Patent Application
20070035162
The invention relates to a temperature control system, which can be used for the rapid cooling and possibly also heating of surfaces—in particular of car seats. In addition, the invention relates to a seat and/or rest element, in particular with leather covering, and to a complete car seat, respectively fitted with such a temperature control system. Finally, the invention also relates to a temperature control mat for such a temperature control system and to a temperature control method for cooling and possibly heating a seat and/or rest element.
It is known not only to heat but also to cool seats—in particular car seats. Cooling is necessary if car seats heat up under strong solar irradiation to high temperatures, which can lead to serious burns of the skin. This problem arises in particular in the case of dark leather seats. In general, the driver must wait until the seat has cooled down to a temperature comfortable for sitting, whether by means of the car's air-conditioning system or by means of natural ventilation. Therefore, a fundamental concern is to lower the surface temperature of seats to a comfortable level in a short time.
It is known from U.S. Pat. No. 6,003,950 to provide between the seat covering and the cushion core a fiber-like insert which is enclosed by a film. The part of the film which faces the seat covering has openings for the passage of air. Air is then sucked through the seat covering and the insert by means of a fan, in order to cool the seat.
It is known from U.S. Pat. No. 6,254,179 B1 to arrange a meandering system of hoselines or pipelines through which water flows in a flat cushion underneath the seat covering, in order to heat or cool the seat area according to requirements. The temperature of the water in the lines is controlled by means of a complex heat exchanger system, which is connected for example to the vehicle's heating and air-conditioning system.
A system of a similar construction is also described in DE 44 32 497 A1. In this case, the pipeline system for the cooling liquid is arranged in a temperature control mat between two layers of air-permeable material, in order that condensed water possibly occurring on the lines can dry. The temperature control mat may serve as a seat support or be an integral component of the vehicle seat.
Because of the relatively rigid nature of the hoses or pipes, the system of lines undesirably presses through the seat covering and adversely affects the feel of the seat. If the system of lines is arranged further in the interior of the seat to remedy this disadvantage, however, a significant reduction in efficiency occurs because of the poor heat transfer associated with the greater distance from the temperature-controlling surface.
It is disadvantageous, furthermore, that, in the case of the previously described systems, no moisture resulting for example from the perspiration of a person sitting on the surface is removed. This may have the consequence on hot days of clothing becoming soaked with perspiration.
Instead of a liquid, a gas may also be used for controlling the temperature of the seat. Such a system is described for example in U.S. Pat. No. 4,572,430. In this case, temperature-controlled air is directed from the rear side into the seat and backrest cushion. The seat covering is air-permeable, so that the air can leave the seat again on the front side.
A similar system is proposed in U.S. Pat. No. 6,273,810 B1. There, the temperature-controlled air is directed into air chambers lying under the seat covering. Individual chambers are merely inflated and serve exclusively for increasing the comfort of the underlying structure of the seat. Other chambers are perforated on their side facing the seat covering and serve for controlling the temperature of the seat, in that the temperature-controlled air is forced to the outside through the perforation of the air-chamber wall and further through the seat covering, which is likewise perforated.
Although no lines press through the seat covering in the case of the two systems last described, the removal of moisture is not ideal in these cases either, although a certain drying is reliably achieved by the air stream emerging from the seat. However, the person sitting on the seat closes the pores in the seat, so that at these points the transporting of moisture and exchange of air is virtually completely blocked. Moreover, the air emerging from the open pores flows past the person, which is felt to be uncomfortable and may be harmful to health, in particular in the lumbar region.
In addition, perforated seat coverings, in particular made of leather, have a tendency to become clogged with dust and dirt particles and are also not desired for design reasons. A further disadvantage is that the systems described only begin to work when the car is started, i.e. the driver initially sits down on a hot seat, before the cooling of the seat begins.
It is therefore the object of the present invention to propose a solution for cooling heated-up surfaces—in particular of car seats with leather coverings—to a comfortable temperature in a very short time, and at the same time for ensuring efficient transporting away of moisture, in particular perspiration, through the seat covering. At the same time, sitting comfort and surface appearance are to be maintained.
This object is achieved by a temperature control system or temperature control mat and a method for controlling the temperature of a seat and/or rest element with the features of the independent patent claims. Advantageous developments and refinements of the invention are specified in claims dependent on these independent claims.
