Compression molding of synthetic wood material

Information

  • Patent Grant
  • 6180257
  • Patent Number
    6,180,257
  • Date Filed
    Tuesday, October 29, 1996
    28 years ago
  • Date Issued
    Tuesday, January 30, 2001
    24 years ago
Abstract
A system of compression molding a synthetic wood formulation into a commercially useable synthetic wood component is described. Surprising results are achieved when the dry formulation is placed under heat and pressure. Many different components may be made using the present invention, such as by example, wood-like trim components for the housing construction industry.
Description




BACKGROUND AND SUMMARY OF THE INVENTION




The present invention relates generally to wood replacement materials. In particular, the present invention relates to a wood-polymer composite material suitable for use in place of natural wood. The present invention describes a process for manufacturing the composite materials.




For several reasons, there is a need to find materials that exhibit the look and feel of natural wood. One reason has to do with the supply of good wood for construction purposes from the world's forest. This supply of wood from mature trees has become an important issue in recent years and as a result the cost of wood has risen.




Several attempts have been made by others to find a wood like material. Many of these efforts have failed due to the qualities of the resultant product.




In addition to natural wood, other materials such as particle board, wafer board, and the like may be replaced by the synthetic wood of the present invention. One noticeable improvement over these materials is that synthetic wood has enhanced moisture resistance.




The present invention overcomes many of the disadvantages of the prior art attempts at a quality wood replacement material that is capable of being produced in a commercially practicable production environment. The present invention includes the combining of cellulosic material with a thermoplastic material and optionally with a cross-linking agent to form a combined product.




In the present invention conventional compression molding equipment is used to fuse the combined product under sufficient conditions to blend the combined product into a homogeneous mixture and a completed useable synthetic wood material component.




In a preferred material composition of the present invention, the synthetic wood material includes approximately two-thirds organic fibrous or cellulosic material and approximately one-third thermoplastic material in combination. The resultant product has an appearance similar to wood and may be sawed, sanded, shaped, turned, fastened and/or finished in the same manner as natural wood. The resultant product is resistant to rot and decay as well as termite attack. The resultant product may be used for example as, decorative moldings inside or outside of a house, picture frames, furniture, porch decks, window moldings, window components, door components, roofing systems, and any other type of use where structural requirements do not exceed the physical properties of the resultant material.




More particularly, in a preferred embodiment of the present invention, it is useful in conjunction with the synthetic wood composition and method as described in U.S. Pat. No. 15 5,516,472 which issued on May 14, 1996, entitled EXTRUDED SYNTHETIC WOOD COMPOSITION AND METHOD FOR MAKING SAME.











BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

is a schematic diagram illustrating the process of the present invention;





FIG. 2

is a schematic representation of a first embodiment of a resultant product of the present invention; and





FIG. 3

is a schematic representation of a second embodiment of a resultant product of the present invention.











DETAILED DESCRIPTION OF PREFERRED EMBODIMENT(S)




The present invention is directed toward synthetic wood compositions of the type in which synthetic wood material composites are compression molded.




The cellulosic fibrous-polymer composite material used in the present invention may have a higher cellulosic fiber content then normally recognized. The overall process may include the mixing of raw materials including cellulosic fibers, thermoplastic materials, cross-linking agents and process lubricants. The cellulosic material may be any one or more cellulosic materials such as sawdust, newspapers, alfalfa, wheat pulp, wood chips, wood fibers, wood particles, ground wood, wood flour, wood flakes, wood veneers, wood laminates, paper, cardboard, straw, cotton, rice hulls, coconut shells, peanut shells, bagass, plant fibers, bamboo or palm fiber, and kenaf Cellulosic material is first dried to a low moisture content. Although apparently not critical a preferred moisture content is about 1%-10%.




Thermoplastic materials may include multilayer films, polyethylene, polypropylene, polyvinyl chloride (PVC), low density polyethylene (LDPE), ethyl-vinyl acetate, other polyethylene copolymers and other thermoplastics.




Examples of cross-linking agents include polyurethanes, such as isocynate, phenolic resins, unsaturated polyesters and epoxy resins and combinations of the same. Lubricants may be added as a process aid. Examples of lubricants include zinc stearate or wax. Other materials may be added which are known to the art and include accelerators, inhibitors, enhancers, compatibilizers and blowing agents.




