Compression molding of synthetic wood material

Information

  • Patent Grant
  • 6511757
  • Patent Number
    6,511,757
  • Date Filed
    Tuesday, November 14, 2000
    24 years ago
  • Date Issued
    Tuesday, January 28, 2003
    21 years ago
Abstract
A system of compression molding a synthetic wood formulation into a commercially useable synthetic wood component is described. Surprising results are achieved when the dry formulation is placed under heat and pressure. Many different components may be made using the present invention, such as by example, wood-like trim components for the housing construction industry.
Description




BACKGROUND AND SUMMARY OF THE INVENTION




The present invention relates generally to wood replacement materials. In particular, the present invention relates to a wood-polymer composite material suitable for use in place of natural wood. The present invention describes a process for manufacturing the composite materials.




For several reasons, there is a need to find materials that exhibit the look and feel of natural wood. One reason has to do with the supply of good wood for construction purposes from the world's forest. This supply of wood from mature trees has become an important issue in recent years and as a result the cost of wood has risen.




Several attempts have been made by others to find a wood like material. Many of these efforts have failed due to the qualities of the resultant product.




In addition to natural wood, other materials such as particle board, wafer board, and the like may be replaced by the synthetic wood of the present invention. One noticeable improvement over these materials is that synthetic wood has enhanced moisture resistance.




The present invention overcomes many of the disadvantages of the prior art attempts at a quality wood replacement material that is capable of being produced in a commercially practicable production environment. The present invention includes the combining of cellulosic material with a thermoplastic material and optionally with a cross-linking agent to form a combined product.




In the present invention conventional compression molding equipment is used to fuse the combined product under sufficient conditions to blend the combined product into a homogeneous mixture and a completed useable synthetic wood material component.




In a preferred material composition of the present invention, the synthetic wood material includes approximately two-thirds organic fibrous or cellulosic material and approximately one-third thermoplastic material in combination. The resultant product has an appearance similar to wood and may be sawed, sanded, shaped, turned, fastened and/or finished in the same manner as natural wood. The resultant product is resistant to rot and decay as well as termite attack. The resultant product may be used for example as, decorative moldings inside or outside of a house, picture frames, furniture, porch decks, window moldings, window components, door components, roofing systems, and any other type of use where structural requirements do not exceed the physical properties of the resultant material.




More particularly, in a preferred embodiment of the present invention, it is useful in conjunction with the synthetic wood composition and method as described in U.S. Pat. No. 5,516,472 which issued on May 14, 1996, entitled EXTRUDED SYNTHETIC WOOD COMPOSITION AND METHOD FOR MAKING SAME.











BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

is a schematic diagram illustrating the process of the present invention;





FIG. 2

is a schematic representation of a first embodiment of a resultant product of the present invention; and





FIG. 3

is a schematic representation of a second embodiment of a resultant product of the present invention.











DETAILED DESCRIPTION OF PREFERRED EMBODIMENT(S)




The present invention is directed toward synthetic wood compositions of the type in which synthetic wood material composites are compression molded.




The cellulosic fibrous-polymer composite material used in the present invention may have a higher cellulosic fiber content then normally recognized. The overall process may include the mixing of raw materials including cellulosic fibers, thermoplastic materials, cross-linking agents and process lubricants. The cellulosic material may be any one or more cellulosic materials such as sawdust, newspapers, alfalfa, wheat pulp, wood chips, wood fibers, wood particles, ground wood, wood flour, wood flakes, wood veneers, wood laminates, paper, cardboard, straw, cotton, rice hulls, coconut shells, peanut shells, bagass, plant fibers, bamboo or palm fiber, and kenaf. Cellulosic material is first dried to a low moisture content. Although apparently not critical a preferred moisture content is about 1%-10%. Thermoplastic materials may include multilayer films, polyethylene, polypropylene, polyvinyl chloride (PVC), low density polyethylene (LDPE), ethyl-vinyl acetate, other polyethylene copolymers and other thermoplastics.