The temperature control mat according to the invention is, on the one hand, air-permeable and, on the other hand, comprises a fluid chamber system, through which a temperature control fluid is directed. For this purpose, two or more layers of liquid-impermeable plastic are connected to each other, for example welded or adhesively bonded, in such a way that the fluid chamber system is formed in the space between the layers of plastic. A number of fluid chamber systems that are separated from one another may also possibly be formed between the layers of plastic.
A fluid chamber system formed between the layers of plastic comprises one or more fluid chambers for receiving the temperature control fluid and one or more fluid inlets and outlets in connection with the fluid chambers for supplying and removing the temperature control fluid to and from the fluid chamber system. The maximum volume of the fluid chamber system in one embodiment may be 0.3 l/m2 to 3 l/m2. Some or all of the fluid chambers of the fluid chamber system are in flow connection with one another, so that the temperature control fluid can flow from the fluid inlet or the fluid inlets through the interconnected fluid chambers of the fluid chamber system to the fluid outlet or the fluid outlets. The connecting zones between the fluid chambers are referred to hereafter as “fluid passages”.
The air permeability of the temperature control mat is based on openings arranged in a distributed manner passing through the temperature control mat. These openings pass through the layers of plastic forming the fluid chamber system in such a way that the fluid chamber system forms a closed system.
To ensure the transporting of moisture through the seat covering, the temperature control mat is combined with an open spacer structure. Any two-dimensional, open structure which on the one hand permits a through-flow of gas to dissipate water vapor passing through the seat covering and on the other hand is adequately flexible and nevertheless stable under pressure, so that it does not collapse even under the weight of a person imparting a load to it, can be used as the spacer structure. The spacer structure may be securely connected to the temperature control mat, for example sewn or preferably adhesively bonded, so that the temperature control mat including the spacer structure can be easily handled and integrated into a seat. The spacer structure preferably lies between the temperature control mat and the seat cushion, so that the sequence of the layer structure is as follows: seat covering, temperature control mat, spacer structure, seat cushion, and any additional layers lying inbetween.
This arrangement is particularly effective, because the temperature control mat lies directly underneath the seat covering. This produces great heat conduction and short diffusion paths for water vapor. The perspiration moisture passing through the seat covering then passes through the openings in the temperature control mat and into the open spacer structure and can be diffused away from there. The transporting away of the moisture is preferably assisted by an air stream, which is directed through the spacer structure parallel to the surface of the seat covering, in order to remove the transmitted moisture actively. The temperature control mat on one side of the spacer structure and the seat cushion, usually consisting of closed-cell foam, on the other side of the spacer structure in this case define an air-directing duct for the air directed through the spacer structure.
It goes without saying that it is also possible to provide the spacer structure on the other side of the temperature control mat, that is between the seat covering and the temperature control mat. In this case, the effectiveness of the temperature control mat is greatly reduced, however, because of the distance from the seat covering, and the through-openings in the temperature control mat are no longer important for allowing perspiration moisture through the temperature control mat. Rather, the openings can then be used for directing an air stream from the rear side through the openings of the temperature control mat into the spacer structure.
If such a temperature control mat combined with a spacer structure is placed in a seat and/or backrest element between the outer seat covering and the actual cushion material, the temperature of the seat covering can be influenced very rapidly and cooled down to body temperature within about 60 seconds. The cooling down of a leather seat covering from about 85° C. to a comfortable body temperature of 37° C. to 40° C. can be achieved for example in one minute. For this purpose, the temperature control fluid flows through the fluid chambers of the fluid chamber system until the desired seat surface temperature is reached. Preferably used as the temperature control fluid is an environmentally compatible liquid, for example water, possibly mixed with an anti-freezing agent, such as glycol or salt solution for example, and an anti-rotting agent and other additives. The use of liquid offers the advantage over a gas of greater heat capacity along with good heat transfer properties, whereby the temperature control of the seat covering is particularly effective.
On account of this effectiveness, the seat covering can be brought to the desired temperature in a very short time, even before a person sits down on it. For example, the temperature control can be switched on automatically when the vehicle is unlocked. Activation by remote control or a timer circuit is likewise possible. In particular, it is not necessary to start the vehicle in order to make the power required for the temperature control of the seat covering available. The temperature control liquid does not necessarily have to be cooled down to cool the seat covering, but may be pumped from a storage tank which is located at a relatively cool place, for example in the region of the vehicle floor, so that the temperature control liquid is at most at ambient temperature. This storage tank preferably has an insulating casing. The supply of liquid contained in it may be additionally cooled, for example during driving or possibly also when the engine is switched off, if the vehicle battery produces sufficient power. A Peltier element comes into consideration for example as the cooling element.
