Patent Grant
10371023
The invention relates to an engine operating in particular with compressed air, or any other gas, and using a chamber called an “active chamber”.
The invention relates to distribution to the intake of such an engine and more particularly an engine including an included active chamber and notably a multi-mode self-pressure-regulating engine with included active chamber.
The term distribution refers to all of the means used to feed such an engine with compressed gas.
The inventors have filed numerous patents relating to motor drives and their installations, using gases and more particularly compressed air for totally clean operation in urban and suburban sites:
They have notably filed an international patent application WO-A1-03/036088, to the content of which reference can be made, relating to an additional compressed air injection motor-compressor—motor-alternator set operating on a single energy and multiple energies.
In these types of engine operating with compressed air and comprising a compressed air storage tank, it is necessary to expand the compressed air stored at very high pressure in the tank—but whose pressure decreases as the tank empties—to a stable intermediate pressure called final pressure of use, in a buffer vessel—called working vessel—before it is used in the drive cylinder or cylinders of the engine.
To solve the pressure regulator problems, the inventors have also filed a patent application WO-A1-03/089764, to the content of which reference can be made, relating to a variable throughput dynamic pressure regulator and a distribution for engines fed with compressed air injection, comprising a high-pressure compressed air tank and a working vessel.
In the operation of these “load relieving” engines, the filling of the expansion chamber always represents an expansion without work that is detrimental to the overall efficiency of the machine.
To solve the above problem, the inventors then filed a patent application WO-A1-2005/049968 describing a compressed air engine preferentially fed with compressed air or any other compressed gas contained in a storage tank at high pressure, previously expanded to a nominal working pressure in a buffer vessel called working vessel.
According to the teachings of WO-A1-2005/049968 in this type of engine:
The expansion chamber of the engine according to this invention actively participates in the work. The engine is thus called “active chamber” engine.
The document WO-A1-2005/049968 notably teaches a thermodynamic cycle in four phases during its operation in compressed air single-energy mode characterized by:
The document WO-A1-2008/028881, which presents a variant of the teachings of the document WO-A1-2005/049968, teaches the same thermodynamic cycle but using a conventional connecting rod and crank device, the expansion chamber of the engine according to the invention actively participating in the work.
The inventors then filed a patent application for a compressed air or gas engine with included active chamber which implements the same thermodynamic cycle as the engines according to the teachings of WO-A1-2005/049968 and WO-A1-2008/028881 as well as a conventional connecting rod and crank device.
According to the teachings of the document WO-A1-2012/045693, the inventors have proposed an included active chamber engine comprising at least one piston mounted to slide in a cylinder and driving a crankshaft by means of a conventional connecting rod and crank device and operating according to a thermodynamic cycle with four phases comprising:
Preferentially fed with compressed air, or any other compressed gas, contained in a storage tank at high pressure, through a buffer vessel called working vessel which is fed by compressed air or any other compressed gas contained in a storage tank at high pressure, which is expanded at an average pressure called working pressure in a working vessel, preferentially via a dynamic pressure-regulating device, in which:
The volume of the included active chamber CA and the volume of the expansion chamber CD are dimensioned in such a way that at the nominal operating pressure of the engine the pressure at the end of expansion at the bottom dead center point is close to the ambient pressure, notably atmospheric pressure. The volume of the active chamber is determined by the closure of the intake.
Advantageously, and notably in compressed air single-energy operation, the included active chamber engine described above includes a plurality of successive cylinders of increasing cubic capacity.
Preferentially the engine is fed in a manner after the teachings of the documents WO-A1-2005/049968 and WO-A1-2008/028881, by compressed air or by any other compressed gas contained in a storage tank at high pressure, previously expanded to a nominal working pressure in a buffer vessel called working vessel.
However, even if it is possible in the case of an engine with a plurality of stages to feed the first of the cylinders at high pressures, it is still necessary to expand the air compressed at very high pressure contained in the storage tank at high pressure to a nominal working pressure and this expansion operation either provokes a loss of efficiency through the use of a conventional pressure regulator or, with the use of the teachings of WO-A1-03/089764, incurs no energy cost, but this expansion does not make it possible to perform any expansion work between the high pressure contained in the tank and the nominal working pressure in the constant volume working vessel.