Examples of cross-linking agents include polyurethanes, such as isocynate, phenolic resins, unsaturated polyesters and epoxy resins and combinations of the same. Lubricants may be added as a process aid. Examples of lubricants include zinc stearate or wax. Other materials may be added which are known to the art and include accelerators, inhibitors, enhancers, compatibilizers and blowing agents.


















Amount (parts per total)



























Recipe A








Wood Flour (40/mesh maple)




250







Polyethylene (HDPE)




100







Zinc Stearate




7.5







External Wax




5







Phenolic Resin




15







Isocyanate (MDI)




2.5







Recipe B







Wood Flour (40/mesh maple)




250







PVC




100







Lubricant (ester)




3







External Wax




4







Process Aids (acrylic)




4







Calcium Stearate




2







Tin Stabilizer




2















In the preferred embodiment of the present invention, as shown in

FIG. 1

, the cellulosic fiber, thermoplastic raw materials, and other minor ingredients are physically mixed or blended by any simple or conventional mixing or blending device. The preferred process temperature at the compression mold is about 350° F. Several well known compression molding machines may be used in the present invention.




The composition achieved surprising results when it was compression molded to form flat boards or other three dimensional shapes. The powder blended composition was placed in a compression mold under heat and pressure to form a three dimensional shaped article as shown in FIG.


2


.




The compression molding device into which the composition is loaded includes one or more mold cavities, a hydraulic press, temperature controls, and cooling features.




As shown in

FIG. 3

, an optional film or sheet layer may be added to adhere to the wood composite material to provide a different aesthetic and functional surface appearance. The compatible films or sheets may include such weatherable polymer films as PVC, CPVC, S-RPVC, fluoropolymer, acrylic, and acrylic-fluoropolymer alloys appropriately selected to match compatibility with the substrate wood-like composite material. These films may naturally adhere to the compression molded composite substrate when compressed onto the substrate while in the compression mold under the temperature and pressure provided by the compression mold process, or they may be later secured to the substrate by using adhesives or compatibilizers such as EVA, EMA, and caprolactone for example.




EXAMPLE




48″×120″ synthetic wood boards were compression molded on a 4000 ton Dominion slab-sided Hydraulic press which was manufactured around 1955. The platen dimensions of the press were 3″×62″×148″.




The loose material was loaded by weight into a ¾″ sheet mold which was lined with a ¾″ thick wooden frame. The height of the frame was between 2 to 2.375 inches. The area inside the wooden frame was 50″×124″.




The material was loaded in the mold and distributed evenly (leveled) in the mold by the use of a straight bar which is indexed equally off the sides of the mold so as to provide an even distribution.




A flat aluminum plate (lid) was placed on top of the synthetic wood material and the mold was loaded into an unheated press.




The press was closed to a line pressure of 700 PSI, and the operating temperature was set at 350° F.




The molds were heated for (1) hour and (5) minutes including the heat-up time. (Heat-up time would be approximately 25 minutes.) After the heat cycle, the press was cooled for approximately one hour and the sheets were done.




Below is a summary of some pertinent facts:




Inside dimension of mold: ¾″×51.5″×125.5″




Mold dimension inside wooden frame: 50″×124″




Weight loaded: 203 lbs. per mold




Height of wooden frame: Approximately 2″




Height of leveled pile before processing: 2.7″




Compressed thickness of finished sheet: 0.903″-0.911″




Total length of heat cycle including 25 minute heat-up period: 1 hour-5 minutes.




Processing temperature: 350° F.




Internal temperature of the material at the end of the heat cycle: 330° F.




Processing pressure: 700 PSI line pressure for the entire heat and cool phase of the cycle.




Processing pressure on the work (specific pressure): 355 PSI




Length of cool cycle: Approximately 1 hour.




Press used: Dominion. 4000 ton slab-sided hydraulic press. Manufacture approximately 1955.




