensor-embedded display panel according to some example embodiments may be a display panel capable of performing a display function and a recognition function (e.g., biometric recognition function), and may be an in-cell type display panel in which a sensor performing a recognition function (e.g., biometric recognition function) is embedded in the display panel.
Referring to
Displaying a color may refer to emitting light corresponding to the color (e.g., light in a wavelength spectrum of the color).
Referring to
The plurality of subpixels PX's including the first subpixel PX1, the second subpixel PX2, and the third subpixel PX3 may constitute (e.g., may define) one unit pixel UP to be arranged repeatedly along the row and/or column. In
Each of the first subpixel PX1, the second subpixel PX2, and the third subpixel PX3 may include a light emitting element. As an example, the first subpixel PX1 may include a first light emitting element 210 capable of emitting light of a wavelength spectrum of a first color, the second subpixel PX2 may include a second light emitting element 220 capable of emitting light of a wavelength spectrum of a second color, and the third subpixel PX3 may include a third light emitting element 230 capable of emitting light having a wavelength spectrum of a third color. However, the inventive concepts are not limited thereto, and at least one of the first subpixel PX1, the second subpixel PX2, or the third subpixel PX3 may include a light emitting element that emits light of a combination of a first color, a second color, and a third color, that is, light in a white wavelength spectrum, and may display a first color, a second color, or a third color through a color filter (not shown). Herein, the terms “wavelength spectrum” and “wavelength region” may be used interchangeably.
The sensor-embedded display panel 1000 according to some example embodiments includes the light absorption sensor 310. The light absorption sensor 310 may be disposed in a non-display area NDA. The non-display area NDA may be an area other than the display area DA, in which the first subpixel PX1, the second subpixel PX2, the third subpixel PX3, and optionally auxiliary subpixels are not arranged (e.g., a portion of the total area of the sensor-embedded display panel 1000 that excludes the display area DA, excludes the subpixels PX, is between adjacent subpixels PX, etc.). For example, the area (e.g., in the xy plane) of the subpixels PX may collectively define the display area DA that is configured to display an image thereon (e.g., configured to display one or more colors). A portion of the area (e.g., in the xy plane) of the sensor-embedded display panel 1000 that excludes the display area DA (e.g., portions of the area of the sensor-embedded display panel 1000 that are between adjacent subpixels PX in the xy direction, xy plane, etc.) may be a non-display area NDA that is configured to not display an image thereon (e.g., configured to not display any color). The light absorption sensor 310 may be disposed between at least two subpixels selected from the first subpixel PX1, the second subpixel PX2, and the third subpixel PX3 (e.g., between at least two subpixels of a first subpixel PX1 of a plurality of first subpixels PX1, a second subpixel PX2 of the plurality of second subpixels PX2, or a third subpixel PX3 of the plurality of third subpixels PX3), and may be disposed in parallel with the first, second, and third light emitting elements 210, 220, and 230 in the display area DA for example in parallel along the in-plane direction of the semiconductor substrate 110 (e.g., the xy direction as shown), which may be a direction extending parallel to an upper surface 110S of the semiconductor substrate 110.
The light absorption sensor 310 may be an optical type recognition sensor (e.g., biometric sensor). The light absorption sensor 310 may absorb light generated by reflection of light emitted from at least one of the first, second, or third light emitting elements 210, 220, or 230 disposed in the display area DA, by a recognition target 90 such as a living body, a tool, or a thing (e.g., may be configured to absorb light of a red wavelength spectrum, a green wavelength spectrum, a blue wavelength spectrum, an infrared wavelength spectrum, or any combination thereof), and then may convert it (the absorbed light) into an electrical signal. Herein, the living body may be a finger, a fingerprint, a palm, an iris, a face, and/or a wrist, but is not limited thereto. The light absorption sensor 310 may be, for example, a fingerprint sensor, an illumination sensor, an iris sensor, a distance sensor, a blood vessel distribution sensor, and/or a heart rate sensor, but is not limited thereto.
The light absorption sensor 310 may be disposed on the semiconductor substrate 110 on the same plane as the first, second, and third light emitting elements 210, 220, and 230, and may be embedded in the sensor-embedded display panel 1000. Restated, the light absorption sensor 310 may be in parallel with the first, second, and third light emitting elements 210, 220, and 230 on the semiconductor substrate 110 along an in-plane direction of the semiconductor substrate 110. As described herein, the in-plane direction of the semiconductor substrate 110 may be a direction (e.g., the xy direction as shown) that extends in parallel with at least a portion of the semiconductor substrate 110, including an upper surface 110S of the semiconductor substrate 110.
Referring to
The semiconductor substrate 110, also referred to herein as a substrate, may be a light-transmitting substrate, for example, a glass substrate or a polymer substrate. The polymer substrate may include, for example, polycarbonate, polymethylmethacrylate, polyethyleneterephthalate, polyethylenenaphthalate, polyimide, polyamide, polyamideimide, polyethersulfone, polyorganosiloxane, a styrene-ethylene-butylene-styrene copolymer, polyurethane, polyacrylate, polyolefin, or any combination thereof, but is not limited thereto.
A plurality of thin film transistors 120 are formed on the semiconductor substrate 110. One or more thin film transistor 120 may be included in each subpixel PX, and may include, for example, at least one switching thin film transistor and/or at least one driving thin film transistor. The semiconductor substrate 110 on which the thin film transistor 120 is formed may be referred to as a thin film transistor substrate (TFT substrate) or a thin film transistor backplane (TFT backplane).
The insulation layer 140 may have a plurality of contact holes 141 for electrically connecting the first, second, and third light emitting elements 210, 220, and 230 and the thin film transistor 120 and a plurality of contact holes 142 for electrically connecting the light absorption sensor 310 and the thin film transistor 120. The insulation layer 140 may include an organic, inorganic, or organic-inorganic insulating material, in some example embodiments, an inorganic insulating material such as silicon oxide, silicon nitride, silicon oxynitride, aluminum oxide, aluminum nitride, or aluminum oxynitride; an organic insulating material such as polyimide, polyamide, polyamideimide, or polyacrylate; or an organic-inorganic insulating material such as polyorganosiloxane or polyorganosilazane.
The pixel definition layer 150 may also be formed on the whole surface of the semiconductor substrate 110 and may be disposed between adjacent subpixels PX's to partition each subpixel PX. The pixel definition layer 150 may have a plurality of openings 151 disposed in each subpixel PX, and in each opening 151, any one of first, second, or third light emitting elements 210, 220, or 230 or the light absorption sensor 310 may be disposed. The pixel definition layer 150 be an insulation layer that may include an organic, inorganic, or organic-inorganic insulating material, in some example embodiments, an inorganic insulating material such as silicon oxide, silicon nitride, or silicon oxynitride; an organic insulating material such as polyimide; or an organic-inorganic insulating material such as polyorganosiloxane or polyorganosilazane.
The first, second and third light emitting elements 210, 220, and 230 are formed on the semiconductor substrate 110 (or thin film transistor substrate), and are repeatedly arranged along the plane direction (e.g., xy direction) of the semiconductor substrate 110 (also referred to as an in-plane direction of the semiconductor substrate 110). As described above, the first, second, and third light emitting elements 210, 220, and 230 may be included in the first subpixel PX1, the second subpixel PX2, and the third subpixel PX3, respectively. The first, second, and third light emitting elements 210, 220, and 230 may be electrically connected to separate thin film transistors 120 and may be driven independently.
The first, second and third light emitting elements 210, 220, and 230 may each independently emit one light selected from a red wavelength spectrum, a green wavelength spectrum, a blue wavelength spectrum, an infrared wavelength spectrum, or any combination thereof. For example, the first light emitting element 210 may emit light of a red wavelength spectrum, the second light emitting element 220 may emit light of a green wavelength spectrum, and the third light emitting element 230 may emit light of a blue wavelength spectrum. Herein, the red wavelength spectrum, the green wavelength spectrum, and the blue wavelength spectrum may have a maximum emission wavelength (Amax) in a wavelength region of greater than about 600 nm and less than about 750 nm, about 500 nm to about 600 nm, and greater than or equal to about 400 nm and less than about 500 nm, respectively.
The first, second, and third light emitting elements 210, 220, and 230 may be, for example, light emitting diodes, for example, an organic light emitting diode including an organic material.