According to the same principle, the seat covering can be heated up. For this purpose, a heated fluid, such as water for example, flows through the fluid chamber system. In a preferred embodiment, the fluid is heated by a heating element to a temperature of approximately 40° C. to 50° C.
The temperature control fluid is pumped through the fluid chamber system until the desired temperature is reached. Subsequently, the fluid chambers of the fluid chamber system are pumped empty. Since the fluid chamber system is formed by interconnected films of plastic, the pumped-empty chambers collapse and form a largely planar surface. To ensure complete emptying of all regions of the fluid chamber system, it is advantageous to integrate spacers, for example thin fibers, woven or non-woven fabrics, into the fluid chamber system. When the fluid chamber system has been emptied, the temperature control mat consequently does not press through the seat covering, so that the original sitting comfort properties are restored immediately after the desired seat covering temperature is reached. The visual impression of the surface is not adversely affected by the temperature control mat. A person sitting on the seat does not feel the temperature control mat at all.
If a person then sits down on the seat, brought to an acceptable temperature in advance, this person will perspire to the usual extent or—in the case of hot outside temperatures—possibly also to an increased extent. In the case of conventional seats, this often leads to clothing that is against the seat covering becoming soaked by perspiration. In this connection, the openings arranged in a distributed manner in the temperature control mat are of great importance. This is so because these openings offer the possibility of removing this perspiration moisture passively or preferably actively. A precondition for this is firstly that the moisture can pass through the seat covering. In the case of textile coverings, this is readily ensured, since textile coverings act like a wick for moisture. Standard leather car seat coverings are not breathable, or scarcely so, i.e. they can at best only remove minimal amounts of water vapor. However, now there are also breathable leathers, which are adequately moisture-permeable without perforation, and can therefore be used for seat coverings. Instead of vapor-permeable leather coverings, it goes without saying that perforated leather may also be used for the seat covering.
Although the previously described temperature control mat is intended essentially for the cooling of surfaces, it can also be used for the heating of surfaces. The two functions can also be combined. A preferred embodiment provides for this purpose a bypass line in the fluid circuit, by which the cooling fluid reservoir is bypassed. In the bypass line there is a heating element, preferably a continuous flow heater, with which the temperature control fluid is heated, in order by this means to heat the surface. It goes without saying that the heating function of the temperature control mat according to the invention may also be combined with conventional heating elements, such as for example with an electrical resistance heater in the seat and/or backrest element and the like, merely to assist the latter.
The particular advantages achieved by the invention are to be seen in that it provides a rapidly acting temperature control system—in particular for rapid cooling/heating and efficient moisture removal—which does not adversely affect the sitting comfort or the appearance of the surface to be cooled, is effective and is not felt to be uncomfortable by a person sitting on the seat. In addition, the temperature control mat according to the invention can be handled easily and can be integrated into a seat and backrest element in a simple way.
A further advantage of the temperature control system according to the invention with the temperature control mat according to the invention is the resistance to the typical loads to which a seat element of a car seat is subjected. Car seats are subjected to sustained loads, which also have to be withstood by the temperature control system integrated into the seat. Conventional pipeline and hoseline temperature control systems can in this case be displaced and mechanically damaged considerably over time unless they are integrated into the seat element in a complex way. By comparison with this, the temperature control mat according to the invention can be securely connected in a simple way to the seat covering or the cushion core by adhesive bonding and/or sewing. But even without such fixing, the temperature control mat according to the invention is not displaced, because of its extent over a large area under the seat covering. This does not occur in particular if the temperature control mat is securely combined with a spacer structure. The high resistance of the temperature control mat according to the invention is also additionally based on the very smooth surface of the films of plastic of the temperature control mat—in particular in the case of fluoropolymers—which on account of this very property does not rub against the seat covering, so that no frictional wear occurs. Finally, it should also be mentioned that the layers of plastic forming the fluid chamber system may have additional reinforcing layers, for example in the form of a nylon woven fabric.