The inventors then filed a new patent application WO-A1-2012/045694 to the content of which reference can be made that claims an included active chamber compressed air engine in which:
The engine according to WO-A1-2012/045694 serves also as pressure regulator, the invention thus making it possible to propose a so-called “self-pressure-regulating” engine which requires no independent pressure regulator, regardless of its type, to feed the active chamber CA.
The multi-mode self-pressure-regulating engine with included active chamber according to the teachings of the document WO-A1-2012/045694 notably implements, when in its operation in compressed air single-energy mode, a thermodynamic cycle with three phases including:
In the operation of this engine, the volume, varying as a function of the pressure of the high-pressure storage tank, of the included active chamber determines the quantity of compressed air injected. The higher the intake pressure, the smaller the volume of the active chamber has to be.
In order to obtain correct operation in all phases of use of the engine it is therefore necessary to feed it with great accuracy as a function of various parameters including the speed or rotation speed, the intake pressure, the load determined by the position of the accelerator, the temperature.
To this end, it is necessary to be able to vary:
The difficulty lies in producing means for opening and closing the intake of compressed air into the included active chamber that make it possible not only to open the intake orifice and duct substantially at the top dead center point of the travel of the piston but also to modify the intake duration and/or angular sector as well as the passage section of the opening.
The distribution of engines of all types is generally provided by valves the operation of which is well known. A valve blocks the intake and/or exhaust duct and includes a valve head pressed by springs onto a circular valve seat formed around a orifice putting the intake duct and/or exhaust duct into communication with the combustion chamber and/or expansion chamber contained in the cylinder.
The valve head opens the circuit by penetrating into the chamber to be fed when moved by mechanical systems of cams and cam-followers acting on the stem of the valve that extends the head of the valve.
In other engine fields and for other technical reasons notably concerning pollution reduction and with the aim of controlling the intake and exhaust of conventional internal combustion engines, many engine manufacturers are working on systems making it possible to control the phasing and the duration of valve opening during operation and have filed numerous patents concerning those applications. Complex mechanical systems driven by electric stepper motors have also been developed and put onto the market, notably by BMW (registered trade mark) with the so-called “Vamos” device.
The inventors have also filed patent application WO-A1-03/089764 to the content of which reference may be made relating to distribution via progressively controlled valves.
Much work has been undertaken on electromechanical devices, notably controlled by solenoids that are easy to control so as to take into account the various operating parameters, but the electrical powers that have to be deployed to make possible the acceleration and the speed of movement of the valves are considerable, given their weight and inertia.
The invention, notably suitable for active chamber compressed air engines, and notably included active chamber multi-mode self-pressure-regulating engines, proposes to solve all of the problems referred to above whilst producing an increase in power.
The intake active distribution device according to the invention applied to compressed air engines uses the compressed air contained in the high-pressure storage tank and/or in the intake circuit to move the intake valve in order to open and then to close the intake duct enabling feeding of the active chamber of the engine, the compressed air having been used to perform these actions thereafter being re-used in the engine to produce additional work.
The invention proposes an active chamber engine operating according to a three-phase thermodynamic cycle including:
According to other features of the invention:
i) opening of the active distribution valve to put the closure chamber in communication with the active chamber to cause the closing of the intake valve and then, during the expansion phase, to enable the expansion of the compressed gas contained in the closure chamber into the expansion chamber of the cylinder, producing work that is added to the work of the charge of gas under pressure previously admitted into the active chamber via the intake duct;
ii) at the end of the expansion phase, reclosing of the active distribution valve to maintain in the interior of the closure chamber the pressure of the expanded gas the value of which is close to that of atmospheric pressure;
k1) at the end of the exhaust phase, when the piston is substantially at the top dead center point of its travel, opening said valve to make it possible to establish in the active chamber a pressure identical to that in the intake duct and to cause the intake valve to lift off its seat;
k2) the intake valve then travels its complete opening travel under the action of the differential pressure forces exerted by the gas under pressure on the corresponding parts of the intake valve;
k3) closing said valve as soon as the intake valve opens;
j) opening the active distribution valve to put the closure chamber in communication with the active chamber to put the closure chamber in communication with the expansion chamber of the cylinder to enable the expansion of the compressed gas contained in the closure chamber into the expansion chamber of the cylinder, producing work that is added to the work of the charge of gas under pressure previously admitted into the active chamber;
jj) at the end of the expansion phase, reclosing the active distribution valve to maintain in the interior of the closure chamber a pressure the value of which is close to that of atmospheric pressure;
Other aims, advantages and features of the invention will become apparent on reading the non-limiting description of a number of embodiments given in light of the appended drawings in which:
Description of
There has been represented in
The engine includes at least one cylinder 1, only one of which is represented, which is fed with a gas under pressure, preferably with compressed air, contained in a high-pressure storage tank 12.