The light absorption sensor 310 may be formed on the semiconductor substrate 110 (or the thin film transistor substrate), and may be randomly or regularly arranged along the plane direction (e.g., xy direction) of the semiconductor substrate 110. As described above, the light absorption sensor 310 may be disposed in the non-display area NDA, and may be connected to a separate thin film transistor 120 to be independently driven. The light absorption sensor 310 may absorb light of the same wavelength spectrum as the light emitted from at least one of the first, second, or third light emitting elements 210, 220, or 230 to convert it (the absorbed light) into an electrical signal. For example, it may absorb light of a red wavelength spectrum, a green wavelength spectrum, a blue wavelength spectrum, an infrared wavelength spectrum, or any combination thereof to convert it into an electrical signal. The light absorption sensor 310 may be, for example, a photoelectric diode, for example, an organic photoelectric diode including an organic material.
Each of the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310 may include separate, respective pixel electrodes 211, 221, 231, and 311; a separate portion of a common electrode 320 facing the pixel electrodes 211, 221, 231, and 311 and to which a common voltage is applied; and separate, respective light emitting layers 212, 222, and 232 or a light absorbing layer 330, a separate portion of a first common auxiliary layer 340, and a separate portion of a second common auxiliary layer 350 between the pixel electrodes 211, 221, 231, and 311 and the common electrode 320.
The first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310 may be arranged in parallel along the plane direction (e.g., xy direction) of the semiconductor substrate 110, and the common electrode 320, the first common auxiliary layer 340, and the second common auxiliary layer 350 which are formed on the whole surface may be shared. For example, as shown in at least
The common electrode 320 is continuously formed as a single piece of material that extends on the upper portion of the light emitting layers 212, 222, and 232 and the light absorbing layer 330, and is substantially formed on the whole surface of the semiconductor substrate 110. The common electrode 320 may apply a common voltage to the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310. As shown, the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310 may include separate portions of a single common electrode 320 that is a single piece of material that extends on each of the respective light emitting layers 212, 222, and 232 and the light absorbing layer 330 and between the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310.
The first common auxiliary layer 340 is disposed between the light emitting layers 212, 222, and 232 and light absorbing layer 330 and the common electrode 320 and may be continuously formed as a single piece of material that extends on the upper portions of the light emitting layers 212, 222, and 232 and the light absorbing layer 330 and on the lower portions of the common electrode 320. As shown, the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310 may include separate portions of a single first common auxiliary layer 340 that is a single piece of material that extends on each of the respective light emitting layers 212, 222, and 232 and the light absorbing layer 330 and between the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310.
The first common auxiliary layer 340 is a charge auxiliary layer (e.g., electron auxiliary layer) that facilitates injection and/or movement of charges (e.g., electrons) from the common electrode 320 to the light emitting layers 212, 222, and 232. For example, the LUMO energy level of the first common auxiliary layer 340 may be disposed between the LUMO energy levels of the light emitting layers 212, 222, and 232 and the work function of the common electrode 320, and the work function of the common electrode 320, the LUMO energy level of the first common auxiliary layer 340, and the LUMO energy levels of the light emitting layers 212, 222, and 232 may become shallow in sequence. On the other hand, the LUMO energy level of the first common auxiliary layer 340 may be shallower than the LUMO energy level of the light absorbing layer 330 and the work function of the common electrode 320, respectively.
The first common auxiliary layer 340 may include an organic material, an inorganic material, an organic-inorganic material, or any combination thereof satisfying the LUMO energy level, for example a halogenated metal such as LiF, NaCl, CsF, RbCl, and Rbl; a lanthanide metal such as Yb; a metal oxide such as Li2O or BaO; Liq (lithium quinolate), Alq3 (tris(8-hydroxyquinolinato)aluminum), 1,3,5-tri[(3-pyridyl)-phen-3-yl]benzene, 2,4,6-tris (3′-(pyridin-3-yl)biphenyl-3-yl)-1,3,5-triazine, 2-(4-(N-phenylbenzoimidazolyl-1-ylphenyl)-9,10-dinaphthylanthracene, TPBi (1,3,5-tri(1-phenyl-1H-benzo[d]imidazol-2-yl)benzene), BCP (2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline), Bphen (4,7-diphenyl-1,10-phenanthroline), TAZ (3-(4-biphenylyl)-4-phenyl-5-tertbutylphenyl-1,2,4-triazole), NTAZ (4-(naphthalen-1-yl)-3,5-diphenyl-4H-1,2,4-triazole), tBu-PBD (2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole), BAlq (bis(2-methyl-8-quinolinolato-N1,O8)-(1,1′-biphenyl-4-olato)aluminum), Bebq2 (beryllium bis(benzoquinolin-10-olate), ADN (9,10-di(naphthalene-2-yl)anthracene), BmPyPhB (1,3-bis[3,5-di(pyridin-3-yl)phenyl]benzene), or any combination thereof, but is not limited thereto. The first common auxiliary layer 340 may be one layer or two or more layers.
The second common auxiliary layer 350 may be disposed between the light emitting layers 212, 222, and 232 and the light absorbing layer 330 and the semiconductor substrate 110, and may be disposed between the light emitting layers 212, 222, and 232 and the light absorbing layer 330 and the pixel electrodes 211, 221, 231, and 311. The second common auxiliary layer 350 may be continuously formed as a single piece of material that extends on the lower portions of the light emitting layers 212, 222, and 232 and the light absorbing layer 330 and on the upper portions of pixel electrodes 211, 221, 231, and 311. As shown, the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310 may include separate portions of a single second common auxiliary layer 350 that is a single piece of material that extends under each of the respective light emitting layers 212, 222, and 232 and the light absorbing layer 330 and between the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310.
The second common auxiliary layer 350 is a charge auxiliary layer (e.g., hole auxiliary layer) that facilitates injection and/or movement of charges (e.g., holes) from the pixel electrodes 211, 221, and 231 to the light emitting layers 212, 222, and 232. For example, the HOMO energy level of the second common auxiliary layer 350 may be disposed between the HOMO energy level of the light emitting layers 212, 222, and 232 and the work functions of the pixel electrodes 211, 221, and 231, and the work functions of the pixel electrodes 211, 221, and 231, the HOMO energy level of the second common auxiliary layer 350, and the HOMO energy levels of the light emitting layers 212, 222, and 232 may be sequentially deepened.
The second common auxiliary layer 350 may include an organic material, an inorganic material, an organic-inorganic material, or any combination thereof satisfying the HOMO energy level, for example a phthalocyanine compound such as copper phthalocyanine; DNTPD (N,N′-diphenyl-N,N′-bis-[4-(phenyl-m-tolyl-amino)-phenyl]-biphenyl-4,4′-diamine), m-MTDATA (4,4′,4″-[tris(3-methylphenyl)phenylamino]triphenylamine), TDATA (4,4′4″-tris(N,N-diphenylamino)triphenylamine), 2-TNATA (4,4′,4″-tris(N-(2-naphthyl)-N-phenylamino)-triphenylamine), PEDOT/PSS (poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate)), PANI/DBSA (polyaniline/dodecylbenzenesulfonic acid), PANI/CSA (polyaniline/Camphor sulfonic acid), PANI/PSS (polyaniline/poly(4-styrenesulfonate)), NPB (N,N′-di(naphthalene-1-yl)-N,N′-diphenylbenzidine), polyetherketone including triphenylamine (TPAPEK), 4-isopropyl-4′-methyldiphenyliodonium[tetrakis(pentafluorophenyl)borate], HAT-CN (dipyrazino[2,3-f: 2′,3′-h] quinoxaline-2,3,6,7,10,11-hexacarbonitrile), a carbazole-based derivative such as N-phenylcarbazole, polyvinylcarbazole, and the like, a fluorene-based derivative, TPD (N,N′-bis(3-methylphenyl)-N,N′-diphenyl-[1,1-biphenyl]-4,4′-diamine), a triphenylamine-based derivative such as TCTA (4,4′,4″-tris(N-carbazolyl)triphenylamine), TAPC (4,4′-cyclohexylidene bis[N,N-bis(4-methylphenyl)benzenamine]), HMTPD (4,4′-bis[N,N′-(3-tolyl)amino]-3,3′-dimethylbiphenyl), mCP (1,3-bis(N-carbazolyl)benzene), or any combination thereof, but is not limited thereto. The second common auxiliary layer 350 may be one layer or two or more layers.
Each of the first, second, and third light emitting elements 210, 220, 230, and the light absorption sensor 310 includes a separate pixel electrode 211, 221, 231, or 311 facing the common electrode 320. One of the pixel electrodes 211, 221, 231, and 311 or the common electrode 320 is an anode and the other is a cathode. For example, the pixel electrodes 211, 221, 231, and 311 may be an anode and the common electrode 320 may be a cathode. The pixel electrodes 211, 221, 231, and 311 are separated for each subpixel PX, and may be electrically connected to a separate thin film transistor 120 to be independently driven.