The aforementioned advantages can be optimized by suitable choice of the layers of plastic forming the fluid chamber system.
To be able to produce the temperature control mat in a simple way, the layers of plastic should be capable of being welded, laminated, coextruded, sintered or blow-molded with one another. In principle, the following materials are suitable for example: thermoplastic polyurethane (TPU), thermoplastic polyester (TPE), polyamide (PA), polytetrafluoroethylene (PTFE), expanded polytetrafluoroethylene (ePTFE), polyvinylidine fluoride (PVDF), ethylene/tetrafluoroethylene copolymer (ETFE), fluorinated ethylene propylene (FEP) and other fluoropolymers. These materials are preferably fiber- or fabric-reinforced.
Of these materials, TPU is suitable to a particular extent because of its flexibility along with good affinity for adhesive bonding with other materials, in particular with leather. Fluoropolymers are suitable because of their diffusion impermeability and good sliding properties, and accompanying resistance to wear, but are less well able to bond adhesively with seat covering materials. Fluoropolymers are additionally highly temperature-resistant and are therefore particularly suitable in combination with a heating element integrated into the cushion. Such heating elements may be up to 120° C. hot. A particularly temperature-resistant fluoropolymer is, for example, PTFE. Finally, fluoropolymers are distinguished by high chemical resistance, which is significant when additives are used in the temperature control fluid.
In addition, the layers of plastic from which the fluid chamber system is formed should be as thin and flexible as possible, in order that the fluid chamber system can be emptied without difficulties and thereby collapses without any major folds, so that the deactivated temperature control mat cannot be felt or seen through the cushion covering. The layers of plastic may, for example, respectively have a thickness in the range from 10 μm to 1 mm, good results having been achieved for example with a layer thickness of 200 μm in each case.
For a low-maintenance system, it is advantageous to operate the fluid circuit in the fluid chamber system as a closed system. In this case, great value should be attached to the diffusion impermeability of the films of plastic used, in order that fluid losses over the service life are kept low.
However, the variant of a partly open system is also possible. In this case, the emptying and complete filling of the fluid chamber system is additionally assisted by at least one of the layers of plastic forming the fluid chamber system being liquid-impermeable but air-permeable, at least in certain regions, so that an exchange of air can take place through the fluid-chamber wall, in particular the venting of undesired inclusions of air. Particularly suitable in this connection is expanded polytetrafluoroethylene (ePTFE) with a low porosity, to keep the evaporation losses low during operation. Tests with a low porosity of, for example, 2% to 30% (measured with a Capillary Flow Porometer CFP-1500-AXLS from PMI—Porous Materials, USA) and a high water ingress pressure of over 6 bar have produced good results.
The openings in the temperature control mat which serve for moisture removal may comprise 20% to 80% of the projected surface area of each of the layers of plastic forming the fluid chamber system. Good results have been obtained for example with an opening surface area accounting for 30% to 40% of the projected total surface area. The contour of the openings may be chosen as desired. In particular, they do not have to be circular and may be of different sizes. The openings should offer the least possible diffusion resistance and therefore in any event be macroscopic, in order not to hinder the moisture removal through the openings. An average opening diameter may for example lie in the range from 1 mm to 30 mm. Good results have been obtained for example with an average opening diameter of approximately 5 mm. On account of the thin wall thickness of the fluid chamber system and the large openings passing through the fluid chamber system, a low diffusion resistance is achieved for the water vapor passing through the openings. Moisture-laden air can pass relatively unhindered through the openings into the spacer structure and is transported away by the air flowing through the spacer structure.
Just as the openings may have any desired contour, size and arrangement within the temperature control mat, the chambers of the fluid chamber system may also have extremely different forms. It goes without saying that a uniform arrangement of the fluid chambers is to be preferred for the purpose of uniform temperature control of the seat covering. There is in this case the possibility of realizing one or more fluid chamber systems in a temperature control mat, it being possible in turn for each fluid chamber system to have one or more fluid inlets and/or fluid outlets. One or more common fluid inlets and outlets may be provided, but fluid inlets and outlets that are independent from one another are to be preferred, to permit a continuous flow through the fluid chambers. It is particularly advantageous if precisely one fluid inlet and one fluid outlet are respectively provided for a seat element and a rest element and if the respective fluid chamber systems have numerous fluid chambers in fluid connection with one another, so that the temperature control fluid flows on one side into the fluid chamber system and flows through the numerous fluid chambers partly in parallel and partly in succession, in order subsequently to flow out again from the fluid outlet.