Two example formulation recipes are described below:


















Amount (parts per total)



























Recipe A








Wood Flour (40/mesh maple)




250







Polyethylene (HDPE)




100







Zinc Stearate




7.5







External Wax




5







Phenolic Resin




15







Isocyanate (MDI)




2.5







Recipe B







Wood Flour (40/mesh maple)




250







PVC




100







Lubricant (ester)




3







External Wax




4







Process Aids (acrylic)




4







Calcium Stearate




2







Tin Stabilizer




2















In the preferred embodiment of the present invention, as shown in

FIG. 1

, the cellulosic fiber, thermoplastic raw materials, and other minor ingredients are physically mixed or blended by any simple or conventional mixing or blending device. The preferred process temperature at the compression mold is about 350° F. Several well known compression molding machines may be used in the present invention.




The composition achieved surprising results when it was compression molded to form flat boards or other three dimensional shapes. The powder blended composition was placed in a compression mold under heat and pressure to form a three dimensional shaped article as shown in FIG.


2


.




The compression molding device into which the composition is loaded includes one or more mold cavities, a hydraulic press, temperature controls, and cooling features.




As shown in

FIG. 3

, an optional film or sheet layer may be added to adhere to the wood composite material to provide a different aesthetic and functional surface appearance. The compatible films or sheets may include such weatherable polymer films as PVC, CPVC, S-RPVC, fluoropolymer, acrylic, and acrylic-fluoropolymer alloys appropriately selected to match compatibility with the substrate wood-like composite material. These films may naturally adhere to the compression molded composite substrate when compressed onto the substrate while in the compression mold under the temperature and pressure provided by the compression mold process, or they may be later secured to the substrate by using adhesives or compatibilizers such as EVA, EMA, and caprolactone for example.




EXAMPLE




48″×120″ synthetic wood boards were compression molded on a 4000 ton Dominion slab-sided Hydraulic press which was manufactured around 1955. The platen dimensions of the press were 3″×62″×148″.




The loose material was loaded by weight into a ¾″ sheet mold which was lined with a ¾″ thick wooden frame. The height of the frame was between 2 to 2.375 inches. The area inside the wooden frame was 50″×124″.




The material was loaded in the mold and distributed evenly (leveled) in the mold by the use of a straight bar which is indexed equally off the sides of the mold so as to provide an even distribution.




A flat aluminum plate (lid) was placed on top of the synthetic wood material and the mold was loaded into an unheated press.




The press was closed to a line pressure of 700 PSI, and the operating temperature was set at 350° F.




The molds were heated for (1) hour and (5) minutes including the heat-up time. (Heat-up time would be approximately 25 minutes.) After the heat cycle, the press was cooled for approximately one hour and the sheets were done.




Below is a summary of some pertinent facts:




Inside dimension of mold: ¾″×51.5″×125.5″




Mold dimension inside wooden frame: 50″×124″




Weight loaded: 203 lbs. per mold




Height of wooden frame: Approximately 2″




Height of leveled pile before processing: 2.7″




Compressed thickness of finished sheet: 0.903″-0.911″




Total length of heat cycle including 25 minute heat-up period: 1 hour—5 minutes.




Processing temperature: 350° F.




Internal temperature of the material at the end of the heat cycle: 330° F.




Processing pressure: 700 PSI line pressure for the entire heat and cool phase of the cycle.




Processing pressure on the work (specific pressure): 355 PSI




Length of cool cycle: Approximately 1 hour.




Press used: Dominion. 4000 ton slab-sided hydraulic press. Manufacture approximately 1955.




Platen size: 3″×62″×148″




Bulk density of the loose material was: 21 lbs./ft.


3






Density of the finished product was: 62.4 lbs./ft.


3






The above described advantages and features of the present invention are offered as an example of the way in which the present invention may be commercially implemented. The embodiments listed herein are, therefore, exemplary in nature and are not intended to unnecessarily limit the scope of the following claims.



