Patent Grant
10115497
This application is the national phase entry of International Application No. PCT/CN2015/071228, filed on Jan. 21, 2015, which is based upon and claims priority to Chinese Patent Application No. 201410563543.4, filed on Oct. 22, 2014, the entire contents of which are incorporated herein by reference.
The present invention, which discloses a compressive graphene hydrogel and a preparation method thereof, belongs to the field of nanometer materials and electrochemistry and electrochemical field.
Graphene is a one-atom-thick planar sheet of sp2-bonded carbon atoms that are densely packed in a honeycomb lattice, It is considered to be the basic unit to construct other dimension SP2 carbon materials. The unique structure of graphene enabled a large specific surface, good electrical conductivity and excellent chemical stability, which has aroused extensive research. It is easy for graphene sheets to agglomerate because of the π-π interactions. Therefore, it is very meaningful to construct three-dimensional graphene macroscopic material with single graphene. In 2010, Gaoquan Shi and others first prepared graphene hydrogel by hydrothermal method (ACS Nano, 2010, 4, 4324-4330). It is worth noting that the mechanical properties of pure graphene hydrogels are poor, which can't meet the requirements of practical applications. Therefore, it is important to improve the physical and mechanical properties of the hydrogel.
Phytic acid is a kind of green environmental protection organic acid which exists widely in nature, easy to form a stable structure between molecules, and whose six membered ring structure has good stability, good electrical conductivity and strong complexing ability. The invention adopted the hydrothermal method, which was used as a coupling agent between the graphene sheets, can avoid irreversible aggregation of graphene, enhanced mechanical properties of graphene hydrogels, but can also improve the conductivity of graphene hydrogels because of the phytic acid's good conductivity.
The present invention aims at provide a compressive graphene hydrogel and a preparation method thereof. The compressive graphene hydrogel disclosed herein offers the features of a more pore structure, higher compressive strength, better structural stability then the prior art. It is excellent in electrochemical performance when used as the material of the supercapacitors. Also the preparation method is simple and feasible, the sources of raw material is rich, its unique structure and properties will make it wide used.
The compressive graphene hydrogel obtainable by using the oxidized graphene and the phytic acid as raw materials.
The process for preparing the compressive graphene hydrogel using the hydrothermal method: use the oxidized graphene as precursor, adding water into said oxidized graphene to make an aqueous solution, place the said aqueous solution in the reactor lining, doping phytic acid, carry out the reaction after mixing, freeze-dried the reaction product to get said compressive graphene hydrogel.
Wherein the concentration of graphene oxide in said aqueous solution is 1-4 mg/mL.
Wherein the amount of phytic acid in every 60 mL aqueous solution is 1-10 mL.
Wherein the reaction is carried out at temperature 120-180° C. for 12-24 h.
The invention has the following advantages:
(1) Under the action of the six-membered ring phytic acid dopant, the graphene oxide self-assembled to form the macroscopic three-dimensional material, and can effectively prevent the agglomeration and stacking of graphene sheets, obtain high specific surface and electrical conductivity, and its performance can be adjusted by the addition of phytic acid, reaction temperature and time.
(2) The mechanical strength of the material was significantly improved after the addition of phytic acid, and the compressive modulus of the material was obviously higher than that of pure graphene hydrogel, which can be applied to the preparation of composite electrode materials of super capacitors.
(3) The material obtained by this method has the advantages of controllable morphology, stable structure, excellent performance, and will promote the popularization of graphene in practical application.
The present invention is further described in the following exemplified embodiments to illustrate the application of the principles of the invention. It is understood that the invention may be embodied otherwise without departing from such principles. The scope of the claims of the present invention expressly should not be limited to such exemplary or preferred embodiments.
In this embodiment, the present application provides a compressive graphene hydrogel using the following method:
Step (1) slowly added 3 g of natural flake graphite to 150 mL of sulfuric acid/phosphoric acid (H2SO4:H3PO4=9:1, v/v) mixed acid solution, followed by adding 18 g of potassium permanganate, mixed evenly, raise the system temperature to 50° C., reacted for 12 h, washed the products with hydrochloric acid and deionized water respectively until the pH is neutral and the rotational speed was 11000 r/min, freeze-dried to get the graphite oxide.
Step (2) added the graphite oxide of Step (1) to the water, obtained aqueous solution of graphene oxide by ultrasonic dispersion, the concentration of the oxidized graphite is 1 mg/mL, took 60 mL of the aqueous solution in the Teflon-lined autoclave, added 4 mL of phytic acid, mixed evenly, and then placed in the reaction 12 h at 150° C.
Step (3) collected the cylindrical graphene hydrogel by step (2), soaked and washed with deionized water for 24 h, obtained the macro porous graphene hydrogel finally by freeze-drying.
The appearance and scanning electron micrograph image of the graphene hydrogel prepared by this embodiment were shown in
In this embodiment, the present application provides a compressive graphene hydrogel using the following method:
Step (1) slowly added 3 g of natural flake graphite to 150 mL of sulfuric acid/phosphoric acid (H2SO4:H3PO4=9:1, v/v) mixed acid solution, followed by adding 18 g of potassium permanganate, mixed evenly, raise the system temperature to 50° C., reacted for 12 h, washed the products with hydrochloric acid and deionized water respectively until the pH is neutral and the rotational speed was 11000 r/min, freeze-dried to get the graphite oxide.
Step (2) added the graphite oxide of Step (1) to the water, obtained aqueous solution of graphene oxide by ultrasonic dispersion, the concentration of the oxidized graphite is 1 mg/mL, took 60 mL of the aqueous solution in the Teflon-lined autoclave, added 1 mL of phytic acid, mixed evenly, and then placed in the reaction 12 h at 1501° C.