The engine includes a piston 2 that is mounted to slide in this cylinder 1 and a crankshaft 5 that is driven by the piston 2 by means of a conventional connecting rod and crank device 3, 4.
The volume of the engine cylinder 1 that is swept by the piston 2 is divided along an imaginary line DD′ (corresponding to a dividing plane orthogonal to the axis of the cylinder) into two parts: a first part constituting the active chamber CA, which is therefore included in the cylinder 1, and a second part constituting the expansion chamber CD.
The engine further includes a cylinder head 6 that closes the volume of the cylinder 1 that is swept by the piston 2 at the top.
The cylinder head 6 includes at least one intake duct 8 that is connected to the tank 12 and in which flows the flow of gas under pressure for filling the cylinder, an intake orifice 7 for the gas under pressure above the piston 2.
The cylinder head further includes at least one exhaust orifice and one exhaust duct (not represented).
The cylinder head 6 is such that, when the piston 2 is at its top dead center point, the residual volume contained between the piston 2 and the cylinder head 6 is, by construction, reduced to just the minimum gaps enabling contactless operation between the piston 2 and the cylinder head 6.
The cylinder head 6 includes at least one intake valve 9, one of which is shown, that cooperates in a sealed manner with a valve seat 20 that is formed in the cylinder head 6 and defines the intake orifice 7.
In known manner, in such an engine:
The torque and the speed of the engine are controlled by controlling the opening and closing of the intake valve 9, making it possible to open the intake valve 9 substantially at the top dead center point of the travel of the piston (which is vertical according to the orientation in the figure), and making it possible, by closing the valve 9, to modify the intake duration and/or angular sector, as well as the passage section of the intake orifice in order, as a function of the pressure of the gas contained in the storage tank 12 and the pressure at the end of the expansion phase, to define the quantity of gas under pressure admitted and the volume of the active chamber CA.
The intake duct 8 is directly connected to the high-pressure tank 12 which therefore feeds the active chamber CA directly and is at the same pressure as the tank.
The pressure in the intake duct 8 is identical to that of the storage tank 12, for example of the order of 100 bar, and is greater than that in the active chamber CA and the expansion chamber CD, for example equal to 1.5 bar at the moment of the cycle corresponding to the bottom dead center point of the piston at the end of expansion just before the exhaust valve opens.
According to the invention, the intake valve 9 is mounted to be mobile so as to move in axial displacement between a low closing position (considering the vertical general orientation of the figures and without reference to terrestrial gravity)—represented in
In its opening direction, the intake valve 9 moves axially—upward, in the direction opposite to that of the flow of the flow F of gas under pressure for filling the cylinder. The intake valve therefore opens in the opposite direction to the flow of air under pressure for filling the cylinder of the engine.
In its closed position, the intake valve 9 is held closed in autoclave fashion on its valve seat 20 by the pressure in the intake duct 8 and applied to the intake valve, i.e. to the head of the valve inside the intake duct 8.
The engine includes means for commanding opening of the intake valve 9 substantially at the top dead center point of the travel of the piston to cause the intake valve 9 to be lifted off its seat 20 and to make it possible to establish in the active chamber a pressure equal to that in the intake duct 8.
During its opening phase, the valve therefore travels its entire opening travel under the action of the differential pressure forces exerted by the gas under pressure on the corresponding parts of the intake valve and notably on the head of the valve, i.e. on the one hand on the lower surface 22 of disk shape subjected to the pressure in the cylinder 1 and on the other hand on the upper surface 24 subjected to the pressure in the intake duct 8, the difference between the areas of these two surfaces substantially corresponding to the area of the section of the stem 26 of the valve 9.
In its closed position, the intake valve 9 is held on its seat 20 in autoclave fashion by the pressure of the compressed air contained in the intake circuit and/or in the compressed air storage tank 12, the pressure in the active chamber CA and the expansion chamber CD of the engine being lower during the expansion and exhaust phases of operation.
