Patent Application
20220263170
The disclosure relates to portable or wearable battery packs and more specifically to conformable battery pack assemblies including an outer shell having a skin-like feel.
Portable consumer electronic devices have certain power requirements. Generally, small, wearable consumer electronic devices receive power from a single battery (contained within the device itself), or from a portable battery pack that may include one or more battery cells. These portable battery packs are usually contained within a hard plastic outer shell that may be attached to a user by a strap, or carried by a user in a pocket or other carrying location. These hard battery packs are uncomfortable when secured to the body with a strap or carried in a pocket. Additionally, such battery packs create bulges in clothing when worn under the clothing, which may be undesirable aesthetically, as well as being uncomfortable. Moreover, current battery packs require an inconvenient connection cord to supply power to the device.
Battery assemblies containing a plurality of cells with top and bottom laminate layers coupled to the cells with an adhesive that allows flexibility and the possible removal of one or more cells to better fit in devices are described in U.S. Pat. No. 9,343,716. These battery assemblies are arranged such that top and bottom laminate layers are connected to the cells and each other by adhesives.
According to a first embodiment, a wearable battery pack includes an array of individual electrochemical cells electrically connected with one another in one of in series, in parallel, or in series and in parallel. An outer shell surrounds and encapsulates the array of individual electrochemical cells. The outer shell comprises a material having one or more of the following properties; a failure stretch ratio of between 1.1 and 1.8, preferably between 1.2 and 1.7, and more preferably between 1.3 and 1.6; an ultimate tensile strength between 1 MPa and 50 MPa, preferably between 15 MPa and 40 MPa, and more preferably between 15 MPa and 35 MPa; and a Young's modulus of between 5 kPa and 140 MPa, preferably between 20 MPa and 100 MPa, and more preferably between 30 MPa and 80 MPa.
According to a second embodiment, a battery pack includes an array of individual electrochemical cells embedded and encapsulated in a matrix of flexible conformable material. The matrix of flexible conformable material provides a protective outer shell and each individual electrochemical cell is electrically connected in one of in series, in parallel, or in series and in parallel, to the other individual electrochemical cells.
According to a third embodiment, a battery pack includes an array of individual electrochemical cells electrically connected with one another. The array is surrounded and encapsulated by a flexible outer shell. An electronic component is operably connected to the array of individual electrochemical cells. The electronic component is surrounded and encapsulated by the flexible outer shell.
The foregoing embodiments of a battery pack may further include any one or more of the following optional features, structures, and/or forms.
In some optional forms, the outer shell material comprises an elastomer.
In other optional forms, the outer shell material is laminated around the array of individual electrochemical cells and around at least some of the wires connecting the individual electrochemical cells.
In yet other optional forms, the outer shell material comprises an adhesive on one side.
In yet other optional forms, the outer shell material is molded around the electrochemical cells.
In yet other optional forms, the outer shell material comprises a hardness of between HOOO-S10 and 90 A, preferably between HOO-5 and 30 A, and more preferably between H00-10 and HOO-50, as defined by ASTM Standard D2440-15.
In yet other optional forms, the outer shell material comprises an elongation break between 350% and 1,000%, preferably between 500% and 900%, and more preferably between 600% and 900%.
In yet other optional forms, the array of individual electrochemical cells comprises individual electrochemical cells having one or more of the following types: cylindrical cells, coin cells, button cells, prismatic cells, or pouch cells.
In yet other optional forms, at least some of the individual cells cylindrical in shape and are spaced from one another between 5% and 100%, preferably between 10% and 100%, and more preferably between 15% and 100% of an average cell diameter.
In yet other optional forms, individual cells are rectangular in shape and at least some of the individual cells are spaced from one another between 5% and 100% of the largest linear dimension of the individual cells.
In yet other optional forms, the flexible outer shell has a thickness to length ratio of between 1:2 and 1:30, preferably between 1:5 and 1:20, and more preferably between 1:10 and 1.15.
In yet other optional forms, the array of individual chemical cells further comprises an antenna or induction coupling coil for wireless charging, the antenna or induction coupling coil being arranged to convert a time varying magnetic field or electrical field into a direct current for battery charging.
In yet other optional forms, the array has at least two layers, each layer including a sub-set of the array of individual chemical cells.
In yet other optional forms, the flexible conformable material is substantially free of entrapped air/gas (less than 5% by volume).
In yet other optional forms, the array includes an opening. In some optional forms an electronic component is located in the opening, and the electronic component is electrically connected in series or in parallel to the array of cells. In some optional forms, the opening is 4 mm or less.