Such a structure is on the one hand uncomplicated in its production and integration into a circuit system. On the other hand, the flow paths are short, so that the flow resistance is low and the heat transfer over the entire length of flow is virtually uniform. The fluid passages formed between fluid chambers in connection with one another should have a length in the range from 3 mm to 50 mm, in order to achieve optimum mixing of the fluid.
An effective heat transfer is assisted furthermore by the fact that the temperature control mat, in the state in which temperature control fluid is flowing through it, swells slightly and presses against the seat covering. The total thickness of the filled temperature control mat ranges between approximately 0.5 mm and 10 mm.
The invention is explained below by way of example on the basis of the accompanying drawings.
a shows a car seat with integrated temperature control mats schematically in cross section.
b shows the arrangement of the temperature control mats according to
a shows a car seat 1 comprising a seat element 2 and a backrest element 3. Located under the seat coverings 4 both of the seat element 2 and of the backrest element 3 there is in each case a temperature control mat 5, which is kept at a distance from the cushion core 7 by a spacer structure 6. Water (H2O) is pumped as a temperature control fluid by means of a pump P from a storage tank 9 through the temperature control mat 5 through a system of fluid lines 8, which is represented as dashed lines with thin, black arrows, in order to control the temperature of (temperature control phase), in particular to cool (cooling phase), the seat covering 4 from the rear side. After completion of the temperature control phase, air is made to flow through the spacer structure 6 by means of a fan (white arrows), in order to assist the dissipation of perspiration moisture passing through the seat covering 4.
b shows the arrangement of the temperature control mat 5 in the car seat 1 according to
The cooling phase (or heating phase) is schematically represented in cross section in
When a desired seat covering temperature has been reached, a shut-off valve, not represented in
If a person sits down on the temperature-controlled seat after the cooling phase, the second temperature control phase begins, aimed at removing moisture perspired by the person through the seat covering 4 and the openings 11 of the temperature control mat 5. For this purpose, the spacer structure 6 is provided between the cushion core 7 and the temperature control mat 5. Any open structure which on the one hand is flexible, in order to make the seat comfortable to sit on, but on the other hand cannot be completely compressed under exposure to pressure, so that ventilation through the spacer structure 6 remains ensured under any circumstances, comes into consideration as the spacer structure 6. Suitable for example are nonwoven or knitted polymer-fiber fabrics. The dissipation of the moisture transported through the seat covering 4 is assisted by an actively produced air stream in the spacer structure 6, which is indicated in
The detail represented in
If it is a leather covering, its outer side is usually largely sealed by a protective layer 12. The moisture permeability of a leather seat covering 4 therefore depends essentially on the water-vapor transporting properties of the protective layer 12. For the purposes of the present invention, the leather covering should preferably have an MVTR value (according to DIN 53 333) of greater than 10 mg/cm2h. Breathable leathers with an MVTR value of more than 12 mg/cm2h are particularly preferred. Such leathers are obtainable for example from the Vogl leather factory in Mattinghofen/Austria. In the case of a non-breathable, in particular fully sealed leather covering, a micro-perforation of the covering also comes into consideration. This is to be understood as meaning a leather with pores usually produced in a needling process, with a pore diameter of 80 μm to 100 μm. Microperforated leathers with a thickness of between 1.9 mm and 2.5 mm achieve an MVTR value of between 2 and 6 mg/cm2h, which may be adequate for the purposes of the invention.
The perspired moisture then diffuses through the permeable seat covering 4 to the temperature control mat 5 and through the openings 11 of the temperature control mat 5 into the spacer structure 6 lying thereunder. The temperature control mat 5 essentially comprises two thin films of plastic 5a, 5b, lying one on top of the other and connected to each other in a suitable way. In the emptied state, the temperature control mat 5 has a slightly rough surface due to fold formations of the thin films of plastic 5a, 5b. As a result, moisture can also reach an opening 11 of the temperature control mat 5 from those points of the seat covering 4 under which an opening 11 is not directly located.