The pixel electrodes 211, 221, 231, and 311 and the common electrode 320 may each be a light-transmitting electrode or a reflective electrode, and for example, at least one of the pixel electrodes 211, 221, 231, and 311 or the common electrode 320 may be a light-transmitting electrode.
The light-transmitting electrode may be a transparent electrode or a semi-transmissive electrode. The transparent electrode may have a light transmittance of greater than or equal to about 85%, greater than or equal to about 90%, or greater than or equal to about 95% and the semi-transmissive electrode may have a light transmittance of greater than or equal to about 30% and less than about 85%, about 40% to about 80%, or about 40% to about 75%. The transparent electrode and the semi-transmissive electrode may include, for example, at least one of an oxide conductor, a carbon conductor, or a metal thin film. The oxide conductors may include, for example, one or more selected from indium tin oxide (ITO), indium zinc oxide (IZO), zinc tin oxide (ZTO), aluminum tin oxide (ATO), and aluminum zinc oxide (AZO), the carbon conductor may include one or more selected from graphene and carbon nanostructures, and the metal thin film may be a very thin film including aluminum (Al), magnesium (Mg), silver (Ag), gold (Au), magnesium-silver (Mg—Ag), magnesium-aluminum (Mg-AI), an alloy thereof, or any combination thereof.
The reflective electrode may include a reflective layer having a light transmittance of less than or equal to about 5% and/or a reflectance of greater than or equal to about 80%, and the reflective layer may include an optically opaque material. The optically opaque material may include a metal, a metal nitride, or any combination thereof, for example silver (Ag), copper (Cu), aluminum (Al), gold (Au), titanium (Ti), chromium (Cr), nickel (Ni), an alloy thereof, a nitride thereof (e.g., TiN), or any combination thereof, but is not limited thereto. The reflective electrode may be formed of a reflective layer or may have a stacked structure of a reflective layer/transmissive layer or a transmissive layer/reflective layer/transmissive layer, and the reflective layer may be one layer or two or more layers.
For example, when the pixel electrodes 211, 221, 231, and 311 are light-transmitting electrodes and the common electrode 320 is a reflective electrode, the sensor-embedded display panel 1000 may be a bottom emission type display panel that emits light toward the semiconductor substrate 110. For example, when the pixel electrodes 211, 221, 231, and 311 are reflective electrodes and the common electrode 320 are light-transmitting electrode, the sensor-embedded display panel 1000 may be a top emission type display panel that emits light to the opposite side of the semiconductor substrate 110. For example, when the pixel electrodes 211, 221, 231, and 311 and the common electrode 320 are light-transmitting electrodes, respectively, the sensor-embedded display panel 1000 may be a both side emission type display panel.
For example, the pixel electrodes 211, 221, 231, and 311 may be reflective electrodes and the common electrode 320 may be a semi-transmissive electrode. In this case, the sensor-embedded display panel 1000 may have a microcavity structure. In the microcavity structure, reflection may occur repeatedly between the reflective electrode and the semi-transmissive electrode separated by a particular (or, alternatively, predetermined) optical length (e.g., a distance between the semi-transmissive electrode and the reflective electrode) and light of a particular (or, alternatively, predetermined) wavelength spectrum may be enhanced to improve optical properties.
For example, among the light emitted from the light emitting layers 212, 222, and 232 of the first, second, and third light emitting elements 210, 220, and 230, light of a particular (or, alternatively, predetermined) wavelength spectrum may be repeatedly reflected between the semi-transmissive electrode and the reflective electrode and then may be modified. Among the modified light, light having a wavelength spectrum corresponding to a resonance wavelength of a microcavity may be enhanced to exhibit amplified light emission characteristics in a narrow wavelength region. Accordingly, the sensor-embedded display panel 1000 may express colors with high color purity.
For example, among the light incident on the light absorption sensor 310, light of a particular (or, alternatively, predetermined) wavelength spectrum may be repeatedly reflected between the semi-transmissive electrode and the reflective electrode to be modified. Among the modified light, light having a wavelength spectrum corresponding to the resonance wavelength of a microcavity may be enhanced to exhibit photoelectric conversion characteristics amplified in a narrow wavelength region. Accordingly, the light absorption sensor 310 may exhibit high photoelectric conversion characteristics in a narrow wavelength region.
Each of the first, second, and third light emitting elements 210, 220, and 230 includes light emitting layers 212, 222, and 232 between the pixel electrodes 211, 221, and 231 and the common electrode 320. Each of the light emitting layer 212 included in the first light emitting element 210, the light emitting layer 222 included in the second light emitting element 220, and the light emitting layer 232 included in the third light emitting element 230 may emit light in the same or different wavelength spectra and may emit light in, for example a red wavelength spectrum, a green wavelength spectrum, a blue wavelength spectrum, an infrared wavelength spectrum, or any combination thereof.
For example, when the first light emitting element 210, the second light emitting element 220, and the third light emitting element 230 are a red light emitting elements, a green light emitting element, and a blue light emitting element, respectively, the light emitting layer 212 included in the first light emitting element 210 may be a red light emitting layer that emits light in a red wavelength spectrum, the light emitting layer 222 included in the second light emitting element 220 may be a green light emitting layer that emits light in a green wavelength spectrum, and the light emitting layer 232 included in the third light emitting element 230 may be a blue light emitting layer that emits light in a blue wavelength spectrum. Herein, the red wavelength spectrum, the green wavelength spectrum, and the blue wavelength spectrum may have a maximum emission wavelength in a wavelength region of greater than about 600 nm and less than about 750 nm, about 500 nm to about 600 nm, and greater than or equal to about 400 nm and less than about 500 nm, respectively.
For example, when at least one of the first light emitting element 210, the second light emitting element 220, or the third light emitting element 230 is a white light emitting element, the light emitting layer of the white light emitting element may emit light of a full visible light wavelength spectrum, for example, light in a wavelength spectrum of greater than or equal to about 380 nm and less than about 750 nm, about 400 nm to about 700 nm, or about 420 nm to about 700 nm.
The light emitting layers 212, 222, and 232 may include at least one host material and a fluorescent or phosphorescent dopant, and at least one of the at least one host material or the fluorescent or phosphorescent dopant may be an organic material. The organic material may include, for example, a low molecular weight organic material, such as a depositable organic material.
For example, the light emitting layers 212, 222, and 232 may include perylene; rubrene; 4-(dicyanomethylene)-2-methyl-6-[p-(dimethylamino)styryl]-4H-pyran; coumarin or a derivative thereof; carbazole or a derivative thereof; TPBi (2,2′,2″-(1,3,5-benzenetriyl)-tris(1-phenyl-1-H-benzimidazole); TBADN (2-t-butyl-9,10-di(naphth-2-yl)anthracene); AND (9,10-di(naphthalene-2-yl)anthracene); CBP (4,4′-bis(N-carbazolyl)-1,1′-biphenyl); TCTA (4,4′,4″-tris(carbazol-9-yl)-triphenylamine); DSA (distyrylarylene); CDBP (4,4′-bis(9-carbazolyl)-2,2′-dimethylbiphenyl); MADN (2-methyl-9,10-bis(naphthalen-2-yl)anthracene); TCP (1,3,5-tris(carbazol-9-yl)benzene); Alq3 (tris(8-hydroxyquinolino)lithium); an organometallic compound including Pt, Os, Ti, Zr, Hf, Eu, Tb, Tm, Rh, Ru, Re, Be, Mg, Al, Ca, Mn, Co, Cu, Zn, Ga, Ge, Pd, Ag, and/or Au; a derivative thereof; or any combination thereof, but is not limited thereto.
The first, second, and third light emitting elements 210, 220, and 230 may be, for example, a quantum dot light emitting diode including quantum dots, or a perovskite light emitting diode including perovskite.