Platen size: 3″×62″X148″




Bulk density of the loose material was: 21 lbs./ft.


3






Density of the finished product was: 62.4 lbs./ft.


3






The above described advantages and features of the present invention are offered as an example of the way in which the present invention may be commercially implemented. The embodiments listed herein are, therefore, exemplary in nature and are not intended to unnecessarily limit the scope of the following claims.



Claims
  • 1. A method of manufacturing an article, said method comprising:providing a mixture comprising about 50% to about 70% by weight of at least one cellulosic material, about 20% to about 40% by weight of at least one thermoplastic material, and 0% to about 30% by weight of additives; and compression molding said mixture said to form said article.
  • 2. The method of claim 1 wherein said compression molding is performed at a line pressure of about 700 pounds per square inch.
  • 3. The method of claim 2 wherein said compression molding includes a heating phase.
  • 4. The method of claim 3 wherein said compression molding is performed during said heating phase at a temperature of about 350 degrees Fahrenheit after an initial heat-up period.
  • 5. The method of claim 3 wherein said heating phase lasts about 65 minutes.
  • 6. The method of claim 3 wherein said compression molding includes a cooling phase that follows said heating phase.
  • 7. The method of claim 6 wherein said cooling phase lasts about 60 minutes.
  • 8. The method of claim 1 wherein said compression molding includes a heating phase.
  • 9. The method of claim 8 wherein said compression molding is performed during said heating phase at a temperature of about 350 degrees Fahrenheit after an initial heat-up period.
  • 10. The method of claim 8 wherein said heating phase lasts about 65 minutes.
  • 11. The method of claim 8 wherein said compression molding includes a cooling phase that follows said heating phase.
  • 12. The method of claim 11 wherein said cooling phase lasts about 60 minutes.
  • 13. The method of claim 1 wherein said additives are selected from the group consisting of cross-linking agents, lubricants, accelerators, inhibitors, enhancers, compatibilizers, and blowing agents.
  • 14. The method of claim 1, wherein said at least one cellulosic material is wood flour.
  • 15. The method of claim 1, wherein said at least one thermoplastic material is polyethylene.
  • 16. The method of claim 1, wherein said at least one thermoplastic material is PVC.
  • 17. The method of claim 1, further comprising securing a weatherable polymer film to said article.
  • 18. The method of claim 17, wherein said weatherable polymer film is PVC.
  • 19. The method of claim 17, wherein said weatherable polymer film is fluoropolymer.
  • 20. The method of claim 17, wherein said weatherable polymer film is adhered to said article with the use of a polymer tie layer.
  • 21. The method of claim 17 wherein said weatherable polymer film is compressed onto said article during said compression molding.
Parent Case Info

This application is a continuation of U.S. patent application Ser. No. 08/739,416 filed Oct. 29, 1996, now U.S. Pat. No. 6,180,257.