The engine includes a pneumatic actuator V for closing the intake valve 9 which, by way of nonlimiting example, is here arranged in the cylinder head 6.
The actuator V includes an actuator cylinder 100 and a closure piston 102 that is connected to move axially with the stem 26 of the intake valve 9 and that is mounted to slide in the actuator cylinder 100 inside which it defines in a sealed manner an upper chamber 104 called closure chamber of the actuator of the valve 9.
The engine has an active distribution channel X1 that connects the closure chamber 104 to the upper part of the active chamber CA included in the cylinder 1.
The high maximum open position of the intake valve 9 is defined by an adjustable stop 30 that extends into the chamber 104 and the axial position in the axial direction of movement of the valve is controlled (by means not represented in the figures) to vary the flow rate of gas under pressure admitted into the cylinder via the intake duct. The controlled adjustable stop therefore serves as a “butterfly valve” controlled by an accelerator. The movements of the stop are produced and controlled by an electric stepper motor, for example.
The adjustable stop 30 makes it possible to stop the automatic upstroke of the intake valve 9 by modifying its lift as a function of required operating parameters of the engine.
The engine includes a control valve Y for blocking the circulation of the gas in the active distribution channel X1, called active distribution valve Y, opening of which may be commanded to put the chamber 104 for closing the intake in communication with the upper part of the active chamber CA by establishing in the closure chamber 104 a complementary pressure on the upper face of the piston 102, the action of this piston pushing the intake valve 9 onto its seat 20 and therefore closing the intake circuit and thereby terminating the work of the active chamber CA.
The active distribution valve Y is then held open during the expansion time, allowing the compressed gas contained in the closure chamber 104 to expand conjointly with the gas contained in the expansion chamber, producing work that is added to the work of the charge of gas under pressure previously admitted into the active chamber via the intake duct.
The engine includes a channel X2 for controlling the opening of the intake valve 9 that connects the upper part of the active chamber CA to the intake duct 8.
The engine includes a controlled valve Z for blocking the circulation of the gas into the channel X2, called intake valve opening valve, opening of which may be commanded to put the upper part of the active chamber CA in communication with the intake duct 8.
When the piston 2 of the engine is close to its top dead center point (
For example, for a 20 mm diameter valve controlled by a 6 mm valve stem, the lower area is equal to 3.14 cm2 and the upper area is equal to 2.86 cm2 (3.14−0.28), a thrust of 28 kg is exerted to open the intake valve 9 automatically and to allow the filling of the active chamber CA.
The intake valve 9 is then closed by putting the active chamber CA in communication with the closure chamber 104 thereby creating a complementary pressure on the upper surface of the piston 102 of the closing actuator V that then pushes the intake valve 9 onto its seat 20 and closes/blocks the intake to enable the expansion cycle from the active chamber CA into the expansion chamber CD.
As soon as expansion begins (
Accordingly, in the context of the invention, the valve Y is an active distribution valve and the channel X1 is an active distribution channel.
At the end of expansion, the communication between the active chamber and the expansion chamber of the cylinder and the closure chamber 104 is again blocked, maintaining in the latter a pressure close to atmospheric pressure, enabling a new cycle.
The operation of the so-called active distribution according to the invention is now clear, the energy necessary for opening and closing the intake valve 9 advantageously being provided by the pressure in the storage tank and/or the intake circuit (opening) and in the active chamber (closing) and then being re-used to produce additional work in the cylinder.
The volume of the closure chamber 104 is small, by way of nonlimiting example less than 10% of the cubic capacity of the cylinder 1.
The same applies in respect of the channels connecting the intake and the active chamber and the closure chamber 104 to the expansion chamber CD, the passage sections of which are calculated to allow a sufficient flow rate to establish the pressures in the various chambers.
These various channels have small diameters, for example of the order of 0.5 to 2 millimeters for a main intake duct of the order of 20 millimeters.
Valves Y and Z of the electromechanical type will preferably be used, preferably in the form of appropriate solenoid valves easily controlled by an electronic management unit (not represented).
Moreover control by an electronic management unit and pneumatic drive makes possible speeds of opening and of closing of the valve or valves and angular control phases of great accuracy.
In the operating cycle of the active distribution described above the volume of air contained in the closure chamber is expanded conjointly with that of the active chamber and ignoring the head losses on going from the nominal pressure to the exhaust pressure.