Claims
  • 1. A method of manufacturing an article, said method comprising:drying at least one cellulosic material to a desired moisture content; mixing said at least one cellulosic material with at least one thermoplastic material and optional additives to form a composition, said composition comprised of 50% to 70% by weight of said at least one cellulosic material, 20% to 40% by weight of said at least one thermoplastic material, and 0% to 30% by weight of said additives; and compression molding said composition to form said article.
  • 2. The method of claim 1 wherein said compression molding is performed at a line pressure of about 700 pounds per square inch.
  • 3. The method of claim 2 wherein said compression molding includes a heating phase.
  • 4. The method of claim 3 wherein said compression molding is performed during said heating phase at a temperature of about 350 degrees Fahrenheit after an initial heat-up period.
  • 5. The method of claim 3 wherein said heating phase lasts about 65 minutes.
  • 6. The method of claim 3 wherein said compression molding includes a cooling phase that follows said heating phase.
  • 7. The method of claim 6 wherein said cooling phase lasts about 60 minutes.
  • 8. The method of claim 1 wherein said compression molding includes a heating phase.
  • 9. The method of claim 8 wherein said compression molding is performed during said heating phase at a temperature of about 350 degrees Fahrenheit after an initial heat-up period.
  • 10. The method of claim 8 wherein said heating phase lasts about 65 minutes.
  • 11. The method of claim 8 wherein said compression molding includes a cooling phase that follows said heating phase.
  • 12. The method of claim 11 wherein said cooling phase lasts about 60 minutes.
  • 13. The method of claim 1 wherein said additives are selected from the group consisting of cross-linking agents, lubricants, accelerators, inhibitors, enhancers, compatibilizers, and blowing agents.
US Referenced Citations (154)
Number Name Date Kind
2188396 Semon Jan 1940
2489373 Gilman Nov 1949
2519442 Delorme et al. Aug 1950
2558378 Petry Jun 1951
2635976 Meiler et al. Apr 1953
2680102 Becher Jun 1954
2789903 Lukman et al. Apr 1957
2935763 Newman et al. May 1960
3287480 Wechsler et al. Nov 1966
3308218 Wiegand et al. Mar 1967
3309444 Schueler Mar 1967
3492388 Inglin-Kn{umlaut over (u)}sel Jan 1970
3493527 Schueler Feb 1970
3562373 Logrippo Feb 1971
3645939 Gaylord Feb 1972
3671615 Price Jun 1972
3864201 Susuki et al. Feb 1975
3867493 Seki Feb 1975
3878143 Baumann et al. Apr 1975
3879505 Boutillier et al. Apr 1975
3888810 Shinomura Jun 1975
3899559 Johnanson et al. Aug 1975
3922328 Johnson Nov 1975
3931384 Forquer et al. Jan 1976
3943079 Hamed Mar 1976
3954555 Kole et al. May 1976
3956541 Pringle May 1976
3956555 McKean May 1976
3969459 Fremont et al. Jul 1976
4005162 Bucking Jan 1977
4012348 Chelland et al. Mar 1977
4016232 Pringle Apr 1977
4016233 Pringle Apr 1977
4018722 Baker Apr 1977
4029831 Daunheimer Jun 1977
4045603 Smith Aug 1977
4056591 Goettler et al. Nov 1977
4058580 Flanders Nov 1977
4071479 Broyde et al. Jan 1978
4071494 Gaylord Jan 1978
4097648 Pringle Jun 1978
4102106 Golder et al. Jul 1978
4107110 Lachowicz et al. Aug 1978
4115497 Halmø et al. Sep 1978
4145389 Smith Mar 1979
4157415 Lindenberg Jun 1979
4168251 Schinzel et al. Sep 1979
4178411 Cole et al. Dec 1979
4181764 Totten Jan 1980
4187352 Klobbie Feb 1980
4191798 Schumacher et al. Mar 1980
4203876 Dereppe et al. May 1980
4228116 Colombo et al. Oct 1980
4239679 Rolls et al. Dec 1980
4241133 Lund et al. Dec 1980
4244903 Schnause Jan 1981