Step (3) collected the cylindrical graphene hydrogel by step (2), soaked and washed with deionized water for 24 h, obtained the macro porous graphene hydrogel finally by freeze-drying.
In this embodiment, the present application provides a compressive graphene hydrogel using the following method:
Step (1) slowly added 3 g of natural flake graphite to 150 mL of sulfuric acid/phosphoric acid (H2SO4:H3PO4=9:1, v/v) mixed acid solution, followed by adding 18 g of potassium permanganate, mixed evenly, raise the system temperature to 50° C., reacted for 12 h, washed the products with hydrochloric acid and deionized water respectively until the pH is neutral and the rotational speed was 11000 r/min, freeze-dried to get the graphite oxide.
Step (2) added the graphite oxide of Step (1) to the water, obtained aqueous solution of graphene oxide by ultrasonic dispersion, the concentration of the oxidized graphite is 2 mg/mL, took 60 mL of the aqueous solution in the Teflon-lined autoclave, added 4 mL of phytic acid, mixed evenly, and then placed in the reaction 12 h at 150° C.
Step (3) collected the cylindrical graphene hydrogel by step (2), soaked and washed with deionized water for 24 h, obtained the macro porous graphene hydrogel finally by freeze-drying.
In this embodiment, the present application provides a compressive graphene hydrogel using the following method:
Step (1) slowly added 3 g of natural flake graphite to 150 mL of sulfuric acid/phosphoric acid (H2SO4:H3PO4=9:1, v/v) mixed acid solution, followed by adding 18 g of potassium permanganate, mixed evenly, raise the system temperature to 50° C., reacted for 12 h, washed the products with hydrochloric acid and deionized water respectively until the pH is neutral and the rotational speed was 11000 r/min. freeze-dried to get the graphite oxide.
Step (2) added the graphite oxide of Step (1) to the water, obtained aqueous solution of graphene oxide by ultrasonic dispersion, the concentration of the oxidized graphite is 4 mg/mL, took 60 mL of the aqueous solution in the Teflon-lined autoclave, added 1 mL of phytic acid, mixed evenly, and then placed in the reaction 12 h at 150° C.
Step (3) collected the cylindrical graphene hydrogel by step (2), soaked and washed with deionized water for 24 h, obtained the macro porous graphene hydrogel finally by freeze-drying.
In this embodiment, the present application provides a compressive graphene hydrogel using the following method:
Step (1) slowly added 3 g of natural flake graphite to 150 mL of sulfuric acid/phosphoric acid (H2SO4:HPO4=9:1, v/v) mixed acid solution, followed by adding 18 g of potassium permanganate, mixed evenly, raise the system temperature to 50° C., reacted for 12 h, washed the products with hydrochloric acid and deionized water respectively until the pH is neutral and the rotational speed was 11000 r/min, freeze-dried to get the graphite oxide.
Step (2) added the graphite oxide of Step (1) to the water, obtained aqueous solution of graphene oxide by ultrasonic dispersion, the concentration of the oxidized graphite is 4 mg/mL, took 60 mL of the aqueous solution in the Teflon-lined autoclave, added 10 mL of phytic acid, mixed evenly, and then placed in the reaction 12 h at 150° C.
Step (3) collected the cylindrical graphene hydrogel by step (2), soaked and washed with deionized water for 24 h, obtained the macro porous graphene hydrogel finally by freeze-drying.
In this embodiment, the present application provides a compressive graphene hydrogel using the following method:
Step (1) slowly added 3 g of natural flake graphite to 150 mL of sulfuric acid/phosphoric acid (H2SO4:H3PO4=9:1, v/v) mixed acid solution, followed by adding 18 g of potassium permanganate, mixed evenly, raise the system temperature to 50° C., reacted for 12 h, washed the products with hydrochloric acid and deionized water respectively until the pH is neutral and the rotational speed was 11000 r/min, freeze-dried to get the graphite oxide.
Step (2) added the graphite oxide of Step (1) to the water, obtained aqueous solution of graphene oxide by ultrasonic dispersion, the concentration of the oxidized graphite is 4 mg/mL, took 60 mL of the aqueous solution in the Teflon-lined autoclave, added 1, 2, 4, 10 mL of phytic acid respectively, mixed evenly, and then placed in the reaction 12 h at 150° C.
Step (3) collected the cylindrical graphene hydrogel by step (2), soaked and washed with deionized water 24 h, obtained the macro porous graphene hydrogel finally by freeze-drying.
Step (4)
The above is only a preferred embodiment of the invention, equal changes and modification within the scope of the invention patent, all should be the scope of the invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2014 1 0563543 | Oct 2014 | CN | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/CN2015/071228 | 1/21/2015 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2016/061926 | 4/28/2016 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 20150232340 | Bao | Aug 2015 | A1 |
| 20170174522 | Park | Jun 2017 | A1 |
| Number | Date | Country |
|---|---|---|
| 101941693 | Jan 2011 | CN |
| 103399063 | Nov 2013 | CN |
| 103768960 | May 2014 | CN |
| 103896256 | Jul 2014 | CN |
| 103399063 | Jul 2015 | CN |
| 101577190 | Dec 2015 | KR |
| Entry |
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| Quanshi Gao et al; Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process; 2010 American Chemical Society; Jun. 30, 2010; 4324-4330; vol. 4; No. 7. |
| Number | Date | Country | |
|---|---|---|---|
| 20170309365 A1 | Oct 2017 | US |