The quantum dot may include, for example, a Group II-VI semiconductor compound, a Group III-V semiconductor compound, a Group IV-VI semiconductor compound, a Group IV semiconductor element or compound, a Group I-III-VI semiconductor compound, a Group I-II-IV-VI semiconductor compound, a Group II-III-V semiconductor compound, or any combination thereof. The Group II-IV semiconductor compound may be, for example, selected from a binary element semiconductor compound selected from CdSe, CdTe, ZnS, ZnSe, ZnTe, ZnO, HgS, HgSe, HgTe, MgSe, MgS, or a mixture thereof; a ternary element semiconductor compound selected from CdSeS, CdSeTe, CdSTe, ZnSeS, ZnSeTe, ZnSTe, HgSeS, HgSeTe, HgSTe, CdZnS, CdZnSe, CdZnTe, CdHgS, CdHgSe, CdHgTe, HgZnS, HgZnSe, HgZnTe, MgZnSe, MgZnS, or a mixture thereof; and a quaternary element semiconductor compound selected from HgZnTeS, CdZnSeS, CdZnSeTe, CdZnSTe, CdHgSeS, CdHgSeTe, CdHgSTe, HgZnSeS, HgZnSeTe, HgZnSTe, or a mixture thereof, but is not limited thereto. The Group III-V semiconductor compound may be, for example, selected from a binary element semiconductor compound selected from GaN, GaP, GaAs, GaSb, AlN, AIP, AIAs, AISb, InN, InP, InAs, InSb, or a mixture thereof; a ternary element semiconductor compound selected from GaNP, GaNAs, GaNSb, GaPAs, GaPSb, AlNP, AlNAs, AlNSb, AIPAs, AIPSb, InNP, InNAs, InNSb, InPAs, InPSb, or a mixture thereof; and a quaternary element semiconductor compound selected from GaAlNP, GaAlNAs, GaAlNSb, GaAIPAs, GaAIPSb, GaInNP, GaInNAs, GalnNSb, GaInPAs, GalnPSb, InAlNP, InAlNAs, InAlNSb, InAIPAs, InAIPSb, or a mixture thereof, but is not limited thereto. The Group IV-VI semiconductor compound may be, for example, selected from a binary element semiconductor compound selected from SnS, SnSe, SnTe, PbS, PbSe, PbTe, or a mixture thereof; a ternary element semiconductor compound selected from SnSeS, SnSeTe, SnSTe, PbSeS, PbSeTe, PbSTe, SnPbS, SnPbSe, SnPbTe, or a mixture thereof; and a quaternary element semiconductor compound selected from SnPbSSe, SnPbSeTe, SnPbSTe, or a mixture thereof, but is not limited thereto. The Group IV semiconductor element or compound may be, for example, selected from a semiconductor element such as Si, Ge, or a mixture thereof; and a binary element compound selected from SiC, SiGe, or a mixture thereof, but is not limited thereto. The Group I-III-VI semiconductor compound may be, for example, CuInSe2, CuInS2, CuInGaSe, CuInGaS, or a mixture thereof, but is not limited thereto. The Group I-II-IV-VI semiconductor compound may be, for example, CuZnSnSe, CuZnSnS, or a mixture thereof, but is not limited thereto. The Group II-III-V semiconductor compound may be, for example, InZnP, but is not limited thereto.
The perovskite may be CH3NH3PbBr3, CH3NH3PbI3, CH3NH3SnBr3, CH3NH3SnI3, CH3NH3Sn1-xPbxBr3, CH3NH3Sn1-xPbxI3, HC(NH2)2PbI3, HC(NH2)2SnI3, (C4H9NH3)2PbBr4, (C6H5CH2NH3)2PbBr4, (C6H5CH2NH3)2PbI4, (C6H5C2H4NH3)2PbBr4, (C6H13NH3)2(CH3NH3)n-1PbnI3n+1 (0<x<1 and n being any positive integer), or any combination thereof, but is not limited thereto.
The light absorption sensor 310 includes a light absorbing layer 330 between the pixel electrode 311 and the common electrode 320. The light absorbing layer 330 is disposed in parallel with the light emitting layers 212, 222, and 232 of the first, second, and third light emitting elements 210, 220, and 230 along the plane direction (e.g., xy direction) of the semiconductor substrate 110. The light absorbing layer 330 and the light emitting layers 212, 222, and 232 may be disposed on the same plane.
The light absorbing layer 330 may absorb light of a particular (or, alternatively, predetermined) wavelength spectrum and convert it into an electrical signal. The light absorbing layer 330 may absorb light generated by reflection of the aforementioned light emitted from at least one of the first, second, or third light emitting elements 210, 220, or 230, by the recognition target 90 and may convert it into an electrical signal. The light absorbing layer 330 may absorb light of a red wavelength spectrum, a green wavelength spectrum, a blue wavelength spectrum, an infrared wavelength spectrum, or any combination thereof.
For example, the light absorbing layer 330 may selectively absorb light of a red wavelength spectrum having a maximum absorption wavelength belonging to greater than about 600 nm and less than about 750 nm, and may absorb light generated by reflection of the light emitted from the red light emitting element among the first, second, and third light emitting elements 210, 220, and 230, by the recognition target 90.
For example, the light absorbing layer 330 may selectively absorb light of a green wavelength spectrum having a maximum absorption wavelength belonging to about 500 nm to about 600 nm, and may absorb light generated by reflection of the light emitted from the green light emitting element among the first, second and third light emitting elements 210, 220, and 230, by the recognition target 90.
For example, the light absorbing layer 330 may selectively absorb light in a blue wavelength spectrum having a maximum absorption wavelength belonging to greater than or equal to about 380 nm and less than about 500 nm, and may absorb light generated by reflection of the light emitted from the blue light emitting element among the first, second, and third light emitting elements 210, 220, and 230, by the recognition target 90.
For example, the light absorbing layer 330 may absorb light of a red wavelength spectrum, a green wavelength spectrum, and a blue wavelength spectrum, that is, light of a full visible wavelength spectrum of greater than or equal to about 380 nm and less than about 750 nm. The light absorbing layer 330 may absorb light generated by reflection of a combination of light emitted from the light emitting elements 210, 220, and 230, by the recognition target 90.
The light absorbing layer 330 may include a p-type semiconductor and/or an n-type semiconductor for photoelectric conversion of the absorbed light. The p-type semiconductor and the n-type semiconductor may form a pn junction, generate excitons by receiving light from the outside, and then separate the generated excitons into holes and electrons. Each of the p-type semiconductor and the n-type semiconductor may be one or two or more, and the p-type semiconductor may be the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof.
In some example embodiments, the light absorbing layer 330 may include the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof as a p-type semiconductor and fullerene, a fullerene derivative, sub-phthalocyanine or a sub-phthalocyanine derivative, thiophene or a thiophene derivative, or the compound represented by Chemical Formula 6 as an n-type semiconductor.
The n-type semiconductor may be represented by Chemical Formula 6A or 6B.
The light absorbing layer 330 may be disposed in parallel with the light emitting layers 212, 222, and 232 along the plane direction (e.g., xy direction) of the semiconductor substrate 110 as described above, and may be disposed on the same plane as the light emitting layers 212, 222, and 232.
The compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof may have an energy level capable of forming effective electrical matching with the first common auxiliary layer 340 as a p-type semiconductor of the light absorbing layer 330. For example, a difference between the LUMO energy level of the first common auxiliary layer 340 and the LUMO energy level of the compound may be less than or equal to about 1.2 eV, and within the above range, less than or equal to about 1.1 eV, less than or equal to about 1.0 eV, less than or equal to about 0.8 eV, less than or equal to about 0.7 eV, less than or equal to about 0.5 eV, about 0 eV to about 1.2 eV, about 0 eV to about 1.1 eV, about 0 eV to about 1.0 eV, about 0 eV to about 0.8 eV, about 0 eV to about 0.7 eV, about 0 eV to about 0.5 eV, about 0.01 eV to about 1.2 eV, about 0.01 eV to about 1.1 eV, about 0.01 eV to about 1.0 eV, about 0.01 eV to about 0.8 eV, about 0.01 eV to about 0.7 eV, or about 0.01 eV to about 0.5 eV. Accordingly, charges (e.g., electrons) generated in the light absorbing layer 330 may pass through the first common auxiliary layer 340 and may be effectively moved and/or extracted to the common electrode 320.
The light absorbing layer 330 may be an intrinsic layer (I layer) in which a p-type semiconductor and the n-type semiconductor are mixed in a bulk heterojunction form. In this case, the p-type semiconductor and the n-type semiconductor may be mixed in a volume ratio (or thickness ratio) of about 1:9 to about 9:1, and within the above range, for example, about 2:8 to about 8:2, about 3:7 to about 7:3, about 4:6 to about 6:4, or about 5:5. By having the volume ratio in the above range, an exciton may be effectively produced, and a pn junction may be effectively formed.
The light absorbing layer 330 may include a p-type layer and/or an n-type layer instead of the intrinsic layer (I layer) or further include a p-type layer and/or an n-type layer on and/or under the intrinsic layer (I layer). The p-type layer may include, for example, a p-type semiconductor and the n-type layer may include an n-type semiconductor. The light absorbing layer 330 may be, for example, an I layer, a p-type layer/n-type layer, a p-type layer/I layer, an I layer/n-type layer, or a p-type layer/I layer/n-type layer, but is not limited thereto.