Description of
The following description is given by way of comparison with the embodiment described above with reference to
The previous design is completed by an additional channel X3 that connects the intake duct 8 to the closure chamber 104 of the actuator V.
The engine also includes a controlled valve T for blocking the circulation of the gas, of the compressed air, in the channel X3, the opening of which may be commanded to put the intake duct 8 and/or the tank 12 in communication with the closure chamber 104.
Thus the closure chamber 104 has at least two ducts X3 and X1 each including controlled blocking means T and Y making it possible to put the closure chamber 104 successively in communication with on the one hand the intake circuit and/or the high-pressure storage tank 12 and on the other hand the active and expansion chamber of the cylinder.
The intake valve 9 is closed by putting the intake circuit and/or the storage tank in communication with the closure chamber 104 via the channel X3 and by commanding opening of the valve T, thereby creating a complementary pressure on the surface of the closure piston 102 that pushes the intake valve 9 onto its seat 20 and closes the intake to allow the cycle of expansion from the active chamber CA into the expansion chamber CD.
Thus the active expansion from the closure chamber 104 can be delayed to occur later in the cycle by controlling opening of the valve Y.
As soon as expansion begins or during expansion the volume of the closure chamber 104 is put in communication with the expansion chamber CD and the compressed air contained in the closure chamber 104 expands into the expansion chamber CD producing work that is added to the work of expansion of the charge admitted into the active chamber CA.
At substantially the end of expansion, the communication between the active and expansion chamber of the engine and the closure chamber 104 is again blocked, maintaining in the latter a pressure close to atmospheric pressure allowing a new cycle.
Description of
The following description is given by way of comparison with the first embodiment shown in
According to this embodiment there are provided mechanical means (rather than pneumatic means) for causing the intake valve 9 to be lifted off its seat 20 that act directly on the head of the intake valve 9.
The opening of the intake valve 9 is advantageously simplified by the integration of such a mechanical device in the case of an engine that has to operate at substantially constant rotation speeds and therefore necessitates no variation of the calibration of the intake opening.
To this end, said means for controlling opening of the intake valve 9 consist of a finger D or plunger upstanding on the upper face of the piston (2) and that extends vertically upwards, facing the facing head of the intake valve 9.
By virtue of its arrangement and its dimensions, the finger D controlling opening is able to cooperate mechanically with the lower face 20 of the head of the intake valve 9 to push the latter vertically upwards.
It is during the end of the travel of the piston toward its top dead center point that the finger D acts via the intake orifice on the facing portion of the lower face 22 of the head of the intake valve 9 to lift it from its seat.
The finger D is positioned in line with the lower part of the head of the intake valve so that it raises the intake valve slightly, creating a leak that puts the intake circuit in communication with the active chamber CA, establishing in the closure chamber 104 a complementary pressure on the upper surface of the piston 102 and, by the action of the piston 102 connected to the stem of the valve, pushing the intake valve 9 onto its seat 20, thus closing the intake circuit and terminating the work of the active chamber CA.
The valve then travels its complete opening travel under the action of the differential pressure forces exerted by the gas under pressure on the corresponding parts of the intake valve 9.
After the intake valve opens and the expansion cycle begins, because of the descent of the piston 2 the finger D no longer acts on the intake valve 9 and the remainder of the cycle is identical to that described with reference to
Description of
The following description is given by way of comparison with the second embodiment shown in
The arrangement of the channel X2 and of the associated valve Z controlling opening of the intake valve is modified.
The actuator V is a double-acting actuator with two sealed chambers separated by the piston 102.
The lower chamber 105 is a chamber controlling opening of the intake valve 9 which is connected via the channel X2 to the intake duct 8 and/or to the tank 12 of gas under pressure.
Thus the closure chamber 104 has at least two ducts X3 and X1 each including blocking control means T, Y making it possible to put the closure chamber 104 successively in communication with on the one hand the intake circuit and/or the high-pressure storage tank 12 and on the other hand the active and expansion chamber of the cylinder.
The opening of the intake valve 9 is commanded by the valve Z which feeds the lower chamber 105 of the actuator V, which is an opening chamber, with gas under pressure.