In some optional forms, the electronic component is a sensor, for example, the electronic component may be a physiological sensor.
In other optional forms, the electronic component comprises one or more of a processor, a microprocessor, a signal processor, an integrated circuit, a display, a capacitor, a resistor, a transistor, a medical application device such as a glucose delivery device or an automatic defibrillator, a global positioning system (GPS) receiver, a sensor (such as a biometric sensor, a temperature sensor, an accelerometer, a moisture sensor), or an antenna.
In other optional forms, the electronic component is operably connected to a face of one electrochemical cell in the array of individual electrochemical cells.
In other optional forms, the electronic component is positioned within the flexible outer shell.
In other optional forms, the electronic component is surrounded and encapsulated by the flexible outer shell.
While the specification concludes with claims particularly pointing out and distinctly claiming the subject matter, which is regarded as forming the present invention, the invention will be better understood from the following description taken in conjunction with the accompanying drawings.
Electrochemical cells, or batteries, may be primary or secondary. Primary batteries are meant to be discharged, e.g., to exhaustion, only once and then discarded. Primary batteries (or disposable batteries) are described, for example, in David Linden, Handbook of Batteries (4th ed. 2011). Secondary batteries (or rechargeable batteries) are intended to be recharged and used over and over again. Secondary batteries may be discharged and recharged many times, e.g., more than fifty times, a hundred times, or more. Secondary batteries are described, for example, in David Linden, Handbook of Batteries (4th ed. 2011). Accordingly, batteries may include various electrochemical couples and electrolyte combinations. The description and examples provided herein apply to both primary and secondary batteries of aqueous, nonaqueous, ionic liquid, and solid state systems. Primary and secondary batteries of the aforementioned systems may be used in the battery pack assemblies according to the disclosure.
As used herein, the term “embedded in and encapsulated by” refers to an individual item such as a battery cell is completely embedded within a matrix of material so that substantially no gap or space exists between the embedded item and the matrix of material (e.g., the matrix of material contains less than 5% by volume of entrapped air/gas). In other words, the matrix of material is in contact with the embedded object at substantially all locations on the exterior of the embedded object. Examples of processes that produce items that are embedded in and encapsulated by a matrix of material include, for example, overmolding, dipping, spraying, casting, and vapor deposition.
As used herein, the term “surrounded and encapsulated” refers to an item, such as a battery cell, is completely surrounded by a matrix of material, but there may be a small gap or space between the item and the surrounding matrix of material. Examples of processes that produce surrounded and encapsulated items include, for example, lamination, vacuum forming, compression molding, and bonding by enclosing the cells within an assembly of at least two pre-formed substrates and bonding at the seams with heat sealing or an adhesive.
The term “bending axis,” “bending axes,” “axis of bending,” or “axes of bending” as used herein refers to one or more substantially straight lines that extend through a flexible outer shell of a battery pack without contacting any battery cells in the flexible outer shell. The bending axis or bending axes allow deformation or bending of the flexible outer shell along the substantially straight lines to readily form non-planar shapes, and thereby significantly enhances a user's comfort when a battery pack is applied to the user's skin. The bending axis or bending axes also allow deformation or bending of the flexible outer shell to conform with non-planar objects. A substantially straight line is a line that diverges by 20 degrees or less from straight, preferably 15 degrees or less, from an idealized line formed by drawing a straight line between the two end points of the bending axis at the perimeter edge of the flexible outer shell, wherein the divergence is measured by establishing an angled cone, beginning at one of the end points and extending 20 degrees (or 15 degrees) on either side of the idealized line such that the bending axis falls within this cone along its entire length. Material in the flexible outer shell advantageously is adapted to deform along the substantially straight line in response to bending forces that are applied to the flexible outer shell. The bending axis may extend along a length, width, and/or thickness dimension of the flexible outer shell. In some cases, an axis of symmetry may also be a bending axis if the axis of symmetry does not intersect or overlap with a battery cell disposed in the flexible outer shell.
As used herein, the term “electronic component” refers to any device powered by electricity. Examples of electronic components include processors, microprocessors, signal processors, integrated circuits, displays, capacitors, resistors, transistors, medical application devices (such as a glucose delivery device or an automatic defibrillator), global positioning system (GPS) receivers, sensors (such as biometric sensors, temperature sensors, accelerometers, moisture sensors), antennas, and combinations of the foregoing.