The light emitting layers 212, 222, and 232 and the light absorbing layer 330 may each independently have a thickness of about 5 nm to about 300 nm, which may be about 10 nm to about 250 nm, about 20 nm to about 200 nm, or about 30 nm to about 180 nm within the above range. The difference between the thicknesses of the light emitting layers 212, 222, and 232 and the light absorbing layer 330 may be less than or equal to about 20 nm, within the above range, less than or equal to about 15 nm, less than or equal to about 10 nm, or less than or equal to about 5 nm. The light emitting layers 212, 222, and 232 and the light absorbing layer 330 may substantially have the same thickness.
An encapsulation layer 95 may be formed on the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310. The encapsulation layer 95 may include, for example, a glass plate, a metal thin film, an organic film, an inorganic film, an organic-inorganic film, or any combination thereof. The organic film may include, for example, an acrylic resin, a (meth)acrylic resin, polyisoprene, a vinyl resin, an epoxy resin, a urethane resin, a cellulose resin, a perylene resin, or any combination thereof, but is not limited thereto. The inorganic film may include, for example, oxides, nitrides and/or oxynitrides, for example silicon oxide, silicon nitride, silicon oxynitride, aluminum oxide, aluminum nitride, aluminum oxynitride, zirconium oxide, zirconium nitride, zirconium oxynitride, titanium oxide, titanium nitride, titanium oxynitride, hafnium oxide, hafnium nitride, hafnium oxynitride, tantalum oxide, tantalum nitride, tantalum oxynitride, or any combination thereof, but is not limited thereto. The organic-inorganic film may include, for example, polyorganosiloxane, but is not limited thereto. The encapsulation layer 95 may have one or two or more layers.
As described above, the sensor-embedded display panel 1000 according to some example embodiments, including the example embodiments shown in
In addition, since the light absorption sensor 310 uses the light emitted from the first, second, and third light emitting elements 210, 220, and 230, a recognition function (e.g., a biometric recognition function) may be performed without a separate light source. Therefore, since there is no need to provide a separate light source outside the display panel, it is possible to prevent a decrease of the aperture ratio of the display panel due to the area occupied by the light source, and at the same time to save the power consumed by the separate light source, improving power consumption of the sensor-embedded display panel 1000.
In addition, as described above, the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310 share the common electrode 320, the first common auxiliary layer 340, and the second common auxiliary layer 350, and thereby the structure and process may be simplified compared to the case of forming the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310 through separate processes.
In addition, as described above, the light absorption sensor 310 may be an organic photoelectric diode including an organic light absorbing layer. Accordingly, it may have a light absorption that is twice or more higher than that of an inorganic diode such as a silicon photodiode and thus may have a high-sensitivity sensing function.
In addition, as described above, the light absorbing layer 330 of the light absorption sensor 310 may include the compound represented by any one of Chemical Formulas 1 to 3 or any combination thereof, thereby selectively increasing the sensitivity to light in the green wavelength spectrum and improving color separation characteristics without mixing the absorption spectrum. Accordingly, the sensor-embedded display panel 1000 may additionally implement an anti-spoofing effect in addition to the aforementioned effect, and thus the color separation characteristics of the light reflected by the recognition target 90 may be improved, thereby further increasing the detail of the shape of the recognition target 90 and the color of the reflected light (e.g., skin color) may be selectively recognized, thereby further enhancing the accuracy of the biometric recognition function.
In addition, as described above, the organic material included in the light absorbing layer 330 of the light absorption sensor 310 has a sublimation temperature difference within a particular (or, alternatively, predetermined) range with the organic materials of the light emitting layers 212, 222, and 232 of the first, second and third light emitting elements 210, 220, and 230, and thus deposition may be performed in the same process, thereby simplifying the process and increasing process stability.
Also, as described above, since the light absorption sensor 310 may be disposed anywhere in the non-display area NDA (e.g., anywhere in a portion of the sensor-embedded display panel 1000 that does not vertically overlap (e.g., in the z direction) with any light emitting elements and thus is not configured to emit light and/or display color), a desired quantity of the light absorption sensors 310 may be disposed at one or more desired locations in the sensor-embedded display panel 1000. Therefore, for example, by randomly or regularly disposing, arranging, and/or distributing light absorption sensors 310 on the entire area of the sensor-embedded display panel 1000, the biometric recognition function may be performed on any part of the screen of the electronic device such as a mobile device, and the biometric recognition function may be selectively performed at a specific location alone where the biometric recognition function is required according to the user's selection.
Hereinafter, another example of the sensor-embedded display panel 1000 according to some example embodiments is described.
Referring to
However, unlike some example embodiments, including the example embodiments illustrated in
Descriptions of the first subpixel PX1, the second subpixel PX2, the third subpixel PX3, the first light emitting element 210, the second light emitting element 220, and the third light emitting element 230 are the same as described above.
The fourth light emitting element 240 is disposed on the semiconductor substrate 110 and may be disposed on the same plane as the first, second, and third light emitting elements 210, 220, and 230 and the light absorption sensor 310. For example, as shown in at least
The fourth light emitting element 240 may be electrically connected to a separate thin film transistor 120 and driven independently. The fourth light emitting element 240 may have a structure in which the pixel electrode 241, the second common auxiliary layer 350, the light emitting layer 242, the first common auxiliary layer 340, and the common electrode 320 are sequentially stacked. Among them, the common electrode 320, the first common auxiliary layer 340, and the second common auxiliary layer 350 may be shared with the first, second, and third light emitting elements 210, 220, and 230, and the light absorption sensor 310. The light emitting layer 242 may emit light of an infrared wavelength spectrum, which may have for example a maximum emission wavelength in a range of greater than or equal to about 750 nm, about 750 nm to about 20 μm, about 780 nm to about 20 μm, about 800 nm to about 20 μm, about 750 nm to about 15 μm, about 780 nm to about 15 μm, about 800 nm to about 15 μm, about 750 nm to about 10 μm, about 780 nm to about 10 μm, about 800 nm to about 10 μm, about 750 nm to about 5 μm, about 780 nm to about 5 μm, about 800 nm to about 5 μm, about 750 nm to about 3 μm, about 780 nm to about 3 μm, about 800 nm to about 3 μm, about 750 nm to about 2 μm, about 780 nm to about 2 μm, about 800 nm to about 2 μm, about 750 nm to about 1.5 μm, about 780 nm to about 1.5 μm, or about 800 nm to about 1.5 μm.
The light absorption sensor 310 may absorb light generated by reflection of light emitted from at least one of the first, second, third, or fourth light emitting elements 210, 220, 230, or 240, by a recognition target 90 such as a living body or a tool, and then convert it into an electrical signal. For example, the light absorption sensor 310 may absorb light in an infrared wavelength spectrum generated by reflection of light emitted from the fourth light emitting element 240, by the recognition target 90, and then convert it into an electrical signal. In this case, the light absorbing layer 330 of the light absorption sensor 310 may include an organic material, an inorganic material, an organic-inorganic material, or any combination thereof that selectively absorbs light in the infrared wavelength spectrum. For example, the light absorbing layer 330 may include a quantum dot, a quinoid metal complex compound, a polymethine compound, a cyanine compound, a phthalocyanine compound, a merocyanine compound, a naphthalocyanine compound, an immonium compound, a diimmonium compound, a triarylmethane compound, a dipyrromethene compound, an anthraquinone compound, a diquinone compound, a naphthoquinone compound, a squarylium compound, a rylene compound, a perylene compound, a squaraine compound, a pyrylium compound, a thiopyrylium compound, a diketopyrrolopyrrole compound, a boron dipyrromethene compound, a nickel-dithiol complex compound, a croconium compound, a derivative thereof, or any combination thereof, but is not limited thereto.
The sensor-embedded display panel 1000 according to some example embodiments includes the fourth light emitting element 240 that emits light in the infrared wavelength spectrum and the light absorption sensor 310 that absorbs light in the infrared wavelength spectrum. Therefore, in addition to the recognition function (biometric recognition function), the sensitivity of the light absorption sensor 310 may be improved even in a low-illumination environment, and the detection capability of a 3D image may be further increased by widening a dynamic range for detailed division of black and white contrast. Accordingly, the sensing capability of the sensor-embedded display panel 1000 may be further improved. In particular, since light in the infrared wavelength spectrum may have a deeper penetration depth due to its long wavelength characteristics and information located at different distances may be effectively obtained, images or changes in blood vessels such as veins, iris and/or face, etc., in addition to fingerprints may be effectively detected, and the scope of application may be further expanded.