US Referenced Citations (155)
Number Name Date Kind
2188396 Semon Jan 1940 A
2489373 Gilman Nov 1949 A
2519442 Delorme et al. Aug 1950 A
2558378 Petry Jun 1951 A
2635976 Meiler et al. Apr 1953 A
2680102 Becher Jun 1954 A
2789903 Lukman et al. Apr 1957 A
2935763 Newman et al. May 1960 A
3287480 Wechsler et al. Nov 1966 A
3308218 Etal Mar 1967 A
3309444 Schueler Mar 1967 A
3492388 Inglin-Knüsel Jan 1970 A
3493527 Schueler Feb 1970 A
3562373 Logrippo Feb 1971 A
3645939 Gaylord Feb 1972 A
3671615 Price Jun 1972 A
3864201 Susuki et al. Feb 1975 A
3867493 Seki Feb 1975 A
3878143 Baumann et al. Apr 1975 A
3879505 Boutillier et al. Apr 1975 A
3888810 Shinomura Jun 1975 A
3899559 Johnanson et al. Aug 1975 A
3922328 Johnson Nov 1975 A
3931384 Forquer et al. Jan 1976 A
3943079 Hamed Mar 1976 A
3954555 Kole et al. May 1976 A
3956541 Pringle May 1976 A
3956555 McKean May 1976 A
3969459 Fremont et al. Jul 1976 A
4005162 Bucking Jan 1977 A
4012348 Chelland et al. Mar 1977 A
4016232 Pringle Apr 1977 A
4016233 Pringle Apr 1977 A
4018722 Baker Apr 1977 A
4029831 Daunheimer Jun 1977 A
4045603 Smith Aug 1977 A
4056591 Goettler et al. Nov 1977 A
4058580 Flanders Nov 1977 A
4071479 Broyde et al. Jan 1978 A
4071494 Gaylord Jan 1978 A
4097648 Pringle Jun 1978 A
4102106 Golder et al. Jul 1978 A
4107110 Lachowicz et al. Aug 1978 A
4115497 Halmø et al. Sep 1978 A
4145389 Smith Mar 1979 A
4157415 Lindenberg Jun 1979 A
4168251 Schinzel et al. Sep 1979 A
4178411 Cole et al. Dec 1979 A
4181764 Totten Jan 1980 A
4187352 Klobbie Feb 1980 A
4191798 Schumacher et al. Mar 1980 A
4203876 Dereppe et al. May 1980 A
4228116 Colombo et al. Oct 1980 A
4239679 Rolls et al. Dec 1980 A
4241133 Lund et al. Dec 1980 A
4244903 Schnause Jan 1981 A
4248743 Goettler Feb 1981 A
4248820 Haataja Feb 1981 A
4250222 Mavel et al. Feb 1981 A
4263184 Leo et al. Apr 1981 A
4263196 Schumacher et al. Apr 1981 A
4272577 Lyng Jun 1981 A
4273688 Porzel et al. Jun 1981 A
4277428 Luck et al. Jul 1981 A
4290988 Nopper et al. Sep 1981 A
4303019 Haatja et al. Dec 1981 A
4305901 Prince et al. Dec 1981 A
4317765 Gaylord Mar 1982 A
4323625 Coran et al. Apr 1982 A
4376144 Goettler Mar 1983 A
4382108 Carroll et al. May 1983 A
4382758 Nopper et al. May 1983 A
4393020 Li et al. Jul 1983 A
4414267 Coran et al. Nov 1983 A
4420351 Lussi et al. Dec 1983 A
4430468 Schumacher Feb 1984 A
4440708 Haataja et al. Apr 1984 A
4480061 Coughlin et al. Oct 1984 A
4491553 Yamada et al. Jan 1985 A
4503115 Hemels et al. Mar 1985 A
4505869 Nishibori Mar 1985 A
4506037 Suzuki et al. Mar 1985 A
4508595 Gåsland Apr 1985 A
4562218 Fornadel et al. Dec 1985 A
4594372 Natov et al. Jun 1986 A
4597928 Terentiev et al. Jul 1986 A
4610900 Nishibori Sep 1986 A
4645631 Hegenstaller et al. Feb 1987 A
4659754 Edwards et al. Apr 1987 A
4663225 Farley et al. May 1987 A
4687793 Motegi et al. Aug 1987 A
4717742 Beshay Jan 1988 A
4734236 Davis Mar 1988 A
4737532 Fujita et al. Apr 1988 A
4769109 Tellvik et al. Sep 1988 A
4769274 Tellvik et al. Sep 1988 A
4783493 Motegi et al. Nov 1988 A