Many wearable electronic devices require a self-contained portable power supply. Typically, power is provided by an electrochemical battery cell or a portable battery pack assembly. However, existing electrochemical battery cells and battery pack assemblies are not sufficiently flexible and stretchable to be comfortable when attached to human skin and thus frequently result in an uncomfortable feel for the user.
Known battery assemblies that contain a plurality of cells with top and bottom laminate layers coupled to the cells with an adhesive generally lack flexibility, stretchability, and conformability.
The battery pack assemblies described herein provide a wide range of power characteristics while being flexible and conformable to advantageously enhance user comfort. The battery pack assemblies described herein also include a protective flexible outer shell having a skin-like feel, further advantageously enhancing user comfort and thereby extending the length of time the battery pack assemblies may be comfortably tolerated when worn. Furthermore, the described battery pack assemblies may be incorporated into articles of clothing, such as wrist bands, belts, suspenders, headbands, arm bands, socks, vests or other smart clothing in general to provide additional energy storage for rechargeable devices, health and fitness equipment, other sensors, audio equipment, and mobile phone power. Because the described battery pack assemblies may completely enclose the individual electrochemical cells within a matrix of waterproof conformable material, smart clothing incorporating the disclosed battery pack assemblies may advantageously be laundered safely, without having to remove the electrochemical cells.
Although the disclosed battery pack assemblies may comprise any type of electrochemical cell, in some examples, relatively low-cost coin or button electrochemical cells of any chemistry (including for example, Li-Primary, Zn—Ag2O, Zn—MnO2, and the like) may be advantageously employed. In other embodiments, the electrochemical cells may comprise cylindrical, prismatic, or pouch cells. In yet other embodiments, the electrochemical cells may comprise other shapes, such as rectangular or square.
Turning now to
The electronic component 20 may comprise one or more of a processor, a microprocessor, a signal processor, an integrated circuit, a display, a capacitor, a resistor, a transistor, a sensor, a medical application device such as a glucose delivery device or an automatic defibrillator, a global positioning system (GPS) receiver, a sensor (such as a biometric sensor, a temperature sensor, an accelerometer, a moisture sensor), an induction coil, or an antenna. Furthermore, the antenna in some embodiments may be arranged such that it can also function as an induction coil that converts a time varying magnetic field or electrical field into a direct current for battery charging. In some embodiments, the electronic component 20 may be a sensor in direct contact with the user's skin. In other embodiments, the electronic component 20 may be located in a separate compartment and embedded and encapsulated in the conformable material 14. Regardless, the electronic component 20 is also electrically connected to one or more of the electrochemical cells 12 to receive power. The electronic component 20 is an optional component. The conformable battery pack assembly 10 may be used to power other devices that are not sensors in other embodiments.
In some embodiments, the electronic component may be connected to a face of a cell 12, or may be located within the matrix of conformable material 14 (e.g., embedded and encapsulated, or surrounded and encapsulated, by the matrix of conformable material) between cells 12 or between one cell 12 and an outer surface of the matrix of conformable material 14. The electronic component and the array of individual electrochemical cells 12 may be embedded in and encapsulated by the matrix of conformable material 12, for example by molding or covering with a film, to form an entire electronics/battery assembly. In yet other embodiments, stretchable (elastomeric) circuits with conductors and components may also be embedded in and encapsulated by the matrix of conformable material 14. Such embodiments produce a single integrated flexible/elastic unit comprising both electronic components and a power supply (the electrochemical cells 12), all of which are protected by the matrix of conformable material 14.
In some embodiments, the electrochemical cells 12 are connected in series and/or in parallel to one another by flexible conductors 24 that electrically connect the respective electrochemical cells 12. While the illustrated embodiment includes two flexible conductors 24 on the top (
When an electronic component 20 is included, it may be virtually any type of sensor. In some embodiments, the electronic component 20 may be a physiological sensor that measures a physiological characteristic or condition. Representative example sensors 20 include but are not limited to heart rate sensors, EKG sensors, nerve impulse sensors, glucose sensors, galvanic skin response sensors, hydration sensors, sweat sensors, and body temperature sensors, although virtually any type of sensor could be used. The battery pack assemblies 10 may also further comprise structure or a medical device capable of providing treatment for a sensed condition, such as a drug delivery system that is activated by a signal from the electronic component 20 (for example, an injection of insulin in response to glucose monitoring), electrical therapy for an abnormal heart rate (such as defibrillation), wound sterilization, and healing (e.g., bone growth stimulation), as further described with reference to
In other embodiments, the electronic component 20 may be a location sensor or a biometric sensor. Representative sensors include, but are not limited to, a GPS sensor, an accelerometer, a gyroscope, a pedometer, etc. In representative examples, these types of sensors may be used in battery pack assemblies that are combined with sportswear to monitor sports performance. In other embodiments, the battery pack with a location sensor, an accelerometer, and/or a moisture sensor may be affixed to a non-planar surface of a package for shipment tracking.