In some example embodiments, the light absorption sensor 310 may be provided separately from (e.g., independently of) a sensor-embedded display panel 1000 and/or from any light emitting elements, for example as a separate component of an electronic device. For example, an electronic device, such as the electronic device 2000 shown in
The aforementioned sensor-embedded display panel 1000 may be applied to (e.g., included in) electronic devices such as various display devices. Electronic devices such as display devices may be applied to, for example, mobile phones, video phones, smart phones, smart pads, smart watches, digital cameras, tablet PCs, laptop PCs, notebook computers, computer monitors, wearable computers, televisions, digital broadcasting terminals, e-books, personal digital assistants (PDAs), portable multimedia player (PMP), enterprise digital assistant (EDA), head mounted display (HMD), vehicle navigation, Internet of Things (IoT), Internet of all things (IoE), drones, door locks, safes, automatic teller machines (ATM), security devices, medical devices, or automotive electronic components, but are not limited thereto.
Referring to
An example of a method of recognizing the recognition target 90 in an electronic device 2000 such as a display device may include, for example, driving the first, second, and third light emitting elements 210, 220, and 230 of the sensor-embedded display panel 1000 (or the first, second, third, and fourth light emitting elements 210, 220, 230, and 240) and the light absorption sensor 310 to detect the light reflected by the recognition target 90 among the light emitted from the first, second, and third light emitting elements 210, 220, and 230 (or the first, second, third and fourth light emitting elements 210, 220, 230, and 240), in the light absorption sensor 310; comparing the image of the recognition target 90 stored in advance with the image of the recognition target 90 detected by the light absorption sensor 310; and judging the consistency of the compared images and if they match according to the determination that recognition of the recognition target 90 is complete, turning off the light absorption sensor 310, permitting user's access to the display device, and driving the sensor-embedded display panel 1000 to display an image.
Referring to
The processor 1320 may include one or more articles (e.g., units, instances, etc.) of processing circuitry such as a hardware including logic circuits; a hardware/software combination such as processor-implemented software; or any combination thereof. For example, the processing circuitry may be a central processing unit (CPU), an arithmetic logic unit (ALU), a digital signal processor, a microcomputer, a field programmable gate array (FPGA), System-on-Chip (SoC), a programmable logic unit, a microprocessor, an application-specific integrated circuit (ASIC), and the like. As an example, the processing circuitry may include a non-transitory computer readable storage device. The processor 1320 may control, for example, a display operation of the sensor-embedded display panel 1000 or a sensor operation of the light absorption sensor 310.
The memory 1330 may be a non-transitory computer readable storage medium, such as, for example, as a solid state drive (SSD) and may store an instruction program (e.g., program of instructions), and the processor 1320 may perform a function related to the sensor-embedded display panel 1000 by executing the stored instruction program.
The at least one additional device 1340 may include one or more communication interfaces (e.g., wireless communication interfaces, wired interfaces), user interfaces (e.g., keyboard, mouse, buttons, etc.), power supply and/or power supply interfaces, or any combination thereof.
The units and/or modules described herein may be implemented using hardware constituent elements and software constituent elements. The units and/or modules described herein may include, may be included in, and/or may be implemented by one or more articles of processing circuitry such as a hardware including logic circuits; a hardware/software combination such as processor-implemented software; or any combination thereof. For example, the processing circuitry may be a central processing unit (CPU), an arithmetic logic unit (ALU), a digital signal processor, a microcomputer, a field programmable gate array (FPGA), System-on-Chip (SoC), a programmable logic unit, a microprocessor, an application-specific integrated circuit (ASIC), and the like. For example, the hardware constituent elements may include microphones, amplifiers, band pass filters, audio-to-digital converters, and processing devices. The processing device may be implemented using one or more hardware devices configured to perform and/or execute program code by performing arithmetic, logic, and input/output operations. The processing device may include a processor, a controller and an arithmetic logic unit, a digital signal processor, a microcomputer, a field programmable array, a programmable logic unit, a microprocessor, or any other device capable of responding to and executing instructions. The processing device may access, store, operate, process, and generate data in response to execution of an operating system (OS) and one or more software running on the operating system.
The software may include a computer program, a code, an instruction, or any combination thereof, and may transform a processing device for a special purpose by instructing and/or configuring the processing device independently or collectively to operate as desired. The software and data may be implemented permanently or temporarily as signal waves capable of providing or interpreting instructions or data to machines, parts, physical or virtual equipment, computer storage media or devices, or processing devices. The software may also be distributed over networked computer systems so that the software may be stored and executed in a distributed manner. The software and data may be stored by one or more non-transitory computer readable storage devices.
The method according to the foregoing example embodiments may be recorded in a non-transitory computer readable storage device including program instructions for implementing various operations of the aforementioned example embodiments. The storage device may also include program instructions, data files, data structures, and the like alone or in combination. The program instructions recorded in the storage device may be specially designed for some example embodiments or may be known to those skilled in computer software and available for use. Examples of non-transitory computer-readable storage devices may include magnetic media such as hard disks, floppy disks, and magnetic tapes; optical media such as CD-ROM discs, DVDs and/or blue-ray discs; magneto-optical media such as optical disks; and a hardware device configured to store and execute program instructions such as ROM, RAM, flash memory, and the like. The aforementioned device may be configured to operate as one or more software modules to perform the operations of the aforementioned example embodiments.
Hereinafter, some example embodiments are illustrated in more detail with reference to examples. However, the present scope of the inventive concepts is not limited to these examples.
9.4 g (36.5 mmol) of 2-iodoselenophene and 7.5 g (30.5 mmol) of 1-bromo-9H-carbazole are dissolved in 30 ml of dioxane. Subsequently, 0.29 g (1.52 mmol) of copper (I) Iodide, 0.70 g (6.09 mmol) of trans-1,2-cyclohexanediamine, and 12.9 g (61.0 mmol) of tripotassium phosphate are added thereto and then, heated under reflux for 30 hours. Herein, a product obtained therefrom is separated and purified through silica gel column chromatography (a volume ratio of hexane:ethyl acetate=5:1) to obtain 8.18 g (a yield: 72%) of Compound 1-1A. The above process is repeated to obtain the desired amount.
12.0 g (32.0 mmol) of Compound 1-1A is dissolved in 300 ml of dehydrated diethyl ether. Subsequently, 12 ml (32.0 mmol) of a 2.76 M n-butyl lithium (n-BuLi) hexane solution is added dropwise thereto at −50° C. and then, stirred at room temperature for 1 hour. In addition, 2.0 g (35.2 mmol) of dehydrated acetone (dimethylketone (CH3COCH3)) is added thereto at −50° C. and then, stirred at room temperature for 2 hours. Then, an organic layer extracted from the diethyl ether is washed with a sodium chloride aqueous solution and then, dried by adding anhydrous magnesium sulfate thereto. Herein, a product obtained therefrom is separated and purified through silica gel column chromatography (by changing the volume ratio of hexane:dichloromethane within a range of 100:0 to 50:50) to obtain 6.3 g (a yield: 56%) of Compound 1-1B.
6.23 g (17.6 mmol) of Compound 1-1B is dissolved in 180 ml of dichloromethane. Subsequently, 4.98 g (35.5 mmol) of a boron trifluoride-ethyl ether (BF3·OEt2) complex is added dropwise thereto at 0° C. and then, stirred for 2 hours. Then, an organic layer extracted from the dichloromethane is washed with a sodium chloride aqueous solution and then, dried by adding anhydrous magnesium sulfate thereto. Herein, a product obtained therefrom is separated and purified through silica gel column chromatography (in a volume ratio of hexane:dichloromethane=50:50) to obtain 5.12 g (a yield: 87%) of Compound 1-1C. The above process is repeated to obtain the desired amount.
1.9 ml (20.2 mmol) of phosphoryl chloride is added dropwise to 6.0 ml (77.5 mmol) of N,N-dimethyl formamide (DMF) at −15° C. and then, stirred at room temperature for 2 hours. This solution is slowly added dropwise to 150 ml a dichloromethane solution of 5.23 g (15.5 mmol) of Compound 1-1C at −15° C. and then, concentrated under a low pressure by stirring at room temperature for 30 hours. After adding water thereto, a sodium hydroxide aqueous solution is added thereto until pH becomes 14 and then, stirred at room temperature for 2 hours. Subsequently, an organic layer extracted with the dichloromethane is washed with a sodium chloride aqueous solution and then, dried by adding anhydrous magnesium sulfate thereto. A product obtained therefrom is separated and purified through silica gel column chromatography (in a volume ratio of hexane:dichloromethane=50:50) to obtain 3.34 g (a yield: 65%) of Compound 1-1 D.