4248743 Goettler Feb 1981
4248820 Haataja Feb 1981
4250222 Mavel et al. Feb 1981
4263184 Leo et al. Apr 1981
4263196 Schumacher et al. Apr 1981
4272577 Lyng Jun 1981
4273688 Porzel et al. Jun 1981
4277428 Luck et al. Jul 1981
4290988 Nopper et al. Sep 1981
4303019 Haataja et al. Dec 1981
4305901 Prince et al. Dec 1981
4317765 Gaylord Mar 1982
4323625 Coran et al. Apr 1982
4376144 Goettler Mar 1983
4382108 Carroll et al. May 1983
4382758 Nopper et al. May 1983
4393020 Li et al. Jul 1983
4414267 Coran et al. Nov 1983
4420351 Lussi et al. Dec 1983
4430468 Schumacher Feb 1984
4440708 Haataja et al. Apr 1984
4480061 Coughlin et al. Oct 1984
4491553 Yamada et al. Jan 1985
4503115 Hemels et al. Mar 1985
4505869 Nishibori Mar 1985
4506037 Suzuki et al. Mar 1985
4508595 G{dot over (a)}sland Apr 1985
4562218 Fornadel et al. Dec 1985
4594372 Natov et al. Jun 1986
4597928 Terentiev et al. Jul 1986
4610900 Nishibori Sep 1986
4645631 Hegenstaller et al. Feb 1987
4659754 Edwards et al. Apr 1987
4663225 Farley et al. May 1987
4687793 Motegi et al. Aug 1987
4717742 Beshay Jan 1988
4734236 Davis Mar 1988
4737532 Fujita et al. Apr 1988
4769109 Tellvik et al. Sep 1988
4769274 Tellvik et al. Sep 1988
4783493 Motegi et al. Nov 1988
4789604 van der Hoeven Dec 1988
4790966 Sandberg et al. Dec 1988
4791020 Kokta Dec 1988
4801495 van der Hoeven Jan 1989
4818604 Tock Apr 1989
4820749 Beshay Apr 1989
4851458 Hopperdietzel Jul 1989
4865788 Davis Sep 1989
4889673 Takimoto Dec 1989
4894192 Warych Jan 1990
4915764 Miani Apr 1990
4927572 van der Hoeven May 1990
4927579 Moore May 1990
4935182 Ehner et al. Jun 1990
4960548 Ikeda et al. Oct 1990
4968463 Levasseur Nov 1990
4973440 Tamura et al. Nov 1990
4978489 Radvan et al. Dec 1990
4988478 Held Jan 1991
5002713 Palardy et al. Mar 1991
5008310 Beshay Apr 1991
5009586 Pallmann Apr 1991
5049334 Bach Sep 1991
5057167 Gersbeck Oct 1991
5064592 Ueda et al. Nov 1991
5075057 Hoedl Dec 1991
5075359 Castagna et al. Dec 1991
5078937 Eela Jan 1992
5082605 Brooks et al. Jan 1992
5087400 Theuveny Feb 1992
5088910 Goforth et al. Feb 1992
5096046 Goforth et al. Mar 1992
5096406 Brooks et al. Mar 1992
5120776 Raj et al. Jun 1992
5153241 Beshay Oct 1992
5194461 Bergquist et al. Mar 1993
5219634 Aufderhaar Jun 1993
5272000 Chenoweth et al. Dec 1993
5276082 Forry et al. Jan 1994
5288772 Hon Feb 1994
5302634 Mushovic Apr 1994
5369147 Mushovic Nov 1994
5406768 Giuseppe et al. Apr 1995
5422170 Iwata et al. Jun 1995
5435954 Wold Jul 1995
5474722 Woodhams Dec 1995
5480602 Nagaich Jan 1996
5486553 Deaner et al. Jan 1996
5497594 Giuseppe et al. Mar 1996
5516472 Laver May 1996
5518677 Deaner et al. May 1996
5532065 G{umlaut over (u)}bitz Jul 1996
5537789 Minke et al. Jul 1996
5539027 Deaner et al. Jul 1996
5576374 Betso et al. Nov 1996
5585155 Heikklia et al. Dec 1996
5593625 Riebel et al. Jan 1997
Foreign Referenced Citations (17)
Number Date Country
2042176 Apr 1971 DE
4403373 Sep 1973 DE
3801574 Jan 1988 DE
40 33 849 A1 Oct 1990 DE
42 21 070 A1 Dec 1993 DE
0 269 470 A2 Jan 1988 EP
93306845 Aug 1993 EP
93306843 Aug 1993 EP
93306844 Aug 1993 EP
74 06548 Feb 1974 FR
76 28288 Sep 1976 FR
79 10288 Apr 1979 FR
84 07466 May 1984 FR
82 23635 Aug 1982 GB
86 04589 Feb 1986 GB
87 02959 Feb 1987 GB
PCTSE9000014 Jan 1990 WO
Non-Patent Literature Citations (29)
Entry
Bibliography of Solid Phase Extrusion, pp. 187-195, 1984.
Dalv{umlaut over (a)}g et al., The Efficiency of Cellulosic Fillers in Common Thermoplastics. Part II. Filling with Processing Aids and Coupling Agents, 1985, vol. 11, pp. 9-38.
Fiberloc Polymer Composites , B.F. Goodrich, Geon Vinyl Division, section 1, pp. 2-15, 1985.