The flexible outer shell 16 comprises an outer shell material having a skin-like feel for enhancing and facilitating user comfort. The outer shell material comprises a material having one or more of the following characteristics: a failure stretch ratio of 1.1 to 1.8, preferably between 1.2 and 1.7, and more preferably between 1.3 and 1.6; an ultimate tensile strength between 1 and 50 MPa, preferably between 15 and 40 MPa, more preferably between 20 and 40 MPa, and more preferably between 15 and 35 MPa; or a Young's modulus of between 5 kPa and 140 MPa, preferably between 20 MPa and 100 MPa, and more preferably between 30 MPa and 80 MPa.
In some embodiments, the outer shell material comprises a hardness value as defined by ASTM Standard D2240-15 between HOOO-S 10 and 90 A, preferably between HOO-5 and 30 A, and more preferably between HOO-10 and HOO-50. In other embodiments, the hardness may be greater than HOOO-S 10, or less than 90 A, preferably between HOOO-S 10 and 90 A.
In some embodiments, the outer shell material comprises an elongation break between 350% and 1,000%, preferably an elongation break between 500% and 900%, and more preferably between 600% and 900%. In other embodiments, the elongation break may be greater than 350%, or less than 1,000%, preferably between 100% and 1500%.
In some embodiments, the outer shell material comprises a 100% modulus (i.e., tensile stress at 100% elongation) of less than 86 psi, preferably a 100% modulus between 8 psi and 86 psi, and more preferably about 10 psi.
In some embodiments, the outer shell material comprises a tensile strength of less than 50 MPa, or a tensile strength of greater than 15 MPa, preferably a tensile strength between 15 and 40 MPa, and more preferably about 25 MPa.
In some embodiments, the outer shell material comprises an elastomer. Elastomers in the form of liquid precursors may be used to embed and encapsulate the individual electrochemical cells 12, for example by pouring the liquid elastomer into a mold that contains the electrochemical cells 12 connected together by the flexible conductors 24, and then by curing the elastomer (for example by drying or heating or letting a two-part liquid elastomer cure over time and/or temperature or by exposure to UV light or radiation). The liquid elastomer may alternatively be applied by dipping or spraying the electrochemical cells 12 and then initiating the curing process. In some embodiments, silicone rubbers suitable for casting, similar to those used for skin effects and movie effects may be particularly advantageous. Suitable silicone rubbers suitable for casting include but are not limited to BODY DOUBLE™ Silk (Bentley Advanced Materials), BODY DOUBLE™ Standard Set (Bentley Advanced Materials), PlatSil® Gels (Polytek Development Corp.), ECO-FLEX™ Series Silicone Rubbers (Smooth-On, Inc.), Smooth-On Dragon Skin™ (Smooth-On, Inc.), or ELASTOSIL® RTV-2 (Wacker). Other materials including other silicones, or other materials, having the characteristics described herein may also be used. In other embodiments, hot melt glues or low pressure molding materials, such as Henkel Technomelt® AS 8998 polyolefin hot melt adhesive having an elongation break of 733% and a hardness of Shore 10 A, may be used to embed and encapsulate the array of electrochemical cells.
Encapsulation can also be achieved by covering the electrochemical cells 12 with thin sheets of elastomeric substrates that are held together with adhesives. In some embodiments, the borders of the substrates and/or the areas around the edges of the batteries may be heat sealed to secure the electrochemical cells 12 in place. For example, the electrochemical cells 12 may be placed on a sheet of thin elastomer coated with an adhesive and then wired together with the flexible conductors 24. Another layer of adhesive coated elastomer film may then be pressed on top of the electrochemical cells 12, thereby providing a matrix of conformable material fully surrounding and encapsulating the electrochemical cells 12. The flexible conductors 24 may exit the encapsulation along the bond line between the two adjacent adhesive layers or at another desired location. In some embodiments, tapes such as 3M Schotchwrap® tape 50 with an elongation break of 200% or 3M Industrial Protective film 7070UV with an elongation break of 635%, may be used to surround and encapsulate the array of electrochemical cells.