1.50 g (4.11 mmol) of Compound 1-1 D is dissolved in 20 ml of tetrahydrofuran, and 0.72 g (4.93 mmol) of 1H-indene-1,3(2H)-dione is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 2.03 g (a yield: 74%) of a compound represented by Chemical Formula 1-1 is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 8.15 (d, 1H), 8.14 (s, 1H), 8.07 (s, 1H), 8.03 (d, 1H), 7.95-7.88 (m, 3H), 7.82-7.77 (m, 2H), 7.72 (td, 1H), 7.45-7.55 (m, 3H), 1.79 (s, 6H).
2.11 g (5.79 mmol) of Compound 1-1 D is dissolved in 50 ml of tetrahydrofuran, 0.82 g (5.25 mmol) of 1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 1.91 g (a yield: 83%) of a compound represented by Chemical Formula 1-2 is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 8.78 (s, 1H), 8.62 (s, 1H), 8.27 (d, 1H), 8.04 (d, 1H), 7.84 (d, 1H), 7.75 (m, 1H), 7.71 (d, 1H), 7.48 (d, 2H), 3.18 (s, 6H), 1.79 (s, 6H).
2.02 g (6.38 mmol) of a compound of 4,4-dimethyl-4H-thieno[3′,2′:5,6]pyrido[3,2,1-jk]carbazole-2-carbaldehyde is dissolved in 50 ml of tetrahydrofuran, and 0.91 g (5.80 mmol) of 1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-trione is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 2.31 g (a yield: 88%) of a compound represented by Chemical Formula 1-3 is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 8.72 (s, 1H), 8.58 (s, 1H), 8.27 (d, 1H), 8.04 (d, 1H), 7.84 (d, 1H), 7.75 (m, 1H), 7.71 (d, 1H), 7.48 (d, 2H), 3.18 (s, 6H), 1.79 (s, 6H).
2.05 g (5.63 mmol) of Compound 1-1 D is dissolved in 50 ml of tetrahydrofuran, and 0.73 g (5.12 mmol) of 1-methylpyrimidine-2,4,6(1H,3H,5H)-trione is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 2.31 g (a yield: 92%) of a compound represented by Chemical Formula 1-4 is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 11.4 (s, 1H) 8.78 (s, 1H), 8.62 (s, 1H), 8.27 (d, 1H), 8.04 (d, 1H), 7.84 (d, 1H), 7.75 (m, 1H), 7.71 (d, 1H), 7.48 (d, 2H), 3.18 (s, 3H), 1.79 (s, 6H).
1.98 g (6.23 mmol) of a compound of 4,4-dimethyl-4H-thieno[3′,2′:5,6]pyrido[3,2,1-jk]carbazole-2-carbaldehyde is dissolved in 50 ml of tetrahydrofuran, and 0.81 g (5.66 mmol) of 1-methylpyrimidine-2,4,6(1H,3H,5H)-trione is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 2.15 g (a yield: 86%) of a compound represented by Chemical Formula 1-5 is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 11.3 (s, 1H), 8.72 (s, 1H), 8.58 (s, 1H), 8.27 (d, 1H), 8.04 (d, 1H), 7.84 (d, 1H), 7.75 (m, 1H), 7.71 (d, 1H), 7.48 (d, 2H), 3.17 (s, 3H), 1.78 (s, 6H).
2.11 g (5.80 mmol) of Compound 1-1 D is dissolved in 50 ml of tetrahydrofuran, and 0.68 g (5.27 mmol) of barbituric acid is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 2.20 g (a yield: 88%) of a compound represented by Chemical Formula 1-6 is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 11.4 (s, 2H) 8.78 (s, 1H), 8.62 (s, 1H), 8.27 (d, 1H), 8.04 (d, 1H), 7.84 (d, 1H), 7.75 (m, 1H), 7.71 (d, 1H), 7.48 (d, 2H), 1.79 (s, 6H).
2.04 g (6.43 mmol) of a compound of 4,4-dimethyl-4H-thieno[3′,2′:5,6]pyrido[3,2,1-jk]carbazole-2-carbaldehyde is dissolved in 50 ml of tetrahydrofuran, and 0.75 g (5.85 mmol) of barbituric acid is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 2.15 g (a yield: 86%) of a compound represented by Chemical Formula 1-7 is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 11.3 (s, 2H), 8.72 (s, 1H), 8.58 (s, 1H), 8.27 (d, 1H), 8.04 (d, 1H), 7.84 (d, 1H), 7.75 (m, 1H), 7.71 (d, 1H), 7.48 (d, 2H), 1.78 (s, 6H).
1.99 g (5.45 mmol) of Compound 1-1 D is dissolved in 50 ml of tetrahydrofuran, 0.78 g (4.96 mmol) of 1-methyl-2-thioxodihydropyrimidine-4,6(1H,5H)-dione is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 2.15 g (a yield: 86%) of a compound represented by Chemical Formula 1-8 is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 11.7 (s, 1H), 8.95 (s, 1H), 8.65 (s, 1H), 8.25 (d, 1H), 8.02 (d, 1H), 7.84 (d, 1H), 7.75 (m, 1H), 7.71 (d, 1H), 7.46 (d, 2H), 3.76 (s, 3H), 1.68 (s, 6H).
1.91 g (6.01 mmol) of a compound of 4,4-dimethyl-4H-thieno[3′,2′:5,6]pyrido[3,2,1-jk]carbazole-2-carbaldehyde is dissolved in 50 ml of tetrahydrofuran, and 0.86 g (5.46 mmol) of 1-methyl-2-thioxodihydropyrimidine-4,6(1H,5H)-dione is added thereto and then, concentrated under a reduced pressure by stirred at 50° C. for 4 hours. Subsequently, 2.15 g (a yield: 86%) of a compound represented by Chemical Formula 1-9 is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 8.72 (s, 1H), 8.58 (s, 1H), 8.25 (d, 1H), 8.02 (d, 1H), 7.84 (d, 1H), 7.75 (m, 1H), 7.71 (d, 1H), 7.46 (d, 2H), 3.76 (s, 6H), 1.68 (s, 6H).
2.08 g (5.03 mmol) of a compound of 4,4-dimethyl-4H-telluropheno[3′,2′:5,6]pyrido[3,2,1-jk]carbazole-2-carbaldehyde is dissolved in 50 ml of tetrahydrofuran, and 0.70 g (4.57 mmol) of 4H-cyclopenta[c]thiophene-4,6(5H)-dione is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 1.9 g (a yield: 76%) of a compound represented by Chemical Formula 1-10 is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 8.72 (s, 1H), 8.58 (s, 1H), 8.22 (d, 1H), 8.01 (d, 1H), 7.99 (s, 2H), 7.82 (d, 1H), 7.72 (m, 1H), 7.69 (d, 1H), 7.44 (d, 2H), 1.68 (s, 6H).
1.85 g (5.08 mmol) of a compound of 12,12-dimethyl-7-phenyl-7,12-dihydrobenzo[a]acridine-3-carbaldehyde is dissolved in 50 ml of tetrahydrofuran, and 0.91 g (4.62 mmol) of 1H-cyclopenta[b]naphthalene-1,3(2H)-dione is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 2.0 g (a yield: 80%) of a compound represented by Chemical Formula 1-1C is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 8.71 (m, 1H), 8.51 (s, 2H), 8.12 (m, 2H), 8.06 (s, 1H), 7.69 (m, 4H), 7.58 (m, 3H), 7.30 (d, 2H), 7.00 (m, 4H), 6.52 (d, 1H), 6.09 (d, 1H), 2.35 (s, 6H).
1.76 g (5.55 mmol) of a compound of 4,4-dimethyl-4H-thieno[3′,2′:5,6]pyrido[3,2,1-jk]carbazole-2-carbaldehyde is dissolved in 50 ml of tetrahydrofuran, and 1.00 g (5.04 mmol) of 1H-cyclopenta[b]naphthalene-1,3(2H)-dione is added thereto and then, concentrated under a reduced pressure by stirring at 50° C. for 4 hours. Subsequently, 2.05 g (a yield: 82%) of a compound represented by Chemical Formula 1-2C is obtained through recrystallization by using chloroform and ethanol. The obtained compound is purified by sublimation to purity of 99.9%.
1H-NMR (300 MHz, Methylene Chloride-d2): δ 8.85 (s, 2H), 8.55 (d, 1H), 8.46 (s, 1H), 8.10 (d, 1H), 7.95-7.50 (m, 10H), 1.79 (s, 6H).