On account of the two thin films 5a, 5b with a thickness of for example 200 μm in each case, the path through the openings 11 is very short. In one embodiment, the filled temperature control mat 5 has a thickness of 4 mm. In particular, no build-up of moisture forms in the openings 11 and no boundary layer forms between the air in the openings 11 and the air flowing through the spacer structure 6, so that the moisture diffused through the seat covering 4 is reliably entrained by the air stream in the spacer structure 6. For the same reason, the opening diameters of the openings 1 are chosen to be comparatively large and, in the exemplary embodiment represented, are approximately 3.5 mm.
The spacer structure 6 has, for its part, a thickness of approximately 6 mm to 10 mm in the exemplary embodiment represented. Depending on the material used for the spacer structure 6, it may be meaningful to make the spacer structure 6 thicker or thinner.
With its rear side, the spacer structure 6 is adjacent to the cushion core 7, which is for example a closed-cell foam core. The air stream directed through the spacer structure 6 (arrow) is therefore guided essentially parallel to the covering between the temperature control mat 5 and the closed-cell cushion core 7.
The spacer structure 6 and the temperature control mat 5 may be adhesively bonded to each other, whereby the entire arrangement can be easily handled and can be correspondingly easily integrated into a car seat. If the temperature control mat 5 is not adhesively bonded to the spacer 6, it is essential that the spacer structure 6 has a non-abrasive surface, since otherwise damage to the thin films of plastic 5a, 5b of the temperature control mat 5 would have to be feared in the long term.
The temperature control mat 5 is preferably connected, preferably adhesively bonded, to the seat covering 4—with or without spacer structure 6. As a result, rubbing between the seat covering 4 and the temperature control mat 5 is avoided, whereby the service life of the temperature control mat 5 is correspondingly increased.
The necessary air throughput through the spacer structure 6 for removing moisture from the seat covering 4 is extremely low, since only little moisture is removed through the seat covering. Therefore, it is adequate if air is blown from the passenger compartment of the vehicle through the spacer structure 6 in an uncomplicated way by means of a simple fan with a power of, for example, 0.3 to 3 W. In one embodiment, the spacer structure 6 is connected directly or indirectly to the vehicle's ventilation system or air-conditioning system.
In
Water (H2O) as the temperature control fluid is directed into the fluid chamber system via a fluid inlet 13 and out again through a fluid outlet 14. The temperature control fluid H2O is thereby distributed uniformly in the fluid chamber system and—by contrast with a meandering system of lines—passes from the fluid inlet 13 to the fluid outlet 14 over a relatively short path. However, as a departure from the exemplary embodiment represented in
The temperature in the storage tank 9 can be monitored by means of a temperature sensor and if need be cooled down by a suitable cooling device. A Peltier element is suitable for example as the cooling device 15. In addition, the storage tank 9 is encased with an insulation 16, in order to prevent heat exchange with the warmer surroundings.
Once the desired seat covering temperature has been reached, the valve 17 in the supply line of the system of fluid lines 8 is blocked and the temperature control mat 5 is pumped empty. In the subsequent moisture removal phase during driving, air is directed past the spacing structure 6, not represented in
A special development provides a bypass 18, with which the cooling fluid storage tank 9 is bypassed. By appropriate switching of the shut-off valve and a further shut-off valve 19, which are accordingly formed as multi-way valves, the fluid present in the temperature control system can be directed through the bypass 18 and heated by means of a heating element 20 arranged therein, for example a continuous flow heater. As a result, the temperature control system may serve both as seat heating and as seat cooling. On account of the operating pressure, the temperature control mat 5 in turn presses against the seat covering 4, whereby an efficient heat transfer is ensured. This heat transfer is additionally assisted by the weight of the person sitting on the seat. The heating element can be regulated by a temperature sensor 21 arranged in the discharge line of the system of fluid lines 8. Further temperature sensors 21 are provided in the temperature control mat or directly on the seat covering and in the cooling liquid storage tank 9. All the temperature sensors 21 are connected to a control system, not represented, in which the measured temperature values are processed and the individual components of the temperature control system are correspondingly controlled.
Test Result
With the system described above it was possible to lower the surface of a leather seat covering from a starting temperature of 85° C. to a temperature of 44° C. within less than 1 minute, the temperature control liquid comprising a temperature of 40° C. and the system an overall volume of 800 ml.
| Number | Date | Country | Kind |
|---|---|---|---|
| 03004905.0 | Mar 2003 | EP | regional |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP04/02268 | 3/5/2004 | WO | 8/14/2006 |