The intake valve 9 is closed by putting the intake circuit and/or the storage tank in communication with the closure chamber 104 via the channel X3 and by commanding opening of the valve T, thereby creating a complementary pressure on the surface of the closure piston 102 that pushes the intake valve 9 onto its seat 20 and closes the intake to allow the cycle of expansion from the active chamber CA into the expansion chamber CD.
The closure is obtained by virtue of the fact that the area of the piston 102 subjected to the pressure is higher on the side of the chamber 104 than on the side of the opening chamber 105 (the difference substantially corresponding to the area of the section of the stem of the intake valve).
The active expansion from the closure chamber can therefore be delayed to occur later in the cycle by controlling the opening of the valve Y.
As soon as expansion begins or during expansion the volume of the closure chamber 104 is then put in communication with the expansion chamber CD and the compressed air contained in the closure chamber 104 expands into the expansion chamber producing work that is added to the work of expansion of the charge admitted into the active chamber.
At substantially the end of expansion the communication between the active and expansion chamber of the engine and the closure chamber 104 is again blocked by maintaining in the latter a pressure close to atmospheric pressure allowing a new cycle.
According to this design, the piston 102 of the actuator V successively commands opening and closing of the intake valve 9.
According to a variant, not represented, it is possible, as for the chamber 104, to connect the chamber 105 to the active chamber thanks to a channel X1′ and a valve Y′, thereby producing two parallel active distribution circuits.
The volumes of the closure chamber 104 and the opening chamber 105 can then be put in communication with the expansion chamber and the compressed air that is contained therein expands into the expansion chamber making it possible to increase the work of expansion of the admitted charge on expanding into the main drive cylinder.
Because of the flexibility of utilization and of the virtually unlimited adjustment possibilities, the engine equipped with the “active” intake distribution according to the invention may be used on all terrestrial, maritime, rail, aeronautical vehicles. The active chamber engine according to the invention may also and advantageously find an application in standby generator sets, likewise in numerous domestic cogeneration electricity, heating and air conditioning applications.
The active chamber engine according to the invention has been described with operation with compressed air. However, it may use any compressed gas/gas at high pressure without this departing from the field of the claimed invention.
The invention is not limited to the embodiments described and represented: the materials, control means, devices described may vary within the limit of equivalence to produce the same results. The number of engine cylinders, their cubic capacity, the maximum volume of the active chamber relative to the displaced volume of the cylinder(s) and the number of expansion stages may vary.
| Number | Date | Country | Kind |
|---|---|---|---|
| 14 54603 | May 2014 | FR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2015/060855 | 5/18/2015 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2015/177076 | 11/26/2015 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 213435 | Cameron | Mar 1879 | A |
| 896439 | Criner | Aug 1908 | A |
| 920991 | Perrault | May 1909 | A |
| 955786 | Frear | Apr 1910 | A |
| 1942711 | Ernest | Jan 1934 | A |
| 3410304 | Paul, Jr. | Nov 1968 | A |
| 7377249 | Dingle | May 2008 | B1 |
| 20040261415 | Negre et al. | Dec 2004 | A1 |
| 20050224059 | Negre et al. | Oct 2005 | A1 |
| 20070101712 | Negre et al. | May 2007 | A1 |
| 20080251041 | Lou | Oct 2008 | A1 |
| 20090211546 | Hedman | Aug 2009 | A1 |
| 20100282225 | Gilbert | Nov 2010 | A1 |
| 20110277711 | Gonigman et al. | Nov 2011 | A1 |
| 20130167520 | Negre et al. | Jul 2013 | A1 |
| 20130239563 | Negre et al. | Sep 2013 | A1 |
| Number | Date | Country |
|---|---|---|
| 1 042 607 | Nov 1958 | DE |
| 20 2005 017 622 | Jan 2006 | DE |
| 10 2009 052 385 | May 2011 | DE |
| 03036088 | May 2003 | WO |
| 2005049968 | Jun 2005 | WO |
| 2008028881 | Mar 2008 | WO |
| 2009023080 | Feb 2009 | WO |
| 2012045693 | Apr 2012 | WO |
| 2012045694 | Apr 2012 | WO |
| 03089764 | Oct 2013 | WO |
| Entry |
|---|
| International Search Report, dated Nov. 27, 2015, from corresponding PCT Application. |
| Number | Date | Country | |
|---|---|---|---|
| 20170211435 A1 | Jul 2017 | US |