A mixture of 1,4,5,8-naphthalenetetracarboxylic dianhydride (1 eq.) and 4-chloroaniline (2.2 eq.) is dissolved in a dimethyl formamide (DMF) solvent and then, added to a two-necked and round-bottomed flask and stirred at 180° C. for 24 hours. After decreasing the temperature to room temperature, methanol is added thereto to precipitate a product, which is filtered to obtain a powder-type material. The material is several times washed with methanol and purified through recrystallization by using ethyl acetate and dimethylsulfoxide (DMSO). Subsequently, the obtained product is placed in an oven and dried at 80° C. under vacuum for 24 hours to obtain a compound represented by Chemical Formula 2-1. A yield thereof is 50% or more.
1H NMR (300 MHz, CDCl3 with Hexafluoroisopropanol): 5=8.85 (s, 4H), 7.63 (s, 4H), 7.60 (s, 4H).
A compound represented by Chemical Formula 2-2 (Tokyo Chemical Industry) is purified by sublimation, so that it may be used as an n-type semiconductor for a photoelectric device.
Fullerene (C60, nanom purple ST, Frontier Carbon Corp.) is prepared, so that it may be used as an n-type semiconductor for the photoelectric device.
The compounds of Synthesis Examples 1-1 to 1-10 and Comparative Synthesis Examples 1-1C and 1-2C are evaluated with respect to a molecule packing density, a molecular volume, an aspect ratio, and a monolayer absorption coefficient according to a wavelength of each compound. The molecular packing density refers to a molecular density in a deposited film and is calculated by using molecular dynamics (MD) simulations (Desmond software). A morphology of 600 molecules is obtained by forming a morphology in an equilibrium state over 2 ns at 500K, 3 ns at 300K, and 30 ns at 300K by using an NPT ensemble.
The molecular volume is calculated by using a Gaussian 09 program and a Multiwfn program (T. Lu, F. Chen, J. Comput. Chem. 2012, 33, 580.). The aspect ratio is calculated at a DFT B3LYP/DGDZVP level by using the Gaussian 09 program.
The monolayer absorption coefficient is obtained by depositing each compound into a 100 nm-thick single thin film at a deposition temperature (Ts(10)). Herein, a sample of the single thin film is measured with respect to an absorption coefficient by using Cary 5000 UV spectrometer (Varian Medical Systems, Inc.) by irradiating ultraviolet rays-visible rays (UV-Vis) to measure absorbance and dividing it by a thickness of the thin film.
The results are shown in Table 1.
Referring to Table 1, the compounds of Synthesis Examples 1-1 to 1-10 have a high molecular packing density and a small molecular volume and thus a plenty of molecules per unit area and accordingly, may be expected to improve an absorption coefficient. Referring to the absorption coefficient results, the compounds of Synthesis Examples 1-1 to 1-10 exhibit a higher absorption coefficient than those of Comparison Synthesis Examples 1-1C and 1-2C.
Compounds respectively having the structures shown in Tables 2 to 4 are evaluated with respect to molecular packing density in the above method. The compounds shown in Table 2 belong to the compound represented by Chemical Formula 1, the compounds shown in Table 3 belong to the compound represented by Chemical Formula 2, and the compounds shown in Table 4 belong to the compound represented by Chemical Formula 3.
Referring to Tables 2 to 4, Compounds 1a to 1-n belonging to the structure of Chemical Formula 1, Compounds 2-a to 2-n belonging to the structure of Chemical Formula 2, and Compounds 3-a to 3-m belonging to the structure of Chemical Formula 3 exhibit excellent molecule packing density.
The compounds of the synthesis examples and the comparative synthesis examples are evaluated with respect to a sublimation temperature.
The sublimation temperature is evaluated through thermogravimetric analysis (TGA) by measuring a temperature where a weight of each sample decreases by 10% from the initial weight by increasing a temperature under a high vacuum (about 10 Pa or less). The results are shown in Table 5.
* Ts(10) (° C.): A temperature (sublimation temperature) where a weight of each sample decreases by 10% from the initial weight by increasing a temperature under a high vacuum (about 10 Pa or less)
Referring to Table 5, the compounds of Synthesis Examples 1-2 to 1-5 exhibit a lower sublimation temperature than the compound of Comparative Example 1-1C and accordingly, exhibit excellent deposition stability.
Al (10 nm), ITO (100 nm), and Al (8 nm) are sequentially deposited on a glass substrate to form a first electrode (lower electrode) with an Al/ITO/Al structure (work function: 4.9 eV). Subsequently, N,N′-bis(3-methylphenyl)-N,N′-diphenyl-[1,1-biphenyl]-4,4′-diamine is deposited on the first electrode to form a 170 nm-thick hole auxiliary layer (HOMO: 5.6 eV, LUMO: 2.1 eV). Then, the compound (p-type semiconductor) obtained in Synthesis Example 1-1 is deposited to a thickness of 10 nm on the hole auxiliary layer, and then the compound (n-type semiconductor) obtained in Synthesis Example 2-1 is deposited to a thickness of 40 nm to form a bilayer light absorption layer. Then, 4,7-diphenyl-1,10-phenanthroline is deposited on the light absorption layer to form a 36 nm-thick electron auxiliary layer (HOMO: 6.1 eV, LUMO: 3.0 eV). Then, magnesium and silver are deposited on the electron auxiliary layer at a volume ratio of 1:10 to form a 16 nm-thick second electrode (Mg:Ag upper electrode) to manufacture a photoelectric device.
Each photoelectric device according to Examples 1-2A to 1-10A is manufactured in the same manner as in Example 1-1A, except that each of the compounds represented by Chemical Formulas 1-2 to 1-10 according to Synthesis Examples 1-2 to 1-10 is used, instead of the compound represented by Chemical Formula 1-1 according to Synthesis Example 1-1.
Each photoelectric device according to Comparative Examples 1-1CA and 1-2CA is manufactured in the same manner as in Example 1-1A, except that the compound represented by Chemical Formula 1-1C or 1-2C according to Comparative Synthesis Example 1-1C or 1-2C is used, instead of the compound represented by Chemical Formula 1-1 according to Synthesis Example 1-1.
ITO is laminated on a glass substrate through sputtering to form an about 150 nm-thick anode, and the ITO glass substrate is ultrasonic wave-cleaned with acetone/isopropyl alcohol/pure water respectively for 15 minutes and then, UV ozone-cleaned. Subsequently, the compound according to Synthesis Example 1-1 and C60 are codeposited in a volume ratio of 1:1 to form a 100 nm-thick active layer, and ITO is vacuum-deposited to be 7 nm thick to manufacture a photoelectric device having a structure of ITO (150 nm)/active layer (100 nm)/ITO (7 nm).
Each photoelectric device according to Examples 1-2B to 1-10B is manufactured in the same manner as in Example 1-1B, except that each of the compounds represented by Chemical Formulas 1-2 to 1-10 according to Synthesis Examples 1-2 to 1-10 is used, instead of the compound represented by Chemical Formula 1-1 according to Synthesis Example 1-1.
Each photoelectric device according to Comparative Examples 1-1CB and 1-2CB is manufactured in the same manner as in Example 1-1B, except that the compound represented by Chemical Formula 1-1C or 1-2C according to Comparative Synthesis Example 1-1C or 1-2C is used, instead of the compound represented by Chemical Formula 1-1 according to Synthesis Example 1-1.
The external quantum efficiency (EQE) of the photoelectric devices according to Examples 1-1A, 1-2A, 1-4A, 1-5A, and 1-8A and Comparative Examples 1-1 CA and 1-2CA is evaluated. The external quantum efficiency (EQE) is evaluated by using incident photon to current efficiency (IPCE) at a wavelength of 450 nm (blue, B), 530 nm (green, G), and 630 nm (red, R). Among these, the external quantum efficiency measurement results in the green wavelength region are shown in Table 6.
Referring to Table 6, the photoelectric devices according to Examples exhibit improved external quantum efficiency (photoelectric conversion efficiency) in the green wavelength spectrum compared to the photoelectric device according to Comparative Examples.
The external quantum efficiency (EQE) of the photoelectric devices according to Examples 1-1B, 1-2B, 1-4B, 1-5B, and 1-8B and Comparative Example 1-1CB is evaluated. The external quantum efficiency (EQE) is evaluated by using incident photon to current efficiency (IPCE) at a wavelength of 450 nm (blue, B), 530 nm (green, G), and 630 nm (red, R). Among these, the external quantum efficiency measurement results in the green wavelength region are shown in Table 7.
Referring to Table 7, the photoelectric devices according to Examples exhibit improved external quantum efficiency (photoelectric conversion efficiency) in the green wavelength spectrum compared to the photoelectric device according to Comparative Examples.
While the present inventive concepts have been described in connection with what is presently considered to be practical example embodiments, it is to be understood that the inventive concepts are not limited to such example embodiments. On the contrary, the scope of the inventive concepts is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2023-0026302 | Feb 2023 | KR | national |