4789604 van der Hoeven Dec 1988 A
4790966 Sandberg et al. Dec 1988 A
4791020 Kokta Dec 1988 A
4801495 van der Hoeven Jan 1989 A
4818604 Tock Apr 1989 A
4820749 Beshay Apr 1989 A
4851458 Hopperdietzel Jul 1989 A
4865788 Davis Sep 1989 A
4889673 Takimoto Dec 1989 A
4894192 Warych Jan 1990 A
4915764 Miani Apr 1990 A
4927572 van der Hoeven May 1990 A
4927579 Moore May 1990 A
4935182 Ehner et al. Jun 1990 A
4960548 Ikeda et al. Oct 1990 A
4968463 Levasseur Nov 1990 A
4973440 Tamura et al. Nov 1990 A
4978489 Radvan et al. Dec 1990 A
4988478 Held Jan 1991 A
5002713 Palardy et al. Mar 1991 A
5008310 Beshay Apr 1991 A
5009586 Pallmann Apr 1991 A
5049334 Bach Sep 1991 A
5057167 Gersbeck Oct 1991 A
5064592 Ueda et al. Nov 1991 A
5075057 Hoedl Dec 1991 A
5075359 Castagna et al. Dec 1991 A
5078937 Eela Jan 1992 A
5082605 Brooks et al. Jan 1992 A
5087400 Theuveny Feb 1992 A
5088910 Goforth et al. Feb 1992 A
5096046 Goforth et al. Mar 1992 A
5096406 Brooks et al. Mar 1992 A
5120776 Raj et al. Jun 1992 A
5153241 Beshay Oct 1992 A
5194461 Bergquist et al. Mar 1993 A
5219634 Aufderhaar Jun 1993 A
5272000 Chenoweth et al. Dec 1993 A
5276082 Forry et al. Jan 1994 A
5288772 Hon Feb 1994 A
5302634 Mushovic Apr 1994 A
5369147 Mushovic Nov 1994 A
5406768 Giuseppe et al. Apr 1995 A
5422170 Iwata et al. Jun 1995 A
5435954 Wold Jul 1995 A
5474722 Woodhams Dec 1995 A
5480602 Nagaich Jan 1996 A
5486553 Deaner et al. Jan 1996 A
5497594 Giuseppe et al. Mar 1996 A
5516472 Laver May 1996 A
5518677 Deaner et al. May 1996 A
5532065 Gübitz Jul 1996 A
5537789 Minke et al. Jul 1996 A
5539027 Deaner et al. Jul 1996 A
5576374 Betso et al. Nov 1996 A
5585155 Heikklia et al. Dec 1996 A
5593625 Riebel et al. Jan 1997 A
6180257 Brandt et al. Jan 2001 B1
Foreign Referenced Citations (17)
Number Date Country
2042176 Apr 1971 DE
4403373 Sep 1973 DE
3801574 Jan 1988 DE
40 33 849 Oct 1990 DE
42 21 070 Dec 1993 DE
0 269 470 Jan 1988 EP
93306843.9 Aug 1993 EP
93306844.7 Aug 1993 EP
93306845.4 Aug 1993 EP
74 06548 Feb 1974 FR
76 28288 Sep 1976 FR
79 10288 Apr 1979 FR
84 07466 May 1984 FR
82 23635 Aug 1982 GB
86 04589 Feb 1986 GB
87 02959 Feb 1987 GB
PCTSE9000014 Jan 1990 WO
Non-Patent Literature Citations (29)
Entry
Bibliography of Solid Phase Extrusion, pp. 187-195.
Dalväg et al., The Efficiency of Cellulosic Fillers in Common Thermoplastics. Part II. Filling with Processing Aids and Coupling Agents, 1985, vol. 11, pp. 9-38.
Fiberloc Polymer Composites, B.F. Goodrich, Geon Vinyl Division, section 1, pp. 2-15.
Henrici-Oliv{acute over (e )} et al., “Integral/Structural Polymer Foams: Technology, Properties and Applications” Springer-Verlag, Berlin, pp. 111-122.
Klason et al., The Efficiency of Cellulosic Fillers in Common Thermoplastics. Part 1. Filling without Processing Aids or Coupling Agents, Polymeric Materials, 1984, vol. 10, pp. 159-187.
Kokta et al., Composites of Poly(Vinyl Choride) and Wood Fibers. Part II: Effect of Chemical Treatment, Polymer Composites, Apr. 1990, pp. 84-89.