Henrici-Oliv{acute over (e)} et al., “Integral/Structural Polymer Foams: Technology, Properties and Applications” Springer-Verlag, Berlin, pp. 111-112, 1983.
Klason et al., The Efficiency of Cellulosic Fillers in Common Thermoplastics. Part I. Filling without Processing Aids or Coupling Agents, Polymeric Materials, 1984, vol. 10, pp. 159-187.
Kokta et al., Composites of Poly(Vinyl Chloride) and Wood Fibers. Part II: Effect of Chemical Treatment, Polymer Composites, Apr. 1990, pp. 84-89.
Kokta et al., Composites of Polyvinyl Chloride-Wood Fibers. I. Effect of Isocyanate as a Bonding Agent, Polym.-Plast. Technol. Eng., 1990, 29(1&2), pp. 87-118.
Kokta et al., Composites of Polyvinyl Chloride-Wood Fibers. III: Effect of Silane as Coupling Agent, Journal of Vinyl Technology, Sep. 1990, pp. 146-153.
Kokta et al., Use of Grafted Wood Fibers in Thermoplastic Composites v. Polystyrene, Centre de recherche en p{circumflex over (a)}tes et papiers, Universit{acute over (e)} du Qu{acute over (e)}bec {grave over (a)} Trois-Rivi{grave over (e)}res, Canada, 1982.
Kokta et al., Use of Wood Fibers in Thermoplastic Composites, Polymer Composites, Oct. 1983, pp. 229-232.
Maldas et al., Composites of Polyvinyl Chloride-Wood Fibers: IV. Effect of the Nature of Fibers, Journal of Vinyl Technology, Jun. 1989, pp. 90-98.
Myers et al., Bibliography: Composites from Plastics and Wood-Based Fillers, USDA Forest Products Laboratory, Madison, WI, pp. 1-27 odds (1991).
Myers et al., Effects of Composition and Polypropylene Melt Flow on Polypropylene-Waste Newspaper Composites, ANTEC, 1984, pp. 602-604.
Myers et al., “Wood flour and polypropylene or high-density polyethylene composites: influence of maleated polypropylene concentration and extrusion temperature on properties”, “Wood Fiber-Polymer Composites: Fundamental Concepts, Processes, and Material Options ”, pp. 49-56, 1983.
Raj et al., Use of Wood Fiber as Filler in Common Thermoplastics: Studies on Mechanical Properties, Science and Engineering of Composite Materials, vol. 1 No. 3, 1989, pp. 85-98.
Raj et al., Use of Wood Fibers in Thermoplastics. VII. The Effect of Coupling Agents in Polyethylene-Wood Fiber Composites, Journal of Applied Polymer Science, vol. 37, pp. 1089-1103 (1989).
Rogalski et al., Poly(Vinyl-Chloride) Wood Fiber Composites, ANTEC, 1987, pp. 1436-1441.
Sonwood: a new PVC wood-flour alloy for Extrusions and other Plastic Processing Techniques, Sonesson Plast AB, Malmo, Sweden, 1986.
Sonwood Outline, Apr., 1975.
Thomas et al., Wood Fibers for Reinforcing Fillers for Polyolefins, ANTEC, 1984, pp. 687-689.
Woodhams et al., Wood Fibers for Reinforcing Fillers for Polyolefins, Polymer Engineering and Science, Oct. 1984, pp. 1166-1171.
Yam et al., Composites from Compounding Wood Fibers With Recycled High Density Polyethylene, Polymer Engineering and Science, mid-Jun. 1990, pp. 693-699.
Zadorecki et al., Future Prospects for Wood Cellulose as Reinforcement In Organic Polymer Composites, Polymer Composites, Apr. 1989, pp. 69-77.
Pornnimit et al., Extrusion of Self-Reinforced Polyethylene, Advances in Polymer Technology, vol.11, No. 2, pp. 92-98.
Bendtsen et al., Mechanical Properties of Wood, pp. 4-2 to 4-44, 1986.
Brzoskowski et al., Air-Lubricated Die for Extrusion of Rubber Compounds, Rubber Chemistry and Technology, vol. 60, pp. 945-956, 1985.
Collier et al., High Strength Extrudates by Melt Transformation Coextrusion, ANTEC, 1987, pp. 497-502.
Collier et al., Streamlined Dies and Profile Extursion, ANTEC, 1987, pp. 203-206.
Techno Material, Techno Material Co., Ltd., 1988.