In some embodiments, the flexible outer shell material is laminated around the individual electrochemical cells 12 so that the individual electrochemical cells 12 are surrounded and encapsulated by the outer shell material, as illustrated in
In some embodiments, the outer shell material comprises an adhesive 30 (
Turning now to
As illustrated in
Returning now to
As illustrated particularly in
Additionally, the flexible outer shell may have a thickness to length ratio of between 1:2 and 1:30, preferably between 1:5 and 1:20, and more preferably between 1:10 and 1:15.
Generally, more axes of bending accommodate skin bending modes and thus advantageously a more comfortable fit for a user. Circular, hexagonal, or octagonal (more generally polygonal) arrays may be preferred, such as the arrays illustrated in
Turning now to
The flexible conductors 24 may comprise highly conducting materials that are flexible and resistant to cracking when bent repeatedly. These types of materials, particularly when the materials are formed to provide the conductor 24 with the stress relieving shapes described above, result in the longest usable life of the battery pack assembly 10. In some embodiments, the flexible conductors 24 may comprise copper, nickel, stainless steel, brass, other metals or alloys, carbon fibers, conductive polymers or combinations of these materials. The electrical conductors are relatively thin to allow maximum flexibility without unacceptable Voltage loss during discharge or charge. In some embodiments, the electrical conductors may comprise 36 gage enameled copper magnet wire, which has a diameter of about 0.14 mm. However, diameters of between about 0.05 mm and about 0.5 mm have been found to balance flexibility with failure due to fatigue. Advantageously, flexible conductors with thicknesses in the disclosed ranges generally are more fatigue resistant due to the support given to the flexible conductors by the flexible outer shell. This support, in turn, advantageously allows smaller gage wires to be used than would be possible if the flexible conductors were exposed and not supported by a matrix material, thereby enhancing flexibility and elasticity characteristics of the battery pack assembly.
The flexible conductors 24 may be attached to the electrochemical cells 12 in various ways; such as resistance welding, ultrasonic welding, laser welding, brazing, soldering or the use of conductive polymers or adhesives.
Turning now to
Turning now to
The control assembly was discharged at 0.8 mA continuously at room temperature until a voltage of 2.0 V was reached.
Stretching: the assembly was stretched along the long dimension of the outer shell by 10% more than the relaxed dimension continuously for 5,000 cycles. After 5,000 cycles, the assembly was discharged at 0.8 mA continuously at room temperature until a voltage of 2.0 V was reached.
Bending: the assembly was bent over a 0.625″ diameter mandrel and then relaxed to its normal shape. Bending cycles were performed at a rate of 22 per minute continuously until 5,000 cycles were achieved. After 5,000 cycles, the battery was discharged at 0.8 mA continuously, at room temperature, until a Voltage of 2.0V was reached.
The results of the tests, as illustrated in
While certain electrochemical cell 12 array configurations are illustrated herein, electrochemical cells 12 that are spaced apart by substantially regular intervals provide relatively uniform overall mechanical properties and are therefore generally preferred in one embodiment for the user. Specific geometric arrangements of electrochemical cells 12, particularly with three or more axes of symmetry, coupled with the size and geometry of the outer shell material being optionally adapted for the specific use, and with the size and geometry of the electrical interconnections, particularly the stress relieving shapes described above, between cells results in improved flexibility and elasticity of the battery assembly thereby providing greater comfort and enhanced wearability and functionality to the user. Individual electrochemical cells in the array may comprise the same or different sizes and may be circular, oval, rectangular or any other suitable shape. Depending on application requirements, the battery pack assembly 10 may take on virtually any outer shape and may have one or more through holes provided in various locations therein at the desired location of the hole or by cutting the hole in a desired space between electrochemical cells 12, for example, to allow a sensor to be disposed in the resulting hole such that it can directly contact skin of the user.
The disclosed battery pack assemblies are relatively thin and have mechanical properties similar enough to skin to feel comfortable when attached by a suitable adhesive to a human body. These battery pack assemblies facilitate skin-attached sensors or other devices that can be worn for longer periods of time with less irritation and discomfort to the user. The disclosed battery pack assemblies advantageously provide a continuous, uninterrupted interconnection between the battery contacts and the sensor contacts. While described as facilitating skin contact, it should be understood that the disclosed battery pack assemblies need not be used in this fashion, but instead may be incorporated into an article of clothing such as, for example, an arm band or the article shown in
The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”
Every document cited herein, including any cross referenced or related patent or application and any patent application or patent to which this application claims priority or benefit thereof, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.
| Number | Date | Country | |
|---|---|---|---|
| 63150659 | Feb 2021 | US |