Kokta et al., Composites of Polyvinyl Chloride-Wood Fibers. I. Effect of Isocyanate as a Bonding Agent, Polym.-Plast. Technol. Eng., 1990, 29(1&2), pp. 87-118.
Kokta et al., Composites of Polyvinyl Chloride-Wood Fibers. III: Effect of Silane as Coupling Agent, Journal of Vinyl Technology, Sep. 1990, pp. 146-153.
Kokta et al., Use of Grafted Wood Fibers in Thermoplastic Composites v. Polystyrene, Centre de recherche en pâtes et papiers. Universiti{acute over (e )} du Québec {grave over (a )} Trois-Riviéres, Canada.
Kokta et al., Use of Wood Fibers in Thermoplastic Composites, Polymer Composites, Oct. 1983, pp. 229-232.
Maldas et al., Composites of Polyvinyl Chloride-Wood Fibers; IV. Effect of the Nature of Fibers, Journal of Vinyl Technology, Jun. 1989, pp. 90-98.
Myers et al., Bibliography: Composites from Plastics and Wood-Based Fillers, USDA Forest Products Laboratory, Madison, WI, pp. 1-27 odds (1991).
Myers et al., Effects of Composition and Polypropylene Melt Flow on Polypropylene-Wasted Newspaper Composites, ANTEC, 1984, pp. 602-604.
Myers et al., “Wood flour and polypropylene or high-density polyethylene composites: influence of maleated polypropylene concentration and extrusion temperature on properties”, “Wood Fiber/Polymer Composites: Fundamental Concepts, Processes, and Material Options”, pp. 49-56.
Raj et al., Use of Wood Fiber as Filler in Common Thermoplastics: Studies on Mechanical Properties, Science and Engineering of Composite Materials, vol. 1, No. 3, 1989, pp. 85-98.
Raj et al., Use of Wood Fibers in Thermoplastics. VII. The Effect of Coupling Agents in Polyethylene-Wood Fiber Composites, Journal of Applied Polymer Science, vol. 37, pp. 1089-1103 (1989).
Rogalski et al., Poly(Vinyl-Chloride) Wood Fiber Composites, ANTEC, 1987, pp. 1436-1441.
Sonwood: a new PVC wood-flour alloy for Extrusions and other Plastic Processing Techniques: Sonesson Plast AB, Malmo, Sweden.
Sonwood Outline, Apr. 1975.
Thomas et al., Wood Fibers for Reinforcing Fillers for Polyolefins, ANTEC, 1984, pp. 687-689.
Woodhams et al., Wood Fibers for Reinforcing Fillers for Polyolefins, Polymer Engineering and Science, Oct. 1984, pp. 1166-1171.
Yam et al., Composites from Compounding Wood Fibers With Recycled High Density Polyethylene, Polymer Engineering and Science, mid-Jun. 1990, pp. 693-699.
Zadorecki et al., Future Prospects for Wood Cellulose as Reinforcement In Organic Polymer Composites, Polymer Composites, Apr. 1989, pp. 69-77.
Pornnimit et al., Extrusion of Self-Reinforced Polyethylene, Advances in Polymer Technology, vol. 11, No. 2, pp. 92-98.
Bendtsen et al., Mechanical Properties of Wood, pp. 4-2 to 4-44.
Brzoskowski et al., Air-Lubricated Die for Extrusion of Rubber Compounds, Rubber Chemistry and Technology, vol. 60, p. 945-956.
Collier et al., High Strength Extrudates in Melt Transformation Coextrusion, ANTEC, 1987, pp. 497-502.
Collier et al., Streamlined Dies and Profile Extrusion, ANTEC, 1987, pp. 203-206.
Techno Material, Techno Material Co., Ltd.
Continuations (1)
Number Date Country
Parent 08/739416 Oct 1996 US
Child 09/712118 US